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Characteristics of the stratigraphic reservoirs and caprocks of the geothermal resources in the Northwestern Shandong region 鲁西北地区地热资源地层储盖层特征
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-06-20 DOI: 10.1177/01445987231183181
Yongming Liu, Zhang Tao, Honghong Zhang, Xing Jin, Xiaofei Ji, Xiaojing Li, M. Meng, Zengxue Li, Jiamin Liu, Xuchao Li
The genetic relationships between the stratigraphic textures, thickness changes, burial depths, and the characteristics of the geothermal zoning of the Cenozoic in the northwestern Shandong region were analyzed in this study. Methods involving segmented water temperature measurements of geothermal well drilling, wellhead hydrological surveys, geothermal reservoirs, and caprock thickness measurements and statistics were adopted. The following findings were revealed in this study's research results: (1) The Paleogene and Neogene reservoir types in the northwestern Shandong region were determined to be mainly water-bearing fine sandstone and medium-fine sandstone pores, with thick layered, interbedded, and zoned stratigraphic structures. The layered and zoned geothermal reservoirs were found to be primarily distributed in a zonal manner on the bedding plane and characterized by good regional continuity. The fine sandstone and medium-fine sandstone sections with well-developed pores and high water content levels were geothermal reservoirs, while mudstone sections were geothermal barriers. The reservoirs and barriers were characterized by interlayer structures; (2) The boundary between the sag basin and the uplifting was taken as the dividing line of the geothermal fields, and the geothermal areas in the northwestern Shandong region were divided into different geothermal fields, all belonging to the sedimentary basin's conductive geothermal resources; (3) The major geothermal reservoirs included the lower members of the Neogene Minghuazhen Formation, Guantao Formation, and Dongying Formation. The Quaternary argillaceous sediment and the mudstone in the upper member of the Minghuazhen Formation formed the caprocks in the study area. In this study, the macroscopic distribution laws of geothermal resources in the northwestern Shandong region were proposed and were considered to have practical significance for further exploration and development.
分析了鲁西北地区新生代地层结构、厚度变化、埋藏深度与地温分带特征的成因关系。采用地热井钻井分段水温测量、井口水文测量、地热储层测量和盖层厚度测量统计等方法。研究结果表明:①鲁西北地区古近系和新近系储层类型以含水细砂岩和中细砂岩孔隙为主,具有较厚的层状、互层状、分带型地层构造;层状分带型地热储层在层理平面上主要呈分带分布,具有较好的区域连续性。孔隙发育、含水率高的细砂岩和中细砂岩段为地热储层,泥岩段为地热屏障。储层和屏障以层间构造为特征;(2)以凹陷盆地与隆起带边界为地热田分界线,将鲁西北地区的地热区划分为不同的地热田,均属于沉积盆地的传导性地热资源;(3)主要储层为新近系明化镇组、馆陶组和东营组下段。研究区盖层主要由第四纪泥质沉积和明化镇组上段泥岩构成。提出了鲁西北地区地热资源的宏观分布规律,对进一步勘探开发具有现实意义。
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引用次数: 0
Milankovitch cycle of continental deep-water fine-grained sedimentary rocks in the lower submember of Es3 of Well FY1 in Dongying Sag and its significance for shale oil exploration 东营凹陷FY1井沙三下亚段陆相深水细粒沉积岩Milankovitch旋回及其页岩油勘探意义
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-06-19 DOI: 10.1177/01445987231181721
Wei Wu, Lin Zhang, Yibo Qiu, Guangxu Wang, Jing Yu
China has recently faced significant difficulties in the exploitation of its shale oil and gas resources. An essential geological obstacle preventing the breakthrough of Chinese shale oil exploration is the precise identification of productive oil and gas pools and ideal formation. Therefore, it is crucial to examine the properties of shale reservoirs. Deep-water fine-grained sedimentary rocks in the lower member of the Well FY1 in Dongying Sag are analyzed using the Milankovitch cycle based on core, geochemical analysis, and gamma logging data. The findings demonstrate that: (1) The entire Milankovitch cycle is preserved in the Es3x of Well FY1 in Dongying Sag, and that the long Eccentricity of 405 ka and the Precession cycle of 23.2 ka are the key controlling factors in the deposition. (2) The “three-end-member” method is used to divide eight different types of lithofacies. The main vertical changes in these lithofacies are from organic massive gray mudstone to organic lamellar callitic mudstone to organic massive gray mudstone to organic lamellar gray mudstone to organic lamellar gray mudstone and back again. From shallow to deep to deeper, the entire water depth fluctuated. (3) Each of the four lengthy Eccentricity cycles has a half-cycle of warm, humid weather and cold, dry weather. Analysis was done on how the lithofacies and organic matter concentration changed with high and small eccentricities. The enrichment of biological materials in warm, wet, dry, and cold climates was hypothesized by examining the response of fine-grain sedimentary rocks to eccentricities and Precession periods. Larger Eccentricity is thought to be more suitable for storing shale oil.
中国最近在开采页岩油气资源方面遇到了重大困难。制约中国页岩油勘探突破的一个重要地质障碍是对生产油气藏和理想储层的准确识别。因此,研究页岩储层的性质至关重要。在岩心、地球化学分析和伽马测井资料的基础上,利用Milankovitch旋回对东营凹陷FY1井下段深水细粒沉积岩进行了分析。结果表明:(1)东营凹陷FY1井es3段保存了完整的Milankovitch旋回,405 ka的长偏心率和23.2 ka的旋进旋回是控制沉积的关键因素。(2)采用“三端元法”划分出8种不同类型的岩相。这些岩相的纵向变化主要是由有机块状灰色泥岩到有机片层状泥质泥岩,再到有机块状灰色泥岩到有机片层状灰色泥岩再到有机片层状灰色泥岩。从浅到深再到深,整个水深起伏不定。(3)四个较长的偏心周期中,每一个都有一个半周期的温暖潮湿天气和寒冷干燥天气。分析了高偏心率和小偏心率对岩相和有机质含量的影响。通过研究细粒沉积岩对偏心率和进动期的响应,提出了在温暖、潮湿、干燥和寒冷气候条件下生物物质富集的假设。偏心率越大,越适合储存页岩油。
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引用次数: 0
Study on surrounding rock deformation and gas control of entry automatically formed by roof cutting in high-gas coal seam 高瓦斯煤层顶板自动进巷围岩变形及瓦斯控制研究
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-06-15 DOI: 10.1177/01445987231181722
Hai-Feng Gao, Yubing Gao, Jingchen Qi, Q. Fu, Xingyu Zhang
Severe deformation of surrounding rock and excess-gas are the main problems faced in mining of high-gas coal seam. This paper analyzes the deformation characteristics and mechanical model of surrounding rock in high-gas coal seam, and proposes the control technology of surrounding rock deformation and gas prevention and control. Based on this, the entry automatically formed by roof cutting (EAFRC) surrounding rock control technology and constant resistance large deformation anchor cable (CRLDA) support control technology in Shaqu coal mine are put forward. At the same time, the surrounding rock stress and gas migration law of the working face under traditional mining method and EAFRC mining were compared and analyzed. Through the field engineering test, the monitoring and analysis of surrounding rock deformation and gas concentration, the average surrounding rock deformation of roof cutting roadway is 310 mm, and the gas concentration of retained roadway by roof cutting is 0.31%. Through the research in this paper, the surrounding rock stability and gas control of the working face have been realized, and the non-pillar mining of EAFRC has ensured the safe mining of high gas working faces, which provides a reference for the mining of similar mines in non-pillar mining. At the same time, the technical system of EAFRC in non-pillar mining was established, which promoted the development and application of non-pillar mining.
高瓦斯煤层开采面临的主要问题是围岩严重变形和瓦斯过剩。分析了高瓦斯煤层围岩变形特征及力学模型,提出了高瓦斯煤岩变形控制及瓦斯防治技术。在此基础上,提出了沙曲煤矿顶板切割自动形成巷道的围岩控制技术和恒阻大变形锚索支护控制技术。同时,对传统采矿方法和EAFRC采矿方法下工作面围岩应力及瓦斯运移规律进行了对比分析。通过现场工程试验、围岩变形及瓦斯浓度监测分析,顶板路堑巷道平均围岩变形310 mm,采空留巷瓦斯浓度为0.31%。通过本文的研究,实现了工作面的围岩稳定性和瓦斯控制,EAFRC的无柱开采确保了高瓦斯工作面的安全开采,为类似矿山在无柱开采中的开采提供了参考。同时,建立了EAFRC无柱采矿技术体系,促进了无柱采矿的发展和应用。
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引用次数: 0
Impact of coal evolution on formation of tight sandstone reservoirs: A case study in the Daniudi gas field, Ordos Basin, China 煤演化对致密砂岩储层形成的影响——以鄂尔多斯盆地大牛地气田为例
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-06-13 DOI: 10.1177/01445987231178561
Zihao Liu, Shenghe Wu, Zhenhua Xu, R. Guo, Zhaowei Liu, Jiandang Liu, Chao Jia, Zhen-fen Xu
Tight sandstone gas in coal-bearing strata has become an important unconventional gas worldwide. This research aims at understanding the impacts of coal evolution on diagenesis and reservoir quality of sandstones by means of thin section, cathode luminescence (CL), scanning electron microscope (SEM), stable isotope analysis, and fluid inclusions. The results show that carbonate cement was the main type of cement developed in tight sandstone reservoirs, of which the carbonate ions were jointly provided by coal layers and reaction in adjacent mudstones. For sandstones close to coal layers, their carbonate ions were mainly controlled by coal evolution and there was various carbonate cement developed due to cations supplied by seawater and the intense dissolution of volcanic fragments and feldspars. Combined with coal thermal simulation and burial history, it implies that at different maturity stages of coal evolution, its impact on sandstone diagenesis was different. In the early stage, the main product was CO2, which caused the dissolution of early calcite and promoted intense compaction. In the mature stage, CO2 and other hydrocarbon gases were released, resulting in more dissolution and silica cementation. In the over-mature stage, the main product was methane, and CO2 that did not spill out preserved by forming carbonate cement. The coal evolution had a strong impact on the reservoir quality of sandstone with large grain sizes, but little effect on medium- and fine-grained sandstones. High porosity and low permeability reservoirs were usually formed in small conglomerates and coarse-grained sandstones away from coal layers. While low porosity and high permeability reservoirs were distributed close to coal layers. This study aids in understanding the formation mechanism of tight sandstone reservoirs in coal measures and provides theoretic support for further exploration.
含煤地层致密砂岩气已成为世界范围内重要的非常规天然气。通过薄片、阴极发光(CL)、扫描电镜(SEM)、稳定同位素分析和流体包裹体等手段,了解煤演化对砂岩成岩作用和储层质量的影响。结果表明:碳酸盐岩胶结物是致密砂岩储层发育的主要胶结物类型,碳酸盐岩离子由煤层和邻近泥岩共同提供;对于靠近煤层的砂岩,碳酸盐离子主要受煤的演化控制,由于海水提供的阳离子以及火山碎屑和长石的强烈溶蚀作用,形成了多种碳酸盐胶结物。结合煤热模拟和埋藏历史,表明在煤演化的不同成熟阶段,其对砂岩成岩作用的影响是不同的。早期主要产物为CO2,使早期方解石溶蚀,促进强压实作用。在成熟阶段,CO2和其他烃类气体被释放,导致更多的溶解和硅胶结。过成熟阶段主要产物为甲烷,未外溢的CO2通过形成碳酸盐胶结物保存下来。煤的演化对大粒度砂岩储层质量影响较大,对中、细粒度砂岩储层质量影响较小。高孔低渗储层通常形成于远离煤层的小砾岩和粗粒砂岩中。而低孔高渗储层则分布在煤层附近。该研究有助于认识煤系致密砂岩储层的形成机理,为进一步勘探提供理论支持。
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引用次数: 0
Maceral and Organic Geochemical Characteristics of the No. 6 Coal Seam from the Haerwusu Surface Mine, Inner Mongolia, China 内蒙古哈尔乌苏露天矿6号煤层宏观及有机地球化学特征
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-06-04 DOI: 10.1177/01445987231176314
Ze-Guang Wang, Zhe Jin, Jun Wang
Haerwusu Surface Mine of the Jungar Coalfield is a large coal mine. Its coal formation environments have not been reported in detail. In order to reconstruct the paleoenvironment of the peat formation, nine samples were collected, and were analyzed using microscope, column chromatography, gas chromatography (GC), and gas chromatography–mass spectrometry (GC–MS). According to the results of the microscopic analysis, the average random vitrinite reflectance (Rr) is 0.73%, indicating a low rank bituminous coal. Vitrinite group is the predominant macerals with an average content of 54.54%, followed by inertinite group with an average of 35.99%. The higher inertinite contents indicate widespread wildfire events during the peat formation. The distribution pattern of n-alkanes, the cross plot between Pr/n-C17 and Ph/n-C18, the lower saturated/aromatic hydrocarbon ratios (0.22–0.68) and the presence of cadalene, retene, simonellite indicates that the organic matter is predominantly terrestrial higher plants with a small amount of aquatic organisms. The ternary diagram of Pr/Ph, Pr/n-C17 and Ph/n-C18 and the relative abundance of fluorene, dibenzofuran and dibenzothiophene indicate a continental–oceanic alternative facies. The higher contents of combustion-derived PAHs are also indicative of widespread wildfire events during peat formation.
准格尔煤田哈尔乌苏露天矿是一座大型煤矿。其成煤环境尚未详细报道。为了重建泥炭形成的古环境,收集了9个样本,并使用显微镜、柱色谱、气相色谱(GC)和气相色谱-质谱(GC–MS)进行了分析。根据微观分析结果,平均随机镜质组反射率(Rr)为0.73%,表明为低阶烟煤。镜质组是主要的显微组分,平均含量为54.54%,其次是惰质组,平均含量35.99%。较高的惰质组分含量表明泥炭形成期间发生了广泛的野火事件。正构烷烃的分布模式、Pr/n-C17和Ph/n-C18之间的交叉图、较低的饱和/芳烃比(0.22–0.68)以及cadalene、retene和simonellite的存在表明有机物主要是陆地高等植物和少量水生生物。Pr/Ph、Pr/n-C17和Ph/n-C18的三元图以及芴、二苯并呋喃和二苯并噻吩的相对丰度表明了大陆-海洋交替相。燃烧产生的多环芳烃含量较高也表明泥炭形成期间发生了广泛的野火事件。
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引用次数: 0
Geochemical characteristics of Jurassic high-sodium coal in Tatuo Coal Mine, Qinghai Province, China 青海塔托煤矿侏罗系高钠煤地球化学特征
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-06-04 DOI: 10.1177/01445987231178939
J. Wang, Ze-Guang Wang, Zhi Yu, Panchal Balaji, Jie Shi, Yanli Yang
Sodium in the coals of West China has received persistent attention due to its high contents and severe pollutions’ problems during coal utilization. A total of seven drill samples of the Jurassic coals from Tatuo coalfield, Qinghai Province, were collected and analysed using optical microscopy, scanning electron microscopy in conjunction with energy-dispersive X-ray spectrometry, X-ray powder diffraction, inductively coupled plasma mass spectrometry and X-ray fluorescence spectrometry. The results indicate that the Tatuo coal is of lower-high ash, medium volatile matter and ultra-low sulphur bituminous coal. Tatuo coal contains much more Na2O (> 2%), and belongs to high-sodium coal. The maceral index and element ratios of Sr/Cu, Fe/Mn and Sr/Ba showed that Tatuo coal was formed in a terrestrial peat swamp environment. The minerals in Tatuo coal, including clay minerals and halite, quartz, gypsum and rutile, are mainly concentrated in the bottom and top parts of the coal seam. Combined with scanning electron microscopy in conjunction with energy-dispersive X-ray spectrometry and optical microscope characteristics, the sodium could be carried into the peat/coal after the peat formation by basin fluids. The East Kunlun orogenic belt may be the main source of these minerals.
我国西部煤中的钠含量高,在煤炭利用过程中存在严重的污染问题,一直受到人们的关注。采用光学显微镜、扫描电子显微镜、能量色散X射线光谱法、X射线粉末衍射法、电感耦合等离子体质谱法和X射线荧光光谱法对青海省塔托煤田侏罗系煤的7个钻孔样品进行了分析。结果表明,塔托煤为低高灰、中挥发分、超低硫烟煤。塔托煤含Na2O较多(>2%),属于高钠煤。岩石显微组分指标和Sr/Cu、Fe/Mn、Sr/Ba元素比值表明,塔托煤形成于陆地泥炭沼泽环境中。塔托煤中的矿物主要集中在煤层的底部和顶部,包括粘土矿物和石盐、石英、石膏和金红石。结合扫描电子显微镜、能量色散X射线光谱法和光学显微镜特性,钠可以在泥炭形成后通过盆地流体携带到泥炭/煤中。东昆仑造山带可能是这些矿物的主要来源。
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引用次数: 0
A novel optimization approach for rural development based on sustainable agriculture planning, considering the energy and water consumption nexus 考虑能源和水消耗关系的基于可持续农业规划的农村发展优化新方法
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-05-30 DOI: 10.1177/01445987231177472
Jing Luo, Ya-Ping Chang, K. Kaliyaperumal
In today's world, there are many changes and transformations in different sectors of the economy, and today's world economy has become more dependent on each other. The economy of many developing countries is highly dependent on agriculture. In addition, in developed countries, the agricultural sector is of special importance, so they are currently turning to the production of more organic and healthy products. One of the reasons that caused the agricultural sector to receive more attention in the economy is the existential importance of this sector in providing the raw materials of a part of the industry and the food industry needed in that country. Accordingly, in this research, the optimal cultivation pattern is determined using a linear multi-objective mathematical model, including economic, social, and environmental objectives. Moreover, the uncertainty in the input parameters of the proposed model is considered, and a robust optimization approach is applied to deal with this uncertainty. After collecting the research data for the crop year 2021-2022, the proposed robust counterpart formulation is optimized using GAMS software. The numerical results show that increasing the level of conservatism in the robust model cause to decrease in the profit of agriculture as well as increasing the total consumed water. Moreover, the results of the current research can help the decision-makers of the agricultural sector in achieving the goal of obtaining the highest profit.
在当今世界,不同经济部门发生了许多变化和转型,当今世界经济变得更加相互依赖。许多发展中国家的经济高度依赖农业。此外,在发达国家,农业部门具有特殊的重要性,因此它们目前正转向生产更有机、更健康的产品。农业部门在经济中受到更多关注的原因之一是,该部门在提供该国所需的部分工业和食品工业的原材料方面具有生存重要性。因此,在本研究中,使用线性多目标数学模型确定了最佳种植模式,包括经济、社会和环境目标。此外,还考虑了所提出模型输入参数的不确定性,并采用鲁棒优化方法来处理这种不确定性。在收集了2021-2022作物年的研究数据后,使用GAMS软件对所提出的稳健对应配方进行了优化。数值结果表明,增加稳健模型中的保守性水平会导致农业利润的下降以及总耗水量的增加。此外,目前的研究结果可以帮助农业部门的决策者实现获得最高利润的目标。
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引用次数: 0
Temperature–air velocity association, experimental and modeling study of stevia leaves solar drying 甜叶菊叶片太阳干燥的温度-风速关联、实验与模型研究
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-05-30 DOI: 10.1177/01445987231176308
B. Castillo‐Téllez, M. C. Téllez, E. C. López-Vidaña, Alfredo Domínguez Niño, G. A. Mejía-Pérez, C. Vega-Gómez
Sugar is a natural high-calorie sweetener. Its excessive consumption is associated with health problems such as obesity, diabetes, heart disease, and degenerative issues. The stevia plant is a great natural substitute. It provides no calories and has medicinal properties such as oral antibacterial, hypoglycemic, and anti-hypertensive with a high nutritional value. In this work, the effects of temperature and air velocity in drying kinetics of stevia leaves were studied using a convective drier operating with air velocities (2, 3, and 4 m/s) and temperatures controlled (45 °C, 55 °C, and 65 °C). The highest drying rate was obtained at 65 °C and 4 m/s air velocity at 0.05 kg water/kg dry matter min. The experimental data were fitted to theoretical drying models to determine the best approach. It is found that the Page model gives a good fit for all experiments, with correlation coefficients (R2) > 0.9994. The equations to correlate this model's variables with air and temperature were determined. The results show that ΔE and glucoside values increase when temperature and air velocity increase.
糖是一种天然的高热量甜味剂。它的过量摄入与健康问题有关,如肥胖、糖尿病、心脏病和退行性疾病。甜叶菊是一种很好的天然替代品。它不提供热量,具有药用特性,如口服抗菌、降糖、降压,营养价值高。在这项工作中,研究了温度和风速对甜菊叶干燥动力学的影响,使用对流干燥器,风速为2、3和4 m/s,温度控制为45°C、55°C和65°C。在65℃、4 m/s风速、0.05 kg水/kg干物质min条件下获得了最高的干燥速率。将实验数据拟合到理论干燥模型中,以确定最佳方法。发现Page模型对所有实验都有很好的拟合,相关系数(R2)为> 0.9994。确定了该模型变量与空气和温度的关联方程。结果表明,随着温度和风速的增加,ΔE和葡萄糖苷值也随之增加。
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引用次数: 0
Using swarm intelligence optimization algorithms to predict the height of fractured water-conducting zone 利用群智能优化算法预测裂缝导水带高度
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-05-30 DOI: 10.1177/01445987231178938
Dekang Zhao, Zhenghao Li, Guo-rui Feng, Fulong Wang, Chenwei Hao, Yaming He, Shuning Dong
The accurate calculation of the height of fractured water-conducting zone (FWCZ) is of great significance for mine optimization design, water disaster prevention, and safety production of the coal mines. In this article, a height-prediction model of FWCZ based on extreme learning machine (ELM) is proposed. To address the issues of low prediction accuracy and challenging parameter optimization, we optimized the ELM model using the gray-wolf optimization algorithm (GOA), whale optimization algorithm (WOA), and salp optimization algorithm (SOA). These optimization algorithms mitigate the issues of slow convergence, poor stability, and local optimality associated with traditional neural networks. The mining depth, mining height, overburden strata structure, working face length, and coal seam dip angle are selected as the main controlling factors for the height of FWCZ. A total of 42 fields-measured samples are collected and divided into 2 subsets for training and validating with a ratio of 36/6. The prediction capability of GOA-ELM, WOA-ELM, and SOA-ELM models are evaluated and compared, and the results show that the calculation results of the three models are optimized compared with the ELM model. The prediction capability of GOA and WOA are similar, while the prediction results of SOA-ELM are better than the other two models, and the relative errors of the test sets are all less than 10%. Therefore, the SOA-ELM model is finally applied to predict the height of FWCZ formed after the mining of No.15 coal seam in Xinjian Coal Mine. Finally, we verified the prediction results using measured data from the borehole television detection instrument, which showed good consistency. This provides further evidence of the effectiveness of the swarm intelligence optimization algorithm in predicting the height of FWCZ.
裂缝导水带高度的准确计算对矿井优化设计、水害防治和煤矿安全生产具有重要意义。提出了一种基于极限学习机(ELM)的FWCZ高度预测模型。为了解决预测精度低和参数优化困难的问题,我们使用灰狼优化算法(GOA)、鲸鱼优化算法(WOA)和salp优化算法(SOA)对ELM模型进行了优化。这些优化算法减轻了与传统神经网络相关的收敛速度慢、稳定性差和局部最优性的问题。选取采深、采高、覆岩地层结构、工作面长度、煤层倾角等为控制采场高度的主要因素。共收集42个实地实测样本,以36/6的比例分成2个子集进行训练和验证。对GOA-ELM、WOA-ELM和SOA-ELM模型的预测能力进行了评价和比较,结果表明,与ELM模型相比,3种模型的计算结果都得到了优化。GOA和WOA的预测能力相似,而SOA-ELM的预测结果优于其他两种模型,测试集的相对误差均小于10%。因此,最终应用SOA-ELM模型对新建煤矿15号煤层开采后形成的FWCZ高度进行了预测。最后利用井眼电视测井仪实测数据对预测结果进行了验证,结果表明预测结果具有较好的一致性。这进一步证明了群体智能优化算法在预测FWCZ高度方面的有效性。
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引用次数: 0
Ketones Production by Catalytic Pyrolysis of Cellulose Using Iron-Modified Ni-Co Composite Catalyst: Products Distribution, Behaviour and Bio-oil Characteristics 铁改性镍钴复合催化剂催化热解纤维素制酮:产物分布、行为及生物油特性
IF 2.7 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2023-05-25 DOI: 10.1177/01445987231164817
Yong Jia, Jianqi Lei
In this work, the iron-modified Ni-Co composite catalyst was synthesized, and its catalytic effect on product distribution, behaviour and liquid characteristics was deeply studied. The result showed that the synthesized catalyst significantly improved the pyrolysis behaviour of cellulose, and the decomposition of cellulose occurred earlier. The highest yield of liquid product was 56.79wt%, which was obtained by adding the NCF-6 catalyst. The optimal ratio of catalyst in the sample was 5%, and the optimal pyrolysis temperature was 530°C. The characteristics of liquid product showed the introduction of the synthesized catalyst enhanced the decomposition of anhydrosugars and significantly promoted the generation of ketones in the liquid. The highest content of ketones in the liquid was 25.12%. Further analysis showed that the selectivity of 2(5H)-Furanone in the liquid component was strongest. These works provided an effective way to produce ketone-rich bio-oil from biomass.
本工作合成了铁改性的Ni-Co复合催化剂,并深入研究了其对产物分布、行为和液体特性的催化作用。结果表明,合成的催化剂显著改善了纤维素的热解行为,纤维素的分解发生得更早。通过添加NCF-6催化剂获得的液体产物的最高产率为56.79wt%。样品中催化剂的最佳比例为5%,最佳热解温度为530°C。液体产物的特性表明,合成催化剂的引入促进了脱水糖的分解,并显著促进了液体中酮的生成。液体中酮的最高含量为25.12%。进一步分析表明,液体组分中2(5H)-呋喃酮的选择性最强。这些工作为利用生物质生产富含酮的生物油提供了一条有效途径。
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Energy Exploration & Exploitation
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