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Development of mesoporous activated carbons derived from brewed coffee waste for CO2 adsorption 咖啡渣中介孔活性炭吸附CO2的研究
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002809
D. N. K. Putra Negara, I. Widiyarta, I. Suriadi, I. G. K. Dwijana, I. M. D. Budiana Penindra, I. G. N. P. Tenaya, I. K. Sukadana, Anton Saladin Ferdinand
The primary cause of rising CO2 concentrations in the atmosphere is the use of fossil fuels in motor vehicles and factory activities in industry. CO2 levels in the atmosphere can be controlled and reduced by using low-carbon energy and capturing and storing CO2. One widely used way for CO2 capture and storage is adsorption method. This method necessitates the use of an adsorbent, one of which is activated carbon. In this study, brewed coffee waste was converted into activated carbons, characterized, and tested for carbon dioxide adsorption. Brewed coffee waste was dehydrated at 105 ºC for an hour before being carbonized at 550 °C and activated at 670, 700, and 730 °C, with a 200-ml/min nitrogen injection during activation. Activated carbons with activation temperatures of 670, 700, and 730 °C were denoted as AC-670, AC-700, and AC-730, respectively. A series of TGA, SEM, and adsorption isotherm tests were used to determine the proximate components, surface morphology, and surface structure of the activated carbons produced. To assess the adsorption capacities of activated carbon on CO2, the gravimetric CO2 adsorption isotherm method was used. According to the findings of the study, increasing activation temperatures cause variable properties in activated carbon. When using an activation temperature of 700 °C, the most appropriate properties of activated carbon can be obtained. It has 425.843 m2/g specific surface area, 0.345 cm3/g pore volume, 3.423 nm pore diameter, 235.628 cm3/g nitrogen adsorption capacity, and 4.183 mmol/g CO2 adsorption performance. This study provided a simple way converting brewed coffee waste into activated carbon with excellent performance for CO2 adsorption
大气中二氧化碳浓度上升的主要原因是机动车和工业工厂活动中使用化石燃料。大气中的二氧化碳水平可以通过使用低碳能源以及捕获和储存二氧化碳来控制和减少。吸附法是目前广泛应用的二氧化碳捕集与封存方法之一。这种方法需要使用吸附剂,其中一种是活性炭。在本研究中,将煮好的咖啡废料转化为活性炭,对其进行了表征,并对其二氧化碳吸附进行了测试。煮好的咖啡渣在105℃下脱水1小时,然后在550℃下碳化,在670、700和730℃下活化,活化过程中注射200 ml/min的氮气。活化温度为670℃、700℃和730℃的活性炭分别记为AC-670、AC-700和AC-730。采用热重分析仪、扫描电镜和吸附等温线测试来确定活性炭的近似成分、表面形貌和表面结构。采用等温线吸附法测定了活性炭对CO2的吸附能力。根据研究结果,提高活化温度会导致活性炭的性能发生变化。当活化温度为700℃时,可获得最合适的活性炭性能。具有425.843 m2/g比表面积,0.345 cm3/g孔体积,3.423 nm孔径,235.628 cm3/g氮气吸附容量,4.183 mmol/g CO2吸附性能。本研究提供了一种简单的方法将冲泡咖啡渣转化为活性炭,并具有优异的CO2吸附性能
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引用次数: 1
Flow distribution analysis of a novel fcc system through experiment study and atomic model 通过实验研究和原子模型分析了一种新型催化裂化系统的流动分布
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002813
A. I. Siswantara, M. Syafei, M. A. Budiyanto, C. D. Widiawaty, Adi Syuriadi, T. A. Farhan, S. Permana
As the largest palm oil producer in the world, Indonesia has a promising potential to produce green fuel through the Fluid Catalytic Cracking (FCC) process. A novel FCC configuration, FCC Proto X 3, which combines a riser reactor and downer reactor in the system, has been developed. However, several valves including in the FCC system remain a black box to the flow distribution in the system. The objective of this paper is to investigate the effect of the valve setting variation on the airflow distribution of the FCC system. The methodology uses experiment and acausal modeling. The effect of valve setting variation on pressure and average velocity of the airflow has been investigated. The experiment is conducted under cold test conditions, while the acausal model of the FCC system is built by using OpenModelica. It is obtained that valve 2 which controls the flow at the channel toward the regenerator is essential due to its role in controlling the air supply combustion process in the regenerator and driving the spent catalyst particles to the regenerator. Valve 3 is responsible for controlling the flow toward the riser reactor directly. Later, it is responsible for supplying the lifting fluid to support the catalytic cracking reaction at the riser sections. Valve 4 contributes to controlling the lifting fluid to the downer reactor. It will also be responsible for supplying thermal energy from the high-temperature particle catalyst to the reactor. When all valves toward the regenerator and reactor are 100 % open, the measured average velocity at the flue gas outlet and the product outlet are 8.04 m/s and 5.775 m/s respectively. The result shows that the airflow at the FCC system tends to flow through the regenerator. The atomic model estimation also shows a similar trend to the experiment result
作为世界上最大的棕榈油生产国,印度尼西亚具有通过流体催化裂化(FCC)工艺生产绿色燃料的巨大潜力。一种新型的FCC配置,FCC Proto x3,在系统中结合了一个提升反应器和一个下行反应器。然而,包括FCC系统在内的几个阀门对于系统中的流量分布仍然是一个黑匣子。本文的目的是研究阀门设置变化对催化裂化系统气流分布的影响。方法采用实验和因果模型。研究了阀门设置变化对气流压力和平均流速的影响。实验是在冷试验条件下进行的,而FCC系统的因果模型是使用OpenModelica建立的。结果表明,控制通道流向蓄热器的阀2是必不可少的,因为它在控制蓄热器内的送风燃烧过程和将废催化剂颗粒驱动到蓄热器中起着重要作用。阀门3负责直接控制流向立管反应堆的流量。随后,它负责提供提升液,以支持立管段的催化裂化反应。阀门4用于控制进入下行反应堆的提升流体。它还将负责从高温颗粒催化剂向反应器提供热能。当所有通向蓄热器和反应器的阀门100%打开时,在烟气出口和产品出口测得的平均速度分别为8.04 m/s和5.775 m/s。结果表明,催化裂化系统内气流有向蓄热器流动的趋势。原子模型估计也显示出与实验结果相似的趋势
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引用次数: 1
Development of simple kits (SK) refraction of light using photodiode sensors for student understanding 开发简单的套件(SK)光的折射使用光电二极管传感器的学生理解
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002728
F. C. Wibowo, Ade Nur Maemunah, H. Nasbey, B. Coştu, B. Prahani, Niki Dian Permana, D. R. Darman, A. Samsudin
Students' understanding to learn science on the concept of light refraction is experiencing serious problems because of the unobservable of light particles. The research object to be resolved in this study is to improve the concept of light refraction using a photodiode sensor. The problem to be solved in this research is to develop a Simple Kit (SK) Refraction of Light (RoL) using a photodiode sensor for students' understanding of concepts. The research method for making SK RoL using photodiode sensors using ADDIE, which consists of the first stage, analysis by analyzing the needs of SK RoL products using photodiode sensors to be developed. Second, the SK RoL design uses a photodiode sensor. Third, Development is developing SK RoL Using Photodiode Sensors. Implementation of the Fourth RoL Decree Using Photodiode Sensors to see student understanding of 74 students from tertiary institutions in one of the provinces in Indonesia. Fifth, Evaluation by revising the product at each stage of SK RoL development. SK RoL product research results include Green Laser, Photodiode sensor, Angle Arc, Display Module and Displayed Data, Arduino Uno R3 Atmega 328, Medium Container and Programs Using Arduino Software. The characteristics of the SK ROL results show that the SK RoL based on the Photodiode Sensor developed can be used as a physics learning medium because it can visualize the unobservable concept of light refraction and increase students' understanding of the concept of light refraction because of the nature of the particles which are difficult to understand by using a green laser which is passed through a photodiode sensor medium and Arduino can be visualized in a real way. SK RoL can work optimally in a room where the light is not too bright or requires a room that is a bit dark so it is possible to observe the laser beam. SK RoL, as a physics learning medium, can be used to increase students' understanding of the concept of light refraction. The implications of developing SK RoL can be used as a learning medium to attract students' interest in learning, support the learning process, and help make it easier for students to understand abstract physics concepts
由于光粒子的不可观测性,学生在学习科学时对光折射概念的理解出现了严重问题。本研究要解决的研究对象是利用光电二极管传感器改进光折射的概念。本研究要解决的问题是开发一个简单的套件(SK)光折射(RoL),使用光电二极管传感器,以帮助学生理解概念。利用ADDIE利用光电二极管传感器制造SK RoL的研究方法,包括第一阶段,通过分析SK RoL即将开发的光电二极管传感器产品的需求进行分析。其次,SK - RoL设计使用光电二极管传感器。第三,开发利用光电二极管传感器的SK RoL。利用光电二极管传感器实施第四项RoL法令,了解来自印度尼西亚一个省份的高等院校74名学生的理解情况。第五,在SK RoL开发的每个阶段通过修改产品进行评估。SK RoL的产品研究成果包括绿色激光器、光电二极管传感器、角弧、显示模块和显示数据、Arduino Uno R3 Atmega 328、中型容器和使用Arduino软件的程序。SK高校的特点,结果表明,SK高校基于光电二极管传感器开发的可以用作物理学习中因为它可以可视化的难以察觉的概念光折射,增加学生对概念的理解光的折射,由于粒子的性质由使用难以理解一个绿色激光通过一个光电二极管传感器介质和Arduino可以可视化在真实的方式。SK RoL可以在光线不太亮的房间里工作,或者需要一个有点暗的房间,这样就可以观察到激光束。SK RoL作为一种物理学习媒介,可以用来增加学生对光折射概念的理解。开发SK RoL的意义可以作为一种学习媒介,以吸引学生的学习兴趣,支持学习过程,并帮助学生更容易理解抽象的物理概念
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引用次数: 1
The effect of hold-melt time of micro-regime precipitation size and hardness in Al-Cu alloy 保温时间对Al-Cu合金微态析出尺寸和硬度的影响
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002684
W. Suprapto, Y. Irawan, S. Suparman, Muhammad Rafi Amrullah, Pratama Auliasyah, Aditya Rafi Ramdhani
This study aims to control the characterization and mechanical properties of smelting Al-Cu Alloy through Hold-Melt Time. This research uses aluminum scrap and copper wire scrap to produce quality as-cast ingots, clean the environment, and increase waste utilization. Copper melting point of 1083 °C is immersed in molten aluminum at a temperature of 900 °C for 10–30 minutes causing copper to dissolve in aluminum due to smelting events based on diffusion phenomena. Parameters of temperature and immersion time of copper in molten aluminum in this study are expressed by hold-melt time. In the copper aluminum alloy trade, commonly called Duralumin, it is commonly used for impact loads and is heat-treatable. Resistance to cryogenic temperatures, in the future Duralumin has the potential to replace stainless steel. This study used an electric resistance furnace with the specifications for smelting aluminum 3 kg, electric power 2.5–3.0 kW, electric voltage 220 Volts, maximum temperature 1000 °C. It had been conducted an experiment where copper had been melted under its melting point in duralumin ingot casting. In this study, copper pieces were soaked in liquid aluminum with temperature of 900 °C. After 10–30 minutes of holding melt, the soaked copper became Al-Cu alloys and was called molten Duralumin. After the molten duralumin had been cleaned from dross, it was poured into ingot casting. From specific weight test, more soaking time of the copper in liquid aluminum caused specific weight of ingot duralumin increase from 47.08 % to 57.56 % and its hardness increase from 93 to 113 BHN. This study contributes on melting energy saving and improves the characteristic and hardness of ingot aluminum type 2xxx
本研究旨在通过保温时间控制铝铜合金的表征和力学性能。本研究利用废铝、废铜线生产优质铸锭,清洁环境,提高废弃物利用率。铜熔点为1083℃,在900℃的铝液中浸泡10-30分钟,由于基于扩散现象的熔炼事件,导致铜溶解在铝中。本研究中铜在铝液中的温度和浸泡时间参数用保温时间表示。在铜铝合金行业中,通常称为硬铝,它通常用于冲击载荷,并且可以热处理。耐低温,在未来硬铝有可能取代不锈钢。本研究使用的电阻炉规格为熔炼铝3kg,电功率2.5-3.0 kW,电压220伏,最高温度1000℃。在硬铝铸锭中对铜进行了熔点以下的熔炼试验。在本研究中,铜片浸泡在温度为900℃的铝液中。保温10-30分钟后,浸过的铜就变成了Al-Cu合金,称为熔融硬铝。熔化的硬铝从杂质中清除后,倒入铸锭中。比重试验结果表明,随着铜在铝液中浸泡时间的延长,铸锭的比重由47.08%提高到57.56%,硬度由93提高到113 BHN。本研究有助于降低熔炼能耗,提高2xxx型铝锭的特性和硬度
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引用次数: 1
Research of methods for determining dynamic stress of the bars in the main structure of gantry crane installed on the cap of bridge pier to serve installation of Super-T girder 为安装超级t型梁而安装在桥墩上的门式起重机主体结构杆的动应力确定方法研究
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002673
Bui Thanh Danh, N. Van Cuong
The article presents briefly findings in researching methods for determining dynamic stress of the bars in the main structure of gantry crane installed on the cap of bridge pier to install and launch SUPER-T girder. In order to study the dynamic stresses in the bars of the main truss structure of the gantry, the author first had to build a dynamic model, using Matlap software to solve the problem of dynamics with two cases cargo lowering combination combines braking and moving of gantry with cargo to find out the rules and values of dynamic cable tension, dynamic inertial force ( time-varying force), then consider these forces is the external force acting on the main truss structure model of the gantry, from which the author calculates the value of internal force and stress of each bar corresponding to the value of dynamic cable tension and corresponding dynamic inertia force. with two adverse working cases of the gantry. Using Matlap software to calculate the author has obtained a graph of internal force, stress changes over time of each bar in the main truss steel structure of the gantry. The findings of the research provided methods for determining the dynamic stress of the bars in the main structure of gantry crane, pointed out values and rules of change of the dynamic stress of the bars in the main structure of gantry crane. The findings of the research may be used to calculate fatigue, life-span of the main steel structures as well as other parts of the gantry crane
本文简要介绍了安装在桥墩顶架上的门式起重机主结构杆的动应力测定方法的研究成果。为了研究动态应力的酒吧主要龙门的桁架结构,作者首先必须建立一个动态模型,使用Matlap软件来解决动力学问题的两箱货物降低组合结合制动和移动的龙门和货物动态电缆张力的规则和价值观,动态惯性力(时变力),然后再考虑这些力量是外力作用于龙门主桁架结构模型,由此计算出与索的动张力值和相应的动惯性力值相对应的各杆的内力和应力值。具有两种不利的龙门工作情况。利用Matlap软件进行计算,得到了龙门主桁架钢结构各杆的内力、应力随时间的变化曲线图。研究结果为确定门式起重机主体结构杆体动应力提供了方法,指出了门式起重机主体结构杆体动应力的取值和变化规律。研究结果可用于门式起重机主要钢结构及其他部件的疲劳、寿命计算
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引用次数: 0
A new approach to numerical simulation of boundary value problems of the theory of elasticity in stresses and strains 应力应变弹性理论边值问题数值模拟的新方法
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002735
A. Khaldjigitov, Umidjon Djumayozov, Otajon Tilovov
The main parameters characterizing the process of deformation of solids are displacements, strain and stress tensors. From the point of view of the strength and reliability of the structure and its elements, researchers and engineers are mainly interested in the distribution of stresses in the objects under study. Unfortunately, all boundary value problems are formulated and solved in solid mechanics mainly with respect to displacements, or an additional stress functions. And the required stresses are calculated from known displacements or stress functions. In this case, the accuracy of stress calculation is strongly affected by the error of numerical differentiation, as well as the approximation order of the boundary conditions. The formulation of boundary value problems directly with respect to stresses or strains allows to increase the accuracy of stress calculation by bypassing the process of numerical differentiation. Therefore, the present work is devoted to the formulation and numerical solution of boundary value problems directly with respect to stresses and strains. Using the well-known Beltrami-Miеchell equation, and considering the equilibrium equation as ah additional boundary condition, a boundary value problem(BVP) is formulated directly with respect to stresses. In a similar way, using the strain compatibility condition, the Beltrami-Mitchell type equations for strains are written. The finite difference equations for two-dimensional BVP are constructed and written in convenient a form for the use of iterative method. A number of problems on the equilibrium of a rectangular plate under the action of various loads applied on opposite sides are numerically solved. The reliability of the results is ensured by comparing the numerical results of the 2D elasticity problems in stresses and strains, and with the exact solution, as well as with the known solutions of the plate tension problem under parabolic and uniformly distributed loads
表征固体变形过程的主要参数是位移、应变和应力张量。从结构及其构件的强度和可靠性的角度来看,研究人员和工程师主要感兴趣的是所研究对象的应力分布。不幸的是,在固体力学中,所有的边值问题主要是根据位移或附加应力函数来表述和解决的。所需的应力由已知的位移或应力函数计算得到。在这种情况下,应力计算的精度受到数值微分误差和边界条件近似顺序的强烈影响。直接关于应力或应变的边值问题的公式可以通过绕过数值微分过程来提高应力计算的准确性。因此,目前的工作是致力于直接与应力和应变有关的边值问题的公式和数值解。利用著名的beltrami - minovelchell方程,将平衡方程作为附加的边界条件,直接建立了关于应力的边值问题。同样地,利用应变相容条件,写出了应变的Beltrami-Mitchell型方程。构造了二维BVP的有限差分方程,并将其写成便于使用迭代法的形式。本文用数值方法解决了矩形板在不同载荷作用下的平衡问题。通过将二维应力应变弹性问题的数值结果与抛物线和均布荷载作用下板张力问题的精确解以及已知解进行比较,保证了计算结果的可靠性
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引用次数: 1
Critical stress evaluation of rigid pavement due to the presence of water in expansive soil subgrade 膨胀土路基含水刚性路面临界应力评价
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002810
W. Wibowo, A. Setyawan, Y. Purwana, B. Setiawan
The use of various types of rigid pavement is widespread because of its superiority in resisting heavy load vehicles. However, traffic loading complexity and subgrade response cause uncertainty during the design process. The presence of water in expansive soil issue swelling affected the flexural behavior of a rigid pavement slab. Rigid pavement relies heavily on the support and stability of the subgrade. Plain concrete is very weak in resisting tensile stresses so that the failure of rigid pavement slab structures often occurs in the expansive subgrade zone. Therefore, this study aims to numerically analyze the relationship between variations in the thickness of rigid pavement slabs on the flexural behavior parameters, such as critical and tensile stresses that affected water in expansive soil. The concrete’s performance limit was determined, using its material’s constitutive equation curve, and the data were analyzed using the finite element method. The results showed that the presence of water in expansive soil caused a change in soil volume (swelling), a reduction in soil bearing capacity (shrinking), and consequently, a rigid pavement cracked due to water variations in the subgrade. Generally, increasing the thickness of rigid pavement is a common method for mitigating the detrimental effects of expansive soil swelling. It is possible to provide reinforcement in other forms, which provide an opportunity to improve the performance of the concrete slab as a rigid pavement. For example, stabilization of expansive soil with materials capable of reducing its expansive power can be done but it requires large resources to realize it. Another method is to provide reinforcement to the rigid pavement slab structure, so that the rigid pavement slab is able to withstand traffic loads and also the expansion and shrinkage behavior of the expansive soil
各种类型的刚性路面因其在抗重载车辆方面的优越性而得到广泛的应用。然而,交通荷载的复杂性和路基的响应导致了设计过程中的不确定性。膨胀土中水的存在影响了刚性路面板的受弯性能。刚性路面在很大程度上依赖于路基的支撑和稳定性。素混凝土抗拉应力能力很弱,在膨胀路基区经常发生刚性路面板结构的破坏。因此,本研究旨在数值分析刚性铺装板厚度变化与影响膨胀土含水量的临界应力和拉应力等弯曲行为参数之间的关系。利用混凝土材料的本构方程曲线确定了混凝土的性能极限,并用有限元法对数据进行了分析。结果表明,膨胀土中存在水分会引起土体体积的变化(膨胀),土体承载能力的降低(收缩),从而导致路基中水分的变化导致刚性路面开裂。一般来说,增加刚性路面的厚度是减轻膨胀土膨胀不利影响的常用方法。提供其他形式的加固是可能的,这为改善混凝土板作为刚性路面的性能提供了机会。例如,用能够降低膨胀土膨胀力的材料来稳定膨胀土是可以做到的,但需要大量的资源来实现。另一种方法是对刚性铺装板结构进行加固,使刚性铺装板既能承受交通荷载,又能承受膨胀土的胀缩特性
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引用次数: 0
Study of the influence of thermobaric conditions on the rheological characteristics of plugging solutions for insulation works 温压条件对保温工程堵漏液流变特性影响的研究
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002731
Novruzova Sudaba, I. Aliyev, Fariz Ahmad
Since most of the fields in the Absheron peninsula of the Republic of Azerbaijan are at the final stage of development, an inevitable reduction in hydrocarbon production is expected. An increase in the proportion of formation water in well production, the presence of intra-reservoir, annulus and other cross-flows in this region, in most cases, is associated with inefficient isolation work. The development of effective recipes for cement slurries with controlled rheological properties is relevant. Natural zeolite was used as an additive to control the rheological properties of cement slurries. A feature of zeolites is the presence of a system of regular channels and communicating cavities capable of holding ions, atoms and molecules of substances, whose size corresponds to the size of free space. Zeolite (clinoptilolite) has the following properties: adsorption ‒ the ability to absorb and release various substances; ion exchange ‒ the ability to exchange cations; catalytic ‒ the ability to speed up chemical reactions. In addition, clinoptilolite has a molecular sieve effect that transmits (filtration) and absorbs molecules of various substances selectively. In the course of experiments, the effects of zeolite dispersions on the physicochemical parameters of cement stone were studied. When regulating the rheological properties of cement slurries with zeolite additives, it is necessary to determine the effect of thermobaric factors on the values of these properties. In studies to assess the effect of temperature on the rheological properties of zeolite-cement mortars, they were carried out for the temperature range of 25÷75 ℃
由于阿塞拜疆共和国阿布歇隆半岛的大多数油田都处于开发的最后阶段,预计碳氢化合物产量将不可避免地减少。在大多数情况下,井生产中地层水的比例增加,储层内、环空和其他交叉流动的存在,都与隔离工作效率低下有关。开发具有控制流变性能的水泥浆的有效配方是有意义的。采用天然沸石作为添加剂控制水泥浆的流变性能。沸石的一个特点是存在一个系统的规则通道和通信腔能够容纳离子,原子和物质的分子,其大小对应于自由空间的大小。沸石(斜发沸石)具有以下性质:吸附性——吸附和释放各种物质的能力;离子交换——交换阳离子的能力;催化-加速化学反应的能力。此外,斜发沸石具有分子筛作用,可以选择性地传递(过滤)和吸收各种物质的分子。在实验过程中,研究了沸石分散体对水泥石理化参数的影响。在调节掺入沸石添加剂的水泥浆的流变性能时,有必要确定热压因素对这些性能值的影响。温度对沸石水泥砂浆流变性能影响的研究,在25÷75℃温度范围内进行
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引用次数: 0
Investigation of the formation of microstructure and strength characteristics of slag-alkaline arbolite 渣碱性碳化物的形成、微观结构及强度特性研究
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002814
B. Isakulov, H. Abdullaev, Almagul Mukasheva, Uzakbai Akishev, Gulsaira Ordabayeva
The creation of the slag-alkaline arbolite's structure is examined in this study, which is based on measurements of the deformation of the mortar component, contact zone, and filler. Composites made of slag and alkaline arbolite are among the lightest building materials available, with excellent sound insulation and low thermal conductivity. Standard measuring equipment and procedures for analyzing the chemical and physico-mechanical properties of slag-alkaline arbolite composites were employed during the experimental tests. All of the test samples were light concrete prisms with a cross section of 150x150 mm and a length of 600 mm. For comparison, one portion of the samples was constructed of slag-alkaline Portland cement, and the other portion was made of slag-alkaline binder with crushed cotton stem fibers as an organic component. The durability and deformability of arbolite were tested under Kazakhstan weather conditions and in standard hardening chambers. The arbolite underwent a compression stress that ranged from (0.3 to 0.75) Rbn of prismatic strength. It was discovered that the organic cellulose filler added to the slag-alkaline binder based on crushed cotton stalk fiber, which makes up to 70 % of the volume, has a major impact on the way structures are formed. The system becomes rigid, the elasticity changes, and the acoustic properties in this case will fix both physical and physico-chemical processes when a porous organic filler is added. The acquired results can be applied to the creation of efficient wall materials for civil buildings, including seismic zones
在本研究中,基于砂浆组分、接触区和填料的变形测量,研究了炉渣碱性碳酸盐结构的形成。由矿渣和碱性碳石制成的复合材料是最轻的建筑材料之一,具有优异的隔音性能和低导热性。试验采用了炉渣-碱性碳石复合材料化学和物理力学性能分析的标准测量设备和程序。试验试样均为轻混凝土棱柱体,截面为150x150mm,长度为600mm。为了进行比较,一部分样品由矿渣碱性硅酸盐水泥构成,另一部分样品由矿渣碱性粘结剂构成,其中粉碎的棉茎纤维为有机组分。在哈萨克斯坦的气候条件下和标准硬化室中测试了亚氏体的耐久性和变形性。弓形体承受的压缩应力范围为(0.3 ~ 0.75)Rbn的棱柱体强度。研究发现,在以碎棉秆纤维为基础的渣碱性粘结剂中添加有机纤维素填料(占体积的70%)对结构的形成方式有重要影响。当加入多孔有机填料时,系统变得刚性,弹性发生变化,在这种情况下,声学特性将固定物理和物理化学过程。所获得的结果可以应用于民用建筑高效墙体材料的创建,包括地震带
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引用次数: 0
Enhanced mechanical and water resistance properties of cassava starch-PVA composites with TiO2 nanofillers for triboelectric nanogenerators films 用TiO2纳米填料增强木薯淀粉-聚乙烯醇复合材料摩擦电纳米发电机薄膜的力学性能和耐水性
Q3 Engineering Pub Date : 2023-03-22 DOI: 10.21303/2461-4262.2023.002647
Aris Ansori, S. Soeparman, D. Widhiyanuriyawan, T. Widodo
The utilization of biopolymers for energy applications continues to attract researchers, due to the unique properties of biopolymers that are easily modified, such as cassava starch (CS) biopolymer that has hydroxyl molecular chains. However, the brittle, and non-waterproof nature of starch films is an obstacle to their use in triboelectric nanogenerator (TENG) solid-solid films. This study aims to improve the physicochemical properties of cassava starch films by modifying them into nanocomposite films. The nanocomposite film was made from 70:30 CS/polyvinyl alcohol (PVA) composite and variation of TiO2 nanoparticles addition using solvent casting method. The results showed that the mechanical properties of cassava starch film increased with the addition of PVA. Meanwhile, the addition of TiO2 above 1 wt % of the mechanical properties of the film tends to decrease. The film has low wettability properties with a contact angle of 83.6°. The performance of the nanocomposite film as a Rotary disc freestanding film (RDF-TENG) produces 4.4-fold the output voltage and 2.8-fold the current compared to the film without TiO2. This is a new finding that the CS/PVA-TiO2 nanocomposite film has the potential for TENG films in high-humidity environmental conditions
由于生物聚合物具有易于修饰的独特性质,例如具有羟基分子链的木薯淀粉(CS)生物聚合物,因此生物聚合物在能源应用方面的利用继续吸引着研究人员。然而,淀粉薄膜的脆性和不防水特性阻碍了它们在摩擦电纳米发电机(TENG)固体-固体薄膜中的应用。本研究旨在通过改性木薯淀粉薄膜来改善其理化性能。采用溶剂浇铸法制备了70:30 CS/聚乙烯醇(PVA)复合材料,并添加了TiO2纳米粒子。结果表明,PVA的加入提高了木薯淀粉膜的力学性能。同时,TiO2添加量在1 wt %以上时,薄膜的力学性能有下降的趋势。膜的润湿性较低,接触角为83.6°。与不含TiO2的薄膜相比,作为旋转盘独立式薄膜(RDF-TENG)的纳米复合薄膜的输出电压是前者的4.4倍,电流是后者的2.8倍。这是一个新的发现,CS/PVA-TiO2纳米复合膜在高湿环境条件下具有成为TENG膜的潜力
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EUREKA: Physics and Engineering
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