Pub Date : 2024-09-18DOI: 10.3390/environments11090205
Karina I. Paredes-Páliz, Benito Mendoza, Jennifer Mesa-Marín
The aim of this work was to determine the content of heavy metals in soil and, for the first time, in wild Cortaderia nitida, and to discuss its potential as a metal phytoremediator plant. We sampled sediments (bulk and rhizosphere) and C. nitida (roots and shoots) in three nearby spots with different land uses (urban, industrialized and agricultural) along the Chibunga river basin (Ecuador). We analyzed the physico-chemical parameters in soil and heavy metal contents in soil and plants. The agricultural sediments showed the highest conductivity and redox potential, but the lowest pH. Among all the metals analyzed in soil and plants, we only found significant values of Zn and Fe. We observed clear differences in patterns of Zn distribution throughout soil and plants among the three areas sampled, thus suggesting that soil properties played an important role in Zn compartmentalization. Also, C. nitida demonstrated effective Zn translocation from roots to shoots, especially in farmlands (translocation factors between 1.64 and 2.51). Together with the results obtained for other Cortaderia species in metal-polluted areas, this study proposes C. nitida as a candidate to further study its metal phytoremediation potential and encourages this research in heavy metal-enriched soils.
{"title":"Zinc Accumulation Pattern in Native Cortaderia nitida in High Andes (Ecuador) and Potential for Zinc Phytoremediation in Soil","authors":"Karina I. Paredes-Páliz, Benito Mendoza, Jennifer Mesa-Marín","doi":"10.3390/environments11090205","DOIUrl":"https://doi.org/10.3390/environments11090205","url":null,"abstract":"The aim of this work was to determine the content of heavy metals in soil and, for the first time, in wild Cortaderia nitida, and to discuss its potential as a metal phytoremediator plant. We sampled sediments (bulk and rhizosphere) and C. nitida (roots and shoots) in three nearby spots with different land uses (urban, industrialized and agricultural) along the Chibunga river basin (Ecuador). We analyzed the physico-chemical parameters in soil and heavy metal contents in soil and plants. The agricultural sediments showed the highest conductivity and redox potential, but the lowest pH. Among all the metals analyzed in soil and plants, we only found significant values of Zn and Fe. We observed clear differences in patterns of Zn distribution throughout soil and plants among the three areas sampled, thus suggesting that soil properties played an important role in Zn compartmentalization. Also, C. nitida demonstrated effective Zn translocation from roots to shoots, especially in farmlands (translocation factors between 1.64 and 2.51). Together with the results obtained for other Cortaderia species in metal-polluted areas, this study proposes C. nitida as a candidate to further study its metal phytoremediation potential and encourages this research in heavy metal-enriched soils.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"18 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Steam stripping of ammonia from ammonia-rich wastewater (5000–20,000 mg/L) was conducted in a continuous-flow rotating packed bed (RPB) at a pH of 11. This study aimed to elucidate the influence of key operational parameters, including the steam-to-liquid ratio, rotational speed (ω), initial ammonia concentration, steam inlet temperature (TSi), and liquid inlet temperature (TLi), on critical performance metrics such as the ammonia removal efficiency (ARE), the volumetric liquid mass transfer coefficient (KLa), and the concentration of the recovered ammonia solution (CR). The findings revealed that a CR of 22.88 wt.% was achieved under the optimal conditions of a steam-to-liquid ratio of 0.175 kg/kg, an initial concentration of 20,000 mg/L, a TSi of 120 °C, and a TLi of 70 °C. Key experimental factors, including the initial ammonia concentration, TSi, and TLi, significantly impacted the achievement of higher ARE and CR values. The KLa values exhibited a decrease with the increase in the steam-to-liquid ratio, while they increased with ω. However, the KLa remained relatively consistent with ω values within the range of 600 to 1200 rpm. In comparison with prior studies, steam stripping of ammonia exhibits a higher ARE than air stripping with RPB and a higher CR than conventional stripping methods. Moreover, RPB requires a smaller size to achieve equivalent ARE compared to conventional stripping apparatuses. Thus, the steam stripping process with RPB equipment emerges as a suitable method for ammonia recovery from ammonia-rich wastewater.
{"title":"Steam Stripping for Recovery of Ammonia from Wastewater Using a High-Gravity Rotating Packed Bed","authors":"Min-Hao Yuan, Minh Viet Trinh, Yi-Hung Chen, Yong-Jhe Lu, Li-Pang Wang, Shikun Cheng, Zifu Li, Malee Santikunaporn, Channarong Asavatesanupap","doi":"10.3390/environments11090206","DOIUrl":"https://doi.org/10.3390/environments11090206","url":null,"abstract":"Steam stripping of ammonia from ammonia-rich wastewater (5000–20,000 mg/L) was conducted in a continuous-flow rotating packed bed (RPB) at a pH of 11. This study aimed to elucidate the influence of key operational parameters, including the steam-to-liquid ratio, rotational speed (ω), initial ammonia concentration, steam inlet temperature (TSi), and liquid inlet temperature (TLi), on critical performance metrics such as the ammonia removal efficiency (ARE), the volumetric liquid mass transfer coefficient (KLa), and the concentration of the recovered ammonia solution (CR). The findings revealed that a CR of 22.88 wt.% was achieved under the optimal conditions of a steam-to-liquid ratio of 0.175 kg/kg, an initial concentration of 20,000 mg/L, a TSi of 120 °C, and a TLi of 70 °C. Key experimental factors, including the initial ammonia concentration, TSi, and TLi, significantly impacted the achievement of higher ARE and CR values. The KLa values exhibited a decrease with the increase in the steam-to-liquid ratio, while they increased with ω. However, the KLa remained relatively consistent with ω values within the range of 600 to 1200 rpm. In comparison with prior studies, steam stripping of ammonia exhibits a higher ARE than air stripping with RPB and a higher CR than conventional stripping methods. Moreover, RPB requires a smaller size to achieve equivalent ARE compared to conventional stripping apparatuses. Thus, the steam stripping process with RPB equipment emerges as a suitable method for ammonia recovery from ammonia-rich wastewater.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-18DOI: 10.3390/environments11090207
Domenica Mosca Angelucci, Valentina Stazi, Maria Concetta Tomei
Dyes employed in many production cycles are characterized by high toxicity and persistence in the environment, and conventional wastewater treatments often fail to reach high removal efficiencies. Consequently, there is an increasing research demand aimed at the development of more efficient and sustainable technologies. A two-step strategy consisting of dye sorption followed by sorbent bio-regeneration is proposed here, with a special focus on the regeneration step. The objective of this study was to establish the best operating conditions to achieve regeneration of dye-loaded polymers and concurrently the ultimate removal of the dyes. To this aim, the bio-regeneration of the Hytrel 8206 polymer, used as a sorbent material to remove Remazol Red dye from textile wastewater, was investigated in a two-phase partitioning bioreactor (TPPB) under alternated anaerobic–aerobic conditions. Comprehensive analysis of operational parameters, including sorbent load and initial contamination levels, was conducted to optimize bio-regeneration efficiency. Experimental data demonstrated high regeneration efficiencies (91–98%) with biodegradation efficiencies up to 89%. This study also examines the biodegradation process to investigate the fate of biodegradation intermediates; results confirmed the successful degradation of the dye without significant by-product accumulation. This research underscores the potential of TPPB-based bio-regeneration of polymeric sorbent material for sustainable wastewater treatment, offering a promising solution to the global challenge of dye pollution in water resources.
许多生产循环中使用的染料都具有高毒性和环境持久性的特点，而传统的废水处理方法往往无法达到很高的去除效率。因此，旨在开发更高效、更可持续技术的研究需求与日俱增。本文提出了一种由染料吸附和吸附剂生物再生组成的两步策略，并特别关注再生步骤。这项研究的目的是确定最佳操作条件，以实现染料负载聚合物的再生，同时最终去除染料。为此，研究人员在厌氧-好氧交替条件下，在两相分离生物反应器（TPPB）中对用作吸附材料的 Hytrel 8206 聚合物进行了生物再生研究，以去除纺织废水中的 Remazol Red 染料。对吸附剂负荷和初始污染水平等操作参数进行了综合分析，以优化生物再生效率。实验数据表明再生效率高（91-98%），生物降解效率高达 89%。这项研究还考察了生物降解过程，以研究生物降解中间产物的去向；结果证实染料降解成功，没有明显的副产品积累。这项研究强调了基于 TPPB 的高分子吸附材料生物再生技术在可持续废水处理方面的潜力，为解决水资源中染料污染这一全球性挑战提供了一种前景广阔的解决方案。
{"title":"The Ultimate Fate of Reactive Dyes Absorbed onto Polymer Beads: Feasibility and Optimization of Sorbent Bio-Regeneration Under Alternated Anaerobic–Aerobic Phases","authors":"Domenica Mosca Angelucci, Valentina Stazi, Maria Concetta Tomei","doi":"10.3390/environments11090207","DOIUrl":"https://doi.org/10.3390/environments11090207","url":null,"abstract":"Dyes employed in many production cycles are characterized by high toxicity and persistence in the environment, and conventional wastewater treatments often fail to reach high removal efficiencies. Consequently, there is an increasing research demand aimed at the development of more efficient and sustainable technologies. A two-step strategy consisting of dye sorption followed by sorbent bio-regeneration is proposed here, with a special focus on the regeneration step. The objective of this study was to establish the best operating conditions to achieve regeneration of dye-loaded polymers and concurrently the ultimate removal of the dyes. To this aim, the bio-regeneration of the Hytrel 8206 polymer, used as a sorbent material to remove Remazol Red dye from textile wastewater, was investigated in a two-phase partitioning bioreactor (TPPB) under alternated anaerobic–aerobic conditions. Comprehensive analysis of operational parameters, including sorbent load and initial contamination levels, was conducted to optimize bio-regeneration efficiency. Experimental data demonstrated high regeneration efficiencies (91–98%) with biodegradation efficiencies up to 89%. This study also examines the biodegradation process to investigate the fate of biodegradation intermediates; results confirmed the successful degradation of the dye without significant by-product accumulation. This research underscores the potential of TPPB-based bio-regeneration of polymeric sorbent material for sustainable wastewater treatment, offering a promising solution to the global challenge of dye pollution in water resources.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"29 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-18DOI: 10.3390/environments11090204
Jorge Bañuelos-Gimeno, Natalia Sobrino, Rosa Arce-Ruiz
Commuting to work by private vehicle is one of the main sources of air pollution in cities, mainly from NO2 and particulate matter (PM2.5 and PM10). With the spread of telework, traffic congestion during peak hours is reduced on certain days of the week, improving air quality. This study analyzes the relationship between the improvement of air quality and urban traffic resulting from teleworking activities after the COVID-19 pandemic in Madrid, Spain. This article considers road traffic and teleworking before the COVID-19 pandemic (2018 and 2019), during the pandemic (2020 and 2021) and in the period after (2022 and 2023) in the city center and the influence on certain environmental factors. Daily NO2, PM2.5, PM10, and O3 concentration data were collected at air quality stations in Madrid municipality, and traffic data and some meteorological variables such as wind speed, precipitation and temperature were considered. When conducting correlation and regression analysis among the variables, there is a clear association between NO2 and traffic before the pandemic, which is lower for both PM and O3. This correlation was maintained during the pandemic, except for O3, the association of which increased during this period and then decreased in the later period due to various motives. These results seem to indicate the existence of a relevant relationship between urban mobility and air quality and an especially relevant relationship with telework, suggesting the need for policies aimed at promoting sustainable mobility in the future.
{"title":"Initial Insights into Teleworking’s Effect on Air Quality in Madrid City","authors":"Jorge Bañuelos-Gimeno, Natalia Sobrino, Rosa Arce-Ruiz","doi":"10.3390/environments11090204","DOIUrl":"https://doi.org/10.3390/environments11090204","url":null,"abstract":"Commuting to work by private vehicle is one of the main sources of air pollution in cities, mainly from NO2 and particulate matter (PM2.5 and PM10). With the spread of telework, traffic congestion during peak hours is reduced on certain days of the week, improving air quality. This study analyzes the relationship between the improvement of air quality and urban traffic resulting from teleworking activities after the COVID-19 pandemic in Madrid, Spain. This article considers road traffic and teleworking before the COVID-19 pandemic (2018 and 2019), during the pandemic (2020 and 2021) and in the period after (2022 and 2023) in the city center and the influence on certain environmental factors. Daily NO2, PM2.5, PM10, and O3 concentration data were collected at air quality stations in Madrid municipality, and traffic data and some meteorological variables such as wind speed, precipitation and temperature were considered. When conducting correlation and regression analysis among the variables, there is a clear association between NO2 and traffic before the pandemic, which is lower for both PM and O3. This correlation was maintained during the pandemic, except for O3, the association of which increased during this period and then decreased in the later period due to various motives. These results seem to indicate the existence of a relevant relationship between urban mobility and air quality and an especially relevant relationship with telework, suggesting the need for policies aimed at promoting sustainable mobility in the future.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"213 3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The remediation of environments contaminated with per- and polyfluoroalkyl substances (PFAS) has become a growing priority due to the persistent, bioaccumulative, and toxic characteristics of these compounds. To promote green and sustainable remediation practices, it is crucial to assess and minimize the environmental impacts of PFAS remediation projects through life cycle assessment (LCA) at the early stages of planning. So far, no systematic literature review has been published to assess the current state of the art or identify the challenges associated with applying LCA to PFAS remediation. This article provides a review of the recent literature on LCAs of PFAS remediation, following the ISO 14040 and 14044 standards. The results indicate that the application of LCA to PFAS remediation remains in its infancy and is highly fragmented. Significant methodological variations, including differences in system boundaries and data quality, hinder the comparability and benchmarking of LCA results across studies. To enhance the use of LCA as a decision support tool for environmental assessment, there is a pressing need for methodological harmonization and improved practices. Key areas for improvement include enhancing data quality, reducing uncertainties, and increasing the robustness of PFAS LCAs, thereby enabling more informed and sustainable decision-making in PFAS remediation efforts.
{"title":"Life Cycle Assessment of Per- and Polyfluoroalkyl Substances (PFAS) Remediation Technologies: A Literature Review","authors":"Xingqiang Song, Malin Montelius, Christel Carlsson","doi":"10.3390/environments11090203","DOIUrl":"https://doi.org/10.3390/environments11090203","url":null,"abstract":"The remediation of environments contaminated with per- and polyfluoroalkyl substances (PFAS) has become a growing priority due to the persistent, bioaccumulative, and toxic characteristics of these compounds. To promote green and sustainable remediation practices, it is crucial to assess and minimize the environmental impacts of PFAS remediation projects through life cycle assessment (LCA) at the early stages of planning. So far, no systematic literature review has been published to assess the current state of the art or identify the challenges associated with applying LCA to PFAS remediation. This article provides a review of the recent literature on LCAs of PFAS remediation, following the ISO 14040 and 14044 standards. The results indicate that the application of LCA to PFAS remediation remains in its infancy and is highly fragmented. Significant methodological variations, including differences in system boundaries and data quality, hinder the comparability and benchmarking of LCA results across studies. To enhance the use of LCA as a decision support tool for environmental assessment, there is a pressing need for methodological harmonization and improved practices. Key areas for improvement include enhancing data quality, reducing uncertainties, and increasing the robustness of PFAS LCAs, thereby enabling more informed and sustainable decision-making in PFAS remediation efforts.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"94 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.3390/environments11090200
Gerald Schernewski, Thomas Neumann, Martynas Bučas, Miriam von Thenen
We assess the ecosystem services across the entire Baltic Sea using ecosystem model simulations and historical socio-economic data. Our approach covers 150 years, aggregated for the years around 1880, 1960, and 2010. The ecosystem services assessed include commercially usable wild fish biomass and wild plant biomass, water quality regulation (nitrogen and phosphorus retention), carbon storage, biodiversity and habitats, as well as active recreation and landscape aesthetics. In 2010, the commercially usable fish biomass in the entire Baltic Sea was 9.24 million tons. The total retention of nitrogen in the Baltic Sea was 884,135 t/a, phosphorus retention was 32,058 t/a, and carbon storage was 3,668,100 t/a. Between 1880 and 2010, the Baltic Sea-wide average biodiversity index decreased from 73 to 60, the active recreational quality index decreased from 76 to 69, and the observational recreation index declined from 91 to 78. In 2010, the most monetarily significant single ecosystem service in the Baltic Sea was nitrogen retention with EUR 26,822 million/a, followed by cultural ecosystem services. Other relevant services were fish catches (EUR 277 million/a), phosphorus retention (EUR 3854 million/a), and carbon storage (202 million/a). The latter recently showed a steep increase due to rising prices for CO2 certificates.
{"title":"Ecosystem Services of the Baltic Sea—State and Changes during the Last 150 Years","authors":"Gerald Schernewski, Thomas Neumann, Martynas Bučas, Miriam von Thenen","doi":"10.3390/environments11090200","DOIUrl":"https://doi.org/10.3390/environments11090200","url":null,"abstract":"We assess the ecosystem services across the entire Baltic Sea using ecosystem model simulations and historical socio-economic data. Our approach covers 150 years, aggregated for the years around 1880, 1960, and 2010. The ecosystem services assessed include commercially usable wild fish biomass and wild plant biomass, water quality regulation (nitrogen and phosphorus retention), carbon storage, biodiversity and habitats, as well as active recreation and landscape aesthetics. In 2010, the commercially usable fish biomass in the entire Baltic Sea was 9.24 million tons. The total retention of nitrogen in the Baltic Sea was 884,135 t/a, phosphorus retention was 32,058 t/a, and carbon storage was 3,668,100 t/a. Between 1880 and 2010, the Baltic Sea-wide average biodiversity index decreased from 73 to 60, the active recreational quality index decreased from 76 to 69, and the observational recreation index declined from 91 to 78. In 2010, the most monetarily significant single ecosystem service in the Baltic Sea was nitrogen retention with EUR 26,822 million/a, followed by cultural ecosystem services. Other relevant services were fish catches (EUR 277 million/a), phosphorus retention (EUR 3854 million/a), and carbon storage (202 million/a). The latter recently showed a steep increase due to rising prices for CO2 certificates.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"54 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.3390/environments11090202
Mariana Martins, Ana Pombo, Susana Mendes, Carlos A. P. Andrade
Plastic pollution is a global problem affecting all ecosystems, and it represents most of the marine litter. Offshore aquaculture is a sector particularly vulnerable to this issue. To investigate this concern, the present study employed videography to monitor macroplastics at an offshore fish farm on Madeira Island (Portugal) and analysis of fish gut content to evaluate macroplastic ingestion by farmed sea bream Sparus aurata. Our analysis revealed that the majority of identified plastic debris originated from domestic use (66.66%) and fisheries/aquaculture activities (24.99%). While the number of dead fish suitable for sampling was limited (1.05% of the total mortality), macroplastic debris ingestion was identified in 5.15% of the total mortalities and reported for the first time in species in offshore farming conditions. Fish ingested fragmented plastic sheets, with the amount positively correlated with fish weight (r = 0.621, p = 0.031, n = 12). Notably, the stretched length of these fragments exceeded 50% of the standard length of most fish. Inconsistencies were observed in the number of samples collected per cage and per week. To ensure robust results, these discrepancies should be rectified in future studies. Additionally, extending the sampling period to encompass all seasons would be beneficial for a more comprehensive understanding of seasonal variations in plastic occurrence.
{"title":"Plastics at an Offshore Fish Farm on the South Coast of Madeira Island (Portugal): A Preliminary Evaluation of Their Origin, Type, and Impact on Farmed Fish","authors":"Mariana Martins, Ana Pombo, Susana Mendes, Carlos A. P. Andrade","doi":"10.3390/environments11090202","DOIUrl":"https://doi.org/10.3390/environments11090202","url":null,"abstract":"Plastic pollution is a global problem affecting all ecosystems, and it represents most of the marine litter. Offshore aquaculture is a sector particularly vulnerable to this issue. To investigate this concern, the present study employed videography to monitor macroplastics at an offshore fish farm on Madeira Island (Portugal) and analysis of fish gut content to evaluate macroplastic ingestion by farmed sea bream Sparus aurata. Our analysis revealed that the majority of identified plastic debris originated from domestic use (66.66%) and fisheries/aquaculture activities (24.99%). While the number of dead fish suitable for sampling was limited (1.05% of the total mortality), macroplastic debris ingestion was identified in 5.15% of the total mortalities and reported for the first time in species in offshore farming conditions. Fish ingested fragmented plastic sheets, with the amount positively correlated with fish weight (r = 0.621, p = 0.031, n = 12). Notably, the stretched length of these fragments exceeded 50% of the standard length of most fish. Inconsistencies were observed in the number of samples collected per cage and per week. To ensure robust results, these discrepancies should be rectified in future studies. Additionally, extending the sampling period to encompass all seasons would be beneficial for a more comprehensive understanding of seasonal variations in plastic occurrence.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"118 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.3390/environments11090201
Reagan Patton Witt, Marcelo I. Guzman
Landfills for disposing of solid waste are designed, located, managed, and monitored facilities expected to comply with government regulations to prevent contamination of the surrounding environment. After the average life expectancy of a typical landfill (30 to 50 years), a large investment in the construction, operation, final closure, and 30-year monitoring of a new site is needed. In this case study, we provide a holistic explanation of the unexpected development of elevated temperature landfills (ETLFs), such as that in the city of Bristol (United States) on the border of the states of Virginia and Tennessee, including the initial role played by coal ash. Despite the increasing frequency of ETLF occurrence, there is limited knowledge available about their associated environmental problems. The study uses mixed (qualitative, quantitative, and mapping) methods to analyze (1) the levels of odoriferous reduced sulfur compounds, ammonia, and volatile organic compounds (VOCs) emitted, (2) the ratio of methane to carbon dioxide concentrations in five locations, which dropped from unity (normal landfill) to 0.565, (3) the location of gas well heads with gradients of elevated temperatures, and (4) the correlation of the filling rate (upward of ~12 m y−1) with depth for registered events depositing coal ash waste. The work identifies spatial patterns that support the conclusion that coal ash served as the initiator for an ETLF creation. The case of the city of Bristol constitutes an example of ETLFs with elevated temperatures above the regulatory United States Environmental Protection Agency (EPA) upper threshold (65 °C), having alongside low methane emissions, large production of leachate, land subsidence, and a large production of organic compounds. Such landfills suffer abnormal chemical reactions within the waste mass that reduce the life expectancy of the site. Residents in such communities suffer intolerable odors from fugitive emissions and poor air quality becomes prominent, affecting the well-being and economy of surrounding populations. Conclusive information available indicates that the Bristol landfill has been producing large amounts of leachate and hazardous gases under the high pressures and temperatures developed within the landfill. A lesson learned, which should be used to prevent this problem in the future, is that the early addition of coal ash into the landfill would have catalyzed the process of ETLF creation. The work considers the public health risks and socioeconomic problems of residents exposed to emissions from an ETLF and discusses the efforts needed to prevent further incidents in other locations.
{"title":"Coal Ash Triggers an Elevated Temperature Landfill Development: Lessons from the Bristol Virginia Solid Waste Landfill Neighboring Community","authors":"Reagan Patton Witt, Marcelo I. Guzman","doi":"10.3390/environments11090201","DOIUrl":"https://doi.org/10.3390/environments11090201","url":null,"abstract":"Landfills for disposing of solid waste are designed, located, managed, and monitored facilities expected to comply with government regulations to prevent contamination of the surrounding environment. After the average life expectancy of a typical landfill (30 to 50 years), a large investment in the construction, operation, final closure, and 30-year monitoring of a new site is needed. In this case study, we provide a holistic explanation of the unexpected development of elevated temperature landfills (ETLFs), such as that in the city of Bristol (United States) on the border of the states of Virginia and Tennessee, including the initial role played by coal ash. Despite the increasing frequency of ETLF occurrence, there is limited knowledge available about their associated environmental problems. The study uses mixed (qualitative, quantitative, and mapping) methods to analyze (1) the levels of odoriferous reduced sulfur compounds, ammonia, and volatile organic compounds (VOCs) emitted, (2) the ratio of methane to carbon dioxide concentrations in five locations, which dropped from unity (normal landfill) to 0.565, (3) the location of gas well heads with gradients of elevated temperatures, and (4) the correlation of the filling rate (upward of ~12 m y−1) with depth for registered events depositing coal ash waste. The work identifies spatial patterns that support the conclusion that coal ash served as the initiator for an ETLF creation. The case of the city of Bristol constitutes an example of ETLFs with elevated temperatures above the regulatory United States Environmental Protection Agency (EPA) upper threshold (65 °C), having alongside low methane emissions, large production of leachate, land subsidence, and a large production of organic compounds. Such landfills suffer abnormal chemical reactions within the waste mass that reduce the life expectancy of the site. Residents in such communities suffer intolerable odors from fugitive emissions and poor air quality becomes prominent, affecting the well-being and economy of surrounding populations. Conclusive information available indicates that the Bristol landfill has been producing large amounts of leachate and hazardous gases under the high pressures and temperatures developed within the landfill. A lesson learned, which should be used to prevent this problem in the future, is that the early addition of coal ash into the landfill would have catalyzed the process of ETLF creation. The work considers the public health risks and socioeconomic problems of residents exposed to emissions from an ETLF and discusses the efforts needed to prevent further incidents in other locations.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"48 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-12DOI: 10.3390/environments11090199
Avri Eitan
In recent years, climate change has escalated significantly, with forecasts indicating that this trend will further accelerate in the future. Renewable energy systems play a crucial role in global efforts to mitigate climate change due to their minimal greenhouse gas emissions. These systems also have the potential to facilitate the energy sector’s adaptation to climate change, given their decentralized nature, which enhances the resilience of energy infrastructure to extreme climate events. Nevertheless, existing literature predominantly focuses on their role in global mitigation efforts, often overlooking their significant adaptation capacity, particularly as reflected in national policies. This study seeks to bridge this gap through a qualitative examination of how renewable energy is incorporated into climate change adaptation policies in three countries: Australia, Canada, and the United Kingdom. It highlights a growing awareness of the role of renewable energy within these countries’ adaptation policies. However, while there is consensus on the importance of policy factors such as local focus, research initiatives, and risk assessment in utilizing renewable energy for adaptation, this study reveals that the actual deployment of renewable energy remains largely centered on mitigation efforts, partly neglecting crucial adaptation needs in the energy sector, such as geographical and technological diversification.
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Pub Date : 2024-09-11DOI: 10.3390/environments11090198
Dimitrios Kalaronis, Eleni Evgenidou, George Z. Kyzas, Dimitrios N. Bikiaris, Dimitra A. Lambropoulou
The main goal of this study is the examination of polypropylene (PP) microplastics (MPs) as possible carriers of daily use pharmaceutical compounds. The selected compounds can be separated into three groups: (i) antibiotics (Trimethoprim, Metronidazole, Indomethacin, Isoniazid), (ii) anti-inflammatories (Ketoprofen, Diclofenac), and (iii) anti-hypertensive (Valsartan). Two types of PP MPs (virgin and UV-aged) were used in the experimental procedure, and the effect of time and the effect of the initial concentrations of the drugs were examined. The impact of various environmental factors such as pH, salinity, and natural organic matter were also explored. The last two factors were studied using real aqueous matrices such as wastewater and seawater. According to the obtained results, the highest uptake was observed in indomethacin (9.3 mg/g) and diclofenac (7.3 mg/g), owing to their physiochemical properties. Aged particles showed enhanced adsorption ability in accordance with the existing literature, as their adsorption capacity was between 0.5–1.5 times greater than that of the virgin ones. Regarding the desorption of compounds from the virgin and aged PP MPs at three different pH values, diclofenac and indomethacin exhibited the highest desorption capacity, while alkaline conditions favored the desorption ability of PP MPs for most of the target compounds.
{"title":"Adsorption of a Mixture of Daily Use Pharmaceuticals on Pristine and Aged Polypropylene Microplastics","authors":"Dimitrios Kalaronis, Eleni Evgenidou, George Z. Kyzas, Dimitrios N. Bikiaris, Dimitra A. Lambropoulou","doi":"10.3390/environments11090198","DOIUrl":"https://doi.org/10.3390/environments11090198","url":null,"abstract":"The main goal of this study is the examination of polypropylene (PP) microplastics (MPs) as possible carriers of daily use pharmaceutical compounds. The selected compounds can be separated into three groups: (i) antibiotics (Trimethoprim, Metronidazole, Indomethacin, Isoniazid), (ii) anti-inflammatories (Ketoprofen, Diclofenac), and (iii) anti-hypertensive (Valsartan). Two types of PP MPs (virgin and UV-aged) were used in the experimental procedure, and the effect of time and the effect of the initial concentrations of the drugs were examined. The impact of various environmental factors such as pH, salinity, and natural organic matter were also explored. The last two factors were studied using real aqueous matrices such as wastewater and seawater. According to the obtained results, the highest uptake was observed in indomethacin (9.3 mg/g) and diclofenac (7.3 mg/g), owing to their physiochemical properties. Aged particles showed enhanced adsorption ability in accordance with the existing literature, as their adsorption capacity was between 0.5–1.5 times greater than that of the virgin ones. Regarding the desorption of compounds from the virgin and aged PP MPs at three different pH values, diclofenac and indomethacin exhibited the highest desorption capacity, while alkaline conditions favored the desorption ability of PP MPs for most of the target compounds.","PeriodicalId":11886,"journal":{"name":"Environments","volume":"5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142199169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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