首页 > 最新文献

Day 4 Thu, March 21, 2019最新文献

英文 中文
Enhanced Hydraulic Modeling and Event Detection Using Real-Time Fluid Properties and Fluid Position Tracking Software 使用实时流体特性和流体位置跟踪软件增强的液压建模和事件检测
Pub Date : 2019-03-15 DOI: 10.2118/194812-MS
Aidan Porter, Vivek Lie, J. S. Gollapalli
Replicating downhole conditions using real-time software helps reduce nonproductive time. Hydraulic outputs trend against sensor outputs, enabling event detection. Using real-time fluid properties with fluid tracking hydraulic software helps improve predictions for comparison, enabling faster and more reliable detection of downhole conditions. Two instances of real-time hydraulics simulators capable of tracking property changes of fluid and the positions of discrete fluid volumes within the wellbore were used. One simulator was used with a real-time fluid properties apparatus that provided full six-speed rheology and fluid density in real time. The second simulator used fluid updates provided by the mud engineer on location. The calculated equivalent circulating density (ECD) and predicted standpipe pressure (SPP) from the hydraulics software was compared to actual pressure while drilling (PWD) and measured SPP sensor outputs. The real-time fluid apparatus provided real-time rheology and density values consistently while drilling the section, and data was provided directly to the hydraulics simulator. Comparing ECD predictions with and without the real-time fluid properties made it possible to identify any improvements achieved using such equipment. Although both sets of data showed that the hydraulics simulator was highly accurate, using real-time fluid inputs enabled ECD predictions to trend considerably closer to the PWD measurements. The capability of tracking the predicted ECD against actual sensor outputs enables users to quickly determine deviations in sensor outputs associated with downhole conditions and to observe deviations occurring as a result of inconsistencies within the fluid system. Data presented in this paper are taken from some of the first global deployments of real-time fluid properties measurement equipment used in conjunction with real-time hydraulics software.
使用实时软件复制井下状况有助于减少非生产时间。液压输出趋势与传感器输出,实现事件检测。将实时流体特性与流体跟踪液压软件结合使用,有助于改进预测对比,实现更快、更可靠的井下状况检测。使用了两个能够跟踪流体性质变化和井筒内离散流体体积位置的实时液压模拟器实例。其中一个模拟器与实时流体特性仪一起使用,可以实时提供全六速流变学和流体密度。第二个模拟器使用泥浆工程师在现场提供的流体更新。将水力软件计算出的等效循环密度(ECD)和预测立管压力(SPP)与钻井时的实际压力(PWD)和测量的SPP传感器输出进行比较。实时流体仪器在钻井过程中持续提供实时流变学和密度值,数据直接提供给液压模拟器。通过比较有无实时流体性质的ECD预测,可以确定使用此类设备所取得的任何改进。虽然两组数据都表明液压模拟器非常精确,但使用实时流体输入可以使ECD预测更加接近PWD测量结果。根据实际传感器输出跟踪预测ECD的能力,使用户能够快速确定与井下条件相关的传感器输出偏差,并观察由于流体系统内部不一致而产生的偏差。本文中提供的数据来自于第一次全球部署的实时流体特性测量设备,该设备与实时液压软件一起使用。
{"title":"Enhanced Hydraulic Modeling and Event Detection Using Real-Time Fluid Properties and Fluid Position Tracking Software","authors":"Aidan Porter, Vivek Lie, J. S. Gollapalli","doi":"10.2118/194812-MS","DOIUrl":"https://doi.org/10.2118/194812-MS","url":null,"abstract":"\u0000 Replicating downhole conditions using real-time software helps reduce nonproductive time. Hydraulic outputs trend against sensor outputs, enabling event detection. Using real-time fluid properties with fluid tracking hydraulic software helps improve predictions for comparison, enabling faster and more reliable detection of downhole conditions.\u0000 Two instances of real-time hydraulics simulators capable of tracking property changes of fluid and the positions of discrete fluid volumes within the wellbore were used. One simulator was used with a real-time fluid properties apparatus that provided full six-speed rheology and fluid density in real time. The second simulator used fluid updates provided by the mud engineer on location. The calculated equivalent circulating density (ECD) and predicted standpipe pressure (SPP) from the hydraulics software was compared to actual pressure while drilling (PWD) and measured SPP sensor outputs.\u0000 The real-time fluid apparatus provided real-time rheology and density values consistently while drilling the section, and data was provided directly to the hydraulics simulator. Comparing ECD predictions with and without the real-time fluid properties made it possible to identify any improvements achieved using such equipment. Although both sets of data showed that the hydraulics simulator was highly accurate, using real-time fluid inputs enabled ECD predictions to trend considerably closer to the PWD measurements. The capability of tracking the predicted ECD against actual sensor outputs enables users to quickly determine deviations in sensor outputs associated with downhole conditions and to observe deviations occurring as a result of inconsistencies within the fluid system.\u0000 Data presented in this paper are taken from some of the first global deployments of real-time fluid properties measurement equipment used in conjunction with real-time hydraulics software.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"231 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74473969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Perforation Damage, Cleanup, and Inflow Performance: Advances in Diagnostics and Characterization 射孔损害、清理和流入性能:诊断和表征的进展
Pub Date : 2019-03-15 DOI: 10.2118/195019-MS
B. Grove, A. Grader, N. Derzhi, J. McGregor
Considering the important role that perforation laboratory testing can play in establishing field completion strategies, and thus ultimately well performance, efforts are currently underway to further strengthen the link between laboratory results and field well performance predictions. Some of these efforts focus on integrating advanced diagnostic and computational tools (namely computed tomography (CT), and pore-scale flow simulation) into the perforation testing workflow. This integration enables local variations in permeability and porosity to be identified and quantified, thus improving the interpretation of perforation laboratory results, and ultimately the translation of these results to the downhole environment. CT techniques have been used for core analysis, characterization, and flow visualization since the early 1980s. By the early 1990s, these techniques were being applied to the investigation of laboratory-perforated cores to enhance the interpretation of tests conducted following API RP19B Section 2 or 4. This application has increased dramatically since 2012, following the installation of a CT scanning system on-site at a perforating laboratory facility. As a result, this non-destructive technique has become a preferred method to routinely characterize perforation tunnels and the surrounding rock, as well as to enable the repeated inspection of a perforated core at multiple steps throughout a test sequence designed to mimic field operations scenarios. Coinciding with this development has been the advancement and application of micro-CT technology to better understand pore-scale phenomena, both near and away from the perforation. This paper introduces an integrated test program currently underway and summarizes key results from two experiments in which stressed rock targets were perforated under significantly different conditions. The first experiment involved perforating a moderate strength sandstone core under conditions that retained substantially all perforation damage, thus preserving the "crushed zone". Micro-CT analysis of different locations within the crushed zone region revealed significant compaction, with porosity reductions ranging from 10 to 50% below that of the native rock. Permeability at one of these selected locations was determined and found to be reduced by approximately 35% below the native rock value. The second experiment involved perforating a very high-strength sandstone core under conditions intended to produce full cleanup. CT and micro-CT analysis revealed fine fractures near the tunnel tip and confirmed the near-complete removal of the perforation damage, with only a very thin (less than 1 mm) compacted zone remaining at the tunnel wall. Although this region is interpreted to have very low permeability (as indicated by the near-zero connected porosity detectable at the resolution investigated), a fracture network combined with the shell’s minimal thickness suggests that this would provide a minimal
考虑到射孔实验室测试在制定现场完井策略以及最终井况方面的重要作用,目前正在努力进一步加强实验室结果与现场井况预测之间的联系。其中一些工作侧重于将先进的诊断和计算工具(即计算机断层扫描(CT)和孔隙尺度流动模拟)集成到射孔测试工作流程中。这种集成可以识别和量化渗透率和孔隙度的局部变化,从而改进对射孔实验室结果的解释,并最终将这些结果转化为井下环境。自20世纪80年代初以来,CT技术已被用于岩心分析、表征和流动可视化。到20世纪90年代初,这些技术被应用于实验室射孔岩心的研究,以提高对API RP19B第2或4节所进行的测试的解释。自2012年以来,在射孔实验室设施现场安装了CT扫描系统后,这种应用急剧增加。因此,这种非破坏性技术已成为常规表征射孔隧道和围岩的首选方法,并且能够在模拟现场作业场景的测试序列中多次重复检查射孔岩心。与此同时,微ct技术的进步和应用也在不断发展,以更好地了解射孔附近和射孔外的孔隙尺度现象。本文介绍了目前正在进行的综合测试方案,并总结了两个在不同条件下进行的应力岩石目标射孔试验的关键结果。第一个实验涉及在基本保留所有射孔损伤的条件下对中等强度砂岩岩心进行射孔,从而保留“破碎区”。对破碎带内不同位置的Micro-CT分析显示,压实作用明显,孔隙度比原生岩石降低了10%至50%。对其中一个选定位置的渗透率进行了测定,发现渗透率比天然岩石值降低了约35%。第二个实验是在完全清洁的条件下对高强度砂岩岩心进行射孔。CT和micro-CT分析显示,隧道尖端附近有细小裂缝,证实射孔损伤几乎完全消除,隧道壁上只剩下一个非常薄(小于1mm)的压实区。尽管该区域的渗透率非常低(在研究的分辨率下可以检测到接近于零的连通孔隙度),但裂缝网络与最小的壳层厚度相结合,表明这将为流入提供最小的障碍。正在进行的工作旨在扩展这些发现和能力。今后的主要工作集中在模拟岩心尺度射孔流入,并结合本文所述确定的局部岩石性质变化。射孔之外的其他属性变化(例如,油藏岩心样品中经常存在的天然非均质性和/或各向异性)也将被考虑在内。在典型的Section 4测试方案中,通常不会考虑射孔附近和远离射孔的这种局部变化。因此,这种持续的努力将最终加强第4段结果与井下环境的相关性。
{"title":"Perforation Damage, Cleanup, and Inflow Performance: Advances in Diagnostics and Characterization","authors":"B. Grove, A. Grader, N. Derzhi, J. McGregor","doi":"10.2118/195019-MS","DOIUrl":"https://doi.org/10.2118/195019-MS","url":null,"abstract":"\u0000 Considering the important role that perforation laboratory testing can play in establishing field completion strategies, and thus ultimately well performance, efforts are currently underway to further strengthen the link between laboratory results and field well performance predictions. Some of these efforts focus on integrating advanced diagnostic and computational tools (namely computed tomography (CT), and pore-scale flow simulation) into the perforation testing workflow. This integration enables local variations in permeability and porosity to be identified and quantified, thus improving the interpretation of perforation laboratory results, and ultimately the translation of these results to the downhole environment.\u0000 CT techniques have been used for core analysis, characterization, and flow visualization since the early 1980s. By the early 1990s, these techniques were being applied to the investigation of laboratory-perforated cores to enhance the interpretation of tests conducted following API RP19B Section 2 or 4. This application has increased dramatically since 2012, following the installation of a CT scanning system on-site at a perforating laboratory facility. As a result, this non-destructive technique has become a preferred method to routinely characterize perforation tunnels and the surrounding rock, as well as to enable the repeated inspection of a perforated core at multiple steps throughout a test sequence designed to mimic field operations scenarios. Coinciding with this development has been the advancement and application of micro-CT technology to better understand pore-scale phenomena, both near and away from the perforation.\u0000 This paper introduces an integrated test program currently underway and summarizes key results from two experiments in which stressed rock targets were perforated under significantly different conditions. The first experiment involved perforating a moderate strength sandstone core under conditions that retained substantially all perforation damage, thus preserving the \"crushed zone\". Micro-CT analysis of different locations within the crushed zone region revealed significant compaction, with porosity reductions ranging from 10 to 50% below that of the native rock. Permeability at one of these selected locations was determined and found to be reduced by approximately 35% below the native rock value. The second experiment involved perforating a very high-strength sandstone core under conditions intended to produce full cleanup. CT and micro-CT analysis revealed fine fractures near the tunnel tip and confirmed the near-complete removal of the perforation damage, with only a very thin (less than 1 mm) compacted zone remaining at the tunnel wall. Although this region is interpreted to have very low permeability (as indicated by the near-zero connected porosity detectable at the resolution investigated), a fracture network combined with the shell’s minimal thickness suggests that this would provide a minimal ","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"92 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75005611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Modeling of Unconventional Reservoirs: A Case Study from Bahrain’s Khalij Al-Bahrain Basin 非常规油藏建模:以巴林Khalij Al-Bahrain盆地为例
Pub Date : 2019-03-15 DOI: 10.2118/195109-MS
Gregory Jackson, Ghada Almoulani, Y. A. Ansari, Jorge Viamontes
Bahrain has begun exploring unconventional resources in the Khalij Al-Bahrain Basin for the Tuwaiq Mountain Formation. This work is a case study presenting the workflow for characterizing and modeling the unconventional development in Bahrain all the way from petrophysics through geology, completion modeling, and dynamic simulation. The work scope consisted of petrophysical modeling 10 key wells including calibration to core data. The petrophysics showed that the lower Tuwaiq Mountain interval with its TOC signature is remarkably consistent across all of Bahrain. The wells modeled in a 3D geological model with reservoir properties distributed throughout the reservoir to confirm resource in-place estimates published in early 2018. Well stimulation treatment on Well 1 was modeled and tied to the production test. A dynamic model was subsequently built to history match the production test. While not unique in its production match, this calibration is an important step for future optimizations in lieu of microseismic data. All of this information was used to form the basis for optimal completions to refine the next appraisal wells with forecasted production rates. The Tuwaiq Mountain reservoir has commercial potential in Bahrain, particularly in the western area where producibility has been proven. Producibility in the East has not been established as no production tests are available. In addition, future appraisal well locations were identified using the 3D geological model. The best trajectory was chosen such that the wells are estimated to yield EURs more than 500,000 bbls. The results of this project are important for Bahrain as it highlights the unconventional resource and production potential in the country. For the industry, unconventional development is in its early stages outside of North America and Bahrain’s case study can be utilized to expedite the learning curve in many other basins.
巴林已经开始在Khalij Al-Bahrain盆地的Tuwaiq Mountain组勘探非常规资源。这项工作是一个案例研究,展示了从岩石物理到地质、完井建模和动态模拟,巴林非常规开发的特征和建模工作流程。工作范围包括对10口重点井进行岩石物理建模,包括岩心数据校正。岩石物理分析表明,图瓦伊克山下段的TOC特征在整个巴林具有显著的一致性。这些井在三维地质模型中建模,储层属性分布在整个储层中,以确认2018年初发布的资源就地估计。对1号井的增产措施进行了模拟,并与生产测试相结合。随后建立了一个动态模型来匹配生产测试。虽然在生产匹配中不是唯一的,但这种校准是未来优化的重要步骤,可以代替微地震数据。所有这些信息都被用来形成最佳完井的基础,从而根据预测的产量来改进下一口评价井。Tuwaiq Mountain油藏在巴林具有商业潜力,特别是在已经证实可生产的西部地区。由于没有生产试验,东部地区的生产能力尚未确定。此外,利用三维地质模型确定了未来评价井的位置。选择的最佳轨迹使这些井的产量估计超过50万桶。该项目的成果对巴林来说非常重要,因为它突出了该国的非常规资源和生产潜力。对于油气行业来说,北美以外地区的非常规开发还处于早期阶段,巴林的案例研究可以用来加快其他盆地的学习曲线。
{"title":"Modeling of Unconventional Reservoirs: A Case Study from Bahrain’s Khalij Al-Bahrain Basin","authors":"Gregory Jackson, Ghada Almoulani, Y. A. Ansari, Jorge Viamontes","doi":"10.2118/195109-MS","DOIUrl":"https://doi.org/10.2118/195109-MS","url":null,"abstract":"\u0000 Bahrain has begun exploring unconventional resources in the Khalij Al-Bahrain Basin for the Tuwaiq Mountain Formation. This work is a case study presenting the workflow for characterizing and modeling the unconventional development in Bahrain all the way from petrophysics through geology, completion modeling, and dynamic simulation.\u0000 The work scope consisted of petrophysical modeling 10 key wells including calibration to core data. The petrophysics showed that the lower Tuwaiq Mountain interval with its TOC signature is remarkably consistent across all of Bahrain. The wells modeled in a 3D geological model with reservoir properties distributed throughout the reservoir to confirm resource in-place estimates published in early 2018. Well stimulation treatment on Well 1 was modeled and tied to the production test. A dynamic model was subsequently built to history match the production test. While not unique in its production match, this calibration is an important step for future optimizations in lieu of microseismic data. All of this information was used to form the basis for optimal completions to refine the next appraisal wells with forecasted production rates.\u0000 The Tuwaiq Mountain reservoir has commercial potential in Bahrain, particularly in the western area where producibility has been proven. Producibility in the East has not been established as no production tests are available. In addition, future appraisal well locations were identified using the 3D geological model. The best trajectory was chosen such that the wells are estimated to yield EURs more than 500,000 bbls.\u0000 The results of this project are important for Bahrain as it highlights the unconventional resource and production potential in the country. For the industry, unconventional development is in its early stages outside of North America and Bahrain’s case study can be utilized to expedite the learning curve in many other basins.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84918096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Characterization of Native Colloids and Study of Emulsions Stabilized by Asphaltene, Wax, Silicates and Calcites Using Optical Analyzer Turbiscan 天然胶体的表征及沥青质、蜡、硅酸盐和方解石稳定乳剂的光学分析仪Turbiscan研究
Pub Date : 2019-03-15 DOI: 10.2118/195082-MS
A. A. Umar, I. Saaid, A. Sulaimon, R. Pilus, N. A. Amer, A. Halilu, B. M. Negash
Water-in-oil petroleum emulsions were prepared using response surface methodology (RSM) based on box-Behnken design (BBD). The emulsions were prepared using a treated Malaysian offshore crude oil, where the saturates, aromatics, resins and asphaltenes (SARA) of the crude oil were extracted using a modified SARA analysis. Other native solids, wax and asphaltenes extracted from oilfield emulsions and other crude oils were used as the emulsifying agents. In this paper, we focus on the characterization of some oilfield solids extracted from Malaysian offshore fields and further investigated their potentials to stabilize petroleum emulsions. The effects of the solids alone, and in combination with asphaltene/resin and wax were studied using statistical methods and the stabilities of the emulsions examined using a Turbiscan optical analyzer. The main advantage of Turbiscan is to obtain a faster and more accurate detection of destabilization phenomena in non-diluted emulsion than can be detected by the naked-eye (observation), especially for an opaque and concentrated dispersion system. The sample characterizations were conducted with FTIR, TGA, FESEM/EDX, XRF and XRD. Results showed that the major native solids present in the samples were paraffins and calcium carbonate. Further analysis revealed that the solids by themselves do not significantly contribute to emulsion stability. However, in the presence of asphaltene/resin compounds, the prominent solids such as paraffins and calcium carbonate enhance the stability of the emulsion irrespective of asphaltene/resin concentrations.
采用基于box-Behnken设计(BBD)的响应面法(RSM)制备了含水石油乳状液。乳剂是用经过处理的马来西亚海上原油制备的,其中原油中的饱和烃、芳烃、树脂和沥青烯(SARA)通过改进的SARA分析提取出来。从油田乳化液和其他原油中提取的其他天然固体、蜡和沥青质作为乳化剂。在本文中,我们重点研究了从马来西亚海上油田提取的一些油田固体的特性,并进一步研究了它们稳定石油乳状液的潜力。使用统计方法研究了固体单独、沥青质/树脂和蜡的影响,并使用Turbiscan光学分析仪检测了乳状液的稳定性。Turbiscan的主要优点是可以比肉眼(观察)更快、更准确地检测未稀释乳液中的不稳定现象,特别是对于不透明和浓缩的分散体系。采用FTIR、TGA、FESEM/EDX、XRF和XRD对样品进行了表征。结果表明,样品中的天然固体主要为石蜡和碳酸钙。进一步的分析表明,固体本身对乳液的稳定性没有显著的贡献。然而,在沥青烯/树脂化合物存在的情况下,石蜡和碳酸钙等突出的固体增强了乳液的稳定性,而与沥青烯/树脂浓度无关。
{"title":"Characterization of Native Colloids and Study of Emulsions Stabilized by Asphaltene, Wax, Silicates and Calcites Using Optical Analyzer Turbiscan","authors":"A. A. Umar, I. Saaid, A. Sulaimon, R. Pilus, N. A. Amer, A. Halilu, B. M. Negash","doi":"10.2118/195082-MS","DOIUrl":"https://doi.org/10.2118/195082-MS","url":null,"abstract":"\u0000 Water-in-oil petroleum emulsions were prepared using response surface methodology (RSM) based on box-Behnken design (BBD). The emulsions were prepared using a treated Malaysian offshore crude oil, where the saturates, aromatics, resins and asphaltenes (SARA) of the crude oil were extracted using a modified SARA analysis. Other native solids, wax and asphaltenes extracted from oilfield emulsions and other crude oils were used as the emulsifying agents. In this paper, we focus on the characterization of some oilfield solids extracted from Malaysian offshore fields and further investigated their potentials to stabilize petroleum emulsions. The effects of the solids alone, and in combination with asphaltene/resin and wax were studied using statistical methods and the stabilities of the emulsions examined using a Turbiscan optical analyzer. The main advantage of Turbiscan is to obtain a faster and more accurate detection of destabilization phenomena in non-diluted emulsion than can be detected by the naked-eye (observation), especially for an opaque and concentrated dispersion system. The sample characterizations were conducted with FTIR, TGA, FESEM/EDX, XRF and XRD. Results showed that the major native solids present in the samples were paraffins and calcium carbonate. Further analysis revealed that the solids by themselves do not significantly contribute to emulsion stability. However, in the presence of asphaltene/resin compounds, the prominent solids such as paraffins and calcium carbonate enhance the stability of the emulsion irrespective of asphaltene/resin concentrations.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"10 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79527990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
The Use of Digital Core Analysis in Understanding the Effects of CO2 Aging to Carbonates Samples 利用数字岩心分析了解二氧化碳老化对碳酸盐样品的影响
Pub Date : 2019-03-15 DOI: 10.2118/195074-MS
Wan Muhammad Luqman Sazali, Sahriza Salwani Md Shah, M. Z. Kashim, B. Kantaatmadja, L. Knuefing, B. Young
PETRONAS is interested in monetizing X Field, a high CO2 carbonate gas field located in East Malaysian waters. Because of its location (more than 200 km from shore) and the preferable geological formation of the field, reinjection of produced CO2 back into the field's aquifer has been considered as part of the field development plan. To ensure feasibility, the PETRONAS R&D team has conducted a set of laboratory analyses to observe the impact of CO2 on the carbonate formations, through combining the use of static CO2 batch reaction experiments with advanced helical digital core analysis techniques. The analysis of two representative samples, from the aquifer zone is presented here. The initial state of the samples was determined through the use of theoretically exact helical micro computed tomography (microCT) techniques. The images were processed digitally to determine the porosity and calibrated with RCA to ensure the reliability of digital core analysis results. After scanning, both plugs were saturated with synthetic brine with similar composition as the fields' formation brine and aged with supercritical CO2 at reservoir temperature and pressure for 45 days. After 45 days, the aged core plugs underwent post reaction analysis using micro-CT scan and image processing software. Based on macroscopic observation, the core plugs showed no changes after aging with supercritical CO2 at high pressure and high temperature (HPHT) as per reservoir condition. However, analysing the high resolution micro CT images, the team was able to determine the changes in porosity before and after CO2 aging, which are around 1%.
马来西亚国家石油公司对X气田感兴趣,该气田位于马来西亚东部海域,是一个高二氧化碳含量的碳酸盐岩气田。由于该油田的地理位置(距海岸200多公里)和较好的地质构造,将产出的二氧化碳重新注入油田的含水层已被视为油田开发计划的一部分。为了确保可行性,马来西亚国家石油公司的研发团队进行了一系列实验室分析,通过将静态CO2间歇反应实验与先进的螺旋数字岩心分析技术相结合,观察CO2对碳酸盐地层的影响。本文介绍了对含水层两个代表性样品的分析。样品的初始状态是通过使用理论上精确的螺旋微计算机断层扫描(microCT)技术确定的。对图像进行数字化处理,确定孔隙度,并用RCA进行校准,以确保数字岩心分析结果的可靠性。扫描后,两个桥塞都被与油田地层卤水成分相似的合成盐水饱和,并在油藏温度和压力下用超临界CO2老化45天。45天后,使用micro-CT扫描和图像处理软件对老化岩心桥塞进行事后分析。宏观观察表明,根据储层条件,岩心塞在高压高温超临界CO2作用下老化后没有发生变化。然而,通过分析高分辨率的微型CT图像,研究小组能够确定二氧化碳老化前后孔隙度的变化,大约为1%。
{"title":"The Use of Digital Core Analysis in Understanding the Effects of CO2 Aging to Carbonates Samples","authors":"Wan Muhammad Luqman Sazali, Sahriza Salwani Md Shah, M. Z. Kashim, B. Kantaatmadja, L. Knuefing, B. Young","doi":"10.2118/195074-MS","DOIUrl":"https://doi.org/10.2118/195074-MS","url":null,"abstract":"\u0000 PETRONAS is interested in monetizing X Field, a high CO2 carbonate gas field located in East Malaysian waters. Because of its location (more than 200 km from shore) and the preferable geological formation of the field, reinjection of produced CO2 back into the field's aquifer has been considered as part of the field development plan. To ensure feasibility, the PETRONAS R&D team has conducted a set of laboratory analyses to observe the impact of CO2 on the carbonate formations, through combining the use of static CO2 batch reaction experiments with advanced helical digital core analysis techniques. The analysis of two representative samples, from the aquifer zone is presented here. The initial state of the samples was determined through the use of theoretically exact helical micro computed tomography (microCT) techniques. The images were processed digitally to determine the porosity and calibrated with RCA to ensure the reliability of digital core analysis results. After scanning, both plugs were saturated with synthetic brine with similar composition as the fields' formation brine and aged with supercritical CO2 at reservoir temperature and pressure for 45 days. After 45 days, the aged core plugs underwent post reaction analysis using micro-CT scan and image processing software. Based on macroscopic observation, the core plugs showed no changes after aging with supercritical CO2 at high pressure and high temperature (HPHT) as per reservoir condition. However, analysing the high resolution micro CT images, the team was able to determine the changes in porosity before and after CO2 aging, which are around 1%.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"28 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83780008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Development of Artificial Intelligence Models for Prediction of Crude Oil Viscosity 原油粘度预测人工智能模型的发展
Pub Date : 2019-03-15 DOI: 10.2118/194741-MS
Luai Ali Al-Amoudi, Ba Geri, S. Patil, Salem O. Baarimah
Crude oil viscosity is a significant parameter for the fluid flow in both porous media and pipe lines. Therefore, it has to be determined using highly accurate methods. Oil viscosity is usually predicted with the correlations obtained from the laboratory measured data. However, some of the presented correlations have very complicated assumptions which make them very difficult to apply in most of the case studies reported. On the other hand, simplified correlations companies the accuracy. The present work in this paper studies predictive capabilities of Artificial Intelligence (AI) to estimate the oil viscosity. Artificial Neural Network (ANN) models are proposed to predict the undersaturated, saturated and dead oil viscosity in Yemeni fields. A data set consisting 545 of laboratory measurements on oil samples was gathered from different oil fields in Yemen. 70% of the data points were used to train the proposed ANN models while the remaining data set was tested the model performance. The performance of the ANN methods was compared with some of the conventional correlations such as (Beal's correlation, Khan's correlation, Kartoatmodjo and Schmidt correlation, Vasquez-Begg's correlation, Chew and Connaly correlation, Beggs and Robinson correlation, Elsharqawy correlation and Glaso's correlation). The result of this study shows the superiority of the Artificial Neural Network (ANN) models over the current models for predicting oil viscosity from PVT data. The comparative results displayed that the proposed ANN models performed better with higher accuracy than those obtained with published correlations.
原油粘度是流体在多孔介质和管道中流动的重要参数。因此,必须使用高度精确的方法来确定。通常用实验室测量数据得到的相关性来预测油的粘度。然而,所提出的一些相关性具有非常复杂的假设,这使得它们很难应用于所报告的大多数案例研究。另一方面,简化相关性提高了准确性。本文研究了人工智能(AI)对油品粘度的预测能力。提出了用人工神经网络(ANN)模型预测也门油田欠饱和、饱和和死油粘度的方法。从也门的不同油田收集了545个油样的实验室测量数据集,其中70%的数据点用于训练所提出的人工神经网络模型,其余数据集用于测试模型的性能。将人工神经网络方法的性能与一些常规相关性(Beal相关、Khan相关、Kartoatmodjo和Schmidt相关、Vasquez-Begg相关、Chew和Connaly相关、Beggs和Robinson相关、Elsharqawy相关和Glaso相关)进行了比较。研究结果表明,人工神经网络(ANN)模型在利用PVT数据预测油品粘度方面优于现有模型。对比结果表明,本文提出的人工神经网络模型比基于已发表相关性的模型性能更好,精度更高。
{"title":"Development of Artificial Intelligence Models for Prediction of Crude Oil Viscosity","authors":"Luai Ali Al-Amoudi, Ba Geri, S. Patil, Salem O. Baarimah","doi":"10.2118/194741-MS","DOIUrl":"https://doi.org/10.2118/194741-MS","url":null,"abstract":"\u0000 Crude oil viscosity is a significant parameter for the fluid flow in both porous media and pipe lines. Therefore, it has to be determined using highly accurate methods. Oil viscosity is usually predicted with the correlations obtained from the laboratory measured data. However, some of the presented correlations have very complicated assumptions which make them very difficult to apply in most of the case studies reported. On the other hand, simplified correlations companies the accuracy.\u0000 The present work in this paper studies predictive capabilities of Artificial Intelligence (AI) to estimate the oil viscosity. Artificial Neural Network (ANN) models are proposed to predict the undersaturated, saturated and dead oil viscosity in Yemeni fields. A data set consisting 545 of laboratory measurements on oil samples was gathered from different oil fields in Yemen. 70% of the data points were used to train the proposed ANN models while the remaining data set was tested the model performance. The performance of the ANN methods was compared with some of the conventional correlations such as (Beal's correlation, Khan's correlation, Kartoatmodjo and Schmidt correlation, Vasquez-Begg's correlation, Chew and Connaly correlation, Beggs and Robinson correlation, Elsharqawy correlation and Glaso's correlation).\u0000 The result of this study shows the superiority of the Artificial Neural Network (ANN) models over the current models for predicting oil viscosity from PVT data. The comparative results displayed that the proposed ANN models performed better with higher accuracy than those obtained with published correlations.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"31 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88555905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
A More Sustainable Approach: Nanofiltered Seawater-Based High-Temperature Fracturing Fluids 一种更可持续的方法:纳米过滤海水基高温压裂液
Pub Date : 2019-03-15 DOI: 10.2118/194708-MS
Leiming Li, Fakuen F. Chang, Saini Rajesh Kumar
In recent decades, the widespread implementation of horizontal drilling and multistage hydraulic fracturing in unconventional plays has increased the use of fresh water in oilfield operations. The formulation of fracturing fluids with non-fresh water sources such as seawater or produced water are attracting more attention due to the long term sustainability of non-fresh water use. Fracturing fluids using seawater are available in the industry. But the compatibility between the composition of local seawater and reservoir brine can add complication in the formation damage consideration. For example, if a seawater rich in sulfate comes in contact with formation brine rich in calcium or barium, severe scale can be expected if the proper caution is not taken. Treated seawater with nano-filtration to removal sulfate is a good practice to eliminate this problem. This paper describes a fracturing fluid formulated by using nanofiltered seawater for high temperature applications at 300 to 325°F. The crosslinked fracturing fluid formulation was optimized in the lab to accommodate the nanofiltered seawater, resulting in satisfactory fluid performance thereby enabling the fracturing operations to conserve fresh water. A high-temperature crosslinked fracturing fluid system was prepared with the nanofiltered local seawater. The fluid system showed robust stability at high temperatures. For example, the fluid viscosity stayed above 400 cP (at 100 sec−1 shear rate) for 2 hr at 300°F, with 45 ppt of the polymer loading. At 325°F, the fluid maintained viscosity above 300 cP for 2 hr with 60 ppt of the polymer loading. The nanofiltered seawater-based fluids was found to be compatible with a number of commonly used fluid additives including biocide, surfactant, and clay stabilizer. The fluid system also showed low formation damage and scaling tendencies. In the coreflow tests at 300°F, a regained permeability of greater than 95% was obtained. In the scaling tests without the presence of scale inhibitor at 300°F, traceable (<0.01 wt %) amount of scale was observed in the mixture of the nanofiltered seawater and high total dissolved solids (TDS) formation brine. Overall, it was found using the nanofiltered seawater can lead to better fluid stability at elevated temperatures, better fluid cleanup, and reduced downhole scaling tendency. By careful selection of the fluid components, the nanofiltered seawater-based fluid relieve the burden of needing fresh water for hydraulic fracturing treatment, allowing for a more sustainable approach. This paper discusses the technical functions of the key fluid additives used in the fracturing fluid preparation.
近几十年来,非常规油藏中水平钻井和多级水力压裂的广泛应用增加了油田作业中淡水的使用量。由于非淡水资源的长期可持续性,使用海水或采出水等非淡水资源配制压裂液越来越受到人们的关注。使用海水的压裂液在工业上是可用的。但当地海水与储层卤水成分的配伍性会增加考虑地层损害的复杂性。例如,如果富含硫酸盐的海水与富含钙或钡的地层盐水接触,如果不采取适当的措施,可能会产生严重的水垢。采用纳滤法去除硫酸盐是解决这一问题的较好方法。本文介绍了一种由纳米过滤海水配制的压裂液,适用于300 ~ 325°F的高温作业。实验室对交联压裂液配方进行了优化,以适应纳米过滤海水,产生了令人满意的流体性能,从而使压裂作业节省了淡水。采用纳滤海水制备了高温交联压裂液体系。该流体体系在高温下表现出较强的稳定性。例如,在300°F、45 ppt的聚合物载荷下,流体粘度保持在400 cP以上(剪切速率为100秒−1)2小时。在325°F的温度下,在60 ppt的聚合物载荷下,流体的粘度保持在300 cP以上2小时。研究发现,纳米过滤的海水基流体与许多常用的流体添加剂(包括杀菌剂、表面活性剂和粘土稳定剂)兼容。该流体体系也表现出较低的地层损害和结垢倾向。在300°F的岩心回流测试中,获得了大于95%的恢复渗透率。在没有阻垢剂的情况下,在300°F的结垢测试中,在纳米过滤海水和高总溶解固体(TDS)地层盐水的混合物中观察到可追踪(<0.01 wt %)的结垢量。总的来说,使用纳米过滤海水可以在高温下获得更好的流体稳定性,更好的流体清洁度,并降低井下结垢倾向。通过仔细选择流体成分,纳米过滤的海水基流体减轻了水力压裂处理需要淡水的负担,从而实现了更可持续的方法。论述了压裂液配制中关键流体添加剂的技术作用。
{"title":"A More Sustainable Approach: Nanofiltered Seawater-Based High-Temperature Fracturing Fluids","authors":"Leiming Li, Fakuen F. Chang, Saini Rajesh Kumar","doi":"10.2118/194708-MS","DOIUrl":"https://doi.org/10.2118/194708-MS","url":null,"abstract":"\u0000 In recent decades, the widespread implementation of horizontal drilling and multistage hydraulic fracturing in unconventional plays has increased the use of fresh water in oilfield operations. The formulation of fracturing fluids with non-fresh water sources such as seawater or produced water are attracting more attention due to the long term sustainability of non-fresh water use.\u0000 Fracturing fluids using seawater are available in the industry. But the compatibility between the composition of local seawater and reservoir brine can add complication in the formation damage consideration. For example, if a seawater rich in sulfate comes in contact with formation brine rich in calcium or barium, severe scale can be expected if the proper caution is not taken. Treated seawater with nano-filtration to removal sulfate is a good practice to eliminate this problem. This paper describes a fracturing fluid formulated by using nanofiltered seawater for high temperature applications at 300 to 325°F. The crosslinked fracturing fluid formulation was optimized in the lab to accommodate the nanofiltered seawater, resulting in satisfactory fluid performance thereby enabling the fracturing operations to conserve fresh water.\u0000 A high-temperature crosslinked fracturing fluid system was prepared with the nanofiltered local seawater. The fluid system showed robust stability at high temperatures. For example, the fluid viscosity stayed above 400 cP (at 100 sec−1 shear rate) for 2 hr at 300°F, with 45 ppt of the polymer loading. At 325°F, the fluid maintained viscosity above 300 cP for 2 hr with 60 ppt of the polymer loading. The nanofiltered seawater-based fluids was found to be compatible with a number of commonly used fluid additives including biocide, surfactant, and clay stabilizer. The fluid system also showed low formation damage and scaling tendencies. In the coreflow tests at 300°F, a regained permeability of greater than 95% was obtained. In the scaling tests without the presence of scale inhibitor at 300°F, traceable (<0.01 wt %) amount of scale was observed in the mixture of the nanofiltered seawater and high total dissolved solids (TDS) formation brine. Overall, it was found using the nanofiltered seawater can lead to better fluid stability at elevated temperatures, better fluid cleanup, and reduced downhole scaling tendency.\u0000 By careful selection of the fluid components, the nanofiltered seawater-based fluid relieve the burden of needing fresh water for hydraulic fracturing treatment, allowing for a more sustainable approach. This paper discusses the technical functions of the key fluid additives used in the fracturing fluid preparation.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"54 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83200655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Efficient Large Volume Acid Fracturing in Openhole Horizontal Well with Pre-Created Circular Notches 带圆形切口的裸眼水平井高效大体积酸压裂
Pub Date : 2019-03-15 DOI: 10.2118/194779-MS
R. Kayumov, R. E. Urbina, K. Bander, G. Aidagulov, Fakuen F. Chang
Tight carbonate reservoirs often require acid fracturing stimulation treatments to exploit them economically. In a horizontal well with a long openhole interval across a tight carbonate reservoir, multiple acid fracturing stages might be desirable, however this typically requires permanent completion devices to isolate discrete target intervals into specific stages. Multistage completions face many complications, such as hole-shape dependence, risk of communication between stages, completion deployment risks, and cost. A simplified completion technique was proposed to enable placement of multiple fractures along the openhole reservoir section without a complex completion. The main challenge in fracturing long openhole horizontal wellbores is limited or lack of control in positioning and orienting initiated fractures. One way to lower the fracturing pressure and force the hydraulic fracture to initiate at one or more desired target depths is to mechanically weaken the formation at specific points along the wellbore. An example of such a weak point is a cavity in the shape of a circular notch cut into the openhole wall. This technique was implemented in a multilateral horizontal water injector well drilled in a tight carbonate reservoir. Four circular notches were cut at predefined depths before stimulation with a goal of creating four separate fractures during one pumping operation. The volume of treating fluids required for the operation was significantly larger compared to a conventional acid fracturing job with only a single fracture propagating. To increase the effectiveness of stimulating all four intervals, degradable particulate diversion material was used during the treatment to temporarily isolate already stimulated fractures and divert treating fluids into less stimulated intervals. The stimulation treatment was successfully placed after the circular notches were created by coiled tubing using a rotational jetting tool with hydrochloric acid. As the primary result of the circular notching and acid fracturing stimulation, the injectivity index of this well increased almost four times. Temperature, caliper, production, and saturation logs were taken before and after fracturing to evaluate the applied completion approach. These measurements confirmed improved overall injectivity and highlighted areas for further improvements to the new technique, mainly related to preventing overstimulation of untargeted laterals in a multilateral well.
致密碳酸盐岩储层通常需要进行酸压裂增产处理,以实现经济开采。对于经过致密碳酸盐岩储层的长裸眼水平井,可能需要多个酸压裂段,但这通常需要永久性完井装置,将离散的目标层段分隔成特定的段。多段完井面临许多复杂问题,如井眼形状依赖性、分段之间的沟通风险、完井部署风险和成本。提出了一种简化的完井技术,可以沿裸眼油藏段放置多条裂缝,而无需进行复杂的完井。长裸眼水平井压裂面临的主要挑战是对裂缝的定位和定向控制有限或缺乏控制。降低压裂压力并迫使水力压裂在一个或多个目标深度启动的一种方法是在沿井筒的特定点机械削弱地层。这种弱点的一个例子是在裸眼井壁上切割成圆形缺口形状的空腔。该技术已在致密碳酸盐岩储层的一口多层水平注水井中实施。增产前在预定深度处切割了四个圆形切口,目的是在一次泵送作业中形成四个独立的裂缝。与传统的酸压裂作业相比,该作业所需的处理液量要大得多,而传统的酸压裂作业只有一条裂缝。为了提高所有四个层段的增产效果,在压裂过程中使用了可降解颗粒导流材料,暂时隔离已经增产的裂缝,并将压裂液分流到增产较少的层段。在连续油管使用盐酸旋转喷射工具形成圆形缺口后,成功进行了增产处理。作为环形切口和酸化压裂增产的主要成果,该井的注入能力指数提高了近4倍。在压裂前后分别测量了温度、井径、产量和饱和度,以评估所采用的完井方法。这些测量结果证实了整体注入能力的提高,并强调了新技术的进一步改进领域,主要涉及防止分支井中非目标分支的过度增产。
{"title":"Efficient Large Volume Acid Fracturing in Openhole Horizontal Well with Pre-Created Circular Notches","authors":"R. Kayumov, R. E. Urbina, K. Bander, G. Aidagulov, Fakuen F. Chang","doi":"10.2118/194779-MS","DOIUrl":"https://doi.org/10.2118/194779-MS","url":null,"abstract":"\u0000 Tight carbonate reservoirs often require acid fracturing stimulation treatments to exploit them economically. In a horizontal well with a long openhole interval across a tight carbonate reservoir, multiple acid fracturing stages might be desirable, however this typically requires permanent completion devices to isolate discrete target intervals into specific stages. Multistage completions face many complications, such as hole-shape dependence, risk of communication between stages, completion deployment risks, and cost. A simplified completion technique was proposed to enable placement of multiple fractures along the openhole reservoir section without a complex completion.\u0000 The main challenge in fracturing long openhole horizontal wellbores is limited or lack of control in positioning and orienting initiated fractures. One way to lower the fracturing pressure and force the hydraulic fracture to initiate at one or more desired target depths is to mechanically weaken the formation at specific points along the wellbore. An example of such a weak point is a cavity in the shape of a circular notch cut into the openhole wall. This technique was implemented in a multilateral horizontal water injector well drilled in a tight carbonate reservoir. Four circular notches were cut at predefined depths before stimulation with a goal of creating four separate fractures during one pumping operation. The volume of treating fluids required for the operation was significantly larger compared to a conventional acid fracturing job with only a single fracture propagating. To increase the effectiveness of stimulating all four intervals, degradable particulate diversion material was used during the treatment to temporarily isolate already stimulated fractures and divert treating fluids into less stimulated intervals.\u0000 The stimulation treatment was successfully placed after the circular notches were created by coiled tubing using a rotational jetting tool with hydrochloric acid. As the primary result of the circular notching and acid fracturing stimulation, the injectivity index of this well increased almost four times. Temperature, caliper, production, and saturation logs were taken before and after fracturing to evaluate the applied completion approach. These measurements confirmed improved overall injectivity and highlighted areas for further improvements to the new technique, mainly related to preventing overstimulation of untargeted laterals in a multilateral well.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"11 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88715326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Novel Characterization of Thin Film at Reservoir Fluids Interfaces in Carbonates 碳酸盐岩储层流体界面薄膜的新表征
Pub Date : 2019-03-15 DOI: 10.2118/194757-MS
M. Alotaibi, D. Cha, S. Alsaleh, A. Yousef
The salinity and ionic strength of injection water can make favorable impacts on wettability and oil recovery in different carbonate and sandstone reservoirs. The interaction mechanism between dissolved ions in injection water and reservoir fluids is a key ongoing research area. Most of these interactions occur at the thin film interfaces and so are considered one of the challenges in identifying and understanding the mechanisms. Conventional macro and microscopic laboratory techniques are commonly applied to determine contact angles, surface charges, and coreflooding to measure any incremental increase in oil recovery. In this paper, advanced sum frequency generation (SFG) spectroscopy is utilized, for the first time, to characterize the chemical structures of molecules at the brine/crude oil interfaces. The change in the chemical structure is perceived with time at a broad wavenumber range from 1000 to 3900 cm−1. Distinct spectral signatures of oil components and water ions are detected for high salinity water (HSW), modified ionic strength water (MIW), and ions-free solutions. The SFG data is also compared with the previous macroscopic wettability results to predict the components that are highly affected during waterflooding/enhanced oil recovery (EOR) processes. This study brings new insights about understanding the chemical structures at brine/crude oil monolayers and aqueous interfaces. The measured spectra at the interfaces along with the observed signal intensity trends are discussed in terms of composition and structure of organic and inorganic components. For example, SFG results from MIW oil interfaces and has higher spectral intensity at 2860 and 1700 cm−1 wavenumbers when compared with other brines used. These results exactly correlate with the C-H and C=O stretching bonds, which consider the key oil components at the interfaces. The novelty of this interfacial study can give more ability to understand the reaction mechanisms as altering the ionic strength and salinity of the injection water. Such understanding is also crucial in optimizing the chemistry of injection water and its interaction with oil components and carbonate rock to ultimately alter wettability toward water-wet.
注入水的矿化度和离子强度对不同碳酸盐岩和砂岩储层的润湿性和采收率都有有利影响。注入水中溶解离子与储层流体的相互作用机理是当前研究的重点。这些相互作用大多发生在薄膜界面,因此被认为是识别和理解机制的挑战之一。常规的宏观和微观实验室技术通常用于确定接触角、表面电荷和岩心驱油,以测量采收率的增量。本文首次利用先进的和频产生(SFG)光谱技术来表征盐水/原油界面处分子的化学结构。在1000 ~ 3900 cm−1的宽波数范围内,化学结构随时间的变化被感知。在高盐度水(HSW)、改性离子强度水(MIW)和无离子溶液中,可以检测到油组分和水离子的不同光谱特征。SFG数据还与之前的宏观润湿性结果进行了比较,以预测在水驱/提高采收率(EOR)过程中受到高度影响的组分。该研究为理解盐水/原油单层和水界面的化学结构提供了新的见解。从有机和无机组分的组成和结构方面讨论了界面处的实测光谱和观测到的信号强度趋势。例如,SFG来自MIW油界面,与使用的其他盐水相比,它在2860和1700 cm−1波数下具有更高的光谱强度。这些结果与C- h和C=O拉伸键完全相关,它们考虑了界面上的关键油组分。该界面研究的新颖性可以为理解通过改变注入水的离子强度和盐度来改变反应机理提供更多的能力。这种理解对于优化注入水的化学性质及其与油组分和碳酸盐岩的相互作用也至关重要,最终将润湿性转变为水湿性。
{"title":"Novel Characterization of Thin Film at Reservoir Fluids Interfaces in Carbonates","authors":"M. Alotaibi, D. Cha, S. Alsaleh, A. Yousef","doi":"10.2118/194757-MS","DOIUrl":"https://doi.org/10.2118/194757-MS","url":null,"abstract":"\u0000 The salinity and ionic strength of injection water can make favorable impacts on wettability and oil recovery in different carbonate and sandstone reservoirs. The interaction mechanism between dissolved ions in injection water and reservoir fluids is a key ongoing research area. Most of these interactions occur at the thin film interfaces and so are considered one of the challenges in identifying and understanding the mechanisms. Conventional macro and microscopic laboratory techniques are commonly applied to determine contact angles, surface charges, and coreflooding to measure any incremental increase in oil recovery.\u0000 In this paper, advanced sum frequency generation (SFG) spectroscopy is utilized, for the first time, to characterize the chemical structures of molecules at the brine/crude oil interfaces. The change in the chemical structure is perceived with time at a broad wavenumber range from 1000 to 3900 cm−1. Distinct spectral signatures of oil components and water ions are detected for high salinity water (HSW), modified ionic strength water (MIW), and ions-free solutions.\u0000 The SFG data is also compared with the previous macroscopic wettability results to predict the components that are highly affected during waterflooding/enhanced oil recovery (EOR) processes. This study brings new insights about understanding the chemical structures at brine/crude oil monolayers and aqueous interfaces. The measured spectra at the interfaces along with the observed signal intensity trends are discussed in terms of composition and structure of organic and inorganic components. For example, SFG results from MIW oil interfaces and has higher spectral intensity at 2860 and 1700 cm−1 wavenumbers when compared with other brines used. These results exactly correlate with the C-H and C=O stretching bonds, which consider the key oil components at the interfaces.\u0000 The novelty of this interfacial study can give more ability to understand the reaction mechanisms as altering the ionic strength and salinity of the injection water. Such understanding is also crucial in optimizing the chemistry of injection water and its interaction with oil components and carbonate rock to ultimately alter wettability toward water-wet.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"27 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84537396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IOT BASED MULTI-HOMING APPLICATIONS - A REVIEW 基于物联网的多归属应用-回顾
Pub Date : 2019-03-12 DOI: 10.36548/jsws.2019.1.003
K. Raj, S. S. Dr
With the ever increasing research in communication technology, smart systems and gadgets are emerging at a very fast pace. A recent trend is the research in internet of things (IoT) which facilitates access of information and services at any point of time around the globe thus elevating the process of digitization to a new era. Multi homing is a concept which facilitates connection of a user over multiple networks. These networks may be heterogeneous or homogeneous. This concept of multihoming acts as a strong backbone to wireless sensor networks where routing of information over the links and channels is quite a critical process. The routing of information from source to destination defines the overall accuracy of the entire wireless network. This efficiency largely dictated by an efficient routing process is influenced by many factors which include node efficiency, node lifetime, and the characteristics of the link between the nodes.
随着通信技术研究的不断深入,智能系统和智能小工具以非常快的速度出现。最近的一个趋势是物联网(IoT)的研究,它可以在全球任何时间点访问信息和服务,从而将数字化进程提升到一个新时代。多归巢是一个方便用户通过多个网络连接的概念。这些网络可能是异质的,也可能是同质的。在无线传感器网络中,信息在链路和信道上的路由是一个相当关键的过程,多归的概念充当了无线传感器网络的强大骨干。信息从源到目的的路由决定了整个无线网络的总体准确性。这种效率在很大程度上取决于有效的路由过程,它受到许多因素的影响,包括节点效率、节点寿命和节点之间的链路特征。
{"title":"IOT BASED MULTI-HOMING APPLICATIONS - A REVIEW","authors":"K. Raj, S. S. Dr","doi":"10.36548/jsws.2019.1.003","DOIUrl":"https://doi.org/10.36548/jsws.2019.1.003","url":null,"abstract":"With the ever increasing research in communication technology, smart systems and gadgets are emerging at a very fast pace. A recent trend is the research in internet of things (IoT) which facilitates access of information and services at any point of time around the globe thus elevating the process of digitization to a new era. Multi homing is a concept which facilitates connection of a user over multiple networks. These networks may be heterogeneous or homogeneous. This concept of multihoming acts as a strong backbone to wireless sensor networks where routing of information over the links and channels is quite a critical process. The routing of information from source to destination defines the overall accuracy of the entire wireless network. This efficiency largely dictated by an efficient routing process is influenced by many factors which include node efficiency, node lifetime, and the characteristics of the link between the nodes.","PeriodicalId":11031,"journal":{"name":"Day 4 Thu, March 21, 2019","volume":"4 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87950016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
Day 4 Thu, March 21, 2019
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1