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Comparison of a supercritical fluid extraction method for the extraction of oilseeds with the DGF standard method B‐I 5 (87) 超临界流体萃取油籽法与DGF标准方法B‐I 5(87)的比较
Pub Date : 1999-06-01 DOI: 10.1002/(SICI)1521-4133(199906)101:6<203::AID-LIPI203>3.0.CO;2-N
B. Matthäus, L. Brühl
Three different oilseeds, rapeseed, sunflower, and soybeans are extracted by SFE (supercritical fluid extraction). As parameter for the extraction conditions the extracts are analyzed regarding the contents of tocopherols, and as parameter for the content of more polar lipids the contents of diglycerides and free fatty acids are analyzed. The extraction temperature has a significant influence on the determined oil content, the content of tocopherols, diglycerides, and free fatty acids. With increasing temperature the oil content increases. The content of tocopherols, diglycerides, and free fatty acids increases up to 75 °C. At 100 °C the content of diglycerides and free fatty acids decreases and the content of tocopherols shows no appreciable changes. The optimal extraction conditions are described and the results of the determination of the oil content under optimal conditions are compared with the results of the DGF standard method B-I 5 (87). The oil contents investigated with both methods correspond well. The content of tocopherols is significantly higher in the oil of rapeseed and soybeans extracted by SFE, whereas the content of diglycerides and free fatty acids varied in dependence on the oilseed. Vergleich einer SFE-Methode zur Extraktion von Olsaaten mit der DGF-Standardmethode B-I 5 (87).Drei verschiedene Olsaaten, Raps, Sonnenblumen und Soja, wurden mittels SFE (supercritical fluid extraction) extrahiert. Die gewonnenen Extrakte wurden hinsichtlich ihres Gehalts an Tocopherolen, als Parameter fur die Extraktionsbedingungen, sowie hinsichtlich des Gehalts an Diglyceriden und freien Fettsauren, als Parameter fur den Gehalt an polareren Lipiden, untersucht. Die Extraktionstemperatur hat einen signifikanten Einflus auf den Ol-gehalt und die Gehalte an Tocopherolen, Diglyceriden und freien Fettsauren. Mit steigender Temperatur nimmt der Olgehalt zu. Der Gehalt an Tocopherolen, Diglyceriden und freien Fettsauren steigt bis zu einer Temperatur von 75 °C an. Bei einer Temperatur des Extraktors von 100 °C nehmen die Gehalte an Diglyceriden und freien Fettsauren wieder ab, und der Gehalt an Tocopherolen bleibt unverandert. Die optimalen Extraktionsbedingungen werden beschrieben, und die Ergebnisse der Olgehaltsbestimmungen unter diesen Bedingungen mit den Ergebnissen der DGF-Standardmethode B-I 5 (87) verglichen. Die mit beiden Methoden ermittelten Olgehalte sind sehr gut vergleichbar. Der Tocopherolgehalt ist in den Olen aus Raps bzw. Soja signifikant hoher nach Extraktion mittels SFE, wobei die Gehalte an Diglyceriden und freien Fettsauren in Abhangigkeit von der Olsaat schwanken.
采用超临界流体萃取法提取油菜籽、葵花籽和大豆三种不同的油菜籽。以生育酚含量为提取条件参数,以双甘油酯和游离脂肪酸含量为极性脂质含量参数。提取温度对测定的含油量、生育酚、二甘油酯和游离脂肪酸含量有显著影响。随着温度的升高,含油量增加。生育酚、二甘油酯和游离脂肪酸的含量增加到75°C。在100℃时,甘油三酯和游离脂肪酸的含量降低,生育酚的含量没有明显变化。描述了最佳提取条件,并将最佳提取条件下的含油量测定结果与DGF标准方法b - i5(87)的结果进行了比较。两种方法测得的含油量吻合良好。SFE提取的油菜籽油和大豆油中生育酚的含量显著高于其他油菜籽油,而甘油三酯和游离脂肪酸的含量则因油菜籽的不同而不同。Vergleich einer sfe法提取Olsaaten与dgf - standard方法B-I 5(87)。Drei verschiedene Olsaaten, Raps, Sonnenblumen和Soja, wurden mittel的超临界流体萃取(SFE)。Die gewonnenen Extrakte wurden hinsichtlich ihres Gehalts and tocopolen, Die Extraktionsbedingungen, sowie hinsichtlich des Gehalts and digididen and freien Fettsauren, Die gewonnenen Parameter for den Gehalts and polareven Lipiden, untersuet。萃取温度可显著提高细菌的抗氧化能力,包括:抗氧化能力、抗氧化能力、生育酚、双甘油三酯和抗氧化能力。Mit steigender temperature的翻译结果:二甘油三酯、生育酚、二甘油三酯和三甘油三酯在75°C和75°C以下的温度下对人体的影响。在100°C的高温条件下,对双甘油三酯和双甘油三酯进行了研究,并对双甘油三酯和生育酚进行了研究。Die optimalen Extraktionsbedingungen werden besklehen, and Die Ergebnisse der Olgehaltsbestimmungen underen Bedingungen mit den Ergebnissen der dgf - standard method b - i5 (87) verglichen。“我爱你,我爱你,我爱你,我爱你。”《生育学家》(the tocopherolgehaist)在《奥伦奥斯》杂志上发表。Soja的另一项重要任务是在SFE,即在Abhangigkeit von der Olsaat schwanken的Abhangigkeit, Diglyceriden和freien Fettsauren。
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引用次数: 12
The effect of rapeseed treatment by microwave and radio-frequency application on oil extraction and oil quality. Part I : Influence on mechanical oil extraction 微波与射频处理对菜籽油脂提取及品质的影响。第一部分:对机械榨油的影响
Pub Date : 1999-05-01 DOI: 10.1002/(SICI)1521-4133(199905)101:5<164::AID-LIPI164>3.0.CO;2-1
C. Oberndorfer, W. Lücke
The effect of a pretreatment of rapeseed with microwaves and radio-frequency energy on the oil yield and on the oil quality was investigated. Rapeseed samples were treated in an experimental microwave applicator and in an experimental radio-frequency applicator at different temperatures. Duration of treatment and the power applied were also varied. Afterwards the samples were pressed in a laboratory screw press and the exploitation rate was calculated. Results showed that pretreatment led to an obvious increase of the exploitation rate. The important parameters for this effect are temperature of pretreatment and power applied. Time of pretreatment is of lower importance. Further investigations also showed an influence of the pretreatment on quality parameters of the oil. These results are presented in the second part of this article The Effect of Rapeseed Pretreatment by Microwave- and RF-application on Oil Extraction and Oil Quality - Part II. Influence on Oil Quality.
研究了微波和射频能量预处理油菜籽对油菜籽出油率和油质的影响。在不同的温度下,在实验微波和实验射频中处理菜籽样品。治疗时间和施加的功率也有所不同。然后在实验室螺旋压力机中对样品进行压榨,并计算出采收率。结果表明,预处理能明显提高采收率。影响这一效果的重要参数是预处理温度和功率。预处理时间的重要性较低。进一步研究还发现了预处理对油的质量参数的影响。本文的第二部分为微波和射频预处理对菜籽油脂提取和品质的影响(二)。对油品质量的影响。
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引用次数: 14
Production of structured lipids by lipase-catalyzed interesterification in a packed bed reactor: effect of reaction parameters on the level of diacylglycerols in the products 在填充床反应器中用脂肪酶催化的酯化反应生产结构化脂质:反应参数对产物中二酰基甘油含量的影响
Pub Date : 1999-05-01 DOI: 10.1002/(SICI)1521-4133(199905)101:5<158::AID-LIPI158>3.0.CO;2-Q
H. Mu, Xuebing Xu, J. Adler-Nissen, C. Høy
The 1,3-specificity of a lipase was utilized in lipase-catalyzed interesterification to produce specific structured lipids containing long-chain polyunsaturated fatty acids at the sn-2 position and medium-chain fatty acids (MCFAs) at the primary position in a packed-bed reactor. Diacylglycerols (DAGs) are important intermediate products in the production of structured lipids, both with regard to the yields of the products and the content of the by-products, but the levels of DAGs produced in lipase-catalyzed interesterification in a continuous process are not well-known. We examined the effects of the following interesterification parameters on the level of DAGs: reaction temperature, residence time, substrate ratio, and water content. Reaction temperature was the most critical factor, with elevated reactor temperatures (particular those above 60 °C) resulting in a considerable increase in the DAG content of the products. Longer residence times increased the level of DAGs in the products, and favoured the formation of 1,3-DAGs from 1,2-DAGs by acyl migration. Increasing the molar ratio between MCFAs and oil, as well as increasing the water content in the reacting substrate mixture affected the DAG content only slightly. The DAG content in the interesterification products had positive correlation with the migration of MCFAs, implying that a high level of DAGs is an indicator for partial acylglycerols and positional isomers, both are impurities in the products. On the other hand, the content of DAGs correlated positively with the incorporation of MCFAs, suggesting that the DAGs are also important for the production of the structured lipids. Under optimized conditions (temperature, 60°C; water, 0.03%; residence time, 4 h; substrate ratio, 6:1), the level of DAGs produced in the packed-bed reactor was less than 4%, and the incorporation and migration of MCFAs were 47% and 1%, respectively.
在填充床反应器中,利用脂肪酶的1,3特异性在脂肪酶催化的酯化反应中产生了含有sn-2位置的长链多不饱和脂肪酸和主要位置的中链脂肪酸(MCFAs)的特定结构脂质。二酰基甘油(Diacylglycerols, DAGs)是生产结构化脂类的重要中间产物,无论是产品的产率还是副产物的含量,但在脂肪酶催化的连续过程中产生的daags的水平尚不清楚。我们考察了反应温度、停留时间、底物比和水含量对dag含量的影响。反应温度是最关键的因素,反应器温度升高(特别是60°C以上的温度)会导致产物中DAG含量的显著增加。较长的停留时间增加了产物中dag的含量,有利于1,2- dag通过酰基迁移形成1,3- dag。增加MCFAs与油的摩尔比以及增加反应底物混合物中的含水量对DAG含量的影响很小。酯化产物中DAG的含量与mcfa的迁移量呈正相关,表明高水平的DAG是部分酰基甘油和位置异构体的指标,两者都是产物中的杂质。另一方面,dag的含量与mcfa的掺入呈正相关,这表明dag对结构脂质的产生也很重要。在优化条件下(温度:60℃;水、0.03%;停留时间,4小时;底物比为6:1),填充床反应器中产生的dag水平小于4%,mcfa的掺入率和迁移率分别为47%和1%。
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引用次数: 22
Determination of free and esterified sterols in potential new oil seed crops by coupled on‐line liquid chromatography‐gas‐chromatography 液相色谱-气相色谱联用在线测定潜在新型油料作物中的游离和酯化甾醇
Pub Date : 1999-05-01 DOI: 10.1002/(SICI)1521-4133(199905)101:5<171::AID-LIPI171>3.0.CO;2-9
M. Lechner, B. Reiter, E. Lorbeer
In vegetable oil, free and esterified sterols are characteristic constituents of the unsaponifiable matter and provide rich information about the oil quality. The sterol pattern of plants discussed as potential new oil seed crops have been determined by using coupled on-line normal phase liquid chromatography-gaschromatography (LC-GC). The content and composition of free sterols as well as the concentration of sterol esters have been analyzed in seed oils of different varieties of crambe (Crambe abyssinica), meadowfoam (Limnanthes alba, L. douglasii(, cape marigold (Dimorphotheca sinuata);, lesquerella (Lesquerella fendleri);, iron weed (Vernonia galamensis, V. petitiana);, spurge (Euphorbia lagascae, E. lathyris);, and various species of cuphea (Cuphea lanceolata, C. lutea, C. paucipetala, C. viscosissima, C. wrightii);. Bestimmung freier und veresterter Sterole in potentiellen neuen Olsaaten mittels gekoppelter Flussigkeitschromatographie-Gaschromatographie.Freie und veresterte Sterole sind charakteristische Bestandteile des Unverseifbaren und liefern wichtige Informationen uber die Qualitat von Pflanzenolen. Das Sterolmuster von Pflanzen, die als potentielle neue Olpflanzen diskutiert werden, wurde mittels gekoppelter Flussigkeitschromatographie-Gaschromatographie (LC-GC) analysiert. Der Gehalt und die Zusammensetzung der freien Sterole sowie die Konzentration der Sterolester wurden in folgenden Pflanzenarten bestimmt: Abessinischer Meerkohl (Crambe abyssinica), Sumpfschnabel (Limnanthes alba), Wiesenschaum (L. douglasii), Kapringelblume (Dimorphotheca sinuata), Blasenschotchen (Lesquerella fendleri), Vernonie (Vernonia galamensis, V. petitiana);, Wolfsmilch (Euphorbia lagascae, E. lathyris); und Kocherblumchen (Cuphea lanceolata, C. lutea, C. paucipetala, C. viscosissima, C. wrightii);.
在植物油中,游离甾醇和酯化甾醇是不皂化物质的特征成分,提供了丰富的油脂品质信息。采用在线正相液相色谱-气相色谱(LC-GC)联用技术测定了潜在新型油料作物植物的甾醇谱。对不同品种的海苔(crambe abyssinica)、绵草(Limnanthes alba, L. douglasii)、金盏花(Dimorphotheca sinuata)、菖蒲(lesquerella fendleri)、铁草(Vernonia galamensis, V. petitiana)、刺花(Euphorbia lagascae, E. lathyris)和不同种类的茶属植物(cuphea lanceolata, C. lutea, C. paucipetala, C. viscosissima, C. wrightii)的种子油中游离甾醇的含量、组成和甾醇酯的浓度进行了分析。液相色谱法-气相色谱法测定活性化合物和甾酮。Freie and veresterte Sterole and characteristicsche Bestandteile des universseifbaren and life and Informationen die Qualitat von Pflanzenolen。Das Sterolmuster von Pflanzen, die als potentielle neue Olpflanzen diskutiert werden, wurde mittels gekoppelter flussikeitchromatography - gas - gc (LC-GC)分析仪。在folgenden phflanzenarten bestim中,对Sterolester wurden的研究:Abessinischer Meerkohl (Crambe abyssinica)、Sumpfschnabel (Limnanthes alba)、Wiesenschaum (L. douglasii)、Kapringelblume (Dimorphotheca sinuata)、Blasenschotchen (Lesquerella fendleri)、Vernonie (Vernonia galamensis, V. petitiana)、Wolfsmilch (Euphorbia lagascae, E. lathyris);和Kocherblumchen (Cuphea lanceolata, C. lutea, C. paucipetala, C. viscosissima, C. wright);
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引用次数: 25
The effect of a moderately thermoxidized dietary fat on the vitamin E status, the fatty acid composition of tissue lipids, and the susceptibility of low‐density lipoproteins to lipid peroxidation in rats 适度热氧化膳食脂肪对大鼠维生素E状态、组织脂质脂肪酸组成和低密度脂蛋白对脂质过氧化的易感性的影响
Pub Date : 1999-05-01 DOI: 10.1002/(SICI)1521-4133(199905)101:5<178::AID-LIPI178>3.0.CO;2-I
K. Eder, M. Kirchgessner
Several studies demonstrated that dietary oxidized oils markedly affect the vitamin E status and alter the fatty acid composition of tissue lipids in animals. It must however be emphasized that highly oxidized oils reduce the feed intake of animals, which makes it difficult to interpret the results. Therefore, the present study used a moderately thermoxidized soybean oil (peroxide value: 75 mEq O 2 /kg), having a similar fatty acid composition as fresh soybean oil (peroxide value: 9.5mEq O 2 /kg) which was used as control. Moreover, according to a bifactorial design, two different vitamin E supplementary levels (11 vs. 511 mg at-tocopherol equivalents per kg diet) were used. The experiment was conducted with male Sprague-Dawley rats. The feeding period lasted for 40 days. In order to assess the vitamin E status, the vitamin E concentrations in plasma, liver, heart, kidney, and adipose tissue were determined. The vitamin E supply had a pronounced effect on the vitamin E concentrations of those tissues whereas the type of fat had only a slight effect. The fatty acid composition of total lipids from liver, erythrocytes, and low-density lipoproteins was also only slightly influenced by the oxidized fat. The osmotic fragility of erythrocytes was even reduced by feeding the oxidized oil. With a low vitamin E supply, the in vitro susceptibility of low-density lipoproteins to lipid peroxidation was slightly increased by feeding the oxidized oil. In contrast, with a high vitamin E supply, there was no adverse effect of the dietary oxidized oil on the susceptibility of low-density lipoproteins to lipid peroxidation. Feeding the oxidized oil, however, increased the concentrations of malondialdehyde in low-density lipoproteins suggesting an increased in vivo lipid peroxidation. Therefore, it cannot be ruled out that moderately oxidized dietary fats increase the atherogenicity of low-density lipoproteins. In contrast, a moderately oxidized oil scarcely affected the vitamin E status and the fatty acid composition of tissue lipids.
几项研究表明,饲料中的氧化油显著影响动物体内维生素E的状态,并改变组织脂质的脂肪酸组成。然而,必须强调的是,高度氧化的油减少了动物的采食量,这使得很难解释结果。因此,本研究使用适度热氧化大豆油(过氧化值:75 mEq O 2 /kg)作为对照,其脂肪酸组成与新鲜大豆油(过氧化值:9.5mEq O 2 /kg)相似。此外,根据双因子设计,使用了两种不同的维生素E补充水平(每公斤饮食11毫克和511毫克生育酚当量)。实验对象为雄性Sprague-Dawley大鼠。饲喂期40 d。为了评估维生素E的状态,测定了血浆、肝脏、心脏、肾脏和脂肪组织中的维生素E浓度。维生素E的供应对这些组织的维生素E浓度有明显的影响,而脂肪的类型只有轻微的影响。来自肝脏、红细胞和低密度脂蛋白的总脂质的脂肪酸组成也仅受氧化脂肪的轻微影响。红细胞的渗透脆弱性甚至通过喂食氧化油而降低。在维生素E供应不足的情况下,通过饲喂氧化油,体外低密度脂蛋白对脂质过氧化的敏感性略有增加。相反,在高维生素E供应的情况下,饲料中氧化油对低密度脂蛋白对脂质过氧化的敏感性没有不利影响。然而,饲喂氧化油增加了低密度脂蛋白中丙二醛的浓度,表明体内脂质过氧化作用增加。因此,不能排除适度氧化的膳食脂肪增加了低密度脂蛋白的动脉粥样硬化性。相反,适度氧化的油几乎不影响维生素E状态和组织脂质的脂肪酸组成。
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引用次数: 7
The effect of rapeseed treatment by microwave and radio-frequency application on oil extraction and oil quality. Part II: Influence on oil quality 微波与射频处理对菜籽油脂提取及品质的影响。第二部分:对油品质量的影响
Pub Date : 1999-05-01 DOI: 10.1002/(SICI)1521-4133(199905)101:5<168::AID-LIPI168>3.0.CO;2-M
I. Irfan, E. Pawelzik
The aim of our research was to investigate the influence of microwave and radio-frequency (RF) pretreatments of rapeseed on oil quality. Oil was extracted from the seeds through mechanical pressing. Few quality parameters of the gained oil as well as special enzymatic activities of the seeds were analyzed. Microwave application at temperatures ranging from 80 to 100°C (surface temperature of the seed) reduced the acid and peroxide values in oil, whilst the intensity of the oil colour increased. On the other hand, there was no effect noted on iodine value. Thiobarbituric acid value (TBA) and lipid acid composition of oil were not affected either. The peroxidase and methylumbelliferyl-palmitic-acid-esterhydrolase (MUPase) activities in the seeds decreased, which is very important in relation to the storability and the later processing of seeds or oils. The advantage of radio frequency (RF) compared to microwaves in this research was that no burning aroma was emitted by treating rapeseeds at 120°C so that the oil yield of the seeds by pressing could be further improved. Despite this high temperature, some parameters of oil quality (acid, peroxide, and TBA values) of treated seeds have not so much changed in general in comparison to untreated control. Like microwaves, RF-waves did not affect lipid acid composition of the oil.
研究了微波预处理和射频预处理对菜籽油品质的影响。油是通过机械压榨从种子中提取出来的。对所得油脂的几个品质参数和种子的特殊酶活性进行了分析。在80至100°C(种子表面温度)的温度下微波应用降低了油中的酸和过氧化值,同时油的颜色强度增加。另一方面,对碘值没有影响。硫代巴比妥酸值(TBA)和油脂的脂肪酸组成也不受影响。种子中过氧化物酶和甲基伞盖酰棕榈酸酯水解酶(MUPase)活性降低,这对种子或油脂的贮藏性和后期加工有重要影响。与微波相比,射频(RF)在120°C下处理油菜籽的优点是没有燃烧香气,可以进一步提高油菜籽的榨油率。尽管温度很高,但处理过的种子的一些油质参数(酸、过氧化物和TBA值)总体上与未处理的相比没有太大变化。像微波一样,射频波不会影响油的脂质酸组成。
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引用次数: 12
The free fatty acid content of fish oil, part V. The effect of microbial contamination on the increase in free fatty acid content of fish oils during storage at 25°C 鱼油的游离脂肪酸含量,第五部分。微生物污染对鱼油在25℃贮藏期间游离脂肪酸含量增加的影响
Pub Date : 1999-05-01 DOI: 10.1002/(SICI)1521-4133(199905)101:5<184::AID-LIPI184>3.0.CO;2-U
A. J. Koning
In this report evidence is presented that the rapid rise in the free fatty acid (FFA) content of fish oils during storage is due to contamination of the oils by bacteria belonging to the genus Alcaligenes. Der Gehalt an freien Fettsauren im Fischol. Teil V. Der Einflus einer Kontamination durch Mikroorganismen auf die Zunahme des Gehalts an freien Fettsauren wahrend der Lagerung bei 25°C.In der vorgliegenden Arbeit wird gezeigt, das der starke Anstieg der freien Fettsauren wahrend der Lagerung von Fischolen eine Folge der Verunreinigung durch Bakterien der Gattung Alcaligenes ist.
这份报告的结论是经过食道的冲力这些脂肪含量在鱼油里一部分的Einflus公元前通过微生物污染增加含丰富的自由Fettsauren,储存在25°C .清理在前面的工作中,科学家发现由于阿尔卡利根属细菌污染,所以块菌含量大增,所以去充饥。
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引用次数: 10
Quantitative determination of tocopherols in single seeds of rapeseed (Brassica napus L.) 油菜单粒种子中生育酚的定量测定
Pub Date : 1999-04-01 DOI: 10.1002/(SICI)1521-4133(199904)101:4<142::AID-LIPI142>3.0.CO;2-J
F. Goffman, L. Velasco, W. Thies
A high-performance liquid chromatography (HPLC) method was developed to determine tocopherols in single seeds of oilseed rape (Brassica napus L.). Single seeds were extracted with isooctane, centrifuged, and the overlayer extract injected into the HPLC instrument without further purification. Separation was performed on a diol-column (250 mm × 3 mm I.D.) using a mobile phase consisting of 94% isooctane and 6% tert-butyl methyl ether. Quantification of individual tocopherols was done by fluorescence detection and with β-tocopherol as internal standard. The standard error (SE) of the present method for total tocopherol content, as determined with 30 ground samples of Samourai (mean = 304 mg kg -1 dry seed) and 20 ground samples of Lirabon (mean = 350 mg kg -1 dry seed), was 9.5 mg tocopherol/kg dry seed. The SEs of the method for the determination of α- and γ-tocopherol percentages were 1.2% and 1.3%, respectively. The low SE values indicate that the method can be effectively used to detect small differences for tocopherol content and composition in studies requiring the analysis of reduced amounts of plant material. In particular, the comparison between the SE of the method and the SD of single seeds within individual plants of Samourai (36.8 mg kg -1 dry seed) and Lirabon (37.6 mg kg -1 dry seed) shows the potential of the present method for the detection of the tocopherol content within plant differences.
建立了高效液相色谱法测定油菜(Brassica napus L.)单粒种子中生育酚的方法。用异辛烷提取单粒种子,离心,不进一步纯化,将外层提取物注入高效液相色谱仪。在二醇柱(250 mm × 3 mm直径)上进行分离,流动相由94%的异辛烷和6%的叔丁基甲基醚组成。以β-生育酚为内标,采用荧光法定量测定单个生育酚。以30份沙乌地(平均304 mg kg -1干种子)和20份利拉贡(平均350 mg kg -1干种子)为样本,本方法测定总生育酚含量的标准误差为9.5 mg /kg干种子。该方法测定α-和γ-生育酚含量的se分别为1.2%和1.3%。低SE值表明,该方法可以有效地用于检测需要分析少量植物材料的生育酚含量和成分的微小差异。特别是,将该方法的SE与Samourai (36.8 mg kg -1干种子)和Lirabon (37.6 mg kg -1干种子)单株内单个种子的SD进行比较,表明了该方法检测植物内生育酚含量差异的潜力。
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引用次数: 43
Investigations on physical refining of animal fats and vegetable oils 动物脂肪和植物油的物理精制研究
Pub Date : 1999-04-01 DOI: 10.1002/(SICI)1521-4133(199904)101:4<138::AID-LIPI138>3.0.CO;2-#
M. Drescher, S. Peter, E. Weidner
Alcohols, polyethyleneglycols, supercritical fluids, and some of their mixtures have been investigated as to their usefulness to purify animal fats and vegetable oils by extraction. The main impurities are free fatty acids. Phase equilibrium was measured as function of temperature and pressure. As primary substances abattoir fat and palm oil were used. Carbon dioxide, dimethylether, and mixtures thereof, likewise methanol and ethanol were tested as extractants for free fatty acids by counter-current extraction in a pilot plant including a high-pressure column and by cross-flow extraction on laboratory scale. With experiments and process simulations including the recovery of the extractants the deacidification of animal fats and vegetable oils was found to be possible. Polyethyleneglycols extract carotenes together with free fatty acids. With the physical refining methods investigated, the formation of waste materials was avoided. Untersuchungen zur physikalischen Raffination tierischer Fette und pflanzlicher Ole. Alkohole, Polyethylenglykole, uberkritische Fluide und einige ihrer Mischungen wurden in Hinsicht auf ihre Eignung zur extraktiven Reinigung von tierischen und pflanzlichen Olen und Fetten untersucht. Die wesentlichen Verunreinigungen sind freie Fettsauren. Die entsprechenden Phasengleichgewichte wurden als Funktion von Temperatur und Druck gemessen. Als Ausgangssubstanzen dienten Schlachtfett und Palmol. Kohlendioxid, Dimethylether und ihre Gemische sowie Methanol und Ethanol wurden als Extraktionsmittel fur freie Fettsauren mit Hilfe einer Gegenstromextraktion in einer Pilotanlage mit einer Hochdruckkolonne getestet und mit Hilfe einer Kreuzstromextraktion im Labormasstab. An Hand von Experimenten und Prozessimulationen, die auch die Entfernung der Losemittel aus Raffinat und Extrakt umfassen, wurde gefunden, das die Entsauerung von tierischen und pflanzlichen Fetten und Olen moglich ist. Polyethylenglycole extrahieren neben den Fettsauren auch die Carotine. Die Entstehung von Abfallstoffen wird bei den untersuchten Verfahrensweisen vermieden.
研究了醇、聚乙二醇、超临界流体和它们的一些混合物在提取纯化动物脂肪和植物油方面的作用。主要的杂质是游离脂肪酸。测定了相平衡随温度和压力的变化。主要物质是屠宰场脂肪和棕榈油。二氧化碳、二甲醚及其混合物、甲醇和乙醇作为游离脂肪酸的萃取剂,在中试装置(包括高压柱)中通过逆流萃取和在实验室规模上通过横流萃取进行了测试。通过实验和工艺模拟,包括提取剂的回收,发现动物脂肪和植物油的脱酸是可能的。聚乙二醇与游离脂肪酸一起提取胡萝卜素。通过对物理精制方法的研究,避免了废料的产生。Untersuchungen zur physikalischen Raffination(推论)醇孔、聚乙烯长烯醇、氢氧化铁流体和氢氧化铁在中国的应用,氢氧化铁和氢氧化铁在中国的应用。Die wesentlichen Verunreinigungen sinfreie Fettsauren。温度与流体动力学的研究。Schlachtfett和Palmol。氢氧化钠,二甲醚,甲醇和乙醇的萃取,氢氧化钠的萃取,氢氧化钠的萃取,氢氧化钠的萃取,氢氧化钠的萃取,氢氧化钠的萃取,氢氧化钠的萃取,氢氧化钠的萃取,氢氧化钠的萃取,氢氧化钠的萃取。a Hand on Experimenten and prozessiationen, die auch die Entfernung der Losemittel ausffinet and Extrakt umfassen, wurde gefunden, das die Entsauerung von tiischen and pflanzlichen Fetten and Olen moglichist。聚乙烯酸盐是一种新型的聚乙烯酸盐。我的意思是,我的意思是我的意思是我的意思是我的意思。
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引用次数: 6
What else besides commodity oils and fats 除了商品油脂还有什么
Pub Date : 1999-04-01 DOI: 10.1002/(SICI)1521-4133(199904)101:4<124::AID-LIPI124>3.0.CO;2-J
F. Gunstone
For over 40 years Oil World publications of Hamburg have provided business data on 17 commercial oils. These include 4 animal fats and 13 vegetable oils from 12 species. But natural oils are seldom optimum for their ultimate human use. This review refers briefly to the technological methods of modifying lipids and describes in more detail five biological procedures by which a wider range of lipids is being developed. These include the domestication of wild crops, the modification of existing crops by seed breeding and by genetic modification, the use of microbial lipids particularly as a source of PUFA, and the modification of triacylglycerol composition by lipase-mediated reaction.
40多年来,汉堡的石油世界出版物提供了17种商业石油的商业数据。其中包括4种动物脂肪和13种来自12种物种的植物油。但天然油很少是人类最终使用的最佳选择。本文简要介绍了脂质改性的技术方法,并详细介绍了开发更广泛的脂质的五种生物学方法。这些包括驯化野生作物,通过种子育种和基因改造改造现有作物,利用微生物脂质,特别是作为多聚脂肪酸的来源,以及通过脂肪酶介导的反应改造三酰基甘油组成。
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引用次数: 15
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Fett-lipid
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