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Atmospheric Solid Fallouts as a Source of Hydrophobicity of Urban Soils and Material for Their Formation 作为城市土壤疏水性来源的大气固体降尘及其形成材料
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-22 DOI: 10.1134/s106422932460074x
N. V. Goncharov, T. V. Prokof’eva, D. I. Potapov, G. N. Fedotov

Abstract

In urban conditions, the soil is exposed to a number of adverse factors that have a great impact on its hydrophobic and hydrophilic properties. The water-repellent properties of urban dust and soils were determined with the water drop penetration time (WDPT) test. Hydrophobization of Albic Retisols in the conditions of a megalopolis was modeled, and its rate was estimated. Three dust samples with different values of the WDPT test from 420 to 850 seconds were studied. According to the results of the model experiment, with an increase of solid atmospheric fallout in the Retisols, the level of their hydrophobicity also increases. The rate of the increase depends on the water-repellent properties of the dust. During pollution with the most hydrophobic dust, the maximum hydrophobization of the humus-accumulative soil horizon is achieved upon a 70-year-long impact. For other dust samples, an increase in the time of absorption of a drop was observed up to the maximum period of aerial soil contamination within the model experiment (200 years). Values of the WDPT test for the studied soil horizons ranged from 2.4 s to 1493.5 s for background soil and urban soil forming near a major highway for 90 years, respectively. In the soil of forty-year-old residential area, the value was 237.1 s. The correspondence of the levels of hydrophobicity, the degree of anthropogenic load and the residence time in the urban environment in the model experiment and in the samples of real urban soils indicates that solid atmospheric fallouts are a component of humus-accumulative horizons of urban soils and have a significant impact on their water-repellent properties.

摘要 在城市环境中,土壤会受到许多不利因素的影响,对其疏水和亲水特性产生很大的影响。通过水滴渗透时间(WDPT)测试确定了城市灰尘和土壤的憎水性。模拟了大城市条件下阿尔卑斯网状土壤的疏水性,并估算了疏水性的速率。研究了 WDPT 测试值从 420 秒到 850 秒不同的三种粉尘样本。根据模型实验的结果,随着 Retisols 中固体大气沉降物的增加,其疏水程度也随之增加。增加的速度取决于灰尘的憎水性。在受到疏水性最强的粉尘污染时,腐殖质累积土壤层的疏水性在受到 70 年的影响后达到最大值。对于其他粉尘样本,在模型实验中观察到吸收一滴粉尘的时间延长到空中土壤污染的最长时间(200 年)。在研究的土壤层中,背景土壤和在主要高速公路附近形成 90 年的城市土壤的 WDPT 测试值分别从 2.4 秒到 1493.5 秒不等。在模型实验和实际城市土壤样本中,疏水性水平、人为负荷程度和在城市环境中的停留时间的对应关系表明,固体大气沉降物是城市土壤腐殖质累积层的组成部分,对其憎水特性有重大影响。
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引用次数: 0
Trace Elements in Marsh Soils of the Pomor Coast of the White Sea 白海波莫尔海岸沼泽土壤中的微量元素
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-22 DOI: 10.1134/s1064229324600817
I. E. Bagdasarov, M. V. Konyushkova, Yu. A. Kryukova, D. V. Ladonin, M. A. Tseits, P. V. Krasilnikov

Abstract

Sea coastal soils are functioning on the contact of terrigenous runoff and the seawater impact, which provides a unique geochemical environment. Migration and accumulation of elements can be partially promoted by the formation and oxidation of iron sulfides. We studied the content and spatial distribution of Fe, Mn and trace elements in the marsh soils of the Pomor coast of the White Sea. The work was carried out near the village of Kolezhma, Belomorsk district, Republic of Karelia. The study revealed the elevated concentrations of trace elements in these soils, such as As and Se, which are usually associated with metal sulfides in marine sediments. A high content of Fe and Mn was registered, i.e., up to 27 300 and 1500 ppm, respectively, which is typical for taiga landscapes. At the same time, the geochemical fate of Fe and Mn is different in coastal soils, probably partly due to the participation of Fe in mineral transitions from sulfides to sulfates. Such microelements as Ni and Cr are present in the soils in concentrations comparable to the background concentrations in the regional zonal soils. Only As and Se may be potentially toxic, if tombolo is used as a hayfield.

摘要海滨土壤在土著径流和海水冲击的接触面上发挥作用,这提供了一个独特的地球化学环境。硫化铁的形成和氧化可部分促进元素的迁移和积累。我们研究了白海波莫尔海岸沼泽土壤中铁、锰和微量元素的含量和空间分布。这项工作是在卡累利阿共和国别洛莫尔斯克区科莱日马村附近进行的。研究发现,这些土壤中的微量元素(如砷和硒)浓度较高,而这通常与海洋沉积物中的金属硫化物有关。铁和锰的含量也很高,分别高达 27 300ppm 和 1500ppm,这是典型的针叶林地貌。同时,沿岸土壤中铁和锰的地球化学归宿不同,部分原因可能是铁参与了从硫化物到硫酸盐的矿物转化。镍和铬等微量元素在土壤中的浓度与区域地带性土壤中的背景浓度相当。如果墓坡被用作干草场,只有砷和硒可能具有潜在毒性。
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引用次数: 0
Effect of Long-Term Use of Nitrogen, Phosphorus, and Potassium Fertilizers on the Contents of Phosphorus Compounds in Soddy-Podzolic Soil of the Urals 长期施用氮肥、磷肥和钾肥对乌拉尔水稻田土壤中磷化合物含量的影响
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-22 DOI: 10.1134/s1064229324600714
M. T. Vasbieva, N. E. Zavyalova, D. G. Shishkov

Abstract

The effect of long-term use of mineral fertilizers on changes in the content of total phosphorus and its organic, mineral, and mobile compounds in soddy-podzolic heavy loamy soil (Albiс Retisol (Abruptic, Aric, Loamic)) was analyzed. The studies were performed in a long-term stationary experiment initiated in Perm krai in 1978. The variants were: 0 (without fertilizers), N90, P90, K90, N90P90, N90K90, P90K90, N90P90K90, N30P30K30, N60P60K60, N120P120K120, and N150P150K150. Ammonium nitrate or urea, double or simple superphosphate, and potassium chloride were used in the experiment. It was established that long-term use of superphosphate during five eight-field crop rotations (P90, P90K90, N90P90, and N90P90K90) resulted in a significant increase in the contents of the total phosphorus, mineral phosphorus (by 1.3–1.8 times), and mobile phosphorus (by 1.9–2.7 times) compounds in the plow layer (0–20 cm). The use of nitrogen fertilizers (N90, N90K90, N90Р90, and N90Р90K90) affected the accumulation of organic phosphorus compounds in the soil. The increase in the content and reserves of both mineral and organic phosphorus compounds was significant only in the case of using complete mineral fertilizer N90P90K90. Different combinations of superphosphate with nitrogen fertilizers and potassium chloride, as well as the rate of fertilizer application, affected the accumulation intensity of mobile phosphorus compounds in the soil during rotations and the changes in their contents in the soil profile. The application of low fertilizer rates ((NPK)30–60) resulted in an increase in the content of mobile phosphorus compounds mainly in the plow layer, whereas higher rates ((NPK)90–150) caused changes in the 80-cm-thick soil layer. Long-term use of nitrogen and potassium fertilizers resulted in an increase in the content of mobile phosphorus compounds in the plow layer over time.

摘要 分析了长期使用矿物肥料对草皮-块状重壤土(Albiс Retisol (Abruptic, Aric, Loamic))中总磷及其有机、矿物和流动化合物含量变化的影响。研究是在 1978 年在彼尔姆边疆区启动的长期固定试验中进行的。实验变量为0(不施肥)、N90、P90、K90、N90P90、N90K90、P90K90、N90P90K90、N30P30K30、N60P60K60、N120P120K120 和 N150P150K150。实验中使用了硝酸铵或尿素、过磷酸钙或单质过磷酸钙以及氯化钾。实验结果表明,在五次八田轮作(P90、P90K90、N90P90 和 N90P90K90)中长期施用过磷酸钙可显著增加犁层(0-20 厘米)中的总磷、矿物磷(增加 1.3-1.8 倍)和移动磷(增加 1.9-2.7 倍)化合物的含量。氮肥(N90、N90K90、N90Р90 和 N90Р90K90)的使用影响了土壤中有机磷化合物的积累。只有在使用完全矿物肥料 N90P90K90 的情况下,矿物磷和有机磷化合物的含量和储量才会显著增加。过磷酸钙与氮肥和氯化钾的不同组合以及施肥量,影响了轮作期间土壤中移动磷化合物的积累强度及其在土壤剖面中含量的变化。低施肥量((NPK)30-60)导致流动磷化合物含量增加,主要集中在耕层,而高施肥量((NPK)90-150)则导致 80 厘米厚的土层发生变化。长期施用氮肥和钾肥会导致犁耕层中的移动磷化合物含量随时间推移而增加。
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引用次数: 0
Identification of Surface-Carbonate Soils and Soils with Variegated Underlying Rocks in the South of Volga Upland on Satellite Images 通过卫星图像识别伏尔加河南岸高地的表层碳酸盐土壤和底岩多变的土壤
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-22 DOI: 10.1134/s1064229324600763
I. N. Gorokhova, N. B. Khitrov, L. A. Tarnopolsky

Abstract

The aim of this work is to reveal correlation between the spectral characteristics of the open soil surface on the Pleiades image (April 25, 2020) and soils of a key site with a complex soil cover pattern in the south of the Volga Upland (Volga–Don irrigation system, Volgograd oblast). The study area is specified by the lithological heterogeneity: Paleogene and Neogene sands and loams are overlain by a mantle of Quaternary brown loams of variable thickness from 1–2 m to complete thinning out. The soil cover is represented by light chestnut solonetzic complexes complicated by a mosaic of lithological variants and erosion–accumulative combinations. Eight soil groups have been specified, and a map of their distribution has been developed for the key site of 343 ha with the use of digital methods of processing the spectral characteristics of the satellite image and ground-based soil information. Soil groups differ in general features of the soil surface due to differences in the contents of gravel and stones, texture of the surface horizon (from sand to silt loam), occurrence of brightened crusts, and surface effervescence depending on the thickness of the upper lithological layer. Soils with different horizonation of the profile—agrochestnut soils, agrozems, and agrosolonetzes—fall within the same groups of surface spectral characteristics; vice versa, soils of the same genetic type and, sometimes, subtype fall into different groups. This is explained by the incomplete correspondence of the properties of the soil surface affecting the spectral characteristics to the internal structure of the soil profile as a whole.

摘要 这项工作的目的是揭示昴星团图像(2020 年 4 月 25 日)上开阔土壤表面的光谱特征与伏尔加河高原南部(伏尔加河-顿河灌溉系统,伏尔加格勒州)一个具有复杂土壤覆盖模式的关键地点的土壤之间的相关性。该研究区域因岩性异质性而得名:古近纪和新近纪砂土和壤土被第四纪棕色壤土覆盖,壤土厚度从 1-2 米到完全变薄不等。土壤覆盖层由浅栗色壤土复合体构成,岩性变异和侵蚀累积组合错综复杂。利用处理卫星图像光谱特征的数字方法和地面土壤信息,为 343 公顷的关键地点绘制了土壤分布图。由于砾石和石块的含量、地表地层的质地(从砂土到淤泥质壤土)、光化结壳的出现以及地表澎湃(取决于上层岩性层的厚度)等方面的差异,土壤组别在土壤表面的总体特征上有所不同。具有不同地层剖面的土壤--农栗树土、农泽土和农壤土--属于相同的地表光谱特征组;反之,具有相同基因类型的土壤,有时是亚类型的土壤,则属于不同的组。这是因为影响光谱特征的土壤表层特性与整个土壤剖面的内部结构不完全对应。
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引用次数: 0
Evaluation of Regional-Scale Soil Organic Carbon Dynamics in Southeastern Siberia Inferred from Stable Carbon Isotopic Values (δ13C) 从稳定碳同位素值(δ13C)推断西伯利亚东南部地区土壤有机碳动态评估
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-22 DOI: 10.1134/s1064229324600775
V. A. Golubtsov, A. A. Cherkashina, Yu. V. Vanteeva, S. M. Turchinskaya

Abstract

The spatial and intraprofile variations of soil δ13C values are assessed along with the corresponding environmental and edaphic factors in the Baikal region, a vast territory in the south of Eastern Siberia, which is highly heterogeneous in terms of physiographic conditions. The studied sites are located in the altitudinal range of 403–2315 m a.s.l., which defines a strong landscape and climatic gradient comprising mountainous tundra, subalpine grasslands, mountainous taiga, subtaiga, and steppe landscapes. The soil organic matter there considerably varies in the 13C/12C isotopic ratio corresponding to δ13C values characteristic of the plants with C3 photosynthesis. The δ13C values in topsoil organic matter vary from –29.50 to –22.98‰. The changes in δ13C values in the altitudinal profile correlate well with the changes in landscapes. The highest δ13C values are characteristic of the soils in mountainous tundra and steppe landscapes. Organic matter of taiga soils is depleted in 13C. A lower carbon turnover rate is observed in the steppe and mountainous tundra soils, which is explained by limited moisture and heat supply, respectively. The soils formed in taiga landscapes with their more favorable balance of temperatures and precipitation display a more intensive carbon turnover (β). The β values in forest soils correlate with the changes in pH, C and N contents, and the variations in C/N ratio in soil organic matter, thereby suggesting a considerable effect of the plant litter quality and microbiological activity on the carbon turnover in the regional soils formed under more favorable climatic conditions.

摘要 在东西伯利亚南部幅员辽阔、地貌条件差异极大的贝加尔湖地区,对土壤δ13C 值的空间和剖面内变化以及相应的环境和气候因素进行了评估。所研究的地点位于海拔 403-2315 米的范围内,这就形成了强烈的地貌和气候梯度,包括山地苔原、亚高山草原、山地泰加林、亚泰加林和草原地貌。那里的土壤有机质在 13C/12C 同位素比值上存在很大差异,这与具有 C3 光合作用的植物所特有的 δ13C 值相对应。表土有机质中的δ13C 值从 -29.50 到 -22.98‰不等。δ13C值在海拔剖面上的变化与地貌的变化密切相关。δ13C值最高的是山地苔原和草原地貌的土壤。针叶林土壤的有机质 13C 含量较低。草原和山地冻原土壤的碳周转率较低,这分别是由于水分和热量供应有限造成的。泰加地貌形成的土壤具有更有利的温度和降水平衡,因此碳转化率(β)更高。森林土壤的 β 值与 pH 值、C 和 N 含量的变化以及土壤有机质中 C/N 比值的变化相关,这表明在气候条件较好的地区形成的土壤中,植物凋落物的质量和微生物活动对碳周转有很大影响。
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引用次数: 0
Chronical Soil Pollution with Chromium in the Tanneries Area: a Case Study in Damascus, Syria 制革厂地区长期的土壤铬污染:叙利亚大马士革的案例研究
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-10 DOI: 10.1134/s1064229324600465
R. Al-Khoury, A. A. K. Jaafar, S. Salim, S. Mandzhieva, A. Barakhov, L. Perelomov, V. D. Rajput

Abstract

The present work was conducted to evaluate the chromium contamination and its relationship with soil components of the Eastern Ghouta of Damascus, Syria. Various areas were chosen in the terms of chromium content analysis. Soil samples were collected from these areas to a depth of 60 cm from the three layers, at intervals of 20 cm. The results showed that the levels of total and CrVI were within the normal limits in Al-Maamouniye (uncontaminated with chromium), Jobar (agricultural land), and Ein Tarma (agricultural land). While it exceeded the maximum permissible limit (MPL) as per FAO and WHO on the area of Tanneries (Dabagat). The soil content of CrIII (536.99, 474.34, 415.77 mg kg–1) and CrVI (0.12, 0.51, 0.75 mg kg–1) were determined in the layers of 0–20, 20–40, 40–60 cm, respectively. The results also showed that 80% of chromium was associated with organic matter in the soil of Al-Dabagat region. In contrast, approximately 85% of chromium was available in the remaining part of the Mamounia soil. It was noted the content of chromium, which is associated with iron and manganese oxides, were high. Although chromium was exchangeable and bounded to CaCO3, however, its quantity was negligible. The results showed that the concentration of CrVI increased with depth at all the selected areas, in contrast to CrIII which decreased with the depth of soils.

摘要 本研究旨在评估叙利亚大马士革东姑塔地区的铬污染及其与土壤成分的关系。从铬含量分析的角度选择了多个地区。从这些地区采集了三层 60 厘米深的土壤样本,每层间隔 20 厘米。结果显示,Al-Maamouniye(未受铬污染)、Jobar(农田)和 Ein Tarma(农田)的总铬含量和六价铬含量均在正常范围内。而在制革厂(达巴加特)地区,则超过了联合国粮农组织和世界卫生组织规定的最大允许限值 (MPL)。在 0-20 厘米、20-40 厘米、40-60 厘米的土层中分别测定了 CrIII(536.99、474.34、415.77 毫克/千克-1)和 CrVI(0.12、0.51、0.75 毫克/千克-1)的含量。结果还显示,在 Al-Dabagat 地区的土壤中,80% 的铬与有机物有关。相比之下,在马穆尼亚土壤的其余部分,约有 85% 的铬存在。人们注意到,与铁和锰氧化物相关的铬含量很高。虽然铬是可交换的,并与 CaCO3 结合在一起,但其数量微乎其微。结果表明,在所有选定地区,铬六的浓度随着土壤深度的增加而增加,而铬三则随着土壤深度的增加而减少。
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引用次数: 0
Thresholds of Soil Moisture on the Temperature Response of Soil Respiration in Semiarid High-Altitude Grassland in Northwestern China 中国西北半干旱高海拔草地土壤湿度对土壤呼吸作用温度响应的阈值
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-10 DOI: 10.1134/s1064229324600143
Zhimin Zhao, Fengxia Shi

Abstract

Although soil temperature (Ts) is generally considered as the primarily factor influencing soil respiration (Rs), the correlation between soil respiration and soil temperature is often affected by soil moisture (Ms). In this study, we analyzed the correlation between Rs and Ts under different soil moisture condition in semiarid high-altitude grassland in northwestern China. The results showed that (1) when the values of Ms were higher than the field capacity (FC), Rs were mainly controlled by Ms. (2) FC was also an important threshold to affect the selection of RsTs model and the determination of temperature sensitivity (Q10). Our findings highlight that Rs is significantly influenced by Ms in a threshold manner, and FC is an important moisture threshold for Rs and its temperature response in high altitude semiarid ecosystems.We suggested that the effect of Ms on Rs cannot be neglected in high altitude semiarid ecosystems.

摘要 虽然土壤温度(Ts)通常被认为是影响土壤呼吸作用(Rs)的主要因素,但土壤呼吸作用与土壤温度之间的相关性往往受到土壤水分(Ms)的影响。本研究分析了中国西北半干旱高海拔草地不同土壤水分条件下 Rs 与 Ts 的相关性。结果表明:(1)当 Ms 值高于田间容纳量(FC)时,Rs 主要受 Ms 控制;(2)FC 也是影响 Rs-Ts 模型选择和温度敏感性(Q10)确定的重要临界值。我们的研究结果表明,在高海拔半干旱生态系统中,Rs受Ms的影响很大,而FC是Rs及其温度响应的重要水分阈值。
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引用次数: 0
Evaluation of Snowmelt and Rainfall Erosion in the Total Soil Losses in a Typical Small Watershed in Black Soil Region of Northeast China 东北黑土区典型小流域融雪和降雨侵蚀对土壤总流失的影响评价
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-10 DOI: 10.1134/s1064229324600477
Zhongzheng Ren, Wei Hu, Yuan Chen, Guihui Ding, Xu Fan, Xingyi Zhang

Abstract

Snowmelt erosion and rainfall erosion are important components of soil erosion in Northeast China. Studying how snowmelt and rainfall affect runoff and sediment yield is essential to control soil erosion in this region. Based on the soil and water loss observation data in small watershed during snowmelt and rainfall periods, snowmelt and rainfall erosion processes were studied. The runoff–sediment relationship was analyzed. The results indicate that 13 snowmelt runoff events and 14 rainfall runoff events were recorded. During the snowmelt period, runoff depth (RD) and sediment yield (SY) exhibited a slow increase (early stage), rapid increase (middle stage), and then rapid decrease (late stage) trend. RD and SY in the middle stage were higher than those in the early and late stages. Moreover, during the rainfall period, soil erosion mainly occurred from July to August; during these two months, the rainfall and rainfall erosivity accounted for 66.0 and 91.1% of the total rainfall and rainfall erosivity, respectively; and the RD and SY in this period accounted for 88.4 and 89.8% of total amounts in the whole rainfall period, respectively. In addition, the contributions of snowmelt and rainfall to RD and SY were 18.6 and 81.4%, and 3.8 and 96.2%, respectively. Hysteresis analysis suggested that clockwise hysteresis loop was the dominant pattern, followed by eight-shaped anticlockwise loop, and complex anticlockwise loop.

摘要融雪侵蚀和降雨侵蚀是中国东北地区水土流失的重要组成部分。研究融雪和降雨对径流和泥沙量的影响对控制该地区的水土流失至关重要。基于融雪期和降雨期小流域水土流失观测资料,研究了融雪和降雨侵蚀过程。分析了径流与沉积物的关系。结果表明,共记录了 13 次融雪径流事件和 14 次降雨径流事件。在融雪期,径流深度(RD)和泥沙产量(SY)呈现出缓慢增加(早期)、快速增加(中期)和快速减少(晚期)的趋势。中期的 RD 和 SY 均高于早期和后期。此外,在降雨期,水土流失主要发生在 7 月至 8 月,这两个月的降雨量和降雨侵蚀量分别占总降雨量和总降雨侵蚀量的 66.0% 和 91.1%,这一时期的 RD 和 SY 分别占整个降雨期总量的 88.4% 和 89.8%。此外,融雪和降雨对 RD 和 SY 的贡献率分别为 18.6% 和 81.4%,以及 3.8% 和 96.2%。滞回分析表明,顺时针滞回是主要模式,其次是八形逆时针滞回和复合逆时针滞回。
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引用次数: 0
Effect of Soil Buffer Capacity on the Transformation of Lead and Cadmium Compounds 土壤缓冲能力对铅和镉化合物转化的影响
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-08 DOI: 10.1134/s1064229324600441
M. V. Burachevskaya, T. M. Minkina, S. S. Mandzhieva, T. V. Bauer, M. V. Kirichkov, D. G. Nevidomskaya, I. V. Zamulina

Abstract—

The aim of this work is to study the transformation of priority pollutants compounds, i.e., of Pb and Cd in soils with different buffer capacity and pollution level. The object of study is southern chernozem (Haplic Chernozem), calcareous, heavy loamy, collected in a virgin site in the Rostov-on-Don region, the layer 0–20 cm. Lead and Cd nitrates were added separately in doses of 2, 5, 10 approximately permissible concentration (APC) of metal (130 mg/kg for Pb and 2 mg/kg for Cd) into soil samples of the model experiment containing quartz sand in the ratios 1 : 0.25, 1 : 0.5, 1 : 0.75 of the soil mass. The buffer capacity of soils in relation to Pb and Cd was assessed according to the method of V.B. Il’in (1995), based on the content of physical clay, organic matter, carbonates, R2O3, and pH. The ability of soils to firmly bind Pb and Cd was studied proceeding from the results of fractional group composition of metals using a combined fractionation scheme. In unpolluted heavy loamy Haplic Chernozem, the buffer capacity of soils in relation to Pb and Cd is high and is ensured by strong retention of metals by silicates and clay minerals (50–64% of the total fractions). Dilution of the initial soil with quartz sand reduces its buffer capacity from high to medium and low. When soil is contaminated, organic matter plays the most active role in the interaction with Pb; and Fe–Mn oxides are most important in the case of Cd. With a decrease in soil buffer capacity and growing pollution, the group of loosely bound compounds increases by 6–54%, mainly due to complex compounds in the case of Pb, and due to exchangeable and specifically sorbed by Fe–Mn oxides in the case of Cd. At the application dose of 10 APC Pb, the soil buffer capacity changes from low to very low. The data obtained are important for predicting and normalizing pollution of soils with different physicochemical properties.

摘要--这项工作的目的是研究重点污染物化合物(即铅和镉)在缓冲能力和污染程度不同的土壤中的转化情况。研究对象是南切尔诺泽姆(Haplic Chernozem),石灰质,重壤土,采集于顿河边罗斯托夫地区的一个原始地点,土层 0-20 厘米。在含有石英砂的模型实验土壤样本中,分别按照 1 : 0.25、1 : 0.5、1 : 0.75 的土壤质量比例添加了 2、5、10 个剂量的铅和镉硝酸盐,约为金属的允许浓度(APC)(铅为 130 毫克/千克,镉为 2 毫克/千克)。按照 V.B. Il'in(1995 年)的方法,根据物理粘土、有机物、碳酸盐、R2O3 和 pH 值的含量,评估了土壤对铅和镉的缓冲能力。土壤牢固结合铅和镉的能力是根据使用组合分馏方案得出的金属组分组成结果进行研究的。在未受污染的重壤土 Haplic Chernozem 中,土壤对铅和镉的缓冲能力很强,硅酸盐和粘土矿物对金属的强力截留(占总馏分的 50-64%)确保了这一点。用石英砂稀释初始土壤会使其缓冲能力从高降至中低。当土壤受到污染时,有机物在与铅的相互作用中起着最积极的作用;而铁锰氧化物在与镉的相互作用中起着最重要的作用。随着土壤缓冲能力的下降和污染的加剧,松散结合的化合物群增加了 6-54%,主要是由于铅的复杂化合物,以及镉的可交换性和铁锰氧化物的特异性吸附。当施用剂量为 10 APC Pb 时,土壤缓冲能力从低变为极低。所获得的数据对于预测不同理化性质土壤的污染情况并使之正常化非常重要。
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引用次数: 0
Use of δ13С Variations in Organic Matter of Paleosols of Western Transbaikalia for Reconstruction of Paleoprecipitation Dynamics in the Late Glacial and Holocene 利用外贝加尔西部古溶胶有机物中的δ13С变化重建晚冰期和全新世的古沉淀动力学
IF 1.4 4区 农林科学 Q4 SOIL SCIENCE Pub Date : 2024-07-08 DOI: 10.1134/s1064229324600374
V. A. Golubtsov, Yu. V. Ryzhov, A. A. Cherkashina

Abstract

Analysis of the stable carbon isotopic composition (δ13C) of soil organic matter is important for assessing past climate changes and the response of landscape components to them. Soils of nine soil-sedimentary sequences formed in various landscape and geomorphological conditions of western Transbaikalia have been studied. The time of their formation covers the last 15 kyr. The phases of pedogenesis within genetically different landforms were rather synchronous, which enabled us to suppose that they were caused by regional landscape-climatic changes, which also affected δ13C of soil organic matter. The range of variations in δ13С values is from –20.99 to –27.00‰. Changes in δ13С over time are the most contrasting for sections formed under driest steppe conditions and are the smallest for sections in taiga landscapes with the greatest precipitation. However, in general, the trends of changes in δ13С in different landscape zones over time are similar: the lowest δ13С values are typical for organic matter of Late Glacial paleosols formed 14–15 and 12 kyr BP, as well as for soils of the Late Holocene (3.5–2.0 and 1.0–0.3 kyr BP). Organic matter of soils of the Middle Holocene (9.0–4.0 kyr BP) and of the time interval of 13–14 kyr BP is enriched in 13C. Based on the identified dependence of δ13C in organic matter of modern soils in the region on the amount of precipitation, we have quantitatively reconstructed precipitation during the past growing seasons. The data obtained enable us to estimate the time intervals of 11.7–10.0 and 4.0–1.5 kyr BP as the most optimal for the formation of soils in Western Transbaikalia. An increase in temperatures and a decrease in atmospheric humidity in Transbaikalia and adjacent areas in the Middle Holocene exerted a negative impact on the pedogenesis intensity.

摘要 分析土壤有机质的稳定碳同位素组成(δ13C)对于评估过去的气候变化以及地貌成分对气候变化的反应非常重要。研究了在外贝加尔西部不同地貌和地形条件下形成的九个土壤沉积序列的土壤。这些土壤的形成时间涵盖过去 15 千年。在基因不同的地貌中,各阶段的成土过程相当同步,这使我们能够推测它们是由区域地貌-气候的变化引起的,这些变化也影响了土壤有机质的δ13C。δ13С值的变化范围从-20.99‰到-27.00‰。在最干旱的草原条件下形成的地段,δ13С随时间的变化反差最大,而在降水量最大的泰加地貌中形成的地段,δ13С随时间的变化最小。不过,总体而言,不同地貌区的δ13С随时间变化的趋势是相似的:形成于公元前 14-15 千年和 12 千年的晚冰期古溶胶以及全新世晚期(公元前 3.5-2.0 千年和 1.0-0.3 千年)土壤的有机质的δ13С值最低。全新世中期(公元前 9.0-4.0 千年)和公元前 13-14 千年的土壤有机质富含 13C。根据已确定的该地区现代土壤有机物质中的δ13C 与降水量的关系,我们对过去生长季节的降水量进行了定量重建。根据所获得的数据,我们可以估计出 11.7-10.0 和 4.0-1.5 千年前是外贝加尔西部土壤形成的最佳时间间隔。在全新世中期,外贝加尔及邻近地区气温升高,大气湿度降低,这对成土强度产生了负面影响。
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引用次数: 0
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Eurasian Soil Science
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