Journal of Ionic Liquids最新文献_第7页

Navigating ice-free Horizons: A Review on the Role of Ionic liquids and Deep eutectic solvents in Anti-icing Technologies 导航无冰视野：离子液体和深共晶溶剂在防冰技术中的作用综述

Journal of Ionic Liquids

Pub Date : 2025-03-06 DOI: 10.1016/j.jil.2025.100139

Saba Goharshenas Moghadam, Gelareh Momen, Reza Jafari

This review investigates the unexplored potential of ionic liquids (ILs) and deep eutectic solvents (DESs) as innovative solutions for advancing anti-icing technologies, particularly in harsh sub-freezing conditions, with a focus on coating applications. Despite limited exploration, ILs and DESs stand out due to their remarkable properties—low melting points, excellent hydrogen-bond donor capabilities, thermal stability, and the formation of quasi-liquid layers that drastically reduce ice adhesion. While research on IL-based coatings for ice mitigation is still in its infancy, the promising synergy between DESs and ILs paves the way for creating highly effective ice-resistant surfaces. DESs, recognized for their eco-friendly and straightforward preparation, have been primarily studied for anti-freezing resilience, leaving their potential as ice growth inhibitors largely unexplored. This review presents DESs as effective ice growth inhibitors and highlights their synergistic combination with ILs, functioning as dynamic interface melting agents, for enhanced ice mitigation performance. Furthermore, the review consolidates current studies, emphasizing the need for further investigation into ILs and DESs for combating ice formation. It also proposes future research directions, such as exploring diverse IL chemistries, enhancing the stability of ILs, and investigating novel matrix materials to improve mechanical durability. The review provides a broad perspective on integrating these materials into various industrial and environmental applications, offering fresh insights into their transformative potential in anti-icing systems.

本文综述了离子液体（ILs）和深度共晶溶剂（DESs）作为推进防冰技术的创新解决方案的潜力，特别是在恶劣的亚冷冻条件下，重点是涂层应用。尽管勘探有限，但ILs和DESs因其显著的特性而脱颖而出——低熔点、出色的氢键供体能力、热稳定性，以及形成的准液态层大大减少了冰的粘附性。虽然基于il的减冰涂层的研究仍处于起步阶段，但DESs和il之间有希望的协同作用为创造高效的抗冰表面铺平了道路。DESs以其环保和简单的制备而闻名，主要研究其抗冻弹性，而其作为冰生长抑制剂的潜力在很大程度上尚未得到开发。这篇综述介绍了DESs是有效的冰生长抑制剂，并强调了它们与ILs的协同作用，作为动态界面融化剂，增强了冰的减缓性能。此外，本报告总结了目前的研究，强调有必要进一步研究ILs和DESs对抗冰的形成。提出了未来的研究方向，如探索不同的IL化学成分，增强IL的稳定性，研究新型基质材料以提高机械耐久性。该综述为将这些材料整合到各种工业和环境应用中提供了广阔的视角，为其在防冰系统中的变革潜力提供了新的见解。

{"title":"Navigating ice-free Horizons: A Review on the Role of Ionic liquids and Deep eutectic solvents in Anti-icing Technologies","authors":"Saba Goharshenas Moghadam, Gelareh Momen, Reza Jafari","doi":"10.1016/j.jil.2025.100139","DOIUrl":"10.1016/j.jil.2025.100139","url":null,"abstract":"<div><div>This review investigates the unexplored potential of ionic liquids (ILs) and deep eutectic solvents (DESs) as innovative solutions for advancing anti-icing technologies, particularly in harsh sub-freezing conditions, with a focus on coating applications. Despite limited exploration, ILs and DESs stand out due to their remarkable properties—low melting points, excellent hydrogen-bond donor capabilities, thermal stability, and the formation of quasi-liquid layers that drastically reduce ice adhesion. While research on IL-based coatings for ice mitigation is still in its infancy, the promising synergy between DESs and ILs paves the way for creating highly effective ice-resistant surfaces. DESs, recognized for their eco-friendly and straightforward preparation, have been primarily studied for anti-freezing resilience, leaving their potential as ice growth inhibitors largely unexplored. This review presents DESs as effective ice growth inhibitors and highlights their synergistic combination with ILs, functioning as dynamic interface melting agents, for enhanced ice mitigation performance. Furthermore, the review consolidates current studies, emphasizing the need for further investigation into ILs and DESs for combating ice formation. It also proposes future research directions, such as exploring diverse IL chemistries, enhancing the stability of ILs, and investigating novel matrix materials to improve mechanical durability. The review provides a broad perspective on integrating these materials into various industrial and environmental applications, offering fresh insights into their transformative potential in anti-icing systems.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100139"},"PeriodicalIF":0.0,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143600764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Molecular interactions of 1-butyl-2,3-dimethylimidazolium chloride ionic liquid in aqueous L-alanine solutions through volumetric and compressibility approaches 1-丁基-2,3-二甲基咪唑氯离子液体在l-丙氨酸水溶液中的分子相互作用

Journal of Ionic Liquids

Pub Date : 2025-03-04 DOI: 10.1016/j.jil.2025.100140

Vandana Patel, Anuja Jain, Sangesh P. Zodape

The interactions of 1-Butyl-2,3-dimethylimidazolium chloride ionic liquid i.e. [BMMIm][Cl] with l-alanine as a function of temperature and concentration have been inspected. The density and speed of sound values for the [BMMIm][Cl] in different concentrations (0.05 mol·kg^-1 and 0.10 mol·kg^-1) of aqueous l-alanine solutions within the concentration range of 0.01 to 0.13 mol·kg^-1 at T = (288.15, 293.15, 298.15, 303.15, 308.15, 313.15 and 318.15) K and atmospheric pressure have been measured. The apparent molar volume of solute, limiting apparent molar volume of solute, and transfer limiting apparent molar volume of solute for [BMMIm][Cl] in aqueous l-alanine solutions have been calculated using density data. The apparent molar isentropic compression of solute, limiting apparent molar isentropic compression of solute, and transfer limiting apparent molar isentropic compression of solute have been assessed utilizing speed of sound data. The expansivity parameter and its derivative with respect to temperature, and the pair and triplet interaction coefficients were evaluated. The findings of the study have been analyzed in terms of solute-solute and solute-solvent interactions in ternary systems.

考察了1-丁基-2,3-二甲基咪唑氯离子液体[BMMIm][Cl]与l-丙氨酸的相互作用随温度和浓度的变化规律。测定了0.01 ~ 0.13 mol·kg-1范围内l-丙氨酸水溶液在T =(288.15、293.15、298.15、303.15、308.15、313.15和318.15)K和大气压条件下，不同浓度（0.05 mol·kg-1和0.10 mol·kg-1） [BMMIm][Cl]的密度和声速值。利用密度数据计算了[BMMIm][Cl]在l-丙氨酸水溶液中的溶质表观摩尔体积、极限溶质表观摩尔体积和转移极限溶质表观摩尔体积。利用声速数据对溶质表观摩尔等熵压缩、极限表观摩尔等熵压缩和传递极限表观摩尔等熵压缩进行了评价。计算了膨胀系数及其随温度的导数、对和三重态相互作用系数。从三元体系中溶质-溶质和溶质-溶剂相互作用的角度对研究结果进行了分析。

{"title":"Molecular interactions of 1-butyl-2,3-dimethylimidazolium chloride ionic liquid in aqueous L-alanine solutions through volumetric and compressibility approaches","authors":"Vandana Patel, Anuja Jain, Sangesh P. Zodape","doi":"10.1016/j.jil.2025.100140","DOIUrl":"10.1016/j.jil.2025.100140","url":null,"abstract":"<div><div>The interactions of 1-Butyl-2,3-dimethylimidazolium chloride ionic liquid i.e. [BMMIm][Cl] with <span>l</span>-alanine as a function of temperature and concentration have been inspected. The density and speed of sound values for the [BMMIm][Cl] in different concentrations (0.05 mol·kg<sup>-1</sup> and 0.10 mol·kg<sup>-1</sup>) of aqueous <span>l</span>-alanine solutions within the concentration range of 0.01 to 0.13 mol·kg<sup>-1</sup> at <em>T</em> = (288.15, 293.15, 298.15, 303.15, 308.15, 313.15 and 318.15) K and atmospheric pressure have been measured. The apparent molar volume of solute, limiting apparent molar volume of solute, and transfer limiting apparent molar volume of solute for [BMMIm][Cl] in aqueous <span>l</span>-alanine solutions have been calculated using density data. The apparent molar isentropic compression of solute, limiting apparent molar isentropic compression of solute, and transfer limiting apparent molar isentropic compression of solute have been assessed utilizing speed of sound data. The expansivity parameter and its derivative with respect to temperature, and the pair and triplet interaction coefficients were evaluated. The findings of the study have been analyzed in terms of solute-solute and solute-solvent interactions in ternary systems.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100140"},"PeriodicalIF":0.0,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143686621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Algae cultivation in Ultra-high concentration Amino acid based ionic liquids 超高浓度氨基酸离子液体中藻类的培养

Journal of Ionic Liquids

Pub Date : 2025-02-25 DOI: 10.1016/j.jil.2025.100138

Yuchao Li , Yuli Kou , Jide Wang , Yansong Zhao

Liquid water is an important solvent for carbon-based life, due to its special structure and hydrogen bond engaging the biochemical reactions and energy transformations in the cell. However, the liquid window of water is narrow, within 0–100 °C at 1 atm. When water is partly replaced using ionic liquids (ILs) to transfer energy and nutrition, life activities may happen at a wide temperature range and a wide pressure range on earth, in the solar system and the universe. Aqueous Gly-based ILs were employed as a culture medium for the cultivation of algae. Four different kinds of Gly-based ILs were first synthesized by neutral reaction. Structure of synthesized ILs was confirmed by FT-IR and NMR. Furthermore, effect of Gly-based ILs concentration on algae growth was investigated. Growth rate of algae was tested by microscope and UV–vis according to the absorption of chlorophyll. The Gly-based IL presented higher biological compatibility of algae than previous work. The highest concentration of glycine phosphate suit for algae cultivation is 15 % and the algae could reproduce for 30 days without obvious inhibition. This research is promising work in the context of the cultivation of algae in amino acid IL based culture medium and exploring the life activity restricted zone on earth.

液态水以其特殊的结构和氢键参与细胞内的生化反应和能量转化，是碳基生命的重要溶剂。但是，水的液窗很窄，在1atm下0-100℃范围内。当水部分被离子液体取代以传递能量和营养时，生命活动可能在地球、太阳系和宇宙的宽温度范围和宽压力范围内发生。采用gly基il作为培养藻类的培养基。通过中性反应首次合成了四种不同的gly基il。通过红外光谱（FT-IR）和核磁共振（NMR）对合成的il的结构进行了确证。此外，我们还研究了gly基ILs浓度对藻类生长的影响。根据叶绿素的吸收情况，用显微镜和紫外-可见法测定了藻类的生长速度。与以往的研究相比，基于gly的IL具有更高的藻类生物相容性。磷酸甘氨酸的最高浓度为15%，海藻可繁殖30 d，无明显抑制作用。本研究在以氨基酸IL为基础的培养基中培养藻类，探索地球上的生命活动禁区的背景下，具有广阔的应用前景。

{"title":"Algae cultivation in Ultra-high concentration Amino acid based ionic liquids","authors":"Yuchao Li , Yuli Kou , Jide Wang , Yansong Zhao","doi":"10.1016/j.jil.2025.100138","DOIUrl":"10.1016/j.jil.2025.100138","url":null,"abstract":"<div><div>Liquid water is an important solvent for carbon-based life, due to its special structure and hydrogen bond engaging the biochemical reactions and energy transformations in the cell. However, the liquid window of water is narrow, within 0–100 °C at 1 atm. When water is partly replaced using ionic liquids (ILs) to transfer energy and nutrition, life activities may happen at a wide temperature range and a wide pressure range on earth, in the solar system and the universe. Aqueous Gly-based ILs were employed as a culture medium for the cultivation of algae. Four different kinds of Gly-based ILs were first synthesized by neutral reaction. Structure of synthesized ILs was confirmed by FT-IR and NMR. Furthermore, effect of Gly-based ILs concentration on algae growth was investigated. Growth rate of algae was tested by microscope and UV–vis according to the absorption of chlorophyll. The Gly-based IL presented higher biological compatibility of algae than previous work. The highest concentration of glycine phosphate suit for algae cultivation is 15 % and the algae could reproduce for 30 days without obvious inhibition. This research is promising work in the context of the cultivation of algae in amino acid IL based culture medium and exploring the life activity restricted zone on earth.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100138"},"PeriodicalIF":0.0,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143552207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Solvent effects of imidazolium ionic liquids on photophysical properties of π-electron extended rhodamine dye ABPX 咪唑类离子液体对π-电子延伸罗丹明染料ABPX光物理性质的溶剂效应

Journal of Ionic Liquids

Pub Date : 2025-02-04 DOI: 10.1016/j.jil.2025.100137

Kaoru Nobuoka , Shinji Enoki , Hideyuki Tanaka , Satoshi Kitaoka

We studied the solvent effect of imidazolium ionic liquids, which are media with microphase separation in their structure, on the cationic dye ABPX01. The proton accepting capacity of ionic liquids differs depending on their anions. Protonation of ABPX01 was enhanced in ionic liquids composed of anions with low proton accepting capacity, resulting in an increased proportion of dicationic forms. The alkyl group of the imidazolium cation caused a macroscopic change in viscosity, leading to a slight enhancement of the fluorescence intensity and an extension of the fluorescence lifetime. ABPX has potential material applications as a probe for the proton accepting capacity of ionic liquids and as a dye with AIE properties when used with suitable ionic liquids as a medium.

研究了咪唑类离子液体在阳离子染料ABPX01上的溶剂效应。离子液体的质子接受能力因其阴离子的不同而不同。ABPX01在由低质子接受能力阴离子组成的离子液体中质子化增强，导致阳离子形式比例增加。咪唑阳离子的烷基引起宏观粘度变化，导致荧光强度略有增强，荧光寿命延长。ABPX具有潜在的材料应用前景，可作为离子液体质子接受能力的探针，当与合适的离子液体作为介质使用时，可作为具有AIE特性的染料。

引用次数: 0

Understanding crystallinity indexes benchmarking concept from optimized parametric ionic liquid pretreatment using 1-ethyl-3-methylimidazolium Acetate [EMIM]Ac on oil palm biomass 了解油棕生物质1-乙基-3-甲基咪唑醋酸酯[EMIM]Ac优化参数离子液体预处理结晶性指标标杆概念

Journal of Ionic Liquids

Pub Date : 2025-02-01 DOI: 10.1016/j.jil.2025.100136

Amizon Azizan , Rosmaria Abu Darim , Intan Suhada Azmi , Rafidah Jalil , Shareena Fairuz Abdul Manaf

So much about the crystallinity details during lignocellulosic biomass pretreatment using ionic liquid as solvent has not been highly progressively described. The high expense associated with specific ionic liquids may have impeded the advancement of their use in pretreatment and its subsequent steps. Initially, the pretreated empty fruit bunch, oil palm frond, and oil palm trunk using 1-ethyl-3-methylimidazolium acetate ([EMIM]Ac) as ionic liquid solvent during pretreatment have indicated prospective distortion of the cellulosic chains. Simply using the calculated crystallinity status, for instance, from X-Ray Diffraction or Fourier Transform Infrared Spectroscopy analyses, may assist during the early decisive point regarding pretreatment effectiveness. Thus, in this article, the crystallinity status, like the crystallinity index (CrI) from X-Ray Diffraction analysis, was used as a beneficial preliminary predictive index to describe the transformation of less ordered structures in lignocellulosic biomass as an early decisive point after pretreatment prior to any succeeding steps. For this, fifteen (15) sets of pretreatment optimization strategies with the Box-Behnken design method (Response Surface Methodology) solely on oil palm frond (OPF) were further proceeded with using [EMIM]Ac concentration percentages of 20, 40, and 60% (v/v), with OPF solid loading percentages of 5, 10, and 15% (w/v), as well as at reactor temperatures of 90, 110, and 130 °C. All the linear model terms of these independent variables, along with the 2-way interaction model between the ionic liquid and solid loading, were found to be significant to the effect of CrI on the pretreated OPF. The proposed optimized pretreatment variable region for lower CrI was observed and concluded to be approximately 48% [EMIM]Ac with a solid loading of 12% OPF-[EMIM]Ac at a temperature of 93 °C. The optimized pretreatment strategy indicated a moderate balance between ionic liquid concentration percentage and operating temperature on a solid loading per volume basis. With this optimization data route, the challenge of determining which highly efficient ionic liquid is costly during pretreatment on any biomass can be shortened by preliminary CrI value benchmarking.

在使用离子液体作为溶剂的木质纤维素生物质预处理过程中，结晶度的细节还没有得到高度进展的描述。与特定离子液体相关的高费用可能阻碍了它们在预处理及其后续步骤中的应用。最初，在预处理过程中，使用1-乙基-3-甲基咪唑醋酸盐（[EMIM]Ac）作为离子液体溶剂，预处理后的空果束、油棕叶和油棕树干显示出纤维素链的潜在扭曲。简单地使用计算的结晶度状态，例如，从x射线衍射或傅里叶变换红外光谱分析，可以帮助在早期决定性的预处理效果。因此，在本文中，结晶度状态，如x射线衍射分析的结晶度指数（CrI），被用作有益的初步预测指标，以描述木质纤维素生物质中较无序结构的转变，作为预处理后任何后续步骤之前的早期决定性点。为此，采用Box-Behnken设计方法（响应面法）对油棕叶（OPF）进行了15组预处理优化策略，分别使用[EMIM]交流浓度百分比为20、40和60% (v/v)， OPF固体负荷百分比为5、10和15% (w/v)，反应器温度为90、110和130℃。所有这些自变量的线性模型项，以及离子液体和固体载荷之间的双向相互作用模型，都发现CrI对预处理后的OPF的影响是显著的。在温度为93℃的条件下，优化后的预处理可变区域为48% [EMIM]Ac，固体负载为12% OPF-[EMIM]Ac。优化后的预处理策略表明，离子液体浓度百分比和操作温度在单位体积固体负荷的基础上达到了适度的平衡。有了这个优化数据路线，通过初步的CrI值基准测试，可以缩短在任何生物质预处理过程中确定哪种高效离子液体成本高的挑战。

{"title":"Understanding crystallinity indexes benchmarking concept from optimized parametric ionic liquid pretreatment using 1-ethyl-3-methylimidazolium Acetate [EMIM]Ac on oil palm biomass","authors":"Amizon Azizan , Rosmaria Abu Darim , Intan Suhada Azmi , Rafidah Jalil , Shareena Fairuz Abdul Manaf","doi":"10.1016/j.jil.2025.100136","DOIUrl":"10.1016/j.jil.2025.100136","url":null,"abstract":"<div><div>So much about the crystallinity details during lignocellulosic biomass pretreatment using ionic liquid as solvent has not been highly progressively described. The high expense associated with specific ionic liquids may have impeded the advancement of their use in pretreatment and its subsequent steps. Initially, the pretreated empty fruit bunch, oil palm frond, and oil palm trunk using 1-ethyl-3-methylimidazolium acetate ([EMIM]Ac) as ionic liquid solvent during pretreatment have indicated prospective distortion of the cellulosic chains. Simply using the calculated crystallinity status, for instance, from X-Ray Diffraction or Fourier Transform Infrared Spectroscopy analyses, may assist during the early decisive point regarding pretreatment effectiveness. Thus, in this article, the crystallinity status, like the crystallinity index (CrI) from X-Ray Diffraction analysis, was used as a beneficial preliminary predictive index to describe the transformation of less ordered structures in lignocellulosic biomass as an early decisive point after pretreatment prior to any succeeding steps. For this, fifteen (15) sets of pretreatment optimization strategies with the Box-Behnken design method (Response Surface Methodology) solely on oil palm frond (OPF) were further proceeded with using [EMIM]Ac concentration percentages of 20, 40, and 60% (v/v), with OPF solid loading percentages of 5, 10, and 15% (w/v), as well as at reactor temperatures of 90, 110, and 130 °C. All the linear model terms of these independent variables, along with the 2-way interaction model between the ionic liquid and solid loading, were found to be significant to the effect of CrI on the pretreated OPF. The proposed optimized pretreatment variable region for lower CrI was observed and concluded to be approximately 48% [EMIM]Ac with a solid loading of 12% OPF-[EMIM]Ac at a temperature of 93 °C. The optimized pretreatment strategy indicated a moderate balance between ionic liquid concentration percentage and operating temperature on a solid loading per volume basis. With this optimization data route, the challenge of determining which highly efficient ionic liquid is costly during pretreatment on any biomass can be shortened by preliminary CrI value benchmarking.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100136"},"PeriodicalIF":0.0,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dynamic properties and diverse applications of deep eutectic solvents 深共晶溶剂的动态特性和多种应用

Journal of Ionic Liquids

Pub Date : 2025-01-28 DOI: 10.1016/j.jil.2025.100135

Sanjeeta, Ajay Singh, Jyoti Kavirajwar

In the current scenario, Deep Eutectic Solvents (DESs) have gained a lot of significance compared to organic solvents and Ionic liquids. Due to the presence of a hydrogen bond donor and hydrogen bond acceptor in DESs, dynamic properties such as high thermal stability, electrochemical stability, good solvating power, and moderate viscosity can be observed. A thorough description of basic characteristic features of the DESs such as their formation, structure, physicochemical properties, and their diverse applications are discussed in this review paper. Different parameters like temperature, composition or molar ratio, and nature of components influence the properties and hence the applications of Deep Eutectic solvents, confirmed in the literature. Their vast uses in different domains, like drug delivery, synthesis, extraction of material, and electrochemistry aspects are discussed in detail. DESs have the potential as sustainable green solvents and can contribute to strengthening green chemistry. Future directions and challenges for research are also focused, on maximizing the performance and extending the applications of DESs for a wide range of academic and industrial endeavors.

在目前的情况下，与有机溶剂和离子液体相比，深共晶溶剂（DESs）具有很大的意义。由于DESs中氢键给体和氢键受体的存在，使得DESs具有较高的热稳定性、电化学稳定性、良好的溶剂化能力和适中的粘度等动力学性能。本文对DESs的形成、结构、理化性质及其应用等基本特性进行了综述。不同的参数，如温度，组成或摩尔比，以及组分的性质会影响深共晶溶剂的性质，从而影响其应用，这在文献中得到证实。详细讨论了它们在不同领域的广泛应用，如药物传递、合成、物质提取和电化学方面。DESs具有作为可持续绿色溶剂的潜力，有助于加强绿色化学。未来的研究方向和挑战也集中在最大限度地提高DESs的性能和扩展其在学术和工业领域的应用上。

{"title":"Dynamic properties and diverse applications of deep eutectic solvents","authors":"Sanjeeta, Ajay Singh, Jyoti Kavirajwar","doi":"10.1016/j.jil.2025.100135","DOIUrl":"10.1016/j.jil.2025.100135","url":null,"abstract":"<div><div>In the current scenario, Deep Eutectic Solvents (DESs) have gained a lot of significance compared to organic solvents and Ionic liquids. Due to the presence of a hydrogen bond donor and hydrogen bond acceptor in DESs, dynamic properties such as high thermal stability, electrochemical stability, good solvating power, and moderate viscosity can be observed. A thorough description of basic characteristic features of the DESs such as their formation, structure, physicochemical properties, and their diverse applications are discussed in this review paper. Different parameters like temperature, composition or molar ratio, and nature of components influence the properties and hence the applications of Deep Eutectic solvents, confirmed in the literature. Their vast uses in different domains, like drug delivery, synthesis, extraction of material, and electrochemistry aspects are discussed in detail. DESs have the potential as sustainable green solvents and can contribute to strengthening green chemistry. Future directions and challenges for research are also focused, on maximizing the performance and extending the applications of DESs for a wide range of academic and industrial endeavors.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100135"},"PeriodicalIF":0.0,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Understanding the affinity of Cyphos Nitrate for Zr(IV) over other metal ions present in simulated high level liquid waste compositions 了解硝酸菌对模拟高浓度废液成分中Zr（IV）与其他金属离子的亲和力

Journal of Ionic Liquids

Pub Date : 2025-01-22 DOI: 10.1016/j.jil.2025.100134

Alok Rout , S. Sriram , N. Ramanathan

The presence of Zr(IV) in the spent nuclear fuel (SNF) is an hindrance for a smooth and safe reprocessing of actinides and other fission products. The separation of Zr(IV) from nitric acid feed through solvent extraction route is a challenging task as far as its aqueous chemistry and the selectivity of the proposed extractants for it is concerned. In this context, we employed a strongly hydrophobic and sustainable quarternary alkyl phosphonium-based ionic liquid (IL): Tri(hexyl)tetradecylphosphonium nitrate ([P₆₆₆₁₄][NO₃]) (or cyphos nitrate) for the extraction of Zr(IV) from a broad range of acidic feed and evaluated the feasibility of its selective separation from a Fast Reactor Simulated High Level Liquid Waste (FR-SHLLW) solution (Burn up: 80 GWd/Te). The extraction factor of [P₆₆₆₁₄][NO₃] was compared with that observed in other classes of ILs in their undiluted condition. The efficient extraction of Zr(IV) without any additional ligand in IL phase by adopting simple complexation mechanism infers the novelty of [P₆₆₆₁₄][NO₃]. High asymmetricity and bulkiness of IL cation enables more freedom to its anion (NO₃^-) to coordinate with Zr(IV), thereby realizing high extraction factors as compared to other ILs having different cations (or anions). The novelty was further clarified from the notable extraction efficiency by consuming very less IL volume (low IL to aqueous phase ratio). The radiation stability of cyphos nitrate was affirmed from the extraction factors at different exposed doses. The uniqueness of [P₆₆₆₁₄][NO₃] for Zr(IV) over the co-extracting Pd(II) was assured using an aqueous soluble complexing agent for the later to be trapped in the raffinate phase of SHLLW solution. At end, a schematic flow-sheet was proposed for selective separation of Zr(IV) from SHLLW solution.

废核燃料（SNF）中Zr（IV）的存在阻碍了锕系元素和其他裂变产物的顺利和安全后处理。溶剂萃取法从硝酸进料中分离Zr（IV）是一项具有挑战性的任务，涉及到它的水化学性质和所提出的萃取剂的选择性。在此背景下，我们采用了一种强疏水性和可持续的四烷基磷基离子液体（IL）：三（己基）十四烷基硝酸磷（[P66614][NO3]）（或硝酸硫）从各种酸性饲料中提取Zr(IV)，并评估了其从快堆模拟高放废液（FR-SHLLW）溶液（燃烧：80 GWd/Te）中选择性分离的可行性。比较了[P66614][NO3]在未稀释条件下与其他类il的提取率。采用简单的络合机制，在IL相中不添加任何配体的情况下，有效地提取Zr(IV)，由此推断出[P66614][NO3]的新颖性。IL阳离子的高不对称性和体积使得其阴离子（NO3-）与Zr（IV）的配位更加自由，从而实现了比其他不同阳离子（或阴离子）的IL更高的萃取因子。通过消耗非常少的IL体积（低IL与水相比）显著的萃取效率，进一步阐明了其新颖性。从提取因子的角度确定了不同辐照剂量下硝酸磷的辐射稳定性。用一种水溶性络合剂保证了[P66614][NO3]对Zr（IV）在共萃取Pd（II）中的唯一性，使后者被困在SHLLW溶液的萃余相中。最后，提出了从SHLLW溶液中选择性分离Zr（IV）的工艺流程图。

{"title":"Understanding the affinity of Cyphos Nitrate for Zr(IV) over other metal ions present in simulated high level liquid waste compositions","authors":"Alok Rout , S. Sriram , N. Ramanathan","doi":"10.1016/j.jil.2025.100134","DOIUrl":"10.1016/j.jil.2025.100134","url":null,"abstract":"<div><div>The presence of Zr(IV) in the spent nuclear fuel (SNF) is an hindrance for a smooth and safe reprocessing of actinides and other fission products. The separation of Zr(IV) from nitric acid feed through solvent extraction route is a challenging task as far as its aqueous chemistry and the selectivity of the proposed extractants for it is concerned. In this context, we employed a strongly hydrophobic and sustainable quarternary alkyl phosphonium-based ionic liquid (IL): Tri(hexyl)tetradecylphosphonium nitrate ([P<sub>66614</sub>][NO<sub>3</sub>]) (or cyphos nitrate) for the extraction of Zr(IV) from a broad range of acidic feed and evaluated the feasibility of its selective separation from a Fast Reactor Simulated High Level Liquid Waste (FR-SHLLW) solution (Burn up: 80 GWd/Te). The extraction factor of [P<sub>66614</sub>][NO<sub>3</sub>] was compared with that observed in other classes of ILs in their undiluted condition. The efficient extraction of Zr(IV) without any additional ligand in IL phase by adopting simple complexation mechanism infers the novelty of [P<sub>66614</sub>][NO<sub>3</sub>]. High asymmetricity and bulkiness of IL cation enables more freedom to its anion (NO<sub>3</sub><sup>-</sup>) to coordinate with Zr(IV), thereby realizing high extraction factors as compared to other ILs having different cations (or anions). The novelty was further clarified from the notable extraction efficiency by consuming very less IL volume (low IL to aqueous phase ratio). The radiation stability of cyphos nitrate was affirmed from the extraction factors at different exposed doses. The uniqueness of [P<sub>66614</sub>][NO<sub>3</sub>] for Zr(IV) over the co-extracting Pd(II) was assured using an aqueous soluble complexing agent for the later to be trapped in the raffinate phase of SHLLW solution. At end, a schematic flow-sheet was proposed for selective separation of Zr(IV) from SHLLW solution.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100134"},"PeriodicalIF":0.0,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oxidative dissolution of metals in metal-based ionic liquids: Iron, copper, silver and aluminum 金属基离子液体中金属的氧化溶解：铁、铜、银和铝

Journal of Ionic Liquids

Pub Date : 2025-01-20 DOI: 10.1016/j.jil.2025.100133

Yuchao Li , Yanxia Zheng , Huishuang Zhao , Qingshan Zhu , Yansong Zhao

Recycling of metals from end-of-life products requires an essential step of metal and alloy dissolution. Metal-based ionic liquids have the potential to be used for this purpose. However, scant work has been reported on oxidative dissolution of metal and alloys using metal-based ionic liquids. In this work, oxidative dissolution of four metals (Fe, Cu, Al and Ag) in pure metal-based ILs and aqueous IL is investigated. It is found that pure [Bmim][FeCl₄] has no significant corrosion on steel. However, steel ball and copper can be dissolved into 20 % [Bmim][FeCl₄] aqueous solution. Meanwhile, iron and copper powder can be quickly dissolved into [Bmim][CuCl₃] and [Bmim][AgCl₂] aqueous solution. Therefore, our results suggest that metal-based ionic liquid can be utilized to dissolve metal from mines using aqueous metal-based ionic liquid and then metal can be deposited from metal-rich aqueous metal-based ionic liquid water by removing water. By this method, high purified metal can be extracted from mines. In addition, with the increasing amount of electrical cars/buses, battery waste will be a big problem in the next 5–10 years. Our results manifest that a promising method for metal extraction from battery waste.

从报废产品中回收金属需要金属和合金溶解的重要步骤。金属基离子液体有潜力用于这一目的。然而，利用金属基离子液体对金属和合金进行氧化溶解的研究很少。本文研究了四种金属（Fe, Cu， Al和Ag）在纯金属基IL和水相IL中的氧化溶解。发现纯[Bmim][FeCl4]对钢没有明显的腐蚀作用。而钢球和铜可溶于20% [Bmim][FeCl4]水溶液中。同时，铁和铜粉末可以快速溶解在[Bmim][CuCl3]和[Bmim][AgCl2]水溶液中。因此，我们的研究结果表明，金属基离子液体可以利用金属基水离子液体溶解矿山中的金属，然后通过除水的方法从富金属的金属基水离子液体中沉积金属。用这种方法可以从矿山中提取出高纯度的金属。此外，随着电动汽车/公共汽车数量的增加，电池浪费将在未来5-10年成为一个大问题。我们的研究结果表明，从电池废料中提取金属是一种很有前途的方法。

{"title":"Oxidative dissolution of metals in metal-based ionic liquids: Iron, copper, silver and aluminum","authors":"Yuchao Li , Yanxia Zheng , Huishuang Zhao , Qingshan Zhu , Yansong Zhao","doi":"10.1016/j.jil.2025.100133","DOIUrl":"10.1016/j.jil.2025.100133","url":null,"abstract":"<div><div>Recycling of metals from end-of-life products requires an essential step of metal and alloy dissolution. Metal-based ionic liquids have the potential to be used for this purpose. However, scant work has been reported on oxidative dissolution of metal and alloys using metal-based ionic liquids. In this work, oxidative dissolution of four metals (Fe, Cu, Al and Ag) in pure metal-based ILs and aqueous IL is investigated. It is found that pure [Bmim][FeCl<sub>4</sub>] has no significant corrosion on steel. However, steel ball and copper can be dissolved into 20 % [Bmim][FeCl<sub>4</sub>] aqueous solution. Meanwhile, iron and copper powder can be quickly dissolved into [Bmim][CuCl<sub>3</sub>] and [Bmim][AgCl<sub>2</sub>] aqueous solution. Therefore, our results suggest that metal-based ionic liquid can be utilized to dissolve metal from mines using aqueous metal-based ionic liquid and then metal can be deposited from metal-rich aqueous metal-based ionic liquid water by removing water. By this method, high purified metal can be extracted from mines. In addition, with the increasing amount of electrical cars/buses, battery waste will be a big problem in the next 5–10 years. Our results manifest that a promising method for metal extraction from battery waste.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100133"},"PeriodicalIF":0.0,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Anti-Bacterial evaluation of 1,3-Benzodioxole derived imidazolium and pyridinium based ionic liquids 1,3-苯二唑衍生咪唑和吡啶类离子液体的抗菌评价

Journal of Ionic Liquids

Pub Date : 2025-01-13 DOI: 10.1016/j.jil.2024.100130

Sagar Panchal , Hitesh Sehrawat , Nisha Yadav , Shipra Chandra , Vivek Mishra , Neera Sharma , Ramesh Chandra

1,3-benzodioxole is one prominent biological active moiety which is abundant in numerous natural products. In this work we have synthesized 1,3-benzodioxole based ionic liquids using the different fluorides and have evaluated their anti-bacterial properties on Gram negative (-) Escherichia coli and Gram positive (+) Staphylococcus aureus bacterial strains were assessed. In this report we have reported the MIC (minimum inhibitor concentration) and ZOI (zone of inhibition) analysis of the different combinations and the best combination was the further used for the in-silico computational study for the interaction at the atomic level.

1,3-苯二唑是一种重要的生物活性成分，在许多天然产物中含量丰富。本研究利用不同的氟化物合成了1,3-苯二唑类离子液体，并评价了它们对革兰氏阴性（-）型大肠杆菌和革兰氏阳性（+）型金黄色葡萄球菌的抑菌性能。在本报告中，我们报道了不同组合的MIC（最小抑制剂浓度）和ZOI（抑制区）分析，并将最佳组合进一步用于原子水平上相互作用的计算机计算研究。

引用次数: 0

Bio-inspired novel choline ester ionic liquid gel polymer electrolytes for safer lithium-ion batteries 仿生新型胆碱酯离子液体凝胶聚合物电解质，用于更安全的锂离子电池

Journal of Ionic Liquids

Pub Date : 2025-01-05 DOI: 10.1016/j.jil.2025.100132

Tommy Hoong Wy Lee, Phei Li Lau, Ianatul Khoiroh

The rise in lithium battery use has triggered concerns regarding safety due to flammable liquid electrolytes. Ionic liquids (ILs) present an alternative, offering low volatility and high stability. This study explores novel choline-based ILs incorporated into a polymer matrix to synthesise ionic liquid gel polymer electrolytes (GPEs). Structural confirmation via Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) spectroscopy verified successful synthesis, while the thermogravimetric analyzer (TGA) revealed their promising thermal stability. GPEs demonstrated remarkable flammability resistance compared to commercial separators. Electrochemical assessments, including electrochemical impedance spectroscopy (EIS), linear sweep voltammetry (LSV), and galvanostatic charge-discharge (GCD), showcased high ionic conductivities and electrochemical stability. Transference numbers and dendrite growth analysis further underscored their excellent performance. Specifically, GPEs comprising 70 % propionyl choline bis(trifluoromethanesulfonyl)imide within a polymer matrix, poly(vinylidene fluoride)-co-hexafluoropropylene (PVDF-HFP), exhibited exceptional conductivity and transference numbers, positioning them as strong candidates for safer and more efficient lithium-ion battery electrolytes.

锂电池使用量的增加引发了人们对易燃液体电解质的安全担忧。离子液体（ILs）提供了一种替代方案，具有低挥发性和高稳定性。本研究探索了一种新的基于胆碱的离子液体凝胶聚合物电解质（gpe）。傅里叶变换红外光谱（FTIR）和核磁共振（NMR）的结构证实了合成的成功，热重分析仪（TGA）显示了它们良好的热稳定性。与商用分离器相比，gpe表现出显著的可燃性。电化学评估，包括电化学阻抗谱（EIS）、线性扫描伏安法（LSV）和恒流充放电（GCD），显示了高离子电导率和电化学稳定性。迁移数和枝晶生长分析进一步强调了它们的优异性能。具体来说，在聚合物基体聚偏氟乙烯-共六氟丙烯（PVDF-HFP）中含有70%丙酰胆碱二（三氟甲烷磺酰）亚胺的gpe表现出优异的导电性和转移率，使其成为更安全、更高效的锂离子电池电解质的有力候选材料。

{"title":"Bio-inspired novel choline ester ionic liquid gel polymer electrolytes for safer lithium-ion batteries","authors":"Tommy Hoong Wy Lee, Phei Li Lau, Ianatul Khoiroh","doi":"10.1016/j.jil.2025.100132","DOIUrl":"10.1016/j.jil.2025.100132","url":null,"abstract":"<div><div>The rise in lithium battery use has triggered concerns regarding safety due to flammable liquid electrolytes. Ionic liquids (ILs) present an alternative, offering low volatility and high stability. This study explores novel choline-based ILs incorporated into a polymer matrix to synthesise ionic liquid gel polymer electrolytes (GPEs). Structural confirmation via Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) spectroscopy verified successful synthesis, while the thermogravimetric analyzer (TGA) revealed their promising thermal stability. GPEs demonstrated remarkable flammability resistance compared to commercial separators. Electrochemical assessments, including electrochemical impedance spectroscopy (EIS), linear sweep voltammetry (LSV), and galvanostatic charge-discharge (GCD), showcased high ionic conductivities and electrochemical stability. Transference numbers and dendrite growth analysis further underscored their excellent performance. Specifically, GPEs comprising 70 % propionyl choline bis(trifluoromethanesulfonyl)imide within a polymer matrix, poly(vinylidene fluoride)-co-hexafluoropropylene (PVDF-HFP), exhibited exceptional conductivity and transference numbers, positioning them as strong candidates for safer and more efficient lithium-ion battery electrolytes.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100132"},"PeriodicalIF":0.0,"publicationDate":"2025-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0