Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-27-36
E.N. Savelyeva, T.V. Burikova, D.E. Savelyev
A comprehensive multi-scale study of the capacitive space was carried out, which allows at different levels to obtain data on the type, morphology and distribution of the hollow space of the rocks of the Domanic stratum of one of the deposits in the northern part of the Bashkir arch. It has been shown that the reservoir properties of the rocks are quite low, while most of the voids are filled with highly viscous hydrocarbons. Siliceous-carbonate and carbonaceous-siliceous highcarbonaceous rocks have the best reservoir properties. The void space in the core samples is mainly of the porous-fractured type, the cavernporous-fractured type is locally noted. The formation of voids is due to both sedimentation and post-sedimentation factors and is associated with the processes of recrystallization, dolomitization, leaching and cracking. Microtomographic studies of high-angle-related rocks made it possible to study local zones and obtain data on the microstructure and capacitive characteristics of the void space in areas not accessible for decoding by other methods. It has been shown that a significant part of the voids in high-carbon rocks is confined to the shells of tentaculites and there is an increase in porosity in these areas.
{"title":"COMPREHENSIVE STUDY OF THE STRUCTURE OF THE HOLLOW SPACE OF DOMANIC DEPOSITS OF ONE OF THE ME-WATCHMEN OF THE NORTHERN PART OF THE BASHKIR ARCH (REPUBLIC OF BASHKORTOSTAN)","authors":"E.N. Savelyeva, T.V. Burikova, D.E. Savelyev","doi":"10.17122/ngdelo-2023-3-27-36","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-27-36","url":null,"abstract":"A comprehensive multi-scale study of the capacitive space was carried out, which allows at different levels to obtain data on the type, morphology and distribution of the hollow space of the rocks of the Domanic stratum of one of the deposits in the northern part of the Bashkir arch. It has been shown that the reservoir properties of the rocks are quite low, while most of the voids are filled with highly viscous hydrocarbons. Siliceous-carbonate and carbonaceous-siliceous highcarbonaceous rocks have the best reservoir properties. The void space in the core samples is mainly of the porous-fractured type, the cavernporous-fractured type is locally noted. The formation of voids is due to both sedimentation and post-sedimentation factors and is associated with the processes of recrystallization, dolomitization, leaching and cracking. Microtomographic studies of high-angle-related rocks made it possible to study local zones and obtain data on the microstructure and capacitive characteristics of the void space in areas not accessible for decoding by other methods. It has been shown that a significant part of the voids in high-carbon rocks is confined to the shells of tentaculites and there is an increase in porosity in these areas.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"69 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86093127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The work describes a method of real-time 3D modeling of mechanical properties over the entire field area for the purposes of hydraulic fracturing. The uniqueness of this modeling approach is associated with the prompt acquisition of mechanical properties along the well paths of the field, which is especially important in conditions of insufficient geomechanics data. Traditional three-dimensional geomechanical modeling is a time-consuming and resource-intensive process. The data often describe the mechanical properties and stress-strain state of the rocks within the current drilling or development sector of the field and do not take into account the interwell space, especially in poorly drilled areas of the field. The method of real-time 3D geomechanical modeling makes it possible to quantify values of minimum horizontal stress used in hydraulic fracturing simulators, as well as static and dynamic Young's modulus and Poisson's ratio over the entire field area using the optimal amount of resources and in a shorter time. Based on the built three-dimensional cubes of elastic properties and stresses, correct data were obtained in the inter-well space, their vertical and lateral changes were analyzed, and frac design data were obtained at any well drilled through the simulated targets of the field. This paper covers the Arlanskoye, Znamenskoye and Yugomashevskoye fields (Bashneft PJSC). The target targets are carbonate deposits: Kashira and Podolsk strata of the Arlanskoye field, Tournaisian strata of the Znamensky field and Bashkir-Vereisky strata of the Yugomashevsky field. For the carbonate rocks of the target targets, laboratory core studies were carried out to determine elastic properties, and stable regional core-core relationships were obtained in the intervals of lower and middle Carboniferous carbonate deposits. 1D geomechanical models were built in RN-SIGMA software 84 wells at the intervals of the study targets. In current 3D geological models are introduced and distributed values of Young's modulus, Poisson's coefficient and minimum horizontal stress gradient is calculated. Analysis of changes in geomechanical properties by area, for each study object was carried out and data were obtained to create frac designs for 15,000 wells.
{"title":"EXPRESS 3D GEOMECHANICAL MODELING FOR INPUT TO HYDRAULIC FRACTURING ON CARBONATE OILFIELDS OF BASHKORTOSTAN REPUBLIC","authors":"V.S. Arzhantsev, E.Yu. Lobova, M.V. Drebushchak, G.B. Zhanadelova, E.K. Mitrofanova, P.A. Vishnevskii","doi":"10.17122/ngdelo-2023-3-49-59","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-49-59","url":null,"abstract":"The work describes a method of real-time 3D modeling of mechanical properties over the entire field area for the purposes of hydraulic fracturing. The uniqueness of this modeling approach is associated with the prompt acquisition of mechanical properties along the well paths of the field, which is especially important in conditions of insufficient geomechanics data. \u0000Traditional three-dimensional geomechanical modeling is a time-consuming and resource-intensive process. The data often describe the mechanical properties and stress-strain state of the rocks within the current drilling or development sector of the field and do not take into account the interwell space, especially in poorly drilled areas of the field. The method of real-time 3D geomechanical modeling makes it possible to quantify values of minimum horizontal stress used in hydraulic fracturing simulators, as well as static and dynamic Young's modulus and Poisson's ratio over the entire field area using the optimal amount of resources and in a shorter time. \u0000Based on the built three-dimensional cubes of elastic properties and stresses, correct data were obtained in the inter-well space, their vertical and lateral changes were analyzed, and frac design data were obtained at any well drilled through the simulated targets of the field. \u0000This paper covers the Arlanskoye, Znamenskoye and Yugomashevskoye fields (Bashneft PJSC). The target targets are carbonate deposits: Kashira and Podolsk strata of the Arlanskoye field, Tournaisian strata of the Znamensky field and Bashkir-Vereisky strata of the Yugomashevsky field. \u0000For the carbonate rocks of the target targets, laboratory core studies were carried out to determine elastic properties, and stable regional core-core relationships were obtained in the intervals of lower and middle Carboniferous carbonate deposits. \u00001D geomechanical models were built in RN-SIGMA software 84 wells at the intervals of the study targets. In current 3D geological models are introduced and distributed values of Young's modulus, Poisson's coefficient and minimum horizontal stress gradient is calculated. Analysis of changes in geomechanical properties by area, for each study object was carried out and data were obtained to create frac designs for 15,000 wells.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"8 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88889516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-177-186
A. Malinin, V. Sitdikov, A.A. Kurilov, A. Makatrov
The work presents the results of studies aimed at analyzing the morphology and dimensional distribution of cementites and pores/microcracks in bainite steel used as tubing couplings during fluid transportation. For the first time, the method of small-angle X-ray scattering (SAXS) has demonstrated the possibility of analyzing not only secondary phases (particles, precipitates), but also shows the potential to expand the limits of applicability of this method for analyzing the morphology and dimensional distribution of pores/microcracks that originated both during casting and heat treatment and during subsequent operation of the tubing. The SAXS approach was adapted, taking into account the shape of cementites/pores, the relationship and ordering of cementites/pores in three-dimensional space, the factor of scale and absorption, analyzed volume and background radiation when processing scattering curves. The analysis of the scattering curves obtained on the transmission revealed cylindrical cementites with a diameter of 26 nm and a length of 180 nm, as well as manganese sulfides of an elliptical shape. Analysis of scattering curves measured in reflection mode has been shown to detect cylindrical nanopores/microcracks 36 nm in diameter and 170 nm in length, as well as spherical macropores 700 nm in diameter. To validate the obtained data, microstructure studies were carried out by scanning and transmission electron microscopy methods, which showed a convincing convergence of results between them. Nature and causes of identified pores in bainite steel are discussed.
{"title":"SMALL ANGLE X-RAY SCATTERING UNIT FOR ANALYSIS OF SECONDARY NANOPHASES AND PORES IN BAINITE STEEL","authors":"A. Malinin, V. Sitdikov, A.A. Kurilov, A. Makatrov","doi":"10.17122/ngdelo-2023-3-177-186","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-177-186","url":null,"abstract":"The work presents the results of studies aimed at analyzing the morphology and dimensional distribution of cementites and pores/microcracks in bainite steel used as tubing couplings during fluid transportation. For the first time, the method of small-angle X-ray scattering (SAXS) has demonstrated the possibility of analyzing not only secondary phases (particles, precipitates), but also shows the potential to expand the limits of applicability of this method for analyzing the morphology and dimensional distribution of pores/microcracks that originated both during casting and heat treatment and during subsequent operation of the tubing. The SAXS approach was adapted, taking into account the shape of cementites/pores, the relationship and ordering of cementites/pores in three-dimensional space, the factor of scale and absorption, analyzed volume and background radiation when processing scattering curves. The analysis of the scattering curves obtained on the transmission revealed cylindrical cementites with a diameter of 26 nm and a length of 180 nm, as well as manganese sulfides of an elliptical shape. Analysis of scattering curves measured in reflection mode has been shown to detect cylindrical nanopores/microcracks 36 nm in diameter and 170 nm in length, as well as spherical macropores 700 nm in diameter. To validate the obtained data, microstructure studies were carried out by scanning and transmission electron microscopy methods, which showed a convincing convergence of results between them. Nature and causes of identified pores in bainite steel are discussed.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"8 19 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90289498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-113-122
E.A. Bannikov
This article discusses the problems identified by the author in the implementation of the function of reducing the material balance unconvergence of hydrocarbon media in the medium-tonnage production of liquefied natural gas, and also outlines ways to solve them. The definition of the concept of material balance is given. A review of existing automated systems for balancing the material balance of hydrocarbon media in the production of liquefied natural gas is given. Structural problems that arise during the implementation of the function of balancing the balance are determined. Such influencing errors are described as: error due to the influence of heterogeneity and instability of liquefied natural gas; error due to the unreliability of the determination of residues in technological pipelines and apparatuses; error due to inaccuracy in determining the flow rate of gaseous media at metering units that are part of the licensed technology and gas carrier ships. A new concept of the function of balance reduction is described. The requirements for the error of measurement units for hydrocarbon media are given, taking into account the status of the metering unit and the measurement method used. Shown is a material flow diagram of the liquefied natural gas production process. A recommendation is given on how to improve the accuracy of the implementation of the function of reducing the material balance of hydrocarbon media in the production of liquefied natural gas. The place of the automated MES-system of material balance in the structure of production accounting is shown.
{"title":"THE CONCEPT OF IMPLEMENTING THE FUNCTION OF REDUCING THE MATERIAL BALANCE UNCONVERGENCE OF HYDROCARBON MEDIA IN THE PRODUCTION OF LIQUEFIED NATURAL GAS","authors":"E.A. Bannikov","doi":"10.17122/ngdelo-2023-3-113-122","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-113-122","url":null,"abstract":"This article discusses the problems identified by the author in the implementation of the function of reducing the material balance unconvergence of hydrocarbon media in the medium-tonnage production of liquefied natural gas, and also outlines ways to solve them. The definition of the concept of material balance is given. A review of existing automated systems for balancing the material balance of hydrocarbon media in the production of liquefied natural gas is given. Structural problems that arise during the implementation of the function of balancing the balance are determined. Such influencing errors are described as: error due to the influence of heterogeneity and instability of liquefied natural gas; error due to the unreliability of the determination of residues in technological pipelines and apparatuses; error due to inaccuracy in determining the flow rate of gaseous media at metering units that are part of the licensed technology and gas carrier ships. \u0000A new concept of the function of balance reduction is described. The requirements for the error of measurement units for hydrocarbon media are given, taking into account the status of the metering unit and the measurement method used. Shown is a material flow diagram of the liquefied natural gas production process. A recommendation is given on how to improve the accuracy of the implementation of the function of reducing the material balance of hydrocarbon media in the production of liquefied natural gas. The place of the automated MES-system of material balance in the structure of production accounting is shown.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"2 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90229417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-201-209
F. D. Baldenko, S. A. Kovalevskiy
Progressive Cavity Pumps (PCP) are becoming more and more common in various industries. In the oil and gas sector, PCP are widely used in downhole pumping units for oil production, as well as multiphase pumps for transporting gas-liquid mixtures. In recent decades, PCP have been widely used in the drilling mud circulation systems in fine cleaning units using centrifuges, as well as in various environmental projects. At the same time, industrial experience shows that in order to increase the efficiency of the PCP in various technological processes in the oil, construction, food and other industries, it is necessary to clarify some provisions of the theory and practice of using single-screw hydraulic machines in nonstandard operating conditions. One of these issues, which has not yet been fully reflected in scientific and reference publications, is the study of the process of filling screw working cavities in the case of pumping high-viscosity fluids. The article discusses the theoretical foundations of modeling the process of filling the PCP and proposes dependencies for determining the filling factor, which allows for a reasonable approach to the choice of geometric and operational parameters of the pump in a wide range of changes in the properties of pumped products.
{"title":"ABOUT THE FILLING FACTOR OF PROGRESSIVE CAVITY PUMPS","authors":"F. D. Baldenko, S. A. Kovalevskiy","doi":"10.17122/ngdelo-2023-3-201-209","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-201-209","url":null,"abstract":"Progressive Cavity Pumps (PCP) are becoming more and more common in various industries. In the oil and gas sector, PCP are widely used in downhole pumping units for oil production, as well as multiphase pumps for transporting gas-liquid mixtures. In recent decades, PCP have been widely used in the drilling mud circulation systems in fine cleaning units using centrifuges, as well as in various environmental projects. At the same time, industrial experience shows that in order to increase the efficiency of the PCP in various technological processes in the oil, construction, food and other industries, it is necessary to clarify some provisions of the theory and practice of using single-screw hydraulic machines in nonstandard operating conditions. One of these issues, which has not yet been fully reflected in scientific and reference publications, is the study of the process of filling screw working cavities in the case of pumping high-viscosity fluids. \u0000The article discusses the theoretical foundations of modeling the process of filling the PCP and proposes dependencies for determining the filling factor, which allows for a reasonable approach to the choice of geometric and operational parameters of the pump in a wide range of changes in the properties of pumped products.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"39 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74093091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-232-242
T. T. Yumalin, R. Salikhov, V. Abdrakhmanov, T. Salikhov, K. Vazhdaev, T.D. Muntyanova
Advances in commercial compact integrated circuit technology have made it possible to integrate wireless transceivers, signal processing, and sensors in a single integrated circuit package. Such solutions provide a low-cost means of communication with the physical world and can have applications in areas as diverse as security, production management, research and environmental monitoring. We outline the challenges of system design for a distributed sensor network in which each node has a limited power source and communication channel. The nodes must establish a synchronous network with multiple hops, determine locations, and communicate for purposes such as relaying a signal and transmitting data to a server device. The confluence of low-cost wireless, computing, and sensors has created a new generation of smart devices. The use of tens and thousands of such devices in self-organizing networks has led to the creation of a new technology called wireless sensor networks. In this article, we will consider an example of the use of such a network based on the Bluetooth Low Energy (BLE) wireless data transfer protocol, which gave a serious impetus to the development of wireless sensors. Together with organic polymers, which are used as a sensor layer, it is possible to achieve high energy efficiency and selective sensitivity in monitoring. It is also worth noting the fast and cheap production of electronics based on organic polymers. Due to the semiconductor and flexible properties of organic semiconductor materials, flexible organic electronics has become the core of our technology. The field of organic electronics is entering a commercial phase. The appearance on the market of the first prototypes based on organic transistors made from solutions is intended to expand the existing presence in the market of organic electronic devices. We'll look at some of the key performance requirements for working devices. We will also look at some of the important advances in semiconductor design and device manufacturing technologies and discuss some of the technical challenges that are needed to optimize next generation products.
{"title":"WIRELESS ENVIRONMENTAL QUALITY MONITORING SYSTEM","authors":"T. T. Yumalin, R. Salikhov, V. Abdrakhmanov, T. Salikhov, K. Vazhdaev, T.D. Muntyanova","doi":"10.17122/ngdelo-2023-3-232-242","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-232-242","url":null,"abstract":"Advances in commercial compact integrated circuit technology have made it possible to integrate wireless transceivers, signal processing, and sensors in a single integrated circuit package. Such solutions provide a low-cost means of communication with the physical world and can have applications in areas as diverse as security, production management, research and environmental monitoring. We outline the challenges of system design for a distributed sensor network in which each node has a limited power source and communication channel. The nodes must establish a synchronous network with multiple hops, determine locations, and communicate for purposes such as relaying a signal and transmitting data to a server device. The confluence of low-cost wireless, computing, and sensors has created a new generation of smart devices. The use of tens and thousands of such devices in self-organizing networks has led to the creation of a new technology called wireless sensor networks. In this article, we will consider an example of the use of such a network based on the Bluetooth Low Energy (BLE) wireless data transfer protocol, which gave a serious impetus to the development of wireless sensors. Together with organic polymers, which are used as a sensor layer, it is possible to achieve high energy efficiency and selective sensitivity in monitoring. It is also worth noting the fast and cheap production of electronics based on organic polymers. Due to the semiconductor and flexible properties of organic semiconductor materials, flexible organic electronics has become the core of our technology. The field of organic electronics is entering a commercial phase. The appearance on the market of the first prototypes based on organic transistors made from solutions is intended to expand the existing presence in the market of organic electronic devices. We'll look at some of the key performance requirements for working devices. We will also look at some of the important advances in semiconductor design and device manufacturing technologies and discuss some of the technical challenges that are needed to optimize next generation products.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"7 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75476380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-96-102
A.G. Latypov, R.M. Sultanov, A.T. Chanysheva, I. V. Ozden
The article presents and discusses the results of experimental studies of the processes of mutual substitution (displacement) of immiscible fluids, proceeding by the mechanism of impregnation and drainage in layered-heterogeneous reservoirs with hydrodynamically connected and separated interlayers. Physical modeling of filtration processes, taking into account the similarity criteria, made it possible to establish that during the mutual substitution of immiscible fluids at the phase boundary and lithological differences, nonequilibrium capillary phenomena develop, which, through the action of capillary forces, significantly affect fluid filtration and saturation distribution in an inhomogeneous porous medium. In order to eliminate the influence of the viscous instability factor on the motion of the displacement front, the processes of displacement of a less viscous fluid by a more viscous one were studied. It has been established that non-equilibrium capillary phenomena manifest themselves most intensively in reservoirs with a heterophilic surface, where capillary forces can initiate or block fluid flows between differently permeable interlayers. It has been experimentally shown that in layered-heterogeneous reservoirs with a heterophilic filtration surface in the interlayers, capillary phenomena largely determine the nature of the movement of the fluid displacement front (from the almost complete suppression of the “run-up” of the displacement fronts in the interlayers to the formation of an advanced front in the low-permeability interlayer). In order to exclude the influence of errors of a systematic or random nature on the results of the experiments, their reproducibility and the significance of differences were assessed using the statistical criteria of Student and Cochran, which showed the reliability of the above conclusions. The results obtained indicate the dominant effect of crossflows between interlayers on the formation of the displacement front of immiscible fluids in layered-heterogeneous reservoirs, especially with a heterophilic wettability characteristic, as well as the possibility of controlling this process by means of physicochemical modification of the wettability conditions of the filtration surface, for example, using surface active substances (surfactants) of various nature and structure.
{"title":"ON INFLUENCE OF PHYSICAL AND CHEMICAL MODIFICATION OF WETTABILITY OF FILTRATION SURFACE ON INTERCHANGEABILITY OF IMMISCIBLE FLUIDS IN RESERVOIR FORMATIONS","authors":"A.G. Latypov, R.M. Sultanov, A.T. Chanysheva, I. V. Ozden","doi":"10.17122/ngdelo-2023-3-96-102","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-96-102","url":null,"abstract":"The article presents and discusses the results of experimental studies of the processes of mutual substitution (displacement) of immiscible fluids, proceeding by the mechanism of impregnation and drainage in layered-heterogeneous reservoirs with hydrodynamically connected and separated interlayers. \u0000Physical modeling of filtration processes, taking into account the similarity criteria, made it possible to establish that during the mutual substitution of immiscible fluids at the phase boundary and lithological differences, nonequilibrium capillary phenomena develop, which, through the action of capillary forces, significantly affect fluid filtration and saturation distribution in an inhomogeneous porous medium. In order to eliminate the influence of the viscous instability factor on the motion of the displacement front, the processes of displacement of a less viscous fluid by a more viscous one were studied. \u0000It has been established that non-equilibrium capillary phenomena manifest themselves most intensively in reservoirs with a heterophilic surface, where capillary forces can initiate or block fluid flows between differently permeable interlayers. It has been experimentally shown that in layered-heterogeneous reservoirs with a heterophilic filtration surface in the interlayers, capillary phenomena largely determine the nature of the movement of the fluid displacement front (from the almost complete suppression of the “run-up” of the displacement fronts in the interlayers to the formation of an advanced front in the low-permeability interlayer). In order to exclude the influence of errors of a systematic or random nature on the results of the experiments, their reproducibility and the significance of differences were assessed using the statistical criteria of Student and Cochran, which showed the reliability of the above conclusions. \u0000The results obtained indicate the dominant effect of crossflows between interlayers on the formation of the displacement front of immiscible fluids in layered-heterogeneous reservoirs, especially with a heterophilic wettability characteristic, as well as the possibility of controlling this process by means of physicochemical modification of the wettability conditions of the filtration surface, for example, using surface active substances (surfactants) of various nature and structure.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"121 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89875643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-60-71
A. Lysenkov, E.M. Sunagatova, D.V. Gilimkhanov, D.S. Kostin
Hydrochloric acid treatments are most widely used to intensify oil production from carbonate reservoirs. But despite a wealth of experience in the use of hydrochloric acid treatments, the results of treatments often do not reach the planned values of oil production growth. Efficiency of acid exposure depends on the depth of penetration of the hydrochloric acid solution into the thickness of the productive reservoir, which, in turn, is conditioned by the degree of reactive activity of the acid composition. It is important to achieve the creation of filtration channels in the zone remote from the borehole, which will lead to an improvement in the filtration characteristics of the bottomhole formation zone to the proper extent. Therefore, in order to achieve the best result when planning acid exposure, it is important to consider the geological and physical properties of the object to be treated and select the appropriate formulation of the acid composition. The reaction rate constant is a parameter that allows you to take into account the compatibility of the acid composition and the geological and physical conditions of the productive reservoir. This parameter characterizes the rate of reaction between substances. However, a generally accepted method for studying the kinetic parameters of the reaction of acid compositions with carbonate formation rock has not yet been developed, which leads to low reproducibility of experimental results. The purpose of the research presented in the article is to develop a methodology for studying the kinetics of the reaction of hydrochloric acid with carbonate rock and to create a unified approach to determining the reaction rate constant, characterized by the greatest reproducibility of the results. The experimental part of the work was carried out in several stages, including the preparation of core material, the preparation of hydrochloric acid solution and its thermostating, and the further conducting of four series of studies at the PIK-OSG volumetric setup to determine the optimal acid-rock ratio, identify the optimal weight of the core material and establish the optimal coarseness of its grinding. The obtained results of experiments on the study of methodological aspects of the study of the rate constant of the reaction of hydrochloric acid with carbonate rock showed that the experiments should be conducted in conditions of an excess of rock relative to acid, in this case the mass of the core sample and the coarseness of the grinding of the core material will not affect the error in determining the reaction rate constant.
{"title":"METHODOLOGICAL ASPECTS OF THE STUDY OF THE RATE CONSTANT OF THE REACTION OF HYDROCHLORIC ACID WITH CARBONATE FORMATION ROCK","authors":"A. Lysenkov, E.M. Sunagatova, D.V. Gilimkhanov, D.S. Kostin","doi":"10.17122/ngdelo-2023-3-60-71","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-60-71","url":null,"abstract":"Hydrochloric acid treatments are most widely used to intensify oil production from carbonate reservoirs. But despite a wealth of experience in the use of hydrochloric acid treatments, the results of treatments often do not reach the planned values of oil production growth. Efficiency of acid exposure depends on the depth of penetration of the hydrochloric acid solution into the thickness of the productive reservoir, which, in turn, is conditioned by the degree of reactive activity of the acid composition. It is important to achieve the creation of filtration channels in the zone remote from the borehole, which will lead to an improvement in the filtration characteristics of the bottomhole formation zone to the proper extent. Therefore, in order to achieve the best result when planning acid exposure, it is important to consider the geological and physical properties of the object to be treated and select the appropriate formulation of the acid composition. \u0000The reaction rate constant is a parameter that allows you to take into account the compatibility of the acid composition and the geological and physical conditions of the productive reservoir. This parameter characterizes the rate of reaction between substances. However, a generally accepted method for studying the kinetic parameters of the reaction of acid compositions with carbonate formation rock has not yet been developed, which leads to low reproducibility of experimental results. The purpose of the research presented in the article is to develop a methodology for studying the kinetics of the reaction of hydrochloric acid with carbonate rock and to create a unified approach to determining the reaction rate constant, characterized by the greatest reproducibility of the results. The experimental part of the work was carried out in several stages, including the preparation of core material, the preparation of hydrochloric acid solution and its thermostating, and the further conducting of four series of studies at the PIK-OSG volumetric setup to determine the optimal acid-rock ratio, identify the optimal weight of the core material and establish the optimal coarseness of its grinding. \u0000The obtained results of experiments on the study of methodological aspects of the study of the rate constant of the reaction of hydrochloric acid with carbonate rock showed that the experiments should be conducted in conditions of an excess of rock relative to acid, in this case the mass of the core sample and the coarseness of the grinding of the core material will not affect the error in determining the reaction rate constant.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"12 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89006270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-220-231
D. Mironova, I.V. Baranov, D.S. Kapustin, Yu.V. Kozhukhov, I.A. Svinkin
Nowadays, the state level has set the task of forming a systematic approach to secondary resources management that were obtained from production waste, as well as increasing the efficiency of resource useage throughout the production life cycle. This is evidenced by the initiation and implementation of the sectoral program «Usage of secondary resources and secondary raw materials from waste in industrial production», supervised by the Ministry of Industry and Trade of the Russian Federation since November 2022, Decree of the President of the Russian Federation of November 4, 2020 No. 666 «On Reducing Greenhouse Gas Emissions», Strategy «Socio-Economic Development of the Russian Federation with Low Greenhouse Gas Emissions by 2050» approved by order of the Government of the Russian Federation of October 29, 2021 No. 3052-r and Federal Law of 02.07.2021 No. 296-FZ «On Limiting Greenhouse Gas Emissions» (entered into force 30.12.2021). To achieve economic, social and environmental sustainability, it is necessary to interact between enterprises, universities and authorities in order to stimulates the application of the principles of circular economics. This article discusses the problem of utilization and use of associated petroleum gas, as well as analyzes the possibilities of applying the concept of industrial symbiosis both to reduce the produced resources and minimize the loss of materials during use. The relevance of this topic is justified by an increase in the volume of associated petroleum gas (APG) production and, accordingly, the damage caused to the environment due to its combustion. In addition, insufficient financial investment hinders the successful development of innovative economic schemes such as industrial symbiosis. The methods of APG disposal and processing used at present were analyzed, the negative consequences of combustion, sanctions imposed by the state and restrictions on their application were investigated. According to the authors, an important problem is the lack of new technologies, as well as the low level of their technological readiness, which leads to the use of most APG as energy resources instead of its processing. The study briefly discusses the main methods of processing associated petroleum gas, their advantages and disadvantages, as well as possible recommended areas of APG use. The effectiveness and feasibility of introducing the concept of industrial symbiosis in the oil industry is justified. As a result of the study, the authors of this article proposed the most optimal option for processing and further use of the obtained components, the probability and reality of the implementation of the described processing method is also described.
{"title":"APPLICATION OF INDUSTRIAL SYMBIOSIS CONCEPT TO OIL AND GAS SECTOR ON EXAMPLE OF ASSOCIATED PETROLEUM GAS PROCESSING","authors":"D. Mironova, I.V. Baranov, D.S. Kapustin, Yu.V. Kozhukhov, I.A. Svinkin","doi":"10.17122/ngdelo-2023-3-220-231","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-220-231","url":null,"abstract":"Nowadays, the state level has set the task of forming a systematic approach to secondary resources management that were obtained from production waste, as well as increasing the efficiency of resource useage throughout the production life cycle. This is evidenced by the initiation and implementation of the sectoral program «Usage of secondary resources and secondary raw materials from waste in industrial production», supervised by the Ministry of Industry and Trade of the Russian Federation since November 2022, Decree of the President of the Russian Federation of November 4, 2020 No. 666 «On Reducing Greenhouse Gas Emissions», Strategy «Socio-Economic Development of the Russian Federation with Low Greenhouse Gas Emissions by 2050» approved by order of the Government of the Russian Federation of October 29, 2021 No. 3052-r and Federal Law of 02.07.2021 No. 296-FZ «On Limiting Greenhouse Gas Emissions» (entered into force 30.12.2021). \u0000To achieve economic, social and environmental sustainability, it is necessary to interact between enterprises, universities and authorities in order to stimulates the application of the principles of circular economics. This article discusses the problem of utilization and use of associated petroleum gas, as well as analyzes the possibilities of applying the concept of industrial symbiosis both to reduce the produced resources and minimize the loss of materials during use. The relevance of this topic is justified by an increase in the volume of associated petroleum gas (APG) production and, accordingly, the damage caused to the environment due to its combustion. In addition, insufficient financial investment hinders the successful development of innovative economic schemes such as industrial symbiosis. \u0000The methods of APG disposal and processing used at present were analyzed, the negative consequences of combustion, sanctions imposed by the state and restrictions on their application were investigated. According to the authors, an important problem is the lack of new technologies, as well as the low level of their technological readiness, which leads to the use of most APG as energy resources instead of its processing. The study briefly discusses the main methods of processing associated petroleum gas, their advantages and disadvantages, as well as possible recommended areas of APG use. \u0000The effectiveness and feasibility of introducing the concept of industrial symbiosis in the oil industry is justified. As a result of the study, the authors of this article proposed the most optimal option for processing and further use of the obtained components, the probability and reality of the implementation of the described processing method is also described.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"12 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82936360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-17DOI: 10.17122/ngdelo-2023-3-169-176
K.A. Mammadov, N. S. Gamidova, R.K. Gazieva, A.V. Akhmedova, G.B. Ibragimova, T.S. Aliyev
One of the urgent problems in the oil industry is the reliable protection of oil field equipment from corrosion. With this in mind, as a result of laboratory studies, three compositions were developed based on phospholipids, fatty acids, phosphoric acid, nitrogen compounds, asidol, naphthenic acids and light gas oil. The complexity of the composition gives the resulting compositions multifunctionality and allows them to be used in various aggressive conditions. In laboratory conditions, the effect of these compositions on the corrosion rate of metals and on the vital activity of sulfate reducing bacteria (SVB) was studied. Based on the obtained results, the concentration of the compositions (500 mg/l) was established, providing a protective effect against corrosion, which was 94–95 %, and the degree of suppression of SVB was 97–99 %. Field tests of corrosion inhibitors also yielded positive results: the protective effect against corrosion was 89–90 %, and the degree of SVB suppression was 92–97 %.
{"title":"DEVELOPMENT AND APPLICATION OF NEW COMPOSITIONS TO IMPROVE THE EFFICIENCY OF OIL FIELD EQUIPMENT OPERATION","authors":"K.A. Mammadov, N. S. Gamidova, R.K. Gazieva, A.V. Akhmedova, G.B. Ibragimova, T.S. Aliyev","doi":"10.17122/ngdelo-2023-3-169-176","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-169-176","url":null,"abstract":"One of the urgent problems in the oil industry is the reliable protection of oil field equipment from corrosion. With this in mind, as a result of laboratory studies, three compositions were developed based on phospholipids, fatty acids, phosphoric acid, nitrogen compounds, asidol, naphthenic acids and light gas oil. The complexity of the composition gives the resulting compositions multifunctionality and allows them to be used in various aggressive conditions. \u0000In laboratory conditions, the effect of these compositions on the corrosion rate of metals and on the vital activity of sulfate reducing bacteria (SVB) was studied. Based on the obtained results, the concentration of the compositions (500 mg/l) was established, providing a protective effect against corrosion, which was 94–95 %, and the degree of suppression of SVB was 97–99 %. \u0000Field tests of corrosion inhibitors also yielded positive results: the protective effect against corrosion was 89–90 %, and the degree of SVB suppression was 92–97 %.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"52 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77561321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}