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Nanostructured Anodes for Solid Oxide Fuel Cells Obtained by Screen-Printing and Infiltration 丝网印刷与渗透法制备固体氧化物燃料电池纳米阳极
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-09-07 DOI: 10.1002/fuce.70017
Martin Michael Juckel, Yanting Liu, André Weber, Olivier Guillon, Norbert H. Menzler

Nanomaterials were used for the investigation of electrochemical performance tests of solid oxide fuel cells. Two different approaches were chosen to produce symmetrical nanoparticle (NP)-based cells: screen printing and infiltration. Screen printing, as a state-of-the-art manufacturing process, leads to unstable NiO/gadolinium-doped ceria (GDC) conductive layers, which either show delamination or flaking after sintering or electrochemical testing. The infiltration of an NiO scaffold with GDC NPs and the infiltration of a GDC scaffold with NiO NPs, on the other hand, were used as a solution for these problems, and stable symmetrical cells with particle sizes down to 10 nm were produced. All stable infiltrated cells were microstructurally and electrochemically characterized and showed an improved electrochemical performance.

采用纳米材料对固体氧化物燃料电池的电化学性能进行了研究。选择了两种不同的方法来生产对称的纳米颗粒(NP)细胞:丝网印刷和浸润。丝网印刷作为一种先进的制造工艺,会导致不稳定的NiO/钆掺杂铈(GDC)导电层,在烧结或电化学测试后会出现分层或剥落。另一方面,采用NiO支架与NiO NPs浸润GDC支架作为解决这些问题的方法,制备了粒径小至10 nm的稳定对称细胞。所有稳定的浸润电池都进行了微观结构和电化学表征,并表现出改善的电化学性能。
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引用次数: 0
Energy Efficiency Analysis and Decoupling Control Design of Air Supply for Vehicle Fuel Cell System 车用燃料电池系统供气效率分析与解耦控制设计
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-09-04 DOI: 10.1002/fuce.70016
Caizhi Zhang, Yuqi Qiu, Christoph Hametner, Zhongbao Wei, Alessandro Ferrara, Tao Zeng, Jun Li, Xiaoxia Ren

The reliability and efficiency of proton exchange membrane fuel cells largely depend on the performance of the air supply system, making high-control accuracy essential. First, the impact of control accuracy on the energy consumption and efficiency of the air compressor is analyzed. Subsequently, a fuel cell system model is established based on experimental data to enable rapid verification of control strategies. Finally, three decoupling control algorithms (feedforward decoupling, feedback decoupling, and diagonal matrix decoupling) are compared in detail. The results show that the diagonal matrix decoupling algorithm has higher stability and minimizes the coupling between pressure and flow. Experimental verification on the fuel cell system test bench further shows that the diagonal matrix decoupling algorithm can limit the flow and pressure fluctuations to less than 0.5 g/s and 0.5 kPa, respectively, and effectively prevent compressor surge during startup. This method provides theoretical guidance for achieving high-precision control of the air supply system of fuel cell vehicles.

质子交换膜燃料电池的可靠性和效率在很大程度上取决于供气系统的性能,因此高控制精度至关重要。首先,分析了控制精度对空压机能耗和效率的影响。随后,基于实验数据建立燃料电池系统模型,实现控制策略的快速验证。最后对三种解耦控制算法(前馈解耦、反馈解耦和对角矩阵解耦)进行了详细的比较。结果表明,对角矩阵解耦算法具有较高的稳定性,能最大限度地减少压力与流量之间的耦合。在燃料电池系统试验台上的实验验证进一步表明,对角矩阵解耦算法可以将流量波动和压力波动分别限制在0.5 g/s和0.5 kPa以下,有效地防止了压气机启动时喘振。该方法为实现燃料电池汽车供气系统的高精度控制提供了理论指导。
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引用次数: 0
Development of Catalyst Ink for Crack-Free Catalyst Coated Membrane Based on Direct Coating of Proton Exchange Membrane Fuel Cells 基于质子交换膜燃料电池直接涂覆的无裂纹膜催化剂油墨的研制
IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-07-27 DOI: 10.1002/fuce.70015
Zhengwei Gong, Zhiyang Feng, Luxin Tao, Wei Chao, Zhou Chang, Pengjuan Zhao

The article explores the various types of solvents and the water content of the ink. It also considers whether dispersion is requisite, the size and weight of zirconia balls during dispersion, the influence of ball milling time and speed on the quality of the catalyst layer, and the determination of the solvent system consisting of n-propanol, 80% water content, and 1 micrometer (µm) zirconia balls, with two equivalents. A formula and method are devised with a rotating speed of 2000 revolutions per minute (rpm) and a duration of 20 min, respectively, to create a crack-free catalyst layer. Through an investigation of the effect of the ionomer content in the formula on performance, it is clarified that a closer bond between the catalyst layer and the proton exchange membrane emerges. This is because the ionomer in the ink shares the same molecular structure with the membrane. Consequently, the catalyst layer becomes more porous, reducing the mass transfer resistance and ohmic resistance under standard operating conditions, resulting in a performance of [email protected]/cm2 for direct coating. However, it also leads to a reduction of the ionomer on the side of the catalyst layer away from the proton exchange membrane.

文章探讨了各种类型的溶剂和油墨的含水量。还考虑了是否需要分散,分散过程中氧化锆球的大小和重量,球磨时间和速度对催化剂层质量的影响,以及由正丙醇、80%含水量和1微米(µm)氧化锆球组成的溶剂体系的确定。本发明设计了一种配方和方法,其转速分别为2000转/分(rpm)和持续时间为20分钟,以产生无裂纹的催化剂层。通过对配方中离子含量对性能影响的研究,明确了催化剂层与质子交换膜之间的联系更加紧密。这是因为油墨中的离聚体与膜具有相同的分子结构。因此,催化剂层变得更加多孔,降低了标准操作条件下的传质电阻和欧姆电阻,从而使直接涂层的性能达到[email protected]/cm2。然而,它也导致远离质子交换膜的催化剂层一侧的离聚体的还原。
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引用次数: 0
A Novel Integration Approach for Photovoltaic/Wind/Fuel Cell-Based Hybrid Renewable Energy Systems With Reliability Indices for Sustainable Electric Vehicle Charging 基于光伏/风能/燃料电池的混合可再生能源系统集成方法及可靠性指标
IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-07-21 DOI: 10.1002/fuce.70012
Khaliq Ahmed, Devkaran Sakravdia, Chandrakant Sharma

Hybrid energy systems that integrate renewable energy sources are driving the green energy revolution and playing an increasingly vital role in supporting sustainable transportation through electric vehicle charging infrastructure. This study involves the meticulous design of a reliable standalone multi-vector hybrid energy configuration comprising photovoltaic panels, wind turbines, and fuel cells (PV/WT/FC) for stochastic electric vehicle (EV) load. Significantly, the research presents a pioneering methodology that incorporates chaotic particle swarm optimization aligned with the Andean Condor algorithm (CPSO-ACA), providing a sophisticated optimization approach. The evaluation process is based on key measures like net present cost (NPC), levelized cost of energy (LCOE), and reliability indicators such as loss of load probability (LOLP), loss of load expectation (LOLE), and loss of energy expected (LOEE). With the proposed hybrid approach, a reliable hybrid energy system with the lowest renewable energy components and promising reliability (LOLP = 0.064) has been reported. From a financial perspective, the values of NPC, LCOE, and LOE ($4.06 M, $0.0636/kWh, and $0.7083 M) enable the hybrid system to be economically sound. Furthermore, the energy-oriented reliability indices, LOEE and LOLE, have significantly reduced to 5920 kWh and 564.144 h, respectively. The effectiveness of the proposed algorithm is compared with GA, GWO, MOPSO, and CPSO algorithms and is indicative of the strength achieved through proposed optimization in the evolving landscape of green energy technology.

整合可再生能源的混合能源系统正在推动绿色能源革命,并通过电动汽车充电基础设施在支持可持续交通方面发挥着越来越重要的作用。这项研究涉及到一个可靠的独立多矢量混合能源配置的精心设计,包括光伏板,风力涡轮机和燃料电池(PV/WT/FC)随机电动汽车(EV)负载。值得注意的是,该研究提出了一种开创性的方法,将混沌粒子群优化与安第斯秃鹰算法(CPSO-ACA)相结合,提供了一种复杂的优化方法。评估过程基于净当前成本(NPC)、平准化能源成本(LCOE)等关键度量,以及可靠性指标,如负荷损失概率(LOLP)、负荷预期损失(LOLE)和预期能源损失(LOEE)。利用本文提出的混合方法,已经报道了一个可靠的混合能源系统,该系统具有最低的可再生能源成分,并且具有良好的可靠性(LOLP = 0.064)。从财务角度来看,NPC、LCOE和LOE的价值(406万美元、0.0636美元/千瓦时和0.7083万美元/千瓦时)使混合动力系统在经济上是合理的。此外,面向能源的可靠性指标LOEE和LOLE分别显著降低至5920 kWh和564.144 h。将该算法的有效性与GA、GWO、MOPSO和CPSO算法进行了比较,表明了通过该算法在不断发展的绿色能源技术领域所取得的优势。
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引用次数: 0
Optimization of Fuel Cell Manifold and Structural Design of End Plates Using Computational Fluid Dynamics and Genetic Algorithm Approach 基于计算流体力学和遗传算法的燃料电池流形优化及端板结构设计
IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-07-08 DOI: 10.1002/fuce.70013
Jeno Salethraj, Balamurugan Chinnasamy, Mokesh Kumar Selvaraj, Mohammed Abdul Kadar Rahiman

Ensuring uniform fluid distribution in high-power fuel cell stacks is crucial for automotive applications. This study introduces and evaluates novel X1- and X2-shaped manifold designs against the conventional U-shaped manifold to enhance distribution uniformity across cells. Computational Fluid Dynamics simulations demonstrated the superiority of the proposed designs, with the X2 manifold exhibiting improved pressure uniformity and reduced pressure drop due to its double-inlet configuration. Further optimization was conducted using a multi-objective genetic algorithm and topology optimization techniques, refining the flow area for enhanced performance. Results indicated that reducing the inlet size while maintaining the outlet size significantly improved gas distribution across all manifold configurations. Additionally, integrating a C-type inlet pipe in the X2 manifold further enhanced flow consistency and reduced manifold size by 50 percent. These findings highlight the effectiveness of advanced computational and optimization strategies in fuel cell manifold design, offering practical solutions to enhance flow distribution and overall stack performance.

确保高功率燃料电池堆中均匀的流体分布对于汽车应用至关重要。本研究介绍并评估了新型X1和x2形歧管设计与传统u形歧管的对比,以提高单元间分布的均匀性。计算流体动力学模拟证明了所提出设计的优越性,X2歧管由于其双入口配置,表现出更高的压力均匀性和更小的压降。使用多目标遗传算法和拓扑优化技术进行进一步优化,细化流区以提高性能。结果表明,在保持出口尺寸的同时减小进口尺寸可以显著改善所有歧管配置中的气体分布。此外,在X2歧管中集成了c型进气管,进一步提高了流动一致性,并将歧管尺寸减小了50%。这些发现突出了先进的计算和优化策略在燃料电池歧管设计中的有效性,为改善流动分布和整体堆性能提供了实用的解决方案。
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引用次数: 0
Horned Lizard Defense Tactics Optimization Algorithm for Precise Identification of PEMFC Parameters 角蜥蜴防御战术优化算法的精确识别PEMFC参数
IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-07-04 DOI: 10.1002/fuce.70011
Badreddine Kanouni, Abdelbaset Laib, Abdelbasset Krama, Salah Necaibia, Josep M. Guerrero

Proton exchange membrane fuel cells (PEMFCs) are emerging as a promising alternative power source, converting hydrogen and oxygen into clean energy. Accurate mathematical modeling of PEMFCs is essential for their simulation, evaluation, optimization, and effective management. This study introduces a newly developed metaheuristic algorithm, the Horned Lizard Defense Tactics Optimization Algorithm (HLDTOA), for parameter identification in PEMFC mathematical models, leveraging semi-empirical equations to enhance precision. The HLDTOA is applied to determine the unknown design parameters of various PEMFCs under diverse operating conditions of pressure and temperature. The HLDTOA achieved a 37.23% improvement in min sum of squared error (SSE) (0.64193093 opposed to 1.0227417), an 18.37% improvement (0.09653342 compared to 0.11827), a 3.32% improvement (1.05636977 compared to 1.0926766), and a 27.32% improvement (1.50432678 opposed to 2.07) for H-12, 250 W PEMFC SR-12, for Nedstack, respectively. Statistical analyses further demonstrate the robustness and superiority of HLDTOA. The high correlation between derived and experimentally measured IV polarization curves underscores its precision and reliability. Additionally, the dynamic characteristics of PEMFCs are evaluated to test the optimized parameters under varying reactant pressures and cell temperatures. The HLDTOA offers exceptional accuracy and reliability in identifying unknown PEMFC parameters, marking a significant advancement in fuel cell modeling and optimization.

质子交换膜燃料电池(pemfc)作为一种有前途的替代能源,将氢和氧转化为清洁能源。pemfc的精确数学建模对其仿真、评估、优化和有效管理至关重要。本文介绍了一种新开发的元启发式算法——角蜥防御策略优化算法(HLDTOA),用于PEMFC数学模型的参数识别,利用半经验方程来提高精度。应用HLDTOA确定了不同压力和温度工况下各种pemfc的未知设计参数。HLDTOA在最小平方误差和(SSE)方面分别提高了37.23%(0.64193093比1.0227417)、18.37%(0.09653342比0.11827)、3.32%(1.05636977比1.0926766)和27.32%(1.50432678比2.07)。统计分析进一步证明了HLDTOA的稳健性和优越性。推导出的I-V极化曲线与实验测量的曲线高度相关,增强了其精度和可靠性。此外,还评估了pemfc在不同反应物压力和电池温度下的动态特性,以测试优化后的参数。HLDTOA在识别未知PEMFC参数方面具有卓越的准确性和可靠性,标志着燃料电池建模和优化的重大进步。
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引用次数: 0
PEMFC Catalyst Layer Degradation at Intermediate Temperatures (80°C, 100°C, and 120°C) 中温(80°C, 100°C和120°C)下PEMFC催化剂层降解
IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-06-25 DOI: 10.1002/fuce.70009
Linnéa Strandberg, Gabor Toth, Gert Göransson, Victor Shokhen, Björn Wickman

A growing interest in operating proton exchange membrane fuel cells at intermediate temperatures (80°C–120°C) has emerged due to the aim of implementing fuel cells in demanding applications like aviation and heavy-duty automotive uses. Operating at intermediate temperatures has several advantages, such as reduced cooling demand and increased kinetics. This is particularly important for applications that frequently experience high-load conditions, where power usage and heat production are high. However, the impact of these temperatures on the degradation of membrane electrode assemblies (MEAs) is not well understood. Here, we show performance degradation of four automotive type MEAs at 80°C, 100°C, and 120°C, studied using electrochemical characterization and electron microscopy. Higher operating temperatures leads to increased performance degradation, increased Pt growth and larger electrochemical surface area (ECSA) losses for all samples. However, neither ECSA losses nor increased resistance are sufficient to explain the severe performance loss observed for most samples at 120°C. These results highlight the importance of optimizing catalyst layers for specific operation conditions and show that the cathodic catalyst layer has a large impact on the increased degradation at intermediate-temperature operation. This study helps to understand the effects of intermediate temperature operation on the catalyst layer.

为了在航空和重型汽车等苛刻的应用中实现燃料电池,人们对在中间温度(80°C - 120°C)下操作质子交换膜燃料电池的兴趣越来越大。在中间温度下操作有几个优点,例如减少冷却需求和增加动力学。这对于经常经历高负载条件的应用尤其重要,在这种情况下,电力使用和热量产生很高。然而,这些温度对膜电极组件(MEAs)降解的影响尚不清楚。在这里,我们展示了四种汽车型MEAs在80°C, 100°C和120°C下的性能退化,并使用电化学表征和电子显微镜进行了研究。较高的工作温度导致所有样品的性能下降,Pt生长增加和电化学表面积(ECSA)损失增加。然而,ECSA损耗和电阻增加都不足以解释大多数样品在120°C下观察到的严重性能损失。这些结果突出了在特定操作条件下优化催化剂层的重要性,并表明阴极催化剂层对中温操作下降解的增加有很大影响。本研究有助于了解中温操作对催化剂层的影响。
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引用次数: 0
Analysis of the Thermal-Electric Performance of the Solid Oxide Fuel Cell With a Zigzag Channel Under Different Operating Conditions 不同工况下之字形通道固体氧化物燃料电池的热电性能分析
IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-06-24 DOI: 10.1002/fuce.70010
Xiaoyi Su, Li Jia, Chao Dang, Qianlong Wanng

In the present study, a strongly coupled three-dimensional thermal-electric-fluid-mass model was developed, and the thermal-electric performance of the solid oxide fuel cell (SOFC) with a zigzag channel under various operating conditions was analyzed. The results indicated that increasing the operating temperature and the anode inlet Reynolds number could enhance the output power density of the SOFC, whereas the temperature gradient within the SOFC also increased accordingly. The enhancement of these parameters led to an increase in the electrical performance (characterized by power density) of the SOFC while concurrently diminishing its thermal performance (characterized by temperature gradient). Under the same conditions, the SOFC with a zigzag channel exhibited superior electrical performance compared to the SOFC with a conventional parallel channel, albeit with slightly inferior thermal performance. Keeping the flow parameters constant (Re = 1.0) and the temperature maintained at 1123 K, the electrical performance of the SOFC with a zigzag channel was 8.6% higher than that of the SOFC with a parallel channel, whereas the thermal performance was 4.2% lower. Keeping the temperature parameter constant (T = 1073 K) and the anode inlet Reynolds number maintained at 1.7, the output power density of the SOFC with a zigzag channel was 5.9% higher than that of the SOFC with a parallel channel, whereas the temperature uniformity was 2.6% lower. The issue of internal temperature non-uniformity caused by the zigzag channel design of the SOFC could be balanced by adopting the co-flow operation condition. At a working temperature and flow condition of T = 1073 K and Re = 1.0, the thermal performance of the SOFC with a zigzag channel in a co-flow configuration was 5% higher than that in a counter-flow configuration, whereas its electrical performance decreased by only 0.2% compared to the counter-flow configuration.

建立了三维强耦合的热电-流-质模型,分析了具有之字形通道的固体氧化物燃料电池(SOFC)在不同工况下的热电性能。结果表明,提高工作温度和阳极入口雷诺数可以提高SOFC的输出功率密度,同时SOFC内部的温度梯度也相应增大。这些参数的增强导致SOFC的电气性能(以功率密度为特征)的增加,同时降低了其热性能(以温度梯度为特征)。在相同的条件下,与传统的并行通道的SOFC相比,具有之字形通道的SOFC表现出更好的电学性能,尽管热性能略差。在流动参数不变(Re = 1.0)、温度为1123 K的条件下,锯齿形通道SOFC的电学性能比平行通道SOFC的电学性能高8.6%,而热学性能却低4.2%。当温度参数T = 1073 K不变,阳极入口雷诺数为1.7时,锯齿形通道SOFC的输出功率密度比平行通道SOFC的输出功率密度高5.9%,温度均匀性降低2.6%。采用共流工况可以平衡SOFC之字形通道设计引起的内部温度不均匀性问题。在T = 1073 K和Re = 1.0的工作温度和流量条件下,锯齿形通道的SOFC在共流配置下的热学性能比逆流配置下提高了5%,而电学性能仅比逆流配置下下降了0.2%。
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引用次数: 0
A Novel Degradation Prediction Method of PEMFC Based on CEEMDAN and Informer-LSTM Parallel Prediction 基于CEEMDAN和Informer-LSTM并行预测的PEMFC退化预测新方法
IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-06-21 DOI: 10.1002/fuce.70008
Haotian Dai, Tao Chen, Yang Lan, Xiao Liang, Jiabin Wen

Proton exchange membrane fuel cells (PEMFC), as an important part of clean energy technology, are widely used in transport, portable power sources and stationary power systems. PEMFC experience aging during use, resulting in degradation of their performance and shorter lifespan. In this paper, a hybrid model of complete ensemble empirical mode decomposition with adaptive noise (CEEMDAN), informer, and long short-term memory (LSTM) is proposed to predict the aging trend. The data are decomposed into multiple Intrinsic Mode Function (IMF) through CEEMDAN, which are reconstructed according to sample entropy (SE) to provide stable data for the model. A new prediction approach is proposed to predict informer and LSTM in parallel while extracting multifaceted features. Different datasets, different training stopping points (TSP), and multiple models are used to validate the accuracy and stability of the model. The root mean square error (RMSE) and mean absolute error (MAE) can reach 0.00137 and 0.00060 for the steady state dataset, and the prediction is better for the quasi–dynamic dataset with RMSE and MAE reaching 0.00126 and 0.00065.

质子交换膜燃料电池(PEMFC)作为清洁能源技术的重要组成部分,广泛应用于交通运输、移动电源和固定式电源系统中。PEMFC在使用过程中会经历老化,导致其性能下降,寿命缩短。本文提出了一种具有自适应噪声(CEEMDAN)、信息源和长短期记忆(LSTM)的全系综经验模态分解混合模型来预测老化趋势。通过CEEMDAN将数据分解为多个内禀模态函数(IMF),并根据样本熵(SE)对其进行重构,为模型提供稳定的数据。提出了一种新的预测方法,在提取多面特征的同时,对信息源和LSTM进行并行预测。采用不同的数据集、不同的训练停止点(TSP)和多个模型来验证模型的准确性和稳定性。稳态数据的均方根误差(RMSE)和平均绝对误差(MAE)可达0.00137和0.00060,准动态数据的均方根误差和平均绝对误差(MAE)可达0.00126和0.00065,预测效果较好。
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引用次数: 0
Impact of Fuel Utilization on Flow and Reaction Uniformity in a 1 kWe SOFC Stack: A CFD-Based Study 燃料利用对1kwe SOFC堆流动和反应均匀性的影响:基于cfd的研究
IF 2.6 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-06-20 DOI: 10.1002/fuce.70007
Kunwoo Yi, Haoyuan Yin, Youngjin Kim, Hyeonjin Kim, Kyongsik Yun, Jihaeng Yu

This study presents a high-fidelity, full-scale 3D CFD model to investigate the effects of fuel utilization on flow and reaction uniformity in a 1 kWe planar SOFC stack consisting of 40 unit cells. Unlike conventional studies relying on simplified geometries, this model integrates detailed channel structures, porous media transport, electrochemical reaction kinetics, and radiative heat transfer. Model validation using experimental data shows less than 3.2% deviation, and grid independence is confirmed using the Richardson extrapolation method. A parametric study was conducted across five different fuel utilization (Uf) conditions ranging from 0.3 to 0.7. Results show that higher fuel utilization enhances the electrochemical reaction rate but may induce fuel depletion in downstream regions. At a utilization rate of 0.7 (Uf = 0.7), rapid hydrogen consumption near the inlet causes a shift in thermal hotspots upstream and increases the H2O molar fraction, resulting in a lower peak temperature than at Uf = 0.6. Furthermore, models that include electrochemical reactions were found to provide a more accurate representation of flow within the stack channels compared to single-phase flow evaluation methods. The production and consumption of chemical species within the channels influence flow uniformity, with differences reaching up to 0.36% at the bottom of the stack and up to 0.72% at the top. These findings offer valuable insights for optimizing SOFC design and operation, contributing to the development of more efficient fuel cell systems.

本研究建立了一个高保真的全尺寸三维CFD模型,以研究由40个单元电池组成的1kwe平面SOFC堆中燃料利用率对流动和反应均匀性的影响。与依赖简化几何的传统研究不同,该模型集成了详细的通道结构、多孔介质传输、电化学反应动力学和辐射传热。采用实验数据验证模型偏差小于3.2%,采用Richardson外推法确认了网格独立性。一项参数研究在5种不同的燃料利用率(Uf)条件下进行,范围从0.3到0.7。结果表明,较高的燃料利用率提高了电化学反应速率,但可能导致下游区域燃料耗竭。在利用率为0.7 (Uf = 0.7)时,入口附近的快速耗氢导致热热点上游移动,H2O摩尔分数增加,峰值温度低于Uf = 0.6时的峰值温度。此外,与单相流动评估方法相比,包括电化学反应的模型可以更准确地表示堆叠通道内的流动。通道内化学物质的产生和消耗对流动均匀性有影响,通道底部差异可达0.36%,通道顶部差异可达0.72%。这些发现为优化SOFC设计和操作提供了有价值的见解,有助于开发更高效的燃料电池系统。
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引用次数: 0
期刊
Fuel Cells
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