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Surface Water Contamination by Mining Wastes: Case of the Sidi Kambar Region (Skikda North-East Algeria) 采矿废物对地表水的污染:以西迪坎巴尔地区(阿尔及利亚东北部斯基达)为例
Pub Date : 2023-03-01 DOI: 10.2478/eces-2023-0003
F. Fekrache, K. Boudeffa
Abstract The objective of this work is to assess the contamination of the Essouk stream, under acid drainage from the Sidi Kambar mine (southwest of Skikda, Algeria), which has been widely exploited during the previous decades. The methodology was conducted to control the current state of water chemistry, its evolution in space and time according to the variation of water physicochemical parameters and the content of trace metals (Pb, Fe, and Zn). In general, Essouk stream are highly sulphated (reached 598.56 mg/L) and have an elevated salinity, resulting in a high conductivity (1925 µS/cm) and presented a low pH (3.01). In addition, Fe, Pb and Zn contents reached 5.17 mg/L, 2.05 mg/L and 4.05 mg/L, respectively. Such results were linked to the bedrock of Sidi Kambar that is composed of galena, pyrite and sphalerite.
摘要本研究的目的是评估来自Sidi Kambar矿(阿尔及利亚Skikda西南部)的酸性排水对Essouk溪流的污染,该矿在过去几十年中被广泛开采。该方法根据水体理化参数的变化及微量金属(Pb、Fe、Zn)的含量,控制水体化学的现状及其时空演化。一般来说,Essouk流具有高硫酸盐(达到598.56 mg/L)和高盐度,导致高电导率(1925µS/cm)和低pH(3.01)。铁、铅、锌含量分别达到5.17 mg/L、2.05 mg/L和4.05 mg/L。这些结果与西迪坎巴尔的基岩有关,基岩由方铅矿、黄铁矿和闪锌矿组成。
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引用次数: 1
Study on the Ecological Succession of Microbial Communities During Hot Composting of Livestock Manure 畜禽粪便热堆肥过程中微生物群落生态演替的研究
Pub Date : 2023-03-01 DOI: 10.2478/eces-2023-0005
X. Zhen, T. Dong, Jia Liu, Miao Luo, Shun-Jie Li
Abstract There have been various environmental issues in the treatment and resource utilisation of solid waste of livestock and poultry industry in Gansu Province. Thus, in this study, manure of cattle, pig, and chicken from farms near the Lanzhou University of Technology in Lanzhou City, Gansu Province were selected as raw materials for composting using 10 % corn stalk as a leavening agent for aerobic static composting. This study focused on bacterial, fungal, and actinomycetes community succession during livestock manure composting and the underlying microbial degradation mechanism. The results demonstrated that during livestock manure composting, the number of the above-mentioned types of microbes was all positively correlated with the temperature of the compost piles. In the initial stage of composting, the number of microbes increased as the temperature increased, and reached the peaks at the highest temperature, after which, their numbers decreased with the decrease in temperature. At the end of composting, in the cattle, pig, and chicken manure compost piles, the number of bacteria were respectively (3.1 ±1.0) · 109 CFU·g−1 d.w., (4.4 ±1.0) · 109 CFU·g−1 d.w. and (6.7 ±1.8) · 109 CFU·g−1 d.w., respectively, those of fungi were (8.6 ±1.2) · 104 CFU·g−1 d.w., (7.2 ±1.6) · 104 CFU·g−1 d.w. and (8.0 ±2.8) · 104 CFU·g−1 d.w., respectively, while those of actinomycetes were (8.8 ±2.2) · 106 CFU·g−1 d.w., (9.5 ±2.1) · 106 CFU·g−1 d.w. and (6.32 ±0.98) · 106 CFU·g−1 d.w., respectively.
摘要甘肃省畜禽工业固体废弃物的处理和资源化利用存在着各种环境问题。因此,本研究选择甘肃省兰州市兰州理工大学附近农场的牛粪、猪粪和鸡粪作为堆肥原料,以10%玉米秸秆为膨松剂进行好氧静态堆肥。研究了畜禽粪便堆肥过程中细菌、真菌和放线菌的群落演替及其微生物降解机制。结果表明,在畜禽粪便堆肥过程中,上述微生物数量均与堆肥堆温度呈正相关。在堆肥初期,微生物数量随着温度的升高而增加,在最高温度时达到峰值,之后随着温度的降低而减少。堆肥结束时,牛、猪、和鸡粪堆肥桩,细菌的数量分别为(3.1±1.0)·109 CFU·克−1 d.w。,(4.4±1.0)·109 CFU·克−1 d.w.和(6.7±1.8)·109 CFU·克−1 d.w。,分别的真菌(8.6±1.2)·104 CFU·g−1 d.w。(7.2±1.6)·104 CFU·克−1 d.w.和(8.0±2.8)·104 CFU·克−1 d.w。,分别,而放线菌106 CFU(8.8±2.2)··g−1 d.w。(9.5±2.1)·106 CFU·克−1 d.w.和(6.32±0.98)·106 CFU·克−1 d.w。,分别。
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引用次数: 0
Model of Deep Information Environmental Factors on the Development of ICE and Snow Sports 冰雪运动发展的深度信息环境因素模型
Pub Date : 2023-03-01 DOI: 10.2478/eces-2023-0013
Yongguo Zhu, Qiao Li, Zhanpeng Ying, Shuxin Tian
Abstract Driven by national policies and international competitions, China’s winter sports and industry development will enter a new course. How to release the enormous potential skiing demand in China is significant to drive 300 million people to participate in winter sports and promote the development of China’s ice and snow industry, and defining the restrictive factors is a necessary prerequisite to realise the effective transformation of potential demand to actual growth power. Based on the in-depth information, this paper further analyses the influence of environmental factors on the development of winter sports. The research shows that the number of skiers about 20 times is the highest, up to 75.5 %, followed by the number of skiers about five times, up to 67.4 %. Then about ten times accounted for 48.6 %, and finally, about 15 times accounted for 37.6 %. This frequency can fully satisfy skiing enthusiasts to enjoy leisure activities, experience modern life fashion, use skiing to increase social opportunities, delight body and mind, and improve health. Based on the in-depth information, this paper reveals the shortcomings and existing environmental factors of China’s winter sports development. It provides a reference for the rational utilisation and development of ice and snow resources and the scientific and practical development of China’s winter sports.
在国家政策和国际竞争的推动下,中国冬季运动及产业发展将进入一个新的进程。如何释放中国巨大的潜在滑雪需求,对于带动3亿人参与冬季运动、推动中国冰雪产业发展具有重要意义,明确制约因素是实现潜在需求有效转化为实际增长动力的必要前提。在深入了解的基础上,进一步分析了环境因素对冬季运动发展的影响。研究表明,滑雪次数最多的是20次左右,达75.5%,其次是5次左右,达67.4%。10倍左右占48.6%,最后15倍左右占37.6%。这个频率可以充分满足滑雪爱好者享受休闲活动,体验现代生活时尚,用滑雪增加社交机会,愉悦身心,增进健康。在深入了解的基础上,揭示了中国冬季运动发展的不足和存在的环境因素。为冰雪资源的合理利用和开发,以及中国冬季运动的科学化、实用化发展提供参考。
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引用次数: 0
The Interaction and Coupling Between Enterprise Value Evaluation and Regional Ecological Environment 企业价值评价与区域生态环境的互动与耦合
Pub Date : 2023-03-01 DOI: 10.2478/eces-2023-0012
Guopeng Zhang, Xin-Ran Chen, Zhi-Ren Li
Abstract The development of industrial Internet technology enterprises plays an important supporting role in green water and green mountains, as a forestry industry with both economic value and ecological value. at present, it is facing a good opportunity for development. However, industrial Internet technology enterprises are faced with many risks, such as long investment cycle, low comparative income, and their ecological value is easy to be ignored. Based on FCFF model and LINEST function, this paper studies the enterprise value evaluation and ecological development. The main conclusions are as follows: (1) the economic value of industrial Internet technology enterprises is greatly affected by non-financial factors; (2) the excess income of industrial Internet technology enterprises is affected by ecological improvement. (3) under the background of green finance, the comprehensive operation ability of enterprises can be effectively improved through internal control of enterprises, formulation of government laws and supervision of social enterprises. This study has important theoretical and practical significance for China to scientifically and reasonably evaluate the value of industrial Internet technology enterprises.
工业互联网科技企业作为兼具经济价值和生态价值的林业产业,其发展具有绿水青山的重要支撑作用。目前,它正面临着一个很好的发展机遇。然而,工业互联网科技企业面临着投资周期长、比较收益低等诸多风险,其生态价值容易被忽视。本文基于FCFF模型和LINEST函数,对企业价值评价与生态发展进行了研究。主要结论如下:(1)工业互联网科技企业的经济价值受非财务因素影响较大;(2)工业互联网科技企业的超额收益受到生态改善的影响。(3)在绿色金融背景下,通过企业内部控制、政府法律的制定和社会企业的监管,可以有效提高企业的综合经营能力。本研究对中国科学合理地评价工业互联网科技企业价值具有重要的理论和现实意义。
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引用次数: 0
On the Influence of the Nugget Effect on the Efficiency of Magnetometric Soil Surface Screening 核块效应对磁强计土壤表面筛分效率的影响
Pub Date : 2022-12-01 DOI: 10.2478/eces-2022-0038
J. Zawadzki, P. Fabijańczyk
Abstract The paper presents selected aspects of calculations and modelling of variograms from measurements of soil surface magnetic susceptibility for rapid screening of surface soil contamination with Technogenic Magnetic Particles (TMP). In particular, the methodology of variogram analysis in the case of multiple magnetometric measurements in one measurement location with the use of the MS2D Bartington sensor was discussed. A new approach to analysing such measurements was proposed that allows determining and using the nugget effect from standard, already existing measurements. This is of key importance for the quality of spatial analyses, and thus the screening results obtained by means of field magnetometry. In the paper, it was shown, step by step, that averaging the measurements performed at one measurement point during the calculation of the empirical variograms does not result in the loss of information on spatial variability in the microscale. As it was calculated non-averaged measurements were characterised by the nugget-to-sill ratio of about 96 % which was much higher than in the case of averaged measurements (close to 0 %). A range of correlation was similar in both cases and was equal to about 300 m - 400 m. The local variogram revealed a range of correlation of about 80 cm. As a result, the screening results are more reliable than is the case with the traditional procedure. An additional advantage of the work was the performance of all calculations in free R software.
摘要:本文介绍了土壤表面磁化率测量的变异函数的计算和建模的选择方面,以快速筛选表面土壤污染的技术磁性颗粒(TMP)。特别地,讨论了使用MS2D巴丁顿传感器在一个测量位置进行多次磁强计测量的变差分析方法。提出了一种分析这种测量的新方法,允许从标准的、已经存在的测量中确定和使用金块效应。这对于空间分析的质量至关重要,因此通过磁场测量获得的筛选结果也至关重要。本文逐步证明,在计算经验变差时,对一个测量点的测量取平均值不会导致微尺度空间变异性信息的丢失。根据计算结果,非平均测量的特征是块岩与地基的比率约为96%,远高于平均测量的情况(接近0%)。在这两种情况下,相关范围是相似的,大约等于300米- 400米。局部变异图显示相关范围约为80 cm。因此,筛选结果比传统程序更可靠。这项工作的另一个优点是所有的计算都是在免费的R软件中进行的。
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引用次数: 1
The Synthesis of 2,2-BIS(1-INDOL-3-YL)Acenaphthylene-1(2)-Ones Using Nanocatalysis: Fluorescent Sensing for Cu2+ Ions 纳米催化合成2,2- bis (1-INDOL-3-YL)苊-1(2)-Ones:对Cu2+离子的荧光传感
Pub Date : 2022-12-01 DOI: 10.2478/eces-2022-0033
G. Mohammadi Ziarani, Mahdieh Khademi, Fatemeh Mohajer, A. Badiei, R. Varma
Abstract 2,2-bis(1H-indol-3-yl)acenaphthylene-1(2H)-ones were synthesised by the reaction of acenaphthenequinone and 2 equivalents of indole using Fe3O4@SiO2@Si-Pr-NH-CH2CH2NH2 as the basic magnetic nanocatalyst, assembled under greener and sustainable conditions in high purity and yields. Furthermore, the photoluminescence properties of 2,2-bis(2-methyl-1H-indol-3-yl)acenaphthylene-1(2H)-one were exploited for the sensing of copper ions in the mixed solvent systems comprising H2O and CH3CN in excitation wavelength at 410 nm with a detection limit of 9.5 ∙ 10–6 M.
摘要以Fe3O4@SiO2@Si-Pr-NH-CH2CH2NH2为基本磁性纳米催化剂,以苊马醌和2个吲哚等价物为原料,合成了2,2-双(1h -吲哚-3-基)苊-1(2H)- 1。此外,利用2,2-二(2-甲基- 1h -吲哚-3-酰基)苊-1(2H)- 1的光致发光特性,在由H2O和CH3CN组成的混合溶剂体系中探测铜离子,激发波长为410 nm,检出限为9.5∙10-6 M。
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引用次数: 0
The Impact of Propanol, N-Butanol and Pentanol on Aqueous Dispersions of Sonicated Liposomes. EPR Study 丙醇、正丁醇和正丁醇对超声脂质体水分散的影响。电子顺磁共振研究
Pub Date : 2022-12-01 DOI: 10.2478/eces-2022-0032
Agnieszka Bartnikowska, B. Pytel, D. Man
Abstract This paper presents the effect of selected alcohols on the fluidity of liposome membranes obtained in sonication of DPPC lecithin. Using the EPR technique, the duality of propanol, n-butanol and pentanol on the behaviour of the aqueous dispersion of liposomes was demonstrated. It was shown that after exceeding a certain concentration, these alcohols initiate dispersion foaming, leading to phase separation: liposome dispersion - lipid foam. The influence of the shape of the molecule and the length of hydrocarbon chains on the effectiveness of destabilisation of the structure of lipid membranes was indicated.
摘要本文研究了不同醇类对超声提取DPPC卵磷脂所得脂质体膜流动性的影响。利用EPR技术,证明了丙醇、正丁醇和戊醇的二元性对脂质体水分散行为的影响。结果表明,在超过一定浓度后,这些醇引发分散性泡沫,导致相分离:脂质体分散-脂质泡沫。指出了分子形状和烃链长度对脂质膜结构失稳效果的影响。
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引用次数: 0
Marine Biotoxin Profile and Karenia selliformis and Alexandrium minitum Occurrence in Boughrara Lagoon During the Last Decade 近十年来Boughrara泻湖海洋生物毒素分布与水生卡雷氏菌和亚历山大菌的发生
Pub Date : 2022-12-01 DOI: 10.2478/eces-2022-0037
R. Marrouchi, Moufida Abdennadher, W. Feki-Sahnoun, Zeineb Marzougui, I. Hamza, A. Hamza, R. Kharrat
Abstract As part of the routine control of the Tunisian network for the monitoring of the most problematic microalgae species Karenia selliformis and Alexandrium minutum and for the study of hydrophilic and lipophilic marine biotoxin profiles, clams and seawater samples from Boughrara lagoon were analysed during the past decade. The results showed that the abundance of Karenia selliformis and Alexandrium minutum in the Boughrara lagoon exhibited significant variability at annual scales. K. selliformis was recorded in all sampling years with interannual variability. Among the nine sampled years, 2010, 2012, 2016 and 2017 were, respectively, the most significant in terms of mean abundance (2.85, 2.42, 1.38, 1.69) ∙ 105 cells L–1. A. minutum species were observed in the water column during all investigated years except in 2013, 2016 and 2017, but in low concentrations compared to K. selliformis (≤ 7.4 ∙ 102 cells L–1). Using LC-FLD, traces of paralytic toxins (C1 and GTX-2) were detected in some clam samples. Their concentrations were largely below the regulatory limit. For the first time, N-sulfocarbamoyl gonyautoxin-2 (C-1) and gonyautoxin 2 (GTX-2) were detected in some clam samples from this region. LC-MS/MS analysis confirmed the presence of gymnodimines in some samples. The main peak corresponds to the GYM-A with high concentrations generally above 1 mg kg–1 of clams meat, which confirms the persistence of this neurotoxin in Boughrara lagoon.
摘要:作为突尼斯监测最具问题的微藻物种卡雷氏藻(Karenia selliformis)和微小亚历山大藻(Alexandrium minutum)的常规控制网络的一部分,以及亲水和亲脂性海洋生物毒素谱的研究,在过去十年中分析了Boughrara泻湖的蛤蜊和海水样本。结果表明:包拉拉泻湖中有丝卡雷氏菌(Karenia selliformis)和小亚历山大菌(Alexandrium minutum)的丰度在年尺度上表现出显著的变化。在所有取样年份均有记录,且具有年际变异性。在9个采样年份中,2010年、2012年、2016年和2017年的平均丰度分别为2.85、2.42、1.38、1.69)∙105个细胞L-1。除2013年、2016年和2017年外,所有调查年份的水柱中均有细小棘球蚴存在,但与selliformis相比浓度较低(≤7.4∙102 cells L-1)。使用LC-FLD,在一些蛤样品中检测到微量麻痹毒素(C1和GTX-2)。它们的浓度大多低于规定限值。在该地区部分蛤类样品中首次检出n-磺胺氨基甲酰性腺毒素-2 (C-1)和性腺毒素2 (GTX-2)。LC-MS/MS分析证实部分样品中存在裸子二胺。主峰对应于高浓度的GYM-A,通常超过1 mg kg-1的蛤肉,这证实了这种神经毒素在Boughrara泻湖的持久性。
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引用次数: 1
Effect of Soil Application of Zeolite-Carbon Composite, Leonardite and Lignite on the Microorganisms 沸石炭复合材料、褐煤和褐煤对土壤微生物的影响
Pub Date : 2022-12-01 DOI: 10.2478/eces-2022-0040
K. Wolny-Koładka, Lidia Marcińska-Mazur, R. Jarosz, M. Juda, T. Lošák, M. Mierzwa-Hersztek
Abstract The aim of the study was to evaluate the effect of mineral-organic mixture on changes in the abundance of selected soil microorganisms. The experiment contained: soil with NPK (nitrogen, potassium, phosphorus) + 3 % or 6 % lignite (MF+CW3 %, MF+CW6 %) and 3 % zeolite-carbon composite (NaX-C); soil with NPK + 3 % or 6 % leonardite (MF+CL3 %, MF+CL6 %) and 3 % NaX-C; soil without fertilisation (C); soil fertilised with mineral NPK fertilisers (MF). Plants participating in the experiment were spring wheat and spring oilseed rape. The presence of the selected microorganisms was determined: Azotobacter spp., actinomycetes, ammonifiers, bacteria and mold fungi. Using Koch’s serial dilution method, the abundance of selected soil microorganisms was performed. The conducted research allows to conclude that the abundance of detected microorganisms depended on both the applied fertilisation and the plant grown. For the spring oilseed rape, the highest abundance of microorganisms was determined in treatments where fertilisation with lignite mixtures was applied, while for spring wheat, with leonardite mixtures. Increasing (from 3 % to 6 %) the share of lignite and leonardite in fertiliser mixtures did not translate into a proportional growth in the abundance of microorganisms, so such a treatment has no economic justification. Given their alkaline pH, the mixtures used can be a substitute for calcium fertilisers to improve soil properties and, consequently, protect soil organic matter from degradation.
摘要本研究的目的是评价矿物-有机混合物对土壤微生物丰度变化的影响。试验条件为:NPK(氮、钾、磷)+ 3%或6%褐煤(MF+CW3 %, MF+CW6 %)和3%沸石碳复合材料(NaX-C)土壤;NPK + 3%或6% (MF+ cl3%, MF+ cl6%)和3% NaX-C的土壤;没有施肥的土壤(C);施用无机氮磷钾(MF)的土壤。参与试验的植物为春小麦和春油菜。确定了所选微生物的存在:固氮菌、放线菌、氨化菌、细菌和霉菌。采用科赫系列稀释法,测定所选土壤微生物的丰度。所进行的研究可以得出这样的结论:检测到的微生物的丰度取决于所施用的肥料和所种植的植物。对春油菜来说,微生物丰度最高的处理是施用褐煤混合物施肥,而对春小麦来说,施用莱纳迪石混合物施肥。增加肥料混合物中褐煤和褐铁矿的比例(从3%增加到6%)并没有转化为微生物丰度的比例增长,因此这种处理没有经济理由。鉴于其碱性pH值,所使用的混合物可以替代钙肥,以改善土壤性质,从而保护土壤有机质免受降解。
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引用次数: 2
Emissions from Municipal Solid Waste Transport Vehicles: Case Study Banja Luka Region (B&H) 城市固体废物运输车辆排放:巴尼亚卢卡地区案例研究(B&H)
Pub Date : 2022-12-01 DOI: 10.2478/eces-2022-0036
Draženko Bjelić, B. Malinovic, Dragana Nešković Markić
Abstract Waste transport is just one of the segments in the solid municipal waste management. Throughout the entire waste life cycle, starting by generation of waste, via storing, collecting, transporting, recycling, treating and depositing, several different polluting substances are emitted. The solid waste transport, apropos, transporting vehicles emit into the air different pollution substances such as CO2, CO, NOx, NMVOC, PM, PAHs etc. These substances can present certain problems for human health and environment. The research subject of this study is the analysis of solid waste transportation within the Banja Luka region (B&H), from towns and municipalities belonging to the region and transporting their mixed municipal waste to the Banja Luka landfill. In the analysis, following parameters are included: distance to the landfill, type of vehicle used for the waste transportation, type of the engine, vehicle capacity and the number of tours during a year. The study estimates the emission of CO, NOx, NMVOC, and PM2.5 during one year using the listed parameters and by applying EMEP/EEA guidelines for estimating the emission of polluting substances into the air. The largest emission of polluting substances (CO, NOx, NMVOC and PM2.5) is from the oldest vehicles. The newest vehicles had a significantly lesser emission of these polluting substances into the air. The recommendation for decreasing the emission from the transportation vehicles is to organise the transfer-stations, procure new vehicles, optimise the collection routes and decrease the number of tours, as well as to better the usage of the vehicle capacity level.
摘要垃圾运输只是城市固体废物管理的一个环节。在整个废物生命周期中,从废物产生开始,通过储存、收集、运输、回收、处理和存放,排放出几种不同的污染物质。固体废物运输、运输车辆向大气排放不同的污染物质,如CO2、CO、NOx、NMVOC、PM、PAHs等。这些物质会给人类健康和环境带来一定的问题。本研究的研究主题是分析巴尼亚卢卡地区(B&H)内的固体废物运输,从属于该地区的城镇和市政当局将其混合城市废物运输到巴尼亚卢卡填埋场。在分析中,包括以下参数:到垃圾填埋场的距离,用于废物运输的车辆类型,发动机类型,车辆容量和一年的旅行次数。该研究使用列出的参数,并应用EMEP/EEA估计空气中污染物质排放的指南,估计一年内CO, NOx, NMVOC和PM2.5的排放量。排放最多污染物质(一氧化碳、氮氧化物、NMVOC和PM2.5)的是老旧车辆。最新的汽车向空气中排放的这些污染物质明显减少了。减少运输车辆排放的建议是:组织转运站、购置新车辆、优化收集路线、减少行程,以及提高车辆容量的使用水平。
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引用次数: 0
期刊
Ecological Chemistry and Engineering S
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