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Distribution and Characteristics of Microplastics in Nhue - Day River Basin, Vietnam 微塑料在越南Nhue-Day河流域的分布与特征
Q3 Environmental Science Pub Date : 2023-04-11 DOI: 10.32526/ennrj/21/202200244
The prevalence of microplastics (MPs) in the environment has had a significant impact on ecosystems and posed a major threat to human health. This study investigated the distribution and characteristics of MPs in the Nhue - Day River basin in Vietnam, which is a critical source of biodiversity and used to support the economic growth of about 12 million people. The effect of seasonal variation and anthropogenic activities on the MP abundance was assessed. The findings revealed that the MPs abundance was significant in this study area. The average abundance of MPs in the dry season (754 items/m3) was insignificantly higher than that in the rainy season (706 items/m3) with n=9. The range in the abundance of MPs in the dry and rainy seasons was 49-2,827 and 400-1,133 items/m3, respectively. Microplastics in fiber forms were dominant in both seasons. The majority of the collected MPs were in the 0.5-2.0 mm size range, varying from 71% to 100% of the total MPs depend on sampling point. The total percentage of MPs size 0.3-0.5 mm in the dry season was 56.97% compared to 119.85% in the rainy season, indicating that the MPs were broken into smaller pieces due to UV exposure and weather conditions. Colored items occupied the majority of the MPs. This study can be used to gain a better knowledge of MP pollution in Vietnam’s river water.
微塑料在环境中的普遍存在对生态系统产生了重大影响,并对人类健康构成了重大威胁。本研究调查了越南Nhue-Day河流域MPs的分布和特征,该流域是生物多样性的重要来源,用于支持约1200万人的经济增长。评估了季节变化和人为活动对MP丰度的影响。研究结果表明,MPs的丰度在该研究区域具有重要意义。旱季MPs的平均丰度(754个项目/m3)略高于雨季(706个项目g/m3),n=9。旱季和雨季MPs的丰度范围分别为49-2827和400-1133个项目/立方米。纤维形式的微塑料在这两个季节都占主导地位。收集到的大多数MP尺寸在0.5-2.0 mm范围内,根据采样点的不同,占总MP的71%至100%不等。旱季尺寸为0.3-0.5 mm的MPs的总百分比为56.97%,而雨季为119.85%,这表明由于紫外线照射和天气条件,MPs被分解成更小的碎片。有色物品占据了国会议员的多数。本研究可用于更好地了解越南河水中的MP污染。
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引用次数: 0
Seed Osmopriming Improves Germination, Physiological, and Root Anatomical Attributes of Red Amaranth (Amaranthus tricolor L.) in Salinity Stress Condition 种子浸渍对盐胁迫条件下红苋菜发芽、生理和根系解剖特性的影响
Q3 Environmental Science Pub Date : 2023-04-10 DOI: 10.32526/ennrj/21/202200258
D. Amalia, D. Rachmawati
Salinity stress is a form of abiotic stress that threatens the sustainability of agriculture in almost all countries in the world. It has an impact in reducing plant productivity. Red amaranth (Amaranthus tricolor L.) is a vegetable crop that has high nutritional value, but extensive saline land area can cause red amaranth yields to decline. Osmopriming is a seed priming method in which seeds are immersed in a solution that has a high osmotic potential, such as PEG (polyethylene glycol) in order to increase germination under unfavorable conditions. This study determined the effect of osmopriming on germination, physiological, and root anatomical attributes of red amaranth roots under salinity stress conditions. The research design used a completely randomized design with two types of treatment, namely, osmopriming and salinity stress. Each treatment used three concentrations, seed osmopriming with 0%, 5%, and 10% of PEG and salinity stress of 0 mM, 50 mM, and 100 mM of NaCl. The measured parameters were germination, growth, physiological, and root anatomical characters. Osmopriming of seeds with 10% PEG increased germination as indicated by the germination percentage, time, and rate reaching 95.55%, 1.393 day, and 71.98%/day, respectively. Red amaranth plants that had been osmoprimed with 10% PEG grew faster when exposed to salinity stress. Application of PEG 5% and 10% increased total chlorophyll levels while decreasing proline levels and Ca-oxalate crystal density. Under salinity stress conditions, PEG application improved the root anatomical characters of red amaranth as shown by increased epidermis thickness, cortex thickness, and stele diameter. Priming application with 10% PEG has the potential to increase the tolerance of red amaranth to salinity stress.
盐度胁迫是一种非生物胁迫,威胁着世界上几乎所有国家农业的可持续性。它对降低工厂生产力有影响。红苋(Amaranthus tricolor L.)是一种营养价值较高的蔬菜作物,但盐碱地面积过大会导致红苋产量下降。渗透引发是一种种子引发方法,将种子浸入具有高渗透电位的溶液中,如PEG(聚乙二醇),以在不利条件下提高发芽率。本研究确定了在盐度胁迫条件下渗透启动对红苋根的发芽、生理和根系解剖特性的影响。该研究设计采用了完全随机的设计,有两种类型的治疗,即渗透启动和盐度应激。每种处理使用三种浓度,用0%、5%和10%的PEG进行种子渗透启动,并用0mM、50mM和100mM的NaCl进行盐度胁迫。测量的参数包括发芽、生长、生理和根系解剖特征。10%PEG对种子的渗透处理提高了种子的发芽率,发芽时间和发芽率分别达到95.55%、1.393天和71.98%。用10%PEG渗透处理过的红苋植物在暴露于盐度胁迫时生长得更快。施用5%和10%的PEG提高了总叶绿素水平,同时降低了脯氨酸水平和草酸钙晶体密度。在盐度胁迫条件下,PEG的施用改善了红苋的根系解剖特征,表现为增加了表皮厚度、皮层厚度和中柱直径。用10%PEG引发施用有可能提高红苋对盐度胁迫的耐受性。
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引用次数: 0
Do Managed Hill Sal (Shorea robusta) Community Forests of Nepal Sequester and Conserve More Carbon than Unmanaged Ones? 尼泊尔管理的Hill Sal(Shorea robusta)社区森林比未管理的森林更能保持和保存碳吗?
Q3 Environmental Science Pub Date : 2023-03-16 DOI: 10.32526/ennrj/21/202200259
S. Gautam, S. Timilsina, M. Shrestha, Bina Adhikari, Binay Bahadur Adhikari Khatri, J. Timsina
Nepalese community forests are globally recognized for sustainable forest management and improving the livelihoods of forest-dependent communities, but their contribution to carbon sequestration in trees and soil is rarely studied. This study was performed to understand the effect of management practices on carbon stock of two community forests (CFs) - Taldanda (managed) and Dangdunge (unmanaged) - dominated by Sal (Shorea robusta) in the mid-hills of Nepal. Twenty-one concentric sample plots, each of 250 m2, were laid out in each forest to estimate different carbon pools and a stratified random sampling intensity of 0.5% used to collect data. Results showed significant (p<0.05) differences in above and below-ground biomass and carbon sequestration potential between the two CFs. The managed and unmanaged forests had total carbon stock of 269.3±27.4 and 150.0±22.7 ton/ha, respectively, demonstrating 1.79 times higher carbon stock in the former than the latter. The managed forest had significantly (p<0.05) greater mean soil organic carbon (SOC) stock than the unmanaged forest. The SOC was highest in the upper soil layer (0-10 cm), with a steady decrease as the soil depth increased. All other measured carbon pools values were higher in managed compared to unmanaged forest. The difference in carbon stock was due to the manipulation of different forest management activities, including thinning, timber extraction, fire control, grazing, and fuel wood/fodder extraction. The study suggests that the implementation of proper forest management would be necessary for enhancing carbon stock in forest trees and soils.
尼泊尔社区森林在可持续森林管理和改善依赖森林的社区生计方面得到全球认可,但它们对树木和土壤中碳固存的贡献却很少得到研究。本研究旨在了解管理措施对尼泊尔中部以萨尔(Shorea robusta)为主的两个群落林(Taldanda)(有管理)和当当格(Dangdunge)(无管理)的碳储量的影响。在每个森林内设置21个同心样地,每个样地面积为250 m2,以估计不同的碳库,并采用0.5%的分层随机抽样强度收集数据。结果表明,两种碳源地上、地下生物量和固碳潜力差异显著(p<0.05)。人工林和非人工林的总碳储量分别为269.3±27.4和150.0±22.7 t /ha,前者是后者的1.79倍。人工林土壤有机碳储量显著高于非人工林(p<0.05)。土壤有机碳在表层(0 ~ 10 cm)最高,随土层深度的增加而逐渐降低。所有其他测量的碳库值在有管理的森林中高于未管理的森林。碳储量的差异是由于不同森林管理活动的操纵,包括间伐、木材提取、火灾控制、放牧和燃料木材/饲料提取。该研究表明,实施适当的森林管理对于增加森林树木和土壤的碳储量是必要的。
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引用次数: 0
A Combined DPSIR Framework and Logical Framework Approach for Sustainable Water Resources Management in the Lagoon Floodplain 泻湖泛滥平原可持续水资源管理的DPSIR框架和逻辑框架相结合的方法
Q3 Environmental Science Pub Date : 2023-03-13 DOI: 10.32526/ennrj/21/202200170
Benchawan Teerakul, Chaiwat Rongsayamanont, Rotchanatch Darnsawasdi, Peerapat Kosolsaksakul
This article describes a combination of the driver-pressure-state-impact-response (DPSIR) framework and the logical framework approach (LFA) to develop water management strategies for a lagoon floodplain in Thailand. The DPSIR framework identified the cause-effect relationship between water and anthropogenic activities. LFA developed management strategies based on a systematic and logical approach. DPSIR analysis for the issue of water shortages for irrigated areas revealed the need for income from agriculture is a major driver, as indicated by agricultural development policy. The driver exerted pressure on increasing irrigation water demand, which increased the risk of a water shortage. The impact of water shortage was indicated by loss of farmer income. Existing responses led to inadequate problem-solving, for example, the promotion of mixed farming. Using data captured from DPSIR analysis for LFA analysis, proposed strategies to address the root causes of “ineffective irrigation water allocation” focused on improving (1) the performance of rotating irrigation systems; (2) monitoring water allocation; and (3) water use efficiency. The strategies developed using the combined DPSIR framework and LFA are effective because: (1) this method provides insight into complex water systems; (2) the strategies are developed logically to solve the problem at its root cause; and (3) there is intensive stakeholder participation and in-depth study of the area. This method is a helpful tool for developing a management strategy for a complex water system and is suitable for application by decision-makers. Stakeholder verification is required for future research to ensure that the strategies are appropriate and capable of being implemented.
本文介绍了驾驶员压力状态影响响应(DPSIR)框架和逻辑框架方法(LFA)的结合,以制定泰国泻湖泛滥平原的水管理策略。DPSIR框架确定了水与人类活动之间的因果关系。LFA制定了基于系统和逻辑方法的管理战略。DPSIR对灌溉区缺水问题的分析表明,正如农业发展政策所表明的那样,对农业收入的需求是一个主要驱动因素。司机对不断增加的灌溉用水需求施加了压力,这增加了缺水的风险。农民收入的损失表明了缺水的影响。现有的应对措施导致解决问题不力,例如促进混合农业。利用DPSIR分析中获得的数据进行LFA分析,提出了解决“灌溉水分配无效”根本原因的策略,重点是改善(1)轮作灌溉系统的性能;(2) 监测水量分配;(3)用水效率。使用DPSIR框架和LFA组合开发的策略是有效的,因为:(1)该方法提供了对复杂水系统的深入了解;(2) 从根本上解决问题的策略是合乎逻辑的;以及(3)利益相关者的密集参与和对该领域的深入研究。该方法是制定复杂水系统管理策略的有用工具,适合决策者应用。未来的研究需要利益相关者的验证,以确保战略是适当的,并且能够实施。
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引用次数: 0
Identification of Potential Groundwater Recharge Zones Using GIS Based Multi-Criteria and AHP Technique: A Case Study of Pune City, Western Maharashtra 基于GIS的多准则和AHP技术识别潜在地下水补给区——以马哈拉施特拉邦西部浦那市为例
Q3 Environmental Science Pub Date : 2023-03-13 DOI: 10.32526/ennrj/21/202200257
Natraj Vaddadi, C. Vansarochana, Venkatesh Raghavan
With dwindling supply of surface water, Ground water is increasingly being used as a source of fresh water in many cities across the world. Consequently, there is an increasing need to evaluate groundwater potential of an area. Over the past few decades, Remote Sensing and GIS have been used for systematic investigations on potential recharge of aquifers. As in major cities of the world, the demand for water in Pune City is also increasing every year and demand outstrips the supply of surface water. This study delineated potential zones for artificial recharge across Pune City by using Multi-criteria analysis and the Analytical Hierarchy Process (AHP) techniques. Artificial recharge techniques especially the use of rainwater harvesting (RWH) are being deployed globally to augment supply of fresh water. Ground-water recharge is directly influenced by surface characteristics such as rainfall, geology, soil types, Land Use/Land Cover (LULC), drainage, lineaments/fractures, etc. Hence, six such parameters, namely, LULC, Slope, Soil texture, Rainfall, Drainage density, and Geology were considered to generate a groundwater recharge potential map. Based on the analysis, the study area was zoned into five classes, namely, low, moderate, good, very good and high groundwater potentials. About 45% of the city shows good to high potential for recharge. The results reveal that the high and good potential recharge zones lie to the western part of the city, whereas the central part (inner city) and the eastern part show medium to low potential for recharge. The results can help to identify areas for recharge and formulate a framework for systematic recharge of the existing aquifers in the area under study.
随着地表水供应的减少,地下水越来越多地被用作世界各地许多城市的淡水来源。因此,越来越需要评估一个地区的地下水潜力。在过去几十年中,遥感和地理信息系统已被用于对含水层的潜在补给进行系统调查。与世界主要城市一样,浦那市的水需求也在逐年增加,地表水供不应求。本研究采用多准则分析和层次分析法(AHP)技术,划定了浦那市人工补给的潜在区域。人工补给技术,特别是雨水收集(RWH)的使用,正在全球范围内部署,以增加淡水供应。地下水补给直接受地表特征的影响,如降雨量、地质、土壤类型、土地利用/土地覆盖(LULC)、排水、线性构造/裂缝等。因此,考虑了六个这样的参数,即LULC、坡度、土壤质地、降雨量、排水密度和地质,以生成地下水补给潜力图。根据分析,将研究区划分为五类,即低、中、好、非常好和高地下水潜力。大约45%的城市显示出良好到高的充电潜力。结果表明,高、良潜力补给带位于城市西部,而中部(内城)和东部则呈现中、低潜力补给。研究结果有助于确定补给区域,并为研究区域内现有含水层的系统补给制定框架。
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引用次数: 1
Hydrogeochemistry of Two Major Mid-hill Lentic Water Bodies for Irrigation of the Central Himalaya, Nepal 尼泊尔喜玛拉雅中部两大中山灌溉水的水文地球化学特征
Q3 Environmental Science Pub Date : 2023-02-22 DOI: 10.32526/ennrj/21/202200195
B. K. Kafle, Chhatra Mani Sharma, S. Gurung, N. Raut, K. R. Kafle, R. Bhatta, Lekhendra Tripathee, Rukumesh Paudyal, Jun-ming Guo, Shi-chang Kang, Bed Mani Dahal
The concentration and composition of different salts in natural water bodies determine the water quality for various purposes. This study assesses the water quality of two mid-mountain lentic water bodies, Lake Phewa and Kulekhani Reservoir. For this purpose, selected physico-chemical parameters along with major ions such as HCO3-, SO42-, PO43-, NO3-, Cl-, Ca2+, Mg2+, Na+, K+, and NH4+ were analyzed. Major ions were analyzed using ion chromatography, anions by DX-600 and cations by Dionex ISC-2500 ion chromatographs. The sources of major ions were determined by using the Gibbs diagram, Piper plot, and Scatter plots. Dissolved oxygen, ammonia and phosphate showed seasonal variations in both lakes. The concentrations of cations are in the order of Ca2+ > Na+ > Mg2+ > K+ in both water bodies. However the trend of anions had small variations for Cl- and SO42- in Lake Phewa (HCO3- > Cl- > SO42- > NO3-) and Kulekhani Reservoir (HCO3- > SO42- > Cl- > NO3-). The Piper plot and equiline plots indicated that the water chemistry is dominantly controlled by the dissolution of carbonate minerals and to a limited extent by weathering of silicate minerals. This is further supported by the Gibbs plot showing bedrock geology as the main source of major ions. The overall study indicates that the hydrogeochemistry of these water bodies is controlled by local geology and is suitable for irrigation purposes.
天然水体中不同盐的浓度和组成决定了不同用途的水质。本文对费瓦湖和库勒卡尼水库这两个山中湖泊水体的水质进行了评价。为此,对选定的理化参数及主要离子HCO3-、SO42-、PO43-、NO3-、Cl-、Ca2+、Mg2+、Na+、K+、NH4+进行了分析。主要离子采用离子色谱法,阴离子采用DX-600,阳离子采用Dionex ISC-2500离子色谱法。利用Gibbs图、Piper图和Scatter图确定了主要离子的来源。两个湖泊的溶解氧、氨和磷酸盐均呈现季节变化。两种水体中阳离子的浓度顺序为Ca2+ > Na+ > Mg2+ > K+。而在Phewa湖(HCO3- > SO42- > SO42- > NO3-)和Kulekhani水库(HCO3- > SO42- > Cl- > NO3-)中Cl-和SO42-阴离子变化趋势较小。Piper图和equiline图表明,水化学主要受碳酸盐矿物的溶蚀作用控制,硅酸盐矿物的风化作用也有一定程度的控制。吉布斯图进一步支持了这一点,表明基岩地质是主要离子的主要来源。综合研究表明,这些水体的水文地球化学受当地地质控制,适合灌溉。
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引用次数: 0
Evaluation of Land Use Land Cover Changes in Nan Province, Thailand, Using Multi-Sensor Satellite Data and Google Earth Engine 利用多传感器卫星数据和谷歌地球引擎评估泰国楠省土地利用-土地覆盖变化
Q3 Environmental Science Pub Date : 2023-02-16 DOI: 10.32526/ennrj/21/202200200
Jiratiwan Kruasilp, Sura Pattanakiat, T. Phutthai, P. Vardhanabindu, Pisut Nakmuenwai
Land use and land cover (LULC) conversion has become a chronic problem in Nan province. The primary factors of changes are lacking arable land, agricultural practices, and agriculture expansion. This study evaluated the usefulness of multi-sensor Landsat-5 (LS5), Landsat-8 (LS8), Sentinel-1 (S1), and Sentinel-2 (S2) satellite data for monitoring changes in LULC in Nan province, Thailand during a 30-year period (1990-2019), using a random forest (RF) model and the cloud-based Google Earth Engine (GEE) platform. Information of established land management policies was also used to describe the LULC changes. The median composite of the input variables selection from multi-sensor data were used to generate datasets. A total of 36 datasets showed the overall accuracy (OA) ranged from 51.70% to 96.95%. Sentinel-2 satellite images combined with the Modified Soil-Adjusted Vegetation Index (MSAVI) and topographic variables provided the highest OA (96.95%). Combination of optical (i.e., S2 and LS8) and S1 Synthetic Aperture Radar (SAR) data expressed better classification accuracy than individual S1 data. Forest cover decreased continuously during five consecutive periods. Coverage of maize and Pará rubber trees rapidly expanded in 2010-2014. These changes indicate an adverse consequence of the established economic development promoted by industrial and export agriculture. The findings strongly support the use of the RF technique, GEE platform and multi-sensor satellite data to enhance LULC classification accuracy in mountainous area. This study recommended that certain informative and science-based evidence will encourage local policymakers to identify priority areas for land management and natural resource conservation.
土地利用和土地覆盖转换已成为南方省的一个长期问题。变化的主要因素是缺乏可耕地、农业实践和农业扩张。本研究使用随机森林(RF)模型和基于云的谷歌地球引擎(GEE)平台,评估了多传感器陆地卫星5号(LS5)、陆地卫星8号(LS8)、哨兵1号(S1)和哨兵2号(S2)卫星数据在30年期间(1990-2019)监测泰国楠省LULC变化的有用性。已制定的土地管理政策的信息也被用来描述土地使用权法的变化。使用从多传感器数据中选择的输入变量的中值组合来生成数据集。共有36个数据集显示,总体准确度(OA)在51.70%至96.95%之间。Sentinel-2卫星图像与改良土壤调整植被指数(MSVI)和地形变量相结合,提供了最高的OA(96.95%)。光学(即S2和LS8)和S1合成孔径雷达(SAR)数据相结合,比单独的S1数据表现出更好的分类准确度。森林覆盖率在连续五个时期内持续下降。2010-2014年,玉米树和帕拉橡胶树的覆盖率迅速扩大。这些变化表明了工业和出口农业促进的既定经济发展的不利后果。研究结果有力地支持了利用RF技术、GEE平台和多传感器卫星数据来提高山区LULC分类的准确性。这项研究建议,某些信息丰富、基于科学的证据将鼓励当地决策者确定土地管理和自然资源保护的优先领域。
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引用次数: 2
Accumulation of Microplastics and Histological Analysis on Marine Fish from Coastal Waters of Baru and Trisik Beaches, Special Region of Yogyakarta 日惹特别地区巴鲁和特里西克海滩海水中微塑料的积累和组织学分析
Q3 Environmental Science Pub Date : 2023-02-14 DOI: 10.32526/ennrj/21/202200207
R. Putri, B. Retnoaji, A. P. Nugroho
River flow to the sea is regarded as a pathway for the dispersion and pollution of microplastics. The hydrodynamics of the coastal water of Baru and Trisik Beaches may increase microplastic concentrations in this estuarine-marine area. This research evaluated the microplastic concentration in surface seawater and microplastic accumulation in consumed marine fish and performed histological analysis on the demersal marine fish intestine under natural exposure. Sample collection was carried out at 12 stations with three replications. The microplastics analysis was performed on marine fish (dorsal muscle, gills, and gastrointestinal tract) and seawater, and microplastic characterization was based on physical and chemical characteristics. Environmental parameters for statistical analysis included air and water temperature, pH, dissolved oxygen, and salinity of seawater. Histological analysis of the intestine was performed on fish from three stations with two demersal fish species. The latter analysis included the length of the villi, the depth of the crypt cells, epithelial denudation with hematoxylin-eosin staining, and the number of goblet cells with periodic acid Schiff alcian blue staining. The results showed that the microplastic concentration was distributed throughout the fish sample for each of the stations. Microplastic concentrations for surface seawater showed the same pattern as marine fish. Microplastic accumulation in marine fish indicated the transfer of microplastic particles to various organs in the fish’s body. The histological analysis indicated, microplastic internalization in the intestine tissue, damaging intestinal structures. Further research is needed as consuming marine fish contaminated by microplastics may present increasing health risks.
河流入海被认为是微塑料扩散和污染的途径。巴鲁和特里西克海滩沿岸水的流体动力学可能会增加该河口海域的微塑料浓度。本研究评估了表层海水中的微塑料浓度和食用海鱼体内的微塑料积累,并对自然暴露下的底层海鱼肠道进行了组织学分析。样本采集在12个站点进行,共进行三次重复。对海鱼(背肌、鳃和胃肠道)和海水进行了微塑料分析,并基于物理和化学特性对微塑料进行了表征。用于统计分析的环境参数包括空气和水温、pH、溶解氧和海水盐度。对来自三个鱼类站的两种底层鱼类的肠道进行了组织学分析。后一种分析包括绒毛的长度、隐窝细胞的深度、苏木精-伊红染色的上皮剥脱以及碘酸希夫-阿尔辛蓝染色的杯状细胞的数量。结果表明,每个站点的微塑料浓度都分布在整个鱼类样本中。表层海水的微塑料浓度显示出与海鱼相同的模式。海洋鱼类体内的微塑料积累表明微塑料颗粒转移到鱼类体内的各个器官。组织学分析表明,微塑料在肠道组织中内化,破坏肠道结构。需要进一步研究,因为食用被微塑料污染的海鱼可能会增加健康风险。
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引用次数: 1
Characteristics of Dissolved Organic Matter and Trihalomethane Forming Potential Occurrence in Watersheds with Different Upstream Land Use 不同上游土地利用方式流域溶解有机质及三卤甲烷形成潜力赋存特征
Q3 Environmental Science Pub Date : 2023-02-13 DOI: 10.32526/ennrj/21/202200179
M. Dirgawati, M. R. Sururi
Dissolved organic matter (DOM) is the most important natural organic matter (NOM) fraction which reacts with chlorine to form harmful trihalomethanes (THMs) in water bodies. The characteristics of DOM could be affected by land use in the catchment, hence comprehensive study to understand DOM in the water body is important. This study was conducted in two watersheds with different upper stream land use to determine: (1) water characteristics, total organic matter (TOM), and DOM quality and quantity based on optical and absorption properties; (2) fluorescence dissolved organic matter (FDOM) compounds; (3) TOM and DOM relationships; and (4) THMs forming potential (THMFP) in both watersheds. Samples were collected from the upper Cimahi and Cijanggel Rivers which are dominated by settlements and plantations, respectively. Water characteristics were determined by pH, electroconductivity (EC), nitrite, and nitrate in unfiltered and filtered samples. TOM and DOM were characterized by chemical oxygen demand (COD) and chromophoric DOM (CDOM) parameters (A254, A355, A3/4), and organic compounds were determined as FDOM compounds. The measured pH, nitrate, and nitrite in the settlements-impacted watershed were greater than those in the plantations-impacted watershed. The main FDOM compounds in the settlement-impacted river were tryptophan microbial byproduct (T1) and tryptophan aromatic protein (T2), fulvic acid (A), and humic acid (C). Meanwhile, in the plantations-impacted river were T1, A, and C. THMFP was detected in both rivers which were greater in the plantations-impacted watershed than the settlements-impacted watershed.
溶解有机物(DOM)是水体中最重要的天然有机物(NOM)部分,它与氯反应形成有害的三卤甲烷(THMs)。集水区土地利用可能会影响DOM的特征,因此全面研究水体中的DOM具有重要意义。本研究在两个不同上游土地利用的流域进行,以确定:(1)基于光学和吸收特性的水特征、总有机质(TOM)和DOM质量和数量;(2) 荧光溶解有机物(FDOM)化合物;(3) TOM和DOM关系;以及(4)两个流域中的THMs形成电位(THMFP)。样本采集自Cimahi河上游和Cijanggel河上游,这两条河分别以定居点和种植园为主。通过未过滤和过滤样品中的pH、电导率(EC)、亚硝酸盐和硝酸盐来测定水的特性。通过化学需氧量(COD)和发色DOM(CDOM)参数(A254,A355,A3/4)对TOM和DOM进行了表征,确定有机化合物为FDOM化合物。受定居点影响的流域测得的pH值、硝酸盐和亚硝酸盐高于受种植园影响的流域。受沉降影响河流中的主要FDOM化合物是色氨酸微生物副产物(T1)和色氨酸芳香蛋白(T2)、黄腐酸(A)和腐殖酸(C)。同时,在受种植园影响的河流中有T1、A和C。在这两条河流中都检测到THMFP,受种植园的流域比受定居点影响的流域更大。
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引用次数: 0
Optimization and Kinetic Study of Phosphorus Dissolution from Primary Settled-Nightsoil Sludge 初沉污泥溶解磷的优化及动力学研究
Q3 Environmental Science Pub Date : 2023-01-31 DOI: 10.32526/ennrj/21/202200213
Wanida Pimpeach, W. Patthanaissaranukool, C. Polprasert, S. Polprasert, Suwisa Mahasandana, B. Panyapinyopol
In this study, chemical extraction using different acid concentrations, solids concentrations, and reaction time with subsequent interactions mechanism were carried out to evaluate the potential of phosphorus (P) recovery from primary settled-nightsoil sludge (PSNS). The response surface methodology (RSM) with Box-Behnken experimental design and one-way ANOVA analysis were also employed to establish optimal P leaching conditions. The extraction efficiency relied mainly on acid and solids concentration. The second-order polynomial model was successfully developed for extracting process designs. Approximately 93% of P could effectively be extracted from PSNS of 20,000 mg/L with 0.5 M of H2SO4 at reaction time of 45 min (optimum condition). Kinetic studies showed that the pseudo-second order was fit to describe leaching of P and metals. Moreover, the rate of kinetic constants (k2) of the P, Fe, Mg, and Ca under optimum condition were found to be 0.1607, 0.1099, 0.0317, and 0.0053 g/mg·min, respectively. The 99% leaching of maximum extracted P concentration at the equilibrium (9.6673 mg/g) took place in less than one hour. The findings of a suitable simple and low-cost method P dissolution from PSNS not only provides understanding of leaching kinetics, but also helps to pave a way of recovering P from a renewable resource in the field of waste utilization.
在本研究中,使用不同的酸浓度、固体浓度和反应时间以及随后的相互作用机制进行了化学萃取,以评估从初级沉降夜土污泥(PSNS)中回收磷的潜力。采用响应面法(RSM)结合Box-Behnken实验设计和单因素方差分析确定了最佳磷浸出条件。萃取效率主要取决于酸和固体浓度。成功地开发了用于提取工艺设计的二阶多项式模型。在反应时间45min(最佳条件)下,用0.5M的H2SO4从20000mg/L的PSNS中可以有效地提取约93%的P。动力学研究表明,拟二阶模型适用于磷和金属的浸出。此外,在最佳条件下,P、Fe、Mg和Ca的动力学常数(k2)分别为0.1607、0.1099、0.0317和0.0053g/Mg·min。平衡时最大提取磷浓度(9.6673mg/g)的99%浸出发生在不到一小时的时间内。从PSNS中溶解磷的合适的简单和低成本方法的发现不仅有助于了解浸出动力学,而且有助于在废物利用领域为从可再生资源中回收磷铺平道路。
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Environment and Natural Resources Journal
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