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COMPREHENSIVE STUDY OF THE STRUCTURE OF THE HOLLOW SPACE OF DOMANIC DEPOSITS OF ONE OF THE ME-WATCHMEN OF THE NORTHERN PART OF THE BASHKIR ARCH (REPUBLIC OF BASHKORTOSTAN) 巴什克尔拱(巴什科尔托斯坦共和国)北段一处梅-守望者(m - watchman)强石矿床空穴结构的综合研究
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-27-36
E.N. Savelyeva, T.V. Burikova, D.E. Savelyev
A comprehensive multi-scale study of the capacitive space was carried out, which allows at different levels to obtain data on the type, morphology and distribution of the hollow space of the rocks of the Domanic stratum of one of the deposits in the northern part of the Bashkir arch. It has been shown that the reservoir properties of the rocks are quite low, while most of the voids are filled with highly viscous hydrocarbons. Siliceous-carbonate and carbonaceous-siliceous highcarbonaceous rocks have the best reservoir properties. The void space in the core samples is mainly of the porous-fractured type, the cavernporous-fractured type is locally noted. The formation of voids is due to both sedimentation and post-sedimentation factors and is associated with the processes of recrystallization, dolomitization, leaching and cracking. Microtomographic studies of high-angle-related rocks made it possible to study local zones and obtain data on the microstructure and capacitive characteristics of the void space in areas not accessible for decoding by other methods. It has been shown that a significant part of the voids in high-carbon rocks is confined to the shells of tentaculites and there is an increase in porosity in these areas.
通过对巴什基尔拱架北段某矿床的容性空间进行综合多尺度研究,在不同层次上获得了该区某矿床多晶层岩石空性空间的类型、形态和分布数据。研究表明,岩石储层物性很低,大部分孔隙被高粘性烃所充填。碳酸硅质和碳硅质高碳质岩储集性能最好。岩心样品中孔隙空间以孔隙-裂缝型为主,局部以洞穴孔-裂缝型为主。孔隙的形成受沉积和后沉积双重因素的影响,与再结晶、白云化、淋溶和裂解等过程有关。高角度相关岩石的显微层析成像研究使得研究局部区域成为可能,并获得了其他方法无法解码的区域的孔隙空间微观结构和电容特性的数据。研究表明,高碳岩石的孔隙很大一部分局限于触手体的壳层,并且在这些区域孔隙度增加。
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引用次数: 0
EXPRESS 3D GEOMECHANICAL MODELING FOR INPUT TO HYDRAULIC FRACTURING ON CARBONATE OILFIELDS OF BASHKORTOSTAN REPUBLIC 对巴什科尔托斯坦碳酸盐岩油田水力压裂输入进行三维地质力学建模
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-49-59
V.S. Arzhantsev, E.Yu. Lobova, M.V. Drebushchak, G.B. Zhanadelova, E.K. Mitrofanova, P.A. Vishnevskii
The work describes a method of real-time 3D modeling of mechanical properties over the entire field area for the purposes of hydraulic fracturing. The uniqueness of this modeling approach is associated with the prompt acquisition of mechanical properties along the well paths of the field, which is especially important in conditions of insufficient geomechanics data. Traditional three-dimensional geomechanical modeling is a time-consuming and resource-intensive process. The data often describe the mechanical properties and stress-strain state of the rocks within the current drilling or development sector of the field and do not take into account the interwell space, especially in poorly drilled areas of the field. The method of real-time 3D geomechanical modeling makes it possible to quantify values of minimum horizontal stress used in hydraulic fracturing simulators, as well as static and dynamic Young's modulus and Poisson's ratio over the entire field area using the optimal amount of resources and in a shorter time. Based on the built three-dimensional cubes of elastic properties and stresses, correct data were obtained in the inter-well space, their vertical and lateral changes were analyzed, and frac design data were obtained at any well drilled through the simulated targets of the field. This paper covers the Arlanskoye, Znamenskoye and Yugomashevskoye fields (Bashneft PJSC). The target targets are carbonate deposits: Kashira and Podolsk strata of the Arlanskoye field, Tournaisian strata of the Znamensky field and Bashkir-Vereisky strata of the Yugomashevsky field. For the carbonate rocks of the target targets, laboratory core studies were carried out to determine elastic properties, and stable regional core-core relationships were obtained in the intervals of lower and middle Carboniferous carbonate deposits. 1D geomechanical models were built in RN-SIGMA software 84 wells at the intervals of the study targets. In current 3D geological models are introduced and distributed values of Young's modulus, Poisson's coefficient and minimum horizontal stress gradient is calculated. Analysis of changes in geomechanical properties by area, for each study object was carried out and data were obtained to create frac designs for 15,000 wells.
该工作描述了一种用于水力压裂的整个油田区域的机械特性实时3D建模方法。这种建模方法的独特之处在于,它可以快速获取油田井眼轨迹的力学特性,这在地质力学数据不足的情况下尤为重要。传统的三维地质力学建模是一个耗时且资源密集的过程。这些数据通常描述的是油田当前钻井或开发区域内岩石的力学特性和应力-应变状态,而没有考虑井间空间,特别是在钻井不足的区域。实时三维地质力学建模方法可以量化水力压裂模拟器中使用的最小水平应力值,以及整个油田区域的静态和动态杨氏模量和泊松比,从而在更短的时间内获得最佳资源。基于所建立的三维弹性属性和应力立方体,获得了井间空间的正确数据,分析了井间空间的垂向和横向变化,并获得了钻穿油田模拟靶区的任意一口井的压裂设计数据。本文涵盖了Bashneft PJSC的Arlanskoye、Znamenskoye和Yugomashevskoye油田。目标目标是碳酸盐岩矿床:Arlanskoye油田的Kashira和Podolsk地层,Znamensky油田的Tournaisian地层和Yugomashevsky油田的Bashkir-Vereisky地层。针对目标靶区碳酸盐岩进行了岩心研究,确定了弹性性质,并在中、下石炭统碳酸盐岩储层段获得了稳定的区域岩心关系。利用RN-SIGMA软件在研究目标层段的84口井中建立了一维地质力学模型。介绍了现有的三维地质模型,计算了杨氏模量、泊松系数和最小水平应力梯度的分布值。对每个研究对象按区域进行地质力学特性变化分析,并获得数据,为15,000口井创建压裂设计。
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引用次数: 0
SMALL ANGLE X-RAY SCATTERING UNIT FOR ANALYSIS OF SECONDARY NANOPHASES AND PORES IN BAINITE STEEL 用于贝氏体钢中二次纳米相和气孔分析的小角x射线散射装置
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-177-186
A. Malinin, V. Sitdikov, A.A. Kurilov, A. Makatrov
The work presents the results of studies aimed at analyzing the morphology and dimensional distribution of cementites and pores/microcracks in bainite steel used as tubing couplings during fluid transportation. For the first time, the method of small-angle X-ray scattering (SAXS) has demonstrated the possibility of analyzing not only secondary phases (particles, precipitates), but also shows the potential to expand the limits of applicability of this method for analyzing the morphology and dimensional distribution of pores/microcracks that originated both during casting and heat treatment and during subsequent operation of the tubing. The SAXS approach was adapted, taking into account the shape of cementites/pores, the relationship and ordering of cementites/pores in three-dimensional space, the factor of scale and absorption, analyzed volume and background radiation when processing scattering curves. The analysis of the scattering curves obtained on the transmission  revealed cylindrical cementites with a diameter of 26 nm and a length of 180 nm, as well as manganese sulfides of an elliptical shape. Analysis of scattering curves measured in reflection mode has been shown to detect cylindrical nanopores/microcracks 36 nm in diameter and 170 nm in length, as well as spherical macropores 700 nm in diameter. To validate the obtained data, microstructure studies were carried out by scanning and transmission electron microscopy methods, which showed a convincing convergence of results between them. Nature and causes of identified pores in bainite steel are discussed.
本文介绍了流体输送过程中用作油管接头的贝氏体钢中渗碳体和孔隙/微裂纹的形貌和尺寸分布的研究结果。小角度x射线散射(SAXS)方法首次证明了不仅可以分析二次相(颗粒、析出相),而且还显示了扩大该方法适用范围的潜力,可用于分析在铸造、热处理以及随后的油管操作过程中产生的孔隙/微裂纹的形貌和尺寸分布。采用SAXS方法,考虑了渗碳体/孔隙的形状、渗碳体/孔隙在三维空间中的关系和顺序、尺度和吸收因素,在处理散射曲线时分析了体积和背景辐射。对透射光散射曲线进行分析,发现了直径为26 nm、长度为180 nm的圆柱形渗碳体和椭圆形的硫化锰。在反射模式下测量的散射曲线分析表明,可以检测到直径为36 nm、长度为170 nm的圆柱形纳米孔/微裂纹,以及直径为700 nm的球形大孔。为了验证所获得的数据,通过扫描和透射电子显微镜方法进行了微观结构研究,结果表明两者之间的结果具有令人信服的收敛性。讨论了贝氏体钢中已识别气孔的性质及产生原因。
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引用次数: 0
THE CONCEPT OF IMPLEMENTING THE FUNCTION OF REDUCING THE MATERIAL BALANCE UNCONVERGENCE OF HYDROCARBON MEDIA IN THE PRODUCTION OF LIQUEFIED NATURAL GAS 实现液化天然气生产中烃类介质物料平衡不收敛功能的概念
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-113-122
E.A. Bannikov
This article discusses the problems identified by the author in the implementation of the function of reducing the material balance unconvergence of hydrocarbon media in the medium-tonnage production of liquefied natural gas, and also outlines ways to solve them. The definition of the concept of material balance is given. A review of existing automated systems for balancing the material balance of hydrocarbon media in the production of liquefied natural gas is given. Structural problems that arise during the implementation of the function of balancing the balance are determined. Such influencing errors are described as: error due to the influence of heterogeneity and instability of liquefied natural gas; error due to the unreliability of the determination of residues in technological pipelines and apparatuses; error due to inaccuracy in determining the flow rate of gaseous media at metering units that are part of the licensed technology and gas carrier ships. A new concept of the function of balance reduction is described. The requirements for the error of measurement units for hydrocarbon media are given, taking into account the status of the metering unit and the measurement method used. Shown is a material flow diagram of the liquefied natural gas production process. A recommendation is given on how to improve the accuracy of the implementation of the function of reducing the material balance of hydrocarbon media in the production of liquefied natural gas. The place of the automated MES-system of material balance in the structure of production accounting is shown.
本文论述了在中吨位液化天然气生产中实施减少烃类介质物料平衡不衔接功能时发现的问题,并提出了解决问题的方法。给出了物料平衡概念的定义。综述了液化天然气生产中现有的烃类介质物料平衡自动化系统。确定了平衡职能实施过程中出现的结构性问题。这种影响误差描述为:由于液化天然气的非均质性和不稳定性的影响而产生的误差;技术管道和设备中残留测定不可靠造成的误差;由于在作为许可技术和气体运输船的一部分的计量装置上确定气体介质流速不准确而导致的错误。提出了平衡缩减函数的新概念。考虑到计量装置的现状和所采用的计量方法,给出了对烃类介质计量装置的误差要求。所示为液化天然气生产过程的物料流程图。就如何提高液化天然气生产中烃类介质减少物质平衡功能的执行精度提出了建议。指出了物料衡算自动化mes系统在生产会计结构中的地位。
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引用次数: 0
ABOUT THE FILLING FACTOR OF PROGRESSIVE CAVITY PUMPS 关于螺杆泵的填充系数
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-201-209
F. D. Baldenko, S. A. Kovalevskiy
Progressive Cavity Pumps (PCP) are becoming more and more common in various industries.  In the oil and gas sector, PCP are widely used in downhole pumping units for oil production, as well as multiphase pumps for transporting gas-liquid mixtures.  In recent decades, PCP have been widely used in the drilling mud circulation systems in fine cleaning units using centrifuges, as well as in various environmental projects.  At the same time, industrial experience shows that in order to increase the efficiency of the PCP in various technological processes in the oil, construction, food and other industries, it is necessary to clarify some provisions of the theory and practice of using single-screw hydraulic machines in nonstandard operating conditions.  One of these issues, which has not yet been fully reflected in scientific and reference publications, is the study of the process of filling screw working cavities in the case of pumping high-viscosity fluids. The article discusses the theoretical foundations of modeling the process of filling the PCP and proposes dependencies for determining the filling factor, which allows for a reasonable approach to the choice of geometric and operational parameters of the pump in a wide range of changes in the properties of pumped products.
螺杆泵(PCP)在各个行业中越来越普遍。在油气行业,PCP广泛应用于井下采油抽油机,以及输送气液混合物的多相泵。近几十年来,PCP已广泛应用于离心机精清装置的钻井泥浆循环系统以及各种环境工程中。同时,工业经验表明,为了提高PCP在石油、建筑、食品等行业各种工艺过程中的效率,有必要明确在非标准工况下使用单螺杆液压机的一些理论和实践规定。其中一个尚未在科学和参考出版物中得到充分反映的问题是,在泵注高粘度流体的情况下,对螺杆工作腔填充过程的研究。本文讨论了PCP填充过程建模的理论基础,并提出了确定填充因子的依赖关系,这允许在泵产品特性的广泛变化中选择泵的几何和操作参数的合理方法。
{"title":"ABOUT THE FILLING FACTOR OF PROGRESSIVE CAVITY PUMPS","authors":"F. D. Baldenko, S. A. Kovalevskiy","doi":"10.17122/ngdelo-2023-3-201-209","DOIUrl":"https://doi.org/10.17122/ngdelo-2023-3-201-209","url":null,"abstract":"Progressive Cavity Pumps (PCP) are becoming more and more common in various industries.  In the oil and gas sector, PCP are widely used in downhole pumping units for oil production, as well as multiphase pumps for transporting gas-liquid mixtures.  In recent decades, PCP have been widely used in the drilling mud circulation systems in fine cleaning units using centrifuges, as well as in various environmental projects.  At the same time, industrial experience shows that in order to increase the efficiency of the PCP in various technological processes in the oil, construction, food and other industries, it is necessary to clarify some provisions of the theory and practice of using single-screw hydraulic machines in nonstandard operating conditions.  One of these issues, which has not yet been fully reflected in scientific and reference publications, is the study of the process of filling screw working cavities in the case of pumping high-viscosity fluids. \u0000The article discusses the theoretical foundations of modeling the process of filling the PCP and proposes dependencies for determining the filling factor, which allows for a reasonable approach to the choice of geometric and operational parameters of the pump in a wide range of changes in the properties of pumped products.","PeriodicalId":9748,"journal":{"name":"Chemical and Petroleum Engineering","volume":"39 1","pages":""},"PeriodicalIF":0.3,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74093091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
WIRELESS ENVIRONMENTAL QUALITY MONITORING SYSTEM 无线环境质量监测系统
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-232-242
T. T. Yumalin, R. Salikhov, V. Abdrakhmanov, T. Salikhov, K. Vazhdaev, T.D. Muntyanova
Advances in commercial compact integrated circuit technology have made it possible to integrate wireless transceivers, signal processing, and sensors in a single integrated circuit package. Such solutions provide a low-cost means of communication with the physical world and can have applications in areas as diverse as security, production management, research and environmental monitoring. We outline the challenges of system design for a distributed sensor network in which each node has a limited power source and communication channel. The nodes must establish a synchronous network with multiple hops, determine locations, and communicate for purposes such as relaying a signal and transmitting data to a server device. The confluence of low-cost wireless, computing, and sensors has created a new generation of smart devices. The use of tens and thousands of such devices in self-organizing networks has led to the creation of a new technology called wireless sensor networks. In this article, we will consider an example of the use of such a network based on the Bluetooth Low Energy (BLE) wireless data transfer protocol, which gave a serious impetus to the development of wireless sensors. Together with organic polymers, which are used as a sensor layer, it is possible to achieve high energy efficiency and selective sensitivity in monitoring. It is also worth noting the fast and cheap production of electronics based on organic polymers. Due to the semiconductor and flexible properties of organic semiconductor materials, flexible organic electronics has become the core of our technology. The field of organic electronics is entering a commercial phase. The appearance on the market of the first prototypes based on organic transistors made from solutions is intended to expand the existing presence in the market of organic electronic devices. We'll look at some of the key performance requirements for working devices. We will also look at some of the important advances in semiconductor design and device manufacturing technologies and discuss some of the technical challenges that are needed to optimize next generation products.
商业紧凑型集成电路技术的进步使得将无线收发器、信号处理和传感器集成到一个集成电路封装中成为可能。这种解决方案提供了一种与物理世界进行通信的低成本手段,可以在安全、生产管理、研究和环境监测等多种领域得到应用。我们概述了分布式传感器网络系统设计的挑战,其中每个节点具有有限的电源和通信信道。节点必须建立一个多跳的同步网络,确定位置,并为了中继信号和向服务器设备传输数据等目的进行通信。低成本无线、计算和传感器的融合创造了新一代智能设备。在自组织网络中使用成千上万个这样的设备导致了一种称为无线传感器网络的新技术的产生。在本文中,我们将考虑使用基于蓝牙低功耗(BLE)无线数据传输协议的这种网络的示例,该协议极大地推动了无线传感器的发展。与用作传感器层的有机聚合物一起,可以在监测中实现高能效和选择性灵敏度。同样值得注意的是,基于有机聚合物的电子产品的快速和廉价生产。由于有机半导体材料的半导体和柔性特性,柔性有机电子已经成为我们技术的核心。有机电子学领域正在进入商业化阶段。以有机晶体管为基础的第一个原型在市场上的出现是为了扩大现有的有机电子器件市场。我们将研究工作设备的一些关键性能要求。我们还将研究半导体设计和器件制造技术的一些重要进展,并讨论优化下一代产品所需的一些技术挑战。
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引用次数: 0
ON INFLUENCE OF PHYSICAL AND CHEMICAL MODIFICATION OF WETTABILITY OF FILTRATION SURFACE ON INTERCHANGEABILITY OF IMMISCIBLE FLUIDS IN RESERVOIR FORMATIONS 过滤表面润湿性的理化改性对储层非混相流体互换性的影响
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-96-102
A.G. Latypov, R.M. Sultanov, A.T. Chanysheva, I. V. Ozden
The article presents and discusses the results of experimental studies of the processes of mutual substitution (displacement) of immiscible fluids, proceeding by the mechanism of impregnation and drainage in layered-heterogeneous reservoirs with hydrodynamically connected and separated interlayers. Physical modeling of filtration processes, taking into account the similarity criteria, made it possible to establish that during the mutual substitution of immiscible fluids at the phase boundary and lithological differences, nonequilibrium capillary phenomena develop, which, through the action of capillary forces, significantly affect fluid filtration and saturation distribution in an inhomogeneous porous medium. In order to eliminate the influence of the viscous instability factor on the motion of the displacement front, the processes of displacement of a less viscous fluid by a more viscous one were studied. It has been established that non-equilibrium capillary phenomena manifest themselves most intensively in reservoirs with a heterophilic surface, where capillary forces can initiate or block fluid flows between differently permeable interlayers. It has been experimentally shown that in layered-heterogeneous reservoirs with a heterophilic filtration surface in the interlayers, capillary phenomena largely determine the nature of the movement of the fluid displacement front (from the almost complete suppression of the “run-up” of the displacement fronts in the interlayers to the formation of an advanced front in the low-permeability interlayer). In order to exclude the influence of errors of a systematic or random nature on the results of the experiments, their reproducibility and the significance of differences were assessed using the statistical criteria of Student and Cochran, which showed the reliability of the above conclusions. The results obtained indicate the dominant effect of crossflows between interlayers on the formation of the displacement front of immiscible fluids in layered-heterogeneous reservoirs, especially with a heterophilic wettability characteristic, as well as the possibility of controlling this process by means of physicochemical modification of the wettability conditions of the filtration surface, for example, using surface active substances (surfactants) of various nature and structure.
本文介绍并讨论了非混相流体相互取代(置换)过程的实验研究结果,从浸渍和排水的机制出发,探讨了层状非均质储层间水动力连接和分离的过程。考虑相似准则的过滤过程物理模拟表明,在相边界非混相流体相互替代和岩性差异的过程中,非平衡毛细现象的产生,通过毛细力的作用,显著影响非均匀多孔介质中流体的过滤和饱和度分布。为了消除粘性不稳定因素对位移锋运动的影响,研究了低粘性流体被高粘性流体置换的过程。已经确定,非平衡毛细管现象在具有异亲表面的油藏中表现得最为强烈,其中毛细管力可以启动或阻止流体在不同渗透性的夹层之间流动。实验表明,在层间具有亲异滤面的层状非均质储层中,毛细现象在很大程度上决定了流体驱替锋面的运动性质(从层间驱替锋面的“上升”几乎完全被抑制到低渗透层间驱替锋面的形成)。为了排除系统性或随机性误差对实验结果的影响,采用Student和Cochran的统计标准对实验结果的可重复性和差异的显著性进行了评估,表明了上述结论的可靠性。研究结果表明,在层状非均质储层中,层间交叉流动对非混相流体驱油前缘的形成起主导作用,特别是具有亲异润湿性特征的储层,并且可以通过物理化学修饰过滤表面的润湿性条件来控制这一过程,例如使用各种性质和结构的表面活性物质(表面活性剂)。
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引用次数: 0
METHODOLOGICAL ASPECTS OF THE STUDY OF THE RATE CONSTANT OF THE REACTION OF HYDROCHLORIC ACID WITH CARBONATE FORMATION ROCK 盐酸与碳酸盐岩反应速率常数的方法学研究
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-60-71
A. Lysenkov, E.M. Sunagatova, D.V. Gilimkhanov, D.S. Kostin
Hydrochloric acid treatments are most widely used to intensify oil production from carbonate reservoirs. But despite a wealth of experience in the use of hydrochloric acid treatments, the results of treatments often do not reach the planned values of oil production growth. Efficiency of acid exposure depends on the depth of penetration of the hydrochloric acid solution into the thickness of the productive reservoir, which, in turn, is conditioned by the degree of reactive activity of the acid composition. It is important to achieve the creation of filtration channels in the zone remote from the borehole, which will lead to an improvement in the filtration characteristics of the bottomhole formation zone to the proper extent. Therefore, in order to achieve the best result when planning acid exposure, it is important to consider the geological and physical properties of the object to be treated and select the appropriate formulation of the acid composition. The reaction rate constant is a parameter that allows you to take into account the compatibility of the acid composition and the geological and physical conditions of the productive reservoir. This parameter characterizes the rate of reaction between substances. However, a generally accepted method for studying the kinetic parameters of the reaction of acid compositions with carbonate formation rock has not yet been developed, which leads to low reproducibility of experimental results. The purpose of the research presented in the article is to develop a methodology for studying the kinetics of the reaction of hydrochloric acid with carbonate rock and to create a unified approach to determining the reaction rate constant, characterized by the greatest reproducibility of the results. The experimental part of the work was carried out in several stages, including the preparation of core material, the preparation of hydrochloric acid solution and its thermostating, and the further conducting of four series of studies at the PIK-OSG volumetric setup to determine the optimal acid-rock ratio, identify the optimal weight of the core material and establish the optimal coarseness of its grinding. The obtained results of experiments on the study of methodological aspects of the study of the rate constant of the reaction of hydrochloric acid with carbonate rock showed that the experiments should be conducted in conditions of an excess of rock relative to acid, in this case the mass of the core sample and the coarseness of the grinding of the core material will not affect the error in determining the reaction rate constant.
盐酸处理被广泛应用于碳酸盐储层的强化采油。但是,尽管在使用盐酸处理方面有丰富的经验,但处理结果往往达不到石油产量增长的计划值。酸暴露的效率取决于盐酸溶液渗透到生产储层厚度的深度,而这又取决于酸成分的反应活性程度。重要的是要在远离井眼的区域建立过滤通道,这将在一定程度上改善井底地层的过滤特性。因此,在规划酸暴露时,为了达到最佳效果,重要的是要考虑待处理对象的地质和物理性质,选择合适的酸成分配方。反应速率常数是一个参数,它可以让你考虑到酸成分与生产油藏的地质和物理条件的相容性。这个参数表示物质之间的反应速率。然而,目前还没有一种被普遍接受的研究碳酸盐岩与酸组成反应动力学参数的方法,导致实验结果的重现性较低。本文提出的研究目的是开发一种研究盐酸与碳酸盐岩反应动力学的方法,并建立一种统一的方法来确定反应速率常数,其特点是结果的可重复性最大。实验部分的工作分几个阶段进行,包括岩心材料的制备,盐酸溶液及其恒温剂的制备,以及在PIK-OSG体积装置上进一步进行四个系列的研究,以确定最佳酸岩比,确定最佳岩心材料重量和确定最佳磨砂粗度。在研究盐酸与碳酸盐岩反应速率常数的方法学方面所获得的实验结果表明,实验应在岩石相对于酸过量的条件下进行,在这种情况下,岩心样品的质量和岩心材料研磨的粗糙程度不会影响测定反应速率常数的误差。
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引用次数: 0
APPLICATION OF INDUSTRIAL SYMBIOSIS CONCEPT TO OIL AND GAS SECTOR ON EXAMPLE OF ASSOCIATED PETROLEUM GAS PROCESSING 工业共生概念在油气行业的应用——以伴生气加工为例
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-220-231
D. Mironova, I.V. Baranov, D.S. Kapustin, Yu.V. Kozhukhov, I.A. Svinkin
Nowadays, the state level has set the task of forming a systematic approach to secondary resources management that were obtained from production waste, as well as increasing the efficiency of resource useage throughout the production life cycle. This is evidenced by the initiation and implementation of the sectoral program «Usage of secondary resources and secondary raw materials from waste in industrial production», supervised by the Ministry of Industry and Trade of the Russian Federation since November 2022, Decree of the President of the Russian Federation of November 4, 2020 No. 666 «On Reducing Greenhouse Gas Emissions», Strategy «Socio-Economic Development of the Russian Federation with Low Greenhouse Gas Emissions by 2050» approved by order of the Government of the Russian Federation of October 29, 2021 No. 3052-r and Federal Law of 02.07.2021  No. 296-FZ «On Limiting Greenhouse Gas Emissions» (entered into force 30.12.2021). To achieve economic, social and environmental sustainability, it is necessary to interact between enterprises, universities and authorities in order to stimulates the application of the principles of circular economics. This article discusses the problem of utilization and use of associated petroleum gas, as well as analyzes the possibilities of applying the concept of industrial symbiosis both to reduce the produced resources and minimize the loss of materials during use. The relevance of this topic is justified by an increase in the volume of associated petroleum gas (APG) production and, accordingly, the damage caused to the environment due to its combustion. In addition, insufficient financial investment hinders the successful development of innovative economic schemes such as industrial symbiosis. The methods of APG disposal and processing used at present were analyzed, the negative consequences of combustion, sanctions imposed by the state and restrictions on their application were investigated. According to the authors, an important problem is the lack of new technologies, as well as the low level of their technological readiness, which leads to the use of most APG as energy resources instead of its processing. The study briefly discusses the main methods of processing associated petroleum gas, their advantages and disadvantages, as well as possible recommended areas of APG use. The effectiveness and feasibility of introducing the concept of industrial symbiosis in the oil industry is justified. As a result of the study, the authors of this article proposed the most optimal option for processing and further use of the obtained components, the probability and reality of the implementation of the described processing method is also described.
目前,国家层面的任务是形成从生产废弃物中获得的二次资源的系统管理方法,并提高整个生产生命周期的资源利用效率。从2022年11月起,由俄罗斯联邦工业和贸易部监督的“工业生产中二次资源和二次原材料的利用”部门计划的启动和实施,以及2020年11月4日俄罗斯联邦总统令第666号“关于减少温室气体排放”,证明了这一点。俄罗斯联邦政府2021年10月29日第3052-r号命令和2021年7月2日第296-FZ号联邦法《关于限制温室气体排放》批准的“到2050年实现俄罗斯联邦社会经济发展战略”(2021年12月30日生效)。为了实现经济、社会和环境的可持续性,有必要在企业、大学和当局之间进行互动,以促进循环经济原则的应用。本文讨论了伴生气的利用问题,并分析了应用工业共生概念减少生产资源和减少使用过程中物质损失的可能性。伴生石油天然气(APG)产量的增加,以及其燃烧对环境造成的破坏,证明了这一主题的相关性。此外,财政投资不足阻碍了工业共生等创新经济计划的成功发展。分析了目前使用的APG处置和处理方法,探讨了燃烧产生的负面影响、国家对其实施的制裁以及对其应用的限制。作者认为,一个重要的问题是缺乏新技术,以及它们的技术准备水平较低,这导致大多数APG被用作能源而不是其加工。简要讨论了伴生气的主要处理方法、优缺点,以及APG可能的推荐应用领域。论证了在石油工业中引入工业共生概念的有效性和可行性。根据研究结果,本文作者提出了对得到的零件进行加工和进一步利用的最优方案,并对所述加工方法实施的概率和现实性进行了描述。
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引用次数: 0
DEVELOPMENT AND APPLICATION OF NEW COMPOSITIONS TO IMPROVE THE EFFICIENCY OF OIL FIELD EQUIPMENT OPERATION 新组合物的开发与应用,提高油田设备的作业效率
IF 0.3 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-17 DOI: 10.17122/ngdelo-2023-3-169-176
K.A. Mammadov, N. S. Gamidova, R.K. Gazieva, A.V. Akhmedova, G.B. Ibragimova, T.S. Aliyev
One of the urgent problems in the oil industry is the reliable protection of oil field equipment from corrosion. With this in mind, as a result of laboratory studies, three compositions were developed based on phospholipids, fatty acids, phosphoric acid, nitrogen compounds, asidol, naphthenic acids and light gas oil. The complexity of the composition gives the resulting compositions multifunctionality and allows them to be used in various aggressive conditions. In laboratory conditions, the effect of these compositions on the corrosion rate of metals and on the vital activity of sulfate reducing bacteria (SVB) was studied. Based on the obtained results, the concentration of the compositions (500 mg/l) was established, providing a protective effect against corrosion, which was 94–95 %, and the degree of suppression of SVB was 97–99 %. Field tests of corrosion inhibitors also yielded positive results: the protective effect against corrosion was 89–90 %, and the degree of SVB suppression was 92–97 %.
如何可靠地保护油田设备免受腐蚀是石油工业迫切需要解决的问题之一。考虑到这一点,作为实验室研究的结果,开发了基于磷脂,脂肪酸,磷酸,氮化合物,asidol,环烷酸和轻气油的三种组合物。该组合物的复杂性使所得到的组合物具有多功能性,并允许它们在各种侵略性条件下使用。在实验室条件下,研究了这些成分对金属腐蚀速率和硫酸盐还原菌(SVB)生命活性的影响。在此基础上,确定了该组合物的浓度(500 mg/l),对腐蚀的防护效果为94 ~ 95%,对SVB的抑制程度为97 ~ 99%。缓蚀剂的现场试验也取得了积极的结果:对腐蚀的保护效果为89 - 90%,对SVB的抑制程度为92 - 97%。
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引用次数: 0
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Chemical and Petroleum Engineering
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