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Investigation of the Oxidative Stability of Li-Ion Battery Electrolytes Using Cathode Materials 正极材料对锂离子电池电解质氧化稳定性的研究
Pub Date : 2015-01-01 DOI: 10.1149/2.0071512EEL
A. Hofmann, Felix Werth, A. Höweling, T. Hanemann
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引用次数: 5
Detection of Internal Defects in Lithium-Ion Batteries Using Lock-in Thermography 利用锁定热成像技术检测锂离子电池内部缺陷
Pub Date : 2015-01-01 DOI: 10.1149/2.0071509EEL
J. Robinson, Erik Engebretsen, D. Finegan, J. Darr, G. Hinds, P. Shearing, D. Brett
Effective thermal management is essential for maximising performance and durability of Li-ion batteries. Infrared thermal imaging is an established technique for studying temperature distribution in real-time with high spatial resolution; however, dynamic thermal imaging offers greater sensitivity, the ability to correct for emissivity variation and identify heat transfer mechanisms and internal defects. Here, for the first time, lock-in thermography using a thermal imaging camera is applied to Li-ion batteries to investigate the effect of periodic electro-thermal stimulation on the amplitude and phase response of both new and aged Li-ion pouch cells. We demonstrate the effectiveness of this technique in the detection of gas pockets formed during cell aging and propose its application in the identification of a range of internal defects in operational systems and validation of thermal models.
有效的热管理对于最大限度地提高锂离子电池的性能和耐用性至关重要。红外热成像是一种成熟的高空间分辨率、实时研究温度分布的技术;然而,动态热成像提供了更高的灵敏度,校正发射率变化和识别传热机制和内部缺陷的能力。本文首次将热像仪的锁定热成像技术应用于锂离子电池,研究了周期性电热刺激对新旧锂离子袋状电池振幅和相位响应的影响。我们证明了该技术在检测细胞老化过程中形成的气囊方面的有效性,并提出了将其应用于识别操作系统中的一系列内部缺陷和验证热模型。
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引用次数: 38
Fabrication of a Sensitive Sensor for Oxygen Using Nitrogen-Doped Carbon Nanotubes-Fe3C Nanoparticles 氮掺杂碳纳米管- fe3c纳米颗粒制备氧敏感传感器
Pub Date : 2015-01-01 DOI: 10.1149/2.0081508EEL
Endong Xing, Yujie Dong, Jun Shi, Weimin Huang
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引用次数: 1
Copper Bottom-up Filling for Through Silicon Via (TSV) Using Single JGB Additive 用单一JGB添加剂自底向上填充通硅孔(TSV)
Pub Date : 2015-01-01 DOI: 10.1149/2.0101509EEL
Junlei Tang, Q. Zhu, Yan Zhang, Xiao Zhang, Jinsong Guo, J. Shang
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引用次数: 34
Preparation of Mesoporous Si@PAN Electrodes for Li-Ion Batteries via the In-Situ Polymerization of PAN 原位聚合法制备锂离子电池介孔Si@PAN电极
Pub Date : 2015-01-01 DOI: 10.1149/2.0011503EEL
Thomas A. Yersak, Jaewook Shin, Ziying Wang, Daniel Estrada, J. Whiteley, Sehee Lee, M. Sailor, Y. Meng
(electrode), the first cycle coulombic efficiency of these electrodeswas still less than 50% without a pre-lithiation treatment. The results of an all-solid-state battery experiment confirmed that low firstcycle reversibility should be attributed primarily to mechanical pulverization of the internal porous structure of mp-Si particles.© 2015 The Electrochemical Society. [DOI: 10.1149/2.0011503eel] All rights reserved.Manuscript received December 12, 2014. Published January 9, 2015.
在未进行预锂化处理的情况下,这些电极的第一循环库仑效率仍低于50%。全固态电池的实验结果证实,低第一循环可逆性主要归因于mp-Si颗粒内部多孔结构的机械粉碎。©2015电化学学会。[DOI: 10.1149/2.0011503]版权所有。稿收于2014年12月12日。出版于2015年1月9日。
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引用次数: 7
Electrochemical Characterization of Iodide Ions Adsorption Kinetics at Bi(111) Electrode from Three-Component Ionic Liquids Mixtures 三组分离子液体混合物在Bi(111)电极上吸附碘离子动力学的电化学表征
Pub Date : 2015-01-01 DOI: 10.1149/2.0011512EEL
C. Siimenson, Liis Siinor, K. Lust, E. Lust
The electrochemical behavior of RTIL mixtures containing 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-ethyl-3methylimidazolium trifluoromethanesulfonate and 1-ethyl-3-methylimidazolium iodide were characterized by using cyclic voltammetry and electrochemical impedance spectroscopy methods. The capacitance values of the system at potentials more positive than −0.6 V (vs. Ag|AgCl| mixture of RTIL) strongly depend on the chemical nature of the anions in the mixture. Also the strong adsorption of I− at Bi(111) (well-known in aqueous and classical organic solvents) has been demonstrated in RTIL media. The capacitance values are noticeably higher for EMImOTF + EMImBF4 + 1 wt% EMImI than that for EMImOTF + 1 wt% EMImI. © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. [DOI: 10.1149/2.0011512eel] All rights reserved.
采用循环伏安法和电化学阻抗法表征了含1-乙基-3-甲基咪唑四氟硼酸盐、1-乙基-3-甲基咪唑三氟甲磺酸盐和1-乙基-3-甲基咪唑碘化物的RTIL混合物的电化学行为。当电位大于- 0.6 V时,系统的电容值(相对于RTIL的Ag|AgCl|混合物)强烈依赖于混合物中阴离子的化学性质。此外,在RTIL介质中也证明了I - at Bi(111)的强吸附(在水溶剂和经典有机溶剂中众所周知)。EMImOTF + EMImBF4 + 1 wt% EMImI的电容值明显高于EMImOTF + 1 wt% EMImI。©作者2015。由ECS出版。这是一篇基于知识共享署名4.0许可(CC BY, http://creativecommons.org/licenses/by/4.0/)的开放获取文章,该许可允许在任何媒体上不受限制地重复使用该作品,前提是正确引用原始作品。[DOI: 10.1149/2.0011512eel]版权所有
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引用次数: 12
The Graphitization of Cellular Carbons and Their Electrochemical Performances in Electrical Double-Layer Capacitors 双层电容器中细胞碳的石墨化及其电化学性能
Pub Date : 2015-01-01 DOI: 10.1149/2.0011511EEL
Zijie Xu, Jingya Wang, Fenfen Wang, Z. Hu, L. Gan
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引用次数: 2
Electroplating of Aluminium on Silicon in an Ionic Liquid 离子液体中铝在硅上的电镀
Pub Date : 2015-01-01 DOI: 10.1149/2.0021504EEL
Wen-cheng Sun, Xiaofei Han, M. Tao
Electroplating of aluminum (Al) on silicon (Si) substrates has been demonstrated in an above-room-temperature ionic liquid for the metallization of wafer-Si solar cells. The electrolyte was prepared by mixing anhydrous aluminum chloride and 1-ethyl-3-methylimidazolium tetrachloroaluminate. The plating was carried out by means of galvanostatic electrolysis. The structural and compositional properties of the Al deposits were characterized, and the sheet resistance of the deposits revealed the effects of pre-bake conditions, deposition temperature, and post-deposition annealing conditions. It was found that dense, adherent Al deposits with resistivity in the high 10[superscript −6] Ω-cm range can be reproducibly obtained directly on Si substrates.
在室温以上的离子液体中,在硅(Si)衬底上电镀铝(Al),用于硅片太阳能电池的金属化。电解质由无水氯化铝和1-乙基-3-甲基咪唑四氯铝酸盐混合制备。电镀是用恒流电解的方法进行的。表征了Al镀层的结构和组成特性,镀层的片状电阻受预焙条件、沉积温度和沉积后退火条件的影响。结果发现,在Si衬底上可以直接获得电阻率在10[上标−6]Ω-cm范围内的致密、粘附的Al沉积。
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引用次数: 6
Pinning Effect of Fe(ClO) and Ti(ClO) Compounds on Cu Grain Growth in Very Narrow Cu Wires Fe(ClO)和Ti(ClO)化合物对极窄铜丝中Cu晶粒生长的钉钉效应
Pub Date : 2015-01-01 DOI: 10.1149/2.0021511EEL
T. Nagano, Y. Sasajima, N. Ishikawa, Kunihiro Tamahashi, K. Hidaka, J. Onuki
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引用次数: 6
Extremely Sensitive SERS Detection through the One-Step Fabrication of a Composite Nanostructure of Substrate and Analyte 通过一步制备衬底和分析物复合纳米结构的极灵敏SERS检测
Pub Date : 2015-01-01 DOI: 10.1149/2.0051512EEL
Xing Yang, Qiong Wang, J. Fan, Min Zhang, Zhaoying Zhou, Jia-cheng Ji
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引用次数: 1
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