A. Madadzada, S. S. Nuhuyeva, E. A. Mammadov, Z. Ibrahimov, Natig S. Jabbarov, Lyudmila P. Strelkova, M. Frontasyeva
Abstract The results of this investigation show that Azerbaijan industries and agricultural sector provide considerable anthropogenic impact on the environment of Caucasus. The use of moss biomonitoring technique and neutron activation analysis (NAA) is a first attempt to study heavy metal atmospheric deposition in Azerbaijan, a country different relief and climate. The study was undertaken in the summer of 2015 of atmospheric deposition of man-made heavy metal pollutants in the area of mining and processing plant in Gadabay and Dashkasan mininig district. At the same time samples were collected from the Goygol State Reserve in the Lesser Caucasus not far from the city of Ganja. A total 85 moss samples (predominantly Pleurozium schreberi) collected in both environmentally contrast area. Elemental determination was carried out by epithermal neutron activation analysis (ENAA) at the reactor IBR-2 of Joint Institute for Nuclear Research (FLNP JINR). For the first time 44 elemental concentrations were determined (Na, Mg, Al, Si, Cl, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Mo, Ag, Cd, In, Sb, I, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Tm, Yb, Hf, Ta, W, Au, Th, U). Multivariate statistical analysis of the analytical results obtained will make it possible to identify the main sources of pollution and to assess the role of long-range transport of pollutants.
{"title":"Heavy Metal Atmospheric Deposition Study in Azerbaijan Based on Moss Technique and Neutron Activation Analysis","authors":"A. Madadzada, S. S. Nuhuyeva, E. A. Mammadov, Z. Ibrahimov, Natig S. Jabbarov, Lyudmila P. Strelkova, M. Frontasyeva","doi":"10.2478/eces-2022-0011","DOIUrl":"https://doi.org/10.2478/eces-2022-0011","url":null,"abstract":"Abstract The results of this investigation show that Azerbaijan industries and agricultural sector provide considerable anthropogenic impact on the environment of Caucasus. The use of moss biomonitoring technique and neutron activation analysis (NAA) is a first attempt to study heavy metal atmospheric deposition in Azerbaijan, a country different relief and climate. The study was undertaken in the summer of 2015 of atmospheric deposition of man-made heavy metal pollutants in the area of mining and processing plant in Gadabay and Dashkasan mininig district. At the same time samples were collected from the Goygol State Reserve in the Lesser Caucasus not far from the city of Ganja. A total 85 moss samples (predominantly Pleurozium schreberi) collected in both environmentally contrast area. Elemental determination was carried out by epithermal neutron activation analysis (ENAA) at the reactor IBR-2 of Joint Institute for Nuclear Research (FLNP JINR). For the first time 44 elemental concentrations were determined (Na, Mg, Al, Si, Cl, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Mo, Ag, Cd, In, Sb, I, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Tm, Yb, Hf, Ta, W, Au, Th, U). Multivariate statistical analysis of the analytical results obtained will make it possible to identify the main sources of pollution and to assess the role of long-range transport of pollutants.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"65 1","pages":"143 - 153"},"PeriodicalIF":0.0,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73644935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. Azzouzi, S. E. Aggadi, M. Ennouhi, A. Ennouari, Imane El Fadil, A. Zrineh
Abstract A serious environmental problem can arise from the presence of pesticides in soils and waters. Hence, in this study we have carried out the adsorption of the Thiabendazole fungicide onto four soils collected from several areas in Morocco as Larache, Laouamra, Ksar kebir and Tlata drissana. Physicochemical properties, elemental analysis, X-ray diffraction (XRD) were investigated to characterise the four selected soils. The experimental equilibrium data were analysed using Langmuir, Freundlich models. The equilibrium data were best described by a Langmuir model for all adsorbents. The maximum estimated adsorption capacity was 0.747 mg∙g−1, 0.751 mg∙g−1, 0.473 mg∙g−1 and 1.083 mg∙g−1, for Larache, Laouamra, Ksar kebir and Tlata drissana soils, respectively.
{"title":"Thiabendazole Fungicide Adsorption Onto Four Agricultural Soils Collected from the Loukkos Area of Northwestern Morocco","authors":"L. Azzouzi, S. E. Aggadi, M. Ennouhi, A. Ennouari, Imane El Fadil, A. Zrineh","doi":"10.2478/eces-2022-0016","DOIUrl":"https://doi.org/10.2478/eces-2022-0016","url":null,"abstract":"Abstract A serious environmental problem can arise from the presence of pesticides in soils and waters. Hence, in this study we have carried out the adsorption of the Thiabendazole fungicide onto four soils collected from several areas in Morocco as Larache, Laouamra, Ksar kebir and Tlata drissana. Physicochemical properties, elemental analysis, X-ray diffraction (XRD) were investigated to characterise the four selected soils. The experimental equilibrium data were analysed using Langmuir, Freundlich models. The equilibrium data were best described by a Langmuir model for all adsorbents. The maximum estimated adsorption capacity was 0.747 mg∙g−1, 0.751 mg∙g−1, 0.473 mg∙g−1 and 1.083 mg∙g−1, for Larache, Laouamra, Ksar kebir and Tlata drissana soils, respectively.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"17 1","pages":"217 - 226"},"PeriodicalIF":0.0,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87585746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Twardowski, I. Gruss, P. Bereś, M. Hurej, Z. Klukowski
Abstract An environmental risk assessment related to the genetically modified crops still needs to be studied. In the non-target organisms, rove beetles seem to be well-chosen arthropods for this purpose. Rove beetle abundance and species diversity were studied in the first large-scale Bt-maize experiment in the south part of Poland for over two years to determine the impact of Bt-maize in comparison to conventional varieties. A genetically engineered Bt-maize variety (DKC 3421 Yield Gard®, event MON 810) and its near-isogenic DKC 3420 were cultivated at two locations. Additionally, two non-Bt varieties sprayed with a lambda-cyhalothrin insecticide were also included for comparative analysis. The results show no significant effects on rove beetle abundance and diversity patterns of the Bt-maize and the nearby isolines. In one locality the mean number of individuals and Simpson dominance was even higher in Bt-maize compared to one reference variety. The Canonical Correspondence Analysis showed rather variety-dependent effects of the rove beetle community. To conclude, considering the abundance and diversity of studied insects, there is no environmental risk arising from Bt-maize cultivation.
{"title":"An Assessment of Environmental Risk of Bt-Maize on Rove Beetle Communities","authors":"J. Twardowski, I. Gruss, P. Bereś, M. Hurej, Z. Klukowski","doi":"10.2478/eces-2022-0019","DOIUrl":"https://doi.org/10.2478/eces-2022-0019","url":null,"abstract":"Abstract An environmental risk assessment related to the genetically modified crops still needs to be studied. In the non-target organisms, rove beetles seem to be well-chosen arthropods for this purpose. Rove beetle abundance and species diversity were studied in the first large-scale Bt-maize experiment in the south part of Poland for over two years to determine the impact of Bt-maize in comparison to conventional varieties. A genetically engineered Bt-maize variety (DKC 3421 Yield Gard®, event MON 810) and its near-isogenic DKC 3420 were cultivated at two locations. Additionally, two non-Bt varieties sprayed with a lambda-cyhalothrin insecticide were also included for comparative analysis. The results show no significant effects on rove beetle abundance and diversity patterns of the Bt-maize and the nearby isolines. In one locality the mean number of individuals and Simpson dominance was even higher in Bt-maize compared to one reference variety. The Canonical Correspondence Analysis showed rather variety-dependent effects of the rove beetle community. To conclude, considering the abundance and diversity of studied insects, there is no environmental risk arising from Bt-maize cultivation.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"1 1","pages":"257 - 266"},"PeriodicalIF":0.0,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83031052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Haorui Chen, W. Zeng, Jiuyi Li, T. Ma, Shenzhou Liu, G. Lei, T. Gaiser, A. Srivastava
Abstract To determine the effects of air pollution on crop yields, weather, air pollution, and maize and winter wheat yield data from 331 cities in China from 2014 to 2016 were collected and analysed. Furthermore, support vector regression and the crop growth model were applied to extrapolate the air pollution data of Beijing and Hetian and verify the relationship between air pollution and yield. Precisely, heavy air pollution usually occurred in North China, but less than moderate air pollution levels affected crop yields statistically insignificantly. Moreover, both the winter wheat and maize yields increased in moderate air pollution periods but decreased in heavy air pollution periods in 2014, 2015 and 2016. Importantly, a threshold value was necessary for the heavy air pollution periods to trigger a yield decrease. The threshold values of maize in 2015 and 2016 were 7 days and 5 days, respectively, while that of winter wheat was 10 days in both 2015 and 2016. Once the heavy air pollution periods exceeded the threshold value, both the winter wheat and maize yields decreased linearly with the periods. PM2.5 was the main air pollutant in Beijing in 2014, while PM2.5 and PM10 were the main air pollutants in Hetian in both 2015 and 2016. Regardless of whether the main air pollutant was PM2.5 or PM10, the simulated potential winter wheat yields by the crop growth model with moderate air pollution for the whole growth period were all higher than the yields under observed and heavy air pollution conditions.
{"title":"Impact of Air Pollution on Maize and Wheat Production","authors":"Haorui Chen, W. Zeng, Jiuyi Li, T. Ma, Shenzhou Liu, G. Lei, T. Gaiser, A. Srivastava","doi":"10.2478/eces-2022-0018","DOIUrl":"https://doi.org/10.2478/eces-2022-0018","url":null,"abstract":"Abstract To determine the effects of air pollution on crop yields, weather, air pollution, and maize and winter wheat yield data from 331 cities in China from 2014 to 2016 were collected and analysed. Furthermore, support vector regression and the crop growth model were applied to extrapolate the air pollution data of Beijing and Hetian and verify the relationship between air pollution and yield. Precisely, heavy air pollution usually occurred in North China, but less than moderate air pollution levels affected crop yields statistically insignificantly. Moreover, both the winter wheat and maize yields increased in moderate air pollution periods but decreased in heavy air pollution periods in 2014, 2015 and 2016. Importantly, a threshold value was necessary for the heavy air pollution periods to trigger a yield decrease. The threshold values of maize in 2015 and 2016 were 7 days and 5 days, respectively, while that of winter wheat was 10 days in both 2015 and 2016. Once the heavy air pollution periods exceeded the threshold value, both the winter wheat and maize yields decreased linearly with the periods. PM2.5 was the main air pollutant in Beijing in 2014, while PM2.5 and PM10 were the main air pollutants in Hetian in both 2015 and 2016. Regardless of whether the main air pollutant was PM2.5 or PM10, the simulated potential winter wheat yields by the crop growth model with moderate air pollution for the whole growth period were all higher than the yields under observed and heavy air pollution conditions.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"37 1","pages":"237 - 256"},"PeriodicalIF":0.0,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82408966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Macroinvertebrates of two ex-manor ponds located in Chroscina, Opole Region (Poland) were studied from 2015 to 2018 to investigate their community composition and diversity and evaluate the heterogeneity of communities on spatial and temporal scale referring to environmental variables and revitalisation work. A total of 32 taxa were recorded (at the family level, except Oligochaeta), 13 of which were Ephemeroptera, Odonata and Trichoptera, recognised as sensitive groups in lentic ecosystems. Macroinvertebrate richness and diversity varied considerably, especially in spring and summer. It was found that habitat heterogeneity influenced benthic invertebrates more than basic water parameters. However, the environmental variables together accounted for only 38 % of the observed variations. Thus, other factors, such as fish predation, may have played a leading role in community shaping. The distinct differences between pond communities, four years after the revitalisation works, resulted more from different habitat features than from the previous sediment removal.
{"title":"Assessing Benthic Macroinvertebrates in Relations to Environmental Variables and Revitalisation Works","authors":"I. Czerniawska-Kusza","doi":"10.2478/eces-2022-0009","DOIUrl":"https://doi.org/10.2478/eces-2022-0009","url":null,"abstract":"Abstract Macroinvertebrates of two ex-manor ponds located in Chroscina, Opole Region (Poland) were studied from 2015 to 2018 to investigate their community composition and diversity and evaluate the heterogeneity of communities on spatial and temporal scale referring to environmental variables and revitalisation work. A total of 32 taxa were recorded (at the family level, except Oligochaeta), 13 of which were Ephemeroptera, Odonata and Trichoptera, recognised as sensitive groups in lentic ecosystems. Macroinvertebrate richness and diversity varied considerably, especially in spring and summer. It was found that habitat heterogeneity influenced benthic invertebrates more than basic water parameters. However, the environmental variables together accounted for only 38 % of the observed variations. Thus, other factors, such as fish predation, may have played a leading role in community shaping. The distinct differences between pond communities, four years after the revitalisation works, resulted more from different habitat features than from the previous sediment removal.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"111 1","pages":"99 - 110"},"PeriodicalIF":0.0,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85359178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
X. Zhen, Miao Luo, Z. Li, Yongheng Zhang, Weiwei Wang, Jian Kang
Abstract For aerobic static composting, fresh cow, pig, and chicken manures were used as feedstock and mixed with 10 % corn straws, which was considered as the bulking agent. In the composting process of different livestock and poultry manures, the changing trends of temperature, pH, conductivity, density, and other parameters were intensively studied. The results were as follows: (1) after the tail biogases of composting systems - using cattle manure, pig manure, and chicken manure - were introduced into the biofilter, the concentration of O2 decreased slightly, but the concentration of CO2 increased. The odour in these tail biogases declined significantly, and thus the biodegradation of tail biogas was obvious. (2) The oxygen consumption in the different periods of the composting process of these three manures was almost the same, and the average oxygen consumption for the three manures was 0.928, 0.937, and 0.945 m3/kg, respectively. Under standard conditions, the density of oxygen is 1.429 g/L, and the average oxygen consumption in the composting processes of these three manures was 1.326, 1.338, and 1.350 kg/kg, respectively.
{"title":"Study on the Rate of O2 Consumption and Purification of Tail Biogas with a Biofilter in the Composting Process","authors":"X. Zhen, Miao Luo, Z. Li, Yongheng Zhang, Weiwei Wang, Jian Kang","doi":"10.2478/eces-2022-0008","DOIUrl":"https://doi.org/10.2478/eces-2022-0008","url":null,"abstract":"Abstract For aerobic static composting, fresh cow, pig, and chicken manures were used as feedstock and mixed with 10 % corn straws, which was considered as the bulking agent. In the composting process of different livestock and poultry manures, the changing trends of temperature, pH, conductivity, density, and other parameters were intensively studied. The results were as follows: (1) after the tail biogases of composting systems - using cattle manure, pig manure, and chicken manure - were introduced into the biofilter, the concentration of O2 decreased slightly, but the concentration of CO2 increased. The odour in these tail biogases declined significantly, and thus the biodegradation of tail biogas was obvious. (2) The oxygen consumption in the different periods of the composting process of these three manures was almost the same, and the average oxygen consumption for the three manures was 0.928, 0.937, and 0.945 m3/kg, respectively. Under standard conditions, the density of oxygen is 1.429 g/L, and the average oxygen consumption in the composting processes of these three manures was 1.326, 1.338, and 1.350 kg/kg, respectively.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"105 1","pages":"87 - 97"},"PeriodicalIF":0.0,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80666101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Brysiewicz, P. Czerniejewski, M. Bonisławska, J. Dąbrowski
Abstract Abiotic and biotic bounty of riparian waters may be affected by inadequate maintenance works. Improper planning and execution of maintenance works cause changes to hydrological and hydrochemical condition of water in small rivers, affecting biocenose of riverbeds by modifying the taxonomic composition of organisms inhabiting the regulated river section. Five (5) rivers were subject to studies - Plonia, Mysla, Tywa, Rurzyca, and Wardynka (Odra river basin), which were monitored before and after maintenance works consisting in desilting, mowing and removal of aquatic plants. This study examined hydrological (mean depth and width of small rivers, speed and flow), physical and chemical parameter of water (temperature, pH, O2, N-NO3, N-NH4, P-PO4) before and after dredging of selected rivers. Obtained results and resulting statistical analysis demonstrated increase in hydrological indices - depth, width, speed and flow. Among other physical and chemical properties that significantly increased following completion of maintenance works, were O2 and NH4. NO3 concentration and temperature dropped, but not statistically significant. Changes in hydrological and hydrochemical properties of waters caused by maintenance works may affect biodiversity of the regulated river sections, including changes in composition of ichthyofauna species.
{"title":"The Effect of Maintenance Works to Physical and Chemical Conditions of Small Rivers in Agricultural Areas","authors":"A. Brysiewicz, P. Czerniejewski, M. Bonisławska, J. Dąbrowski","doi":"10.2478/eces-2022-0005","DOIUrl":"https://doi.org/10.2478/eces-2022-0005","url":null,"abstract":"Abstract Abiotic and biotic bounty of riparian waters may be affected by inadequate maintenance works. Improper planning and execution of maintenance works cause changes to hydrological and hydrochemical condition of water in small rivers, affecting biocenose of riverbeds by modifying the taxonomic composition of organisms inhabiting the regulated river section. Five (5) rivers were subject to studies - Plonia, Mysla, Tywa, Rurzyca, and Wardynka (Odra river basin), which were monitored before and after maintenance works consisting in desilting, mowing and removal of aquatic plants. This study examined hydrological (mean depth and width of small rivers, speed and flow), physical and chemical parameter of water (temperature, pH, O2, N-NO3, N-NH4, P-PO4) before and after dredging of selected rivers. Obtained results and resulting statistical analysis demonstrated increase in hydrological indices - depth, width, speed and flow. Among other physical and chemical properties that significantly increased following completion of maintenance works, were O2 and NH4. NO3 concentration and temperature dropped, but not statistically significant. Changes in hydrological and hydrochemical properties of waters caused by maintenance works may affect biodiversity of the regulated river sections, including changes in composition of ichthyofauna species.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"323 1","pages":"39 - 49"},"PeriodicalIF":0.0,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86770906","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Tarangini, K. Rao, S. Wacławek, M. Černík, V. Padil
Abstract In this study, nanoiron and nanoiron+Au particles were synthesised using aqueous Aegle marmelos extract using a facile and one-pot approach. Lower size non-magnetic nanoiron (~34 nm) and nanoiron (~34 nm) +Au particles (1 to 1.5 µm) were produced from the same medium individually. Nanoparticles suspension behaviour and structural characterisations were carried out by UV-Vis spectroscopy, electron microscopy and by X-ray diffraction techniques. Primarily, for synthesis, a simple bioreduction approach generated amorphous nanoiron particles, which on annealing produced magnetic maghemite, γ-Fe2O3 type nanoparticles with sizes 100 to 1000 nm. Posteriorly, the bioreduction process also produces nanoiron+Au particles and can be used for multifunctional applications. As a model application, catalytic application of the as-prepared nanoiron and nanoiron+Au particles towards methylene blue, a thiazine dye degradation is investigated and found to be effective within 20 min. Langmuir-Hinshelwood kinetic model was exploited to know the degradation behaviour, and the model was found to be fit based on R2 values with the observed experimental data. We suggest that the formed highly stable nanoiron particles with in situ stabilisation offer benefits like consistency, environmental friendliness and suits well for large-scale applicability.
{"title":"Aegle marmelos Leaf Extract Based Synthesis of Nanoiron and Nanoiron+Au Particles for Degradation of Methylene Blue","authors":"K. Tarangini, K. Rao, S. Wacławek, M. Černík, V. Padil","doi":"10.2478/eces-2022-0002","DOIUrl":"https://doi.org/10.2478/eces-2022-0002","url":null,"abstract":"Abstract In this study, nanoiron and nanoiron+Au particles were synthesised using aqueous Aegle marmelos extract using a facile and one-pot approach. Lower size non-magnetic nanoiron (~34 nm) and nanoiron (~34 nm) +Au particles (1 to 1.5 µm) were produced from the same medium individually. Nanoparticles suspension behaviour and structural characterisations were carried out by UV-Vis spectroscopy, electron microscopy and by X-ray diffraction techniques. Primarily, for synthesis, a simple bioreduction approach generated amorphous nanoiron particles, which on annealing produced magnetic maghemite, γ-Fe2O3 type nanoparticles with sizes 100 to 1000 nm. Posteriorly, the bioreduction process also produces nanoiron+Au particles and can be used for multifunctional applications. As a model application, catalytic application of the as-prepared nanoiron and nanoiron+Au particles towards methylene blue, a thiazine dye degradation is investigated and found to be effective within 20 min. Langmuir-Hinshelwood kinetic model was exploited to know the degradation behaviour, and the model was found to be fit based on R2 values with the observed experimental data. We suggest that the formed highly stable nanoiron particles with in situ stabilisation offer benefits like consistency, environmental friendliness and suits well for large-scale applicability.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"20 1","pages":"7 - 14"},"PeriodicalIF":0.0,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80687452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xueping Wang, Huibin Zhu, Yue Geng, Kexuan Ding, Lina Ye
Abstract This paper analyses and discusses the monthly and annual changes of chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) concentrations from main sewage discharge ports in Xiangshan Bay. Using monitoring data obtained from 2010 to 2019, it systematically examines the monthly variation characteristics of the sewage discharge ports and the interannual changes in the fluxes of major pollutants into the sea. The concentrations of COD, TN, and TP, which were relatively high in November and January-March, generally declined. The annual and monthly changes fluctuated, but the flux into the sea generally decreased. The ecological environment of the nearby sea area is adversely affected, chiefly by land-based pollutants. During the five-year period, COD mainly came from soil erosion and domestic pollution, while TN and TP mainly came from agricultural activities and soil erosion. Hence, it is both necessary and urgent to improve the management of the sewage outfalls from land sources into the sea.
{"title":"Investigation the Effect of the Main Land-Based Pollutants in Xiangshan Bay","authors":"Xueping Wang, Huibin Zhu, Yue Geng, Kexuan Ding, Lina Ye","doi":"10.2478/eces-2022-0004","DOIUrl":"https://doi.org/10.2478/eces-2022-0004","url":null,"abstract":"Abstract This paper analyses and discusses the monthly and annual changes of chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) concentrations from main sewage discharge ports in Xiangshan Bay. Using monitoring data obtained from 2010 to 2019, it systematically examines the monthly variation characteristics of the sewage discharge ports and the interannual changes in the fluxes of major pollutants into the sea. The concentrations of COD, TN, and TP, which were relatively high in November and January-March, generally declined. The annual and monthly changes fluctuated, but the flux into the sea generally decreased. The ecological environment of the nearby sea area is adversely affected, chiefly by land-based pollutants. During the five-year period, COD mainly came from soil erosion and domestic pollution, while TN and TP mainly came from agricultural activities and soil erosion. Hence, it is both necessary and urgent to improve the management of the sewage outfalls from land sources into the sea.","PeriodicalId":11395,"journal":{"name":"Ecological Chemistry and Engineering S","volume":"29 1","pages":"27 - 38"},"PeriodicalIF":0.0,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73274611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
X. Lv, Xinlei Wang, J. Pan, Wenhao Deng, Yuchun Li
Abstract Nitrate reductase (NR) and nitrite reductase (NiR) play important roles in nitrate assimilation in plants. Previous studies have indicated that NR and NiR in eelgrass may contribute to its NaCl tolerance. This study investigated the expression characteristics and the biological functions of NR and NiR in eelgrass (Zostera marina), named as ZmNR and ZmNiR, were cloned, characterised and overexpressed in both bacteria and tobacco. The open reading frames of ZmNR and ZmNiR contain 2628 and 1773 nucleotides that encode 875 and 590 amino acids respectively. Amino acid sequence alignment indicated that the purported ZmNR and ZmNiR proteins presented low homology with other plant NR and NiR sequences. Real-time quantitative PCR revealed that the expression of ZmNR and ZmNiR was supressed when exposed to low salinity and induced by high salinity. Further physiological analyses demonstrated that blocking nitrate assimilation by adding Na2WO4 in eelgrass reduced its tolerance to NaCl stress. The heterologous expression of the ZmNR and ZmNiR genes in Escherichia coli and Nicotiana benthamiana could confer tolerance to NaCl stress. Physiological and growth analyses suggested that ZmNR and ZmNiR in plants could resist NaCl stress by regulating various physiological pathways and biochemical processes triggered by nitric oxide (NO). Taken together, these results suggested that NR-dependent NO synthesis may play an important role in NaCl tolerance in eelgrass.
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