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Use of a convolutional neural network to segment signals of motor operated valves 使用卷积神经网络分割电机操作阀门的信号
Pub Date : 2021-09-23 DOI: 10.3897/nucet.7.73489
Konstantin I. Kotsoyev, Yevgeny L. Trykov, I. Trykova
Motor operated valves (MOV) are one of the most numerous classes of the nuclear power plant components. An important issue concerned with the MOV diagnostics is the lack of in-process (online) automated control for the MOV technical condition during full power operation of the NPP unit. In this regard, a vital task is that of the MOV diagnostics based on the signals of the current and voltage consumed during MOV ‘opening’ and ‘closing’ operations. The current and voltage signals represent time series measured at regular intervals. The current (and voltage) signals can be received online and contain all necessary information for the online diagnostics of the MOV status. Essentially, the approach allows active power signals to be calculated from the current and voltage signals, and characteristics (‘diagnostic signs’) to be extracted from particular portions (segments) of the active power signals using the values of which MOVs can be diagnosed. The paper deals with the problem of automating the segmentation of active power signals. To accomplish this, an algorithm has been developed based on using a convolutional neural network.
电机操作阀(MOV)是核电站中数量最多的部件之一。与MOV诊断有关的一个重要问题是,在核电站机组全功率运行期间,缺乏对MOV技术状态的过程(在线)自动控制。在这方面,一个重要的任务是基于MOV“打开”和“关闭”操作期间消耗的电流和电压信号的MOV诊断。电流和电压信号表示按一定间隔测量的时间序列。电流(和电压)信号可以在线接收,并包含在线诊断MOV状态所需的所有信息。从本质上讲,该方法允许从电流和电压信号中计算有功功率信号,并使用可诊断动动的值从有功功率信号的特定部分(段)中提取特征(“诊断信号”)。本文研究了有源电力信号的自动分割问题。为了实现这一目标,我们开发了一种基于卷积神经网络的算法。
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引用次数: 0
Effect of the burnable absorber arrangement on the VVER-1200 fuel assembly neutronic performance 可燃吸收器布置对VVER-1200燃料组件中子性能的影响
Pub Date : 2021-09-23 DOI: 10.3897/nucet.7.73490
R. A. Vnukov, V. Kolesov, I. Zhavoronkova, Ya. A. Kotov, Md Masum Rana Pramanik
Optimizing the use of fuel in a power reactor is a task of current concern. However, little attention has been given to investigating the dependences among the enrichment used, the content of gadolinium oxide in fuel elements, and the life time in combination with assessing the efficiency of using Gd fuel elements with different Gd2O3 contents. The paper considers fuel assembly (FA) versions for VVER-1200 reactors having different enrichments for fuel elements, including those with Gd, and different contents of gadolinium oxide in fuel. A comparative analysis is presented for assemblies with homogeneous Gd2O3 arrangements in each fuel element and with profiled Gd2O3 arrangements. In the latter case, profiling depends on the neutron flux density in the layer which includes Gd fuel elements. This suggests that the arrangement of gadolinium oxide proportionally to the neutron flux density will improve the FA neutronic performance. The results were obtained using SERPENT (a continuous-energy multi-purpose three-dimensional Monte Carlo particle transport code). The assemblies with the used parameters for a 12-month fuel cycle have shown the method under consideration to be inefficient for a period of over 300 eff. days. With increased enrichment and content of gadolinium oxide, the use of profiled versions has turned out to be more rational for longer periods (up to 900 eff. days). Therefore, this phenomenon is relevant for the reactor life, whereas it proves to be insignificant for the fuel life. A complex relationship is noted between the gadolinium and uranium content in an assembly and the effective multiplication factor for the profiled and standard assemblies. This relationship requires further detailed consideration.
优化动力反应堆燃料的使用是当前备受关注的课题。然而,结合使用不同Gd2O3含量的Gd燃料元件的效率,研究所使用的富集程度、燃料元件中氧化钆含量和寿命之间的依赖关系却很少有人关注。本文考虑了VVER-1200反应堆的燃料组件(FA)版本,它们具有不同的燃料元件富集度,包括含有Gd的燃料元件,以及燃料中氧化钆的不同含量。比较分析提出了具有均匀Gd2O3排列的组件在每个燃料元件和与轮廓Gd2O3排列。在后一种情况下,剖面取决于包含Gd燃料元件的层中的中子通量密度。这表明氧化钆与中子通量密度成比例的排列将改善FA的中子性能。结果使用SERPENT(连续能量多用途三维蒙特卡罗粒子输运码)得到。具有12个月燃料循环使用参数的组件表明,所考虑的方法在超过300个月的周期内效率低下。天。随着氧化钆的富集和含量的增加,在更长的时间(高达900年)内,使用异形版本更为合理。天)。因此,这一现象与反应堆寿命有关,而与燃料寿命无关。注意到组件中的钆和铀含量与剖面组件和标准组件的有效倍增因子之间存在复杂的关系。这种关系需要进一步详细考虑。
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引用次数: 2
Use of the chemical Fricke dosimeter and its modifications for dosimetry of gamma neutron radiation of a pulsed reactor 化学弗里克剂量计及其改进在脉冲反应堆中子辐射剂量测定中的应用
Pub Date : 2021-09-23 DOI: 10.3897/nucet.7.74149
V. Potetnya, E. Koryakina, M. Troshina, S. Koryakin
The paper investigates the characteristics of the chemical Fricke dosimeter (with the standard composition (D1), without NaCl addition to the solution (D2), without NaCl but with a tenfold increased concentration of Fe2+ (D3)) under continuous and pulsed irradiation with an ultra-high dose rate of the BARS-6 reactor with unshielded metallic cores. The dosimeter radiosensitivity had a linear dependence on the gamma neutron radiation dose in a range of 25 to 750 Gy and was respectively 1.96 ± 0.05 μGy–1 (D1), 2.04 ± 0.05 μGy–1 (D2), and 2.08 ± 0.5 μGy–1 (D3) in the continuous irradiation mode, and 1.24 ± 0.05 μGy–1, 2.00 ± 0.05 μGy–1, and 1.94 ± 0.05 μGy–1 in the pulsed irradiation mode. This makes ≈ 60% of their sensitivity to the 60Со gamma radiation (3.40 ± 0.02 μGy–1), and 36%, 1.6 times as less, for a standard Fricke dosimeter irradiated in the pulsed mode. The experimental value of the radiation chemical yield, Gn(Fe3+), for all solution modifications and both irradiation modes varied slightly and was 0.84 ± 0.11 μM/J on the average, except for the standard solution in the pulsed mode (0.66 ± 0.07 μM/J). The neutron doses determined by chemical and activation dosimeters coincided within the error limits, but the chemical dosimeter readings were systematically higher, by about 20%. Therefore, in the fission spectrum neutron dose rate range of 0.4 to 7×108 Gy/min, there is no dose rate effect both in the standard Fricke dosimeter version (without NaCl) and in the modified version, which makes it possible to use modified Fricke dosimeters to assess the physical and dosimetry characteristics of mixed gamma neutron radiation beams.
本文研究了化学弗里克剂量计(D1为标准组成,D2为不加NaCl, D3为不加NaCl)在bar -6无屏蔽金属堆芯的超高剂量率连续脉冲照射下的特性。剂量计辐射灵敏度在25 ~ 750 Gy范围内与γ -中子辐射剂量呈线性关系,在连续照射模式下分别为1.96±0.05 μGy-1 (D1)、2.04±0.05 μGy-1 (D2)和2.08±0.5 μGy-1 (D3),在脉冲照射模式下分别为1.24±0.05 μGy-1、2.00±0.05 μGy-1和1.94±0.05 μGy-1。这使得它们对60Со γ辐射(3.40±0.02 μGy-1)的灵敏度≈60%,对脉冲模式辐照的标准Fricke剂量计的灵敏度为36%,低1.6倍。除标准溶液在脉冲模式下(0.66±0.07 μM/J)外,两种辐照模式下的辐照化学产率Gn(Fe3+)实验值变化不大,平均值为0.84±0.11 μM/J。化学剂量计和活化剂量计测定的中子剂量在误差范围内一致,但化学剂量计的读数系统地高出约20%。因此,在0.4 ~ 7×108 Gy/min的裂变谱中子剂量率范围内,标准版本的Fricke剂量计(不含NaCl)和改进版本均不存在剂量率效应,这使得使用改进版本的Fricke剂量计评估混合伽马中子辐射束的物理特性和剂量学特性成为可能。
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引用次数: 0
Simulating operation of power units 1 and 2 at Novovoronezh NPP II with two electrical feed pumps disabled and the backup pump not enabled 模拟新沃罗涅日第二核电站1号和2号动力机组的运行,两台电动给水泵被禁用,备用泵未启用
Pub Date : 2021-09-23 DOI: 10.3897/nucet.7.72394
I. Gusev, Aleksandr P. Vorobyev, Mikhail N. Kozlovsky, S. P. Padun
Introduction. The article analyzes the operation of Unit 1 and 2 of Novovoronezh Nuclear Power Plant II (equipped with VVER-1200 reactors) with two electrical feed pumps disabled and the backup pump not enabled. These operating conditions are subsequently simulated using the power unit model software-hardware package (PUM SHC) developed by LLC IF SNIIP ATOM. Research objectives. The objective of this work was to check the reliability of the forecasts of changes in the power unit parameters obtained using the PUM SHC, based on operational data. Methods. The simulated power unit parameter changes in transient conditions were in good agreement with the data collected in real tests. During the simulation, the power unit dynamic stability was preserved, i.e., the operational parameters were within the design limits and did not exceed the protection operation set points. Results. The results of the work suggest the possibility of using current NPP power unit simulations: for developing proposals for adjusting the operation control algorithms in case of malfunctions and emergency modes with the main equipment shutdown and power unit protection actuation; and for verifying design solutions for updating the power unit systems, which are associated with the use of new equipment or changes in flow diagrams. Conclusion. Current power unit models can be applied both for existing power units and for new ones that are being commissioned.
介绍。本文分析了新沃罗涅日核电站1号机组和2号机组(配备VVER-1200反应堆)在两台给水泵停用、备用泵未启用的情况下的运行情况。随后,使用LLC IF SNIIP ATOM开发的动力单元模型软硬件包(PUM SHC)对这些运行条件进行了模拟。研究的目标。这项工作的目的是检查使用PUM SHC根据运行数据获得的动力单元参数变化预测的可靠性。方法。模拟的机组暂态参数变化与实际试验数据吻合较好。在仿真过程中,保持了机组的动态稳定性,即运行参数在设计范围内,不超过保护运行设定点。结果。研究结果表明,有可能采用目前的核电站动力单元模拟:在主设备关闭和动力单元保护启动的故障和紧急模式下,为调整运行控制算法提出建议;并验证更新动力单元系统的设计解决方案,这些解决方案与使用新设备或流程图的变化有关。结论。目前的动力单元模型既适用于现有的动力单元,也适用于正在服役的新动力单元。
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引用次数: 0
Ensuring radiation safety during temporary storage of solidified radioactive waste in light hangar-type facilities 确保放射性固体废物在轻型机库式设施临时贮存期间的辐射安全
Pub Date : 2021-09-23 DOI: 10.3897/nucet.7.73487
Sergey V. Rosnovsky, V. Povarov
Expensive permanent storage facilities with massive engineered structures are used traditionally to ensure safe temporary storage of solidified radioactive waste at the NPP sites. Such approach is dictated by the need to comply with the regulatory requirements for limiting the gamma background in the area adjacent to the storage facility. The costs involved in temporary storage of solidified RW can be optimized by using light hangar-type storage facilities. At the same time, the safety of storage, including radiation protection of the personnel, the public and the environment, is undoubtedly ensured through the use of special organizational and engineering solutions. The Novovoronezh NPP, a branch of JSC Concern Rosenergoatom, operates successfully light hangar-type facilities for temporary storage of solidified RW classified as medium-level waste in accordance with OSPORB-99/2009. In the process of operation, a methodology and a method for conditioning and temporary storage of solidified RW were developed to ensure the RW removal for final disposal with no extra process operations and unreasonable costs. A methodology has been developed to assess the radiation situation around storage facilities during temporary storage of RW, as well as a software package for predicting the radiation situation when deciding on the arrangement of the storage facility’s peripheral rows.
传统上,使用昂贵的大型工程结构的永久性储存设施来确保核电厂场址固化放射性废物的安全临时储存。这种方法是由于需要遵守限制储存设施附近区域的伽马背景辐射的法规要求。采用轻型机库式存储设施可以优化固化废渣临时存储的成本。同时,储存的安全性,包括人员、公众和环境的辐射防护,无疑是通过使用特殊的组织和工程解决方案来保证的。新沃罗涅日核电站是JSC关注Rosenergoatom的一个分支,根据OSPORB-99/2009,成功地运行了轻型机库式设施,用于临时储存被分类为中等水平废物的固化RW。在运行过程中,提出了一种固化RW的调理和临时储存的方法和方法,以确保最终处理的RW去除不需要额外的工艺操作和不合理的成本。已经开发了一种方法来评估临时储存放射性废物期间储存设施周围的辐射情况,以及在决定储存设施外围行排列时预测辐射情况的软件包。
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引用次数: 0
Investigations of regularities in the accumulation of hydrogen-reduced slags in circulation circuits with lead-containing coolants 含铅冷却剂循环回路中氢还原渣积累规律的研究
Pub Date : 2021-09-23 DOI: 10.3897/nucet.7.74154
V. Ulyanov, M. Koshelev, V. S. Kremlyova, S. Kharchuk
The paper presents a computational analysis of regularities in the accumulation of slags during the interaction of lead and lead-bismuth coolants with oxygen gas. Oxidation of lead-containing coolants will cause the formation of lead oxide, while the formation of bismuth oxide is unlikely. Dosed supply of oxidizing gas to lead-containing coolants makes it possible to oxidize, selectively, chromium and nickel to their oxides without the slag formation from solid lead oxide. Regularities were studied which are involved in the lead oxide formation during the interaction of lead-containing coolants with oxygen gas. It has been found that, in the process of interacting with oxygen gas, a lead-bismuth alloy is oxidized 1.7 times as intensively as lead, this being explained by the presence of bismuth in the alloy. Bismuth is oxidized more intensively than both lead and the lead-bismuth alloy. The inert gas overpressure during depressurization does not prevent air oxygen from entering the circuit, and the dependence of the nitrogen and oxygen flow into the circuit on the argon flow out of the loop is close to linear regardless of the circuit state (cold, without coolant; heated, without coolant; heated, with circulating coolant). Oxygen is a chemically active impurity and is absorbed by the circuit; it is therefore important to control nitrogen in the gas spaces of the reactor and research plant circuits with lead-containing coolants. This will make it possible to signal, in a timely manner, the ingress of oxygen into the circuit and to take measures required to avoid or reduce the scale of the slag formation from lead oxides.
本文对铅和铅铋冷却剂与氧气相互作用过程中炉渣积累规律进行了计算分析。含铅冷却剂的氧化会导致氧化铅的形成,而不太可能形成氧化铋。向含铅冷却剂提供一定量的氧化气体,可以选择性地将铬和镍氧化成它们的氧化物,而不会形成固体氧化铅的渣。研究了含铅冷却剂与氧气相互作用过程中氧化铅形成的规律。人们发现,在与氧气相互作用的过程中,铅铋合金的氧化强度是铅的1.7倍,这可以用合金中铋的存在来解释。铋比铅和铅铋合金更容易被氧化。减压过程中的惰性气体超压不能阻止空气氧进入回路,并且无论回路状态如何(冷,无冷却剂;加热,无冷却剂;加热,循环冷却液)。氧是一种化学活性杂质,被电路吸收;因此,控制反应堆气体空间中的氮和研究含铅冷却剂的工厂回路是很重要的。这将有可能及时发出信号,表明氧气进入电路,并采取必要措施,避免或减少铅氧化物形成渣的规模。
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引用次数: 0
Multi-criteria evaluation and ranking of potential scenarios for the development of Russian two-component nuclear energy system with thermal and sodium-cooled fast reactors 俄罗斯热冷快堆和钠冷快堆双组份核能系统发展潜在方案的多准则评估和排序
Pub Date : 2021-09-14 DOI: 10.3897/nucet.7.72391
V. Usanov, Stepan A. Kvyatkovskiy, A. Andrianov, I. Kuptsov
The paper presents the results from a multi-criteria comparative evaluation of potential deployment scenarios for Russian nuclear power with thermal and sodium-cooled fast reactors in a closed nuclear fuel cycle (the so-called two-component nuclear energy system). The comparison and the ranking were performed taking into account the recommendations and using the IAEA/INPRO software tools for comparative evaluation of nuclear energy systems, including tools for sensitivity/uncertainty analysis with respect to weighting factors. Ten potential Russian nuclear power deployment scenarios with different shares of thermal and sodium-cooled fast reactors were considered, including options involving the use of MOX fuel in VVER reactors. Eight key indicators were used, estimated as of 2100 and structured into a three-level objectives tree. The comparative evaluation and the ranking were carried out based on the multi-attribute value theory. The model for assessing the key indicators was developed using the IAEA/INPRO MESSAGE-NES energy system planning software tool. The information base for the study was formed by publications of experts from JSC SSC RF-IPPE, NRC Kurchatov Institute and NRNU MEPhI. The presented results show that it is possible to enhance significantly the sustainability of the Russian nuclear energy system, when considering multiple performance indicators, through the intensive deployment of sodium-cooled fast reactors and the transition to a closed nuclear fuel cycle. Tasks have been outlined for the follow-up studies to make it possible to obtain more rigorous conclusions regarding the preferred options for the evolution of a two-component nuclear energy system.
本文介绍了对俄罗斯核电在封闭核燃料循环(所谓的双组分核能系统)中使用热冷和钠冷快堆的潜在部署方案进行多标准比较评估的结果。考虑到这些建议并使用原子能机构/INPRO软件工具对核能系统进行比较评价,包括对加权因素进行敏感性/不确定性分析的工具,进行了比较和排名。考虑了10种不同份额的热冷和钠冷快堆的潜在俄罗斯核电部署方案,包括在VVER反应堆中使用MOX燃料的方案。使用了八个关键指标,估计截至2100年,并构成了一个三级目标树。基于多属性值理论进行了对比评价和排序。评估关键指标的模型是利用原子能机构/INPRO MESSAGE-NES能源系统规划软件工具开发的。本研究的信息库由JSC SSC RF-IPPE、NRC Kurchatov研究所和NRNU MEPhI的专家出版物组成。所提出的结果表明,在考虑多个性能指标时,通过密集部署钠冷快堆和向封闭核燃料循环过渡,有可能显著提高俄罗斯核能系统的可持续性。已概述了后续研究的任务,以便能够就发展双组分核能系统的首选办法得出更严格的结论。
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引用次数: 0
Sorption of 90Sr and 137Cs on clays used to build safety barriers in radioactive waste storage facilities 在放射性废物贮存设施中建立安全屏障用粘土对90Sr和137Cs的吸附
Pub Date : 2021-06-24 DOI: 10.3897/nucet.7.69930
I. Volkov, Viktoriya O. Zharkova, Y. Y. Karaseva, Еlena I. Lysakova, Е.V. Zakharova
The purpose of the work was to investigate the sorptive capacity of natural clay samples with respect to 90Sr and 137Cs to assess the possibility of using these as components of protective barriers at radioactive waste isolation facilities. Bentonite clays of the Zyryanskoye and Desyaty Khutor deposits and high-melting clay of the Kampanovskoye deposit were selected for the investigation. The capacity of clays for sorption through ionic exchange is characterized by the value of the cation exchange capacity (CEC). In the process of sorption experiments, all of the test clays displayed a high rate of extracting strontium and cesium radionuclides from aqueous solutions. It was shown that the sorption of 90Sr is affected by the content of montmorillonite in the samples: bentonite clays absorb up to 98–99% of the initial radionuclide content in the solution, while about 80% of strontium is sorbed by high-melting clay. Cesium is practically fully sorbed by the tested samples and the degree of sorption amounts to over 99%, the highest value of the distribution coefficient having been recorded for the Kampanovskoye sample (Kd = 5.0×103 cm3/g). The method of sorbed radionuclides fixation on the clay samples were identified by selective desorption using the modified Tessier methodology. It was shown that strontium ions are more mobile than ions of cesium up to 97% of which is retained by clays.
这项工作的目的是调查天然粘土样品对90Sr和137Cs的吸附能力,以评估在放射性废物隔离设施中将它们用作防护屏障成分的可能性。选取了Zyryanskoye和Desyaty Khutor矿床的膨润土粘土和Kampanovskoye矿床的高熔点粘土作为研究对象。粘土通过离子交换吸附的能力用阳离子交换容量(CEC)的值来表征。在吸附实验过程中,所有试验粘土均表现出较高的萃取率,可从水溶液中提取锶和铯放射性核素。结果表明,样品中蒙脱土的含量对90Sr的吸附有影响:膨润土粘土吸附了溶液中初始放射性核素含量的98-99%,而高熔点粘土吸附了约80%的锶。所测样品对铯几乎完全吸附,吸附程度达99%以上,在Kampanovskoye样品中记录到了最高的分布系数(Kd = 5.0×103 cm3/g)。采用改进的Tessier方法,通过选择性解吸鉴定了吸附核素固定粘土样品的方法。结果表明,锶离子比铯离子具有更强的流动性,其中97%被粘土保留。
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引用次数: 2
Influence of operating time on the corrosion in single-phase and two-phase media 操作时间对单相和两相介质腐蚀的影响
Pub Date : 2021-06-23 DOI: 10.3897/NUCET.7.69175
Valeriy Ivanovich Baranenko, O. M. Gulina, N. L. Salnikov
Modern foreign computer codes predict a linear growth in the pipeline wall thinning with time due to the process of flow-accelerated corrosion (FAC), i.e. erosion-corrosion wear (ECW). Linear time-thinning dependence and corrosion rate constancy are not however typical of the NPP piping operating conditions. And the associated excessive conservatism of the residual life estimates leads to increased economic costs of repeated inspections. In domestic software tools, EKI-02 and EKI-03, the influence of operating time are taken into account by introducing the respective coefficient into the Chexal-Horowitz model based on the yield of corrosion products into the coolant. The ECW intensity can be however reduced through improvements in operating conditions, preventive measures, improvements in water chemistry, etc., and the use of the dependences once obtained may turn out to be too conservative. Based on a large number of repeated measurements as well as on data from corrosion testers, it has been shown that the influence of time can be described by the function of a particular form, the coefficients of which differ for different units and component and subsystem types. This makes it possible to determine the ‘aging function’ based on inspection data, and then use it in a targeted way for particular components. It has been shown that such estimates are much less conservative.
现代国外计算机代码预测,由于流动加速腐蚀(FAC)过程,即侵蚀-腐蚀磨损(ECW),管道壁随时间变薄呈线性增长。然而,线性时间稀释依赖性和腐蚀速率常数并不是核电厂管道运行条件的典型特征。与此相关的剩余寿命估计的过度保守性导致重复检查的经济成本增加。在国内的软件工具EKI-02和EKI-03中,根据腐蚀产物进入冷却剂的量,在Chexal-Horowitz模型中引入了相应的系数,考虑了操作时间的影响。然而,可以通过改善操作条件、预防措施、改善水化学等措施来降低ECW强度,并且一旦获得依赖性的使用可能会变得过于保守。根据大量的重复测量和腐蚀试验数据,时间的影响可以用一种特定形式的函数来描述,其系数因单元、部件和子系统类型的不同而不同。这使得根据检测数据确定“老化函数”成为可能,然后针对特定部件有针对性地使用它。事实证明,这样的估计远没有那么保守。
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引用次数: 0
Generation of hydrogen by hydroheterogeneous compositions based on aluminum and alkali metals 以铝和碱金属为基础的氢非均相化合物生成氢
Pub Date : 2021-06-23 DOI: 10.3897/NUCET.7.69178
S. R. Askhadullin, Victor Konstantinovich Milinchuk
The process of hydrogen formation and the associated risk of combustion and explosion is a complex problem concerned with the hydrogen and radiation safety of nuclear reactors. Lithium, potassium and sodium hydroxides are used in VVER reactors as corrective additives for keeping the hydrogen potential of the water coolant with boric acid at a controlled level of 5.8 to 10.3. In the process of investigating the interaction of aqueous solutions of the above hydroxides with aluminum, the most chemically active of these is lithium hydroxide; this reaction proceeds with hydrogen formed at a high rate at room temperature (in an exothermic mode). The processes of hydrogen generation in hydroheterogeneous compositions with potassium and sodium hydroxides proceed at an acceptable rate with heating to ~ 60 °C. The kinetics of hydrogen generation depends in a complex way on the content of boric acid, namely, the hydrogen yield is at a level of ~ 1000 ml at a low concentration of 0.01 to 0.05 g/l, and there is no hydrogen formation at a concentration of 0.6 g/l. According to the coolant quality standards, in the hot state of a VVER-1000 unit or in the reactor state at the minimum controlled power level, the total concentration of alkali metals is about 1 mg/dm3, i.e. two to three orders of magnitude as less as in the investigated compositions. The discovery of the influence of alkali metal hydroxides on the formation of hydrogen with the participation of structural materials based on the example of aluminum makes it possible to suggest that the hydroxides of these metals contained in the coolant in a small amount can also take part in the hydroheterogeneous process of formation of minor hydrogen amounts. The potential for hydrogen formation in such a way needs to be taken into account during long-term operation of nuclear reactors, and during accidents and incidents at NPPs
氢的形成过程及其燃烧爆炸危险是一个涉及核反应堆氢与辐射安全的复杂问题。氢氧化锂、钾和氢氧化钠在VVER反应堆中用作校正添加剂,以使含硼酸的水冷剂的氢势保持在5.8至10.3的受控水平。在研究上述氢氧化物水溶液与铝的相互作用过程中,化学活性最高的是氢氧化锂;在室温下(在放热模式下)以高速率生成氢气进行反应。在加热至~ 60°C时,以可接受的速率在氢氧化钾和氢氧化钠的非均相组合物中生成氢的过程进行。产氢动力学与硼酸的含量有复杂的关系,即在0.01 ~ 0.05 g/l的低浓度下,产氢量为~ 1000 ml,而在0.6 g/l的浓度下则不产氢。根据冷却剂质量标准,在VVER-1000机组的热态或在最小控制功率水平的反应堆状态下,碱金属的总浓度约为1 mg/dm3,即比所研究的组合物低两到三个数量级。在以铝为例的结构材料的参与下,碱金属氢氧化物对氢的形成的影响的发现使人们有可能提出,冷却剂中含有的少量碱金属氢氧化物也可以参与形成少量氢的非均相过程。在核反应堆的长期运行过程中,以及在核电站发生事故和事故时,需要考虑以这种方式形成氢气的可能性
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引用次数: 0
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Nuclear Energy and Technology
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