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Thermal management system and its impact on PEMFC performance: Review 热管理系统及其对PEMFC性能的影响综述
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-28 DOI: 10.1002/ep.70131
Dinesh Kumar, Hemant Kumar, Amandeep Singh Oberoi

Polymer electrolyte membrane fuel cells (PEMFCs) are prominent green energy sources that generate power 50%–60% more efficiently than internal combustion engines. They emit only heat and water, avoiding carbon emissions, but their operating temperatures are limited by membrane hydration, flooding prevention, and material deterioration. A good heat management system boosts PEMFC's performance and flexibility. Most systems use air cooling under 2 kW and liquid cooling beyond 5 kW. Conventional air- and liquid-cooled systems have parasitic power, cost, maintenance, leakage, reliability, and portability concerns. We aim to solve air- and liquid-cooled system problems with innovative passive and hybrid solutions. This study explores innovative thermal management systems (TMS) like heat pipes, heat spreaders, PCMs, metal foam thermal management, microchannel heat sinks, and integrated cooling technologies for mid-range power applications (10–100 W and up). The presented work articulates both active and passive cooling systems in detail, followed by phase change materials (PCMs) and metal foam-based cooling systems. Thermal management systems incorporating PCMs minimize coolant pump requirements, improve water removal, and distribute reactants. PCMs cause system design, flow instability, working fluid leaks, and durability concerns. On the other hand, metal foam flow fields improve PEMFC performance over other cooling systems, but their pressure dips, humidity balance, electrolyte dehydration, and complexity make them challenging to deploy. Hybrid nanofluids, PCMs, metal foams, and hybrid cooling systems may increase application-specific cooling. This report advises more investigation in these areas. Understanding PEMFC thermal dynamics enhances system efficiency and longevity, enabling fuel cell commercialization and mainstream use.

聚合物电解质膜燃料电池(pemfc)是一种突出的绿色能源,其发电效率比内燃机高出50%-60%。它们只排放热量和水,避免了碳排放,但它们的工作温度受到膜水合作用、防淹和材料变质的限制。良好的热管理系统可以提高PEMFC的性能和灵活性。大多数系统使用2千瓦以下的风冷和5千瓦以上的液冷。传统的空气和液冷系统存在寄生功率、成本、维护、泄漏、可靠性和便携性等问题。我们的目标是用创新的被动和混合解决方案解决空气和液冷系统问题。本研究探讨了创新的热管理系统(TMS),如热管、散热器、pcm、金属泡沫热管理、微通道散热器,以及用于中程功率应用(10-100 W及以上)的集成冷却技术。提出的工作详细阐述了主动和被动冷却系统,其次是相变材料(PCMs)和金属泡沫冷却系统。热管理系统结合pcm最大限度地减少冷却剂泵的要求,提高水的去除,并分配反应物。pcm会导致系统设计、流动不稳定、工作流体泄漏和耐久性问题。另一方面,与其他冷却系统相比,金属泡沫流场提高了PEMFC的性能,但其压力下降、湿度平衡、电解质脱水和复杂性使其难以部署。混合纳米流体,pcm,金属泡沫和混合冷却系统可以增加特定应用的冷却。这份报告建议在这些领域进行更多的调查。了解PEMFC热动力学可以提高系统效率和寿命,促进燃料电池的商业化和主流应用。
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引用次数: 0
Sustainable polypropylene chair: A life cycle assessment and cost analysis of industrial production 可持续聚丙烯椅:工业生产的生命周期评估和成本分析
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-25 DOI: 10.1002/ep.70126
Lucrezia Maggi, Alberto Pietro Damiano Baltrocchi, Marco Carnevale Miino, Elena Cristina Rada, Vincenzo Torretta

Due to their multiple properties, including flexibility, lightness, and strength, thermoplastics are an essential material in the development of processes at both industrial and domestic levels. However, thermoplastics are often derived from polymers synthesized using non-renewable petroleum resources. This has environmental consequences. The following research is proposed as the first environmental and economic impact evaluation of the extrusion and molding process of polypropylene (PP) generated by an industrial site for monobloc plastic chair production, through a Life Cycle Assessment (LCA) and Cost Analysis (CA) methodology. The analysis was conducted using SimaPro v10.1 software, Ecoinvent v3.10 database, and ReCiPe 2016 v1.07 impact assessment method. This study proposes multiple mitigative scenarios applicable to reduce the business-as-usual impact. Primary data was collected in 2024. The results show a significant environmental impact reduction caused by the substitution of the virgin PP with the recycled PP (−39%), a lower one generated by the substitution of the Italian country energy mix with the adoption of renewable energy sources (−12%), and a global added reduction obtained summarizing the two alternatives (−55%). The economic impacts are, instead, slightly influenced by the change in input raw materials, due to similar market costs. However, the cost reductions associated with the change in energetic source can be considered not negligible, excluding the plant design and commissioning costs. This research provides decision-makers with valuable guidance for implementing PP production plants, promoting sustainability and a circular economy. Advancing these prerogatives supports the achievement of Sustainable Development Goals, particularly SDGs 3, 11, and 13.

由于其多种特性,包括柔韧性、轻盈性和强度,热塑性塑料在工业和家庭层面的工艺发展中都是必不可少的材料。然而,热塑性塑料通常是由使用不可再生的石油资源合成的聚合物制成的。这对环境造成了影响。下面的研究是通过生命周期评估(LCA)和成本分析(CA)的方法,作为第一个对聚丙烯(PP)挤出和成型过程的环境和经济影响评估,该过程是由一个生产整体塑料椅子的工业基地产生的。采用SimaPro v10.1软件,Ecoinvent v3.10数据库,ReCiPe 2016 v1.07影响评价方法进行分析。本研究提出了适用于减少“一切照旧”影响的多种缓解方案。主要数据是在2024年收集的。结果表明,用再生PP替代原生PP对环境的影响显著降低(- 39%),用可再生能源替代意大利国家能源结构(- 12%)对环境的影响较低,两种替代方案的总体减排量为- 55%。相反,由于市场成本相似,经济影响受到投入原材料变化的轻微影响。然而,与能源变化相关的成本降低可以被认为是不可忽略的,不包括工厂设计和调试成本。本研究为决策者实施PP生产工厂、促进可持续发展和循环经济提供了有价值的指导。推进这些特权有助于实现可持续发展目标,特别是可持续发展目标3、11和13。
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引用次数: 0
Sustainable biodiesel production from jatropha: Optimization, characterization and life cycle assessment 麻疯树可持续生物柴油生产:优化、表征和生命周期评估
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-25 DOI: 10.1002/ep.70109
Trang Thi Cam Truong, Phuc Tuong Ngo Hoang, Ha Manh Bui

Biodiesel derived from Jatropha curcas presents a sustainable alternative to fossil fuels due to its non-edible nature and suitability for marginal lands. To improve both yield and environmental performance, this study investigates an innovative two-step ultrasound-assisted biodiesel production process combined with Taguchi optimization. Key parameters including oil-to-methanol molar ratio, reaction time, and catalyst dosage were optimized using the Taguchi method, while a laboratory-scale Life Cycle Assessment (LCA) was conducted using the ReCiPe Midpoint 2016 method. Under optimized reaction conditions, a biodiesel yield of 91.2% was achieved, with a methyl ester content of 97.8%, satisfying EN 14214 standards. LCA results revealed that the transesterification step was the main contributor to environmental impacts, notably climate change and toxicity. This study highlights a scalable and environmentally friendly approach to biodiesel production, aligning with Sustainable Development Goals (SDGs) 7 (Affordable and Clean Energy) and 13 (Climate Action).

从麻疯树中提取的生物柴油由于其不可食用的性质和适合边缘土地而成为化石燃料的可持续替代品。为了提高产量和环境性能,本研究结合田口优化研究了一种创新的两步超声辅助生物柴油生产工艺。采用Taguchi法优化油甲醇摩尔比、反应时间、催化剂用量等关键参数,采用ReCiPe Midpoint 2016法进行实验室规模的生命周期评价(LCA)。在优化的反应条件下,生物柴油收率为91.2%,甲酯含量为97.8%,符合en14214标准。LCA结果表明,酯交换反应是环境影响的主要因素,特别是气候变化和毒性。这项研究强调了可扩展和环保的生物柴油生产方法,符合可持续发展目标(sdg) 7(负担得起的清洁能源)和13(气候行动)。
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引用次数: 0
Study of CO2 mitigation in a CI engine exhaust using a potential adsorbent: An experimental investigation 使用潜在吸附剂减少CI发动机废气中二氧化碳排放的研究:一项实验研究
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-22 DOI: 10.1002/ep.70129
Maniarasu Ravi, Sushil Kumar Rathore, Murugan Sivalingam

The atmospheric carbon dioxide (CO2) concentration has reached its elevated peak, a severe threat to the world. Post-combustion CO2 capture is the most crucial method to mitigate CO2 emissions. Recently, the biomass-based adsorbent used in the adsorption technique has grabbed the great attention of the scientific communities. The adsorbent-packed post-combustion carbon capture unit can easily integrate with the existing working system without affecting efficiency. In the present research study, an experimental investigation has been conducted on biomass-derived adsorbent to explore the feasibility of CO2 adsorption performance from the exhaust of a compression ignition (CI) engine. As a first step, rice husk is chosen as a suitable raw material to produce activated carbon using simultaneous carbonization and activation. As a second step, the prepared activated carbon material is subjected to distinctive characterization and analytical approaches to determine its surface aspects and physical and chemical characteristics. As a third step, the sample is loaded in-built of the capture unit and connected to the system. The main findings of the experimental test results are compared using the adsorbent capture efficacy with two distinct test fuels employed in the CI engine. The experimental outcomes show that the maximum CO2 adsorption is achieved by about 24% and 28% for D2 quality diesel and Jatropha methyl ester biodiesel fuel operations, respectively, at normal operating conditions.

大气中二氧化碳(CO2)浓度已达到峰值,对世界构成严重威胁。燃烧后二氧化碳捕获是减少二氧化碳排放的最关键方法。近年来,生物质吸附剂在吸附技术中的应用引起了科学界的极大关注。吸附剂填充的燃烧后碳捕集装置可以很容易地与现有的工作系统集成而不影响效率。在本研究中,对生物质吸附剂进行了实验研究,以探索从压缩点火(CI)发动机排气中吸附CO2性能的可行性。首先,选择稻壳作为合适的原料,采用同时炭化和活化的方法生产活性炭。作为第二步,制备的活性炭材料受到不同的表征和分析方法,以确定其表面方面和物理和化学特性。作为第三步,样品被装入内置的捕获单元并连接到系统。利用吸附剂捕获效能与两种不同的CI发动机试验燃料进行了实验测试结果的比较。实验结果表明,在正常操作条件下,D2质量柴油和麻风树甲酯生物柴油的最大CO2吸附量分别为24%和28%左右。
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引用次数: 0
Testing results of a novel air cavity enabled domestic solar dryer for potato drying 一种新型空腔式家用太阳能干燥机用于马铃薯干燥的试验结果
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-19 DOI: 10.1002/ep.70107
Shimpy, Mahesh Kumar, Anil Kumar

The ever-increasing global food requirement, food waste and loss, climate change, and energy and food insecurities have forced researchers around the world to think about sustainable development. This study has been designed to test a novel air cavity enabled renewably powered domestic solar dryer (DSD) for potato slices drying under natural convection (NC) and forced convection (FC) modes. The effect of potato slice thicknesses (3, 4, and 5 mm) on the performance of the DSD under NC and FC modes has also been presented. The average final moisture content of potato slices was 6.43% and 11.2% (wb) under NC and FC modes, respectively. The drying behavior of potato slice samples was found to be in accordance with the Midilli-Kucuk model. The total cost and embodied energy of the DSD under NC and FC modes were found to be INR 1557.14 ($18.68) and 126.84 kWh, and INR 1788.14 ($21.45) and 157.87 kWh, respectively. Drying rate, effective moisture diffusivity, heat transfer coefficients, thermal and exergy efficiencies were higher for 4 mm thick potato slice samples drying under both modes. The performance of the DSD under NC mode was found to be more desirable for potato slice samples drying.

不断增长的全球粮食需求、粮食浪费和损失、气候变化以及能源和粮食不安全迫使世界各地的研究人员思考可持续发展问题。本研究旨在测试一种新型空气腔驱动的可再生家用太阳能干燥机(DSD),用于在自然对流(NC)和强制对流(FC)模式下干燥马铃薯片。研究了马铃薯片厚度(3、4和5 mm)对NC和FC模式下DSD性能的影响。NC和FC处理下马铃薯片的平均最终含水率分别为6.43%和11.2% (wb)。马铃薯片样品的干燥行为符合midli - kuucuk模型。NC和FC模式下DSD的总成本和隐含能量分别为1557.14 INR(18.68美元)和126.84 kWh, 1788.14 INR(21.45美元)和157.87 kWh。两种干燥方式下,4 mm厚马铃薯片样品的干燥速率、有效水分扩散系数、传热系数、热效率和火用效率均较高。在NC模式下,DSD的干燥性能更为理想。
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引用次数: 0
The relationship between energy poverty and gender inequality: A comparative study of Southern Asian, Sub-Saharan African, and European countries 能源贫困与性别不平等的关系:南亚、撒哈拉以南非洲和欧洲国家的比较研究
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-19 DOI: 10.1002/ep.70124
Mehdi Seraj, Nathan Y. Bellepea, Huseyin Ozdeser, Fatma Turuc Seraj

This study examines the impact of gender inequality (GIQ) on energy poverty (EP) across Southeast Asia (SA), Sub-Saharan Africa (SSA), and European Union (EU) countries over the period 2000–2020 using the Panel Mean Group (PMG) estimation method. The findings reveal that a 1% increase in GIQ leads to a 1.09% rise in EP in SA and a 0.14% increase in SSA, while in the EU, GIQ significantly mitigates EP. Renewable energy consumption (REN) has a strong negative effect on EP, particularly in SA (−0.66%). Additionally, economic development exhibits a non-linear relationship with EP, where early growth phases may exacerbate deprivation before reversing at higher income levels. These results highlight that gender disparities, even when moderated by economic and energy policy factors, remain a critical determinant of energy access outcomes. Policymakers are urged to adopt gender-sensitive energy strategies, enhance women's inclusion in energy governance, and increase investments in renewable infrastructure to bridge access gaps and promote inclusive development.

本研究采用面板平均组(PMG)估计方法,探讨了2000-2020年期间,性别不平等(GIQ)对东南亚(SA)、撒哈拉以南非洲(SSA)和欧盟(EU)国家能源贫困(EP)的影响。研究结果显示,GIQ每增加1%,SA的EP增加1.09%,SSA增加0.14%,而在欧盟,GIQ显著减轻EP。可再生能源消费(REN)对EP有很强的负面影响,尤其是在SA(- 0.66%)。此外,经济发展与gdp呈非线性关系,早期增长阶段可能加剧贫困,然后在较高收入水平逆转。这些结果强调,即使经济和能源政策因素缓和了性别差异,性别差异仍然是能源获取结果的关键决定因素。我们敦促政策制定者采取对性别问题敏感的能源战略,加强妇女在能源治理中的参与,增加对可再生能源基础设施的投资,以弥合可及性差距,促进包容性发展。
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引用次数: 0
Optimizing energy, quality, and emissions in button mushroom (Agaricus bisporus) drying using infrared-convective dryer with heat recovery 利用热回收红外对流干燥机优化双孢蘑菇(Agaricus bisporus)干燥的能量、质量和排放
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-19 DOI: 10.1002/ep.70103
Hosain Darvishi, Farzam Afzali, Nasser Behroozi-Khazaei

Mushroom drying faces significant challenges, including high-energy consumption, prolonged processing times, and quality degradation, while conventional methods contribute substantially to greenhouse gas (GHG) emissions. This study investigates the synergistic effects of infrared power, air temperature, and heat recovery on energy efficiency, product quality, and GHG emissions during continuous conveyor infrared-hot air drying of white button mushroom (Agaricus bisporus) slices. Results demonstrate that elevating air temperature and infrared power density enhances drying rates (up to 4.67 g water/min) and rehydration capacity (33.91%), while specific energy consumption declines with infrared power ≤850 W and air recirculation ≤70%. Integration of a heat recovery system reduced energy usage by 18%–62% and GHG emissions by 15%–32%, with total color difference (ΔE = 13.21) minimized at higher recirculation percentages. Through Response Surface Methodology optimization, ideal parameters were identified as 90°C drying temperature, 810.6 W infrared power, and 81.4% air recirculation (1 m/s velocity), yielding a desirability factor of 0.838. These findings underscore the viability of infrared-convective drying with heat recovery as a sustainable, high-efficiency solution for industrial mushroom processing, balancing productivity, energy conservation, and environmental stewardship.

蘑菇干燥面临着巨大的挑战,包括高能量消耗、加工时间延长和质量退化,而传统方法对温室气体(GHG)排放有很大贡献。本研究探讨了红外功率、空气温度和热回收对双孢蘑菇(Agaricus bisporus)切片连续输送红外热风干燥过程中能效、产品质量和温室气体排放的协同效应。结果表明:提高空气温度和红外功率密度可提高干燥速率(4.67 g水/min)和再水化能力(33.91%),而当红外功率≤850 W、空气再循环率≤70%时,比能耗降低;热回收系统的集成减少了18%-62%的能源使用和15%-32%的温室气体排放,总色差(ΔE = 13.21)在较高的再循环百分比下最小化。通过响应面法优化,确定了理想的干燥温度为90℃,红外功率为810.6 W,空气循环率为81.4% (1 m/s速度),理想系数为0.838。这些发现强调了热回收红外对流干燥作为一种可持续的、高效的工业蘑菇加工解决方案的可行性,平衡了生产力、节能和环境管理。
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引用次数: 0
Simulation study on parameters affecting performance of direct methanol fuel cell 直接甲醇燃料电池性能影响参数的仿真研究
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-19 DOI: 10.1002/ep.70123
A. Ismail, M. J. S. Ng, S. K. Kamarudin

Direct methanol fuel cell (DMFC) is one of the most advanced fuel cells that is being considered as a future energy source. The objective of this study is to develop a mathematical model based on optimal operating parameters and to assess DMFC performance. Significant outcomes of two-dimensional (2D) simulations were anticipated to maximize the performance of the fuel cell for usage in portable applications and the transportation sectors. Simulation of the 2D fuel cell model built on the basis of physical principles was also used to forecast how the cell will operate under various operating situations. Using the Taguchi method, experimental data from previous researchers has been analyzed to obtain the optimum parameter for DMFC. This study focused on four important parameters: effects of fuel, oxidant concentrations, reactant flow direction, and membrane properties. Optimizing these parameters ensures better fuel utilization, reduced losses, and enhanced power density, leading to a more efficient and durable DMFC system. From the results obtained, DMFC with 1.0 M of methanol concentration as the fuel concentration, oxygen as the oxidant, counter-current flow as the flow direction, and Nafion® 211 as the type of membrane is the best configuration. This configuration achieved the highest current density of 3025 A/m2.

直接甲醇燃料电池(DMFC)是最先进的燃料电池之一,被认为是未来的能源来源。本研究的目的是建立一个基于最佳操作参数的数学模型,并评估DMFC的性能。二维(2D)模拟的重要结果有望最大限度地提高燃料电池在便携式应用和运输部门的性能。通过对基于物理原理建立的二维燃料电池模型进行仿真,预测电池在各种工况下的运行情况。采用田口法对前人实验数据进行分析,得到DMFC的最佳参数。研究了四个重要参数:燃料、氧化剂浓度、反应物流动方向和膜性能的影响。优化这些参数可确保更好的燃料利用率,减少损耗,增强功率密度,从而实现更高效、更耐用的DMFC系统。结果表明,以1.0 M甲醇浓度为燃料浓度,氧为氧化剂,逆流为流动方向,以Nafion®211为膜型的DMFC为最佳配置。这种配置实现了最高电流密度3025 A/m2。
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引用次数: 0
Linking clean energy consumption to environmental sustainability in Africa: Puzzling evidence from new artificial intelligence methods 将非洲的清洁能源消费与环境可持续性联系起来:来自新的人工智能方法的令人困惑的证据
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-19 DOI: 10.1002/ep.70117
Solomon Prince Nathaniel, Dimitrios Dimitriou, Süleyman Bolat, Aviral Kumar Tiwari

The literature is inundated with studies emphasizing the importance of renewable energy consumption (REN) and sustainable resource management as a panacea to the threats of climate change, which include loss of species, food insecurity, extreme weather, sea level rise, and security risks. The current study examines the dynamic relationships in spatial and time domains between REC, natural resource rents (NR), and ecological footprint (EF) from 1990 to 2022, using the novel spatiotemporal intelligent regression models, specifically the Geographically Neural Network Weighted Regression (GNNWR) model for sub-Saharan Africa (SSA) countries. This novel method introduced by Yin et al. (2024) integrates a spatiotemporal weighting framework with neural network architectures. The GNNWR results suggest that REN, NR, and urbanization are significant supportive elements of ecological sustainability in SSA. Conversely, non-renewable energy consumption (NRE), economic growth, and globalization hurt the environment by upsurging the EF. The causality results display a bidirectional causality between REN and EF, NRE and EF, and economic growth and EF. However, unidirectional causality flows from NR and globalization to EF. In line with the results, policymakers in SSA will need to redefine their energy consumption portfolio. Efforts must be made to encourage energy transition by raising adequate awareness of the availability and benefits of consuming clean energies such as solar, tidal, geothermal, wind, and hydropower.

文献中充斥着强调可再生能源消费(REN)和可持续资源管理作为应对气候变化威胁的灵丹妙药的重要性的研究,包括物种丧失、粮食不安全、极端天气、海平面上升和安全风险。本研究利用新颖的时空智能回归模型,特别是撒哈拉以南非洲(SSA)国家的地理神经网络加权回归(GNNWR)模型,研究了1990 - 2022年生态足迹(REC)、自然资源租金(NR)和生态足迹(EF)在时空上的动态关系。Yin等人(2024)提出的这种新方法将时空加权框架与神经网络架构相结合。GNNWR结果表明,REN、NR和城市化是SSA生态可持续性的重要支持因素。相反,不可再生能源消费(NRE)、经济增长和全球化通过提高EF而损害环境。因果关系结果表明,经济增长与经济增长、经济增长与经济增长之间存在双向因果关系。然而,单向因果关系从NR和全球化流向EF。根据研究结果,SSA的政策制定者需要重新定义他们的能源消费组合。必须作出努力,通过提高对诸如太阳能、潮汐能、地热能、风能和水力等清洁能源的可得性和效益的充分认识,鼓励能源转型。
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引用次数: 0
Issue Information - Cover and Table of Contents 发行资料-封面及目录
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-17 DOI: 10.1002/ep.14408
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引用次数: 0
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