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A comprehensive analysis of photovoltaic panel integrated thermoelectric cooling system for enhanced power generation 光伏板集成热电冷却系统增强发电能力的综合分析
Pub Date : 2024-08-21 DOI: 10.1002/appl.202400100
Rahul Chandel, Shyam Singh Chandel, Deo Prasad, Ram Prakash Dwivedi

The integrated photovoltaic-thermoelectric cooling systems (PV-TECS) can be used to enhance the performance and life expectancy of commercial PV power plants for sustainable power generation. The objective of the study is to assess the efficacy of PV-TECS to address these concerns. In this study, computational fluid dynamics/finite element method analysis and experimental investigation of photovoltaic micro-modules (PVMM-2) with a thermoelectric cooling system and a reference system without it (PVMM-1), is carried out under real outdoor conditions. The logged data and infrared thermal imaging analysis results show that thermoelectric cooling is very effective in maintaining a consistent PV back temperature difference of 18.24°C between PVMM-2 and the reference system, even reaching subzero temperature when the reference module operates close to 60°C. The simulated results are found to be in close agreement with the experimental results (R2 values of 0.83 and 0.94) which allows accurate prediction of system performance under actual solar loading conditions. Further analysis shows that PV-TECS can be effectively used in photovoltaic power plants for efficiency enhancement with a gain in the range of 1%–22% for a monocrystalline PV module depending on location and type of integration. The study is of interest for further research to develop industrial applications.

集成光伏热电冷却系统(PV- tecs)可用于提高商业光伏电站的性能和预期寿命,实现可持续发电。本研究的目的是评估PV-TECS在解决这些问题方面的功效。本研究在室外实际条件下,对光伏微模块(PVMM-2)进行了热电冷却系统和参考系统(PVMM-1)的计算流体力学/有限元方法分析和实验研究。测井数据和红外热成像分析结果表明,热电冷却非常有效地保持了PVMM-2与参考系统之间18.24°C的PV背温差,甚至在参考模块接近60°C时达到零下温度。模拟结果与实验结果(R2分别为0.83和0.94)吻合较好,可以准确预测系统在实际太阳能负载条件下的性能。进一步的分析表明,PV- tecs可以有效地用于光伏发电厂,提高效率,单晶光伏组件的增益在1%-22%之间,具体取决于集成的位置和类型。该研究对进一步研究开发工业应用具有重要意义。
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引用次数: 0
Physicochemical and sensory properties of fermented milk supplemented with sundried African horned melon 加干非洲角瓜发酵乳的理化及感官特性
Pub Date : 2024-08-13 DOI: 10.1002/appl.202400102
Brenda Micheni, Eddy Owaga, Beatrice Mugendi

African horned melon (AHM) (Cucumis metuliferus), indigenous to Kenya. It contains high polyphenol and antioxidant content, yet remains underutilized in food products. This study sought to increase the utilization of AHM by developing a supplemented milk product and evaluating the effects of sundried AHM powder on the physicochemical and sensory properties of the fermented milk product. The fermented milk was supplemented with three different forms of AHM powder: whole fruit, peel, and seed, at concentrations of 0.5%, 0.7%, and 1% w/v. Physicochemical parameters such as pH, total titratable acidity (TTA), syneresis, texture, and viscosity were measured, alongside sensory acceptability assessments. Statistical analysis demonstrated significant differences (p < 0.05) in physicochemical and sensory properties between the control (did not contain AHM) and supplemented samples, particularly at higher concentrations and extended storage periods. The inclusion of AHM powder markedly influenced the fermented milk's properties, with increased TTA and syneresis in samples with higher melon powder concentrations. TTA ranged between 0.32% and 0.46% among all samples during storage which were comparatively higher than the recommended values for fermented milk products at 0.3%. pH findings range was 4.22 and 4.58. The pH range between 4.2 and 4.6 is recommended by FDA for fermented milk. Syneresis were between 2% and 13%. Texture was between 1.24 and 3.95 N. Viscosity was between 1.67 and 3.87 cP. Sensory scores ranged from 8.00 to 2.67 during storage. Fruit seed powder (FSP1) recorded the lowest amount of pH. Control maintained a higher score in the sensory attributes.

非洲角瓜(AHM) (metuliferus),原产于肯尼亚。它含有高多酚和抗氧化剂含量,但在食品中仍未充分利用。本研究旨在通过开发一种补充乳制品,并评估干燥的AHM粉对发酵乳制品的物理化学和感官特性的影响,以提高AHM的利用率。在发酵乳中添加三种不同形式的AHM粉:全果、果皮和种子,浓度分别为0.5%、0.7%和1% w/v。测量了物理化学参数,如pH值,总可滴定酸度(TTA),协同作用,质地和粘度,以及感官可接受性评估。统计分析表明,对照(不含AHM)和补充样品在理化和感官特性上存在显著差异(p < 0.05),特别是在较高浓度和较长的储存期限下。甜瓜粉的掺入对发酵乳的性能有显著影响,甜瓜粉浓度越高,发酵乳的TTA和synesis越高。所有样品在贮存期间的TTA在0.32%至0.46%之间,相对高于发酵乳制品的推荐值0.3%。pH值范围为4.22 ~ 4.58。FDA推荐发酵乳的pH值范围在4.2到4.6之间。在2%到13%之间。质地在1.24 ~ 3.95 N之间。黏度在1.67 ~ 3.87 cP之间。贮藏期间感官评分为8.00 ~ 2.67分。果子粉(FSP1)的ph值最低,而对照的感官属性得分较高。
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引用次数: 0
The effect of three types of heat treatment on the hardness and corrosion resistance of Al 2014 alloy 三种热处理方式对Al 2014合金硬度和耐蚀性的影响
Pub Date : 2024-08-13 DOI: 10.1002/appl.202400134
Ansari Shadab Azhar Nazeer Iqbal, M Abdur Rahman, Hussain H. Naveed

Al 2014 is a high-strength aluminum alloy widely used in the aerospace and automotive industries for its mechanical strength. This research examines the effects of three heat treatment processes—retrogression and re-aging (RRA), T6 standard aging, and a modified RRA with high-temperature pre-aging—on the hardness and corrosion resistance of Al 2014. Polarization studies using potentiodynamic electrochemical methods in a 3.5 wt% sodium chloride solution were conducted to evaluate the corrosion resistance. The results showed that heat treatment, which causes precipitation hardening, shifted the corrosion potential (E) toward a more noble direction. The formation of Al2Cu precipitates is associated with improved corrosion resistance. Additionally, samples treated with the T6 process exhibited a higher corrosion current density compared to untreated Al 2014 alloy samples, indicating superior corrosion resistance. Analysis of corroded surfaces using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS) showed evidence of general and pitting corrosion, with distinct patterns among the three heat treatment processes. A comparison of the results revealed that the T6 standard aging process provided the best combination of hardness and corrosion resistance. This was likely due to the formation of stable precipitates during aging. The results also indicated that the RRA process showed good performance, suggesting it is a viable alternative when a balance between hardness and toughness is required. The modified RRA with high-temperature pre-aging resulted in lower performance, likely due to overaging, which reduced hardness and corrosion resistance. These findings highlight the significance of heat treatment in improving the corrosion resistance of Al 2014 alloy. This suggests that particular processes can enhance the alloy's durability in corrosive environments, potentially leading to a longer lifespan and reduced maintenance costs. The T6 standard aging process offers the best balance of enhanced hardness and corrosion resistance for Al 2014 alloy, making it ideal for extending lifespan and reducing maintenance costs in corrosive environments. Careful selection of heat treatment is crucial based on specific alloy performance requirements.

Al 2014是一种高强度铝合金,因其机械强度高,广泛应用于航空航天和汽车工业。本研究考察了三种热处理工艺——回归再时效(RRA)、T6标准时效和高温预时效改性RRA对Al 2014硬度和耐蚀性的影响。采用动电位电化学方法在3.5 wt%氯化钠溶液中进行极化研究,以评价其耐蚀性。结果表明,热处理引起沉淀硬化,使腐蚀电位(E)向更高贵的方向移动。Al2Cu析出相的形成与耐蚀性的提高有关。此外,与未经处理的Al 2014合金样品相比,经过T6工艺处理的样品显示出更高的腐蚀电流密度,表明具有更好的耐腐蚀性。利用扫描电子显微镜(SEM)和能量色散x射线能谱(EDS)对腐蚀表面进行分析,发现腐蚀表面存在一般腐蚀和点蚀,三种热处理工艺之间存在明显的腐蚀模式。结果表明,T6标准时效工艺能提供最佳的硬度和耐蚀性组合。这可能是由于在老化过程中形成了稳定的沉淀物。结果还表明,RRA工艺表现出良好的性能,表明当需要在硬度和韧性之间取得平衡时,RRA工艺是一种可行的替代方案。经高温预时效处理的改性RRA,可能由于过时效而导致性能降低,硬度和耐腐蚀性降低。这些发现凸显了热处理对提高Al 2014合金耐蚀性的重要意义。这表明,特定的工艺可以提高合金在腐蚀性环境中的耐久性,从而有可能延长使用寿命并降低维护成本。T6标准时效工艺为Al 2014合金提供了增强硬度和耐腐蚀性的最佳平衡,使其成为延长寿命和降低腐蚀环境中维护成本的理想选择。根据特定的合金性能要求,仔细选择热处理是至关重要的。
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引用次数: 0
Cover Image: Volume 3 Issue 4 封面图片:第 3 卷第 4 期
Pub Date : 2024-08-11 DOI: 10.1002/appl.202470401

Applied Research is a multidisciplinary journal that focuses on bridging fundamental research and practical applications, supporting sustainable problem-solving and global initiatives. The journal covers high-quality research in fields such as Materials, Applied Physics, Chemistry, Applied Biology, Food Science, Engineering, Biomedical Sciences, and Social Sciences. Authors can submit various article types, including Reviews, Tutorials, and Research Articles. The journal aims to highlight innovative research that demonstrates the application of knowledge, methods, instrumentation, and technology into solutions.

应用研究》是一本多学科期刊,重点关注基础研究与实际应用之间的联系,支持可持续的问题解决和全球倡议。该期刊涵盖材料、应用物理、化学、应用生物学、食品科学、工程学、生物医学科学和社会科学等领域的高质量研究。作者可以提交各种类型的文章,包括综述、教程和研究文章。该期刊旨在突出创新研究,展示知识、方法、仪器和技术在解决方案中的应用。
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引用次数: 0
Analysis of the limitations of organic powder for high-temperature reprocessing of printed PLA parts 有机粉末用于PLA打印件高温再加工的局限性分析
Pub Date : 2024-08-07 DOI: 10.1002/appl.202400165
Leonardo Santana, João F. F. Machado, Guilherme M. O. Barra, Jorge Lino Alves

Fused filament fabrication (FFF) is the most predominant additive manufacturing technology, not only in the industry but also for many hobbyists. This technology's popularity is because it is inexpensive, user-friendly, and open source. However, compared to other manufacturing processes, like injection molding, FFF products still have some limitations, particularly mechanical properties. Despite this, some post-processing techniques have been developed to improve such properties. One of these techniques involves applying heat treatments (HT). The objective of these HTs is to densify these FFF products and increase the crystallization degree of the semi-crystalline polylactic acid (PLA). This kind of post-processing is claimed to be a viable way to improve mechanical properties. The reprocessing in a powder bed is a type of HT which prevents thermal distortion by using a powder as a mold for the FFF component. The powder should be low cost and have easy access for any user. In this work, this HT was performed in flexural samples with an organic powder (corn flour) and it has improved maximum flexural strength (MFS) and flexural modulus (FM) by 18% and 14%, respectively. The color of parts, before and after HT, was also measured and a slight modification of the response was observed due to the HT. Despite the gains in mechanical properties, it was verified that corn flour produces a considerable amount of smoke during this HT. Thus, it was performed a thermogravimetric analysis (TGA) in three types of powders, namely corn flour, coffee powder, and corn starch. It was concluded that starch is the best one, however considering that all three organic powders release smoke, it is advisable not to use them for HT.

熔丝制造(FFF)是最主要的增材制造技术,不仅在工业上,而且对许多爱好者来说。这项技术之所以受欢迎,是因为它价格低廉、用户友好且开源。然而,与注射成型等其他制造工艺相比,FFF产品仍有一些局限性,特别是机械性能。尽管如此,一些后处理技术已经被开发出来以改善这些特性。其中一项技术涉及应用热处理(HT)。目的是使FFF产品致密化,提高半结晶聚乳酸(PLA)的结晶度。这种后处理被认为是改善机械性能的可行方法。粉末床中的再加工是一种HT,通过使用粉末作为FFF组件的模具来防止热变形。这种粉末应该是低成本的,并且对任何用户来说都很容易获得。在这项工作中,用有机粉末(玉米粉)对弯曲样品进行了高温处理,它使最大弯曲强度(MFS)和弯曲模量(FM)分别提高了18%和14%。还测量了高温前后零件的颜色,并观察到由于高温引起的响应略有变化。尽管机械性能有所提高,但经证实玉米粉在高温加热过程中产生了相当多的烟雾。因此,对玉米粉、咖啡粉和玉米淀粉三种粉末进行热重分析(TGA)。结果表明,淀粉是最好的,但考虑到这三种有机粉末都有烟雾释放,不宜用于高温灭菌。
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引用次数: 0
Effect of magnesia additive on the morphology and physico-mechanical properties of kaolinitic clays ceramics 氧化镁添加剂对高岭石粘土陶瓷形貌及物理力学性能的影响
Pub Date : 2024-08-04 DOI: 10.1002/appl.202400053
Abdulhakeem Nurudeen, Ishaya Dagwa, Benjamin Ugheoke, Ibrahim Muhammad, Adiat Arogundade

Nigeria is rich in various minerals, including crude oil and solid minerals. However, despite this abundance, effectively utilizing these resources remains a challenge. Kaolin, also known as white China clay, is a crucial raw material used in industries such as ceramics, paper, paint, plastic, and welding electrodes. Despite its plentiful availability in Nigeria, kaolin has not been adequately exploited. Consequently, Nigeria spends approximately 14.35 million USD annually to import refined kaolin to meet local demand, due to the lack of capacity to process it to the required industrial standards. This study investigates the effect of magnesia (MgO) on the morphology and physico-mechanical properties of kaolinitic clay ceramics using the slip-casting method. Various analytical techniques were employed to examine the kaolin, including X-ray fluorescence (XRF), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscopy (SEM). Also, compressive and flexural tests were conducted. The XRF analysis revealed that all samples contained SiO2 (54.41%wt), Al2O3 (34.05%wt), and other trace elements. The main mineral phases identified were quartz, microcline, and orthoclase. Among the samples, 30–200 exhibited the highest compressive strength at 218 MPa, while the highest flexural rigidity was observed in sample 15–200. The results indicated that MgO significantly affected the properties of kaolin, as the control sample had a compressive strength of 59 MPa. The study also found that the quantities of additives should align with stoichiometric requirements. Results showed hypo-stoichiometry in samples 30–600 and 15–400, and hyper-stoichiometry in sample 60–200. XRF, XRD, and FTIR spectra confirmed the elemental and chemical compositions of the samples, while SEM analysis revealed the morphological structure. It was observed that increasing the magnesia content from 10% to 30% led to an increase in pore spaces within the samples. TGA analysis provided insights into the relationship between mass loss and temperature variation in the ceramic samples, While The DTG curves explain the endothermic phase changes over changes in temperature; at 50–150°C, loss of the water phase is complete, at 300–400°C burning of organic matter phase is achieved and at 500–700°C endothermic dihyroxylation phase begins forming armorphous meta-kaolin.

尼日利亚拥有丰富的各种矿产,包括原油和固体矿产。然而,尽管资源丰富,有效利用这些资源仍然是一个挑战。高岭土,也被称为白瓷土,是陶瓷、造纸、油漆、塑料和焊接电极等行业的重要原材料。尽管高岭土在尼日利亚储量丰富,但尚未得到充分利用。因此,由于缺乏将其加工成所需工业标准的能力,尼日利亚每年花费约1435万美元进口精制高岭土以满足当地需求。采用滑铸法研究了氧化镁对高岭石粘土陶瓷形貌和物理力学性能的影响。采用x射线荧光(XRF)、x射线衍射(XRD)、热重分析(TGA)、傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)等分析技术对高岭土进行了表征。此外,还进行了压缩和弯曲试验。XRF分析表明,样品中含有SiO2 (54.41%wt)、Al2O3 (34.05%wt)等微量元素。主要矿物相为石英、微斜长石和正长石。试件30-200的抗压强度最高,为218 MPa,试件15-200的抗弯刚度最高。结果表明,MgO对高岭土的性能影响显著,对照样品的抗压强度为59 MPa。该研究还发现,添加剂的数量应符合化学计量学要求。结果表明,样品30-600和15-400的化学计量量偏低,样品60-200的化学计量量较高。XRF, XRD和FTIR光谱证实了样品的元素和化学组成,SEM分析揭示了样品的形态结构。结果表明,当氧化镁含量从10%增加到30%时,孔隙空间增大。TGA分析揭示了陶瓷样品的质量损失和温度变化之间的关系,而DTG曲线解释了吸热相随温度变化的变化;在50-150°C时,水相完全损失,在300-400°C时,有机物相燃烧,在500-700°C时,吸热二羟基化相开始形成非晶间高岭土。
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引用次数: 0
Recent improvements in quantification of energy-dispersive X-ray spectra and maps in electron microscopy of semiconductors 半导体电子显微镜中能量色散x射线光谱和图量化的最新进展
Pub Date : 2024-07-30 DOI: 10.1002/appl.202300128
Thomas Walther

This tutorial-style article describes recent improvements in the quantitative application of energy-dispersive X-ray spectroscopy and mapping in electron microscopes to semiconductors, with a focus on spatial resolution, sensitivity and accuracy obtainable in characterising the chemical composition of thin layers, quantum wells and quantum dots. Various approaches applicable in scanning electron microscopy of bulk and (scanning) transmission electron microscopy of thin film samples are outlined. Applications to semiconductor quantum well systems, mainly based on indium gallium arsenide and silicon germanium studied in the author's laboratory, are provided as examples.

这篇教程风格的文章描述了能量色散x射线光谱学定量应用的最新改进,以及电子显微镜对半导体的映射,重点是在表征薄层、量子阱和量子点的化学成分时可获得的空间分辨率、灵敏度和准确性。各种方法适用于扫描电子显微镜的大块和(扫描)透射电子显微镜的薄膜样品概述。举例说明了以砷化铟镓和硅锗为主要材料在半导体量子阱系统中的应用。
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引用次数: 0
Comparative study of pure and mixed phase sulfurized-carbon black in battery cathodes for lithium sulfur batteries 硫化锂电池正极中纯碳黑和混相硫化碳黑的比较研究
Pub Date : 2024-07-23 DOI: 10.1002/appl.202400034
Surjit Sahoo, Debayan Chatterjee, Subhasish Basu Majumder, Kh M Asif Raihan, Brice LaCroix, Suprem R. Das

Lithium-sulfur battery (LSB) chemistry is regarded as one of the most promising contenders for powering next-generation electronics, including electric vehicles. This is due to its high theoretical capacity, the use of inexpensive and environmentally friendly materials, and its alignment with climate-smart manufacturing principles. Sulfur, the electroactive element in LSBs, undergoes lithiation to form a series of polysulfides, each contributing to the battery's energy density. However, this chemistry encounters several challenges, particularly concerning the stability of sulfur. Recent studies have shown that the presence of a full gamma phase of sulfur in an LSB cathode significantly enhances the capacity and overall cell performance. However, despite the advantages of cathodes with gamma sulfur, the characteristics of LSBs with mixed crystal phases of sulfur (alpha, beta, and gamma) have not been extensively studied. In this context, we developed a simple and cost-effective synthesis method to produce both single-phase (alpha) and mixed-phase sulfur (primarily a mixture of alpha and gamma, with a trace of beta) and conducted their detailed physical and electrochemical characterization for use as electroactive cathode materials in LSBs. The cells fabricated using sulfur-carbon black as the cathode delivered a specific capacity of approximately 640 mAh/g at a current density of 275 mA/g, demonstrating excellent cyclic stability over 50 cycles with a capacity retention of around 97%. This performance is superior to that of the sulfur-baked carbon black composite cathode, which achieved 440 mAh/g at the same current density.

锂硫电池(LSB)化学被认为是为包括电动汽车在内的下一代电子产品提供动力的最有前途的竞争者之一。这得益于其理论容量高、使用廉价环保材料以及符合气候智能制造原则。LSB中的电活性元素硫会发生锂化反应,形成一系列多硫化物,从而提高电池的能量密度。然而,这种化学反应遇到了一些挑战,尤其是硫的稳定性。最近的研究表明,在 LSB 阴极中存在全伽马硫相可显著提高电池容量和整体性能。然而,尽管伽马硫阴极具有优势,但对具有混合硫晶相(α、β 和伽马)的 LSB 的特性还没有进行广泛的研究。在这种情况下,我们开发了一种简单而经济有效的合成方法来生产单相硫(α)和混合相硫(主要是α和γ的混合物,还有微量的β),并对它们进行了详细的物理和电化学表征,以用作 LSB 中的电活性阴极材料。使用硫碳黑作为阴极制造的电池在电流密度为 275 mA/g 时的比容量约为 640 mAh/g,在 50 个循环周期内表现出卓越的循环稳定性,容量保持率约为 97%。这一性能优于硫焙烧炭黑复合阴极,后者在相同电流密度下的比容量为 440 mAh/g。
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引用次数: 0
Electrical cell-substrate impedance sensing (ECIS) in lung biology and disease 肺部生物学和疾病中的细胞-基质电阻抗传感(ECIS)
Pub Date : 2024-07-19 DOI: 10.1002/appl.202400059
Lena Schaller, Katharina Hofmann, Fabienne Geiger, Alexander Dietrich

The lungs are exposed to a hostile environment from both sites: the airways and the vasculature. However, an efficient gas exchange of oxygen (O2) and CO2 is only possible through a very thin alveolo-capillary membrane. Therefore, maintaining cell barrier integrity is essential for respiratory health and function. On the vascular site, endothelial cells form a natural barrier, while in the airways epithelial cells are most important for protection of the lung tissues. Moreover, fibroblasts, by transforming to myofibroblasts, are essential for wound closure after mechanical and chemical microinjuries in the respiratory tract. Along this line, loss of cell resistance in vascular endothelial and lung epithelial cells enhances invasion of pathogens (e.g., SARS-CoV-2) and results in pulmonary edema formation, while increasing barrier function of pulmonary (myo)fibroblasts blocks gas exchange in patients with pulmonary fibrosis. Therefore, electrical cell-substrate impedance sensing-based quantification of changes in cell barrier function in lung endothelial and epithelial cells as well as fibroblasts after application of harmful triggers (e.g., hypoxia, receptor agonists, and toxicants) is a convenient and state-of-the-art technique. After isolation of primary cells from mouse models and human tissues, changes in cell resistance can be detected in real time. By using lung cells from gene-deficient mouse models, microRNAs or the small-interfering RNA technology essential proteins for cell adhesion, for example, ion channels of the transient receptor potential family are identified in comparison to wild-type control cells. In the future, these proteins may be useful as drug targets for novel therapeutic options in patients with lung edema or pulmonary fibrosis.

肺从气道和血管两个部位暴露在恶劣的环境中。然而,只有通过非常薄的肺泡-毛细血管膜才能进行有效的氧气(O2)和二氧化碳气体交换。因此,保持细胞屏障的完整性对呼吸系统的健康和功能至关重要。在血管部位,内皮细胞形成天然屏障,而在气道中,上皮细胞对保护肺组织最为重要。此外,成纤维细胞通过转化为肌成纤维细胞,对呼吸道机械和化学微损伤后的伤口闭合至关重要。沿着这一思路,血管内皮细胞和肺上皮细胞中细胞阻力的丧失会增强病原体(如 SARS-CoV-2)的入侵并导致肺水肿的形成,而肺(肌)成纤维细胞屏障功能的增强会阻碍肺纤维化患者的气体交换。因此,基于细胞-基质阻抗电传感技术来量化肺内皮细胞、上皮细胞和成纤维细胞在施加有害诱因(如缺氧、受体激动剂和毒物)后细胞屏障功能的变化是一种便捷而先进的技术。从小鼠模型和人体组织中分离出原代细胞后,可实时检测细胞抵抗力的变化。通过使用基因缺陷小鼠模型的肺细胞、microRNA 或小干扰 RNA 技术,与野生型对照细胞相比,可以鉴定出细胞粘附所必需的蛋白质,例如瞬时受体电位家族的离子通道。未来,这些蛋白质可能会成为肺水肿或肺纤维化患者的新型治疗方案的药物靶点。
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引用次数: 0
Xanthan gum modification to surface and interfacial properties between soil-based matrixes and petroleum oils to minimize soil pollution 黄原胶改性土壤基质与石油之间的表面和界面特性,最大限度地减少土壤污染
Pub Date : 2024-07-15 DOI: 10.1002/appl.202400096
Firoz Ahmed, Brenda Hutton-Prager

A novel approach exploiting surfaces and interfaces between liquid oils and porous soil media was used to investigate the role of xanthan gum (XG) in minimizing the spread of petroleum oil spills on land. 1.6 wt% XG added to soil-based mixture matrixes (topsoil, sand, clay, and moisture) resulted in a 50% reduction in oil spreading area at 0 and 5 wt% moisture content, at 1.3 cm depth of soil matrix. Also recorded was a 45% increase in time taken for the low- and medium-viscosity oils to penetrate this soil depth. XG alters the surface energy and roughness of the soil matrixes, which additionally contributes to a reduction in oil spreading capabilities. Interfacial phenomena between individual oil droplets and soil matrixes demonstrated variable findings of droplet spreading and penetration with XG, depending upon the heterogeneity of the soil matrix itself. XG assisted a reduced lateral spread in heterogeneous soil matrixes and a reduced vertical penetration in clay-based matrixes. These interfacial results highlighted the often-observed differing transport phenomena at the interface compared with the bulk. This initial study demonstrates a novel approach to incorporate surface energy phenomena into the suite of soil remediation efforts by introducing natural biopolymers in high-risk land oil-spill areas to slow oil contaminant spread. Future studies will further characterize the benefits of XG in containing oil flow.

利用液态油和多孔土壤介质之间的表面和界面的新方法,研究了黄原胶 (XG) 在最大限度地减少陆地石油泄漏扩散方面的作用。在以土壤为基础的混合物基质(表土、沙子、粘土和水分)中添加 1.6 wt% 的黄原胶后,在含水量为 0 和 5 wt%、深度为 1.3 cm 的土壤基质中,石油扩散面积减少了 50%。此外,低粘度和中等粘度油类渗入这一土壤深度所需的时间也增加了 45%。XG 改变了土壤基质的表面能和粗糙度,从而降低了油类的铺展能力。单个油滴与土壤基质之间的界面现象表明,油滴在 XG 作用下的扩散和渗透结果各不相同,这取决于土壤基质本身的异质性。在异质土壤基质中,XG 有助于减少横向扩散,而在粘土基质中则会减少垂直渗透。这些界面结果凸显了在界面上经常观察到的与主体不同的传输现象。这项初步研究展示了一种将表面能现象纳入土壤修复工作的新方法,即在高风险的陆地漏油区域引入天然生物聚合物,以减缓石油污染物的扩散。未来的研究将进一步确定 XG 在遏制油流方面的优势。
{"title":"Xanthan gum modification to surface and interfacial properties between soil-based matrixes and petroleum oils to minimize soil pollution","authors":"Firoz Ahmed,&nbsp;Brenda Hutton-Prager","doi":"10.1002/appl.202400096","DOIUrl":"10.1002/appl.202400096","url":null,"abstract":"<p>A novel approach exploiting surfaces and interfaces between liquid oils and porous soil media was used to investigate the role of xanthan gum (XG) in minimizing the spread of petroleum oil spills on land. 1.6 wt% XG added to soil-based mixture matrixes (topsoil, sand, clay, and moisture) resulted in a 50% reduction in oil spreading area at 0 and 5 wt% moisture content, at 1.3 cm depth of soil matrix. Also recorded was a 45% increase in time taken for the low- and medium-viscosity oils to penetrate this soil depth. XG alters the surface energy and roughness of the soil matrixes, which additionally contributes to a reduction in oil spreading capabilities. Interfacial phenomena between individual oil droplets and soil matrixes demonstrated variable findings of droplet spreading and penetration with XG, depending upon the heterogeneity of the soil matrix itself. XG assisted a reduced lateral spread in heterogeneous soil matrixes and a reduced vertical penetration in clay-based matrixes. These interfacial results highlighted the often-observed differing transport phenomena at the interface compared with the bulk. This initial study demonstrates a novel approach to incorporate surface energy phenomena into the suite of soil remediation efforts by introducing natural biopolymers in high-risk land oil-spill areas to slow oil contaminant spread. Future studies will further characterize the benefits of XG in containing oil flow.</p>","PeriodicalId":100109,"journal":{"name":"Applied Research","volume":"3 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/appl.202400096","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141646461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Applied Research
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