The introduction of pyrolytic carbon (PyC) interphase in SiCf/SiC composites significantly improves their toughness, primarily by deflecting matrix cracks, while the underlying toughening mechanisms toward various PyC microstructures remain mysterious due to the challenges in experimentally observing microscopic deformations within PyC. This paper addresses this gap by constructing distinct PyC models based on orientation angle (OA), a key experimental characteristic, and then conducting Mode I loading simulations on SiCf/PyC/SiC systems by molecular dynamics (MD). Results indicate that as OA increases, the deformation behavior of PyC transits from multilayer sliding to delamination, which correlates to a reduction in the fracture energy of SiCf/PyC/SiC systems. Energy dissipation models are established for two microscopic deformation patterns as multilayer sliding and delamination based on homogenization theory, with results demonstrating that the energy dissipation caused by multilayer sliding within PyC surpasses that of delamination. Furthermore, mesoscale stochastic simulations of crack propagation in PyC with different textures are carried out to obtain crack path configurations and corresponding energy dissipations. The outcomes highlight the superior toughening effect of high texture (HT) PyC over medium texture (MT) and low texture (LT) PyC due to longer crack path within HT PyC, aligning well with experimental findings. This study provides valuable insights into cracking through PyC with varying textures, offering a foundation for optimizing PyC coating processes in SiCf/SiC composites to enhance performance.