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Indoor Environmental Quality Assessment and Building Shading Measures Research 室内环境质量评价与建筑遮阳措施研究
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/33930
Mingheng Li, Wenli Fan, Juan Lu, Dongfei Xue
This paper starts with the evaluation of indoor environmental quality, and on this basis, analyzes the relationship between human comfort and various environmental factors, establishes a temperature-comfort evaluation model, and uses ECOTEC software to correlate according to the evaluation results of influencing factors. The laboratory simulation of the energy-saving measures for building shading shows that the temperature parameter is an important indicator for evaluating comfort. The relevant optimization measures such as building shading can not only save energy, but also significantly improve the environmental comfort. Introduction China's current green building assessment system puts forward higher requirements and standards for indoor environmental quality, indoor environment comfort and building energy conservation. Comfort is not a single feeling, but a combination of people and the environment, with a combination of environmental factors. Therefore, we collect the environmental parameters we need under appropriate conditions, make an accurate assessment of the excellent indoor environment, and associate it with comfort to complete the evaluation of comfort. This paper starts with the evaluation of indoor environmental quality, and analyzes the relationship between human comfort and various environmental factors, establishes a temperature-comfort evaluation model, and uses ECOTEC software to carry out relevant energy-saving measures based on the evaluation results of influencing factors. The laboratory simulation shows that the use of three-dimensional information technology to assist the design of the building can not only improve the design efficiency, but also make the design of the building more reasonable and the user more comfortable. Determination of Environmental Quality Assessment In the comprehensive environmental assessment, determining the membership function is an extremely important part, which largely determines the accuracy of data fusion. In this study, the Cauchy distribution was used to calculate membership. refers to the degree of attachment of the value of each sensor to the jth element in the set of reviews V established by it, then: ) 0 , 0 ( , ) ( 1 / 1 , 1              a a x a x a a x r ij i ij i ij i ij (1) According to the principle determined by the above comment set, combined with the relevant specifications, the membership degree of each sensor is set separately, and the normalized analysis is completed to obtain the fuzzy relationship evaluation matrix R:
本文从室内环境质量评价入手,在此基础上,分析人体舒适度与各种环境因素之间的关系,建立温度-舒适度评价模型,并根据影响因素的评价结果,利用ECOTEC软件进行关联。对建筑遮阳节能措施的室内模拟表明,温度参数是评价舒适性的重要指标。建筑遮阳等相关优化措施不仅可以节约能源,还可以显著提高环境舒适度。中国现行的绿色建筑评价体系对室内环境质量、室内环境舒适性和建筑节能提出了更高的要求和标准。舒适不是一种单一的感觉,而是人与环境的结合,与环境因素的结合。因此,我们在适当的条件下收集我们所需要的环境参数,对优秀的室内环境进行准确的评价,并将其与舒适度联系起来,完成舒适度的评价。本文从室内环境质量评价入手,分析人体舒适度与各种环境因素之间的关系,建立温度-舒适度评价模型,并利用ECOTEC软件根据影响因素评价结果实施相关节能措施。实验室仿真表明,利用三维信息技术辅助建筑设计,不仅可以提高设计效率,而且可以使建筑设计更加合理,用户更加舒适。在综合环境评价中,隶属度函数的确定是一个极其重要的环节,它在很大程度上决定了数据融合的准确性。本研究采用柯西分布计算隶属度。指的是每个传感器的值的依恋程度j元素的一组评论V建立,然后:0,0(,)(1/1,1一一个x x x r ij我ij ij ij(1)根据上述原则确定评价集,结合相关规范,每个传感器的隶属度分别设置,并且完成了规范化分析得到模糊评价矩阵r的关系:
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引用次数: 0
Amorphous Forming Ability, Thermal Stability, Viscosity and Thermoplastic Formability of (Cu43Zr48Al9)100-xREx (x=0-4, RE: Y,Gd) Alloy (Cu43Zr48Al9)100-xREx (x=0-4, RE: Y,Gd)合金的非晶态成形能力、热稳定性、粘度和热塑性成形性
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/33959
Jinbao Zhao, Fan Xinhui, Bing Li, Ke‐Ke Yang, Y. Kong, Zhaofeng Wang, Jie Liu
The width, deformation and viscosity change of super cooled liquid region of (Cu43Zr48Al9)100-xREx(x=0-4, RE: Y, Gd) bulk metallic glasses in super cooled liquid region are systemically investigated by thermoanalysis tests. By analyzing the width, deformation and viscosity of super cooled liquid region, the amorphous forming ability, thermal stability and thermoplastic forming ability of (Cu43Zr48Al9)100-xREx (x=0-4, RE: Y, Gd) in the super cooled liquid region were obtained. It was found that the addition of rare earth elements Y and Gd improved amorphous forming ability, thermal stability, viscosity and deformation, however, by adding rare earth Y, Gd, viscosity and ΔT was no obvious connection. With the increase of Y content, the thermal stability first increases and then decreases, the viscosity decreases firstly, then increases and decreases finally, the deformation increases firstly and then decreases, it preliminary reveals the relationship between viscosity and amorphous forming ability. (Cu43Zr48Al9)98Y2 amorphous alloy has better thermal stability and thermoplastic formability by adding a small amount of Y.
通过热分析试验系统研究了(Cu43Zr48Al9)100-xREx(x=0-4, RE: Y, Gd)块状金属玻璃在过冷液区的宽度、变形和粘度变化。通过对过冷液区宽度、变形和粘度的分析,得到了(Cu43Zr48Al9)100-xREx (x=0-4, RE: Y, Gd)在过冷液区的非晶态成形能力、热稳定性和热塑性成形能力。结果发现,稀土元素Y和Gd的加入改善了非晶成形能力、热稳定性、粘度和变形,而添加稀土Y、Gd、粘度与ΔT没有明显的联系。随着Y含量的增加,热稳定性先增大后减小,粘度先减小后增大后减小,变形先增大后减小,初步揭示了粘度与非晶成形能力之间的关系。(Cu43Zr48Al9)98Y2非晶合金加入少量Y后,具有较好的热稳定性和热塑性成形性。
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引用次数: 1
Research on Variable Topological Structure and Flexible Networking Mode of Remote Monitoring System for Wind Farm 风电场远程监控系统变拓扑结构及灵活组网模式研究
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/34016
Feng Zhou, Kun Lin, Peng Jiang, Wen-Bo Hao
The requirements of the modern wind power development on the monitoring system networking mode are analyzed, and the wireless sensor network based on ZigBee protocol and the remote monitoring network scheme of wind farm based on 3G network are designed. The system has the advantages of variable topology and flexible networking, and realizes a two-layer and three-layer variable topology networking scheme for the self-organizing network, easy expansion and remote monitoring system of the wireless sensor network. A wind farm video surveillance solution based on 3G network is designed for unattended wind farms. The system has the advantages of strong scalability, high reliability, strong real-time performance, safety and reliability, and low operating cost. It is especially suitable for online monitoring of remote wind farms.
分析了现代风电发展对监测系统组网方式的要求,设计了基于ZigBee协议的无线传感器网络和基于3G网络的风电场远程监测网络方案。该系统具有可变拓扑和灵活组网的优点,实现了无线传感器网络自组织网络、易扩展和远程监控系统的两层和三层可变拓扑组网方案。针对无人值守风电场,设计了一种基于3G网络的风电场视频监控解决方案。该系统具有可扩展性强、可靠性高、实时性强、安全可靠、运行成本低等优点。它特别适用于远程风电场的在线监测。
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引用次数: 0
Design of Multi-effect Evaporator for Sewage Treatment 污水处理多效蒸发器的设计
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/33923
Aoni Zhang, Jin-hui Zhao, Yuxia Bai, Haifen Han, Y. Bu
This paper takes chemical salt water treatment as an example, to describe the desigen process of multi-effect evaporation sewage treatment equipment. Using software to simulate and analyze the influence of different factors on the results. Using line graphs to show the results of operating conditions of Luoyang Sinopec Branch. Introduction Evaporation refers to the process of evaporating and concentrating the solution containing the non-volatile solute and the volatile solvent, mainly by heating to vaporize a part of the solvent in the solution [1]. The multi-effect evaporator uses the secondary steam produced in the evaporation production as the heat source of the next unit. Such as, liter film multi-effect evaporator, falling film multi-effect evaporator [2], steam recompression multi-effect evaporator[3]. Multi-effect Evaporator Design Select Design Software and Reasons Aspen Plus was used to establish a chemical salt water treatment system. (1) The model physical property database is complete and suitable for more complex process simulation. (2) Fast unit simulation is possible. (3) With advanced calculation methods, the model can be optimized. Setting the Composition of Salty Sewage It is difficult to determine accurate data for these substances, such as chemical formula, content, etc. Therefore, in the modeling verification, the sewage composition needs to be simplified. In this design experiment, according to the sewage component in the sewage data of Luoyang Sinopec Branch, it is assumed that the large particle insoluble sludge has been removed. Common electrolytes such as ions and potassium ions are used as impurities, and volatile impurities are not considered at present[4]. Determination of Multi-effect Evaporator Efficiency With the increase in the efficiency of the multi-effect evaporator, the amount of steam required is reduced and the operating cost is reduced with the same total evaporation,the equipment and infrastructure costs will increase[5]. Therefore, the multi-effect evaporation system referred to herein is three-effect evaporator. Design Evaporato The heat exchanger model HeatX in Aspen plus, the separator model flash and the pressure transmission module Valve represent the multi-effect evaporator. Design Condenser In multi-effect evaporation, using the HeatX model in the Aspen plus module library instead. The final multi-effect evaporator system is: Figure 1. Multi-effect Evaporation System. Determine the Convergence Method The current simulation convergence method selects the traditional WEGSTEIN method. Module Parameter Setting The system parameters simulated in this paper are as follows: Table 1. Parameters of the Simulated Plate. HeatX Stream flash Valve Calculation shortcut — — Pressure change parameter Hot fluid outlet gas fraction Flow rate temperature Outlet pressure Hot fluid outlet temperature temperature pressure — — ingredient — — — pressure — — According to the above table, the fluid parameters of the evapora
本文以化学盐水处理为例,阐述了多效蒸发污水处理设备的设计过程。利用软件模拟分析了不同因素对结果的影响。利用折线图对中国石化洛阳分公司的经营状况进行了分析。蒸发是指对含有非挥发性溶质和挥发性溶剂的溶液进行蒸发浓缩的过程,主要是通过加热使溶液中的一部分溶剂蒸发[1]。多效蒸发器利用蒸发生产中产生的二次蒸汽作为下一机组的热源。如升膜多效蒸发器、降膜多效蒸发器[2]、蒸汽再压缩多效蒸发器[3]。多效蒸发器设计选择设计软件及原因利用Aspen Plus建立了化学盐水处理系统。(1)模型物性数据库完备,适合更复杂的过程仿真。(2)快速单元模拟成为可能。(3)采用先进的计算方法,可以对模型进行优化。这些物质的化学式、含量等准确数据很难确定。因此,在建模验证中,需要对污水成分进行简化。在本次设计实验中,根据中国石化洛阳分公司污水数据中的污水成分,假设已去除大颗粒不溶性污泥。常用离子、钾离子等电解质作为杂质,目前不考虑挥发性杂质[4]。多效蒸发器效率的确定随着多效蒸发器效率的提高,在总蒸发量相同的情况下,所需蒸汽量减少,运行成本降低,设备和基础设施成本随之增加[5]。因此,本文所指的多效蒸发系统为三效蒸发器。用Aspen plus中的换热器型号HeatX、分离器型号flash和传压模块Valve代表多效蒸发器。设计多效蒸发冷凝器,使用Aspen plus模块库中的HeatX模型代替。最终的多效蒸发器系统为:图1。多效蒸发系统。目前的仿真收敛方法选择传统的WEGSTEIN方法。本文仿真的系统参数如下:表1。模拟板参数。热液出口气体馏分流量温度出口压力热液出口温度温度压力——成分——压力——根据上表,本文设计的蒸发系统的流体参数为:表2。单效蒸发模块设定参数。热流冷流热阀闪蒸120℃60℃0.5℃- 116.2℃0.3Mpa 0.12Mpa - 0.07Mpa 0.12Mpa 10kg/h 10kg/h表3参数由双效蒸发模块设定。热阀闪速0.78 - 104°C - 0.04Mpa双效蒸发模块Heatx Flash设定参数94℃89.1℃- 0.04Mpa模型验证结果完成以上多效蒸发器模型设计工作后,可使用仿真软件进行运行验证。根据这些数据,可以估算出多效蒸发器的产水比和换热面积。蒸发效率对过程影响的模拟本模拟分别比较了一种效应、两种效应和三种效应的产水量比。数据更改如图2所示。由上图可以看出,在其他工艺参数不变的情况下,产水量随着效果的增加而显著增加,换热面积也随着效果的增加而增加。但随着蒸发量的增加,出水量的增幅减小。
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引用次数: 0
CFD Simulation of Symbiotic Disaster Arising from Gas Explosion and Spontaneous Combustion in Longwall Mining Gobs 长壁采空区瓦斯爆炸与自燃共生灾害的CFD模拟
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/33940
Zhen Xing
With the increasing of mining depth, the symbiotic disaster of gas and coal spontaneous combustion is gradually increasing. In order to explore the multi-field coupling law of gas and coal spontaneous combustion in the goaf, the numerical simulation method was used to optimize the key parameters and find the best balance between effectively controlling the gas without expanding the danger zone of spontaneous combustion. The results show that, the higher the level of the high-level drainage roadway, the better the drainage effect, but considering the spontaneous combustion period, it is necessary to reasonably calculate the optimal drainage roadway layout position; the buried pipe extraction has good effect on gas control, but it is not conducive to fire prevention.
随着开采深度的增加,瓦斯与煤自燃共生灾害逐渐增多。为了探索采空区瓦斯与煤自燃的多场耦合规律,采用数值模拟方法对关键参数进行优化,寻找有效控制瓦斯而不扩大自燃危险区的最佳平衡点。结果表明:高位排水巷道水平越高,排水效果越好,但考虑自燃期,有必要合理计算最佳排水巷道布置位置;埋管抽采对瓦斯控制效果好,但不利于防火。
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引用次数: 0
Research on Registration Deviation Detection of Printed Glass LED Circuit Board 印刷玻璃LED电路板配准偏差检测研究
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/33979
Tian Xi, Guo-sheng Zhang, Xiaoqiang Liu, Yang Li
To improve the registration accuracy, save the printing material, and optimize the printing space on printed glass circuit board for LED, the dual-cameras are introduced to capture the image of screen-printing plate. Considering the configuration of LED circuit, the dual-cameras are separately used to capture two parts of circuit image with 5mm × 4mm scale, which are from whole circuit with 200mm × 100mm scale. In this paper, the bolding pads are considered as the registration mark, the line fitting with global least square method is used to extract the image character points, and the registration deviation are calculated. According to this detection method, the registration printing experience results that the actual registration deviation ( 13μm in x-direction, 14μm in y-direction) satisfy the registration printing requirement of glass circuit board for LED (less than 30μm in x-direction, and less than 24μm in y-direction). Introduction Silver is used as the printing material in the most printed glass circuit boards that is printed by monochrome screen-printing machine in current. In this way, there is an issue that the silver bonding pad is possibly absorbed by the high temperature soldering, and peeled off from the glass substrate. To solve this issue, gold can be used as the bonding pad overprinted on the silver transmission line, because gold cannot be peeled off from sliver substrate by high temperature soldering. To improve the registration accuracy, it’s important to determine the position and shape of the registering mark. The common registering marks, such as the cross-shape mark [1], CMYK mark [2], independent solid circle mark [3] and star-shape mark [4], require to be printed individually, and occupy the printing space. In common, there is only one single camera in the registration system, therefore, it’s difficult to large the captured image scale and improve the registration accuracy at the same time. The Selection of Registering Mark The screen-printing plate for printed glass circuit board is shown in fig. 1, and the registration printing plate is shown in fig. 2. In this paper, to improve the registration accuracy, the dual-cameras with a resolution of 640 × 480, are applied in the experience device. The center distance of two cameras is 170mm. These two cameras are occupied to capture the field in 5mm × 4mm on the plate. Every pixel in this image is actually corresponding to 7.8μm in x-direction, and 8.3μm in y-direction. To save the printing material and optimize the printing space, according to the character of the circuit shape, the bonding pads are selected to be the registering mark, which is shown in fig. 3. In experience, the model of LED chip is ETi-KB358A-BL. According to the datasheet, the distance between each two bonding pads should be large than 240μm. Therefore, the maximum permission registration deviation should be 30μm in x-direction, and 24μm in y-direction. Figure 1. The printed screen plate for printed glas
为了提高LED玻璃印刷电路板的配准精度,节省印刷材料,优化印刷空间,采用双摄像头对丝网印版进行图像采集。考虑到LED电路的配置,采用双摄像头分别采集两部分规模为5mm × 4mm的电路图像,分别来自规模为200mm × 100mm的整个电路。本文以抱垫为配准标记,采用全局最小二乘法进行直线拟合提取图像特征点,并计算配准偏差。根据该检测方法,配准印刷经验表明,实际配准偏差(x方向13μm, y方向14μm)满足LED玻璃电路板的配准印刷要求(x方向小于30μm, y方向小于24μm)。目前大多数单色丝网印刷机印刷的玻璃电路板都采用银作为印刷材料。这样,就有一个问题,银键合垫可能被高温焊接吸收,并从玻璃基板上剥离。为了解决这个问题,可以使用金作为覆印在银传输线上的键合垫,因为金不能通过高温焊接从银衬底上剥离。为了提高配准精度,必须确定配准标记的位置和形状。常见的配准标记,如十字形标记[1]、CMYK标记[2]、独立实心圆标记[3]、星形标记[4]等,需要单独打印,占用打印空间。通常,配准系统中只有一台相机,因此很难在扩大捕获图像规模的同时提高配准精度。玻璃印刷电路板的丝网印版如图1所示,配准印版如图2所示。为了提高配准精度,本文将分辨率为640 × 480的双摄像头应用于体验装置中。两台摄像机的中心距离为170mm。这两台相机被占用来捕捉板上5mm × 4mm的场。该图像中的每个像素在x方向上对应7.8μm,在y方向上对应8.3μm。为节省打印材料,优化打印空间,根据电路形状的特点,选择键合垫作为配准标记,如图3所示。根据经验,LED芯片的型号为ti - kb358a - bl。根据数据表,两个焊盘之间的距离应大于240μm。因此,x方向最大权限配准偏差为30μm, y方向最大权限配准偏差为24μm。图1所示。印刷屏板用于印刷玻璃LED电路板。图2。用于印刷玻璃LED电路板的配准屏板。图3。注册号。由于玻璃是刚性材料,基板和配准标记不能变形,因此对图像进行预处理[5]分为3步。印版和套印版的预处理方法是相同的。Step1:灰化处理[6],如图3b所示,将3路彩色图像转换为1路灰度图像。Step2:直方图均衡化处理,如图3-c所示,通过拉伸对比度,增大前景与背景的差值来增强对比度。Step3:二值化处理,如图3- 3所示,得到二值化图像。图4。图像预处理示意图。图像特征点的提取图像特征点的提取分为三个步骤。印网版和套印网版的提取方法相同。Step1:对于图5-a所示二值图像中行方向上的数据,计算0值像素(黑色像素)的平均坐标值,即二值图像中每条水平线的中点坐标值。计算水平线所有中间点的列坐标与其平均值之间的绝对误差,根据权限偏差阈值,所有偏差大于阈值的点可以忽略。采用最小二乘法[7]进行直线拟合,可以用图5-b所示的左侧点拟合垂直线。Step2:对于图5-b所示二值图像中水平方向的数据,使用与step1相同的方法,可以得到如图5-c所示的水平线拟合。 Step3:在step1和step2中拟合的垂线和水平线的连接点为特征点的坐标值,如图5-d所示。图5。字符点提取处理流程图。上述字符点的坐标值在图像坐标系中,相机和印版的坐标值在世界坐标系中。首先确定图像坐标系与世界坐标系的映射关系[8],然后计算出实际配准偏差。这种映射关系如式1所示:[i j 1] = N [x y 1](1)式中,i和j为图像坐标,x和y为关系世界坐标系中的实际物理坐标。从图像坐标和世界坐标系中选取N(N≥4)个关系点,得到单应性矩阵N(3 × 3)。根据这个单应性矩阵,可以将图像坐标系中任意一点的坐标值转换为世界坐标系中实际的物理坐标值。首先捕获的两个特征点的坐标作为参考坐标。对比以下字符点的坐标值,可以计算出在x方向、y方向和旋转角度上的偏差。然后,可以提供这个坐标偏差来调整配准板的实际位置。假设首先捕获的两个字符点的世界坐标为A(xa, ya), B(xb, yb),以及下面两个字符点的A(xa ', ya '), B(xb ', yb '),如图6所示。图6。偏差计算。在y方向上方向偏差和旋转可以确定:方向上的偏差是∆x =Δxa +Δxb 2 = | xa−xa ' | + | xb−xb的| 2 (2)y方向上的偏差是∆y =Δya +Δ2 = |丫−ya ' | + | yb−yb的| 2(3)旋转的偏差是Δθ= |θ1−θ2 | = |反正切| yb−丫| | xb xa |−−反正切| yb−丫的| | xb−xa的| |(4)登记注册偏差检测算法的检测经验[9]是编码在Visual Studio 2010和OpenCV 3.0的平台。在实验中,捕获的屏板图像[10]如图7所示。图7。所捕获的屏板图像。点A、B、C、D的像素坐标分别为A(271, 394)、B(369, 394)、C(271, 77)、D(369, 77)。世界坐标(μm)为A(2113.8, 3270.2), B(2878.2, 3270.2), C(2113.8, 639.1), D(2878.2, 639.1)。则,单应性矩阵为N = | 0.254719−0.00179 59.3197−9.4802e 0.478092 82.8394 6.4975e−9.4398e 1 |,该矩阵表示图像坐标系与世界坐标系的映射关系。双摄像头拍摄两幅图像,尺寸为5mm × 4mm,整屏尺寸为200mm × 100mm。经历的偏差数据如表1所示。由此可知,实际平均配准偏差在x方向上为13μm,在y方向上为14μm。满足LED印刷玻璃电路板的配准要求。本文采用双摄像头采集电路图像,根据LED电路的形状特点,选择池垫图像作为新的配准标记。根据经验,板材位置偏差满足LED印刷玻璃电路板的要求。表1。体验结果[μm]。(xa, ya) (xb, yb) (xa, ya) (xb,yb)∆x∆y 1(1026,3476)(4672,827)(1009,3466)(4659,815) 15 11 2(997,3410)(4630,813)(987,3393)(4614,800) 13 15 3(1011,3425)(4611,820)(999,3017)(4605,808) 9 104(1048,3380)(4702,832)(1028,3361)(4686,823) 18 14 5(1031,3496)(4685,845)(1018,3476)(4670,827) 14 19 6(1005,3368)(4701,859)(990,3361)(4690,848) 13 7(1028,3294)(4659,871)(1017,3287)(4636,854) 17 12平均/ / / / 14 13致谢本研究由北京市教育局资助项目编号:KM201610015001,重点科研项目编号:Ea201604。
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引用次数: 0
Technological Preparation to the Manufacturing of Thick-Walled Polymer Composite Products 制备厚壁高分子复合材料制品的工艺准备
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/33962
O. Dmitriev, A. A. Barsukov, A. Dmitriev
The paper explores the technological problems that occur in the manufacturing of thick-walled polymer composite products. A detailed causal analysis of technological problems was carried out. We found the most vulnerable stages of the technology and outlined the ways to resolve them based on the method of mathematical modeling and optimization. The method allows to calculate the temperature-conversion fields during the curing of polymer composites and to choose the right optimization strategy of technological process molding.
探讨了厚壁高分子复合材料制品制造中存在的技术问题。对技术问题进行了详细的原因分析。我们找到了该技术最脆弱的阶段,并基于数学建模和优化的方法概述了解决这些问题的方法。该方法可以计算聚合物复合材料固化过程中的温度转换场,从而选择合适的工艺过程成型优化策略。
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引用次数: 0
Investigation on the Performance of Perovskite Solar Cells Based on All-oxide Charge Transport Layers 基于全氧化物电荷传输层的钙钛矿太阳能电池性能研究
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/34023
Xiao Zonghu, W. Zhong, H. Ou, Haiyan Fu, Shunjian Xu, Yongping Luo, Chen Liu
A perovskite solar cell with NiO and ZnO as charge transport layers was successfully fabricated. Intramolecular exchange technology was used to improve the morphology of CH3NH3PbI3 thin films. Doping was used to improve the conductivity of the NiO layer. X-ray diffractometer and scanning electron microscopy were used to analyze CH3NH3PbI3 thin films. A solar simulator with a digital source meter and quantum efficiency measurement system were used to test devices performance. The perovskite solar cells with FTO/p-NiO/CH3NH3PbI3/n-ZnO/Ag structure, have optimal PCE of 11.02% and long-term stability at 25 °C and 30 ± 2% humidity. This provides the possibility for the application of perovskite solar cells in the atmospheric environment. Introduction Various countries in the world have stepped up their efforts to develop new energy sources, duing to issues such as the energy crisis and environmental pollution. Recently, a new type of solar cell using an organic-inorganic hybrid halide perovskite as a light absorber has attracted the attention of many scientific researchers, which has the advantages of excellent performance, simple structure, and low preparation cost. The photoelectric conversion Efficiency has increased rapidly from 3.8% [1] to over 25.2% [2] in the past 10 years. The hole-transport materials currently used in such perovskite solar cells are usually organic polymers, such as Spiro-OMeTAD, PTAA [3], P3HT [4], PCBM [5], DEH [6], etc. Among them, spiro ometad device has the best performance, but the price is more expensive, 10 times of gold, which greatly improves the device cost, and the long-term stability of organic materials also needs to be further tested. Therefore, the development of high-efficiency and low-cost inorganic materials has become one of the important research directions of this kind of new solar cells. NiO is a p-type transparent oxide semiconductor with a wide band gap (Eg of 3.6 ~ 4.0 eV) and excellent performance. It has been successfully used as a hole-collecting and electron-blocking layer in dye-sensitized solar cells and organic solar cells. Compared with organic hole materials, NiO-based devices show better stability and comparable conversion efficiency [7]. Compared with TiO2, ZnO has a close band structure and higher electron mobility, which is 100 times that of TiO2 [8]. This enables photo-generated electrons to be more effectively injected into their conduction bands, and to transmit quickly to reduce electron losses and increase photocurrent. In addition, ZnO materials have the advantages of simple preparation, diverse morphology, and high crystal quality. These properties make ZnO the most ideal substitute for TiO2. In this work, NiO was used to replace the expensive and poorly stable Spiro-OMeTAD as the hole transport layer, and ZnO was used to replace TiO2 with low electron mobility as the electron transport layer. A perovskite solar cell with p-NiO/CH3NH3PbI3/n-ZnO simple sandwich structures were cons
成功制备了以NiO和ZnO为电荷传输层的钙钛矿太阳能电池。采用分子内交换技术改善了CH3NH3PbI3薄膜的形貌。采用掺杂的方法提高了NiO层的导电性。采用x射线衍射仪和扫描电镜对CH3NH3PbI3薄膜进行了分析。采用带数字源计和量子效率测量系统的太阳模拟器对器件性能进行了测试。具有FTO/p-NiO/CH3NH3PbI3/n-ZnO/Ag结构的钙钛矿太阳能电池在25°C和30±2%湿度下具有11.02%的最佳PCE和长期稳定性。这为钙钛矿太阳能电池在大气环境中的应用提供了可能。由于能源危机和环境污染等问题,世界各国都加大了对新能源的开发力度。近年来,一种以有机-无机杂化卤化物钙钛矿为光吸收剂的新型太阳能电池因其性能优异、结构简单、制备成本低等优点,引起了众多科研人员的关注。在过去的10年里,光电转换效率从3.8%[1]迅速提高到超过25.2%[2]。目前用于钙钛矿太阳能电池的空穴输运材料通常为有机聚合物,如Spiro-OMeTAD、PTAA[3]、P3HT[4]、PCBM[5]、DEH[6]等。其中,螺旋金属器件性能最好,但价格较贵,是黄金的10倍,这大大提高了器件成本,并且有机材料的长期稳定性也需要进一步测试。因此,开发高效、低成本的无机材料成为这类新型太阳能电池的重要研究方向之一。NiO是一种p型透明氧化物半导体,具有较宽的带隙(例如3.6 ~ 4.0 eV)和优异的性能。它已成功地用作染料敏化太阳能电池和有机太阳能电池中的空穴收集和电子阻挡层。与有机空穴材料相比,nio基器件具有更好的稳定性和相当的转换效率[7]。与TiO2相比,ZnO具有紧密的能带结构和更高的电子迁移率,是TiO2的100倍[8]。这使得光产生的电子能够更有效地注入到它们的导带中,并快速传输以减少电子损失并增加光电流。此外,ZnO材料还具有制备简单、形态多样、晶体质量高等优点。这些特性使ZnO成为TiO2最理想的替代品。在这项工作中,用NiO取代昂贵且稳定性差的Spiro-OMeTAD作为空穴传输层,用ZnO取代电子迁移率低的TiO2作为电子传输层。构建了一种具有p-NiO/CH3NH3PbI3/n-ZnO简单夹层结构的钙钛矿太阳能电池,并对其性能进行了研究。
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引用次数: 0
Effects of Pyrolysis Temperature on ZnCl2 Impregnated Corn Straw-derived Biochar Properties and Vanadium (III, IV, V) Adsorption in Aqueous Solution 热解温度对ZnCl2浸渍玉米秸秆生物炭性能及水溶液中对钒(III, IV, V)吸附的影响
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/33947
Ruihong Meng, Tan Chen, Yanting Liu, P. Lv, Qingshui Hong, Hanwen Guo, Hongtao Wang
In this study, corn straw derived biochars were prepared at different temperatures of 300, 500, 700C, respectively, and the characteristics of corn straw biochars were investigated. Additionally, the adsorption behaviors of vanadium (III, IV, V) on biochars were systematically studied by batch experiments. The absorbents were characterized by ion-exchange capacity (IEC), X-ray Diffraction, N2 adsorption-desorption, and FTIR. The yield of biochar decreases with the increase of pyrolysis temperature. The more ash content is retained, the more alkaline biochar is. The specific area of biochars increased with the rising pyrolysis temperature. With the increase of temperature, the structure became porous and the content of surface functional group elements remained low. Although the content of zinc in biochar is relatively high, the leaching toxicity of biochar does not exceed the Chinese standard. The adsorption capacity of biochars for vanadium (V) decreased under high temperature (700C). In the contrast, The adsorption capacities of biochars for vanadium (IV) and vanadium (III) improved under high temperature. The adsorption mechanisms for vanadium (V), vanadium (IV) and vanadium (III) were surface complexation, which can be proved by FTIR analysis.
本研究分别在300、500、700℃的不同温度下制备玉米秸秆生物炭,并对玉米秸秆生物炭的特性进行了研究。此外,通过批量实验系统地研究了钒(III, IV, V)在生物炭上的吸附行为。采用离子交换容量(IEC)、x射线衍射、N2吸附-解吸和红外光谱(FTIR)对吸附剂进行了表征。随着热解温度的升高,生物炭的产率降低。保留的灰分越多,生物炭的碱性越强。随着热解温度的升高,生物炭的比表面积增大。随着温度的升高,结构变得多孔,表面官能团元素含量保持在较低水平。虽然生物炭中锌含量较高,但其浸出毒性未超过国家标准。高温(700℃)下,生物炭对钒(V)的吸附能力下降。高温条件下,生物炭对钒(IV)和钒(III)的吸附能力有所提高。钒(V)、钒(IV)和钒(III)的吸附机理为表面络合,FTIR分析证实了这一点。
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引用次数: 1
Research on Laser Absorption Spectrum Detection Technology for CO2 and NH3 Regional Emission CO2和NH3区域发射激光吸收光谱检测技术研究
Pub Date : 2020-04-01 DOI: 10.12783/dteees/peems2019/34004
Ying He, Boqiang Fan, Mengqi Li, Zhang Yujun, Kun You, Hao Xie, Dongqi Yu, Boen Lei, Li Xiaoyi, Jian-guo Liu, Wenqing Liu
High-sensitivity emission monitoring of CO2 and NH3 in farmland region is very important for analyzing environment and climate change. The on-line detection technology was studied based on open-path tunable diode laser absorption spectroscopy technology (OP-TDLAS). The detection spectrum of open path was extracted to realize accurate concentration inversion by designing the multi-line fitting algorithm. The system detection stability was evaluated by Allan variance that the detection limit of NH3 and CO2 were about 0.048 L/L and 4.31 L/L respectively. The detection experiment was carried out in farmland of north Anhui to prove that both of the fertilization and straw returning to the field were the emission source of CO2 and NH3 from soil. The growth effect of the former was slower but higher than that of fertilization. This stable spectrum detection method can obtain large-scale concentration results and clear emission rules, which provide technical support for the environment-friendly agriculture. Introduction In recent years, our country has adopted straw returning to the field [1,2] which has changed the physical and chemical properties of the soil in a certain extent and even increased the possibility of CO2 and NH3 emission from the soil. Therefore, CO2 and NH3 emission data in large-scale farmland need obtain by effective and stable detection method to assess its impact on the atmospheric environment, which has become an urgent problem in agriculture and environmental fields [3,4] . Gas monitoring in farmland ecosystem usually adopts box method [5] , micrometeorology method [6-7] and so on. These methods mainly study local soil emissions which are vulnerable to environmental factors, and the requirements to underlying surface and atmospheric stability are high. In recent years, open-path tunable diode laser absorption spectroscopy (OP-TDLAS) technology has been gradually applied for large-scale monitoring. This technology [8,9] continuously measures the gas without sampling and pretreatment. It is more effective to monitor adsorbed gases (such as NH3). Moreover, it has the advantage of fast detection [10] and high sensitivity combined with long optical path technology. Flesch et al. (2007) measured methane volatilization in pasture based on TDLAS technology to verify its measurement accuracy. Todd et al. (2015) carried out ammonia emission monitoring in dairy farmland, and the volatilization rate obtained was 304g·head -1 ·d -1 . Anning Zhu et al. (2012) carried out ammonia emission monitoring before and after nitrogen fertilizer application in Huang-Huai-Hai farmland with TDLAS and BLS technology to obtain the emission rule. At present, there are few reports on effective extraction of characteristic absorption spectrum and improvement of detection stability in open-path detection. In this paper, the multi-line fitting algorithm was designed to realize spectrum detection. Allan variance analysis was carried out to determine the measureme
农田CO2和NH3的高灵敏度排放监测对分析环境和气候变化具有重要意义。研究了基于开路可调谐二极管激光吸收光谱技术(OP-TDLAS)的在线检测技术。通过设计多线拟合算法,提取开路检测谱,实现浓度精确反演。通过Allan方差评价体系的检测稳定性,NH3和CO2的检出限分别为0.048L/L和4.31L/L。在皖北农田进行了检测试验,证明施肥和秸秆还田都是土壤CO2和NH3的排放源。前者的生长效果较施肥慢,但高于施肥。这种稳定的光谱检测方法可以获得大规模的浓度结果和清晰的排放规律,为环境友好型农业提供技术支持。近年来,我国采用秸秆还田[1,2],在一定程度上改变了土壤的理化性质,甚至增加了土壤排放CO2和NH3的可能性。因此,需要通过有效、稳定的检测方法获取大规模农田CO2和NH3排放数据,评估其对大气环境的影响,这已成为农业和环境领域亟待解决的问题[3,4]。农田生态系统气体监测通常采用箱法[5]、微气象法[6-7]等。这些方法主要研究易受环境因素影响的局部土壤排放,对下垫面和大气稳定性要求较高。近年来,开路可调谐二极管激光吸收光谱(OP-TDLAS)技术已逐渐应用于大规模监测。该技术[8,9]无需采样和预处理即可连续测量气体。对吸附气体(如NH3)的监测更有效。并且结合长光路技术具有检测速度快[10]、灵敏度高的优点。Flesch et al.(2007)基于TDLAS技术对牧场甲烷挥发进行了测量,验证了其测量精度。Todd等(2015)对奶牛场进行了氨排放监测,得到的挥发率为304g·head -1·d -1。朱安宁等(2012)利用TDLAS和BLS技术对黄淮海农田施氮前后的氨排放进行了监测,得到了排放规律。目前,开路检测中有效提取特征吸收光谱和提高检测稳定性的报道很少。本文设计了多线拟合算法来实现频谱检测。采用Allan方差分析确定测量结果的稳定性,并采用OP-TDLAS系统对农田CO2和NH3区域排放进行监测。基本原则根据Lambert-Beer定律,单色激光的激光发射频率和初始光强度0我穿过一个吸收介质有一定的长度L和激光接收之间的关系强度t我和吸光度表示为:0 ln t我k L(1)k单一气体的光谱吸收系数在一个转变:kv=S(T) () v Px(2)其中S(T)为线强度,P为压力,x为气体浓度,()v为归一化线性函数。通过对式(2)积分,气体浓度表示为[11]:()A x S T PL(3)在温度、谱线强度和压力已知的情况下,调整光谱跃迁波长范围,从跃迁吸光度结果中提取气体浓度。探测系统与技术系统设计OP-TDLAS系统结构如图1所示。采用DFB激光器作为光源,分别监测了6528.8cm−1的NH3吸收线和6336.3cm−1的CO2吸收线。光束合并器将两束时分扫描激光束耦合,并将其分成三束。一束光通过一个充满标准气体的基准室,另外两束光进入由望远镜和反光镜组成的开放式光学系统。两种光学系统分别用于测量背景路径和顺风路径的气体吸收光谱,用于定量反演浓度。温度控制器电流供应信号处理模块Detector1 Detector3 NH3 DFB激光分束器准直器测量开路参考路径数据采集处理器DAC
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引用次数: 1
期刊
DEStech Transactions on Environment, Energy and Earth Science
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