首页 > 最新文献

Frontiers in Environmental Science最新文献

英文 中文
Enhancing the health and wellbeing benefits of biodiversity citizen science 提高生物多样性公民科学对健康和福祉的益处
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-22 DOI: 10.3389/fenvs.2024.1444161
Rachel R. Y. Oh, Richard A. Fuller, Birte Peters, Angela J. Dean, Nancy A. Pachana, Corey T. Callaghan, Nicola J. Sockhill, Aletta Bonn, Andres F. Suarez-Castro
Engagement in biodiversity citizen science initiatives can confer health and wellbeing benefits to individuals and communities. Yet, few biodiversity citizen science initiatives are explicitly planned to optimize health and wellbeing as a potential co-benefit, leading to missed opportunities for biodiversity conservation and human health. In this perspective, we use a dose-response approach to discuss the components that determine how engagement in biodiversity citizen science initiatives map onto opportunities to foster health and wellbeing benefits. We considered aspects related to the duration and frequency of contact with nature, and the intensity of interactions with nature and between individuals to highlight the different health benefits across the variety of citizen science initiatives. To illustrate these aspects, we use a sample of 95 citizen science initiatives from seven English and non-English-speaking countries and show how careful project design can increase the potential to confer health and wellbeing benefits to participants. We conclude with considerations on how to enhance the health and wellbeing benefits from citizen science initiatives, and propose potential research avenues to assess synergies and trade-offs between benefits to biodiversity and human health from these initiatives.
参与生物多样性公民科学计划可为个人和社区带来健康和福利。然而,很少有生物多样性公民科学计划明确将优化健康和福祉作为潜在的共同利益,导致错失生物多样性保护和人类健康的机会。在这一视角中,我们采用剂量-反应方法来讨论决定参与生物多样性公民科学计划如何与促进健康和福利的机会相匹配的因素。我们考虑了与自然接触的持续时间和频率、与自然的互动强度以及个人之间的互动强度等相关方面,以强调各种公民科学活动对健康的不同益处。为了说明这些方面,我们使用了来自七个英语和非英语国家的 95 个公民科学计划样本,并展示了精心的项目设计如何能够提高为参与者带来健康和幸福益处的潜力。最后,我们考虑了如何提高公民科学活动对健康和福祉的益处,并提出了潜在的研究途径,以评估这些活动对生物多样性和人类健康的益处之间的协同作用和权衡。
{"title":"Enhancing the health and wellbeing benefits of biodiversity citizen science","authors":"Rachel R. Y. Oh, Richard A. Fuller, Birte Peters, Angela J. Dean, Nancy A. Pachana, Corey T. Callaghan, Nicola J. Sockhill, Aletta Bonn, Andres F. Suarez-Castro","doi":"10.3389/fenvs.2024.1444161","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1444161","url":null,"abstract":"Engagement in biodiversity citizen science initiatives can confer health and wellbeing benefits to individuals and communities. Yet, few biodiversity citizen science initiatives are explicitly planned to optimize health and wellbeing as a potential co-benefit, leading to missed opportunities for biodiversity conservation and human health. In this perspective, we use a dose-response approach to discuss the components that determine how engagement in biodiversity citizen science initiatives map onto opportunities to foster health and wellbeing benefits. We considered aspects related to the duration and frequency of contact with nature, and the intensity of interactions with nature and between individuals to highlight the different health benefits across the variety of citizen science initiatives. To illustrate these aspects, we use a sample of 95 citizen science initiatives from seven English and non-English-speaking countries and show how careful project design can increase the potential to confer health and wellbeing benefits to participants. We conclude with considerations on how to enhance the health and wellbeing benefits from citizen science initiatives, and propose potential research avenues to assess synergies and trade-offs between benefits to biodiversity and human health from these initiatives.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"37 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142209841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Use of graphene oxide for the removal of norfloxacin and ceftriaxone antibiotics from aqueous solution: process optimization using response surface approach 利用氧化石墨烯去除水溶液中的诺氟沙星和头孢曲松抗生素:采用响应面法优化工艺
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-22 DOI: 10.3389/fenvs.2024.1436848
Zhihui Li, Shuhang Zhang, Guina Zhu, Jie Xing
In this research, graphene oxide (GO) as an adsorbent was used to remove norfloxacin and ceftriaxone antibiotics from aqueous solutions. All environmental factors affecting removal (e.g., pH, adsorbent mass, contact time, and concentration) were optimized in a discontinuous system. The design of experiments and the optimization of variables were carried out using the response surface method (RSM). The results of the analysis of variance (ANOVA) and the regression coefficients of the quadratic terms indicated that the responses were significantly affected by all the studied variables (P < 0.05). Also, the quadratic polynomial model results corresponded to empirical data with a high coefficient of determination (i.e., R2 ˃ 0.99 for both antibiotics). Besides, the adjusted R2 (R2-adj ˃ 0.98 for both antibiotics) was close to R2 values, indicating a good and acceptable statistical model. According to the results, the optimal removal of antibiotics by GO occurs in conditions of pH of 8, 0.034 g of the adsorbent mass, a sonication time of 20 min, and a concentration of 25 mg L−1. In these conditions, the maximum removal efficiencies of ceftriaxone and norfloxacin were equal to 95.87% and 98.64%, respectively. GO was recovered in five adsorption/desorption processes, and the removal efficiency declined very slightly after using the adsorbent for five cycles. Therefore, it is concluded that GO is an efficient and acceptable adsorbent for removing ceftriaxone and norfloxacin from aqueous environments.
本研究使用氧化石墨烯(GO)作为吸附剂来去除水溶液中的诺氟沙星和头孢曲松抗生素。在不连续系统中,对所有影响去除的环境因素(如 pH 值、吸附剂质量、接触时间和浓度)进行了优化。实验设计和变量优化采用响应面法(RSM)进行。方差分析(ANOVA)和二次项回归系数的结果表明,反应受到所有研究变量的显著影响(P < 0.05)。同时,二次多项式模型结果与经验数据相符,具有较高的决定系数(即两种抗生素的 R2 ˃ 0.99)。此外,调整后的 R2(两种抗生素的 R2-adj ˃0.98)也接近 R2 值,表明这是一个良好的、可接受的统计模型。结果表明,在 pH 值为 8、吸附剂质量为 0.034 克、超声时间为 20 分钟、浓度为 25 毫克/升的条件下,GO 对抗生素的去除效果最佳。在这些条件下,头孢曲松和诺氟沙星的最大去除率分别为 95.87% 和 98.64%。在五个吸附/解吸过程中,GO 都得到了回收,在使用该吸附剂五个周期后,去除率略有下降。因此,可以得出结论:GO 是一种从水环境中去除头孢曲松和诺氟沙星的高效、可接受的吸附剂。
{"title":"Use of graphene oxide for the removal of norfloxacin and ceftriaxone antibiotics from aqueous solution: process optimization using response surface approach","authors":"Zhihui Li, Shuhang Zhang, Guina Zhu, Jie Xing","doi":"10.3389/fenvs.2024.1436848","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1436848","url":null,"abstract":"In this research, graphene oxide (GO) as an adsorbent was used to remove norfloxacin and ceftriaxone antibiotics from aqueous solutions. All environmental factors affecting removal (e.g., pH, adsorbent mass, contact time, and concentration) were optimized in a discontinuous system. The design of experiments and the optimization of variables were carried out using the response surface method (RSM). The results of the analysis of variance (ANOVA) and the regression coefficients of the quadratic terms indicated that the responses were significantly affected by all the studied variables (<jats:italic>P</jats:italic> &amp;lt; 0.05). Also, the quadratic polynomial model results corresponded to empirical data with a high coefficient of determination (i.e., R<jats:sup>2</jats:sup> ˃ 0.99 for both antibiotics). Besides, the adjusted R<jats:sup>2</jats:sup> (R<jats:sup>2</jats:sup>-adj ˃ 0.98 for both antibiotics) was close to R<jats:sup>2</jats:sup> values, indicating a good and acceptable statistical model. According to the results, the optimal removal of antibiotics by GO occurs in conditions of pH of 8, 0.034 g of the adsorbent mass, a sonication time of 20 min, and a concentration of 25 mg L<jats:sup>−1</jats:sup>. In these conditions, the maximum removal efficiencies of ceftriaxone and norfloxacin were equal to 95.87% and 98.64%, respectively. GO was recovered in five adsorption/desorption processes, and the removal efficiency declined very slightly after using the adsorbent for five cycles. Therefore, it is concluded that GO is an efficient and acceptable adsorbent for removing ceftriaxone and norfloxacin from aqueous environments.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"56 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142209842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing towards a low-carbon urban future in China: the role of producer services agglomeration 中国城市迈向低碳未来:生产者服务集聚区的作用
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-22 DOI: 10.3389/fenvs.2024.1458029
Shuyang Zhu
The reduction of greenhouse gas emissions is a shared challenge encountered by nations worldwide. As China is on its way toward a green economy, it is worth studying whether producer services agglomeration, a key driver of economic transition, can promote low-carbon urban development. Using panel data of 257 cities across China from 2006 to 2019, this paper examines the influence of producer services agglomeration on urban carbon emissions with spatial econometric models. The findings reveal a positive spatial correlation in regional carbon emissions. The agglomeration of producer services notably decreases the intensity of local carbon emissions, yet it appears to have minimal influence on the emissions from adjacent regions. Enhancing energy efficiency and adjusting the industrial structure are two critical mechanisms by which producer services agglomeration reduces urban carbon emissions. This beneficial effect varies with city type, the abatement effect of producer services agglomeration is more pronounced in non-resource-based cities. When considering city size, the carbon reduction potential of producer services agglomeration is not apparent in smaller cities. As city size increases, the emission reduction effect becomes more apparent. However, in mega-cities, this impact is somewhat diminished. Accordingly, this paper proposes exploring methods of coordinated air pollution management across cities, promoting producer services agglomeration in line with market mechanisms, and driving low-carbon urban development in a manner tailored to local conditions.
减少温室气体排放是世界各国共同面临的挑战。在中国迈向绿色经济的道路上,生产性服务业集聚作为经济转型的重要驱动力,能否促进城市低碳发展值得研究。本文利用 2006 年至 2019 年中国 257 个城市的面板数据,通过空间计量经济模型研究了生产者服务业集聚对城市碳排放的影响。研究结果表明,区域碳排放存在正空间相关性。生产性服务业集聚显著降低了当地的碳排放强度,但似乎对相邻地区的碳排放影响甚微。提高能源效率和调整产业结构是生产者服务业集聚减少城市碳排放的两个关键机制。这种有利效应因城市类型而异,在非资源型城市,生产者服务业集聚的减排效应更为明显。如果考虑城市规模,生产者服务业集聚的碳减排潜力在规模较小的城市并不明显。随着城市规模的扩大,减排效应会更加明显。然而,在特大城市,这种影响会有所减弱。因此,本文建议探索跨城市大气污染协同治理的方法,按照市场机制促进生产者服务业集聚,因地制宜地推动城市低碳发展。
{"title":"Advancing towards a low-carbon urban future in China: the role of producer services agglomeration","authors":"Shuyang Zhu","doi":"10.3389/fenvs.2024.1458029","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1458029","url":null,"abstract":"The reduction of greenhouse gas emissions is a shared challenge encountered by nations worldwide. As China is on its way toward a green economy, it is worth studying whether producer services agglomeration, a key driver of economic transition, can promote low-carbon urban development. Using panel data of 257 cities across China from 2006 to 2019, this paper examines the influence of producer services agglomeration on urban carbon emissions with spatial econometric models. The findings reveal a positive spatial correlation in regional carbon emissions. The agglomeration of producer services notably decreases the intensity of local carbon emissions, yet it appears to have minimal influence on the emissions from adjacent regions. Enhancing energy efficiency and adjusting the industrial structure are two critical mechanisms by which producer services agglomeration reduces urban carbon emissions. This beneficial effect varies with city type, the abatement effect of producer services agglomeration is more pronounced in non-resource-based cities. When considering city size, the carbon reduction potential of producer services agglomeration is not apparent in smaller cities. As city size increases, the emission reduction effect becomes more apparent. However, in mega-cities, this impact is somewhat diminished. Accordingly, this paper proposes exploring methods of coordinated air pollution management across cities, promoting producer services agglomeration in line with market mechanisms, and driving low-carbon urban development in a manner tailored to local conditions.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"3 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142209844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of an evaluation system for the effectiveness of rural sewage treatment facilities and empirical research 农村污水处理设施效果评价体系的构建与实证研究
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-22 DOI: 10.3389/fenvs.2024.1430068
Yuxiao He, Lu Yang, Huashan Xu, Xu Han, Changlei Sun, Yanming Di, Tongqian Zhao
IntroductionRural domestic sewage treatment is an important starting point to improve the quality of the rural ecological environment, an important part of new rural construction, and an inherent requirement to promote rural economic development. The operation of rural sewage treatment facilities is not good, and there is a lack of long-term operation guarantees and supervision mechanisms. It is urgent to carry out research on the evaluation index system, evaluation method, and evaluation benchmark of the operational effectiveness of rural sewage treatment facilities.MethodsThis article used rural sewage treatment facilities in a city in northern China as the research object and constructed an evaluation method for the operational effectiveness of rural sewage treatment facilities. This study selected evaluation indexes from three perspectives, namely, economy, technology, and management, which are divided into two stages, namely, planning and operation. A judgment matrix was constructed using the analytic hierarchy process (AHP), and index weights were calculated using Yaahp10.3 software to determine the evaluation criteria. Fifteen rural sewage treatment plant stations were selected to evaluate their planning and operation effectiveness.ResultsThe results of the weight assignment show that the weight of the COD removal rate, operating load rate, and operating cost indexes are high, which is in line with the actual evaluation of the effectiveness of rural sewage treatment facilities at different stages. The empirical calculation results showed that the rural sewage treatment facilities have a comprehensive score of more than 80 points in 7 cases and 60–80 points in 8 cases, with an average score of 79.05 points; the overall performance of the score in the operation stage was better than that in the planning stage, and the overall operation effect was good.DiscussionThe calculation results were consistent with the actual operation, verifying the scientific nature and availability of the selected indices, the evaluation method constructed, and the evaluation benchmark determined. The research results can provide technical methods for evaluating the operational effectiveness of rural sewage treatment facilities in similar areas and provide technical support for the planning, design, optimization, upgrading, and transformation of rural sewage treatment plants.
引言农村生活污水处理是改善农村生态环境质量的重要抓手,是新农村建设的重要内容,也是促进农村经济发展的内在要求。农村生活污水处理设施运行状况不容乐观,缺乏长效运行保障和监管机制。方法本文以我国北方某市农村污水处理设施为研究对象,构建了农村污水处理设施运行效果评价方法。本研究从经济、技术、管理三个角度选取评价指标,分为规划和运行两个阶段。利用层次分析法(AHP)构建了判断矩阵,并利用 Yaahp10.3 软件计算了指标权重,确定了评价标准。结果权重赋值结果表明,COD去除率、运行负荷率、运行成本指标权重较高,符合农村污水处理设施不同阶段效果评价的实际情况。实证计算结果表明,农村污水处理设施综合得分在80分以上的有7个,60-80分的有8个,平均得分79.05分;运行阶段得分总体表现优于规划阶段,总体运行效果良好。讨论计算结果与实际运行情况一致,验证了所选指标、构建的评价方法、确定的评价基准的科学性和可用性。研究成果可为类似地区农村污水处理设施运行效果评价提供技术方法,为农村污水处理厂的规划、设计、优化、提标、改造等提供技术支持。
{"title":"Construction of an evaluation system for the effectiveness of rural sewage treatment facilities and empirical research","authors":"Yuxiao He, Lu Yang, Huashan Xu, Xu Han, Changlei Sun, Yanming Di, Tongqian Zhao","doi":"10.3389/fenvs.2024.1430068","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1430068","url":null,"abstract":"IntroductionRural domestic sewage treatment is an important starting point to improve the quality of the rural ecological environment, an important part of new rural construction, and an inherent requirement to promote rural economic development. The operation of rural sewage treatment facilities is not good, and there is a lack of long-term operation guarantees and supervision mechanisms. It is urgent to carry out research on the evaluation index system, evaluation method, and evaluation benchmark of the operational effectiveness of rural sewage treatment facilities.MethodsThis article used rural sewage treatment facilities in a city in northern China as the research object and constructed an evaluation method for the operational effectiveness of rural sewage treatment facilities. This study selected evaluation indexes from three perspectives, namely, economy, technology, and management, which are divided into two stages, namely, planning and operation. A judgment matrix was constructed using the analytic hierarchy process (AHP), and index weights were calculated using Yaahp10.3 software to determine the evaluation criteria. Fifteen rural sewage treatment plant stations were selected to evaluate their planning and operation effectiveness.ResultsThe results of the weight assignment show that the weight of the COD removal rate, operating load rate, and operating cost indexes are high, which is in line with the actual evaluation of the effectiveness of rural sewage treatment facilities at different stages. The empirical calculation results showed that the rural sewage treatment facilities have a comprehensive score of more than 80 points in 7 cases and 60–80 points in 8 cases, with an average score of 79.05 points; the overall performance of the score in the operation stage was better than that in the planning stage, and the overall operation effect was good.DiscussionThe calculation results were consistent with the actual operation, verifying the scientific nature and availability of the selected indices, the evaluation method constructed, and the evaluation benchmark determined. The research results can provide technical methods for evaluating the operational effectiveness of rural sewage treatment facilities in similar areas and provide technical support for the planning, design, optimization, upgrading, and transformation of rural sewage treatment plants.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"6 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142209840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced photochemical formation of active nitrogen species from aqueous nitrate in the presence of halide ions 在卤化物离子存在的情况下,硝酸盐水溶液中活性氮物质的光化学形成得到增强
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-22 DOI: 10.3389/fenvs.2024.1466512
Yilong Zhao, Chengwei Liu, Xiang Tu, Wenkai Huang, Yu Liu, Hongbo Fu
Field observations have confirmed that halide ions are widely distributed among aerosols from the marine boundary layer and on the surfaces of ice and snow in polar regions. Consequently, the coexistence of halide ions may play a more significant role in nitrate photolysis than previously thought. In this study, we simultaneously measured HONO, NO2, and NO2in situ to gain a deeper understanding of the coexisting system, including the photogenerated nitrogen products and the effects on nitrate photolysis rates due to enhanced aqueous nitrite and HONO transfer rates by halides. The presence of halides significantly increased the photogenerated nitrogen products across various molar ratios ([X]/[NO3]) at pH 3.5. By eliminating oxygen flux, the transformation of the primary photogenerated products was affected, resulting in higher concentrations of N(III) as both HONO and NO2. Experiments involving OH scavengers indicated that the attack from·OH initiated by halides leads to side reactions that enhance nitrate photolysis. Both theoretical calculations and nitrate actinometry were used to determine the photolysis rate of nitrate solutions, which together indicated that the presence of halides enhances nitrate photolysis. A newly developed model was used to determine the HONO transfer rate, finding that the presence of halides ([X]/[NO3] = 0.2) enhanced the evaporation of N(III) in solution by factors of 0.68, 0.95, and 1.27 for Cl, Br, and I, respectively. To our knowledge, this is the first determination of halide effects on the mass transfer of HONO. The enhanced nitrate photolysis rate can be attributed to the differential surface effects of halides and parallel reactions initiated via ·OH stemming from nitrate photolysis, with varying rates leading to different quantities of nitrogenous products. Additionally, simultaneous measurements of photoproducts in both gas and condensed phases are recommended to better constrain the rate constants of NO3 photolysis.
实地观测证实,卤化离子广泛分布于海洋边界层气溶胶和极地冰雪表面。因此,卤化离子的共存可能在硝酸盐光解过程中发挥着比以前想象的更重要的作用。在这项研究中,我们同时对 HONO、NO2 和 NO2 进行了现场测量,以深入了解共存系统,包括光生成的氮产物以及卤化物增强水体亚硝酸盐和 HONO 转移率对硝酸盐光解率的影响。在 pH 值为 3.5 时,不同摩尔比([X-]/[NO3-])下,卤化物的存在明显增加了光生氮产物。通过消除氧通量,主要光生产物的转化受到了影响,导致以 HONO 和 NO2- 形式存在的 N(III)浓度升高。涉及羟基清除剂的实验表明,由卤化物引发的羟基攻击会导致副反应,从而增强硝酸盐的光解作用。理论计算和硝酸盐光度测定法都被用来确定硝酸盐溶液的光解速率,它们共同表明卤化物的存在会增强硝酸盐的光解。利用新开发的模型确定了 HONO 的转移率,发现卤化物的存在([X-]/[NO3-] = 0.2)增强了溶液中 N(III)的蒸发,Cl-、Br- 和 I- 的系数分别为 0.68、0.95 和 1.27。据我们所知,这是首次测定卤化物对 HONO 质量转移的影响。硝酸盐光解速率的提高可归因于卤化物的不同表面效应以及硝酸盐光解产生的-OH引发的平行反应,不同的速率会产生不同数量的含氮产物。此外,建议同时测量气相和凝聚相中的光产物,以便更好地确定 NO3- 光解的速率常数。
{"title":"Enhanced photochemical formation of active nitrogen species from aqueous nitrate in the presence of halide ions","authors":"Yilong Zhao, Chengwei Liu, Xiang Tu, Wenkai Huang, Yu Liu, Hongbo Fu","doi":"10.3389/fenvs.2024.1466512","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1466512","url":null,"abstract":"Field observations have confirmed that halide ions are widely distributed among aerosols from the marine boundary layer and on the surfaces of ice and snow in polar regions. Consequently, the coexistence of halide ions may play a more significant role in nitrate photolysis than previously thought. In this study, we simultaneously measured HONO, NO<jats:sub>2</jats:sub>, and NO<jats:sub>2</jats:sub><jats:sup>−</jats:sup><jats:italic>in situ</jats:italic> to gain a deeper understanding of the coexisting system, including the photogenerated nitrogen products and the effects on nitrate photolysis rates due to enhanced aqueous nitrite and HONO transfer rates by halides. The presence of halides significantly increased the photogenerated nitrogen products across various molar ratios ([X<jats:sup>–</jats:sup>]/[NO<jats:sub>3</jats:sub><jats:sup>−</jats:sup>]) at pH 3.5. By eliminating oxygen flux, the transformation of the primary photogenerated products was affected, resulting in higher concentrations of N(III) as both HONO and NO<jats:sub>2</jats:sub><jats:sup>−</jats:sup>. Experiments involving OH scavengers indicated that the attack from·OH initiated by halides leads to side reactions that enhance nitrate photolysis. Both theoretical calculations and nitrate actinometry were used to determine the photolysis rate of nitrate solutions, which together indicated that the presence of halides enhances nitrate photolysis. A newly developed model was used to determine the HONO transfer rate, finding that the presence of halides ([X<jats:sup>–</jats:sup>]/[NO<jats:sub>3</jats:sub><jats:sup>−</jats:sup>] = 0.2) enhanced the evaporation of N(III) in solution by factors of 0.68, 0.95, and 1.27 for Cl<jats:sup>−</jats:sup>, Br<jats:sup>−</jats:sup>, and I<jats:sup>−</jats:sup>, respectively. To our knowledge, this is the first determination of halide effects on the mass transfer of HONO. The enhanced nitrate photolysis rate can be attributed to the differential surface effects of halides and parallel reactions initiated via ·OH stemming from nitrate photolysis, with varying rates leading to different quantities of nitrogenous products. Additionally, simultaneous measurements of photoproducts in both gas and condensed phases are recommended to better constrain the rate constants of NO<jats:sub>3</jats:sub><jats:sup>−</jats:sup> photolysis.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"47 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142209839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microbiome analyses of the Uraim River in the Amazon and georeferencing analyses to establish correlation with anthropogenic impacts of land use 对亚马逊乌拉伊姆河进行微生物组分析,并进行地理坐标分析,以确定与土地使用的人为影响之间的相关性
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-09 DOI: 10.3389/fenvs.2024.1404230
Oscar Victor Cardenas-Alegria, Victor Benedito Costa Ferreira, Wylerson Guimarães Noguera, David Tavares Martins, Artur Pedro Martins Neto, Paulo Rógenes Monteiro Pontes, Rosane Barbosa Lopes Cavalcante, Sandy Ingrid Aguiar Alves, Artur Luiz da Costa da Silva, Rosilene Gomes Costa, Edian Franklin Franco de Los Santos, Vasco Ariston de Carvalho Azevedo, Rommel Thiago Juca Ramos
One of the primary challenges in the spread of infectious diseases is the consumption of poorly or untreated water, which is increasingly being used due to the growth of different human activities and the effect of urbanization on freshwater sources, which are often used for consumption purposes. The determination of pathogenic bacteria in freshwater rivers influenced by anthropogenic activities allows for the assessment of the impact these factors have on water quality. Thus, the purpose of this study was to identify the diversity of pathogenic bacteria and virulence genes in the Uraim River in the northern region of Brazil. For this purpose, surface water was collected from five points with varying degrees of anthropogenic impact along the Uraim River. In situ measurements of physicochemical components were conducted, and metagenomic analysis was used for the identification of pathogenic bacteria and virulence genes. Regarding the physicochemical parameters, variability was observed among the different analysis points, as well as diversity among bacteria and virulence genes. Notably, enterobacteria and the ESKAPE group were highlighted among the bacteria, with significant negative associations found between dissolved oxygen and the diversity of virulence genes and between deforestation and population density with the presence of ESKAPE group bacteria.
传染病传播的主要挑战之一是饮用劣质或未经处理的水,由于各种人类活动的增长和城市化对淡水水源的影响,人们越来越多地使用淡水,而淡水通常被用于消费目的。通过测定受人类活动影响的淡水河流中的病原菌,可以评估这些因素对水质的影响。因此,本研究的目的是确定巴西北部地区乌莱姆河中致病菌的多样性和毒力基因。为此,研究人员从乌莱姆河沿岸受到不同程度人为影响的五个点采集地表水。对理化成分进行了现场测量,并利用元基因组分析鉴定了病原菌和毒力基因。在理化参数方面,不同分析点之间存在差异,细菌和毒力基因之间也存在多样性。值得注意的是,细菌中突出的是肠杆菌和 ESKAPE 组,发现溶解氧与毒力基因的多样性之间存在显著的负相关,森林砍伐和种群密度与 ESKAPE 组细菌的存在之间存在显著的负相关。
{"title":"Microbiome analyses of the Uraim River in the Amazon and georeferencing analyses to establish correlation with anthropogenic impacts of land use","authors":"Oscar Victor Cardenas-Alegria, Victor Benedito Costa Ferreira, Wylerson Guimarães Noguera, David Tavares Martins, Artur Pedro Martins Neto, Paulo Rógenes Monteiro Pontes, Rosane Barbosa Lopes Cavalcante, Sandy Ingrid Aguiar Alves, Artur Luiz da Costa da Silva, Rosilene Gomes Costa, Edian Franklin Franco de Los Santos, Vasco Ariston de Carvalho Azevedo, Rommel Thiago Juca Ramos","doi":"10.3389/fenvs.2024.1404230","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1404230","url":null,"abstract":"One of the primary challenges in the spread of infectious diseases is the consumption of poorly or untreated water, which is increasingly being used due to the growth of different human activities and the effect of urbanization on freshwater sources, which are often used for consumption purposes. The determination of pathogenic bacteria in freshwater rivers influenced by anthropogenic activities allows for the assessment of the impact these factors have on water quality. Thus, the purpose of this study was to identify the diversity of pathogenic bacteria and virulence genes in the Uraim River in the northern region of Brazil. For this purpose, surface water was collected from five points with varying degrees of anthropogenic impact along the Uraim River. <jats:italic>In situ</jats:italic> measurements of physicochemical components were conducted, and metagenomic analysis was used for the identification of pathogenic bacteria and virulence genes. Regarding the physicochemical parameters, variability was observed among the different analysis points, as well as diversity among bacteria and virulence genes. Notably, enterobacteria and the ESKAPE group were highlighted among the bacteria, with significant negative associations found between dissolved oxygen and the diversity of virulence genes and between deforestation and population density with the presence of ESKAPE group bacteria.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"213 6 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141934419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Byte-Sized Finance, Bushel-Sized Benefits: unraveling digital financial inclusion impact on China’s agricultural green development 字节级金融,蒲式耳级效益:解读数字普惠金融对中国农业绿色发展的影响
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-08 DOI: 10.3389/fenvs.2024.1411866
Ludan Zhang, Yanbin Qi, Xin Deng
IntroductionChina’s rural financial landscape has long been characterized by exclusion, leaving countless farmers without access to essential financial services. However, the advent of digital financial inclusion presents a promising solution, offering low-cost, high-penetration avenues to bolster agricultural sustainability. This paper unravels how “Byte-Sized Finance” can yield “Bushel-Sized Benefits” in China’s agricultural green development.MethodsMethodologically, we pioneer a novel system to gauge agricultural green development across 31 Chinese provinces spanning from 2013 to 2021. Empirically, employing fixed-effect, mediation effect, and spatial Durbin models.ResultsOur study reveals the intricate pathways through which digital financial inclusion influences agricultural green development. We find that it exerts its impact through the lenses of industrial structure and entrepreneurship, operating at both macro and micro levels. Furthermore, our analysis uncovers spatial spillover effects, shedding light on the differential roles played by these mechanisms across regions.DiscussionThis groundbreaking discovery underscores the transformative potential of leveraging digital financial inclusion to propel China toward agricultural green development. By shedding light on these crucial dynamics, our findings offer insights for policymakers, researchers, and practitioners striving to foster sustainability within China’s agricultural sector.
导言:长期以来,中国的农村金融环境一直存在排斥现象,导致无数农民无法获得基本的金融服务。然而,数字普惠金融的出现提供了一个前景广阔的解决方案,为促进农业可持续发展提供了低成本、高渗透率的途径。本文揭示了 "字节级金融 "如何在中国农业绿色发展中产生 "蒲式耳级效益"。方法从方法论上讲,我们开创了一种新的系统来衡量中国 31 个省份从 2013 年到 2021 年的农业绿色发展情况。结果我们的研究揭示了数字普惠金融影响农业绿色发展的复杂路径。我们发现,数字普惠金融通过产业结构和创业精神的视角,在宏观和微观两个层面上产生影响。此外,我们的分析还发现了空间溢出效应,揭示了这些机制在不同地区发挥的不同作用。 讨论这一突破性发现强调了利用数字普惠金融推动中国农业绿色发展的变革潜力。通过揭示这些关键的动态变化,我们的发现为努力促进中国农业部门可持续发展的政策制定者、研究人员和从业人员提供了启示。
{"title":"Byte-Sized Finance, Bushel-Sized Benefits: unraveling digital financial inclusion impact on China’s agricultural green development","authors":"Ludan Zhang, Yanbin Qi, Xin Deng","doi":"10.3389/fenvs.2024.1411866","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1411866","url":null,"abstract":"IntroductionChina’s rural financial landscape has long been characterized by exclusion, leaving countless farmers without access to essential financial services. However, the advent of digital financial inclusion presents a promising solution, offering low-cost, high-penetration avenues to bolster agricultural sustainability. This paper unravels how “Byte-Sized Finance” can yield “Bushel-Sized Benefits” in China’s agricultural green development.MethodsMethodologically, we pioneer a novel system to gauge agricultural green development across 31 Chinese provinces spanning from 2013 to 2021. Empirically, employing fixed-effect, mediation effect, and spatial Durbin models.ResultsOur study reveals the intricate pathways through which digital financial inclusion influences agricultural green development. We find that it exerts its impact through the lenses of industrial structure and entrepreneurship, operating at both macro and micro levels. Furthermore, our analysis uncovers spatial spillover effects, shedding light on the differential roles played by these mechanisms across regions.DiscussionThis groundbreaking discovery underscores the transformative potential of leveraging digital financial inclusion to propel China toward agricultural green development. By shedding light on these crucial dynamics, our findings offer insights for policymakers, researchers, and practitioners striving to foster sustainability within China’s agricultural sector.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"41 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141934496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Woodland expansion and upland management strategy dilemmas for biodiversity and carbon storage in the Cairngorms national park 林地扩张和高地管理战略对凯恩戈姆国家公园生物多样性和碳储存的困境
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-07 DOI: 10.3389/fenvs.2024.1411659
Michel Valette, Scott Newey, Kate Schreckenberg, Terence P. Dawson
Nature-based solutions are increasingly advocated to mitigate climate change and biodiversity loss, while improving ecosystem resilience and providing additional ecosystem services. In Scotland, woodland expansion and restoration of degraded peatlands are expected to play a major role in meeting net-zero emissions by 2045 and have prompted debates about the impact of increased woodland cover and prescribed fire on the biodiversity and ecosystem services provided by upland landscapes. In alignment with national policy, the Cairngorms National Park, the UK’s largest national park, has committed to an ambitious programme of woodland expansion and peatland restoration in a landscape dominated by heather moorlands that is predominantly managed through prescribed burning for game management. Using the Native Woodland Model and the InVest modelling platform, we assessed the effects of five land cover and land use change scenarios, with different levels of prescribed fire regulation and woodland expansion, to evaluate their benefits and costs on biodiversity and carbon sequestration. Results show that changing the extent and management of habitats will result in different carbon sequestration pathways, as well as biodiversity winners and losers. The scenario presenting greater benefits for the conservation of biodiversity also has lower above-ground carbon sequestration potential and a larger negative impact on red grouse habitats, thus being less profitable to sporting estates. Hence, trade-offs will be necessary to achieve optimal carbon sequestration and biodiversity gains, with a potential role played by the continuation of prescribed fires and traditional moorland management practices as well as complementary grants and support measures based on biodiversity benefits rather than carbon sequestration. The results from this study could support discussions regarding future management of the uplands, trade-offs between loss of carbon in soils, carbon sequestration in woodlands and conservation of biodiversity, as well as stakeholders likely to be affected.
人们越来越多地提倡以自然为基础的解决方案,以减缓气候变化和生物多样性的丧失,同时提高生态系统的恢复能力并提供额外的生态系统服务。在苏格兰,林地的扩大和退化泥炭地的恢复预计将在 2045 年实现净零排放方面发挥重要作用,这也引发了关于增加林地覆盖率和明火对高地景观所提供的生物多样性和生态系统服务的影响的讨论。为了与国家政策保持一致,英国最大的国家公园--凯恩戈姆国家公园(Cairngorms National Park)已承诺在以石楠荒地为主的地貌中实施一项雄心勃勃的林地扩展和泥炭地恢复计划,该地貌主要通过规定的焚烧进行野味管理。利用原生林地模型和 InVest 建模平台,我们评估了五种土地覆盖和土地利用变化情景的影响,以及不同程度的规定焚烧管理和林地扩展,以评估其对生物多样性和碳封存的效益和成本。结果表明,改变栖息地的范围和管理将导致不同的碳封存途径,以及生物多样性的赢家和输家。对保护生物多样性有更大益处的方案,其地面固碳潜力也较低,对红松鸡栖息地的负面影响也较大,因此对体育庄园来说利润较低。因此,为了实现最佳固碳效果和生物多样性收益,有必要进行权衡,而继续使用规定的火种和传统的荒地管理方法以及基于生物多样性收益而非固碳效果的补充补助和支持措施则有可能发挥作用。这项研究的结果将有助于讨论高地的未来管理、土壤碳损失、林地碳固存和生物多样性保护之间的权衡以及可能受到影响的利益相关者。
{"title":"Woodland expansion and upland management strategy dilemmas for biodiversity and carbon storage in the Cairngorms national park","authors":"Michel Valette, Scott Newey, Kate Schreckenberg, Terence P. Dawson","doi":"10.3389/fenvs.2024.1411659","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1411659","url":null,"abstract":"Nature-based solutions are increasingly advocated to mitigate climate change and biodiversity loss, while improving ecosystem resilience and providing additional ecosystem services. In Scotland, woodland expansion and restoration of degraded peatlands are expected to play a major role in meeting net-zero emissions by 2045 and have prompted debates about the impact of increased woodland cover and prescribed fire on the biodiversity and ecosystem services provided by upland landscapes. In alignment with national policy, the Cairngorms National Park, the UK’s largest national park, has committed to an ambitious programme of woodland expansion and peatland restoration in a landscape dominated by heather moorlands that is predominantly managed through prescribed burning for game management. Using the Native Woodland Model and the InVest modelling platform, we assessed the effects of five land cover and land use change scenarios, with different levels of prescribed fire regulation and woodland expansion, to evaluate their benefits and costs on biodiversity and carbon sequestration. Results show that changing the extent and management of habitats will result in different carbon sequestration pathways, as well as biodiversity winners and losers. The scenario presenting greater benefits for the conservation of biodiversity also has lower above-ground carbon sequestration potential and a larger negative impact on red grouse habitats, thus being less profitable to sporting estates. Hence, trade-offs will be necessary to achieve optimal carbon sequestration and biodiversity gains, with a potential role played by the continuation of prescribed fires and traditional moorland management practices as well as complementary grants and support measures based on biodiversity benefits rather than carbon sequestration. The results from this study could support discussions regarding future management of the uplands, trade-offs between loss of carbon in soils, carbon sequestration in woodlands and conservation of biodiversity, as well as stakeholders likely to be affected.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"57 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141934493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of autumn tillage with straw return on soil physical characteristics of corn fields in the eastern loess plateau 秸秆还田秋耕对东部黄土高原玉米田土壤物理特征的影响
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-07 DOI: 10.3389/fenvs.2024.1362616
Yuchen Fan, Yaqi Yuan, Tao Li, Wen Lin, Xiwang Tang, Gaimei Liang, Nana Li
The implementation of unsuitable tillage practices has the potential to disrupt the structure integrity of the ploughed layer, as well as to influence the physical parameters of the soil. The application of a reasonable tillage method has been demonstrated to result in an improvement in the physical quality of the soil. Three autumn tillage practices have been implemented at the Dongyang Experimental Station of Shanxi Agricultural University since 2016: no-tillage with straw mulch (NTS), autumn rotary tillage with straw incorporation (RTS), and autumn plough tillage with straw incorporation (PTS). The impact of autumn tillage practices on soil physical quality in the 0–30 cm profile of spring corn fields was evaluated following the corn harvest in 2018 and 2019. The results showed that compared to the NTS treatment, the application of RTS was found to have decreased significantly by 9.6%–24.2% in soil bulk density, while it increased significantly by 12.8%–34.0% in total porosity and by 43.5%–146.4% in macroporosity at a depth of 5–10 cm. In comparison to the NTS treatment, the adoption of PTS was found to decrease significantly by 10.7%–30.5% soil bulk density, while it increased significantly by 9.9%–42.7% the total porosity and 23.1%–202.8% the macroporosity at a depth of 0–10 cm. Furthermore, the soil microporosity significantly increase of 7.5%–11.1% under the RTS treatment at the 0–5 cm soil depth and 7.7%–11.2% under the PTS treatment at the 10–20 cm soil depth. Soil physical quality index (SQI) significantly increase under the RTS and PTS treatments, with a 41.26% and 57.57% improvement, respectively, in comparison to the NTS treatment. In summary, the adoption of autumn tillage with straw return (RTS and PTS) demonstrated a reduction in soil bulk density, an increase in soil porosity, macroporosity, and a promotion of capillary porosity, and promoted the improvement of soil physical quality on the Eastern Loess Plateau when compared to no-tillage with straw mulch (NTS).
采用不合适的耕作方法有可能破坏耕作层结构的完整性,并影响土壤的物理参数。实践证明,采用合理的耕作方法可以改善土壤的物理质量。山西农业大学东阳试验站自 2016 年起实施了三种秋耕方式:秸秆覆盖免耕(NTS)、秸秆掺入秋旋耕(RTS)和秸秆掺入秋犁耕(PTS)。在 2018 年和 2019 年玉米收获后,评估了秋季耕作方法对春玉米田 0-30 厘米剖面土壤物理质量的影响。结果表明,与NTS处理相比,施用RTS后,土壤容重显著降低了9.6%-24.2%,而在5-10厘米深度处,土壤总孔隙度显著增加了12.8%-34.0%,大孔隙度显著增加了43.5%-146.4%。与 NTS 处理相比,采用 PTS 后,土壤容重显著降低了 10.7%-30.5%,而 0-10 厘米深度的总孔隙度显著增加了 9.9%-42.7%,大孔隙度显著增加了 23.1%-202.8%。此外,在 RTS 处理下,0-5 厘米土壤深度的土壤微孔显著增加了 7.5%-11.1%;在 PTS 处理下,10-20 厘米土壤深度的土壤微孔显著增加了 7.7%-11.2%。土壤物理质量指数(SQI)在 RTS 和 PTS 处理下明显提高,与 NTS 处理相比,分别提高了 41.26% 和 57.57%。总之,与秸秆覆盖免耕(NTS)相比,秸秆还田秋耕(RTS 和 PTS)降低了土壤容重,增加了土壤孔隙度、大孔隙度,促进了毛细管孔隙度的提高,促进了东部黄土高原土壤物理质量的改善。
{"title":"Effects of autumn tillage with straw return on soil physical characteristics of corn fields in the eastern loess plateau","authors":"Yuchen Fan, Yaqi Yuan, Tao Li, Wen Lin, Xiwang Tang, Gaimei Liang, Nana Li","doi":"10.3389/fenvs.2024.1362616","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1362616","url":null,"abstract":"The implementation of unsuitable tillage practices has the potential to disrupt the structure integrity of the ploughed layer, as well as to influence the physical parameters of the soil. The application of a reasonable tillage method has been demonstrated to result in an improvement in the physical quality of the soil. Three autumn tillage practices have been implemented at the Dongyang Experimental Station of Shanxi Agricultural University since 2016: no-tillage with straw mulch (NTS), autumn rotary tillage with straw incorporation (RTS), and autumn plough tillage with straw incorporation (PTS). The impact of autumn tillage practices on soil physical quality in the 0–30 cm profile of spring corn fields was evaluated following the corn harvest in 2018 and 2019. The results showed that compared to the NTS treatment, the application of RTS was found to have decreased significantly by 9.6%–24.2% in soil bulk density, while it increased significantly by 12.8%–34.0% in total porosity and by 43.5%–146.4% in macroporosity at a depth of 5–10 cm. In comparison to the NTS treatment, the adoption of PTS was found to decrease significantly by 10.7%–30.5% soil bulk density, while it increased significantly by 9.9%–42.7% the total porosity and 23.1%–202.8% the macroporosity at a depth of 0–10 cm. Furthermore, the soil microporosity significantly increase of 7.5%–11.1% under the RTS treatment at the 0–5 cm soil depth and 7.7%–11.2% under the PTS treatment at the 10–20 cm soil depth. Soil physical quality index (SQI) significantly increase under the RTS and PTS treatments, with a 41.26% and 57.57% improvement, respectively, in comparison to the NTS treatment. In summary, the adoption of autumn tillage with straw return (RTS and PTS) demonstrated a reduction in soil bulk density, an increase in soil porosity, macroporosity, and a promotion of capillary porosity, and promoted the improvement of soil physical quality on the Eastern Loess Plateau when compared to no-tillage with straw mulch (NTS).","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"52 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141934494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Integrated machine learning and geospatial analysis enhanced gully erosion susceptibility modeling in the Erer watershed in Eastern Ethiopia 综合机器学习和地理空间分析增强了埃塞俄比亚东部埃勒流域沟壑侵蚀易发性建模能力
IF 4.6 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-06 DOI: 10.3389/fenvs.2024.1410741
Tadele Bedo Gelete, Pernaidu Pasala, Nigus Gebremedhn Abay, Gezahegn Weldu Woldemariam, Kalid Hassen Yasin, Erana Kebede, Ibsa Aliyi
Land degradation from gully erosion poses a significant threat to the Erer watershed in Eastern Ethiopia, particularly due to agricultural activities and resource exploitation. Identifying erosion-prone areas and underlying factors using advanced machine learning algorithms (MLAs) and geospatial analysis is crucial for addressing this problem and prioritizing adaptive and mitigating strategies. However, previous studies have not leveraged machine learning (ML) and GIS-based approaches to generate susceptibility maps identifying these areas and conditioning factors, hindering sustainable watershed management solutions. This study aimed to predict gully erosion susceptibility (GES) and identify underlying areas and factors in the Erer watershed. Four ML models, namely, XGBoost, random forest (RF), support vector machine (SVM), and artificial neural network (ANN), were integrated with geospatial analysis using 22 geoenvironmental predictors and 1,200 inventory points (70% used for training and 30% for testing). Model performance and robustness were validated through the area under the curve (AUC), accuracy, precision, sensitivity, specificity, kappa coefficient, F1 score, and logarithmic loss. The relative slope position is most influential, with 100% importance in SVM and RF and 95% importance in XGBoost, while annual rainfall (AR) dominated ANN (100% importance). Notably, XGBoost demonstrated robustness and superior prediction/mapping, achieving an AUC of 0.97, 91% accuracy, 92% precision, and 81% kappa while maintaining a low logloss (0.0394). However, SVM excelled in classifying gully resistant/susceptible areas (97% sensitivity, 98% specificity, and 91% F1 score). The ANN model predicted the most areas with very high gully susceptibility (13.74%), followed by the SVM (11.69%), XGBoost (10.65%), and RF (7.85%) models, while XGBoost identified the most areas with very low susceptibility (70.19%). The ensemble technique was employed to further enhance GES modeling, and it outperformed the individual models, achieving an AUC of 0.99, 93.5% accuracy, 92.5% precision, 97.5% sensitivity, 95.4% specificity, 85.8% kappa, and 94.9% F1 score. This technique also classified the GES of the watershed as 36.48% very low, 26.51% low, 16.24% moderate, 11.55% high, and 9.22% very high. Furthermore, district-level analyses revealed the most susceptible areas, including the Babile, Fedis, Harar, and Meyumuluke districts, with high GES areas of 32.4%, 21.3%, 14.3%, and 13.6%, respectively. This study offers robust and flexible ML models with comprehensive validation metrics to enhance GES modeling and identify gully prone areas and factors, thereby supporting decision-making for sustainable watershed conservation and land degradation prevention.
沟壑侵蚀造成的土地退化对埃塞俄比亚东部的埃勒流域构成了严重威胁,特别是由于农业活动和资源开发造成的土地退化。利用先进的机器学习算法(MLAs)和地理空间分析来识别易受侵蚀的地区和潜在因素,对于解决这一问题以及确定适应和缓解战略的优先次序至关重要。然而,以往的研究并没有利用机器学习(ML)和基于地理信息系统的方法来生成确定这些地区和影响因素的易感性地图,从而阻碍了可持续的流域管理解决方案。本研究旨在预测沟谷侵蚀易发性(GES),并确定埃尔河流域的潜在区域和因素。利用 22 个地理环境预测因子和 1,200 个清单点(70% 用于训练,30% 用于测试),将四种 ML 模型,即 XGBoost、随机森林 (RF)、支持向量机 (SVM) 和人工神经网络 (ANN) 与地理空间分析相结合。通过曲线下面积(AUC)、准确度、精确度、灵敏度、特异性、卡帕系数、F1 分数和对数损失验证了模型的性能和稳健性。相对坡度位置的影响最大,在 SVM 和 RF 中的重要性为 100%,在 XGBoost 中的重要性为 95%,而年降雨量(AR)在 ANN 中占主导地位(重要性为 100%)。值得注意的是,XGBoost 表现出稳健性和出色的预测/绘图能力,其 AUC 达到 0.97,准确率达到 91%,精确率达到 92%,卡帕率达到 81%,同时保持了较低的对数损失(0.0394)。然而,SVM 在沟壑抗性/易受影响区域的分类方面表现出色(灵敏度 97%、特异性 98% 和 F1 分数 91%)。ANN 模型预测出了最多的沟壑易感性极高的区域(13.74%),其次是 SVM(11.69%)、XGBoost(10.65%)和 RF(7.85%)模型,而 XGBoost 则识别出了最多的易感性极低的区域(70.19%)。采用集合技术进一步增强了 GES 建模能力,其 AUC 值为 0.99,准确率为 93.5%,精确率为 92.5%,灵敏度为 97.5%,特异性为 95.4%,卡帕率为 85.8%,F1 分数为 94.9%,表现优于单个模型。该技术还将流域的 GES 分为极低 36.48%、低 26.51%、中等 16.24%、高 11.55%、极高 9.22%。此外,区级分析显示了最易受影响的地区,包括巴比莱区、菲迪斯区、哈拉尔区和梅乌穆卢克区,其 GES 高的地区分别为 32.4%、21.3%、14.3% 和 13.6%。本研究提供了稳健灵活的 ML 模型和全面的验证指标,以加强 GES 建模并识别沟壑易发地区和因素,从而为可持续流域保护和防止土地退化的决策提供支持。
{"title":"Integrated machine learning and geospatial analysis enhanced gully erosion susceptibility modeling in the Erer watershed in Eastern Ethiopia","authors":"Tadele Bedo Gelete, Pernaidu Pasala, Nigus Gebremedhn Abay, Gezahegn Weldu Woldemariam, Kalid Hassen Yasin, Erana Kebede, Ibsa Aliyi","doi":"10.3389/fenvs.2024.1410741","DOIUrl":"https://doi.org/10.3389/fenvs.2024.1410741","url":null,"abstract":"Land degradation from gully erosion poses a significant threat to the Erer watershed in Eastern Ethiopia, particularly due to agricultural activities and resource exploitation. Identifying erosion-prone areas and underlying factors using advanced machine learning algorithms (MLAs) and geospatial analysis is crucial for addressing this problem and prioritizing adaptive and mitigating strategies. However, previous studies have not leveraged machine learning (ML) and GIS-based approaches to generate susceptibility maps identifying these areas and conditioning factors, hindering sustainable watershed management solutions. This study aimed to predict gully erosion susceptibility (GES) and identify underlying areas and factors in the Erer watershed. Four ML models, namely, XGBoost, random forest (RF), support vector machine (SVM), and artificial neural network (ANN), were integrated with geospatial analysis using 22 geoenvironmental predictors and 1,200 inventory points (70% used for training and 30% for testing). Model performance and robustness were validated through the area under the curve (AUC), accuracy, precision, sensitivity, specificity, kappa coefficient, F1 score, and logarithmic loss. The relative slope position is most influential, with 100% importance in SVM and RF and 95% importance in XGBoost, while annual rainfall (AR) dominated ANN (100% importance). Notably, XGBoost demonstrated robustness and superior prediction/mapping, achieving an AUC of 0.97, 91% accuracy, 92% precision, and 81% kappa while maintaining a low logloss (0.0394). However, SVM excelled in classifying gully resistant/susceptible areas (97% sensitivity, 98% specificity, and 91% F1 score). The ANN model predicted the most areas with very high gully susceptibility (13.74%), followed by the SVM (11.69%), XGBoost (10.65%), and RF (7.85%) models, while XGBoost identified the most areas with very low susceptibility (70.19%). The ensemble technique was employed to further enhance GES modeling, and it outperformed the individual models, achieving an AUC of 0.99, 93.5% accuracy, 92.5% precision, 97.5% sensitivity, 95.4% specificity, 85.8% kappa, and 94.9% F1 score. This technique also classified the GES of the watershed as 36.48% very low, 26.51% low, 16.24% moderate, 11.55% high, and 9.22% very high. Furthermore, district-level analyses revealed the most susceptible areas, including the Babile, Fedis, Harar, and Meyumuluke districts, with high GES areas of 32.4%, 21.3%, 14.3%, and 13.6%, respectively. This study offers robust and flexible ML models with comprehensive validation metrics to enhance GES modeling and identify gully prone areas and factors, thereby supporting decision-making for sustainable watershed conservation and land degradation prevention.","PeriodicalId":12460,"journal":{"name":"Frontiers in Environmental Science","volume":"193 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141934498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Frontiers in Environmental Science
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1