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Sensitivity of Heat of Reaction for Polyurethane Foams 聚氨酯泡沫的反应热敏感性
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-179
D. Pau, C. Fleischmann, M. Spearpoint, K. Li
The heat of reaction for the decomposition of polyurethane foam and its melt are determined from the heat flow measurements obtained through simultaneous differential scanning calorimetry and thermogravimetric analysis. Under nitrogen environment, the decomposition of foam experiences two endothermic pyrolysis reactions based on the experimental results. Through the investigation on the sensitivity of heat of reaction to heating rate and sample mass, a region where the heat of reaction remains constant is found for the melt samples tested. This consistent region includes heating rate from 5 to 20 °C/min and sample mass between ~20 and ~50 mg. No consistent region is found for the foam samples because of the reduced accuracy in the heat flow measured. For the foams and melts tested, the consistent heat of reaction for the second reaction ranges from endothermic 164 ‐ 295 J/g while the recommended heat of reaction for the first reaction ranges from endothermic 610 ‐ 1023 J/g.
通过差示扫描量热法和热重法同时测定的热流数据,确定了聚氨酯泡沫及其熔体分解的反应热。根据实验结果,在氮气环境下,泡沫的分解经历了两次吸热热解反应。通过对反应热对加热速率和试样质量的敏感性的研究,找到了熔体试样反应热保持恒定的区域。这一一致区域包括升温速率为5 ~20°C/min,样品质量为~20 ~ ~50 mg。由于测量的热流精度降低,泡沫样品没有发现一致的区域。对于测试的泡沫和熔体,第二反应的一致反应热范围为吸热164‐295 J/g,而第一反应的推荐反应热范围为吸热610‐1023 J/g。
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引用次数: 11
Impact of solid fuel particle size upon the propagation of a surface fire through a homogeneous vegetation layer 固体燃料颗粒大小对地表火灾通过均匀植被层传播的影响
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1326
D. Morvan, A. Lamorlette
The aim of this paper is to investigate the role played by the size (thickness) of solid fuel particles upon both the heat transfer and the propagation of a surface fire through a homogeneous vegetation layer. Because all the interactions (mass, momentum, and heat transfer) between the solid fuel layer and the gas phase occur at the interface between these two media, the surface area to volume (SA/V) ratio (inversely proportional to the thickness of the solid fuel particles), which appears in the expression of the specific surface separating these two phases, must affect, more or less significantly, the fire dynamics. This problem has been studied numerically, using a multiphase formulation. Various variables, such as the temperature of the solid fuel, the temperature of the gas, the fire residence time and the heat flux by radiation and convection have been analyzed, in order to understand the role played by the SA/V upon the behaviour of the fire.
本文的目的是研究固体燃料颗粒的大小(厚度)对热传递和表面火灾在均匀植被层中的传播所起的作用。由于固体燃料层和气相之间的所有相互作用(质量、动量和热传递)都发生在这两种介质之间的界面上,因此在分离这两相的比表面的表达式中出现的表面积体积比(SA/V)(与固体燃料颗粒的厚度成反比)必然或多或少地影响着火灾动力学。用多相公式对这一问题进行了数值研究。分析了固体燃料的温度、气体的温度、火焰停留时间以及辐射和对流的热通量等各种变量,以了解SA/V对火灾行为的作用。
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引用次数: 5
Electrical Receptacles - Overheating, Arcing, and Melting 插座。过热、电弧和熔化
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1010
M. Benfer, D. Gottuk
This study was designed to experimentally characterize factors that can cause electrical failures (i.e., overheating connections), to assess the damage and potential forensic signatures of these failures, and to characterize the similarities and differences between arcing and melting in receptacle components and wiring. Laboratory testing evaluated the impact of a wide range of variables on the formation of overheating connections in residential duplex receptacles including screw terminal torque, wiring method (back-wired, or side-wired), and primary receptacle materials. A total of 408 trials of receptacles with various terminal connections were tested in the laboratory setting; receptacles were powered for up to 16 months. A small portion of receptacles with loose connections overheated to the point of failure of the receptacle; some including flaming events. Failure events occurred between 5 and 365 days after tests were started. Four hundred and sixty eight (468) receptacles were placed in compartment fire tests and furnace fire tests. These tests were designed to evaluate the persistence after fire exposure of overheating/arcing evidence from failure events (i.e., from potential fire cause events). The fire exposure tests also served to analyze the characteristic traits of arcing and melting damage. The results indicated that only very loose connections (less than 0.339 N-m [3 in-lb]) at moderately high currents (9A or higher) tend to form significant overheating connections and receptacle failures, irrespective of other variables such as receptacle materials and installation. Characteristic indicators of overheating and glowing terminal connections were identified and were found to persist after fire exposure.
本研究旨在通过实验表征可能导致电气故障的因素(即过热连接),评估这些故障的损坏和潜在的法医特征,并表征插座组件和布线中电弧和熔化之间的异同。实验室测试评估了一系列变量对住宅复式插座中过热连接形成的影响,包括螺旋端子扭矩、接线方法(背接线或侧接线)和主插座材料。在实验室环境中,共有408个不同端子连接的插座试验进行了测试;插座的供电时间长达16个月。一小部分连接松动的插座过热到插座失效点;其中一些包括燃烧事件。故障事件发生在测试启动后的5天到365天之间。468个容器被放置在隔间防火试验和熔炉防火试验中。这些测试旨在评估故障事件(即潜在的火灾原因事件)引起的过热/电弧证据在火灾暴露后的持久性。火灾暴露试验也用于分析电弧和熔化损伤的特征特征。结果表明,在中等高电流(9A或更高)下,只有非常松散的连接(小于0.339 N-m [3 in-lb])才容易形成明显的过热连接和插座故障,而与插座材料和安装等其他变量无关。确定了过热和发光端子连接的特征指标,并发现在火灾暴露后持续存在。
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引用次数: 5
Experimental approach to estimate species concentrations in a compartment fire 估计隔间火灾中物种浓度的实验方法
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-346
J. Lassus, L. Courty, E. Studer, J. Garo, P. Aîne
An approach for estimating species concentration during a fire in a well-stirred compartment is investigated. A semi-empirical model based on oxygen concentration is used. It gives an estimate of the concentrations of carbon monoxide, carbon dioxide, hydrogen and hydrocarbons with a carbon chain length lower than five. Three intervals of oxygen concentration are noticed, they correspond to sufficiently ventilated, underventilated and very underventilated fires. In order to validate this model, fire experiments are performed in a reduced-scale compartment . Species concentrations predicted by the model are in good agreement with our experimental data and with those of literature. Coefficients used for the model are obtained for heptane and dodecane fires.
研究了一种在搅拌均匀的隔间内进行火灾时估算物质浓度的方法。采用了基于氧浓度的半经验模型。它给出了一氧化碳、二氧化碳、氢和碳链长度小于5的碳氢化合物的浓度估计。注意到三个氧气浓度间隔,它们对应于充分通风,不通风和非常不通风的火灾。为了验证该模型,在缩小尺寸的隔间中进行了火灾实验。该模型预测的物种浓度与实验数据和文献数据吻合较好。模型中使用的系数是由庚烷和十二烷燃烧得到的。
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引用次数: 2
Parametric Analysis of Heat Transfer in Gypsum Wallboard Partitions 石膏墙板隔墙传热参数分析
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-598
M. Bruns, K. Prasad
One-dimensional heat transfer in gypsum wallboard partitions is studied using sensitivity analysis and calibration by error minimization. Analysis of an existing heat and mass transfer model indicates that mass transfer and condensation of water vapor are not of primary importance in predicting board temperatures. A computationally efficient and robust heat transfer model is developed for predicting temperatures in gypsum wallboard partitions. Kinetic parameters are calibrated by error minimization with respect to literature thermogravimetric analysis (TGA) data. Additional thermophysical parameters are calibrated by error minimization with respect to literature ASTM E119 furnace test data. It is found that the calibrated heat transfer model is capable of predicting board temperatures given large thermal conductivities and specific heats at high temperatures. It is hypothesized that these observations imply the need to account for porous media radiation, temperature varying specific heats, and calcium carbonate decomposition in future models. Local sensitivity analysis reveals that board temperatures are most sensitive to initial density, thermal conductivity at moderately high temperatures ( 800 C), and the activation energy of the dehydration reactions. Conversely, model predictions are relatively insensitive to dehydration reaction pre-exponentials and low-temperature heat capacities.
采用灵敏度分析和误差最小化校正方法研究了石膏墙板隔板的一维传热。对现有的传热传质模型的分析表明,在预测板温度时,传质和水蒸气的冷凝并不是最重要的。建立了一种计算效率高、鲁棒性强的石膏墙板隔墙温度预测模型。动力学参数是通过误差最小化校准相对文献热重分析(TGA)数据。额外的热物理参数根据文献ASTM E119炉测试数据通过误差最小化进行校准。校正后的传热模型能够在较大导热系数和高温比热条件下预测板的温度。据推测,这些观测结果意味着在未来的模型中需要考虑多孔介质辐射、温度变化比热和碳酸钙分解。局部敏感性分析表明,板料温度对初始密度、中高温(800℃)下的导热系数和脱水反应的活化能最为敏感。相反,模型预测对脱水反应前指数和低温热容相对不敏感。
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引用次数: 3
Fire development in different scales of train carriages 不同规模火车车厢的火灾发展
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-302
Ying Zhen Li, H. Ingason, Anders Lönnermark
A fire development analysis of three series of train carriage fire tests in different scales was carried out. These train carriage fire tests included 1:10 model scale tests, 1:3 model scale tests and 1:1 full scale tunnel tests. The heat release rate (HRR) correlations between different scales of carriage fire tests were carefully investigated. The mechanism of fire development is very similar in different scales of tests involving fully developed fires. After the critical fire spread, the fire travelled along the carriage at an approximately constant speed. The maximum heat release rate obtained for a fully developed fire is dependent on the ventilation conditions and also the type and configuration of the fuels, and a simple equation has been proposed to estimate the maximum heat release rate. A global correction factor of the maximum heat release rate is presented and examined.
对三个系列不同规模的火车车厢火灾试验进行了火灾发展分析。这些火车车厢火灾试验包括1:10模型比例试验、1:3模型比例试验和1:1全尺寸隧道试验。仔细研究了不同尺度车厢燃烧试验的放热率(HRR)相关性。在涉及完全发展的火灾的不同规模的试验中,火灾发展的机制非常相似。在临界火势蔓延后,火势以大约恒定的速度沿着车厢蔓延。充分发展的火灾的最大放热率取决于通风条件以及燃料的类型和配置,并提出了一个简单的公式来估计最大放热率。提出并检验了最大放热率的全局校正因子。
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引用次数: 35
Correlations for Evaluation of Flame Spread over an Inclined Fuel Surface 倾斜燃料表面火焰扩散评价的相关系数
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-222
Xinyan Huang, M. Gollner
The time-dependent flame spread process over thermally thick slabs of polymethyl methacrylate (PMMA) is investigated with particular emphasis on the burning behavior and geometry of the flame. 10 cm wide by 20 cm long samples are ignited and allowed to spread upwards at angles of orientation between pool and ceiling burning. Correlations between the flame length and the fuel mass-loss rate have revealed a delayed transition to turbulence for flames residing on the underside of fuel samples, and an earlier transition to turbulence for flames on the topside of these samples, compared to traditional vertical wall flames. As the fuel inclination increases, the relationship between the flame length and fuel mass-loss rate ranges between a recent theoretical prediction for a laminar wall plume dominated by diffusion and the traditional prediction for a turbulent wall plume dominated by convective mixing. The buoyancy-induced flow field, characterized by the flame tilt angle is shown to correspond to previously-found modifications of heat-flux profiles ahead of the flame front, which control flame spread, and the heat flux to the burning surface of the fuel, which controls fuel mass-loss rates. Other correlations between some of these parameters, such as the flame and pyrolysis lengths are also presented as a function of inclination.
在热厚的聚甲基丙烯酸甲酯(PMMA)板上研究了随时间变化的火焰传播过程,特别强调了火焰的燃烧行为和几何形状。点燃10厘米宽,20厘米长的样品,并允许在池和天花板燃烧之间的方向角向上扩散。火焰长度与燃料质量损失率之间的相关性表明,与传统的垂直壁火焰相比,位于燃料样品底面的火焰向湍流的过渡延迟,而这些样品顶部的火焰向湍流的过渡提前。随着燃料倾斜度的增大,火焰长度与燃料质量损失率之间的关系介于以扩散为主的层流壁羽和以对流混合为主的湍流壁羽之间。以火焰倾斜角度为特征的浮力诱导流场与先前发现的火焰锋面前的热流密度曲线的变化相对应,前者控制火焰的蔓延,后者控制燃料燃烧表面的热流密度,后者控制燃料的质量损失率。其中一些参数(如火焰和热解长度)之间的其他相关性也被表示为倾角的函数。
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引用次数: 35
Carbon monoxide production during underventilated fires in corridors 走廊通风不良时产生的一氧化碳
Pub Date : 2014-01-01 DOI: 10.3801/IAFSS.FSS.11-316
S. Ukleja, M. Delichatsios, Jianping Zhang, M. Suzanne
This work presents experimental results and non-dimensional correlations of factors and conditions affecting carbon monoxide (CO) production in corridor-like enclosure fires. Thirty eight experiments were performed in a three metre long corridor-like enclosure having a cross section 0.5 m x 0.5 m, door-like openings in the front panel and a propane gas burner located near the closed end being flushed with the floor. Measurements of carbon monoxide concentrations were performed at locations inside the enclosure and also in the exhaust duct of a hood collecting the combustion products for direct comparison. Visual observations through the opening revealed that flames were detaching from the burner for tests with global equivalence ratios (GERs) greater than one for the burning inside the enclosure (underventilated fires). After detachment, flames were travelling towards the opening then finally stayed anchored in the vicinity of the opening and emerged outside. After flames were visible outside, the concentration of CO inside the corridor increases to much higher levels owing to the recirculation of gases inside the enclosure behind the flames. A correlation between CO concentration inside the enclosure and GER was found with CO increasing initially but then decreasing for high global equivalence ratios. An additional correlation was found between the CO yield and the GER in the enclosure before the flames reached and then, anchored at the opening of the enclosure. Finally, it was found that the ratio of CO to smoke yield, yco/ys, is not constant but increases for global equivalence ratios of the enclosure greater than one in contrast to its value being constant for over ventilated conditions.
这项工作提出了实验结果和影响一氧化碳(CO)生产的因素和条件的无量纲相关性在走廊状围场火灾。38个实验是在一个3米长的走廊式封闭室内进行的,该封闭室内的横截面为0.5米× 0.5米,前面板上有类似门的开口,丙烷气体燃烧器位于封闭端附近,与地板一起冲洗。一氧化碳浓度的测量在箱体内的位置进行,也在一个引擎盖的排气管道中进行,收集燃烧产物进行直接比较。通过开口进行的目视观察显示,火焰正在从燃烧器上分离出来,用于测试整体等效比(ger)大于1的外壳内燃烧(通风不良的火灾)。分离后,火焰向洞口移动,最终停留在洞口附近,并向外蔓延。在看到外面的火焰后,由于火焰后面的外壳内气体的再循环,走廊内的CO浓度增加到更高的水平。封地内CO浓度与GER之间存在相关性,当整体等效比较高时,CO浓度先升高后降低。在火焰到达之前,在外壳内的CO产量和GER之间发现了额外的相关性,然后锚定在外壳的开口处。最后,我们发现CO与产烟量之比yco/ys不是恒定的,但当围护结构的整体等效比大于1时,它的值会增加,而在过度通风条件下,它的值是恒定的。
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引用次数: 3
An Experimental Study Evaluating the Burning Dynamics of Pitch Pine Needle Beds Using the FPA 用FPA评价沥青松针床燃烧动力学的实验研究
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1406
Jan C. Thomas, A. Simeoni, Michael R. Gallagher, N. Skowronski
Pine needle litters, a key fuel in coniferous forest systems, are highly porous fuel beds. They provide a source of continuous fuel medium that can be easily ignited and will sustain flame spread on the ground during forest fires. This work represents an experimental study that is focused on the influence of the fuel moisture content on the burning dynamics and the flammability characteristics of forest fuel beds. The FM Global Fire Propagation Apparatus was utilized to obtain time to ignition, heat release rate, total heat released and CO/CO2 concentration data. The methodologies applied in previous studies were improved with new modifications. The results were analyzed with respect to the sample’s fuel moisture content as well as other test conditions, such as airflow condition (wind), sample holder openness and external heat flux. The importance of the fuel moisture content is critical to understand as the majority of fuels present in the natural environment have elevated moisture content compared to dead dry fuel. Samples studied are representative of wet ground fuels as well as live fuels which do burn when crowning conditions develop. The results presented here are a building block for developing an experimental database that can be used to understand the influence of environmental conditions on the flammability of porous forest fuels and assess the risks that comes with a wildfire. Furthermore, the data can also be used for fire behavior model validation.
松针凋落物是针叶林系统的重要燃料,是高度多孔的燃料床。它们提供了一种连续的燃料介质,可以很容易地点燃,并在森林火灾期间维持火焰在地面上的蔓延。本文主要研究了燃料含水率对森林燃料床燃烧动力学和可燃性特性的影响。利用FM全球火焰传播仪获得点火时间、放热率、总放热量和CO/CO2浓度数据。在以往的研究中应用的方法得到了改进,并进行了新的修改。分析了样品的燃料含水率以及其他测试条件,如气流条件(风)、样品支架开度和外部热通量。理解燃料水分含量的重要性是至关重要的,因为与完全干燥的燃料相比,存在于自然环境中的大多数燃料的水分含量较高。所研究的样品既有湿地燃料的代表,也有在形成顶盖条件时燃烧的活燃料的代表。这里提出的结果是开发一个实验数据库的基础,该数据库可用于了解环境条件对多孔森林燃料可燃性的影响,并评估野火带来的风险。此外,这些数据还可以用于火灾行为模型的验证。
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引用次数: 12
Effects of cable fire smoke on electronic boards 电缆火灾烟气对电路板的影响
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1035
R. Gracia, S. Mongruel, E. Wizenne
The consequences of a fire are twofold: an increase in temperature and heat fluxes, and smoke propagation at the source of the fire and in adjacent rooms. These may lead to malfunctions of fire safety electrical equipment in nuclear power plants. A survey of relevant literature has shown that the equipment most affected by smoke particles and gases are electronic boards. Smoke causes electronic boards to malfunction in four ways: loss of metallic contact due to chemical corrosion, increased short circuiting between the conductors, loss of mechanical contact conductivity, and reduced capacity for movement in electromechanical systems as a result of particle deposits. These effects can occur over different timescales: – In the short term, malfunctions that have critical impact in terms of plant safety occur – such as electrical short circuiting and increased contact resistance, – Mid to longer term, corrosion effects can appear. A test procedure based on the repeatability of a 20-minute duration cable fire was set up. Temperature and smoke composition in terms of both gaseous products and soot were controlled. Tests were performed on boards designed to sum test and regulation signals, or to control an analog chain fitted with relays. Although the behaviour of the equipment may be dependent upon its construction material and equipment layout, no electronic board malfunctions occurred during the 24-hour tests. Furthermore, no malfunctions were detected in the boards when they were retested six months later under normal conditions and without any clean-up following the smoke exposure.
火灾的后果是双重的:温度和热流的增加,以及烟雾在火源和邻近房间的传播。这些都可能导致核电站消防安全电气设备的故障。对相关文献的调查表明,受烟雾颗粒和气体影响最大的设备是电子电路板。烟雾以四种方式导致电子电路板故障:由于化学腐蚀而失去金属接触,导体之间短路增加,机械接触导电性丧失,以及由于颗粒沉积而降低机电系统的运动能力。这些影响可能在不同的时间尺度上发生:-短期内,对工厂安全产生重大影响的故障发生-例如电气短路和接触电阻增加;-中长期内,可能出现腐蚀影响。建立了基于20分钟持续电缆火灾可重复性的测试程序。控制了气体产物和烟尘的温度和烟雾成分。测试是在设计用于汇总测试和调节信号的电路板上进行的,或者用于控制装有继电器的模拟链。虽然设备的性能可能取决于其结构材料和设备布局,但在24小时测试期间没有发生电子板故障。此外,六个月后在正常条件下重新测试时,没有发现电路板出现故障,并且在烟雾暴露后没有进行任何清理。
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引用次数: 2
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Fire Safety Science
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