Pub Date : 2025-12-04DOI: 10.1016/j.rinma.2025.100835
Md Moinul Hasan Sadik , Akash Baral , Md Sojeeb Ahmed , Md Khalid Al Zuhanee , Md Ashraful Islam , Md Abdul Wakil , Md Abdul Hasib
The reliable prediction of mechanical properties in natural fiber–based composites is crucial for their advancement as sustainable structural materials. The development of natural fiber–based hybrid composites is often hindered by costly, resource-intensive, and time-consuming experimental iterations. While Machine Learning (ML) offers a powerful alternative for accelerating property prediction, standard models often function as 'black boxes,' which limits their trustworthiness and fails to provide the scientific insights needed for true material design. This study addresses this critical gap by developing and validating an integrated framework that combines experiments, Finite Element Analysis, and Explainable Machine learning to predict and interpret mechanical properties of banana fiber reinforced composites. Four supervised machine learning (ML) models—Random Forest, XGBoost, Gradient Boosting, and k-Nearest Neighbor—were developed and trained on a combined literature–experimental dataset. Among them, the XGBoost model exhibited the highest predictive accuracy, achieving R2 values of 0.71 for tensile strength and 0.76 for flexural strength in validation. To address the “black box” challenge of ML, SHapley Additive exPlanations (SHAP) analysis was employed, revealing fiber length and filler percentage as the most influential features governing strength predictions. The integration of ML with experimental and numerical validation demonstrates a powerful framework for reducing trial-and-error in composite design, while providing interpretable insights into the role of key material parameters. This work establishes explainable ML as an effective and sustainable tool for optimizing natural fiber–based hybrid composites.
{"title":"Integrating experiments, finite element analysis, and explainable machine learning for natural fiber based hybrid composites","authors":"Md Moinul Hasan Sadik , Akash Baral , Md Sojeeb Ahmed , Md Khalid Al Zuhanee , Md Ashraful Islam , Md Abdul Wakil , Md Abdul Hasib","doi":"10.1016/j.rinma.2025.100835","DOIUrl":"10.1016/j.rinma.2025.100835","url":null,"abstract":"<div><div>The reliable prediction of mechanical properties in natural fiber–based composites is crucial for their advancement as sustainable structural materials. The development of natural fiber–based hybrid composites is often hindered by costly, resource-intensive, and time-consuming experimental iterations. While Machine Learning (ML) offers a powerful alternative for accelerating property prediction, standard models often function as 'black boxes,' which limits their trustworthiness and fails to provide the scientific insights needed for true material design. This study addresses this critical gap by developing and validating an integrated framework that combines experiments, Finite Element Analysis, and Explainable Machine learning to predict and interpret mechanical properties of banana fiber reinforced composites. Four supervised machine learning (ML) models—Random Forest, XGBoost, Gradient Boosting, and k-Nearest Neighbor—were developed and trained on a combined literature–experimental dataset. Among them, the XGBoost model exhibited the highest predictive accuracy, achieving R<sup>2</sup> values of 0.71 for tensile strength and 0.76 for flexural strength in validation. To address the “black box” challenge of ML, SHapley Additive exPlanations (SHAP) analysis was employed, revealing fiber length and filler percentage as the most influential features governing strength predictions. The integration of ML with experimental and numerical validation demonstrates a powerful framework for reducing trial-and-error in composite design, while providing interpretable insights into the role of key material parameters. This work establishes explainable ML as an effective and sustainable tool for optimizing natural fiber–based hybrid composites.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"29 ","pages":"Article 100835"},"PeriodicalIF":0.0,"publicationDate":"2025-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145750179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.rinma.2025.100824
S. Benkhirat , E. Ribeiro , S. Eichendorff , E. Beche , K. Nouneh , G. Plantard
This work is part of a context of development of efficient photocatalytic materials for solar photoconversion in order to produce reactive species for degradation. Cellular foams, perfectly suited candidates, are the main subject of this work. Geopolymer foams were developed using two shaping methods, namely a replication method and a direct foaming method using a pore-forming agent. Macroporous cellular foams with a wide range of porous characteristics and porosities ranging from 0.06 to 0.9 were thus developed. The radiative properties were calculated by an experimental approach coupled with modeling. The absorption and diffusion coefficients, which depend on the porous characteristics, vary from 2 to more than 12 m2/kg depending on the porosity of the foams. The absorption capacity is directly correlated to the average porosity of macroporous cellular foams, which promotes the diffusion of radiation within the cellular structure. The photoconversion process via the evaluation of the photocatalytic efficiency was then studied for the different foams. It appears that the photocatalytic efficiency is correlated to the porous characteristics of the foams. The photocatalytic efficiency of geopolymer foams consisting of closed or partially connected pores varies slightly. On the other hand, beyond the porosity threshold of 0.5, the photocatalytic efficiency of reticulated cellular foams consisting of an open porous network increases significantly depending on the porosity. A cellular geopolymer foam with a porosity equal to 0.89 gives an efficiency of 0.7 %. This value is of the order of magnitude of those obtained in the literature for reticulated foams with high porosity. It also appears that catalytic performances are correlated with the radiative properties and in particular with the absorption coefficient of the foams. This original study establishes a correlation between porosity and photocatalytic performance highlighting the importance of porous properties. It seems essential to move towards the shaping of reticulated alveolar foams with high porosity consisting of open pores and millimeter sizes.
{"title":"Implementation of ZnO-functionalized macroporous cellular geopolymer foams: influence of porosity on radiative and photocatalytic properties","authors":"S. Benkhirat , E. Ribeiro , S. Eichendorff , E. Beche , K. Nouneh , G. Plantard","doi":"10.1016/j.rinma.2025.100824","DOIUrl":"10.1016/j.rinma.2025.100824","url":null,"abstract":"<div><div>This work is part of a context of development of efficient photocatalytic materials for solar photoconversion in order to produce reactive species for degradation. Cellular foams, perfectly suited candidates, are the main subject of this work. Geopolymer foams were developed using two shaping methods, namely a replication method and a direct foaming method using a pore-forming agent. Macroporous cellular foams with a wide range of porous characteristics and porosities ranging from 0.06 to 0.9 were thus developed. The radiative properties were calculated by an experimental approach coupled with modeling. The absorption and diffusion coefficients, which depend on the porous characteristics, vary from 2 to more than 12 m<sup>2</sup>/kg depending on the porosity of the foams. The absorption capacity is directly correlated to the average porosity of macroporous cellular foams, which promotes the diffusion of radiation within the cellular structure. The photoconversion process via the evaluation of the photocatalytic efficiency was then studied for the different foams. It appears that the photocatalytic efficiency is correlated to the porous characteristics of the foams. The photocatalytic efficiency of geopolymer foams consisting of closed or partially connected pores varies slightly. On the other hand, beyond the porosity threshold of 0.5, the photocatalytic efficiency of reticulated cellular foams consisting of an open porous network increases significantly depending on the porosity. A cellular geopolymer foam with a porosity equal to 0.89 gives an efficiency of 0.7 %. This value is of the order of magnitude of those obtained in the literature for reticulated foams with high porosity. It also appears that catalytic performances are correlated with the radiative properties and in particular with the absorption coefficient of the foams. This original study establishes a correlation between porosity and photocatalytic performance highlighting the importance of porous properties. It seems essential to move towards the shaping of reticulated alveolar foams with high porosity consisting of open pores and millimeter sizes.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100824"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145693002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.rinma.2025.100833
Shimelis Tamene Gobena , Abraham Debebe Woldeyohannes
Polyether ether ketone (PEEK) is a high-performance thermoplastic polymer known for its exceptional mechanical strength, high thermal stability, and chemical resistance, making it suitable for aerospace, automotive, and biomedical applications. The aim of this study is to characterize and analyze the effects of process parameters on 3D Printed PEEK, using numerical modeling and experimental investigation. Finite element analysis (FEA) using ANSYS Workbench was applied to investigate molten PEEK flow through the nozzle and assess the influence of critical process parameters including printing temperature (380 °C, 400 °C, and 420 °C), nozzle diameter (Ø0.4 mm), layer thicknesses (0.2 mm, 0.25 mm, and 0.3 mm), and filament feeding speeds (20 mm/s, 25 mm/s, and 30 mm/s). The simulation considered relevant boundary conditions and thermal-fluid material properties to replicate realistic flow behavior. The results demonstrated that nozzle diameter significantly affected pressure drop, while printing temperature and feeding speed influenced viscosity and temperature distribution within the nozzle. A smaller nozzle diameter increased pressure drop, while higher temperatures and feeding speeds improved molten PEEK flow behavior, positively impacting the quality of printed parts. Phase transformations during extrusion were also observed, from solid to vitreous and then to liquid as the temperature increased. These transitions were found to influence the bonding quality and uniformity of extruded layers. Experimental validation was performed on 3D-printed PEEK samples using the same set of process parameters.
The simulation modeling was employed to select critical printing parameters and understand the flow behavior of PEEK prior to actual FDM printing. Mechanical testing showed that impact strength improved with increasing printing temperature, ranging from 44 kJ/m2 at 380 °C to 50 kJ/m2 at 420 °C, while achieving a UTS of 120 MPa and modulus of 4.6 GPa. Interaction effects indicated that lower printing speeds (20 mm/s) enhanced interlayer adhesion through prolonged thermal contact, especially with moderate layer thicknesses of 0.2–0.25 mm.
Unlike previous studies, this work also investigated multiple properties, Mechanical properties, physical properties, including porosity and density, alongside thermal stability, crystallinity, and microstructure. The results demonstrate that careful optimization of printing parameters significantly improves the overall performance of 3D-printed PEEK. These findings provide comprehensive guidance for producing high-quality, mechanically robust PEEK components.
{"title":"Characterization and effects of process parameters on the mechanical, microstructural, and thermal behavior of PEEK in fused deposited modeling 3D printing","authors":"Shimelis Tamene Gobena , Abraham Debebe Woldeyohannes","doi":"10.1016/j.rinma.2025.100833","DOIUrl":"10.1016/j.rinma.2025.100833","url":null,"abstract":"<div><div>Polyether ether ketone (PEEK) is a high-performance thermoplastic polymer known for its exceptional mechanical strength, high thermal stability, and chemical resistance, making it suitable for aerospace, automotive, and biomedical applications. The aim of this study is to characterize and analyze the effects of process parameters on 3D Printed PEEK, using numerical modeling and experimental investigation. Finite element analysis (FEA) using ANSYS Workbench was applied to investigate molten PEEK flow through the nozzle and assess the influence of critical process parameters including printing temperature (380 °C, 400 °C, and 420 °C), nozzle diameter (Ø0.4 mm), layer thicknesses (0.2 mm, 0.25 mm, and 0.3 mm), and filament feeding speeds (20 mm/s, 25 mm/s, and 30 mm/s). The simulation considered relevant boundary conditions and thermal-fluid material properties to replicate realistic flow behavior. The results demonstrated that nozzle diameter significantly affected pressure drop, while printing temperature and feeding speed influenced viscosity and temperature distribution within the nozzle. A smaller nozzle diameter increased pressure drop, while higher temperatures and feeding speeds improved molten PEEK flow behavior, positively impacting the quality of printed parts. Phase transformations during extrusion were also observed, from solid to vitreous and then to liquid as the temperature increased. These transitions were found to influence the bonding quality and uniformity of extruded layers. Experimental validation was performed on 3D-printed PEEK samples using the same set of process parameters.</div><div>The simulation modeling was employed to select critical printing parameters and understand the flow behavior of PEEK prior to actual FDM printing. Mechanical testing showed that impact strength improved with increasing printing temperature, ranging from 44 kJ/m<sup>2</sup> at 380 °C to 50 kJ/m<sup>2</sup> at 420 °C, while achieving a UTS of 120 MPa and modulus of 4.6 GPa. Interaction effects indicated that lower printing speeds (20 mm/s) enhanced interlayer adhesion through prolonged thermal contact, especially with moderate layer thicknesses of 0.2–0.25 mm.</div><div>Unlike previous studies, this work also investigated multiple properties, Mechanical properties, physical properties, including porosity and density, alongside thermal stability, crystallinity, and microstructure. The results demonstrate that careful optimization of printing parameters significantly improves the overall performance of 3D-printed PEEK. These findings provide comprehensive guidance for producing high-quality, mechanically robust PEEK components.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100833"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145693003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/S2590-048X(25)00197-9
{"title":"Aims and Scope","authors":"","doi":"10.1016/S2590-048X(25)00197-9","DOIUrl":"10.1016/S2590-048X(25)00197-9","url":null,"abstract":"","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100852"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145750046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.rinma.2025.100816
Yosra M. Atteya, Mohamed F. Aly, Mahmoud M. Farag
Thermoplastic starch (TPS) are natural composites that have shown in the recent decay a promising outcomes as a natural material friend to the environment, that could replace the synthetic petroleum derived plastics. TPS materials have a varied ranges of mechanical and physical characteristics that differs with the difference of the used components, and with the preparation method. Also, TPS composites have a variable textures and structural features, that is formed according to the incorporated fillers and reinforcements, whether they are cellulosic fibers or resins, renewable or nonrenewable, metallic or organic, synthetic or natural. This review aims to comprise and categories the parameters that influence the TPS chemical, physical and mechanical characteristics, and to study how the fillers (reinforcements) type, size, treatment procedures and preparation methodology affect the composite features, characteristics and applications.
{"title":"TPS and natural composites elements, techniques, challenges, and applications","authors":"Yosra M. Atteya, Mohamed F. Aly, Mahmoud M. Farag","doi":"10.1016/j.rinma.2025.100816","DOIUrl":"10.1016/j.rinma.2025.100816","url":null,"abstract":"<div><div>Thermoplastic starch (TPS) are natural composites that have shown in the recent decay a promising outcomes as a natural material friend to the environment, that could replace the synthetic petroleum derived plastics. TPS materials have a varied ranges of mechanical and physical characteristics that differs with the difference of the used components, and with the preparation method. Also, TPS composites have a variable textures and structural features, that is formed according to the incorporated fillers and reinforcements, whether they are cellulosic fibers or resins, renewable or nonrenewable, metallic or organic, synthetic or natural. This review aims to comprise and categories the parameters that influence the TPS chemical, physical and mechanical characteristics, and to study how the fillers (reinforcements) type, size, treatment procedures and preparation methodology affect the composite features, characteristics and applications.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100816"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145693679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.rinma.2025.100828
Arezou Abyazi, Faezeh Fakheri
In this study, the formation of Fe3O4 nanoparticle coatings on gray cast iron was investigated. Two blackening methods, including a hot alkaline (open system) and a hydrothermal method (closed system), were employed. The hot alkaline method faced challenges due to the presence of near-surface graphite, leading to the formation of a porous and defective coating containing significant amounts of hematite (Fe2O3), as confirmed by thermodynamic calculations. In contrast, a dense and uniform high-quality Fe3O4 coating was produced by the hydrothermal method, and the issues related to surface graphite were effectively resolved by converting it into carbon-based nanomaterials inside the autoclave. Quantitative comparison showed that the hot alkaline coated specimens had icorr = (2.11 ± 0.04) × 10−6 A cm−2, bond strength = 1.34 ± 0.04 MPa, and Ra ≈ 1.42 ± 0.36 μm, whereas the hydrothermally treated samples exhibited icorr = (1.54 ± 0.03) × 10−6 A cm−2, bond strength = 2.56 ± 0.03 MPa, and Ra ≈ 40.36 ± 1.2 nm, indicating markedly improved corrosion resistance, adhesion, and surface quality. The resulting coatings were characterized using XRD, Field Emission Scanning Electron Microscopy (FE-SEM), Atomic Force Microscopy (AFM), Pull-off adhesion test, and corrosion tests, including Open Circuit Potential (OCP), potentiodynamic polarization, and Electrochemical Impedance Spectroscopy (EIS).
本文研究了灰口铸铁表面纳米Fe3O4涂层的形成。采用热碱性(开放体系)和水热法(封闭体系)两种发黑方法。热力学计算证实,由于近表面石墨的存在,热碱性方法面临挑战,导致形成含有大量赤铁矿(Fe2O3)的多孔和有缺陷的涂层。相比之下,水热法制备了致密均匀的高质量Fe3O4涂层,通过在热压釜内将其转化为碳基纳米材料,有效地解决了表面石墨的相关问题。定量比较表明,热碱性涂层样品的icorr =(2.11±0.04)× 10−6 A cm−2,结合强度= 1.34±0.04 MPa, Ra≈1.42±0.36 μm,而水热处理样品的icorr =(1.54±0.03)× 10−6 A cm−2,结合强度= 2.56±0.03 MPa, Ra≈40.36±1.2 nm,耐蚀性、粘附性和表面质量均有显著提高。采用XRD、场发射扫描电镜(FE-SEM)、原子力显微镜(AFM)、拉脱附着力测试和腐蚀测试(包括开路电位(OCP)、动电位极化和电化学阻抗谱(EIS))对涂层进行了表征。
{"title":"Deposition of magnetite nano-particles on gray cast iron via hot alkaline and hydrothermal conversion methods: with regarding corrosion behaviour","authors":"Arezou Abyazi, Faezeh Fakheri","doi":"10.1016/j.rinma.2025.100828","DOIUrl":"10.1016/j.rinma.2025.100828","url":null,"abstract":"<div><div>In this study, the formation of Fe<sub>3</sub>O<sub>4</sub> nanoparticle coatings on gray cast iron was investigated. Two blackening methods, including a hot alkaline (open system) and a hydrothermal method (closed system), were employed. The hot alkaline method faced challenges due to the presence of near-surface graphite, leading to the formation of a porous and defective coating containing significant amounts of hematite (Fe<sub>2</sub>O<sub>3</sub>), as confirmed by thermodynamic calculations. In contrast, a dense and uniform high-quality Fe<sub>3</sub>O<sub>4</sub> coating was produced by the hydrothermal method, and the issues related to surface graphite were effectively resolved by converting it into carbon-based nanomaterials inside the autoclave. Quantitative comparison showed that the hot alkaline coated specimens had <em>i</em><sub><em>corr</em></sub> = (2.11 ± 0.04) × 10<sup>−6</sup> A cm<sup>−2</sup>, bond strength = 1.34 ± 0.04 MPa, and <em>R</em><sub>a</sub> ≈ 1.42 ± 0.36 μm, whereas the hydrothermally treated samples exhibited <em>i</em><sub><em>corr</em></sub> = (1.54 ± 0.03) × 10<sup>−6</sup> A cm<sup>−2</sup>, bond strength = 2.56 ± 0.03 MPa, and <em>R</em><sub>a</sub> ≈ 40.36 ± 1.2 nm, indicating markedly improved corrosion resistance, adhesion, and surface quality. The resulting coatings were characterized using XRD, Field Emission Scanning Electron Microscopy (FE-SEM), Atomic Force Microscopy (AFM), Pull-off adhesion test, and corrosion tests, including Open Circuit Potential (OCP), potentiodynamic polarization, and Electrochemical Impedance Spectroscopy (EIS).</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100828"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145623811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.rinma.2025.100829
Husam Al Qablan
The stress–strain diagram of SFRC is a crucial tool for evaluating its mechanical properties, as it clearly illustrates the enhanced strength, ductility, and energy absorption provided by the steel fibers. The present research presents a novel method for developing a predictive model for predicting the compression stress-strain curve of steel fiber reinforced concrete (SFRC), offering a reliable tool to capture its complex mechanical response. The Generalized Reduced Gradient Method (GRG) and Gene Expression Programming (GEP) were employed to develop a formula that incorporates the main influencing factors, including steel fiber volume percentage, yield stress, reinforcing index, and concrete compressive strength and strain. These characteristics were carefully investigated to develop a powerful formula capable of accurately predicting the stress-strain diagram of SFRC. The model is based on a large dataset of 182 experimental samples used for both development and validation. The models' accuracy was assessed through the root mean square error (RMSE), mean absolute error (MAE), and coefficient of determination () by comparing actual and predicted values. The model's predictions correspond well with experimental data, demonstrating its robustness and reliability in predicting the stress-strain curves. This study sheds light on the intricate interaction of material characteristics in SFRC. It provides a powerful tool for engineers and researchers seeking to enhance the mechanical performance of fiber-reinforced concrete structures.
{"title":"Innovative approach to SFRC analysis: Using gene expression programming (GEP) to predict stress-strain behavior of steel fiber-reinforced concrete under compression","authors":"Husam Al Qablan","doi":"10.1016/j.rinma.2025.100829","DOIUrl":"10.1016/j.rinma.2025.100829","url":null,"abstract":"<div><div>The stress–strain diagram of SFRC is a crucial tool for evaluating its mechanical properties, as it clearly illustrates the enhanced strength, ductility, and energy absorption provided by the steel fibers. The present research presents a novel method for developing a predictive model for predicting the compression stress-strain curve of steel fiber reinforced concrete (SFRC), offering a reliable tool to capture its complex mechanical response. The Generalized Reduced Gradient Method (GRG) and Gene Expression Programming (GEP) were employed to develop a formula that incorporates the main influencing factors, including steel fiber volume percentage, yield stress, reinforcing index, and concrete compressive strength and strain. These characteristics were carefully investigated to develop a powerful formula capable of accurately predicting the stress-strain diagram of SFRC. The model is based on a large dataset of 182 experimental samples used for both development and validation. The models' accuracy was assessed through the root mean square error (RMSE), mean absolute error (MAE), and coefficient of determination (<span><math><mrow><msup><mi>R</mi><mn>2</mn></msup></mrow></math></span>) by comparing actual and predicted values. The model's predictions correspond well with experimental data, demonstrating its robustness and reliability in predicting the stress-strain curves. This study sheds light on the intricate interaction of material characteristics in SFRC. It provides a powerful tool for engineers and researchers seeking to enhance the mechanical performance of fiber-reinforced concrete structures.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100829"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145623812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.rinma.2025.100827
Jin-Kwan Lee , Keun-Soo Kim , Jae-Ho Shin , Seung-Min Cho , Sung Yi , Sang-Wook Kim , Soong-Keun Hyun
Void formation in solder joints is a critical reliability challenge in high-power electronics, as it degrades thermal dissipation and mechanical integrity. This study investigates a novel structural approach to mitigate this issue. The influence of an uni-directional porous structure in lotus-type porous Cu (Louts Cu) on void formation in solder joints was investigated. All pores in lotus Cu were infiltrated with SAC305 (Sn–3.0Ag–0.5Cu) solder paste. Then reflow soldering was performed under three different atmospheric conditions: air, nitrogen, and vacuum. The microstructure and void fraction were characterized. The shear strength was evaluated. The shear strength of Louts Cu joint was slightly higher than that of non-porous Cu joint. The characterization of void fraction in joints exhibited that lotus Cu joint is lower than that of non-porous Cu joint.
{"title":"Effect of pore structure on void formation in lotus type porous Cu/solder joints","authors":"Jin-Kwan Lee , Keun-Soo Kim , Jae-Ho Shin , Seung-Min Cho , Sung Yi , Sang-Wook Kim , Soong-Keun Hyun","doi":"10.1016/j.rinma.2025.100827","DOIUrl":"10.1016/j.rinma.2025.100827","url":null,"abstract":"<div><div>Void formation in solder joints is a critical reliability challenge in high-power electronics, as it degrades thermal dissipation and mechanical integrity. This study investigates a novel structural approach to mitigate this issue. The influence of an uni-directional porous structure in lotus-type porous Cu (Louts Cu) on void formation in solder joints was investigated. All pores in lotus Cu were infiltrated with SAC305 (Sn–3.0Ag–0.5Cu) solder paste. Then reflow soldering was performed under three different atmospheric conditions: air, nitrogen, and vacuum. The microstructure and void fraction were characterized. The shear strength was evaluated. The shear strength of Louts Cu joint was slightly higher than that of non-porous Cu joint. The characterization of void fraction in joints exhibited that lotus Cu joint is lower than that of non-porous Cu joint.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100827"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145623815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.rinma.2025.100826
Hasan Shamseddine , Nour Abi Aad , Ghassan Younes , Rami Al-Oweini
This study reports the synthesis and characterization of Europium-doped silica nanoparticles (adsorbent) (S1), prepared via an eco-friendly sol-gel method, aimed at the efficient removal of lead (Pb2+) ions from aqueous solutions. Comprehensive structural and surface analyses were performed using Scanning Electron Microscopy (SEM), Dynamic Light Scattering (DLS), Fourier-transform Infrared Spectroscopy (FTIR), and Thermogravimetric Analysis (TGA) to confirm the formation and stability of the nanoparticles.
The maximum adsorption capacity of S1 for Pb2+ ions was achieved at a solid-to-solution ratio of 4 g/L. Equilibrium was reached within 60 min. The adsorption kinetics followed a pseudo-second-order model, indicating that chemisorption played a significant role in the extraction process. Furthermore, the adsorption isotherm data fitted well with the Langmuir model, yielding a maximum adsorption capacity of 25.73 mg/g at 298.15 K. This suggests that adsorption predominantly occurs at specific active sites on the nanoparticle surface, involving interactions between Pb (II) ions and oxygen atoms present on the surface.
Thermodynamic studies revealed that the adsorption process is spontaneous. The enthalpy data indicated that the interaction involves both electrostatic and chemical contributions. A 90 % recovery of the used S1 material was achieved using 20 mM HCl under the following conditions: 2-h contact time, temperature of 298 K, shaking rate of 180 rpm, and an adsorbent dose of 10 mg/L. The material maintained its efficiency over five adsorption-desorption cycles.
These results demonstrate the potential of europium-doped silica nanoparticles as effective and reusable adsorbents for sustainable heavy metal remediation, contributing to advancements in colloid and interface science for environmental applications.
{"title":"Europium-doped silica nanoparticles for efficient and sustainable lead removal from aqueous solutions","authors":"Hasan Shamseddine , Nour Abi Aad , Ghassan Younes , Rami Al-Oweini","doi":"10.1016/j.rinma.2025.100826","DOIUrl":"10.1016/j.rinma.2025.100826","url":null,"abstract":"<div><div>This study reports the synthesis and characterization of Europium-doped silica nanoparticles (adsorbent) (<em>S</em><sub><em>1</em></sub>), prepared via an eco-friendly sol-gel method, aimed at the efficient removal of lead (Pb<sup>2+</sup>) ions from aqueous solutions. Comprehensive structural and surface analyses were performed using Scanning Electron Microscopy (SEM), Dynamic Light Scattering (DLS), Fourier-transform Infrared Spectroscopy (FTIR), and Thermogravimetric Analysis (TGA) to confirm the formation and stability of the nanoparticles.</div><div>The maximum adsorption capacity of <em>S</em><sub><em>1</em></sub> for Pb<sup>2+</sup> ions was achieved at a solid-to-solution ratio of 4 g/L. Equilibrium was reached within 60 min. The adsorption kinetics followed a pseudo-second-order model, indicating that chemisorption played a significant role in the extraction process. Furthermore, the adsorption isotherm data fitted well with the Langmuir model, yielding a maximum adsorption capacity of 25.73 mg/g at 298.15 K. This suggests that adsorption predominantly occurs at specific active sites on the nanoparticle surface, involving interactions between Pb (II) ions and oxygen atoms present on the surface.</div><div>Thermodynamic studies revealed that the adsorption process is spontaneous. The enthalpy data indicated that the interaction involves both electrostatic and chemical contributions. A 90 % recovery of the used <em>S</em><sub><em>1</em></sub> material was achieved using 20 mM HCl under the following conditions: 2-h contact time, temperature of 298 K, shaking rate of 180 rpm, and an adsorbent dose of 10 mg/L. The material maintained its efficiency over five adsorption-desorption cycles.</div><div>These results demonstrate the potential of europium-doped silica nanoparticles as effective and reusable adsorbents for sustainable heavy metal remediation, contributing to advancements in colloid and interface science for environmental applications.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100826"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145693004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.rinma.2025.100832
Naol Dessalegn Dejene , Dame Alemayehu Efa
In additive manufacturing (AM), especially Laser (Powder Bed Fusion (L-PBF), having excellent and consistent mechanical properties is important for high-value applications in aerospace, automobile industries, and biomedical engineering. This study employs a novel, complementary bottom-up approach to systematically investigate how scanning strategies (spiral, island, and bi-directional) and part orientations influence the microstructural and mechanical properties of L-PBF components. Microstructural characterization, using optical microscopy, scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD), allowed the evaluation of grain size, porosity, and crystallographic texture. Mechanical properties and their relationship with the microstructural features of tensile strength, yield strength, elastic modulus, strain percentage, and hardness were evaluated. Ultimately, the results demonstrate that both scanning strategies and part orientations have a considerable effect on the mechanical properties of key features such as strength, ductility, and anisotropy. Specifically, island scanning showed the best ductility while spiral scanning demonstrated better strength at the cost of greater brittleness. Additionally, this study demonstrated that controlling scanning strategies and part orientation offers valuable insights for optimizing the L-PBF process, with significant implications for the design and fabrication of high-performance components in demanding industrial applications.
{"title":"Bottom-up optimization of additive manufacturing: Process–structure–property relationships in laser powder bed fusion","authors":"Naol Dessalegn Dejene , Dame Alemayehu Efa","doi":"10.1016/j.rinma.2025.100832","DOIUrl":"10.1016/j.rinma.2025.100832","url":null,"abstract":"<div><div>In additive manufacturing (AM), especially Laser (Powder Bed Fusion (L-PBF), having excellent and consistent mechanical properties is important for high-value applications in aerospace, automobile industries, and biomedical engineering. This study employs a novel, complementary bottom-up approach to systematically investigate how scanning strategies (spiral, island, and bi-directional) and part orientations influence the microstructural and mechanical properties of L-PBF components. Microstructural characterization, using optical microscopy, scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD), allowed the evaluation of grain size, porosity, and crystallographic texture. Mechanical properties and their relationship with the microstructural features of tensile strength, yield strength, elastic modulus, strain percentage, and hardness were evaluated. Ultimately, the results demonstrate that both scanning strategies and part orientations have a considerable effect on the mechanical properties of key features such as strength, ductility, and anisotropy. Specifically, island scanning showed the best ductility while spiral scanning demonstrated better strength at the cost of greater brittleness. Additionally, this study demonstrated that controlling scanning strategies and part orientation offers valuable insights for optimizing the L-PBF process, with significant implications for the design and fabrication of high-performance components in demanding industrial applications.</div></div>","PeriodicalId":101087,"journal":{"name":"Results in Materials","volume":"28 ","pages":"Article 100832"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145623813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}