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Sensitivity of Heat of Reaction for Polyurethane Foams 聚氨酯泡沫的反应热敏感性
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-179
D. Pau, C. Fleischmann, M. Spearpoint, K. Li
The heat of reaction for the decomposition of polyurethane foam and its melt are determined from the heat flow measurements obtained through simultaneous differential scanning calorimetry and thermogravimetric analysis. Under nitrogen environment, the decomposition of foam experiences two endothermic pyrolysis reactions based on the experimental results. Through the investigation on the sensitivity of heat of reaction to heating rate and sample mass, a region where the heat of reaction remains constant is found for the melt samples tested. This consistent region includes heating rate from 5 to 20 °C/min and sample mass between ~20 and ~50 mg. No consistent region is found for the foam samples because of the reduced accuracy in the heat flow measured. For the foams and melts tested, the consistent heat of reaction for the second reaction ranges from endothermic 164 ‐ 295 J/g while the recommended heat of reaction for the first reaction ranges from endothermic 610 ‐ 1023 J/g.
通过差示扫描量热法和热重法同时测定的热流数据,确定了聚氨酯泡沫及其熔体分解的反应热。根据实验结果,在氮气环境下,泡沫的分解经历了两次吸热热解反应。通过对反应热对加热速率和试样质量的敏感性的研究,找到了熔体试样反应热保持恒定的区域。这一一致区域包括升温速率为5 ~20°C/min,样品质量为~20 ~ ~50 mg。由于测量的热流精度降低,泡沫样品没有发现一致的区域。对于测试的泡沫和熔体,第二反应的一致反应热范围为吸热164‐295 J/g,而第一反应的推荐反应热范围为吸热610‐1023 J/g。
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引用次数: 11
Impact of solid fuel particle size upon the propagation of a surface fire through a homogeneous vegetation layer 固体燃料颗粒大小对地表火灾通过均匀植被层传播的影响
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1326
D. Morvan, A. Lamorlette
The aim of this paper is to investigate the role played by the size (thickness) of solid fuel particles upon both the heat transfer and the propagation of a surface fire through a homogeneous vegetation layer. Because all the interactions (mass, momentum, and heat transfer) between the solid fuel layer and the gas phase occur at the interface between these two media, the surface area to volume (SA/V) ratio (inversely proportional to the thickness of the solid fuel particles), which appears in the expression of the specific surface separating these two phases, must affect, more or less significantly, the fire dynamics. This problem has been studied numerically, using a multiphase formulation. Various variables, such as the temperature of the solid fuel, the temperature of the gas, the fire residence time and the heat flux by radiation and convection have been analyzed, in order to understand the role played by the SA/V upon the behaviour of the fire.
本文的目的是研究固体燃料颗粒的大小(厚度)对热传递和表面火灾在均匀植被层中的传播所起的作用。由于固体燃料层和气相之间的所有相互作用(质量、动量和热传递)都发生在这两种介质之间的界面上,因此在分离这两相的比表面的表达式中出现的表面积体积比(SA/V)(与固体燃料颗粒的厚度成反比)必然或多或少地影响着火灾动力学。用多相公式对这一问题进行了数值研究。分析了固体燃料的温度、气体的温度、火焰停留时间以及辐射和对流的热通量等各种变量,以了解SA/V对火灾行为的作用。
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引用次数: 5
Electrical Receptacles - Overheating, Arcing, and Melting 插座。过热、电弧和熔化
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1010
M. Benfer, D. Gottuk
This study was designed to experimentally characterize factors that can cause electrical failures (i.e., overheating connections), to assess the damage and potential forensic signatures of these failures, and to characterize the similarities and differences between arcing and melting in receptacle components and wiring. Laboratory testing evaluated the impact of a wide range of variables on the formation of overheating connections in residential duplex receptacles including screw terminal torque, wiring method (back-wired, or side-wired), and primary receptacle materials. A total of 408 trials of receptacles with various terminal connections were tested in the laboratory setting; receptacles were powered for up to 16 months. A small portion of receptacles with loose connections overheated to the point of failure of the receptacle; some including flaming events. Failure events occurred between 5 and 365 days after tests were started. Four hundred and sixty eight (468) receptacles were placed in compartment fire tests and furnace fire tests. These tests were designed to evaluate the persistence after fire exposure of overheating/arcing evidence from failure events (i.e., from potential fire cause events). The fire exposure tests also served to analyze the characteristic traits of arcing and melting damage. The results indicated that only very loose connections (less than 0.339 N-m [3 in-lb]) at moderately high currents (9A or higher) tend to form significant overheating connections and receptacle failures, irrespective of other variables such as receptacle materials and installation. Characteristic indicators of overheating and glowing terminal connections were identified and were found to persist after fire exposure.
本研究旨在通过实验表征可能导致电气故障的因素(即过热连接),评估这些故障的损坏和潜在的法医特征,并表征插座组件和布线中电弧和熔化之间的异同。实验室测试评估了一系列变量对住宅复式插座中过热连接形成的影响,包括螺旋端子扭矩、接线方法(背接线或侧接线)和主插座材料。在实验室环境中,共有408个不同端子连接的插座试验进行了测试;插座的供电时间长达16个月。一小部分连接松动的插座过热到插座失效点;其中一些包括燃烧事件。故障事件发生在测试启动后的5天到365天之间。468个容器被放置在隔间防火试验和熔炉防火试验中。这些测试旨在评估故障事件(即潜在的火灾原因事件)引起的过热/电弧证据在火灾暴露后的持久性。火灾暴露试验也用于分析电弧和熔化损伤的特征特征。结果表明,在中等高电流(9A或更高)下,只有非常松散的连接(小于0.339 N-m [3 in-lb])才容易形成明显的过热连接和插座故障,而与插座材料和安装等其他变量无关。确定了过热和发光端子连接的特征指标,并发现在火灾暴露后持续存在。
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引用次数: 5
Experimental approach to estimate species concentrations in a compartment fire 估计隔间火灾中物种浓度的实验方法
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-346
J. Lassus, L. Courty, E. Studer, J. Garo, P. Aîne
An approach for estimating species concentration during a fire in a well-stirred compartment is investigated. A semi-empirical model based on oxygen concentration is used. It gives an estimate of the concentrations of carbon monoxide, carbon dioxide, hydrogen and hydrocarbons with a carbon chain length lower than five. Three intervals of oxygen concentration are noticed, they correspond to sufficiently ventilated, underventilated and very underventilated fires. In order to validate this model, fire experiments are performed in a reduced-scale compartment . Species concentrations predicted by the model are in good agreement with our experimental data and with those of literature. Coefficients used for the model are obtained for heptane and dodecane fires.
研究了一种在搅拌均匀的隔间内进行火灾时估算物质浓度的方法。采用了基于氧浓度的半经验模型。它给出了一氧化碳、二氧化碳、氢和碳链长度小于5的碳氢化合物的浓度估计。注意到三个氧气浓度间隔,它们对应于充分通风,不通风和非常不通风的火灾。为了验证该模型,在缩小尺寸的隔间中进行了火灾实验。该模型预测的物种浓度与实验数据和文献数据吻合较好。模型中使用的系数是由庚烷和十二烷燃烧得到的。
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引用次数: 2
Parametric Analysis of Heat Transfer in Gypsum Wallboard Partitions 石膏墙板隔墙传热参数分析
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-598
M. Bruns, K. Prasad
One-dimensional heat transfer in gypsum wallboard partitions is studied using sensitivity analysis and calibration by error minimization. Analysis of an existing heat and mass transfer model indicates that mass transfer and condensation of water vapor are not of primary importance in predicting board temperatures. A computationally efficient and robust heat transfer model is developed for predicting temperatures in gypsum wallboard partitions. Kinetic parameters are calibrated by error minimization with respect to literature thermogravimetric analysis (TGA) data. Additional thermophysical parameters are calibrated by error minimization with respect to literature ASTM E119 furnace test data. It is found that the calibrated heat transfer model is capable of predicting board temperatures given large thermal conductivities and specific heats at high temperatures. It is hypothesized that these observations imply the need to account for porous media radiation, temperature varying specific heats, and calcium carbonate decomposition in future models. Local sensitivity analysis reveals that board temperatures are most sensitive to initial density, thermal conductivity at moderately high temperatures ( 800 C), and the activation energy of the dehydration reactions. Conversely, model predictions are relatively insensitive to dehydration reaction pre-exponentials and low-temperature heat capacities.
采用灵敏度分析和误差最小化校正方法研究了石膏墙板隔板的一维传热。对现有的传热传质模型的分析表明,在预测板温度时,传质和水蒸气的冷凝并不是最重要的。建立了一种计算效率高、鲁棒性强的石膏墙板隔墙温度预测模型。动力学参数是通过误差最小化校准相对文献热重分析(TGA)数据。额外的热物理参数根据文献ASTM E119炉测试数据通过误差最小化进行校准。校正后的传热模型能够在较大导热系数和高温比热条件下预测板的温度。据推测,这些观测结果意味着在未来的模型中需要考虑多孔介质辐射、温度变化比热和碳酸钙分解。局部敏感性分析表明,板料温度对初始密度、中高温(800℃)下的导热系数和脱水反应的活化能最为敏感。相反,模型预测对脱水反应前指数和低温热容相对不敏感。
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引用次数: 3
Fire development in different scales of train carriages 不同规模火车车厢的火灾发展
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-302
Ying Zhen Li, H. Ingason, Anders Lönnermark
A fire development analysis of three series of train carriage fire tests in different scales was carried out. These train carriage fire tests included 1:10 model scale tests, 1:3 model scale tests and 1:1 full scale tunnel tests. The heat release rate (HRR) correlations between different scales of carriage fire tests were carefully investigated. The mechanism of fire development is very similar in different scales of tests involving fully developed fires. After the critical fire spread, the fire travelled along the carriage at an approximately constant speed. The maximum heat release rate obtained for a fully developed fire is dependent on the ventilation conditions and also the type and configuration of the fuels, and a simple equation has been proposed to estimate the maximum heat release rate. A global correction factor of the maximum heat release rate is presented and examined.
对三个系列不同规模的火车车厢火灾试验进行了火灾发展分析。这些火车车厢火灾试验包括1:10模型比例试验、1:3模型比例试验和1:1全尺寸隧道试验。仔细研究了不同尺度车厢燃烧试验的放热率(HRR)相关性。在涉及完全发展的火灾的不同规模的试验中,火灾发展的机制非常相似。在临界火势蔓延后,火势以大约恒定的速度沿着车厢蔓延。充分发展的火灾的最大放热率取决于通风条件以及燃料的类型和配置,并提出了一个简单的公式来估计最大放热率。提出并检验了最大放热率的全局校正因子。
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引用次数: 35
Correlations for Evaluation of Flame Spread over an Inclined Fuel Surface 倾斜燃料表面火焰扩散评价的相关系数
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-222
Xinyan Huang, M. Gollner
The time-dependent flame spread process over thermally thick slabs of polymethyl methacrylate (PMMA) is investigated with particular emphasis on the burning behavior and geometry of the flame. 10 cm wide by 20 cm long samples are ignited and allowed to spread upwards at angles of orientation between pool and ceiling burning. Correlations between the flame length and the fuel mass-loss rate have revealed a delayed transition to turbulence for flames residing on the underside of fuel samples, and an earlier transition to turbulence for flames on the topside of these samples, compared to traditional vertical wall flames. As the fuel inclination increases, the relationship between the flame length and fuel mass-loss rate ranges between a recent theoretical prediction for a laminar wall plume dominated by diffusion and the traditional prediction for a turbulent wall plume dominated by convective mixing. The buoyancy-induced flow field, characterized by the flame tilt angle is shown to correspond to previously-found modifications of heat-flux profiles ahead of the flame front, which control flame spread, and the heat flux to the burning surface of the fuel, which controls fuel mass-loss rates. Other correlations between some of these parameters, such as the flame and pyrolysis lengths are also presented as a function of inclination.
在热厚的聚甲基丙烯酸甲酯(PMMA)板上研究了随时间变化的火焰传播过程,特别强调了火焰的燃烧行为和几何形状。点燃10厘米宽,20厘米长的样品,并允许在池和天花板燃烧之间的方向角向上扩散。火焰长度与燃料质量损失率之间的相关性表明,与传统的垂直壁火焰相比,位于燃料样品底面的火焰向湍流的过渡延迟,而这些样品顶部的火焰向湍流的过渡提前。随着燃料倾斜度的增大,火焰长度与燃料质量损失率之间的关系介于以扩散为主的层流壁羽和以对流混合为主的湍流壁羽之间。以火焰倾斜角度为特征的浮力诱导流场与先前发现的火焰锋面前的热流密度曲线的变化相对应,前者控制火焰的蔓延,后者控制燃料燃烧表面的热流密度,后者控制燃料的质量损失率。其中一些参数(如火焰和热解长度)之间的其他相关性也被表示为倾角的函数。
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引用次数: 35
Effects of Sample Width and Sidewalls on Downward Flame Spread over XPS Slabs 试样宽度和侧壁对XPS板火焰向下蔓延的影响
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-234
W. An, H. Xiao, Jinhua Sun, K. Liew, W. Yan, Y. Zhou, L. Jiang, X. Huang
To study the effects of sample width and sidewalls on downward flame spread over extruded polystyrene (XPS) slabs, a series of laboratory-scale experiments were conducted. Flame shape, flame spread rate, mass loss rate and temperature were recorded. For XPS without sidewalls, the average maximum flame height (H) and average flame area per unit of width (A/w) rise linearly with an increase in sample width (w) and mass loss rate per unit of width. When sidewalls are absent, flame spread rate first drops and then rises with an increase in width. This trend is determined by gas-phase heat transfer. When sidewalls are present, flame spread rate increases with a rise in width, and solid-phase heat conduction determines the trend. Sidewall effects are comprised of four aspects: oxygen concentration near the sidewalls and gypsum board is low, which leads to reduced flame heat flux; upward and front air flow is intensified; the flame is stretched, and the surface flame is weakened; and molten XPS mass decreases. For narrow samples, H and A/w with sidewalls are higher than those without sidewalls, while the reverse was observed in wider samples. The mass loss rate, preheating length and average flame spread rate with sidewalls are smaller than those obtained without sidewalls. Flame spread acceleration with sidewalls occurs at a broader width than that without sidewalls. The experimental results agree well with the theoretical analysis.
为了研究样品宽度和侧壁对挤压聚苯乙烯(XPS)板火焰向下蔓延的影响,进行了一系列实验室规模的实验。记录火焰形状、火焰蔓延速度、质量损失率和温度。对于无侧壁的XPS,平均最大火焰高度(H)和单位宽度平均火焰面积(A/w)随样品宽度(w)和单位宽度质量损失率的增加而线性上升。当没有侧壁时,火焰蔓延速度随宽度的增加先下降后上升。这种趋势是由气相传热决定的。当侧壁存在时,火焰蔓延速度随宽度的增加而增加,固相热传导决定了趋势。侧壁效应包括四个方面:靠近侧壁和石膏板的氧气浓度较低,导致火焰热流密度降低;向上和前方气流加强;火焰伸展,表面火焰减弱;熔融XPS质量减小。在较窄的样品中,有侧壁的H和A/w高于无侧壁的样品,而在较宽的样品中则相反。有侧壁时的质量损失率、预热长度和平均火焰蔓延速度均小于无侧壁时。有侧壁时火焰传播加速的宽度比无侧壁时宽。实验结果与理论分析吻合较好。
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引用次数: 6
Effects of cable fire smoke on electronic boards 电缆火灾烟气对电路板的影响
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1035
R. Gracia, S. Mongruel, E. Wizenne
The consequences of a fire are twofold: an increase in temperature and heat fluxes, and smoke propagation at the source of the fire and in adjacent rooms. These may lead to malfunctions of fire safety electrical equipment in nuclear power plants. A survey of relevant literature has shown that the equipment most affected by smoke particles and gases are electronic boards. Smoke causes electronic boards to malfunction in four ways: loss of metallic contact due to chemical corrosion, increased short circuiting between the conductors, loss of mechanical contact conductivity, and reduced capacity for movement in electromechanical systems as a result of particle deposits. These effects can occur over different timescales: – In the short term, malfunctions that have critical impact in terms of plant safety occur – such as electrical short circuiting and increased contact resistance, – Mid to longer term, corrosion effects can appear. A test procedure based on the repeatability of a 20-minute duration cable fire was set up. Temperature and smoke composition in terms of both gaseous products and soot were controlled. Tests were performed on boards designed to sum test and regulation signals, or to control an analog chain fitted with relays. Although the behaviour of the equipment may be dependent upon its construction material and equipment layout, no electronic board malfunctions occurred during the 24-hour tests. Furthermore, no malfunctions were detected in the boards when they were retested six months later under normal conditions and without any clean-up following the smoke exposure.
火灾的后果是双重的:温度和热流的增加,以及烟雾在火源和邻近房间的传播。这些都可能导致核电站消防安全电气设备的故障。对相关文献的调查表明,受烟雾颗粒和气体影响最大的设备是电子电路板。烟雾以四种方式导致电子电路板故障:由于化学腐蚀而失去金属接触,导体之间短路增加,机械接触导电性丧失,以及由于颗粒沉积而降低机电系统的运动能力。这些影响可能在不同的时间尺度上发生:-短期内,对工厂安全产生重大影响的故障发生-例如电气短路和接触电阻增加;-中长期内,可能出现腐蚀影响。建立了基于20分钟持续电缆火灾可重复性的测试程序。控制了气体产物和烟尘的温度和烟雾成分。测试是在设计用于汇总测试和调节信号的电路板上进行的,或者用于控制装有继电器的模拟链。虽然设备的性能可能取决于其结构材料和设备布局,但在24小时测试期间没有发生电子板故障。此外,六个月后在正常条件下重新测试时,没有发现电路板出现故障,并且在烟雾暴露后没有进行任何清理。
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引用次数: 2
Mathematical Modelling of Pool Fire Burning Rates in a Full- Scale Ventilated Tunnel 全尺寸通风隧道池火燃烧速率的数学模型
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-361
Hui Wang, H. Sahraoui
A computational fluid dynamic model with full coupling between gaseous and liquid phases is developed to predict buring rates of liquid pool fires in ventilated full-scale tunnel. Rates of fuel release are calculated using predictions of flame feedback to the surface of the pool. A pool fire in tunnel is modelled as an unsteady process, from the time of ignition until convergence to a quasi-steady burning rate. This feedback supports sustained flame above the pool surface and controls the burning rate of the fuel. The numerical model solves three dimensional, time-dependent Navier-Stokes equations, coupled with submodels for soot formation and thermal radiation transfer. Turbulent combustion process is modelled by an Eddy Dissipation Concept (EDC) by using two chemical reaction steps to CO prediction. The numerical model is shown to possess the ability to predict the effect of ventilation on burning rate and the initial growth period in a fullscale tunnel fire. The current study indicates that CO generation is relatively independent of position in the overfire region, and correlated solely as a function of mixture fraction. While no correlation of soot concentrations in terms of the mixture fraction is found. Abundant CO and soot are formed around the fire base, which is later deflected near the tunnel ceiling, and the backflow brings about the toxic products with a noticeable smoke stratification as the airflow velocity is below a critical value.
建立了一个气、液相完全耦合的计算流体动力学模型,用于预测全尺寸通风隧道中液池火灾的燃烧速率。燃料的释放速率是通过火焰反馈到池表面的预测来计算的。将隧道池火从点火到收敛到准稳态燃烧速率的非定常过程建模。这种反馈支持池表面以上的持续火焰,并控制燃料的燃烧速度。该数值模型求解三维、时变的Navier-Stokes方程,并结合烟尘形成和热辐射传递的子模型。用涡流耗散概念(EDC)模拟了湍流燃烧过程,采用两个化学反应步骤对CO进行了预测。结果表明,该数值模型能够较好地预测全尺寸隧道火灾中通风对燃烧速率和初生长期的影响。目前的研究表明,CO的生成相对独立于过火区域的位置,而仅与混合物分数相关。而煤烟浓度在混合分数方面没有相关性。在火基周围形成大量的CO和烟尘,随后在隧道顶板附近偏转,当气流速度低于临界值时,回流产生有毒产物,烟雾分层明显。
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引用次数: 4
期刊
Fire Safety Science
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