首页 > 最新文献

Comput. Chem. Eng.最新文献

英文 中文
Steady vs. Dynamic Contributions of Different Doped Conducting Polymers in the Principal Components of an Electronic Nose’s Response 不同掺杂导电聚合物对电子鼻响应主成分的稳态与动态贡献
Pub Date : 2023-09-22 DOI: 10.3390/eng4040141
Wiem Haj Ammar, Aicha Boujnah, Aimen Boubaker, Adel Kalboussi, Kamal Lmimouni, Sébastien Pecqueur
Multivariate data analysis and machine learning classification have become popular tools to extract features without physical models for complex environments recognition. For electronic noses, time sampling over multiple sensing elements must be a fair compromise between a period sufficiently long to output a meaningful information pattern and sufficiently short to minimize training time for practical applications. Particularly when a reactivity’s kinetics differ from the thermodynamics in sensitive materials, finding the best compromise to get the most from the data is not obvious. Here, we investigate the influence of data acquisition to improve or alter data clustering for molecular recognition on a conducting polymer electronic nose. We found out that waiting for sensing elements to reach their steady state is not required for classification, and that reducing data acquisition down to the first dynamical information suffices to recognize molecular gases by principal component analysis with the same materials. Especially for online inference, this study shows that a good sensing array is not an array of good sensors, and that new figures of merit should be defined for sensing hardware using machine learning pattern recognition rather than metrology.
多变量数据分析和机器学习分类已经成为复杂环境识别中无需物理模型提取特征的流行工具。对于电子鼻,在多个传感元件上进行时间采样必须在足够长的时间以输出有意义的信息模式和足够短的时间以最大限度地减少实际应用的训练时间之间折衷。特别是当反应性的动力学与敏感材料的热力学不同时,找到从数据中获得最大收益的最佳折衷方案并不明显。在这里,我们研究了数据采集对改进或改变导电聚合物电子鼻分子识别数据聚类的影响。我们发现,等待传感元件达到稳定状态并不需要分类,并且将数据采集减少到第一个动态信息足以通过主成分分析识别相同材料的分子气体。特别是在在线推理方面,本研究表明,一个好的传感阵列并不是一个好的传感器阵列,并且应该使用机器学习模式识别而不是计量来定义传感硬件的新优点。
{"title":"Steady vs. Dynamic Contributions of Different Doped Conducting Polymers in the Principal Components of an Electronic Nose’s Response","authors":"Wiem Haj Ammar, Aicha Boujnah, Aimen Boubaker, Adel Kalboussi, Kamal Lmimouni, Sébastien Pecqueur","doi":"10.3390/eng4040141","DOIUrl":"https://doi.org/10.3390/eng4040141","url":null,"abstract":"Multivariate data analysis and machine learning classification have become popular tools to extract features without physical models for complex environments recognition. For electronic noses, time sampling over multiple sensing elements must be a fair compromise between a period sufficiently long to output a meaningful information pattern and sufficiently short to minimize training time for practical applications. Particularly when a reactivity’s kinetics differ from the thermodynamics in sensitive materials, finding the best compromise to get the most from the data is not obvious. Here, we investigate the influence of data acquisition to improve or alter data clustering for molecular recognition on a conducting polymer electronic nose. We found out that waiting for sensing elements to reach their steady state is not required for classification, and that reducing data acquisition down to the first dynamical information suffices to recognize molecular gases by principal component analysis with the same materials. Especially for online inference, this study shows that a good sensing array is not an array of good sensors, and that new figures of merit should be defined for sensing hardware using machine learning pattern recognition rather than metrology.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"62 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136061141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative Study of Musical Timbral Variations: Crescendo and Vibrato Using FFT-Acoustic Descriptor 音乐音色变化的比较研究:使用fft声学描述符的渐强和颤音
Pub Date : 2023-09-21 DOI: 10.3390/eng4030140
Yubiry Gonzalez, Ronaldo C. Prati
A quantitative evaluation of the musical timbre and its variations is important for the analysis of audio recordings and computer-aided music composition. Using the FFT acoustic descriptors and their representation in an abstract timbral space, variations in a sample of monophonic sounds of chordophones (violin, cello) and aerophones (trumpet, transverse flute, and clarinet) sounds are analyzed. It is concluded that the FFT acoustic descriptors allow us to distinguish the timbral variations in the musical dynamics, including crescendo and vibrato. Furthermore, using the Random Forest algorithm, it is shown that the FFT-Acoustic provides a statistically significant classification to distinguish musical instruments, families of instruments, and dynamics. We observed an improvement in the FFT-Acoustic descriptors when classifying pitch compared to some timbral features of Librosa.
音乐音色及其变化的定量评价是重要的录音和计算机辅助作曲的分析。利用FFT声学描述符及其在抽象音质空间中的表示,分析了弦乐器(小提琴、大提琴)和管乐器(小号、横笛和单簧管)单音声音样本的变化。结论是FFT声学描述符使我们能够区分音乐动态中的音色变化,包括渐强和颤音。此外,使用随机森林算法,结果表明FFT-Acoustic在区分乐器、乐器族和动态方面提供了统计上显著的分类。与Librosa的一些音质特征相比,我们观察到fft声学描述符在分类音高时的改进。
{"title":"Comparative Study of Musical Timbral Variations: Crescendo and Vibrato Using FFT-Acoustic Descriptor","authors":"Yubiry Gonzalez, Ronaldo C. Prati","doi":"10.3390/eng4030140","DOIUrl":"https://doi.org/10.3390/eng4030140","url":null,"abstract":"A quantitative evaluation of the musical timbre and its variations is important for the analysis of audio recordings and computer-aided music composition. Using the FFT acoustic descriptors and their representation in an abstract timbral space, variations in a sample of monophonic sounds of chordophones (violin, cello) and aerophones (trumpet, transverse flute, and clarinet) sounds are analyzed. It is concluded that the FFT acoustic descriptors allow us to distinguish the timbral variations in the musical dynamics, including crescendo and vibrato. Furthermore, using the Random Forest algorithm, it is shown that the FFT-Acoustic provides a statistically significant classification to distinguish musical instruments, families of instruments, and dynamics. We observed an improvement in the FFT-Acoustic descriptors when classifying pitch compared to some timbral features of Librosa.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136236450","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Machine Learning-Based Real-Time Prediction of Formation Lithology and Tops Using Drilling Parameters with a Web App Integration 基于机器学习的实时预测地层岩性和顶部,利用钻井参数与Web应用程序集成
Pub Date : 2023-09-21 DOI: 10.3390/eng4030139
Houdaifa Khalifa, Olusegun Stanley Tomomewo, Uchenna Frank Ndulue, Badr Eddine Berrehal
The accurate prediction of underground formation lithology class and tops is a critical challenge in the oil industry. This paper presents a machine-learning (ML) approach to predict lithology from drilling data, offering real-time litho-facies identification. The ML model, applied via the web app “GeoVision”, achieves remarkable performance during its training phase with a mean accuracy of 95% and a precision of 98%. The model successfully predicts claystone, marl, and sandstone classes with high precision scores. Testing on new data yields an overall accuracy of 95%, providing valuable insights and setting a benchmark for future efforts. To address the limitations of current methodologies, such as time lags and lack of real-time data, we utilize drilling data as a unique endeavor to predict lithology. Our approach integrates nine drilling parameters, going beyond the narrow focus on the rate of penetration (ROP) often seen in previous research. The model was trained and evaluated using the open Volve field dataset, and careful data preprocessing was performed to reduce features, balance the sample distribution, and ensure an unbiased dataset. The innovative methodology demonstrates exceptional performance and offers substantial advantages for real-time geosteering. The accessibility of our models is enhanced through the user-friendly web app “GeoVision”, enabling effective utilization by drilling engineers and marking a significant advancement in the field.
准确预测地下地层岩性和顶部是石油工业面临的一个关键挑战。本文提出了一种机器学习(ML)方法,通过钻井数据预测岩性,提供实时岩相识别。通过web应用程序“GeoVision”应用的ML模型在训练阶段取得了显着的表现,平均准确率为95%,精度为98%。该模型成功地预测了粘土岩、泥灰岩和砂岩的分类,得分精度很高。对新数据的测试总体准确率达到95%,提供了有价值的见解,并为未来的努力设定了基准。为了解决当前方法的局限性,例如时间滞后和缺乏实时数据,我们利用钻井数据作为预测岩性的独特尝试。我们的方法集成了9个钻井参数,超越了以往研究中对机械钻速(ROP)的狭隘关注。该模型使用开放的Volve现场数据集进行训练和评估,并进行仔细的数据预处理,以减少特征,平衡样本分布,确保数据集无偏。这种创新的方法表现出卓越的性能,为实时地质导向提供了巨大的优势。通过用户友好的web应用程序“GeoVision”增强了我们模型的可访问性,使钻井工程师能够有效利用,标志着该领域的重大进步。
{"title":"Machine Learning-Based Real-Time Prediction of Formation Lithology and Tops Using Drilling Parameters with a Web App Integration","authors":"Houdaifa Khalifa, Olusegun Stanley Tomomewo, Uchenna Frank Ndulue, Badr Eddine Berrehal","doi":"10.3390/eng4030139","DOIUrl":"https://doi.org/10.3390/eng4030139","url":null,"abstract":"The accurate prediction of underground formation lithology class and tops is a critical challenge in the oil industry. This paper presents a machine-learning (ML) approach to predict lithology from drilling data, offering real-time litho-facies identification. The ML model, applied via the web app “GeoVision”, achieves remarkable performance during its training phase with a mean accuracy of 95% and a precision of 98%. The model successfully predicts claystone, marl, and sandstone classes with high precision scores. Testing on new data yields an overall accuracy of 95%, providing valuable insights and setting a benchmark for future efforts. To address the limitations of current methodologies, such as time lags and lack of real-time data, we utilize drilling data as a unique endeavor to predict lithology. Our approach integrates nine drilling parameters, going beyond the narrow focus on the rate of penetration (ROP) often seen in previous research. The model was trained and evaluated using the open Volve field dataset, and careful data preprocessing was performed to reduce features, balance the sample distribution, and ensure an unbiased dataset. The innovative methodology demonstrates exceptional performance and offers substantial advantages for real-time geosteering. The accessibility of our models is enhanced through the user-friendly web app “GeoVision”, enabling effective utilization by drilling engineers and marking a significant advancement in the field.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"125 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136236416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and Numerical Analysis on a Thermal Barrier Coating with Nano-Ceramic Base: A Potential Solution to Reduce Urban Heat Islands? 纳米陶瓷基热障涂层的实验与数值分析:减少城市热岛的潜在解决方案?
Pub Date : 2023-09-19 DOI: 10.3390/eng4030138
Bruno Malet-Damour, Dimitri Bigot, Garry Rivière
Adopting a multiscale approach is crucial for optimizing urban and building performance, prompting inquiries about the link between a technology’s local efficiency (building scale) and its broader impact (city-wide). To investigate this correlation and devise effective strategies for enhancing building and city energy performance, we experimentally examined a commercial nano-ceramic Thermal Barrier Coating (TBC) on a small-scale building and assessed numerically its influence on mitigating Urban Heat Islands (UHIs) at a city scale, translated in our case by the use of the thermal comfort index: the Universal Thermal Climate Index (UTCI). Our results reveal that the coating significantly curbs heat transfer locally, reducing surface temperatures by over 50 ∘C compared to traditional roofs and attenuating more than 70% of heat flux, potentially alleviating air conditioning demands and associated urban heat effects. However, implementing such coatings across a city does not notably advance overall efficiency and might trigger minor overheating on thermal perception. Hence, while nano-ceramic coatings indirectly aid UHI mitigation, they are not a standalone fix; instead, an integrated strategy involving efficient coatings, sustainable urban planning, and increased vegetation emerges as the optimal path toward creating enduringly sustainable, pleasant, and efficient urban environments to counter urban heat challenges effectively.
采用多尺度方法对于优化城市和建筑性能至关重要,这促使人们对一项技术的局部效率(建筑规模)与其更广泛的影响(城市范围)之间的联系提出了疑问。为了研究这种相关性,并制定有效的策略来提高建筑和城市的能源性能,我们在一个小型建筑上实验研究了一种商业纳米陶瓷热障涂层(TBC),并在城市尺度上评估了其对缓解城市热岛(UHIs)的影响,在我们的案例中,使用热舒适指数:通用热气候指数(UTCI)进行了数值评估。我们的研究结果显示,这种涂层显著地抑制了局部的热传递,与传统屋顶相比,表面温度降低了50°C以上,并减少了70%以上的热流,潜在地减轻了空调需求和相关的城市热效应。然而,在整个城市实施这种涂料并不能显著提高整体效率,而且可能会在热感知上引发轻微过热。因此,虽然纳米陶瓷涂层间接有助于缓解UHI,但它们并不是一个独立的解决方案;相反,一个包括高效涂料、可持续城市规划和增加植被的综合战略成为创造持久可持续、宜人和高效的城市环境的最佳途径,以有效应对城市热挑战。
{"title":"Experimental and Numerical Analysis on a Thermal Barrier Coating with Nano-Ceramic Base: A Potential Solution to Reduce Urban Heat Islands?","authors":"Bruno Malet-Damour, Dimitri Bigot, Garry Rivière","doi":"10.3390/eng4030138","DOIUrl":"https://doi.org/10.3390/eng4030138","url":null,"abstract":"Adopting a multiscale approach is crucial for optimizing urban and building performance, prompting inquiries about the link between a technology’s local efficiency (building scale) and its broader impact (city-wide). To investigate this correlation and devise effective strategies for enhancing building and city energy performance, we experimentally examined a commercial nano-ceramic Thermal Barrier Coating (TBC) on a small-scale building and assessed numerically its influence on mitigating Urban Heat Islands (UHIs) at a city scale, translated in our case by the use of the thermal comfort index: the Universal Thermal Climate Index (UTCI). Our results reveal that the coating significantly curbs heat transfer locally, reducing surface temperatures by over 50 ∘C compared to traditional roofs and attenuating more than 70% of heat flux, potentially alleviating air conditioning demands and associated urban heat effects. However, implementing such coatings across a city does not notably advance overall efficiency and might trigger minor overheating on thermal perception. Hence, while nano-ceramic coatings indirectly aid UHI mitigation, they are not a standalone fix; instead, an integrated strategy involving efficient coatings, sustainable urban planning, and increased vegetation emerges as the optimal path toward creating enduringly sustainable, pleasant, and efficient urban environments to counter urban heat challenges effectively.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"185 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135107081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analytical Hierarchical Process to Establish the Criteria for Choosing Explosives Suppliers in Small and Medium Mining Companies 层次分析法建立中小型矿山企业炸药供应商选择标准
Pub Date : 2023-09-18 DOI: 10.3390/eng4030137
Edison Ramírez Olivares, Mauricio Castillo-Vergara
Mining plays a pivotal role in economies worldwide, contributing to employment, infrastructure, and the supply of essential raw materials. Chile’s global mining powerhouse, particularly in copper production, exemplifies this industry’s economic significance. The supplier selection process in the mining industry, a complex and multifaceted task, is explored in detail, specifically focusing on explosives procurement, a critical component for mineral extraction. The paper underscores the importance of informed supplier selection decisions, especially for SMEs, which often need more resources and capabilities for efficient management. To address these challenges, the study proposes applying the Analytic Hierarchical Process (AHP), a multi-criteria decision-making methodology, to identify and prioritize the criteria and sub-criteria pertinent to choosing explosives suppliers. A case study in the Coquimbo Region, Chile, involving SMEs in the mining sector is the empirical foundation for this research. Our research highlights that the foremost criterion for SMEs in the Coquimbo Region’s mining sector is “relationship with the environment and communities”. This reflects the national context of mining community tensions and the rising environmental standards and social expectations, which can profoundly impact mining operations. “Quality of products and services” is the second most crucial criterion, underscoring SMEs’ drive to enhance productivity and efficiency. “Contractual compliance” follows closely, signifying the integration of SMEs into broader social and environmental sustainability efforts. Conversely, “innovation” ranks as the least relevant criterion, indicating that SMEs prioritize traditional processes due to limited resources and cost constraints. These insights are valuable for mining supplier company managers, emphasizing the need for sustainability, corporate social responsibility, and management control systems.
矿业在全球经济中发挥着关键作用,为就业、基础设施和重要原材料的供应做出了贡献。智利是全球矿业大国,尤其是铜生产大国,这充分说明了该行业的经济重要性。采矿业的供应商选择过程是一项复杂和多方面的任务,本文详细探讨了这一过程,特别侧重于炸药的采购,这是矿物开采的一个关键组成部分。本文强调了明智的供应商选择决策的重要性,特别是对于中小型企业来说,它们通常需要更多的资源和能力来进行有效的管理。为了应对这些挑战,该研究建议应用层次分析法(AHP),一种多标准决策方法,来确定和优先考虑与选择炸药供应商相关的标准和子标准。在智利科金博地区进行的涉及矿业部门中小企业的案例研究是本研究的实证基础。我们的研究强调,科金博地区采矿业中小企业的首要标准是“与环境和社区的关系”。这反映了矿业社区紧张局势的国家背景以及不断提高的环境标准和社会期望,这些都可能对采矿作业产生深远影响。“产品和服务的质素”是第二重要的标准,突显中小企业致力提高生产力和效率。“合同合规”紧随其后,标志着中小企业融入更广泛的社会和环境可持续发展努力。相反,“创新”被列为最不相关的标准,这表明由于有限的资源和成本约束,中小企业优先考虑传统流程。这些见解对采矿供应商公司的管理人员很有价值,强调了可持续发展、企业社会责任和管理控制系统的必要性。
{"title":"Analytical Hierarchical Process to Establish the Criteria for Choosing Explosives Suppliers in Small and Medium Mining Companies","authors":"Edison Ramírez Olivares, Mauricio Castillo-Vergara","doi":"10.3390/eng4030137","DOIUrl":"https://doi.org/10.3390/eng4030137","url":null,"abstract":"Mining plays a pivotal role in economies worldwide, contributing to employment, infrastructure, and the supply of essential raw materials. Chile’s global mining powerhouse, particularly in copper production, exemplifies this industry’s economic significance. The supplier selection process in the mining industry, a complex and multifaceted task, is explored in detail, specifically focusing on explosives procurement, a critical component for mineral extraction. The paper underscores the importance of informed supplier selection decisions, especially for SMEs, which often need more resources and capabilities for efficient management. To address these challenges, the study proposes applying the Analytic Hierarchical Process (AHP), a multi-criteria decision-making methodology, to identify and prioritize the criteria and sub-criteria pertinent to choosing explosives suppliers. A case study in the Coquimbo Region, Chile, involving SMEs in the mining sector is the empirical foundation for this research. Our research highlights that the foremost criterion for SMEs in the Coquimbo Region’s mining sector is “relationship with the environment and communities”. This reflects the national context of mining community tensions and the rising environmental standards and social expectations, which can profoundly impact mining operations. “Quality of products and services” is the second most crucial criterion, underscoring SMEs’ drive to enhance productivity and efficiency. “Contractual compliance” follows closely, signifying the integration of SMEs into broader social and environmental sustainability efforts. Conversely, “innovation” ranks as the least relevant criterion, indicating that SMEs prioritize traditional processes due to limited resources and cost constraints. These insights are valuable for mining supplier company managers, emphasizing the need for sustainability, corporate social responsibility, and management control systems.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135202890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the Genesis of a Catalyst: A Brief Review with an Experimental Case Study 催化剂的起源:一个实验案例的简要回顾
Pub Date : 2023-09-17 DOI: 10.3390/eng4030136
Simón Yunes, Jeffrey Kenvin, Antonio Gil
The science of catalysis has a direct impact on the world economy and the energy environment that positively affects the environmental ecosystem of our universe. Any catalyst, before being tested in a reaction, must undergo a specific characterization protocol to simulate its behavior under reaction conditions. In this work, these steps that must be carried out are presented, both generically and with examples, to the support and to the catalyst itself before and after the reaction. The first stage consists of knowing the textural and structural properties of the support used for the preparation of the catalysts. The specific surface area and the pore volume are fundamental properties, measured by N2 adsorption at −196 °C when preparing the catalyst, dispersing the active phase, and allowing the diffusion and reaction of the reactants and products on its surface. If knowing the structure of the catalyst is important to control its behavior against a reaction, being able to analyze the catalyst used under the reaction conditions is essential to have knowledge about what has happened inside the catalytic reactor. The most common characterization techniques in heterogeneous catalysis laboratories are those described in this work. As an application example, the catalytic conversion of CO2 to CH4 has been selected and summarized in this work. In this case, the synthesis and characterization of Cu and Ni catalysts supported on two Al2O3 with different textural properties, 92 and 310 m2/g, that allow for obtaining various metallic dispersions, between 3.3 and 25.5%, is described. The catalytic behavior of these materials is evaluated from the CO2 methanation reaction, as well as their stability from the properties they present before and after the reaction.
催化科学对世界经济和能源环境有着直接的影响,对我们宇宙的环境生态系统有着积极的影响。任何催化剂在进行反应测试之前,都必须经过特定的表征方案来模拟其在反应条件下的行为。在这项工作中,必须执行的这些步骤,无论是一般的还是举例,都是在反应前后对载体和催化剂本身提出的。第一阶段包括了解用于制备催化剂的载体的结构和结构性质。比表面积和孔体积是制备催化剂时的基本性质,在- 196℃下通过N2吸附来测量,使活性相分散,并允许反应物和生成物在其表面扩散和反应。如果了解催化剂的结构对控制其对反应的行为很重要,那么能够分析反应条件下使用的催化剂对于了解催化反应器内部发生的情况是必不可少的。在多相催化实验室中最常见的表征技术是在这项工作中描述的。作为应用实例,本文选取并总结了CO2催化转化为CH4的方法。在这种情况下,描述了Cu和Ni催化剂的合成和表征,这两种催化剂具有不同的结构性质,92和310 m2/g,允许获得不同的金属分散度,在3.3和25.5%之间。这些材料的催化行为是通过CO2甲烷化反应来评估的,以及它们在反应前后表现出的性能的稳定性。
{"title":"On the Genesis of a Catalyst: A Brief Review with an Experimental Case Study","authors":"Simón Yunes, Jeffrey Kenvin, Antonio Gil","doi":"10.3390/eng4030136","DOIUrl":"https://doi.org/10.3390/eng4030136","url":null,"abstract":"The science of catalysis has a direct impact on the world economy and the energy environment that positively affects the environmental ecosystem of our universe. Any catalyst, before being tested in a reaction, must undergo a specific characterization protocol to simulate its behavior under reaction conditions. In this work, these steps that must be carried out are presented, both generically and with examples, to the support and to the catalyst itself before and after the reaction. The first stage consists of knowing the textural and structural properties of the support used for the preparation of the catalysts. The specific surface area and the pore volume are fundamental properties, measured by N2 adsorption at −196 °C when preparing the catalyst, dispersing the active phase, and allowing the diffusion and reaction of the reactants and products on its surface. If knowing the structure of the catalyst is important to control its behavior against a reaction, being able to analyze the catalyst used under the reaction conditions is essential to have knowledge about what has happened inside the catalytic reactor. The most common characterization techniques in heterogeneous catalysis laboratories are those described in this work. As an application example, the catalytic conversion of CO2 to CH4 has been selected and summarized in this work. In this case, the synthesis and characterization of Cu and Ni catalysts supported on two Al2O3 with different textural properties, 92 and 310 m2/g, that allow for obtaining various metallic dispersions, between 3.3 and 25.5%, is described. The catalytic behavior of these materials is evaluated from the CO2 methanation reaction, as well as their stability from the properties they present before and after the reaction.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135259416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Setup Time Reduction of an Automotive Parts Assembly Line Using Lean Tools and Quality Tools 利用精益工具和质量工具减少汽车零件装配线的安装时间
Pub Date : 2023-09-13 DOI: 10.3390/eng4030134
Cátia Oliveira, Tânia M. Lima
The business world is becoming more competitive. Therefore, it is crucial to increase the flexibility of production by decreasing the time used in the processes of preparing the production lines for new items’ production, reducing changeover and setup times. This paper presents a case study where the main goal is to reduce the setup time of welding robots. Single Minute Exchange of Die (SMED) was implemented, using other tools such as the Spaghetti Diagram, ERCS Analysis (Eliminate, Rearrange, Combine, Simplify), Gemba Walk, Standardized Work, Flowcharts, and Pareto Diagram. The setup time decreased by 36% in the welding robots studied, decreasing the motions by 43% during the changeover process and reducing the time from the categories: “transportation”, “main”, “other”, and “waiting”. In addition to SMED implementation, this study offers an integrated study of several Lean tools and Quality tools to achieve the maximum reduction of changeover and setup times.
商业世界的竞争越来越激烈。因此,通过减少生产线准备新产品生产的时间、减少转换和安装时间来增加生产的灵活性至关重要。本文给出了一个案例研究,其主要目标是减少焊接机器人的设置时间。通过使用其他工具,如意大利面图、ERCS分析(消除、重新排列、组合、简化)、Gemba Walk、标准化工作、流程图和帕累托图,实现了单分钟换模(SMED)。所研究的焊接机器人的设置时间减少了36%,在转换过程中减少了43%的运动,并且减少了“运输”,“主要”,“其他”和“等待”类别的时间。除了SMED的实施,本研究还提供了几个精益工具和质量工具的综合研究,以最大限度地减少转换和设置时间。
{"title":"Setup Time Reduction of an Automotive Parts Assembly Line Using Lean Tools and Quality Tools","authors":"Cátia Oliveira, Tânia M. Lima","doi":"10.3390/eng4030134","DOIUrl":"https://doi.org/10.3390/eng4030134","url":null,"abstract":"The business world is becoming more competitive. Therefore, it is crucial to increase the flexibility of production by decreasing the time used in the processes of preparing the production lines for new items’ production, reducing changeover and setup times. This paper presents a case study where the main goal is to reduce the setup time of welding robots. Single Minute Exchange of Die (SMED) was implemented, using other tools such as the Spaghetti Diagram, ERCS Analysis (Eliminate, Rearrange, Combine, Simplify), Gemba Walk, Standardized Work, Flowcharts, and Pareto Diagram. The setup time decreased by 36% in the welding robots studied, decreasing the motions by 43% during the changeover process and reducing the time from the categories: “transportation”, “main”, “other”, and “waiting”. In addition to SMED implementation, this study offers an integrated study of several Lean tools and Quality tools to achieve the maximum reduction of changeover and setup times.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"107 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135741955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Solar Thermal Technology Aided Membrane Distillation Process for Wastewater Treatment in Textile Industry—A Technoeconomic Feasibility Assessment 太阳能热技术辅助膜蒸馏法处理纺织工业废水的技术经济可行性评价
Pub Date : 2023-09-13 DOI: 10.3390/eng4030135
Mukesh Kumar Gupta, Rajendra B. Mohite, Salunkhe Madhav Jagannath, Pankaj Kumar, Dipak Shankar Raskar, Malay Kumar Banerjee, Suraj Kumar Singh, Dragana Dogančić, Bojan Đurin
Because textile industries are intensely water-consuming and generate a huge quantity of wastewater, the present study examines the scope of using solar thermal technology to treat wastewater from textile industries. A hybrid technology, comprising a compound parabolic concentrator-based solar thermal system in conjunction with a Membrane Distillation (MD) system, is experimented with for wastewater treatment in textile industries. The MD system requires a water temperature of around 90 °C for efficient functioning. The advanced MD technology using waste heat combined with solar heat to meet the system’s thermal load is technologically evaluated for an experimental textile industry in India. Moreover, the present study critically analyses the techno economics of the proposed hybrid technology. A detailed financial analysis has revealed that, besides technological superiority, the recommended technology is also financially rewarding for wastewater treatment in the textile industry. To cope with the delayed payback period, financial incentives are recommended so that the system becomes a lucrative technological option.
由于纺织工业用水量大,废水量大,本研究探讨了利用太阳能热技术处理纺织工业废水的范围。一种混合技术,包括基于复合抛物面聚光器的太阳能热系统与膜蒸馏(MD)系统相结合,用于纺织工业的废水处理试验。MD系统需要90°C左右的水温才能有效运行。先进的MD技术利用废热与太阳能热相结合来满足系统的热负荷,为印度的一个实验性纺织工业进行了技术评估。此外,本研究批判性地分析了所提出的混合技术的技术经济学。详细的财务分析表明,除了技术优势外,所推荐的技术对纺织行业的废水处理也具有经济效益。为了应对延迟的投资回收期,建议采取财政激励措施,使该系统成为有利可图的技术选择。
{"title":"Solar Thermal Technology Aided Membrane Distillation Process for Wastewater Treatment in Textile Industry—A Technoeconomic Feasibility Assessment","authors":"Mukesh Kumar Gupta, Rajendra B. Mohite, Salunkhe Madhav Jagannath, Pankaj Kumar, Dipak Shankar Raskar, Malay Kumar Banerjee, Suraj Kumar Singh, Dragana Dogančić, Bojan Đurin","doi":"10.3390/eng4030135","DOIUrl":"https://doi.org/10.3390/eng4030135","url":null,"abstract":"Because textile industries are intensely water-consuming and generate a huge quantity of wastewater, the present study examines the scope of using solar thermal technology to treat wastewater from textile industries. A hybrid technology, comprising a compound parabolic concentrator-based solar thermal system in conjunction with a Membrane Distillation (MD) system, is experimented with for wastewater treatment in textile industries. The MD system requires a water temperature of around 90 °C for efficient functioning. The advanced MD technology using waste heat combined with solar heat to meet the system’s thermal load is technologically evaluated for an experimental textile industry in India. Moreover, the present study critically analyses the techno economics of the proposed hybrid technology. A detailed financial analysis has revealed that, besides technological superiority, the recommended technology is also financially rewarding for wastewater treatment in the textile industry. To cope with the delayed payback period, financial incentives are recommended so that the system becomes a lucrative technological option.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"27 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135782467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Artificial Intelligence and Industry 4.0? Validation of Challenges Considering the Context of an Emerging Economy Country Using Cronbach’s Alpha and the Lawshe Method 人工智能与工业4.0?基于Cronbach 's Alpha和Lawshe方法的新兴经济体背景下的挑战验证
Pub Date : 2023-09-12 DOI: 10.3390/eng4030133
Paulliny Araújo Moreira, Reimison Moreira Fernandes, Lucas Veiga Avila, Leonardo dos Santos Lourenço Bastos, Vitor William Batista Martins
Background: Artificial Intelligence has been an area of great interest and investment in the industrial sector, offering numerous possibilities to enhance efficiency and accuracy in production processes. In this regard, this study aimed to identify the adoption challenges of Artificial Intelligence and determine which of these challenges apply to the industrial context of an emerging economy, considering the aspects of Industry 4.0. Methods: To achieve this objective, a literature review was conducted, and a survey was carried out among professionals in the industrial field operating within the Brazilian context. The collected data were analyzed using a quantitative approach through Cronbach’s alpha and the Lawshe method. Results: The results indicate that to enhance the adoption of Artificial Intelligence in the industrial context of an emerging economy, taking into account the needs of Industry 4.0, it is important to prioritize overcoming challenges such as “Lack of clarity in return on investment,” “Organizational culture,” “Acceptance of AI by workers,” “Quantity and quality of data,” and “Data protection”. Conclusions: Therefore, based on the achieved results, it can be concluded that they contribute to the development of strategies and practical actions aimed at successfully driving the adoption of Artificial Intelligence in the industrial sector of developing countries, aligning with the principles and needs of Industry 4.0.
背景:人工智能一直是工业部门非常感兴趣和投资的领域,为提高生产过程的效率和准确性提供了许多可能性。在这方面,本研究旨在确定人工智能的采用挑战,并考虑到工业4.0的各个方面,确定哪些挑战适用于新兴经济体的工业背景。方法:为了实现这一目标,进行了文献综述,并对巴西工业领域的专业人员进行了调查。收集的数据通过Cronbach’s alpha和Lawshe方法进行定量分析。结果:研究结果表明,考虑到工业4.0的需求,要在新兴经济体的工业背景下加强人工智能的采用,重要的是要优先克服诸如“投资回报缺乏明确性”、“组织文化”、“工人对人工智能的接受程度”、“数据的数量和质量”以及“数据保护”等挑战。因此,根据取得的成果,可以得出结论,它们有助于制定战略和实际行动,旨在成功推动发展中国家工业部门采用人工智能,与工业4.0的原则和需求保持一致。
{"title":"Artificial Intelligence and Industry 4.0? Validation of Challenges Considering the Context of an Emerging Economy Country Using Cronbach’s Alpha and the Lawshe Method","authors":"Paulliny Araújo Moreira, Reimison Moreira Fernandes, Lucas Veiga Avila, Leonardo dos Santos Lourenço Bastos, Vitor William Batista Martins","doi":"10.3390/eng4030133","DOIUrl":"https://doi.org/10.3390/eng4030133","url":null,"abstract":"Background: Artificial Intelligence has been an area of great interest and investment in the industrial sector, offering numerous possibilities to enhance efficiency and accuracy in production processes. In this regard, this study aimed to identify the adoption challenges of Artificial Intelligence and determine which of these challenges apply to the industrial context of an emerging economy, considering the aspects of Industry 4.0. Methods: To achieve this objective, a literature review was conducted, and a survey was carried out among professionals in the industrial field operating within the Brazilian context. The collected data were analyzed using a quantitative approach through Cronbach’s alpha and the Lawshe method. Results: The results indicate that to enhance the adoption of Artificial Intelligence in the industrial context of an emerging economy, taking into account the needs of Industry 4.0, it is important to prioritize overcoming challenges such as “Lack of clarity in return on investment,” “Organizational culture,” “Acceptance of AI by workers,” “Quantity and quality of data,” and “Data protection”. Conclusions: Therefore, based on the achieved results, it can be concluded that they contribute to the development of strategies and practical actions aimed at successfully driving the adoption of Artificial Intelligence in the industrial sector of developing countries, aligning with the principles and needs of Industry 4.0.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"216 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135878631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Power Transmission Using Circular Elements Bounded by Given Central Angle in Rolling Contact 以给定圆心角为界的圆单元滚动接触动力传动
Pub Date : 2023-09-11 DOI: 10.3390/eng4030132
Christopher G. Provatidis
In the present study, the concept of utilizing two circular cam-track disks, of the same central angle, in combination with one circular roller is presented. The roller is restrained to move within a vertical groove, and at the same time it rotates with rolling-contact on both cam tracks. When the upper cam is fully travelled by the roller, the same occurs with the lower one, despite their different lengths. Therefore, during the rolling contact, the two cams always sweep the same central angle. The aforementioned configuration of the two circular arcs may be considered as a unit cell, which can be repeated an even number of times, and when folded forms a closed circular groove between two cam-track disks. For better understanding, a manufactured prototype and 3D CAD-models have been developed. The operation of this setup as a gearless automotive differential is demonstrated by performing two bench experiments, which are then explained by a simplified mechanical model. The latter focuses on the implementation of the principle of the inclined plane, in which an upper limit of the inclination angle is imposed in accordance with the coefficient of friction at the friction disks. Previous patents on gearless differentials are discussed and other possible applications in mechanical engineering are outlined.
在本研究中,提出了利用两个圆心角相同的凸轮轨迹圆盘与一个圆滚子相结合的概念。滚子被限制在垂直槽内移动,同时它在两个凸轮轨道上滚动接触旋转。当上凸轮被滚子完全移动时,下凸轮也会发生同样的情况,尽管它们的长度不同。因此,在滚动接触过程中,两个凸轮始终扫过相同的圆心角。上述两个圆弧的结构可以看作是一个单元格,它可以重复偶数次,并且当折叠时在两个凸轮轨道盘之间形成一个封闭的圆槽。为了更好地理解,已经开发了一个制造原型和3D cad模型。通过两个台架实验证明了该装置作为无齿轮汽车差速器的运行,然后用简化的力学模型进行了解释。后者侧重于斜面原理的实现,即根据摩擦盘处的摩擦系数设定倾角的上限。讨论了以前的无齿轮差速器专利,并概述了机械工程中其他可能的应用。
{"title":"Power Transmission Using Circular Elements Bounded by Given Central Angle in Rolling Contact","authors":"Christopher G. Provatidis","doi":"10.3390/eng4030132","DOIUrl":"https://doi.org/10.3390/eng4030132","url":null,"abstract":"In the present study, the concept of utilizing two circular cam-track disks, of the same central angle, in combination with one circular roller is presented. The roller is restrained to move within a vertical groove, and at the same time it rotates with rolling-contact on both cam tracks. When the upper cam is fully travelled by the roller, the same occurs with the lower one, despite their different lengths. Therefore, during the rolling contact, the two cams always sweep the same central angle. The aforementioned configuration of the two circular arcs may be considered as a unit cell, which can be repeated an even number of times, and when folded forms a closed circular groove between two cam-track disks. For better understanding, a manufactured prototype and 3D CAD-models have been developed. The operation of this setup as a gearless automotive differential is demonstrated by performing two bench experiments, which are then explained by a simplified mechanical model. The latter focuses on the implementation of the principle of the inclined plane, in which an upper limit of the inclination angle is imposed in accordance with the coefficient of friction at the friction disks. Previous patents on gearless differentials are discussed and other possible applications in mechanical engineering are outlined.","PeriodicalId":10630,"journal":{"name":"Comput. Chem. Eng.","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136024392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Comput. Chem. Eng.
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1