: The binding of Ru(II) polypyridyl complexes [Ru(bpy) 3 ] 2+ , [Ru(dmbpy) 3 ] 2+ with 1,4-benzoquinone (BQ) and 2,6-dimethyl -1,4-benzoquinone (DMBQ) have been studied in triton x-100 using absorption spectral technique. The binding constant (K b ) for these reactions are determined from the Benesi-Hildebrand equation by means of absorption intensity data. Values of the binding constant reveal that they depend on the nature of the ligand, medium and also on the structure of the quinones. The ground state interaction between the luminophore and the quencher are hydrophobic in nature. Hydrophobic and structural effects play a vital role on the binding of the quinones with Ru(II) complexes.
{"title":"Binding Studies of Ruthenium(II) Polypyridyl Complexes with Quinones in Triton X-100","authors":"T. S. Celin, G. Raj","doi":"10.7598/cst2018.1540","DOIUrl":"https://doi.org/10.7598/cst2018.1540","url":null,"abstract":": The binding of Ru(II) polypyridyl complexes [Ru(bpy) 3 ] 2+ , [Ru(dmbpy) 3 ] 2+ with 1,4-benzoquinone (BQ) and 2,6-dimethyl -1,4-benzoquinone (DMBQ) have been studied in triton x-100 using absorption spectral technique. The binding constant (K b ) for these reactions are determined from the Benesi-Hildebrand equation by means of absorption intensity data. Values of the binding constant reveal that they depend on the nature of the ligand, medium and also on the structure of the quinones. The ground state interaction between the luminophore and the quencher are hydrophobic in nature. Hydrophobic and structural effects play a vital role on the binding of the quinones with Ru(II) complexes.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81686161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Belhassan, Samir CHTITA, T. Lakhlifi, M. Bouachrine
: ACD/ChemSketch, MarvinSketch and ChemOffice programs were used to calculate several molecular descriptors of 138 volatile compounds (32 hydrocarbons, 29 ketones, 28 aldehydes, 23 alcohols, 7 carboxylic acids, 6 halogenated compounds, 4 furans, 2 pyrazines, 1 ester, 1 sulphur compounds, 1 pyridine, 1 amine and three other compounds). The best descriptors were selected to establish the quantitative structure retention relationship (QSRR) of linear retention indices of volatile compounds using multiple linear regressions (MLR), multiple non-linear regressions (MNLR) and artificial neural network (ANN) methods. We propose quantitative models according to these analyses. The models were used to predict the linear retention indices of the test set compounds and agreement between the experimental and predicted values was verified. The descriptors showed by QSRR study were used for study and designing of new compounds. The statistical results indicate that the predicted values are in good agreement with the experimental results. To validate the predictive power of the resulting models, external validation multiple correlation coefficient was calculated and has both in addition to a performance prediction power, a favorable estimation of stability.
{"title":"QSRR Study of Linear Retention Indices for Volatile Compounds using Statistical Methods","authors":"A. Belhassan, Samir CHTITA, T. Lakhlifi, M. Bouachrine","doi":"10.7598/cst2018.1501","DOIUrl":"https://doi.org/10.7598/cst2018.1501","url":null,"abstract":": ACD/ChemSketch, MarvinSketch and ChemOffice programs were used to calculate several molecular descriptors of 138 volatile compounds (32 hydrocarbons, 29 ketones, 28 aldehydes, 23 alcohols, 7 carboxylic acids, 6 halogenated compounds, 4 furans, 2 pyrazines, 1 ester, 1 sulphur compounds, 1 pyridine, 1 amine and three other compounds). The best descriptors were selected to establish the quantitative structure retention relationship (QSRR) of linear retention indices of volatile compounds using multiple linear regressions (MLR), multiple non-linear regressions (MNLR) and artificial neural network (ANN) methods. We propose quantitative models according to these analyses. The models were used to predict the linear retention indices of the test set compounds and agreement between the experimental and predicted values was verified. The descriptors showed by QSRR study were used for study and designing of new compounds. The statistical results indicate that the predicted values are in good agreement with the experimental results. To validate the predictive power of the resulting models, external validation multiple correlation coefficient was calculated and has both in addition to a performance prediction power, a favorable estimation of stability.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84084367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Shukla, P. Gaur, Preeti Vaidya, B. Chaurasia, Sangeeta Jhariya
Four novel mix ligand complexes of manganese(II), iron(III), cobalt(II) and nickel(II) with dibasic tetra dentate Schiff base ligand BENZOEN and 1, 10-phenanthroline have been synthesized with the general composition of [M(BENZOEN)(1,10-phen)], where M = Mn(II), Co(II), Ni(II) and [Fe(BENZOEN)(1,10-phen)]Cl. The synthesized ligand and complexes were characterized on the basis of elemental analysis, molar conductance, magnetic susceptibility, ESIMS spectrometry, electronic spectra, FT-IR, H NMR and C NMR spectroscopy. Theoretical computation and combined experimental theoretical characterization were carrying out by Gaussian 09 software package using density functional theory (DFT) method to confirm the geometry of the investigated compounds. Additionally, molecular electrostatic potential map (MEP), HOMO, LUMO, NBO and Mullikan charge analysis were also been performed. Spectroscopic chracterization and DFT study proposed a distorted octahedral structure of complex 1-4. In vitro biomimetic catalase activity of the ligand and complexes was done by measuring amount of dioxygen evolve. Saturation kinetics of H2O2 decomposition was fitted to the Michaelis-Menten equation and Lineweaver-Burk plot. The antibacterial activity of the ligand and complexes against Escherichia coli shows complexes were found more potent than the BENZOEN. MIC of complexes shows that complex 2 is more active than other complexes even at lower concentration.
{"title":"Bio-Mimetic Catalase-like Activity, Corrosion Inhibition, Antibacterial, DFT and Spectroscopic Characterization of Mixed Ligand Complexes of 1,10-Phenanthroline with Dibasic Benzoin Schiff Base Ligand","authors":"S. Shukla, P. Gaur, Preeti Vaidya, B. Chaurasia, Sangeeta Jhariya","doi":"10.7598/cst2018.1519","DOIUrl":"https://doi.org/10.7598/cst2018.1519","url":null,"abstract":"Four novel mix ligand complexes of manganese(II), iron(III), cobalt(II) and nickel(II) with dibasic tetra dentate Schiff base ligand BENZOEN and 1, 10-phenanthroline have been synthesized with the general composition of [M(BENZOEN)(1,10-phen)], where M = Mn(II), Co(II), Ni(II) and [Fe(BENZOEN)(1,10-phen)]Cl. The synthesized ligand and complexes were characterized on the basis of elemental analysis, molar conductance, magnetic susceptibility, ESIMS spectrometry, electronic spectra, FT-IR, H NMR and C NMR spectroscopy. Theoretical computation and combined experimental theoretical characterization were carrying out by Gaussian 09 software package using density functional theory (DFT) method to confirm the geometry of the investigated compounds. Additionally, molecular electrostatic potential map (MEP), HOMO, LUMO, NBO and Mullikan charge analysis were also been performed. Spectroscopic chracterization and DFT study proposed a distorted octahedral structure of complex 1-4. In vitro biomimetic catalase activity of the ligand and complexes was done by measuring amount of dioxygen evolve. Saturation kinetics of H2O2 decomposition was fitted to the Michaelis-Menten equation and Lineweaver-Burk plot. The antibacterial activity of the ligand and complexes against Escherichia coli shows complexes were found more potent than the BENZOEN. MIC of complexes shows that complex 2 is more active than other complexes even at lower concentration.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84729582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shivangi Sharma, R. Sachar, G. D. Bajju, Vikas Sharma
A series of adducts of o-hexyl dithiocarbonate of nickel(II) [(C6H13OCS2)2 Ni] have been synthesized in 1:2 molar ratio by the reaction of aqueous solution of NiCl2.6H2O with aqueous solution of potassium salt of o-hexyl dithiocarbonate. These complexes were further reacted with nitrogen donor ligands to obtain donor stabilized complex of the type [(C6H13OCS2)2 Ni.nL], (L=2-,3-,4cyanopyridines and 2-,3-,4-aminopyridines, n=2). These adducts were characterized by elemental analysis, molar conductance, magnetic susceptibility measurements, IR and electronic spectral studies. The spectral studies revealed the trans octahedral geometry of the adducts around the Ni(II) metal ion. All the adducts were paramagnetic and non-electrolytic in nature. These complexes have also depicted the potential antifungal activity against the fungus Curvularia lunata.
{"title":"Synthesis and Characterization of Some Adducts of O-Hexyl Dithiocarbonates of Nickel(II) with Heterocyclic Amines","authors":"Shivangi Sharma, R. Sachar, G. D. Bajju, Vikas Sharma","doi":"10.7598/cst2018.1496","DOIUrl":"https://doi.org/10.7598/cst2018.1496","url":null,"abstract":"A series of adducts of o-hexyl dithiocarbonate of nickel(II) [(C6H13OCS2)2 Ni] have been synthesized in 1:2 molar ratio by the reaction of aqueous solution of NiCl2.6H2O with aqueous solution of potassium salt of o-hexyl dithiocarbonate. These complexes were further reacted with nitrogen donor ligands to obtain donor stabilized complex of the type [(C6H13OCS2)2 Ni.nL], (L=2-,3-,4cyanopyridines and 2-,3-,4-aminopyridines, n=2). These adducts were characterized by elemental analysis, molar conductance, magnetic susceptibility measurements, IR and electronic spectral studies. The spectral studies revealed the trans octahedral geometry of the adducts around the Ni(II) metal ion. All the adducts were paramagnetic and non-electrolytic in nature. These complexes have also depicted the potential antifungal activity against the fungus Curvularia lunata.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81558287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A series of new combretastatin urea derivatives (12a-j) were synthesized by reacting of substituted aromatic isocyanates (11a-j) to the combretastatin pyrazole-amine. The synthesized derivatives 11a-j were evaluated for their cytotoxicity against four human cancer cell lines (breast, lung and ovarian). Among them, compounds 12a, 12c, 12d, 12f, 12g and 12i were showed potent anticancer activity.
{"title":"Synthesis and Biological Evaluation of Urea Derivatives of Combretastatins as Anticancer Agents","authors":"V. Ramesh, G. Rao, B. Chakrapani, A. Chakravarthy","doi":"10.7598/cst2018.1525","DOIUrl":"https://doi.org/10.7598/cst2018.1525","url":null,"abstract":"A series of new combretastatin urea derivatives (12a-j) were synthesized by reacting of substituted aromatic isocyanates (11a-j) to the combretastatin pyrazole-amine. The synthesized derivatives 11a-j were evaluated for their cytotoxicity against four human cancer cell lines (breast, lung and ovarian). Among them, compounds 12a, 12c, 12d, 12f, 12g and 12i were showed potent anticancer activity.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77478220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A simple and convenient method for the synthesis of N3-substituted 3,4-dihydropyrimidinones has been achieved by the condensation of 3,4-dihydropyrimidinones with benzoyl chloride in pyridine. The advantages of this method are excellent yields, short reaction time, no-side reaction, operational simplicity and ease in experimental procedure. The key intermediate 3,4dihydropyrimidin-2(1H)-ones have been synthesized by condensation of β-ketoester, aromatic aldehydes and N-methyl urea using PTSA.
{"title":"Convenient Synthesis of Some Novel N3-Substituted 3, 4-Dihydropyrimidin-2(1H)-one Derivatives","authors":"R. Shastri","doi":"10.7598/cst2018.1543","DOIUrl":"https://doi.org/10.7598/cst2018.1543","url":null,"abstract":"A simple and convenient method for the synthesis of N3-substituted 3,4-dihydropyrimidinones has been achieved by the condensation of 3,4-dihydropyrimidinones with benzoyl chloride in pyridine. The advantages of this method are excellent yields, short reaction time, no-side reaction, operational simplicity and ease in experimental procedure. The key intermediate 3,4dihydropyrimidin-2(1H)-ones have been synthesized by condensation of β-ketoester, aromatic aldehydes and N-methyl urea using PTSA.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74353899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
: Two Schiff bases 9 H -carbazole-3-carbaldehyde-4-phenylthiosemicarbazone (CCPTSC) and 2-thiophenecarboxaldehyde-4-methylthiosemicarbazone (TCMTSC) were synthesized. Both the CCPTSC and TCMTSC were characterized by elemental analysis, molar conductivity studies, Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR), and x-ray powder diffraction (XRD). All the spectral studies confirmed that the formation of both CCPTSC and TCMTSC. Thermal stabilities of the both Schiff bases were reported based on thermogravimetric analysis (TGA) studies. This paper describes synthesis and characterization of two new ligands namely, 9 H -carbazole-3-carbaldehyde-4-phenylthiosemicarbazone (CCPTSC) and 2-thiophene-carboxaldehyde-4-methylthiosemicarbazone (TCMTSC). These newly synthesized chelating agents were characterized with elemental analysis, Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR), x-ray powder diffraction (XRD). The thermal stabilities of these compounds were established with thermogravimetric analysis studies.
合成了两个希夫碱9 H -咔唑-3-碳醛-4-苯基硫代氨基脲酮(CCPTSC)和2-噻吩碳醛-4-甲基硫代氨基脲酮(tccmtsc)。采用元素分析、摩尔电导率、傅里叶变换红外光谱(FT-IR)、核磁共振光谱(NMR)和x射线粉末衍射(XRD)对CCPTSC和tccmtsc进行了表征。所有的光谱研究都证实了CCPTSC和tccmtsc的形成。基于热重分析(TGA)研究报道了这两种希夫碱的热稳定性。本文介绍了9 H -咔唑-3-碳醛-4-苯基硫代氨基脲酮(CCPTSC)和2-噻吩-碳醛-4-甲基硫代氨基脲酮(tccmtsc)两种新配体的合成和表征。采用元素分析、傅里叶红外光谱(FT-IR)、核磁共振光谱(NMR)、x射线粉末衍射(XRD)等手段对新合成的螯合剂进行了表征。用热重分析方法确定了这些化合物的热稳定性。
{"title":"Synthesis and Characterization of 9H-Carbazole-3-carbaldehyde-4-phenylthiosemicarbazone and 2-Thiophenecarboxaldehyde-4-methyl-thiosemicarbazone","authors":"N. R. Jyothi, N. Farook","doi":"10.7598/cst2018.1545","DOIUrl":"https://doi.org/10.7598/cst2018.1545","url":null,"abstract":": Two Schiff bases 9 H -carbazole-3-carbaldehyde-4-phenylthiosemicarbazone (CCPTSC) and 2-thiophenecarboxaldehyde-4-methylthiosemicarbazone (TCMTSC) were synthesized. Both the CCPTSC and TCMTSC were characterized by elemental analysis, molar conductivity studies, Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR), and x-ray powder diffraction (XRD). All the spectral studies confirmed that the formation of both CCPTSC and TCMTSC. Thermal stabilities of the both Schiff bases were reported based on thermogravimetric analysis (TGA) studies. This paper describes synthesis and characterization of two new ligands namely, 9 H -carbazole-3-carbaldehyde-4-phenylthiosemicarbazone (CCPTSC) and 2-thiophene-carboxaldehyde-4-methylthiosemicarbazone (TCMTSC). These newly synthesized chelating agents were characterized with elemental analysis, Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR), x-ray powder diffraction (XRD). The thermal stabilities of these compounds were established with thermogravimetric analysis studies.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75350265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Charansing B. Ghoti, Shivangi S. Apte, M. Bhandarkar
: A 25 years old woman who ate her birthday cake, which was brought by her husband. After consumption of cake she felt some illness like irritation in chest and vomiting, so she was brought to hospital for treatment and doctors collected her gastric lavage during treatment. Chemical analysis of cake sample by thin layer chromatography and Gas chromatography-mass spectroscopy (GC-MS) revealed organophosphorus insecticide chlorpyrifos and pyrethroid insecticide cypermethrin, which confirmed intention of accused to cause health hazard to victim which may lead to homicide.
{"title":"A Rare Case of Insecticide Mixture Attempted Homicidal Poisoning Using Cake as a Medium: A Case Report","authors":"Charansing B. Ghoti, Shivangi S. Apte, M. Bhandarkar","doi":"10.7598/cst2018.1521","DOIUrl":"https://doi.org/10.7598/cst2018.1521","url":null,"abstract":": A 25 years old woman who ate her birthday cake, which was brought by her husband. After consumption of cake she felt some illness like irritation in chest and vomiting, so she was brought to hospital for treatment and doctors collected her gastric lavage during treatment. Chemical analysis of cake sample by thin layer chromatography and Gas chromatography-mass spectroscopy (GC-MS) revealed organophosphorus insecticide chlorpyrifos and pyrethroid insecticide cypermethrin, which confirmed intention of accused to cause health hazard to victim which may lead to homicide.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78273591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nonlinear optical (NLO) properties of N-substituted p-nitroaniline molecules, N-[3(naphthalene-1-yloxy)butyl]-4-nitroaniline (1), N-[3-(2,4,5-triazanaphthalene-1-yloxy)butyl]-4-nitroaniline (2) and N-[3-(2,4,5,7-tetraazanaphthalene-1-yloxy)butyl]-4-nitroaniline (3) have been calculated theoretically. The theoretical calculations were performed with three different hybrid density functional theories (DFT) i.e. BPV86, B3LYP and M-06 with 6-31++G (d,p) basis set. These molecular systems exhibit large first static hyperpolarizabilities. The optical response of these molecular systems is compared with that of p-nitroaniline, which is an excellent NLO dye. The result shows that, naphthalene or azanaphthalene derivatives of p-nitroaniline, exhibit large hyperpolarizability than p-nitroaniline and hence can be recommended for photovoltaic device fabrication.
{"title":"Theoretical Estimation of Non Linear Optical Properties of Organic Framework Containing p-Nitroaniline Linked to Naphthalene/azanaphthalene Through Saturated Carbon Chain","authors":"A. Varghese, M. George","doi":"10.7598/cst2018.1530","DOIUrl":"https://doi.org/10.7598/cst2018.1530","url":null,"abstract":"Nonlinear optical (NLO) properties of N-substituted p-nitroaniline molecules, N-[3(naphthalene-1-yloxy)butyl]-4-nitroaniline (1), N-[3-(2,4,5-triazanaphthalene-1-yloxy)butyl]-4-nitroaniline (2) and N-[3-(2,4,5,7-tetraazanaphthalene-1-yloxy)butyl]-4-nitroaniline (3) have been calculated theoretically. The theoretical calculations were performed with three different hybrid density functional theories (DFT) i.e. BPV86, B3LYP and M-06 with 6-31++G (d,p) basis set. These molecular systems exhibit large first static hyperpolarizabilities. The optical response of these molecular systems is compared with that of p-nitroaniline, which is an excellent NLO dye. The result shows that, naphthalene or azanaphthalene derivatives of p-nitroaniline, exhibit large hyperpolarizability than p-nitroaniline and hence can be recommended for photovoltaic device fabrication.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78491686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Two Schiff bases 10-hexyl-10H-phenothiazine-3-carbaldehyde-4-phenylthiosemicarbazone (HPCPTSC) and 4-methylbenzaldehyde-4-methylthiosemicarbazone (MBMTSC) were synthesized. Both the HPCPTSC and MBMTSC were characterized by elemental analysis, molar conductivity studies, Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR) and x-ray powder diffraction (XRD). All the spectral studies confirmed that the formation of both HPCPTSC and MBMTSC. Thermal stabilities of the both Schiff bases were reported based on thermogravimetric analysis (TGA) studies
{"title":"Synthesis and Characterization of 10-Hexyl-10H-phenothiazine-3-carbaldehyde-4-phenylthiosemi-carbazone and 4-Methylbenzaldehyde-4-methylthiosemicarbazone","authors":"N. R. Jyothi, N. Farook","doi":"10.7598/cst2018.1546","DOIUrl":"https://doi.org/10.7598/cst2018.1546","url":null,"abstract":"Two Schiff bases 10-hexyl-10H-phenothiazine-3-carbaldehyde-4-phenylthiosemicarbazone (HPCPTSC) and 4-methylbenzaldehyde-4-methylthiosemicarbazone (MBMTSC) were synthesized. Both the HPCPTSC and MBMTSC were characterized by elemental analysis, molar conductivity studies, Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR) and x-ray powder diffraction (XRD). All the spectral studies confirmed that the formation of both HPCPTSC and MBMTSC. Thermal stabilities of the both Schiff bases were reported based on thermogravimetric analysis (TGA) studies","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72613331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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