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SPIN-SELECTIVE INTERACTION OF TRIPLET-EXCITED MOLECULES ON THE SURFACE OF A FERROMAGNETIC NANOPARTICLE 铁磁纳米粒子表面三重态激发分子的自旋选择性相互作用
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/5-16
M. Kucherenko
Influence of a magnetic field generated by a ferromagnetic nanoparticle on the annihilation of triplet-excited organic molecules or triplet excitons in a near-surface particle layer is studied. A detailed mathematical model is presented that accounts for electron excitation diffusive mobility and geometry of the system. The kinetic operator is given in the complete 9x9 basis of triplet- triplet pair spin states. Time dependencies of the singlet spin state population of the triplet-triplet pair and the dependence of the triplet-triplet annihilation magnetic response profile (magnetic reaction effect) from the magnetic field induction are obtained. It is found that the influence of a magnetic field gradient on the reaction yield dominates over the other known mechanisms of spin-dynamics in triplet- triplet pairs.
研究了铁磁性纳米粒子产生的磁场对近表面粒子层中三重态激发的有机分子或三重态激子湮灭的影响。给出了一个详细的数学模型,该模型考虑了系统的电子激发扩散迁移率和几何结构。动力学算符是在三重态-三重态对自旋态的完全9x9基上给出的。获得了三重态-三重态对的单重态自旋态布居的时间依赖性和三重态湮灭磁响应轮廓(磁反应效应)与磁场感应的依赖性。研究发现,磁场梯度对反应产率的影响超过了三重态-三重态对中其他已知的自旋动力学机制。
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引用次数: 0
DEVELOPMENT OF ONBOARD CONTROL SYSTEM ARCHITECTURE FOR NANOSATELLITES 纳米卫星机载控制系统体系结构的研制
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/58-66
K. Alipbayev
This article presents development of the architecture of the onboard control system. In particular, the hardware and circuit solutions in the development of the module are presented. Technical solutions, the concept of the mechanical layout of the onboard control system and block diagrams of the presented modules of the onboard complex are also discussed. Main functions of the on-board software are described in details, which will help in design and development of ultra-small artificial satellites. This article serves as a new approach for how to effectively configure and operate the on-board control system.
本文介绍了车载控制系统体系结构的发展。重点介绍了该模块开发过程中的硬件方案和电路方案。文中还讨论了机载控制系统的技术方案、机械布局的概念和机载控制系统各模块的框图。详细介绍了星载软件的主要功能,为超小型人造卫星的设计和研制提供了依据。本文为如何有效配置和操作车载控制系统提供了一种新的途径。
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引用次数: 0
TRANSIENT ABSORPTION OF GOLD NANOPARTICLES OF VARIOUS DIAMETERS 不同直径金纳米粒子的瞬态吸收
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/73-77
N. Ibrayev
excitation by nanosecond laser pulses has been studied. It was shown that the maximum of stationary absorption exhibits as a wide structureless band with a maximum at about 520–540 nm. The transient absorption band of gold nanoparticles with a maximum at about 430 nm has a fine structure with a frequency of maxima of 6–8 nm and it does not depend on the size of the nanoparticles. The absorption duration decreases with a decrease in the average size of nanoparticles. The lifetime of transient absorption is equal to 23±2 and 19.5±2 ns for large and small particles, respectively. The nanosecond lifetime of the transient absorption of Au nanoparticles is the result of a prolonged relaxation process in the “interface of Au nanoparticle–solvent molecule” system as a manifestation of hindered heat exchange with the environment.
研究了纳秒激光脉冲的激发。结果表明,稳态吸收的最大值表现为宽无结构带,最大值在520 ~ 540 nm左右。金纳米粒子的瞬态吸收带在430nm处具有良好的结构,其频率最大值为6 ~ 8nm,与纳米粒子的尺寸无关。吸收持续时间随着纳米粒子平均尺寸的减小而减小。大颗粒和小颗粒的瞬态吸收寿命分别为23±2和19.5±2 ns。金纳米粒子的瞬态吸收的纳秒寿命是“金纳米粒子-溶剂分子界面”系统弛豫过程延长的结果,是与环境热交换受阻的表现。
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引用次数: 0
AUTOMATED MEASURING SYSTEM FOR INVESTIGATING TEMPERATURE DEPENDENCE OF LOW-FREQUENCY NOISE SPECTRA IN ELECTRONIC ELEMENTS AND STRUCTURES 用于研究电子元件和结构低频噪声谱温度相关性的自动测量系统
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/51-57
A. Ermachikhin
In this paper a measuring analytical system for low-frequency noise spectroscopy is presented. The measuring system is adapted for the automated study of low-frequency noise spectra in electronic elements, components and semiconductor materials and structures. A distinctive feature of the proposed measuring system is an automated complex local and precise study of the dependence of the low-frequency noise spectra in the sample on electrical voltage and temperature. The frequency range is 0.001-10000 Hz, DC bias range is 0-50 V and the temperature range is 7-500 К. The measuring system is adapted for use with an atomic force microscope for local measurements of electronic materials and structures noise characteristics. The measuring system makes it possible to obtain a larger amount of experimental data, which makes it possible to draw comprehensive conclusions about the mechanisms and causes of noise generation in the test sample. The results of testing the operation of the measuring system are given as an example of the Schottky diode-like structure study.
本文介绍了一种低频噪声谱测量分析系统。该测量系统适用于电子元件、元器件、半导体材料和结构中低频噪声谱的自动研究。所提出的测量系统的一个显著特点是对样品中低频噪声频谱对电压和温度的依赖性进行了自动化、复杂的局部精确研究。频率范围为0.001-10000 Hz,直流偏压范围为0-50 V,温度范围为7-500К。该测量系统适用于与原子力显微镜一起用于电子材料和结构噪声特性的局部测量。该测量系统可以获得大量的实验数据,从而可以对试样中噪声产生的机制和原因得出全面的结论。以肖特基类二极管结构研究为例,给出了测量系统的工作测试结果。
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引用次数: 0
INVESTIGATION OF THE STRESS STATE OF MINE WORKINGS USING METHODS OF DEFORMABLE SOLID MECHANICS 用变形固体力学方法研究矿山巷道的应力状态
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/68-72
G. Shaikhova
The assessment of the reliability of a mining and technological scheme, taking into account the stress state of mine workings, depends on a combination of mining and geological, technical and technological factors. The article demonstrates the creation of a model of a rock mass and a scheme for calculating the stress state based on modern methods of mechanics of a deformable solid body.The object of study is a single mine working of great length, passed through the rock parallel to the strike of the coal seam (field drift) and located in the zone of influence of the support pressure. Due to the fact that the field drift is laid in the soil of the formation, which is a layered stratum in the zone of influence of clearing operations, the predominant load is the bearing pressure on the formation. The areas of application of the methods of complex potentials of integral equations and their combinations in solving applied problems are determined. The data of mine (field) measurements and observations, laboratory experiments and their generalizations are taken into account both when setting tasks and assigning boundary conditions, and when checking the results obtained. The mixed problem of the theory of elasticity about the contact stress on half-strips with varying along the longitudinal axis was solved; moving away from the ends, deformative properties, when these half-strips are clamped with friction between the layered half-planes.
考虑到矿山工作的应力状态,对采矿和技术方案可靠性的评估取决于采矿和地质、技术和工艺因素的综合。本文介绍了基于可变形固体力学的现代方法建立岩体模型和计算应力状态的方案。研究对象是一个大长度的单矿,穿过平行于煤层走向的岩石(场进路),位于支护压力影响区。由于现场漂移是在地层的土壤中铺设的,而地层是清理作业影响区内的层状地层,因此主要荷载是对地层的承载压力。确定了积分方程复势方法及其组合方法在解决实际问题中的应用范围。在设定任务和分配边界条件时,以及在检查所得结果时,都考虑到矿(场)测量和观测数据、实验室实验数据及其概括。解决了沿纵轴变化的半条接触应力的弹性理论混合问题;当这些半条被层状半平面之间的摩擦夹紧时,从两端移动,变形特性。
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引用次数: 0
CARBON FOOTPRINT COMPARATIVE ANALYSIS FOR EXISTING AND PROMISING THERMAL POWER PLANTS 现有和有前景的火力发电厂碳足迹比较分析
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/34-43
N. Rogalev
The power production industry is the main greenhouse gas emitter that makes its contribution to global warming. The greenhouse gas emission takes place in fuel production, transportation, and combustion. A prospective method for emission mitigation is the transition to organic fuel-burning facilities with small emissions by capturing carbon dioxide. Power consumption on the carbon dioxide capture remarkably reduces the efficiency of these facilities, which leads to increasing of fuel consumption and greenhouse gas emission because of the larger fuel production and transportation. Based on the material balance method, taking into account system effect of changes in efficiency and amount of fuel consumed, the paper estimated the carbon footprint over a twenty-year lifecycle for following thermal power plants types: combined cycle and oxy-fuel combustion plants for both natural gas and coal with internal gasification. It is shown that the transition to oxygen-fuel plants can reduce the carbon footprint near 90% for natural gas and near 75% for coal. The study also demonstrates the positive effect of carbon capture and storage system implementation for reducing carbon footprint near 75% for natural gas and near 70% for coal.
电力生产行业是造成全球变暖的主要温室气体排放国。温室气体排放发生在燃料生产、运输和燃烧过程中。一种有前景的减排方法是通过捕获二氧化碳向排放量小的有机燃料燃烧设施过渡。二氧化碳捕获的电力消耗显著降低了这些设施的效率,由于燃料生产和运输量较大,导致燃料消耗和温室气体排放增加。基于材料平衡法,考虑到效率和燃料消耗量变化的系统效应,本文估计了以下类型的火力发电厂在20年生命周期内的碳足迹:天然气和煤的联合循环和氧燃料燃烧厂,以及内部气化。研究表明,向氧气燃料工厂的过渡可以将天然气的碳足迹减少近90%,将煤炭的碳足迹降低近75%。该研究还证明了碳捕获和储存系统的实施对减少天然气近75%的碳足迹和煤炭近70%的碳足迹的积极影响。
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引用次数: 0
INFLUENCE OF IONIZING RADIATION ON THE DIFFUSE REFLECTION SPECTRA OF STEATITE CERAMICS SNC 电离辐射对滑石陶瓷SNC漫反射光谱的影响
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/22-27
M. Ashurov
In this article, the radiation defects induced in steatite ceramics type- SNC- irradiated with high doses of gamma-rays of 60Co source and mixed reactor nо-gamma-irradiation were studied using optical spectroscopy, i.e. diffuse reflection method. An analysis of the results of the diffuse reflection spectra showed that some structural defects are formed under gamma-irradiation. These are oxygen vacancies, unbound oxygen atoms, and E1 -centers (a three-coordinated silicon atom that has captured an electron) in the ultraviolet region of the spectrum. In the visible region of the spectrum, the types of hole centers are different. After decomposing the spectrum of the visible region into Gaussians, it was found that in this region of the spectrum, with no –gamma- irradiation of the reactor, in comparison with gamma-irradiation, various types of hole centers - (O-Me, Me-metal) are additionally formed. The efficiency of creating these structural defects in nо-gamma-reactor irradiated samples was higher compared to gamma irradiated samples.
本文采用漫反射光谱学方法研究了高剂量60Co源γ射线和混合反应堆γ射线辐照下滑石陶瓷- SNC型的辐射缺陷。对漫反射光谱结果的分析表明,在γ辐照下形成了一些结构缺陷。这些是氧空位,未结合的氧原子和E1中心(一个三配位的硅原子捕获了一个电子)在光谱的紫外区域。在光谱可见区域,空穴中心的类型是不同的。将可见区光谱分解成高斯谱后发现,在该光谱区域,在反应器没有- γ辐照的情况下,与γ辐照相比,额外形成了各种类型的空穴中心- (O-Me, Me-metal)。与伽玛辐照样品相比,在辐照后的样品中产生这些结构缺陷的效率更高。
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引用次数: 0
TESTING OF DIFFERENT MATERIAL TYPE PHOTOELECTRIC BATTERY AND PHOTOTHERMAL BATTERIES COMPOSED 测试不同材料类型的光电电池和光热电池组成
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/44-50
M. Tursunov
In the world, over the years, the use of hydrocarbon resources is decreasing, and their place is being replaced by ecologically clean alternative and renewable energy sources. Therefore, the world is paying a lot of attention to improved devices based on photoelectric batteries. Conducting targeted scientific research in this direction is one of the urgent issues of the present time. This article presents the results of comparing the electrical parameters of photovoltaic and photothermal batteries based on them in natural conditions. The experiments were carried out on three traditional photoelectric batteries with different materials and constructions, as well as photothermal batteries made on their basis. All batteries are installed in a mobile structure, and two planes (reflectors) that reflect sunlight are installed along the long side of the device connecting the batteries. In the same conditions, the intensity of solar radiation is increased with the help of reflectors that return light to photoelectric and photothermal batteries. On the front surface of the photovoltaic batteries, a vertical (90) fall of the sun's rays is provided. As a result, their electrical parameters changed to different values depending on the type of material and construction. Compared to traditional photoelectric batteries, photothermal batteries produced 1.3-1.4 times more electricity depending on the type of material. In the results of the experiment, data were obtained on the open circuit voltage, short circuit current and power of photoelectric and photothermal batteries in hot climate conditions. According to results, the high indicators in terms of electrical parameters are monocrystalline photoelectric and photothermal batteries based on them.
多年来,在世界上,碳氢化合物资源的使用正在减少,它们的位置正在被生态清洁的替代能源和可再生能源所取代。因此,全世界都在关注基于光电电池的改进型器件。在这个方向上进行有针对性的科学研究是当前紧迫的问题之一。本文介绍了在自然条件下比较光伏电池和光热电池的电气参数的结果。在三种不同材料和结构的传统光电电池以及在此基础上制成的光热电池上进行了实验。所有电池都安装在移动结构中,两个反射阳光的平面(反射器)沿着连接电池的设备的长边安装。在相同的条件下,太阳能辐射的强度在反射器的帮助下增加,反射器将光返回光电和光热电池。在光伏电池的前表面上) 提供了太阳光线的下落。因此,根据材料类型和结构,它们的电气参数会变为不同的值。与传统的光电电池相比,根据材料的类型,光热电池的发电量是传统光电电池的1.3-1.4倍。在实验结果中,获得了光电和光热电池在高温气候条件下的开路电压、短路电流和功率数据。根据结果,在电学参数方面的高指标是基于它们的单晶光电和光热电池。
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引用次数: 0
EFFECT OF ANODIZING VOLTAGE ON THE PHOTOCATALYTIC ACTIVITY OF FILMS FORMED BY TITANIUM DIOXIDE NANOTUBES 阳极氧化电压对二氧化钛纳米管薄膜光催化活性的影响
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/28-33
T. Serikov
The influence of the anodizing voltage during synthesis on the specific surface area and on the photocatalytic activity of the TiO2 nanotube was studied. Films formed by titanium dioxide nanotubes were obtained on the surface of titanium foil by electrochemical anodizing. It has been found that an increase in the anodizing voltage from 20 V to 60 V leads to an increase in the inner and outer diameters of nanotubes, an increase in the growth rate and the interpore distance of nanotubes. The photocatalytic activity of the samples was evaluated by measuring the magnitude of the photoinduced current. The film produced at low voltage generated a current 3.5 times higher than the film produced at high voltage, and the degradation of the dye in the presence of the films was 75 and 38%, respectively, over the same period of time. An increase in the photocatalytic activity of the films is mainly associated with an increase in the specific surface area of the nanotubes. Thus, the values of the specific surface area of TiO2 nanotubes were determined by the method of low-temperature nitrogen adsorption. It has been established that with an increase in the anodizing voltage, the specific surface area of the films decreases.
研究了合成过程中阳极氧化电压对TiO2纳米管比表面积和光催化活性的影响。采用电化学阳极氧化法在钛箔表面制备了二氧化钛纳米管薄膜。已经发现,阳极氧化电压从20V增加到60V导致纳米管的内径和外径增加,纳米管的生长速率和电极间距离增加。通过测量光诱导电流的大小来评估样品的光催化活性。在低电压下制备的膜产生的电流是在高电压下制得的膜的3.5倍,并且在相同的时间段内,在膜的存在下染料的降解分别为75%和38%。膜的光催化活性的增加主要与纳米管的比表面积的增加有关。因此,通过低温氮吸附法测定了TiO2纳米管的比表面积值。已经证实,随着阳极氧化电压的增加,薄膜的比表面积减小。
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引用次数: 0
EFFECT OF HIGH-PRESSURE TORSION ON MICROSTRUCTURE CHANGES IN MICROALLOYED STEEL 高压扭转对微合金钢组织变化的影响
Q3 Engineering Pub Date : 2022-12-26 DOI: 10.31489/2022no4/17-21
I. Volokitina
Тhe most common method of manufacturing parts is metal pressure treatment, as a result of which the entire reserve of strength and ductility of the material is not exhausted. Therefore, the issues of the influence of plastic deformation on the cyclic durability and endurance limits of steel rings are relevant. In this article experimental studies of the effect of high pressure torsion in a die of new design on the evolution of the microstructure and the change of mechanical properties have been carried out. As a result, the fundamental possibility and efficiency of using the proposed method for the formation of ultrafine grained structure and increasing the strength properties of steel rings has been proved. Strain was carried out at ambient temperature in six passes. The strain resulted in an ultrafine-grained structure with an average grain size of 0.5 μm and a great number of large-angle boundaries. The strength properties of microalloyed steel increased almost threefold compared to the initial state, the microhardness also increased threefold, i.e. increased from 760 MPa in the initial state to 1935 MPa after strain. The greatest increase in strength properties occurred in the first 3 cycles of strain.
Тhe制造零件最常用的方法是金属压力处理,其结果是材料的强度和延展性的全部储备不会耗尽。因此,塑性变形对钢环循环耐久性和极限耐久性的影响问题具有重要意义。本文对新设计模具进行了高压扭转对模具组织演变和力学性能变化的影响试验研究。结果证明了采用该方法形成超细晶组织和提高钢环强度性能的可行性和有效性。在环境温度下分六道进行应变。变形形成平均晶粒尺寸为0.5 μm的超细晶组织和大量的大角度晶界。微合金钢的强度性能比初始状态提高了近3倍,显微硬度也提高了3倍,即从初始状态的760 MPa提高到应变后的1935 MPa。强度性能的最大提高发生在应变的前3次循环中。
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引用次数: 0
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Eurasian Physical Technical Journal
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