Pub Date : 2025-10-01Epub Date: 2025-09-06DOI: 10.1016/j.cjsc.2025.100714
Yi-Chang Yang , Rui-Xi Wang , Li-Ming Wu , Ling Chen
The donor-acceptor hydrogen bonding strategy has been proposed to enforce coplanar packing of anisotropic π-conjugated units, thereby maximizing the material's achievable birefringence. Herein, employing this strategy, we successfully obtain two highly coplanar birefringent crystals, FAHC2O4 and FAH2C3N3S3 (FA+: CH5N2+, formamidinium). FAHC2O4 shows a wide bandgap (4.20 eV), while FAH2C3N3S3 exhibits a narrower bandgap (2.96 eV) due to the involvement of sulfur atom. Both crystals display notable birefringence in their respective material classes: 0.275@546 nm and 0.504@546 nm, respectively. X-ray crystallography and computational studies attribute the pronounced birefringence to their π-conjugated moieties and their near-coplanar configurations. Comparative analysis of FAHC2O4 and FAH2C3N3S3 further establishes that the hydrogen bond strength directly influences the molecular coplanarity degree. These findings provide new insights for applying the donor-acceptor hydrogen bonding strategy in the rational design of high-performance birefringent materials.
{"title":"Regulating the coplanarity of π-conjugated units through hydrogen bonding in FAHC2O4 and FAH2C3N3S3 crystals","authors":"Yi-Chang Yang , Rui-Xi Wang , Li-Ming Wu , Ling Chen","doi":"10.1016/j.cjsc.2025.100714","DOIUrl":"10.1016/j.cjsc.2025.100714","url":null,"abstract":"<div><div>The donor-acceptor hydrogen bonding strategy has been proposed to enforce coplanar packing of anisotropic π-conjugated units, thereby maximizing the material's achievable birefringence. Herein, employing this strategy, we successfully obtain two highly coplanar birefringent crystals, FAHC<sub>2</sub>O<sub>4</sub> and FAH<sub>2</sub>C<sub>3</sub>N<sub>3</sub>S<sub>3</sub> (FA<sup>+</sup>: CH<sub>5</sub>N<sub>2</sub><sup>+</sup>, formamidinium). FAHC<sub>2</sub>O<sub>4</sub> shows a wide bandgap (4.20 eV), while FAH<sub>2</sub>C<sub>3</sub>N<sub>3</sub>S<sub>3</sub> exhibits a narrower bandgap (2.96 eV) due to the involvement of sulfur atom. Both crystals display notable birefringence in their respective material classes: 0.275@546 nm and 0.504@546 nm, respectively. X-ray crystallography and computational studies attribute the pronounced birefringence to their π-conjugated moieties and their near-coplanar configurations. Comparative analysis of FAHC<sub>2</sub>O<sub>4</sub> and FAH<sub>2</sub>C<sub>3</sub>N<sub>3</sub>S<sub>3</sub> further establishes that the hydrogen bond strength directly influences the molecular coplanarity degree. These findings provide new insights for applying the donor-acceptor hydrogen bonding strategy in the rational design of high-performance birefringent materials.</div></div>","PeriodicalId":10151,"journal":{"name":"结构化学","volume":"44 10","pages":"Article 100714"},"PeriodicalIF":10.3,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145398089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01Epub Date: 2025-09-17DOI: 10.1016/j.cjsc.2025.100728
Huarui Han , Yangrui Xu , Yu Cheng , Liguang Tang , Jie Jin , Xinlin Liu , Changchang Ma , Ziyang Lu
Photocatalytic CO2 reduction is a promising route toward carbon neutrality, yet its practical application is hindered by the high activation energy barrier of CO2, rapid recombination of photo-generated electrons, and poor product selectivity of traditional catalysts. Frustrated Lewis pairs (FLPs), which feature spatially separated Lewis acid and base sites, have recently emerged as a novel strategy to overcome these limitations. This review systematically examines the progress in FLPs-based photocatalytic systems. We focus on the construction strategies for FLPs active sites, the optimization of charge carrier dynamics, and the synergistic electron transfer mechanisms with photoactive components. Central theme is the elucidation of microscopic mechanisms governing CO2 activation, key intermediate conversion, and the efficient utilization of photogenerated electrons. By synthesizing current knowledge and outlining future prospects, this review aims to provide a theoretical framework that guides the rational design of highly active and selective catalysts for solar-driven CO2 reduction.
{"title":"Frustrated Lewis pairs in CO2 photoreduction: A review on synergistic activation and charge separation","authors":"Huarui Han , Yangrui Xu , Yu Cheng , Liguang Tang , Jie Jin , Xinlin Liu , Changchang Ma , Ziyang Lu","doi":"10.1016/j.cjsc.2025.100728","DOIUrl":"10.1016/j.cjsc.2025.100728","url":null,"abstract":"<div><div>Photocatalytic CO<sub>2</sub> reduction is a promising route toward carbon neutrality, yet its practical application is hindered by the high activation energy barrier of CO<sub>2</sub>, rapid recombination of photo-generated electrons, and poor product selectivity of traditional catalysts. Frustrated Lewis pairs (FLPs), which feature spatially separated Lewis acid and base sites, have recently emerged as a novel strategy to overcome these limitations. This review systematically examines the progress in FLPs-based photocatalytic systems. We focus on the construction strategies for FLPs active sites, the optimization of charge carrier dynamics, and the synergistic electron transfer mechanisms with photoactive components. Central theme is the elucidation of microscopic mechanisms governing CO<sub>2</sub> activation, key intermediate conversion, and the efficient utilization of photogenerated electrons. By synthesizing current knowledge and outlining future prospects, this review aims to provide a theoretical framework that guides the rational design of highly active and selective catalysts for solar-driven CO<sub>2</sub> reduction.</div></div>","PeriodicalId":10151,"journal":{"name":"结构化学","volume":"44 10","pages":"Article 100728"},"PeriodicalIF":10.3,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145398060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01Epub Date: 2025-07-29DOI: 10.1016/j.cjsc.2025.100695
Ziqi Chen , Miriding Mutailipu
Birefringent materials play a crucial role in light polarization, with important applications in fiber-optic communications. However, developing such materials for the solar-blind region and shorter wavelengths remains challenging due to the inherent trade-off between birefringence and bandgap. In this work, we introduce a strategic assembly of cyanuric rings with biuret units—the latter identified for the first time as a birefringence-active motif—resulting in two new compounds: [H5C2N3O2][H3C3N3O3] (1) and [H5C2N3O2][H3C3N3O3]·xH2O (x ≈ 0.43) (2). Through hydrogen bonding-driven structural optimization, compound 2 achieves a 50% increase in birefringence (Δn = 0.403 @ 546 nm) compared to 1, while retaining a short cutoff edge of 208 nm. This advancement demonstrates that hydrogen-bond-guided structural design, combined with novel functional units, can overcome the traditional birefringence-bandgap conflict, opening new possibilities for short-wavelength birefringent materials with strong optical anisotropy.
{"title":"Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate","authors":"Ziqi Chen , Miriding Mutailipu","doi":"10.1016/j.cjsc.2025.100695","DOIUrl":"10.1016/j.cjsc.2025.100695","url":null,"abstract":"<div><div>Birefringent materials play a crucial role in light polarization, with important applications in fiber-optic communications. However, developing such materials for the solar-blind region and shorter wavelengths remains challenging due to the inherent trade-off between birefringence and bandgap. In this work, we introduce a strategic assembly of cyanuric rings with biuret units—the latter identified for the first time as a birefringence-active motif—resulting in two new compounds: [H<sub>5</sub>C<sub>2</sub>N<sub>3</sub>O<sub>2</sub>][H<sub>3</sub>C<sub>3</sub>N<sub>3</sub>O<sub>3</sub>] (<strong>1</strong>) and [H<sub>5</sub>C<sub>2</sub>N<sub>3</sub>O<sub>2</sub>][H<sub>3</sub>C<sub>3</sub>N<sub>3</sub>O<sub>3</sub>]·<em>x</em>H<sub>2</sub>O (<em>x</em> ≈ 0.43) (<strong>2</strong>). Through hydrogen bonding-driven structural optimization, compound <strong>2</strong> achieves a 50% increase in birefringence (Δ<em>n</em> = 0.403 @ 546 nm) compared to <strong>1</strong>, while retaining a short cutoff edge of 208 nm. This advancement demonstrates that hydrogen-bond-guided structural design, combined with novel functional units, can overcome the traditional birefringence-bandgap conflict, opening new possibilities for short-wavelength birefringent materials with strong optical anisotropy.</div></div>","PeriodicalId":10151,"journal":{"name":"结构化学","volume":"44 10","pages":"Article 100695"},"PeriodicalIF":10.3,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145398093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01Epub Date: 2025-08-26DOI: 10.1016/j.cjsc.2025.100702
Yan-Jia Lin, Qing-Xin Zeng, Xiao-Min Shen, Shou-Tian Zheng, Xin-Xiong Li
Crystalline metal cluster-based organic-inorganic hybrid materials have emerged as a significant frontier in materials chemistry due to their unique structural designability and tunable properties. The bifunctional ligand 2-(hydroxymethyl)-2-(4-pyridyl)-1,3-propanediol (H3L), featuring both hard hydroxyl donors on one side and a soft pyridyl group on the other side, enables selective metal coordination via hard-soft acid-base (HSAB) theory and directs hierarchical metal cluster assembly. This review systematically summarizes the recent advances on metal cluster-based materials coordinated by H3L, including their syntheses, crystal structures, and related physicochemical properties.
{"title":"Construction of metal cluster-based materials directed by a bifunctional pyridyl tripodal alcohol ligand according to hard and soft acid-base theory","authors":"Yan-Jia Lin, Qing-Xin Zeng, Xiao-Min Shen, Shou-Tian Zheng, Xin-Xiong Li","doi":"10.1016/j.cjsc.2025.100702","DOIUrl":"10.1016/j.cjsc.2025.100702","url":null,"abstract":"<div><div>Crystalline metal cluster-based organic-inorganic hybrid materials have emerged as a significant frontier in materials chemistry due to their unique structural designability and tunable properties. The bifunctional ligand 2-(hydroxymethyl)-2-(4-pyridyl)-1,3-propanediol (H<sub>3</sub>L), featuring both hard hydroxyl donors on one side and a soft pyridyl group on the other side, enables selective metal coordination via hard-soft acid-base (HSAB) theory and directs hierarchical metal cluster assembly. This review systematically summarizes the recent advances on metal cluster-based materials coordinated by H<sub>3</sub>L, including their syntheses, crystal structures, and related physicochemical properties.</div></div>","PeriodicalId":10151,"journal":{"name":"结构化学","volume":"44 10","pages":"Article 100702"},"PeriodicalIF":10.3,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145398058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01Epub Date: 2025-09-20DOI: 10.1016/j.cjsc.2025.100735
Ying Xu , Yan Pu , Qiong Zhang, Xi Kang, Manzhou Zhu
It remains highly challenging to achieve the high-order nonlinear optical (NLO) properties of atomically precise metal nanoclusters via template-maintained manipulation. Here, based on the M1Ag24(SR)18 (M = Ag/Au/Pt/Pd; SR = 2,4-dimethylthiophenol) cluster template, we demonstrated that the innermost kernel alloying rendered these nanoclusters highly controllable towards the nonlinear optics. The Pd-alloyed Pd1Ag24(SR)18 only displayed single-photon-excited fluorescence, while the homo-silver Ag25(SR)18 nanocluster generated the two-photon-excited fluorescence characterization. The Au- and Pt-doped M1Ag24(SR)18 nanoclusters showed high-order three- and four-photon-excited fluorescence, respectively, demonstrating that the order-by-order control over the nonlinear optics of nanoclusters has been accomplished. Moreover, Pt1Ag24(SR)18 with high-order NLO characterization exhibited the best optical limiting performance under 1000 nm excitation, in agreement with its most prominent NLO property. Overall, this work presents an intriguing cluster template that enables successive order control over the nonlinear optics of atomically precise metal nanoclusters, hopefully paving the way for developing cluster-based nanomaterials with customized optical characterizations.
通过模板维持操作来实现原子精密金属纳米团簇的高阶非线性光学（NLO）特性仍然是一个极具挑战性的问题。基于M1Ag24(SR)18 （M = Ag/Au/Pt/Pd; SR = 2,4-二甲基噻吩）簇模板，我们证明了最内层的核合金使这些纳米簇具有高度的非线性光学可控性。钯合金的Pd1Ag24(SR)18纳米团簇仅显示单光子激发荧光，而均银的Ag25(SR)18纳米团簇产生双光子激发荧光表征。Au和pt掺杂的M1Ag24(SR)18纳米团簇分别表现出高阶的三光子和四光子激发荧光，表明对纳米团簇非线性光学的有序控制已经完成。此外，具有高阶NLO表征的Pt1Ag24(SR)18在1000 nm激发下表现出最佳的光限制性能，这与其最突出的NLO特性相一致。总的来说，这项工作提出了一个有趣的簇模板，可以对原子精确金属纳米簇的非线性光学进行连续顺序控制，有望为开发具有定制光学特性的簇基纳米材料铺平道路。
{"title":"Order-by-order control over the nonlinear optical properties of atomically precise nanoclusters","authors":"Ying Xu , Yan Pu , Qiong Zhang, Xi Kang, Manzhou Zhu","doi":"10.1016/j.cjsc.2025.100735","DOIUrl":"10.1016/j.cjsc.2025.100735","url":null,"abstract":"<div><div>It remains highly challenging to achieve the high-order nonlinear optical (NLO) properties of atomically precise metal nanoclusters via template-maintained manipulation. Here, based on the M<sub>1</sub>Ag<sub>24</sub>(SR)<sub>18</sub> (M = Ag/Au/Pt/Pd; SR = 2,4-dimethylthiophenol) cluster template, we demonstrated that the innermost kernel alloying rendered these nanoclusters highly controllable towards the nonlinear optics. The Pd-alloyed Pd<sub>1</sub>Ag<sub>24</sub>(SR)<sub>18</sub> only displayed single-photon-excited fluorescence, while the homo-silver Ag<sub>25</sub>(SR)<sub>18</sub> nanocluster generated the two-photon-excited fluorescence characterization. The Au- and Pt-doped M<sub>1</sub>Ag<sub>24</sub>(SR)<sub>18</sub> nanoclusters showed high-order three- and four-photon-excited fluorescence, respectively, demonstrating that the order-by-order control over the nonlinear optics of nanoclusters has been accomplished. Moreover, Pt<sub>1</sub>Ag<sub>24</sub>(SR)<sub>18</sub> with high-order NLO characterization exhibited the best optical limiting performance under 1000 nm excitation, in agreement with its most prominent NLO property. Overall, this work presents an intriguing cluster template that enables successive order control over the nonlinear optics of atomically precise metal nanoclusters, hopefully paving the way for developing cluster-based nanomaterials with customized optical characterizations.</div></div>","PeriodicalId":10151,"journal":{"name":"结构化学","volume":"44 10","pages":"Article 100735"},"PeriodicalIF":10.3,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145398057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01Epub Date: 2025-09-08DOI: 10.1016/j.cjsc.2025.100712
Xing-Cheng Hu , Qiu-Shui Mu , Shu-Jin Bao , Yan Zou , Xin-Yu Wang , Guo-Xin Jin
Mechanically interlocked molecules (MIMs) have unique properties with broad applications, yet constructing both knotted and linked topologies from the same ligand remains challenging due to their distinct geometric demands. To address this, we design and synthesize a conformationally adaptive ligand 4,7-bis(3-(pyridin-4-yl)phenyl) benzo[c][1,2,5]thiadiazole (L1) with a tunable torsional angle θ of N1–C1–C2–N2 ranging from 7.5° to 108.9°. Utilizing coordination-driven self-assembly at ambient temperature, L1 selectively assembles with binuclear half-sandwich units Rh–B1, Rh–B2, Rh–B3, and Rh–B4 featuring Cp∗RhIII (Cp∗ = η5-pentamethylcyclopentadienyl) into distinct topologies: Solomon links Rh-1, trefoil knots Rh-2, molecular tweezers Rh-3, and Rh-4, respectively. Crucially, the self-adaptability of ligand L1 directs topology formation through programming different combination of noncovalent interactions (π-π stacking, CH⋯π interaction, and lone pair-π interaction), thus navigating divergent assembly pathways by conformational switching, as evidenced by X-ray crystallography analysis, independent gradient model (IGM) analysis, detailed nuclear magnetic resonance (NMR) spectroscopy and electrospray ionization time-of-flight/mass spectrometry (ESI-TOF/MS). This strategy can also be extended to construct Cp∗IrIII analogs (Solomon links Ir-1, trefoil knots Ir-2, molecular tweezers Ir-3 and Ir-4), demonstrating metal-independent control and achieving intricate topologies in a high yield.
{"title":"Ligand conformational adaptability modulated self-assembly of Solomon links (412) and trefoil knots (31)","authors":"Xing-Cheng Hu , Qiu-Shui Mu , Shu-Jin Bao , Yan Zou , Xin-Yu Wang , Guo-Xin Jin","doi":"10.1016/j.cjsc.2025.100712","DOIUrl":"10.1016/j.cjsc.2025.100712","url":null,"abstract":"<div><div>Mechanically interlocked molecules (MIMs) have unique properties with broad applications, yet constructing both knotted and linked topologies from the same ligand remains challenging due to their distinct geometric demands. To address this, we design and synthesize a conformationally adaptive ligand 4,7-bis(3-(pyridin-4-yl)phenyl) benzo[c][1,2,5]thiadiazole (<strong>L1</strong>) with a tunable torsional angle <em>θ</em> of N1–C1–C2–N2 ranging from 7.5° to 108.9°. Utilizing coordination-driven self-assembly at ambient temperature, <strong>L1</strong> selectively assembles with binuclear half-sandwich units <strong>Rh–B1</strong>, <strong>Rh–B2</strong>, <strong>Rh–B3</strong>, and <strong>Rh–B4</strong> featuring Cp∗Rh<sup>III</sup> (Cp∗ = <em>η</em><sup>5</sup>-pentamethylcyclopentadienyl) into distinct topologies: Solomon links <strong>Rh-1</strong>, trefoil knots <strong>Rh-2</strong>, molecular tweezers <strong>Rh-3</strong>, and <strong>Rh-4</strong>, respectively. Crucially, the self-adaptability of ligand <strong>L1</strong> directs topology formation through programming different combination of noncovalent interactions (π-π stacking, CH⋯π interaction, and lone pair-π interaction), thus navigating divergent assembly pathways by conformational switching, as evidenced by X-ray crystallography analysis, independent gradient model (IGM) analysis, detailed nuclear magnetic resonance (NMR) spectroscopy and electrospray ionization time-of-flight/mass spectrometry (ESI-TOF/MS). This strategy can also be extended to construct Cp∗Ir<sup>III</sup> analogs (Solomon links <strong>Ir-1</strong>, trefoil knots <strong>Ir-2</strong>, molecular tweezers <strong>Ir-3</strong> and <strong>Ir-4</strong>), demonstrating metal-independent control and achieving intricate topologies in a high yield.</div></div>","PeriodicalId":10151,"journal":{"name":"结构化学","volume":"44 10","pages":"Article 100712"},"PeriodicalIF":10.3,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145398055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01Epub Date: 2025-09-09DOI: 10.1016/j.cjsc.2025.100719
Pengfu Gao, Yuan Geng, Wei Gong
Chiral metal-organic frameworks (CMOFs), a class of highly crystalline and porous materials with tailorable chiral characteristics, have currently become an interdisciplinary between chirality chemistry, coordination chemistry, and material chemistry, which involve in many subjects including chemistry, physics, optics, medicine, pharmacology, biology, crystal engineering, environmental science, etc. Their special structural features such as porosity, modularity, and chirality have endowed them with a variety of unique effects in promoting enantioselective processes, particularly asymmetric catalysis. Here, we provide a brief review of the state of CMOF field from the privileged ligand design to the heterogeneous enantioselective catalysis. We hope that this review will provide researchers a better understanding of CMOF chemistry and facilitate the future research endeavors for rationally designing privileged chiral framework materials for challenging catalytic applications.
{"title":"Homochiral metal-organic frameworks bearing privileged ligands for heterogeneous asymmetric catalysis","authors":"Pengfu Gao, Yuan Geng, Wei Gong","doi":"10.1016/j.cjsc.2025.100719","DOIUrl":"10.1016/j.cjsc.2025.100719","url":null,"abstract":"<div><div>Chiral metal-organic frameworks (CMOFs), a class of highly crystalline and porous materials with tailorable chiral characteristics, have currently become an interdisciplinary between chirality chemistry, coordination chemistry, and material chemistry, which involve in many subjects including chemistry, physics, optics, medicine, pharmacology, biology, crystal engineering, environmental science, etc. Their special structural features such as porosity, modularity, and chirality have endowed them with a variety of unique effects in promoting enantioselective processes, particularly asymmetric catalysis. Here, we provide a brief review of the state of CMOF field from the privileged ligand design to the heterogeneous enantioselective catalysis. We hope that this review will provide researchers a better understanding of CMOF chemistry and facilitate the future research endeavors for rationally designing privileged chiral framework materials for challenging catalytic applications.</div></div>","PeriodicalId":10151,"journal":{"name":"结构化学","volume":"44 10","pages":"Article 100719"},"PeriodicalIF":10.3,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145398059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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