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An Extended Viscoelastic Model for Predicting Polymer Apparent Viscosity at Different Shear Rates 预测不同剪切速率下聚合物表观粘度的扩展粘弹性模型
Pub Date : 2021-09-15 DOI: 10.2118/206010-ms
Mursal Zeynalli, Emad W. Al-Shalabi, W. Alameri
Polymer flooding is one of the most commonly used chemical EOR methods. Conventionally, this technique was believed to improve macroscopic sweep efficiency by sweeping only bypassed oil. Nevertheless, recently it has been found that polymers exhibiting viscoelastic behavior in the porous medium can also improve microscopic displacement efficiency resulting in higher additional oil recovery. Therefore, an accurate prediction of the complex rheological response of polymers is crucial to obtain a proper estimation of incremental oil to polymer flooding. In this paper, a novel viscoelastic model is proposed to comprehensively analyze the polymer rheological behavior in porous media. The proposed viscoelastic model is considered an extension of the unified apparent viscosity model provided in the literature and is termed as extended unified viscosity model (E-UVM). The main advantage of the proposed model is its ability to capture the polymer mechanical degradation at ultimate shear rates primarily observed near wellbores. Furthermore, the fitting parameters used in the model were correlated to rock and polymer properties, significantly reducing the need for time-consuming coreflooding tests for future polymer screening works. Moreover, the extended viscoelastic model was implemented in MATLAB Reservoir Simulation Toolbox (MRST) and verified against the original shear model existing in the simulator. It was found that implementing the viscosity model in MRST might be more accurate and practical than the original method. In addition, the comparison between various viscosity models proposed earlier and E-UVM in the reservoir simulator revealed that the latter model could yield more reliable oil recovery predictions since it accommodates the mechanical degradation of polymers. This study presents a novel viscoelastic model that is more comprehensive and representative as opposed to other models in the literature.
聚合物驱是最常用的化学提高采收率方法之一。传统上,人们认为该技术通过只扫过的原油来提高宏观扫油效率。然而,最近研究发现,在多孔介质中表现出粘弹性行为的聚合物也可以提高微观驱油效率,从而获得更高的额外采收率。因此,准确预测聚合物的复杂流变响应对于正确估计聚合物驱的增油量至关重要。本文提出了一种新的粘弹性模型来综合分析聚合物在多孔介质中的流变行为。提出的粘弹性模型被认为是文献中提供的统一表观粘度模型的扩展,被称为扩展统一粘度模型(E-UVM)。该模型的主要优点是能够捕捉到聚合物在井筒附近的极限剪切速率下的机械降解。此外,模型中使用的拟合参数与岩石和聚合物性质相关,大大减少了未来聚合物筛选工作中耗时的岩心驱油测试的需要。在MATLAB油藏模拟工具箱(MRST)中实现了扩展粘弹性模型,并与模拟器中已有的原始剪切模型进行了验证。结果表明,在MRST中实现黏度模型比原来的方法更准确、更实用。此外,将之前提出的各种粘度模型与油藏模拟器中的E-UVM进行比较,发现后者模型可以产生更可靠的采收率预测,因为它考虑了聚合物的机械降解。本研究提出了一种新颖的粘弹性模型,与文献中的其他模型相比,该模型更全面,更具代表性。
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引用次数: 1
Autonomous Control of Well Downtime to Optimize Production and Cycling in Sucker Rod Pump Artificially Lifted Wells 有杆泵人工举升井自动停机控制优化生产和循环
Pub Date : 2021-09-15 DOI: 10.2118/206236-ms
I. Nickell, Terry Treiberg
For decades sucker rod pump artificially lifted wells have used devices called pump off controllers (POC) to match the pumping unit's runtime to the available reservoir production by idling the well for a set time where variable frequencies drives are not available. In doing this the POC allows the well to enter a set period of downtime when the downhole pump fillage is incomplete to avoid premature failures, and then brings the well back online to operate before production is lost. Although this method has been successful for several years, autonomous control algorithms can be utilized to reduce failures or increase production in cases where the downtime is not already optimized. Optimizing the idle time for a sucker rod pump artificially lifted well involves understanding the amount of time required to fill the near wellbore storage area before generating a fluid column above the pump intake that will begin to hinder inflow from the reservoir into the wellbore. By varying the idle time and observing the impact on production and cycles the program hunts for the optimal idle time. By constantly hunting for the optimal idle time the optimization process can adjust the idle time when operating conditions change. This gives the advantage of always meeting the current well bore and reservoir conditions without having to have a user make these changes and determine what the downtime for the well is. Autonomously modulating the idle time for a well, if done properly will either reduces incomplete fillage pump strokes, in cases where the idle time is too short, or will increase the wells production in cases where the idle time is too long. Overall this will result in the optimization of wells by reducing failures and/or increasing production, generating a huge value to the end user by automating the entire process of downtime optimization.
几十年来,有杆泵人工举升井一直使用一种叫做泵停控制器(POC)的设备,通过在没有变频驱动的情况下空转一段时间,将抽油机的运行时间与可用的油藏产量相匹配。这样,POC可以在井下泵充填不完全的情况下进入一段固定的停机时间,以避免过早失效,然后在生产损失之前将井恢复在线运行。虽然这种方法已经成功了好几年,但在没有优化停机时间的情况下,自主控制算法可以用来减少故障或增加产量。优化有杆泵人工举升井的空闲时间,需要了解在泵进水口上方形成流体柱之前填满近井储存区所需的时间,这将开始阻碍从油藏流入井筒的流体。通过改变空闲时间并观察对生产和周期的影响,程序寻找最佳空闲时间。通过不断寻找最佳空闲时间,优化过程可以在操作条件变化时调整空闲时间。这样做的优点是可以满足当前井眼和油藏条件,而无需用户进行这些更改并确定井的停机时间。自动调节井的闲置时间,如果操作得当,在闲置时间过短的情况下,可以减少不完全填充泵冲程,或者在闲置时间过长的情况下,可以增加油井产量。总的来说,这将通过减少故障和/或增加产量来优化油井,通过自动化整个停机优化过程,为最终用户创造巨大的价值。
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引用次数: 0
Formation Characterization and Production Forecast of Tight Sandstone Formations in Daqing Oilfield Through Digital Rock Technology 基于数字岩石技术的大庆油田致密砂岩储层表征及产量预测
Pub Date : 2021-09-15 DOI: 10.2118/206055-ms
D. Zhang, Xiao-xing Shi, Chunyan Qi, Jianfei Zhan, Xue Han, D. Klemin
With the decline of conventional resources, the tight oil reserves in the Daqing oilfield are becoming increasingly important, but measuring relative permeability and determining production forecasts through laboratory core flow tests for tight formations are both difficult and time consuming. Results of laboratory testing are questionable due to the very small pore volume and low permeability of the reservoir rock, and there are challenges in controlling critical parameters during the special core analysis (SCAL) tests. In this paper, the protocol and workflow of a digital rock study for tight sandstones of the Daqing oilfield are discussed. The workflow includes 1) using a combination of various imaging methods to build rock models that are representative of reservoir rocks, 2) constructing digital fluid models of reservoir fluids and injectants, 3) applying laboratory measured wettability index data to define rock-fluid interaction in digital rock models, 4) performing pore-scale modelling to accelerate reservoir characterization and reduce the uncertainty, and 5) performing digital enhanced oil recovery (EOR) tests to analyze potential benefits of different scenarios. The target formations are tight (0.01 to 5 md range) sandstones that have a combination of large grain sizes juxtaposed against small pore openings which makes it challenging to select an appropriate set of imaging tools. To overcome the wide range of pore and grain scales, the imaging tools selected for the study included high resolution microCT imaging on core plugs and mini-plugs sampled from original plugs, overview scanning electron microscopy (SEM) imaging, mineralogical mapping, and high-resolution SEM imaging on the mini-plugs. High resolution digital rock models were constructed and subsequently upscaled to the plug level to differentiate bedding and other features could be differentiated. Permeability and porosity of digital rock models were benchmarked against laboratory measurements to confirm representativeness. The laboratory measured Amott-Harvey wettability index of restored core plugs was honored and applied to the digital rock models. Digital fluid models were built using the fluid PVT data. A Direct HydroDynamic (DHD) pore-scale flow simulator based on density functional hydrodynamics was used to model multiphase flow in the digital experiments. Capillary pressure, water-oil, surfactant solution-oil, and CO2-oil relative permeability were computed, as well as primary depletion followed with three-cycle CO2 huff-n-puff, and primary depletion followed with three-cycle surfactant solution huff-n-puff processes. Recovery factors were obtained for each method and resulting values were compared to establish most effective field development scenarios. The workflow developed in this paper provides fast and reliable means of obtaining critical data for field development design. Capillary pressure and relative permeability data obtained through digital experiments
随着常规资源的日益减少,大庆油田致密油储量的重要性日益突出,但致密储层相对渗透率的测定和室内岩心流动试验的产量预测既困难又耗时。由于储层岩石孔隙体积非常小,渗透率很低,实验室测试结果存在问题,在特殊岩心分析(SCAL)测试中,关键参数的控制存在挑战。本文讨论了大庆油田致密砂岩数字化岩石研究的方案和工作流程。工作流程包括:1)结合各种成像方法建立具有代表性的储层岩石模型;2)建立储层流体和注入剂的数字流体模型;3)应用实验室测量的润湿性指数数据来定义数字岩石模型中的岩石-流体相互作用;4)进行孔隙尺度建模以加速储层表征并降低不确定性。5)进行数字提高采收率(EOR)测试,分析不同方案的潜在效益。目标地层为致密砂岩(0.01 ~ 5 md范围内),具有大粒度和小孔径的组合,这使得选择一套合适的成像工具具有挑战性。为了克服大范围的孔隙和颗粒尺度,研究中选择的成像工具包括对岩心桥塞和原始桥塞取样的小桥塞进行高分辨率微ct成像,扫描电子显微镜(SEM)成像,矿物学成像以及小桥塞的高分辨率SEM成像。建立了高分辨率的数字岩石模型,随后将其升级到堵头水平,以区分层理和其他特征。将数字岩石模型的渗透率和孔隙度与实验室测量结果进行基准比对,以确定其代表性。实验室测量了修复岩心桥塞的amot - harvey润湿性指数,并将其应用于数字岩石模型。利用流体PVT数据建立了数字流体模型。采用基于密度泛函流体力学的直接流体动力学(DHD)孔隙尺度流动模拟器对多相流进行了数值模拟实验。计算毛细压力、水-油、表面活性剂溶液-油和CO2-油相对渗透率,并计算了一次衰竭后的三循环CO2吞吐过程,以及一次衰竭后的三循环表面活性剂溶液吞吐过程。获得了每种方法的采收率,并对结果进行了比较,以确定最有效的油田开发方案。本文提出的工作流程为油田开发设计提供了快速可靠的关键数据获取手段。通过数字实验获得的毛管压力和相对渗透率数据为储层模拟提供了关键输入参数;生产情景预测有助于评估各种提高采收率方法。数字模拟允许在相同的岩石样本上多次运行不同的场景,这在实验室是不可能的。
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引用次数: 0
A Back Allocation Methodology to Estimate the Real-Time Flow and Assist Production Monitoring 一种估算实时流量和辅助生产监控的逆向分配方法
Pub Date : 2021-09-15 DOI: 10.2118/205916-ms
G. Chaves, D. D. Monteiro, Virgílio José Martins Ferreira
Commingle production nodes are standard practice in the industry to combine multiple segments into one. This practice is adopted at the subsurface or surface to reduce costs, elements (e.g. pipes), and space. However, it leads to one problem: determine the rates of the single elements. This problem is recurrently solved in the platform scenario using the back allocation approach, where the total platform flowrate is used to obtain the individual wells’ flowrates. The wells’ flowrates are crucial to monitor, manage and make operational decisions in order to optimize field production. This work combined outflow (well and flowline) simulation, reservoir inflow, algorithms, and an optimization problem to calculate the wells’ flowrates and give a status about the current well state. Wells stated as unsuited indicates either the input data, the well model, or the well is behaving not as expected. The well status is valuable operational information that can be interpreted, for instance, to indicate the need for a new well testing, or as reliability rate for simulations run. The well flowrates are calculated considering three scenarios the probable, minimum and maximum. Real-time data is used as input data and production well test is used to tune and update well model and parameters routinely. The methodology was applied using a representative offshore oil field with 14 producing wells for two-years production time. The back allocation methodology showed robustness in all cases, labeling the wells properly, calculating the flowrates, and honoring the platform flowrate.
混合生产节点是将多个部分组合成一个的行业标准实践。这种做法在地下或地面采用,以减少成本、元件(如管道)和空间。然而,它导致了一个问题:确定单个元素的速率。在平台场景中,这个问题经常使用回分配方法来解决,其中使用平台总流量来获得单口井的流量。为了优化油田生产,井的流量对于监测、管理和制定作业决策至关重要。该工作结合了流出(井和管线)模拟、油藏流入、算法和优化问题来计算井的流量,并给出了当前井的状态状态。不适合井表示输入数据、井模型或井的行为不符合预期。井的状态是有价值的操作信息,可以进行解释,例如,指示是否需要进行新井测试,或者作为模拟运行的可靠性。井流量的计算考虑了三种情况:可能、最小和最大。实时数据作为输入数据,生产井测试用于常规调整和更新井模型和参数。以某代表性海上油田14口生产井为例,进行了2年的生产实践。反向分配方法在所有情况下都显示出鲁棒性,正确标记井,计算流量,并尊重平台流量。
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引用次数: 0
Message-Passing-Interface MPI Parallelization of Iteratively Coupled Fluid Flow and Geomechanics Codes for the Simulation of System Behavior in Hydrate-Bearing Geologic Media 含水地质介质中流体流动与地质力学迭代耦合代码的消息传递接口MPI并行化模拟
Pub Date : 2021-09-15 DOI: 10.2118/206161-ms
Jiecheng Zhang, G. Moridis, T. Blasingame
The Reservoir GeoMechanics Simulator (RGMS), a geomechanics simulator based on the finite element method and parallelized using the Message Passing Interface (MPI), is developed in this work to model the stresses and deformations in subsurface systems. RGMS can be used stand-alone, or coupled with flow and transport models. pT+H V1.5, a parallel MPI-based version of the serial T+H V1.5 code that describes mass and heat flow in hydrate-bearing porous media, is also developed. Using the fixed-stress split iterative scheme, RGMS is coupled with the pT+H V1.5 to investigate the geomechanical responses associated with gas production from hydrate accumulations. The code development and testing process involve evaluation of the parallelization and of the coupling method, as well as verification and validation of the results. The parallel performance of the codes is tested on the Ada Linux cluster of the Texas A&M High Performance Research Computing using up to 512 processors, and on a Mac Pro computer with 12 processors. The investigated problems are: Group 1: Geomechanical problems solved by RGMS in 2D Cartesian and cylindrical domains and a 3D problem, involving 4x106 and 3.375 x106 elements, respectively; Group 2: Realistic problems of gas production from hydrates using pT+H V1.5 in 2D and 3D systems with 2.45x105 and 3.6 x106 elements, respectively; Group 3: The 3D problem in Group 2 solved with the coupled RGMS-pT+H V1.5 simulator, fully accounting for geomechanics. Two domain partitioning options are investigated on the Ada Linux cluster and the Mac Pro, and the code parallel performance is monitored. On the Ada Linux cluster using 512 processors, the simulation speedups (a) of RGMS are 218.89, 188.13, and 284.70 in the Group 1 problems, (b) of pT+H V1.5 are 174.25 and 341.67 in the Group 2 cases, and (c) of the coupled simulators is 331.80 in Group 3. The results produced in this work show the necessity of using full geomechanics simulators in marine hydrate-related studies because of the associated pronounced geomechanical effects on production and displacements and (b) the effectiveness of the parallel simulators developed in this study, which can be the only realistic option in these complex simulations of large multi-dimensional domains.
储层地质力学模拟器(RGMS)是一种基于有限元方法并使用消息传递接口(MPI)并行化的地质力学模拟器,用于模拟地下系统的应力和变形。RGMS可以单独使用,也可以与流和传输模型结合使用。pT+H V1.5是一种基于mpi的并行T+H V1.5代码,用于描述含水合物多孔介质中的质量和热流。使用固定应力分裂迭代方案,RGMS与pT+H V1.5相结合,研究与水合物聚集产气相关的地质力学响应。代码开发和测试过程包括对并行化和耦合方法的评估,以及对结果的验证和确认。在Texas A&M High performance Research Computing的Ada Linux集群(多达512个处理器)和Mac Pro计算机(12个处理器)上测试了代码的并行性能。研究的问题包括:第1组:RGMS在二维笛卡尔和圆柱域中解决的地质力学问题,以及一个三维问题,分别涉及4x106和3.375 x106个单元;第2组:pT+H V1.5在2D和3D体系(分别为2.45x105和3.6 x106元素)中产气的现实问题;第3组:第2组的三维问题采用RGMS-pT+H V1.5耦合模拟器解决,充分考虑了地质力学。在Ada Linux集群和Mac Pro上研究了两种域分区选项,并对代码并行性能进行了监控。在使用512个处理器的Ada Linux集群上,RGMS在第1组问题中的仿真加速(a)分别为218.89、188.13和284.70,pT+H V1.5在第2组问题中的仿真加速(b)分别为174.25和341.67,耦合模拟器在第3组中的仿真加速(c)分别为331.80。这项工作产生的结果表明,在海洋水合物相关研究中使用完整的地质力学模拟器是必要的,因为相关的地质力学对产量和位移有明显的影响,并且(b)本研究中开发的并行模拟器的有效性,这可能是这些大型多维域复杂模拟中唯一现实的选择。
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引用次数: 1
Economic Evaluation of CO2 Capture, Transportation, and Storage Potentials in Oklahoma 俄克拉何马州二氧化碳捕获、运输和储存潜力的经济评估
Pub Date : 2021-09-15 DOI: 10.2118/206106-ms
J. Daneshfar, D. Nnamdi, R. Moghanloo, K. Ochie
Oklahoma is known for having ample sources of CO2, pipelines and sinks where for many decades, oil and gas operators were injecting CO2 into geological formations for EOR purposes. We utilized SimCCS, an economic-engineering software tool (DOE-NETL), to integrate infrastructure related to CO2 sources, pipeline, and geological formations. The approved tax incentive program by IRS (45Q) has motivated many oil and gas operators to participate in reducing CO2 concentration and minimizing global warming effect by collecting CO2 from various sources, select the best pipeline route and the safest location to inject into geological formation for EOR purpose or deep saline aquifer for sequestration. This paper presents an economic evaluation of CO2 capture, utilization, storage (CCUS) into geological formation in the state of Oklahoma. Under this comprehensive approach, the process of capturing, transporting, and storing CO2 into geological or saline formations has been economically evaluated for different sites and routes utilizing an ad hoc simulation software (SimCCS) for integrated modeling of CCUS. The outcome of this paper determines the most optimal scenario using optimization algorithms embedded in SimCCS. This case study will mitigate the CO2 sequestration approval process when operator apply for tax credit under 45Q program. Our work will assist oil and gas operators by comparing different scenarios based on utilizing existing infrastructure, making decision in building new transportation system or new injection well to benefit the approved tax incentive program at its maximum capacity. Moreover, the outcome of this work will shed lights into future legislation demands (locally and nation-wide) to maintain CCUS momentum after its initial implementation phase is concluded.
俄克拉荷马州以其丰富的二氧化碳来源、管道和汇而闻名,几十年来,石油和天然气运营商一直将二氧化碳注入地质地层中以提高采收率。我们利用经济工程软件工具(DOE-NETL) SimCCS整合了与二氧化碳源、管道和地质构造相关的基础设施。美国国税局(IRS)批准的税收激励计划(45Q)激励了许多油气运营商参与降低二氧化碳浓度,最大限度地减少全球变暖效应,通过从各种来源收集二氧化碳,选择最佳管道路线和最安全的位置,将二氧化碳注入地质地层以提高采收率或深层盐层进行封存。本文介绍了俄克拉何马州地质地层二氧化碳捕集、利用、封存(CCUS)的经济评价。在这种综合方法下,利用特设模拟软件(SimCCS)对CCUS进行综合建模,对不同地点和路线的二氧化碳捕获、运输和储存过程进行了经济评估。本文的结果利用SimCCS中嵌入的优化算法确定了最优的场景。当运营商根据45Q计划申请税收抵免时,本案例研究将简化二氧化碳封存的审批过程。我们的工作将通过比较不同的方案来帮助油气运营商利用现有的基础设施,决定建立新的运输系统或新的注入井,以最大限度地利用已批准的税收激励计划。此外,这项工作的结果将有助于在初始实施阶段结束后,在地方和全国范围内保持CCUS势头的未来立法需求。
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引用次数: 3
Numerical Mechanistic Study of In-Situ CO2 EOR – Kinetics and Recovery Performance Analysis CO2原位提高采收率数值机理研究——动力学与采收率分析
Pub Date : 2021-09-15 DOI: 10.2118/206292-ms
S. Hussain, Xingru Wu, B. Shiau
The success of supercritical CO2 Enhanced Oil Recovery (EOR) cannot be duplicated if the cost of CO2 transposition and processing becomes prohibitive. Research results of the in-situ CO2 EOR (ICE) approach offered a potential technology for many waterflooded stripper wells that lack access to affordable CO2 sources. Previously the ICE synergetic mechanisms were only qualitatively attributed to oil swelling and viscosity reduction due to the preferential partition of CO2 into the oleic phase. This study aims to quantify the contributions to recovery factors from several plausible mechanisms with numerical modeling and simulation. First, the urea reaction was modeled as the CO2 generating chemical decomposing to CO2 and ammonia in the reservoir conditions. The CO2 partitions into oil, which leads to the reaction continuation to generate more CO2. The resulting ammonia largely left in water may further react with certain crudes to generate surfactants, thus, decrease the oil/water interfacial tension (IFT). It is expected that the oil containing CO2 also has a lower IFT with water. The reaction kinetics under different temperatures were incorporated into the numerical model. A numerical model featuring the synergetic mechanisms was built including stoichiometry and kinetics of urea reaction, oil swelling effect, oil viscosity reduction, and IFT reduction effect on the relative permeabilities. The laboratory experiments, pore volume injection versus oil saturation were history matched for three different oils including Dodecane, Earlsboro oil, and DeepStar oil. The phase behavior was modeled with the equation of state (EOS) under different mole fractions of CO2. The reaction kinetics were also modified to history match the laboratory experiment. The estimated reduction of oil viscosity was calculated, 76% for Earlsboro oil, 91% in DeepStar oil, and 75% in dodecane oil. The oil swelling factors ranged from 1.60% to 19% in the three lab models, which translates to the recovery factor of oil. The endpoints of relative permeability were modified to account for the recovery contribution to the IFT and viscosity reduction. The impact of reaction kinetics on oil swelling and recovery factor was also determined, and they are not numerically close to reaction kinetics used in the lab cases. The matched reaction kinetics, activation energy and reaction frequency factor for the dodecane laboratory experiment were 91.80 kJ/gmol and 6.5E+09 min−1. The study concluded that the incremental recovery due to oil swelling ranges between 3.16% and 18.30%, and then from 12.91% to 41.59% is due to IFT reduction for all the cases. The relative permeability and urea reaction kinetics remained the most uncertain parameters during history matching and modeling the ICE synergetic mechanisms.
如果二氧化碳转换和处理的成本过高,超临界二氧化碳提高采收率(EOR)的成功就无法复制。原位CO2 EOR (ICE)方法的研究成果为许多无法获得廉价CO2源的水淹低产井提供了一种潜在的技术。在此之前,人们只定性地将ICE的协同机制归结为由于CO2优先分配到油相而导致的油膨胀和粘度降低。本研究旨在通过数值模拟和模拟来量化几种可能的机制对采收率因子的贡献。首先,将尿素反应建模为储层条件下产生的CO2化学分解为CO2和氨。二氧化碳分解成油,导致反应继续产生更多的二氧化碳。大部分留在水中的氨可能会进一步与某些原油反应生成表面活性剂,从而降低油水界面张力(IFT)。预计含CO2的油与水的IFT也较低。将不同温度下的反应动力学纳入数值模型。建立了尿素反应化学计量学和动力学、油溶胀效应、油粘度降低和IFT降低对相对渗透率的影响等协同机理的数值模型。在实验室实验中,对Dodecane、Earlsboro和DeepStar三种不同的油进行了孔隙体积注入与油饱和度的历史匹配。用状态方程(EOS)模拟了不同CO2摩尔分数下的相行为。对反应动力学进行了修正,使其符合实验室实验。计算结果表明,Earlsboro油的粘度降低率为76%,DeepStar油为91%,十二烷油为75%。三种实验模型的油膨胀系数范围为1.60% ~ 19%,即油的采收率。对相对渗透率的端点进行了修改,以考虑采收率对IFT和粘度降低的贡献。反应动力学对油膨胀和采收率的影响也被确定,它们与实验室案例中使用的反应动力学在数值上并不接近。十二烷实验室实验的反应动力学、活化能和反应频率因子分别为91.80 kJ/gmol和6.5E+09 min−1。研究得出结论,在所有情况下,油膨胀导致的采收率增量在3.16% ~ 18.30%之间,而IFT降低导致的采收率增量在12.91% ~ 41.59%之间。相对渗透率和尿素反应动力学是历史拟合和模拟ICE协同机理时最不确定的参数。
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引用次数: 0
Integrating XRD and Well Logging Data to Establish Electro-Facies and Permeability Models for an Unconventional Heterogeneous Tight Gas Reservoir, Obaiyed Giant Gas Field 结合XRD和测井数据建立非常规非均质致密气藏电相及渗透率模型
Pub Date : 2021-09-15 DOI: 10.2118/208626-stu
I. Mabrouk
Formation evaluation in heterogeneous reservoirs can be very challenging especially in fields that extend over several kilometers in area where the permeability varies from 0.1 mD up to 1000 D within the same porosity. The porosity, hydrocarbon saturation and net sand thickness in most of Obaiyed field wells are consistent; hence, the productivity of these wells is enormously dependent on the reservoir permeability. Since the permeability is highly heterogeneous, initial production rate of the wells varies between few MMSCFD to almost one hundred MMSCFD. The huge permeability variation led to a tremendous uncertainty in the dynamic modeling, which resulted in an inaccurate production forecast affecting the field economics estimation. Understanding permeability distribution and heterogeneity in Obaiyed field is the key factor for establishing a realistic permeability model, which will lead to a successful field development strategy. Extensive work was performed to understand key factors that govern the permeability in Obaiyed using the data of 1-kilometer length of cores acquired in more than 50 wells covering different reservoir properties in the field. Core data were used to separate the reservoir into different Hydraulic Flow Units (HFU) according to Amaefule's work performed on the Kozeny-Carmen model. Afterwards, a correlation between the HFU and well logs was established using IPSOM Electro-Facies module in order to define the flow units in un-cored wells. The result of this correlation was used to calibrate a Porosity-Permeability relationship for each flow unit. The next step was examining the clay-type distribution and diagenesis in each flow unit using the petrographic analysis (XRD) results from the core xdata. All factors controlling the permeability can now be represented in hydraulic flow units which are considered as a method of measurement of the reservoir quality. Consequently, property maps were constructed showing the location and continuity of each of the flow units, leading to a more deterministic approach in the well placement process. Based on this new work methodology, a production cut-off criteria relating the reservoir productivity to both clay minerals presence and percentages was established for multiple wells scenarios. As a result, the development strategy of the field changed from only vertical wells to include horizontal wells as well which proved to be the only economic approach to produce the Illite dominated zones. This paper presents a workflow to provide a representative estimation of permeability in extremely heterogeneous reservoirs especially the ones dominated by complex clay distribution.
非均质储层的储层评价是非常具有挑战性的,特别是在渗透率从0.1 mD到1000 D不等,延伸数公里的油田。大部分油田井的孔隙度、含油饱和度和净砂厚度基本一致;因此,这些井的产能很大程度上取决于储层渗透率。由于渗透率是高度非均匀的,因此井的初始产量在几MMSCFD到近100 MMSCFD之间变化。巨大的渗透率变化导致动态建模存在很大的不确定性,导致产量预测不准确,影响油田经济效益评价。了解目标油田的渗透率分布和非均质性是建立符合实际的渗透率模型的关键因素,这将有助于制定成功的油田开发策略。为了了解影响Obaiyed渗透率的关键因素,研究人员进行了大量工作,使用了50多口井1公里长的岩心数据,覆盖了油田不同的储层性质。根据Amaefule在Kozeny-Carmen模型上所做的工作,利用岩心数据将储层划分为不同的水力流量单元(HFU)。随后,使用IPSOM电相模块建立HFU与测井曲线之间的相关性,以确定未取心井的流动单元。这种相关性的结果被用来校准每个流动单元的孔隙度-渗透率关系。下一步是使用岩心xdata的岩石学分析(XRD)结果检查每个流动单元中的粘土类型分布和成岩作用。控制渗透率的所有因素现在都可以用水力流量单位表示,水力流量单位被认为是测量储层质量的一种方法。因此,构建了属性图,显示了每个流动单元的位置和连续性,从而在排井过程中提供了更确定的方法。基于这种新的工作方法,建立了一个将储层产能与粘土矿物存在和百分比联系起来的生产截止标准,适用于多口井。因此,该油田的开发策略从只开发直井转变为同时开发水平井,这被证明是开采伊利石占主导地位的唯一经济途径。本文提出了一种具有代表性的非均质储层渗透率估算方法,特别是以复杂粘土分布为主的储层渗透率估算方法。
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引用次数: 0
Analytical Solutions for the Injection of Wettability Modifiers in Carbonate Reservoirs Based on a Reduced Surface Complexation Model 基于表面简化络合模型的碳酸盐岩储层润湿性改进剂注入解析解
Pub Date : 2021-09-15 DOI: 10.2118/206088-ms
Ricardo A. Lara Orozco, R. Okuno, L. Lake
The potential of tuned-composition waterflooding to enhance oil recovery from carbonate reservoirs has been widely investigated in the literature. The consensus is that wettability alteration occurs because of the electrostatic interactions between the carbonate rock surface and the potential determining ions, Ca2+, Mg2+, CO32−, and SO42−. Recently, glycine, the simplest amino acid, has also been investigated as a wettability modifier for carbonates that acts similarly as the sulfate ions in brine. The impact of wettability modifiers like glycine and calcite's potential determining ions has been described by surface complexation models (SCM) and the wetting-state of the rock has been related to change of the surface potential. However, determining the relevance of the geochemical reactions is obstructed by the complexity of the SCM. Moreover, the surface potential as a surrogate of the wetting-state of the rock does not correlate with the experimental results with glycine reported in the literature. The present research analyzed the results of single-phase displacement using a SCM for calcite to determine the important surface complexation reactions. Then, wettability alteration is modeled as a set of anion exchange reactions between wettability modifiers, like SO42− and Gly−, and adsorbed carboxylic acids. Finally, analytical solutions are presented for the coupled two-phase and multicomponent reactive-transport model with anion exchange reactions.
调成分水驱提高碳酸盐岩油藏采收率的潜力已经在文献中得到了广泛的研究。一致认为,润湿性变化的发生是由于碳酸盐岩表面与电位决定离子Ca2+、Mg2+、CO32−和SO42−之间的静电相互作用。最近,甘氨酸作为最简单的氨基酸,也被研究作为碳酸盐的润湿性改性剂,其作用类似于盐水中的硫酸盐离子。通过表面络合模型(SCM)描述了甘氨酸和方解石等润湿性调节剂对岩石润湿性的影响,并将润湿性与表面电位的变化联系起来。然而,地球化学反应相关性的确定受到SCM复杂性的阻碍。此外,表面电位作为岩石润湿状态的替代品与文献中报道的甘氨酸实验结果不相关。本研究利用单片机对方解石的单相置换结果进行了分析,确定了重要的表面络合反应。然后,将润湿性变化建模为润湿性改性剂(如SO42 -和Gly -)与吸附的羧酸之间的一系列阴离子交换反应。最后,给出了具有阴离子交换反应的两相多组分反应输运耦合模型的解析解。
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引用次数: 0
Mitigation of High Temperature Challenges in Limestone Acidizing through the use of Chelating Agents 通过使用螯合剂缓解石灰石酸化过程中的高温挑战
Pub Date : 2021-09-15 DOI: 10.2118/206039-ms
Mandeep Khan, M. Qamruzzaman, D. Roy, R. Raman
Acid jobs with conventional acid systems like hydrochloric acid in high temperature conditions is challenging on various fronts. Enhanced reactivity of strong acids results in poor penetration and severe face dissolution. Also, it aggravates the issue of corrosion of downhole equipment and may also result in sludge formation/asphaltene deposition. Worldwide, chelating agents has emerged as a standalone stimulation fluid for high temperature acidizing. Their unique attributes and properties have been proved very useful for acid jobs at elevated temperatures. However, the chelating agents-based formulations need to be carefully evaluated on various acidization parameters for a fruitful stimulation. Mumbai Offshore field has been encountering the above-mentioned problems in acidizing of its high temperature (>275°F) limestone reservoirs. The paper presents innovative solutions devised for high temperature matrix acidizing. Two chelating agents viz., EDTA (Ethylenediaminetetraceticacid) and GLDA (L-Glutamic Acid N, N-diacetic acid) were explored and evaluated with meticulous laboratory studies. The performance of the chelating agent-based stimulation fluid was compared with acetic acid. Slurry tests were performed to quantify the dissolving power of each acid. Consequently, core flooding tests were carried out to to find the optimum pH of the chelating agents from stimulation point of view. Core flooding studies were performed at anticipated injection rates on representative core samples from a payzone A, with BHT 275-290° F, from Mumbai Offshore. pH optimized formulations were tested against N-80 metallurgy coupons at reservoir temperature for corrosion potential estimation. Also, sludge, asphaltene and emulsion formation tendencies were analyzed with representative oil samples. The results convey that both EDTA and GLDA were able to mitigate the challenges encountered at elevated temperatures. EDTA and GLDA were found to stimulate the cores with wormholes formed at wide pH range with no face dissolution observed. Chelating agents enjoyed good dissolving power with negligible corrosion rates, absence of sludge and asphaltene deposition, compatibility with formation fluid and excellent iron control properties.
在高温条件下,使用盐酸等传统酸系统进行酸作业在各个方面都具有挑战性。强酸增强的反应性导致渗透不良和严重的表面溶解。此外,它还会加剧井下设备的腐蚀问题,并可能导致污泥形成/沥青质沉积。在世界范围内,螯合剂已成为高温酸化的独立增产液。它们独特的特性和性质已被证明对高温下的酸作业非常有用。然而,为了获得有效的增产效果,需要仔细评估基于螯合剂的配方的各种酸化参数。孟买海上油田在高温(> - 275°F)石灰石储层酸化过程中一直遇到上述问题。本文提出了针对高温基质酸化的创新解决方案。两种螯合剂即EDTA(乙二胺四乙酸)和GLDA (l -谷氨酸N, N-二乙酸)进行了细致的实验室研究和评估。将螯合剂基增产液的性能与乙酸进行了比较。进行浆料试验以量化每种酸的溶解能力。因此,进行岩心驱替试验,从增产角度寻找螯合剂的最佳pH值。对孟买近海a产层的代表性岩心样品进行了岩心驱油研究,BHT为275-290°F。在储层温度下,对pH优化后的配方进行了N-80冶金粉的腐蚀电位测试。并用代表性油样分析了油泥、沥青质和乳化液的形成趋势。结果表明,EDTA和GLDA都能够缓解高温下遇到的挑战。EDTA和GLDA在较宽的pH范围内刺激岩心形成虫孔,没有观察到表面溶解。螯合剂具有良好的溶解能力,腐蚀速率可忽略不计,没有污泥和沥青质沉积,与地层流体的相容性以及优异的铁控制性能。
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引用次数: 2
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