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Crystallographic study of vertebrate fossils from the Central Narmada valley, India 印度纳尔马达河谷中部脊椎动物化石的晶体学研究
Pub Date : 2024-01-01 DOI: 10.1016/j.eve.2024.100033
Sakina Abdeali Halvadwala, Prateek Chakraborty

The Narmada River originates in eastern Madhya Pradesh near Amarkantak (200 40′ N, 81 46′ E), travels through Madhya Pradesh, Maharashtra, and Gujarat before emptying into the Gulf of Cambay in the Arabian Sea, close to Baruch in Gujarat. Numerous fossil discoveries in the region include various mammals, reptiles, fishes, amphibians, and molluscan shells. In addition to being a rare mid-continental location in the Old World, the Narmada Valley has traditionally served as a line delineating Northern and Southern India. This valley has produced countless animal fossils as well as a few human fossils. This has been a crucial route for the movement of both faunal migrations from the north to the south and the transmission of the monsoons from the southeast to the northwest. The present work examines the crystallization index of the faunal fossils from three (Barmanghat,Talayyaghat,Devakachar) localities in the Central Narmada valley falling within the region of Madhya Pradesh. Fossil samples were subjected to X-Ray diffraction in order to calculate the Crystallization index as a direct indicator of the degree of fossilization. The materials of Narmada river valley have been studied extensively by previous scholars; however, this study is first attempt to study the fossils using scientific technique such as XRD.

纳尔马达河发源于中央邦东部的阿马尔坎塔克附近(北纬 200 40′,东经 81 46′),流经中央邦、马哈拉施特拉邦和古吉拉特邦,在古吉拉特邦的巴鲁克附近注入阿拉伯海的坎拜湾。该地区发现的大量化石包括各种哺乳动物、爬行动物、鱼类、两栖动物和软体动物贝壳。纳尔马达河谷不仅是旧大陆罕见的中间位置,而且历来是划分印度北部和南部的分界线。该河谷出土了无数动物化石和少量人类化石。这里是动物从北方向南方迁徙和季风从东南向西北传播的重要通道。本研究对位于中央邦纳尔马达河谷的三个地方(巴曼加特、塔拉亚加特和德瓦卡查尔)的动物化石的结晶指数进行了研究。对化石样本进行了 X 射线衍射,以计算作为化石化程度直接指标的结晶指数。之前的学者已经对纳尔马达河流域的材料进行了广泛的研究,但本研究是首次尝试使用 X 射线衍射等科学技术来研究化石。
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引用次数: 0
Potential of pine forest in controlling soil erosion in Himalayan region - Investigation using fallout radionuclide (137Cs) measurements 松树林控制喜马拉雅地区土壤侵蚀的潜力--利用落尘放射性核素(137Cs)测量进行的研究
Pub Date : 2024-01-01 DOI: 10.1016/j.eve.2024.100031
Anu David Raj , Suresh Kumar , Sankar Mariappan , K.R. Sooryamol , Justin George Kalambukattu

The Himalayas possess a distinctive topography owe to the dynamic interplay of tectonic activity, geological erosion and sedimentation, glacial processes, and climatic influences over the millions of years. The rugged, steep terrain and poor land management make it more prone to water erosion, negatively impacts the soil, affecting the goods and services supported by the soil ecosystems. Traditional methods used in soil erosion assessment face limitations when dealing with topographically complex hillslopes. The use of Fallout Radionuclide (FRN) -137Cs provides a feasible alternative for measurement of soil erosion in the region with such topography. However, there is lack of 137Cs-based soil erosion studies in the north-west Himalayas. Pine (Pinus roxburghii) is the predominant forest type in the Himalayas, offering numerous benefits to both natural ecosystems and human beings. In this study, we selected a typical steep hillslope covered with pine forest in the Himalayas for soil erosion assessment. The study measured 137Cs reference inventory of 1409 Bq m−2 in the landscape. Importantly, the concentration of 137Cs along the hillslope positions showed a significant variation attributed to topographic variability. Topographic factors, such as the slope shape and gradient, were identified as the major governing parameters of soil erosion in the hilly and mountainous region. The net soil erosion rate over hillslope positions revealed highest at upper hillslope followed by ridge, middle and valley hillslope positions. The net soil erosion rate under the pine forest ranged from 8.0 to 14.6 t ha−1 yr−1, with an average rate of 9.9 t ha−1 yr−1. Erosion rate over the hillslope positions were found in accordance to the soil loss tolerance limit (SLTL) except for the upper hillslope, indicating it as critical slope position requires to adopt suitable conservation measures. The study signifies the role of the forest in mitigating soil erosion and, in turn, conserving soil resources. The findings provide crucial insights and guidance to land managers and decision-makers, emphasizing the necessity of conserving and restoring forests in the Himalayas.

喜马拉雅山拥有独特的地形,这要归功于数百万年来构造活动、地质侵蚀和沉积、冰川过程和气候影响的动态相互作用。崎岖陡峭的地形和不良的土地管理使其更容易受到水的侵蚀,对土壤造成负面影响,影响土壤生态系统所提供的产品和服务。在处理地形复杂的山坡时,用于土壤侵蚀评估的传统方法面临着局限性。使用放射性核素(FRN)-137Cs 为测量此类地形地区的土壤侵蚀情况提供了一种可行的替代方法。然而,喜马拉雅山西北部缺乏基于 137Cs 的土壤侵蚀研究。松树(Pinus roxburghii)是喜马拉雅山脉的主要森林类型,为自然生态系统和人类带来了诸多益处。在这项研究中,我们选择了喜马拉雅山地区松林覆盖的典型陡峭山坡进行土壤侵蚀评估。研究测得该地貌的 137Cs 参考库存量为 1409 Bq m-2。重要的是,沿山坡位置的 137Cs 浓度因地形变化而出现显著差异。坡形和坡度等地形因素被认为是丘陵山区土壤侵蚀的主要影响因素。山坡净土壤侵蚀率显示,山坡上部的净土壤侵蚀率最高,其次是山脊、山坡中部和山谷。松林下的净土壤侵蚀率介于 8.0 至 14.6 吨/公顷/年之间,平均为 9.9 吨/公顷/年。除上部山坡外,其他山坡位置的土壤侵蚀率均符合土壤流失容限(SLTL),表明上部山坡是需要采取适当保护措施的关键坡位。这项研究表明了森林在减轻土壤侵蚀、进而保护土壤资源方面的作用。研究结果为土地管理者和决策者提供了重要的见解和指导,强调了保护和恢复喜马拉雅山森林的必要性。
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引用次数: 0
Seismic risk assessment using integrated MCDM method in West Bengal, India 在印度西孟加拉邦使用 MCDM 综合方法进行地震风险评估
Pub Date : 2024-01-01 DOI: 10.1016/j.eve.2024.100036
Monalisa Malakar , Sukanta Malakar , Mohd Sayeed Ul Hasan , Abhishek K. Rai , Vijay K. Kannaujiya
Earthquakes are one of the natural hazards that threaten human lives and properties. Consequently, seismic risk assessment plays a significant role in disaster mitigation. This study estimates seismic risk in West Bengal, India, by integrating the two multi-criteria decision-making (MCDM) models: analytical hierarchy process (AHP) and Entropy. Integrated AHP-Entropy is used to determine vulnerability, seismic hazard, and coping capacity. The seismic risk was then assessed by integrating the thematic information of vulnerability, seismic hazard, and coping capacity. The results show that about 19% of the total area and 70% of the total population in West Bengal may be at very high seismic risk. The result is validated through a receiver operating characteristic curve, displaying satisfactory performance in seismic risk estimation. The findings of this study may help governmental agencies identify seismic-risk zones and establish seismic hazard plans in advance against any potential threat in the study region.
地震是威胁人类生命和财产安全的自然灾害之一。因此,地震风险评估在减灾中发挥着重要作用。本研究通过整合两种多标准决策(MCDM)模型:层次分析法(AHP)和熵,对印度西孟加拉邦的地震风险进行了评估。综合 AHP-Entropy 用于确定脆弱性、地震灾害和应对能力。然后,通过整合脆弱性、地震灾害和应对能力的专题信息来评估地震风险。结果显示,西孟加拉邦约 19% 的总面积和 70% 的总人口可能面临极高的地震风险。该结果通过接收器工作特征曲线得到验证,在地震风险估计方面表现令人满意。本研究的结果可帮助政府机构确定地震风险区,并提前制定地震危害计划,以应对研究地区的任何潜在威胁。
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引用次数: 0
Geochemical modeling of diagenetic reactions between albitization of K-feldspar and plagioclase feldspar in sandstone reservoirs under the influence of CO2 partial pressure 二氧化碳分压影响下砂岩储层中 K 长石和斜长石白化成岩反应的地球化学建模
Pub Date : 2024-01-01 DOI: 10.1016/j.eve.2024.100042
Marcos Antonio Klunk , Tiago Jonatan Girelli , Soyane Juceli Siqueira Xavier , Farid Chemale Jr , Renzo D'souza , Mohuli Das , Sudipta Dasgupta
Diagenetic albitization has been observed in sedimentary basins around the world. This process significantly changes the original composition of sandstones and the chemistry of the formation waters under the influence of partial pressure of CO2. The transformation of detrital feldspars into albite is considered a crucial diagenetic process in the Gulf Coast and North Sea reservoirs. Earlier studies suggest that plagioclase albitization typically happens before that of K-feldspar. In the Gulf Coast's Frio Sandstone, located in the Upper Oligocene at depths between 900 and 2400 m, detrital plagioclase is often dissolved and replaced by albite, while K-feldspar mostly dissolves without much substitution. Similarly, in the North Sea reservoirs, especially in the upper section of the Upper Triassic Lunde Formation at depths beyond 2900 m, plagioclase tends to undergo albitization, whereas K-feldspar remains largely unaffected or experiences minimal transformation. This research focuses on analyzing the differences in the albitization patterns of detrital and K-feldspar plagioclase through the KINDISP and Geochemist's Workbench (GWB) geochemical modeling tools, aiming to compare them. These diagenetic processes are crucial for reservoir geology, as they influence the concentration of silica in water, which, in turn, affects quartz cementation. This study aims to explore the variations in the albitization behavior of detrital and K-feldspar plagioclase using the KINDISP and Geochemist's Workbench (GWB) geochemical models and conduct a comparative analysis between them. Understanding these diagenetic reactions becomes relevant for reservoir geology analysis, as such phenomena control the aqueous silica concentration to some extent, which is consequently reflected in the quartz cementation. The dissolution of plagioclase and K-feldspar releases silica into the pore fluids. As the concentration of silica in the fluid increases, it leads to the precipitation of quartz as overgrowths on detrital quartz grains, a process known as quartz cementation. This was observed particularly in simulations involving temperature increases up to 150 °C, where the equilibrium between albite and anorthite was closely linked to the stability of quartz (Ben et al., 1993). The removal of feldspar through albitization reduces porosity and permeability but contributes silica to the system, which promotes quartz cementation. This, in turn, decreases the reservoir quality by filling pore spaces with secondary quartz, reducing the rock's ability to store and transmit fluids. Thus, the study highlights the importance of these diagenetic processes in reservoir evaluation, as the balance between feldspar dissolution and quartz cementation ultimately controls reservoir properties.
在世界各地的沉积盆地中都观察到了二基因白化现象。在二氧化碳分压的影响下,这一过程极大地改变了砂岩的原始成分和地层水的化学性质。在墨西哥湾沿岸和北海储层中,斜长石转变为白云石被认为是一个关键的成岩过程。早期的研究表明,斜长石白云石化通常发生在 K 长石白云石化之前。在海湾沿岸的弗里奥砂岩(位于上新世,深度在 900 米至 2400 米之间)中,脱落的斜长石通常会溶解并被白云石取代,而 K 长石大多会溶解而不会被大量取代。同样,在北海储层中,特别是在深度超过 2900 米的上三叠统隆德地层上段,斜长石往往会发生白云石化,而 K 长石则基本不受影响或发生极少的转变。本研究的重点是通过 KINDISP 和 Geochemist's Workbench (GWB) 地球化学建模工具,分析碎屑斜长石和 K 长石白化模式的差异,旨在对两者进行比较。这些成岩过程对储层地质至关重要,因为它们会影响水中二氧化硅的浓度,进而影响石英的胶结。本研究旨在利用 KINDISP 和 Geochemist's Workbench (GWB) 地球化学模型,探索斜长石和 K 长石的白化行为的变化,并对它们进行比较分析。了解这些成岩反应与储层地质分析息息相关,因为这些现象在一定程度上控制了水硅浓度,从而反映在石英胶结上。斜长石和钾长石的溶解会将二氧化硅释放到孔隙流体中。随着流体中二氧化硅浓度的增加,会导致石英沉淀,在脱落的石英颗粒上过度生长,这一过程被称为石英胶结。在温度升高到 150 ℃ 的模拟中尤其可以观察到这一现象,白云石和阳起石之间的平衡与石英的稳定性密切相关(Ben 等人,1993 年)。通过白云石化去除长石会降低孔隙度和渗透率,但会为系统提供二氧化硅,从而促进石英胶结。这反过来又会用次生石英填充孔隙,降低岩石储存和传输流体的能力,从而降低储层质量。因此,该研究强调了这些成岩过程在储层评价中的重要性,因为长石溶解和石英胶结之间的平衡最终控制着储层的性质。
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引用次数: 0
Morphospecies of potentially toxic cyanobacterium Microcystis - A review on colony formation and its global distribution
Pub Date : 2024-01-01 DOI: 10.1016/j.eve.2024.100049
Renju Mohan , Afnitha K.H , Ajayakumar P , Lathika Cicily Thomas , K.B. Padmakumar
The increased occurrence of toxic blooms of Microcystis is emerging as a global concern due to the health implications and associated water quality issues. Microcystis are single-celled ubiquitous cyanobacteria capable of forming colonies of different morphologies in various eutrophic water bodies, including freshwater, estuaries and marine systems. Their distribution and severity have increased during past decades, contributed by factors like warmer temperatures, climate change, eutrophication and other hydrological changes. They form colonies of varying shapes and sizes depending on the type of species and environmental factors. This cyanobacterial genus consists of more than 50 distinct morphological variants, mainly based on their physical characteristics like cell shape, size, colony arrangement etc. However, their greater morphological variations and phenotypic plasticity often complicate their morphological identification. Studies regarding their morphospecies are thus crucial for improved taxonomic classification, identifying the major bloom-forming species and their ecological impacts. This review has attempted to provide a brief knowledge about some of the common morphospecies of Microcystis, its colony formation and distribution worldwide.
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引用次数: 0
Bonebed amber deposits: A review of taphonomy and palaeontological significance 骨床琥珀沉积:岩石学和古生物学意义综述
Pub Date : 2024-01-01 DOI: 10.1016/j.eve.2024.100032
Pierre Cockx , Ryan C. McKellar

Bonebeds and amber deposits provide a wealth of palaeontological information allowing palaeobiologists to reconstruct ancient ecosystems in great detail. It is a common view that these two sources of data rarely intersect in the fossil record, owing to distinct taphonomic pathways. Nonetheless, the past decades have seen an increasing number of bonebed amber deposits reported and investigated, suggesting that some depositional environments might provide the appropriate conditions for preserving plant material and bones. By reviewing the current knowledge of the taphonomy of amber deposits and that of bonebeds, and through examination of a series of Cretaceous deposits in North America and Europe, we identify a taphonomic window that permits the long-term preservation of both materials. This synthesis allows us to provide some keys for bonebed amber prospecting, which will hopefully lead to additional finds in the field. We also review the main findings of the first comprehensive studies of bonebed amber deposits which focus on the amber assemblage, the chemistry of the fossil resin, and its stable isotopic composition, to demonstrate the utility of combined studies. This approach enables palaeobiologists to reconstruct past forest habitats by (i) exploring the faunal communities (especially, arthropod communities) of the forests, (ii) identifying the dominant source tree, (iii) identifying the ecological conditions, and (iv) characterizing the palaeogeography of the region. These findings show that amber represents a source of complementary data within bonebeds and can help achieving a better knowledge of past terrestrial habitats.

骨床和琥珀沉积物提供了丰富的古生物学信息,使古生物学家能够非常详细地重建古代生态系统。人们普遍认为,这两种数据来源在化石记录中很少有交集,原因是它们有着不同的出土途径。然而,在过去的几十年中,越来越多的骨床琥珀沉积物被报道和研究,这表明某些沉积环境可能为保存植物材料和骨骼提供了适当的条件。通过回顾目前对琥珀沉积和骨床琥珀沉积的认识,并通过对北美和欧洲一系列白垩纪沉积的研究,我们发现了一个可以长期保存这两种物质的沉积学窗口。通过这一综合研究,我们为骨床琥珀的勘探提供了一些关键信息,希望能为我们带来更多的实地发现。我们还回顾了首批骨床琥珀沉积综合研究的主要发现,这些研究侧重于琥珀的组合、化石树脂的化学性质及其稳定同位素组成,以证明综合研究的实用性。这种方法使古生物学家能够通过(i)探索森林中的动物群落(尤其是节肢动物群落),(ii)确定主要来源树种,(iii)确定生态条件,以及(iv)描述该地区的古地理特征,重建过去的森林栖息地。这些发现表明,琥珀是骨床内补充数据的来源,有助于更好地了解过去的陆地生境。
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引用次数: 0
Reconstruction of avulsion history of the Brahmaputra River: Rare example of a giant braided river course alteration through multi-channel multi-avulsion processes 重建雅鲁藏布江的侵蚀历史:通过多河道多侵蚀过程改变巨型辫状河河道的罕见实例
Pub Date : 2024-01-01 DOI: 10.1016/j.eve.2024.100034
MD. Raihanul Islam, Imran Khan, MD. Alifnur Salim, M.D. Musfequzzaman

The avulsion scenario of the Brahmaputra has been a debated issue for quite a long time. This study aims to resolve this debate through reconstruction of the avulsion history of the Brahmaputra. We have addressed the processes, timeline and causes of the avulsion. Old maps and images from 1776 to 2023, evidence from contemporary literature and recent studies have been used in our study. We find that the process of creation of the Jamuna was started through capturing the flow of the Brahmaputra by the Jenni during the 1780s. Between 1780 and 1800 the Brahmaputra created two primary avulsion channels upstream and initiated the multi-avulsion process which was completed in the 1880s. The first avulsion channel conveyed the Brahmaputra flow into the Konaie directly and the second avulsion channel diverted the flow captured by the Jenni into the Konaie. Contemporarily, the flow-enriched Konaie switched its flow into the Jenni at downstream through an unnamed channel and the combined flow traveled through the bed of the Jenni before creating the confluence with the Ganges. In the whole process, the Konaie received, inflated and transported the dominant flow of the Brahmaputra and the Jenni became inferior over time. We have introduced a bend migration concept along with local sediment overload to focus on setting up a lower stability threshold of avulsion that led to the eruptive creation of the avulsion channels by a coupled switching mechanism imparted by high monsoonal discharges, avulsion of the Tista into the Brahmaputra and the high-magnitude floods.

长期以来,雅鲁藏布江的崩蚀情况一直是一个争论不休的问题。本研究旨在通过重建雅鲁藏布江的断流历史来解决这一争论。我们探讨了雅鲁藏布江断流的过程、时间表和原因。我们在研究中使用了从 1776 年到 2023 年的老地图和图片、当代文献中的证据以及最新研究。我们发现,贾木纳河的形成过程始于 17 世纪 80 年代詹尼河对雅鲁藏布江水流的截流。1780 年至 1800 年间,雅鲁藏布江在上游形成了两条主要河道,并开始了多级河道的形成过程,该过程于 1880 年代完成。第一条导流河道将雅鲁藏布江的水流直接引入科纳耶河,第二条导流河道则将杰尼河捕获的水流引入科纳耶河。与此同时,流量增大的科纳耶河通过一条未命名的河道将其水流转入下游的杰尼河,合流后的水流穿过杰尼河河床,然后与恒河汇合。在整个过程中,科纳伊河接收、膨胀并输送雅鲁藏布江的主要水流,而杰尼河则逐渐变小。我们引入了弯曲迁移概念和局部泥沙超载概念,重点是设定一个较低的崩蚀稳定阈值,该阈值通过季风大排水量、蒂斯塔河向雅鲁藏布江的崩蚀以及大洪水的耦合转换机制,导致崩蚀河道的爆发性形成。
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引用次数: 0
A new model for Early Paleozoic ichnostratigraphy based on trace fossil assemblages from Brazil 基于巴西微量化石组合的早古生代地层新模式
Pub Date : 2023-12-01 DOI: 10.1016/j.eve.2023.100026
Sara C. Memória , Renata G. Netto , Daniel Sedorko

Trace fossils are not generally utilized as biostratigraphic indicators due to their long stratigraphic ranges. Despite the use of intricate behavioral traces in the absence of other indicators, existing models like the Precambrian–Cambrian boundary and Cruziana stratigraphy encounter limitations due to crucial data gaps and regional constraints. To surmount these challenges, in this paper, we critically assess established models and present a new framework for Early Paleozoic strata, drawing on trace fossils from the intracratonic basins of Brazil. Our ichnostratigraphic model is calibrated using ichnological data from the Parnaíba, Paraná, and Amazonas basins, including new data. The analysis focuses on trace fossils in strata that are independently dated using chitinozoan, miospore, and acritarch biozonation. Key ichnotaxa, such as Arthrophycus and Cruziana, are identified as prominent indicators of the Llandovery Stage in Brazil. Occurrences of Heimdallia and Musculopodus in the Tianguá Formation also may be used to suggest a Llandovery interval. Notably, Bifungites, found widely across Brazilian basins, emerges as a potential ichnomarker for the Early to mid-Paleozoic interval, with a global presence throughout Cambrian to Mississippian deposits. While current ichnostratigraphic models lack robust calibration with chronostratigraphic or biostratigraphic data, our new proposed model integrates key ichnotaxa, including Bifungites, Climactichnites, Heimdallia, Oldhamia, and Musculopodus, surpassing those pre-existing zonations based on Cruziana and arthrophycids. These ichnotaxa exhibit unique features and narrow temporal ranges, meeting essential biostratigraphic criteria. Although their spatial distribution is somewhat limited, our new model, which is continually evolving with new data, holds promise for enhancing global stratigraphic correlations, particularly where independent age information is available.

由于微量化石的地层范围较长,一般不用作生物地层指示物。尽管在没有其他指标的情况下使用了复杂的行为痕迹,但由于关键数据缺口和区域限制,现有模型(如前寒武纪-寒武纪边界和Cruziana地层学)遇到了局限性。为了克服这些挑战,在本文中,我们对已建立的模型进行了批判性评估,并利用巴西克拉通内盆地的痕迹化石,提出了早古生代地层的新框架。我们的技术地层模型使用Parnaíba、paranas 和Amazonas盆地的技术数据(包括新数据)进行校准。分析的重点是利用几丁质动物、小孢子动物和水蛭生物区带独立测定年代的地层中痕量化石。节肢类和Cruziana是巴西陆地发育阶段的重要标志。在天关组中出现的海马目和肌肉足目也可以用来说明一个陆交期。值得注意的是,在巴西盆地广泛发现的双辉石,作为早古生代至中古生代区间的潜在标志,在全球范围内存在于寒武纪至密西西比沉积。虽然目前的海洋地层模型缺乏与年代地层或生物地层数据的可靠校准,但我们提出的新模型整合了关键的海洋类群,包括biungites, Climactichnites, Heimdallia, Oldhamia和Musculopodus,超越了先前基于Cruziana和节肢动物的分区。这些鱼分类群表现出独特的特征和狭窄的时间范围,符合基本的生物地层标准。虽然它们的空间分布有些有限,但我们的新模型随着新数据的不断发展,有望增强全球地层相关性,特别是在有独立年龄信息的情况下。
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引用次数: 0
Wildfire in the geological record: Application of Quaternary methods to deep time studies 地质记录中的野火:第四纪方法在深时研究中的应用
Pub Date : 2023-12-01 DOI: 10.1016/j.eve.2023.100025
Jennifer M. Galloway , Sofie Lindström

For hundreds of millions of years wildfire has influenced, and been influenced by, plant evolution, biogeochemical cycling, and climate. Wildfire has even been implicated as one of the causative agents of mass extinctions. The deep time geologic record offers demonstrated, but underdeveloped, potential to advance knowledge on the role of wildfire in the Earth system. Herein, we present and discuss the geologic history of wildfire and methods for its reconstruction. We argue that application of the numeric approaches to wildfire reconstruction often used in Quaternary studies would advance understanding of deep time wildfire. Application of numeric methods increases statistical rigour, with the intent of reducing bias and increasing accuracy. For example, numeric methods offer a means to robustly calibrate the provenance and taphonomy of particles used to reconstruct wildfire, and to quantify uncertainties. Statistical methods should be used to assess the fidelity of new chemical proxies of wildfire, such as the types, amounts, distributions, and isotope signatures of polycyclic aromatic hydrocarbons, to represent source area and fuel type.

几亿年来,野火一直影响着植物进化、生物地球化学循环和气候,同时也受到它们的影响。野火甚至被认为是导致大规模物种灭绝的原因之一。深时间地质记录提供了证明,但不发达的潜力,以促进对野火在地球系统中的作用的认识。在此,我们介绍并讨论了野火的地质历史及其重建方法。我们认为,第四纪研究中常用的野火重建数值方法的应用将促进对深时野火的理解。数值方法的应用增加了统计的严谨性,目的是减少偏差和提高准确性。例如,数值方法提供了一种强大的方法来校准用于重建野火的颗粒的来源和埋藏,并量化不确定性。应采用统计方法评估野火新的化学指标的保真度,如多环芳烃的类型、数量、分布和同位素特征,以代表源区域和燃料类型。
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引用次数: 0
Changes in Fe-redox and Fe-species across the end-Permian ‘Dead Zone’ in the Sydney Basin, Australia (252.10 ± 0.06 Ma): Evidence from X-ray absorption spectroscopy 澳大利亚悉尼盆地二叠纪末“死区”(252.10±0.06 Ma)铁氧化还原和铁种类的变化:来自x射线吸收光谱的证据
Pub Date : 2023-11-19 DOI: 10.1016/j.eve.2023.100029
Vivi Vajda , Kajsa G.V. Sigfridsson Clauss , Ashley Krüger , Susan Nehzati

The end-Permian mass extinction event is traceable across several non-marine basins in Australia. In the Sydney Basin, the lithological succession is characterized by a change from coal seams to mudstones and sandstones, recording a major environmental change following the disappearance of the Permian vegetation. A few millimeter-thick iron-rich ‘rusty’ layer occurs between the uppermost Permian coal seam and the mudstone, a layer that extends laterally across the basin and which has also been documented from coeval successions in Antarctica. This layer is overlain by the <1.5-m-thick Frazer Beach Member, whose basal 10-cm-thick microbreccia bed comprises 99% kaolinite and quartz, and is dated as 252.10 ± 0.06 Ma. The Frazer Beach Member corresponds to the so-called end-Permian ‘Dead Zone’ lacking fossil pollen and leaves. This distinctive member was deposited directly following the extinction of the Permian peat-forming forests.

Here we identify, through X-ray absorption spectroscopy, a drastic redox shift across the extinction interval with increasing amount of reduced Fe-species followed by highly oxidized Fe-species, most resembling Fe(III) complexed with organic matter. Values subsequently normalise in younger samples through the ‘Dead Zone’, attaining only slightly higher redox-levels than before the event. The organically complexed Fe-species in the event bed is consistent with the standard Suwannee River fulvic acid, an acid Fe-complex with iron bound to organic matter, whereas the samples above and below the extinction layer yield spectra predominantly resembling magnetite (Fe3O4) mineral phase. We consider that the iron redox fluctuation marking the extinction interval is related to significant environmental changes with accumulation of organic matter following the mass extinction. The highly reduced iron in the extinction layer may relate to methane release from bacterial degradation, or emissions from clathrates. The presence of fulvic acid in the distinct iron-rich extinction layer indicates that an abrupt onset of the process of degradation of plant matter, lipids and calcium hydroxide (CaOH) took place, resulting in this ‘Death layer’. This was followed by millions of years of erosive conditions before new, complex vegetation could establish.

二叠纪末的大灭绝事件可以追溯到澳大利亚的几个非海洋盆地。悉尼盆地的岩性演替以煤层到泥岩和砂岩的变化为特征,记录了二叠纪植被消失后的主要环境变化。在最上层的二叠纪煤层和泥岩之间有几毫米厚的富含铁的“锈”层,这一层横向延伸穿过盆地,在南极洲的同时期演替中也有记录。该层被1.5 m厚的Frazer Beach段覆盖,其基底10 cm厚的微角砾岩层由99%的高岭石和石英组成,其年代为252.10±0.06 Ma。弗雷泽海滩成员对应于所谓的二叠纪末“死区”,缺乏化石花粉和树叶。这个独特的成员是在二叠纪泥炭形成森林灭绝后直接沉积的。在这里,我们通过x射线吸收光谱发现,在消光区间内,随着铁的还原量的增加,出现了剧烈的氧化还原位移,其次是高度氧化的铁,最类似于铁(III)与有机物的络合。随后,年轻样本中的值通过“死区”正常化,氧化还原水平仅略高于事件发生前。事件层中的有机络合铁与标准的苏万尼河黄腐酸一致,是一种与有机物结合的酸性铁络合物,而消光层上下样品的产谱主要类似于磁铁矿(Fe3O4)矿物相。我们认为,标志灭绝间隔的铁氧化还原波动与大灭绝后有机质积累的显著环境变化有关。消光层中高度还原的铁可能与细菌降解释放的甲烷或笼形物的排放物有关。富铁灭绝层中黄腐酸的存在表明,植物物质、脂质和氢氧化钙(CaOH)的降解过程突然开始,导致了这一“死亡层”的形成。接下来是数百万年的侵蚀环境,新的复杂植被才得以形成。
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Evolving Earth
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