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Comparison of Real Versus Synthetic NOM on Lead and Copper Release Using Dump and Fill Studies 真正的和合成的NOM对铅和铜释放的比较,利用倾倒和填充研究
IF 1.8 Pub Date : 2025-09-25 DOI: 10.1002/aws2.70039
Patrick W. King, Benjamin F. Trueman, Sigrid Peldszus, Anushka Mishrra, Kimia Aghasadeghi, Graham A. Gagnon, Daniel E. Giammar, Nastaran Mosavari Nezamabad, Peter M. Huck

The main objective of this study was to evaluate and compare the impact of real and synthetic NOM on lead and copper release from galvanic corrosion. A 21-week “dump and fill” experiment was completed using test pieces with new lead and copper pipes exposed to various drinking waters. The real waters consisted of unchlorinated, but otherwise conventionally treated, river water and raw municipal well water. Each real water was simulated using two synthetic waters: one with Suwannee River NOM (SRNOM) at the same DOC concentration as in the real water and another without NOM. The synthetic waters with SRNOM released the most dissolved lead, followed by the real waters, and finally by the synthetic waters without SRNOM. Using advanced techniques of characterizing colloidal lead and NOM, complexation was found to be responsible for much of the NOM-induced dissolved lead release, and humic substances were the component that complexed most strongly.

本研究的主要目的是评估和比较真实的和合成的NOM对电偶腐蚀中铅和铜释放的影响。一项为期21周的“倾倒和填充”实验完成了,将带有新铅和铜管的试件暴露在各种饮用水中。真正的水包括未经氯化处理的河水和未经处理的市政井水。每种真实水都使用两种合成水模拟,一种是含有与真实水相同DOC浓度的Suwannee River NOM (SRNOM)的合成水,另一种是不含NOM的合成水。含有SRNOM的合成水释放的溶解铅最多,其次是真实水,最后是不含SRNOM的合成水。利用表征胶体铅和NOM的先进技术,发现络合作用是NOM诱导的溶解铅释放的主要原因,腐殖质物质是络合作用最强烈的成分。
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引用次数: 0
Demystifying Impact of NOM Fouling in the Pore and Surface Diffusion Model 揭开NOM污染对孔隙和表面扩散模型的影响
IF 1.8 Pub Date : 2025-09-23 DOI: 10.1002/aws2.70037
Jonathan B. Burkhardt

Adsorption process modeling of drinking water systems can be a powerful tool for evaluating treatment performance, especially if the impact of natural organic matter (NOM), which can have a significant effect on system effectiveness, is considered. Models such as the pore and surface diffusion model (PSDM) in AdDesignS have been used extensively to model water treatment with granular activated carbon (GAC). PSDM can incorporate the impact of NOM on adsorption capacity; however, media fouling is only considered for five water types, limiting the extension of this approach or considering uncertainty in modeling results. A one-point derivation process to simplify parameter estimation is introduced to provide additional understanding about the mechanisms of fouling and how it could be implemented within the PSDM. This could allow users to consider other factors—specifically total organic carbon breakthrough—when incorporating fouling into their GAC performance predictions, leading to improvements in future modeling efforts.

饮用水系统的吸附过程建模可以成为评估处理性能的有力工具,特别是如果考虑到天然有机物(NOM)的影响,它可以对系统的有效性产生重大影响。AdDesignS中的孔隙和表面扩散模型(PSDM)等模型已被广泛用于模拟颗粒活性炭(GAC)的水处理。PSDM可以纳入NOM对吸附容量的影响;然而,介质污染只考虑了五种水类型,限制了该方法的扩展或考虑到建模结果的不确定性。引入了一个简化参数估计的单点推导过程,以提供对污垢机制的额外理解,以及如何在PSDM中实现。这可以让用户在将污染纳入其GAC性能预测时考虑其他因素,特别是总有机碳突破,从而改进未来的建模工作。
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引用次数: 0
Evaluating State Nitrification Action Plans for Controlling Distribution System Nitrification and MDBPs 评价控制配电系统硝化和mdbp的国家硝化行动计划
IF 1.8 Pub Date : 2025-09-23 DOI: 10.1002/aws2.70036
Natchaya Luangphairin, J. Alan Roberson, Katherine Alfredo

With public water systems switching to chloramination for secondary disinfection, distribution system nitrification and diminished disinfectant residuals are a growing concern. While some states have adopted Nitrification Action Plans (NAPs), no comparative assessment exists on their impact on drinking water quality trends. This study uses causal impact analysis to evaluate the effectiveness of state-mandated NAPs in controlling nitrification. Chloraminated systems with residual challenges before NAPs showed increased residuals and at least a 26% reduction in total coliform detection post-mandate. Maintaining chloramine residuals above 1.5 mg/L can prevent nitrification and reduce violations without significantly increasing disinfection byproduct occurrences. In contrast, states with no notable challenges before the plan's enactment saw limited benefits. These findings offer policymakers valuable insights into the plan's implications, supporting informed decision-making, especially in areas where nitrate violation hotspots exist without a current plan.

随着公共供水系统转向氯胺化进行二次消毒,分配系统硝化和减少消毒剂残留物日益受到关注。虽然一些州采用了硝化行动计划(nap),但没有对其对饮用水质量趋势的影响进行比较评估。本研究使用因果影响分析来评估国家强制实施的nap在控制硝化方面的有效性。在nap之前存在残留挑战的氯胺化系统显示残留物增加,授权后总大肠菌群检测至少减少26%。将氯胺残留量维持在1.5 mg/L以上可以防止硝化作用并减少违规行为,而不会显著增加消毒副产物的发生率。相比之下,在该计划实施前没有明显挑战的州受益有限。这些发现为政策制定者提供了宝贵的见解,以了解该计划的影响,支持明智的决策,特别是在硝酸盐违规热点地区没有当前计划的地区。
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引用次数: 0
National Cost of Compliance With a Drinking Water MCL for Hexavalent Chromium 全国饮用水六价铬MCL符合性成本
IF 1.8 Pub Date : 2025-09-14 DOI: 10.1002/aws2.70035
Issam Najm

With the publication of the toxicological review for hexavalent chromium, Cr(VI), the US Environmental Protection Agency may be initiating the process to develop a Maximum Contaminant Level (MCL) for Cr(VI) in US drinking water. This study developed national costs of compliance with Cr(VI) MCLs between 5 and 20 μg/L. All California water systems were excluded from the costs for MCLs of 10 μg/L and greater since California already adopted an MCL of 10 μg/L. For a national MCL of 10 μg/L, the minimum non-California capital cost is projected to be between $3.8B and $8.2B, with the minimum annual O&M cost ranging from $340M/year to $720M/year in 2024 dollars. The total population impacted by this MCL is projected at 4.36 million people. For communities smaller than 101 people, the minimum 2024 household cost for this MCL may have a 5th percentile value of $566/year and a 95th percentile value of $1611/year.

随着六价铬(Cr(VI))毒理学审查报告的发表,美国环境保护局可能正在启动制定美国饮用水中Cr(VI)的最大污染物水平(MCL)的过程。本研究确定了5至20 μg/L的Cr(VI) mcl的国家合规成本。由于加州已经采用了10 μg/L的MCL,因此所有加州水系统都被排除在10 μg/L及以上的MCL成本之外。对于10 μg/L的全国MCL,非加州的最低资本成本预计在38亿至82亿美元之间,最低年度运营和管理成本为3.4亿美元/年至7.2亿美元/年(2024美元)。预计受该次MCL影响的总人口为436万人。对于小于101人的社区,2024年最低MCL家庭成本的第5个百分位数值为566美元/年,第95个百分位数值为1611美元/年。
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引用次数: 0
Estimating the Relationship Between Water Utility Workforce Quality and Water Utility Performance 估计水务公司员工素质与水务公司绩效之间的关系
IF 1.8 Pub Date : 2025-09-04 DOI: 10.1002/aws2.70032
Robin Rose Saywitz

Workforce quality has been a major concern in the water utility sector for decades. While previous research presumes that workforce quality plays an important role in water utility performance, no research to date has explored this relationship empirically. This study represents a first attempt at quantifying the relationship between workforce quality and performance using a dataset containing water utilities in Texas serving over 500 customers, data on Safe Drinking Water Act (SDWA) violations, and water utility operator classes. The results of two negative binomial models, where the dependent variables are the count of SDWA health and SDWA monitoring and reporting violations between 2020 and 2024, show that workforce quality has a substantively large and statistically significant negative effect on SDWA compliance across both types of violations. An additional analysis explores the interactive effect of workforce quality and median income and workforce quality and water source on utility performance.

几十年来,劳动力质量一直是水务部门关注的主要问题。虽然以前的研究假设劳动力素质在水务公司绩效中起着重要作用,但迄今为止还没有研究对这种关系进行实证研究。本研究首次尝试量化劳动力质量与绩效之间的关系,使用的数据集包含德克萨斯州服务于500多名客户的水务公司、违反《安全饮用水法》(SDWA)的数据以及水务公司运营商类别。两个负二项模型的结果表明,在2020年至2024年期间,SDWA健康状况和SDWA监测和报告违规行为的数量是两个负二项模型的因变量,劳动力质量对两种违规行为的SDWA合规性都有相当大的、统计上显著的负面影响。另一项分析探讨了劳动力质量和收入中位数以及劳动力质量和水源对公用事业绩效的互动影响。
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引用次数: 0
Correction to “Why CODMn Is Not Suitable for Assessing NOM Concentration in Source Waters” 更正“为何CODMn不适合评估水源中NOM浓度”
IF 1.8 Pub Date : 2025-08-27 DOI: 10.1002/aws2.70034

Naceradska, J., E. Tobolkova, J. Haidl, L. Pivokonska, and M. Pivokonsky. 2025. “ Why CODMn Is Not Suitable for Assessing NOM Concentration in Source Waters.” AWWA Water Science 7, no. 4: e70026. https://doi.org/10.1002/aws2.70026.

The spelling of the third author's name, Jan Haidl, has been corrected.

We apologize for this error.

纳克拉斯卡,J.托博尔科娃,J.海德尔,L.皮沃康斯卡和M.皮沃康斯基。2025。“为什么CODMn不适合评估水源中NOM的浓度。”AWWA水科学,第7期。4: e70026。https://doi.org/10.1002/aws2.70026。第三位作者Jan Haidl的名字拼写已被更正。我们为这个错误道歉。
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引用次数: 0
Increasing Irrigation Restriction Compliance With Water Conservation Messages of Varying Complexity 增加灌溉限制遵守不同复杂性的节水信息
IF 1.8 Pub Date : 2025-08-18 DOI: 10.1002/aws2.70030
Laura A. Warner, Sadie Hundemer, Jamie Loizzo, Tina McIntyre

Permanent residential irrigation restrictions employed in locales, including Florida, are limited by poor awareness and compliance. To inform improved public communication, this electronic survey study, based on the elaboration likelihood model, tested three visual messages conveying varying levels of information (days, times, seasonality) surrounding irrigation restrictions. Nonprobability, quota-based sampling was used to recruit 2,615 Floridians and randomly assign message treatments to those subject to irrigation restrictions (n = 459). Treatments influenced information-seeking likelihood through some modalities; the most informative message prompted the greatest information-seeking likelihood. “Aware individuals” familiar with irrigation restrictions applicable to them, and thus motivated to engage more deeply with the message, reported greater intent to set their irrigation in alignment with policy, suggesting more information delivered to aware individuals could promote compliance. Potential negative effects among “unaware individuals” (who may have been less motivated to engage) suggest a need for cautious irrigation restriction campaign targeting and development.

包括佛罗里达州在内的一些地方采用了永久性住宅灌溉限制,但由于缺乏意识和遵守规定而受到限制。为了改善公众沟通,这项电子调查研究基于详细可能性模型,测试了三种视觉信息,传达了围绕灌溉限制的不同程度的信息(天数、时间、季节性)。采用非概率、基于配额的抽样方法招募了2615名佛罗里达人,并随机分配信息处理给那些受灌溉限制的人(n = 459)。治疗通过某些方式影响信息寻求可能性;信息量最大的信息激发了最大的信息搜寻可能性。“有意识的个人”熟悉适用于他们的灌溉限制,因此有动力更深入地参与这一信息,报告说他们更有意愿将灌溉与政策保持一致,这表明向有意识的个人提供更多信息可以促进遵守。对“不知情的个人”(他们可能不太积极参与)的潜在负面影响表明,需要谨慎地针对和发展灌溉限制运动。
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引用次数: 0
Lighting Up MS2: Exploring Fluence Rates for Virus Inactivation 点亮MS2:探索病毒灭活的通量率
IF 1.8 Pub Date : 2025-08-14 DOI: 10.1002/aws2.70033
Dana Pousty, Yifaat Betzalel, Hadas Mamane

This study examined the impact of UV-LED fluence rate (incident irradiance) and wavelengths on the inactivation of MS2 bacteriophage, determined by log reduction value (LRV). Three levels of fluence rates, each differing by an order of magnitude, were examined at various UV-LED wavelengths: 267 nm (UVC), 286 nm (UVB), and simultaneous 267 + 286 nm. The results challenge the Bunsen-Roscoe reciprocity law, demonstrating that for longer wavelengths (286 nm) and simultaneous UVC + UVB irradiation (267 + 286 nm), lower fluence rates yield higher LRV, contrary to expectations. The similar LRV between the simultaneous UVC + UVB exposure and the weighted summation of UVC LRV and UVB LRV separately highlights that synergistic effects are generally absent in viruses under combined UV wavelengths. The data indicate that lower fluence rates at UVB, while requiring longer exposure times, can lead to higher energy efficiency. The electrical energy efficiency per order for N-log inactivation underlines the significance of both inactivation efficacy and energy consumption in the design of UV-LED disinfection systems.

本研究考察了UV-LED辐照率(入射辐照度)和波长对MS2噬菌体失活的影响,以对数还原值(LRV)确定。在不同的UV-LED波长:267 nm (UVC)、286 nm (UVB)和同时267 + 286 nm下,研究了三个不同数量级的通量水平。结果挑战了Bunsen-Roscoe互易定律,表明对于较长的波长(286 nm)和UVC + UVB同时照射(267 + 286 nm),较低的通量率产生较高的LRV,这与预期相反。UVC + UVB同时暴露与UVC + UVB分别暴露的LRV和UVC + UVB分别暴露的LRV的加权总和相似,说明在复合UV波长下,病毒通常不存在协同效应。数据表明,较低的中波辐射通量,虽然需要较长的曝光时间,但可以提高能源效率。N-log灭活的每订单电能效率强调了灭活效果和能耗在UV-LED消毒系统设计中的重要性。
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引用次数: 0
Impact of Premise Plumbing Design, Velocity, and Operational Factors on Microbial Activity During Stagnation in Pipes 前提管道设计、速度和操作因素对管道停滞期间微生物活动的影响
IF 1.8 Pub Date : 2025-08-06 DOI: 10.1002/aws2.70031
Patrick L. Gurian, Shahzaib Samuel, Neha Yadav, Michael Krieger, Rajveer Singh, Tim Bartrand

Water systems using chloramine as a disinfectant are vulnerable to nitrification, which can degrade water quality by enhancing the loss of residual disinfectant, lowering pH, and providing substrates for the growth of heterotrophs, leading to a more active biofilm that may support opportunistic pathogen growth in the premise plumbing (i.e., piping within a building). This study examined the influence of a variety of domestic plumbing factors, specifically: use frequency (pipes used once per week vs. five times per week), pipe material (copper vs. CPVC vs. PEX-b), pipe diameter (3/8″ vs. 1/2″ vs. 3/4″), and flow rates (0.2 gal/min vs. 3.2–3.7 gal/min), on indicators of water quality and nitrification, specifically: residual disinfectant, ammonia, nitrite, nitrate, turbidity, pH, and adenosine triphosphate (ATP, a non-specific proxy for biological activity). Experiments were conducted on a set of 28 pipes connected to a chloraminated public drinking water supply. Fourteen of the pipes were operated at fast flow rates of 3.2–3.7 gal per minute (12.4–13.9 L/min), which corresponded to 2.7, 5.7, and 9.5 ft/s (0.81, 1.7, 2.9 m/s) for the 3/4, 1/2, and 3/8 in. pipes, respectively. The remaining 14 pipes were operated at slow flow rates of 0.2 gal per minute (0.8 L/min), which corresponds to 0.15, 0.36, and 0.56 ft/s (0.045, 0.11, and 0.17 m/s) for the 3/4 in. (19 mm), 1/2 in. (13 mm), and 3/8 in. pipes (9.5 mm), respectively. Faster velocity flows were associated with higher residual disinfectant, less degradation of ammonia, lower turbidity and lower ATP. These results suggest that the faster flow velocity altered the biofilm and reduced the amount of microbial activity and nitrification occurring. Differences were particularly strong in the 3/8 in. (9.5 mm) pipes, suggesting that a velocity of 9.5 ft/s (2.9 m/s) offered additional benefits in biofilm control, beyond those achieved at the velocities of 2.7 ft/s (0.81 m/s) and 5.7 ft/s (1.7 m/s) in 3/4 in. (19 mm) and 1/2 in. (13 mm) pipes, respectively. Pipes flushed once per week tended to reach a similar end state of loss of residual and progression of nitrification, with limited differences due to velocity, pipe material, or diameter. Better understanding of the conditions that are associated with nitrification offers the potential to better control nitrification. This in turn may help maintain residual disinfectant as a protection against harmful microorganisms in drinking water.

使用氯胺作为消毒剂的水系统容易受到硝化作用的影响,这可以通过增加残留消毒剂的损失,降低pH值,并为异养生物的生长提供基质来降低水质,从而导致更活跃的生物膜,可能支持前提管道(即建筑物内的管道)中的机会性病原体生长。本研究考察了各种家庭管道因素的影响,特别是:使用频率(管道每周使用一次vs.每周使用五次)、管道材料(铜vs. CPVC vs. pegx -b)、管径(3/8″vs. 1/2″vs. 3/4″)和流速(0.2加仑/分钟vs. 3.2-3.7加仑/分钟)对水质和硝化指标的影响,特别是:剩余消毒剂、氨、亚硝酸盐、硝酸盐、浊度、pH值和三磷酸腺苷(ATP,生物活性的非特异性代用品)。实验是在一组连接氯胺公共饮用水供应的28根管道上进行的。其中14根管道的快速流量为3.2-3.7加仑/分钟(12.4-13.9升/分钟),对应于3/4、1/2和3/8英寸的2.7、5.7和9.5英尺/秒(0.81、1.7、2.9米/秒)。管道,分别。其余14根管子以0.2加仑/分钟(0.8升/分钟)的慢流速运行,对应于3/4英寸的0.15、0.36和0.56英尺/秒(0.045、0.11和0.17米/秒)。(19mm), 1/2 in。(13毫米)和3/8英寸。管道(分别为9.5 mm)。流速越快,消毒剂残留量越高,氨的降解越少,浊度越低,ATP越低。这些结果表明,更快的流速改变了生物膜,减少了微生物活性和硝化作用的发生。3/8英寸的差异尤其明显。这表明,在3/4英寸管道中,除了2.7英尺/秒(0.81米/秒)和5.7英尺/秒(1.7米/秒)的速度外,9.5英尺/秒(2.9米/秒)的速度对生物膜的控制有额外的好处。(19毫米)和1/2英寸。(13mm)管路。每周冲洗一次的管道往往达到类似的残余损失和硝化进展的最终状态,由于速度,管道材料或直径的差异有限。更好地了解与硝化有关的条件可以更好地控制硝化。这反过来又可以帮助保持残留的消毒剂,作为对饮用水中有害微生物的保护。
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引用次数: 0
Enhancing Biofilm Recovery From Carbon Filters for Molecular Analysis and Flow Cytometry 提高碳过滤器的生物膜回收率用于分子分析和流式细胞术
IF 1.8 Pub Date : 2025-08-01 DOI: 10.1002/aws2.70029
Andrew Black, Natchaya Luangphairin, Katerina Papp, Daniel Gerrity, Eric Dickenson, Katherine Alfredo

Effective biofilm recovery is essential when characterizing microbial communities on granular filter media in water treatment applications. This study evaluated (1) DNA extraction kit modifications to maximize DNA recovery and (2) low frequency sonication (40 kHz) durations to maximize recovery of viable cells for flow cytometry (FCM) considering filter media type (anthracite and granular activated carbon [GAC]), media age, and filter runtime. Both DNA and intact cell concentrations were greater for new GAC (< 12 months of full-scale operation) and anthracite compared to old GAC (> 20 years). Biomass yields for old GAC were improved by using a less aggressive bead-beating protocol (for DNA) and reduced sonication duration (for intact cells). Finally, collecting media at the beginning of a filter run (i.e., post-backwash) improved biomass recovery compared to sampling after long filter runtimes. Further study of carbon attrition during extraction is recommended.

在水处理应用中,当表征颗粒过滤介质上的微生物群落时,有效的生物膜回收是必不可少的。本研究评估了(1)DNA提取试剂盒的改进,以最大限度地提高DNA回收率;(2)低频超声(40 kHz)持续时间,以最大限度地恢复流式细胞术(FCM)的活细胞,考虑过滤介质类型(无烟煤和颗粒活性炭[GAC]),培养基年龄和过滤运行时间。与旧GAC(20年)相比,新GAC(12个月)和无烟煤的DNA和完整细胞浓度都更高。旧GAC的生物量产量通过使用较少侵略性的串珠敲打协议(DNA)和缩短超声时间(完整细胞)得到提高。最后,与长时间过滤器运行后取样相比,在过滤器运行开始时收集介质(即反冲洗后)提高了生物质回收率。建议进一步研究提取过程中的碳磨损。
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引用次数: 0
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AWWA water science
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