Patrick W. King, Benjamin F. Trueman, Sigrid Peldszus, Anushka Mishrra, Kimia Aghasadeghi, Graham A. Gagnon, Daniel E. Giammar, Nastaran Mosavari Nezamabad, Peter M. Huck
The main objective of this study was to evaluate and compare the impact of real and synthetic NOM on lead and copper release from galvanic corrosion. A 21-week “dump and fill” experiment was completed using test pieces with new lead and copper pipes exposed to various drinking waters. The real waters consisted of unchlorinated, but otherwise conventionally treated, river water and raw municipal well water. Each real water was simulated using two synthetic waters: one with Suwannee River NOM (SRNOM) at the same DOC concentration as in the real water and another without NOM. The synthetic waters with SRNOM released the most dissolved lead, followed by the real waters, and finally by the synthetic waters without SRNOM. Using advanced techniques of characterizing colloidal lead and NOM, complexation was found to be responsible for much of the NOM-induced dissolved lead release, and humic substances were the component that complexed most strongly.
本研究的主要目的是评估和比较真实的和合成的NOM对电偶腐蚀中铅和铜释放的影响。一项为期21周的“倾倒和填充”实验完成了,将带有新铅和铜管的试件暴露在各种饮用水中。真正的水包括未经氯化处理的河水和未经处理的市政井水。每种真实水都使用两种合成水模拟,一种是含有与真实水相同DOC浓度的Suwannee River NOM (SRNOM)的合成水,另一种是不含NOM的合成水。含有SRNOM的合成水释放的溶解铅最多,其次是真实水,最后是不含SRNOM的合成水。利用表征胶体铅和NOM的先进技术,发现络合作用是NOM诱导的溶解铅释放的主要原因,腐殖质物质是络合作用最强烈的成分。
{"title":"Comparison of Real Versus Synthetic NOM on Lead and Copper Release Using Dump and Fill Studies","authors":"Patrick W. King, Benjamin F. Trueman, Sigrid Peldszus, Anushka Mishrra, Kimia Aghasadeghi, Graham A. Gagnon, Daniel E. Giammar, Nastaran Mosavari Nezamabad, Peter M. Huck","doi":"10.1002/aws2.70039","DOIUrl":"https://doi.org/10.1002/aws2.70039","url":null,"abstract":"<p>The main objective of this study was to evaluate and compare the impact of real and synthetic NOM on lead and copper release from galvanic corrosion. A 21-week “dump and fill” experiment was completed using test pieces with new lead and copper pipes exposed to various drinking waters. The real waters consisted of unchlorinated, but otherwise conventionally treated, river water and raw municipal well water. Each real water was simulated using two synthetic waters: one with Suwannee River NOM (SRNOM) at the same DOC concentration as in the real water and another without NOM. The synthetic waters with SRNOM released the most dissolved lead, followed by the real waters, and finally by the synthetic waters without SRNOM. Using advanced techniques of characterizing colloidal lead and NOM, complexation was found to be responsible for much of the NOM-induced dissolved lead release, and humic substances were the component that complexed most strongly.</p>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"7 5","pages":""},"PeriodicalIF":1.8,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://awwa.onlinelibrary.wiley.com/doi/epdf/10.1002/aws2.70039","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145146427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}