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HEAVY METAL PROFILES IN VARIOUS MATRICES OF THE BONNY/NEW CALABAR RIVER ESTUARY, NIGER DELTA, NIGERIA 尼日利亚尼日尔三角洲邦尼/新卡拉巴尔河口不同基质重金属剖面
Pub Date : 2015-01-19 DOI: 10.4314/GJES.V12I1.1
B. Babatunde, F. Sikoki, M. Onojake, R. U. Akpiri, D. Akpuloma
A study of the concentrations of Ca, Mg, K, Zn, Pb, Cd, Co, Cr, Cu, Fe, Ni and Na in the sediment, sea water, fish and crab of the Bonny/New Calabar River Estuary in Niger Delta, Nigeria was carried out using atomic absorption spectrophotometer A-100 for two consecutive years. The contamination levels of the respective metals varied between 2011 and 2012and the range of mean values for all metals in mg/kg were presented along with variations at statistically significant level (P <0.05) between the two years studied. Only K, Zn and Co exhibited variation in their concentrations in water samples between the two years at a statistical significant level (P <0.05) probability. In sediment, only Cr varied between the two years at a statistically significant level (P = 0.05). All metals concentrations were higher in sediment than in water samples.Bioaccumulation factor (BF) indicated a more potent source of metals from sediment than water with organisms accumulating Zn, Fe and Ni in the magnitude of 10, 6 and 5 times more from sediment than from water. Some metals were more accumulated in fish than crab and vice versa. The evidence of elevated levels of heavy metals in sediment and bioaccumulation in biota in the studied area may poise a wanton threat to the health of inhabitants whose diet is predominantly fish. This calls for regular monitoring to avert potential public health problems arising from consumption of metals in seafood.
采用原子吸收分光光度计A-100连续两年研究了尼日利亚尼日尔三角洲邦尼/新卡拉巴尔河口沉积物、海水、鱼和蟹中Ca、Mg、K、Zn、Pb、Cd、Co、Cr、Cu、Fe、Ni和Na的浓度。各金属污染水平在2011年和2012年之间存在差异,并给出了所有金属(mg/kg)的平均值范围,两年间差异具有统计学意义(P <0.05)。两年间水样中只有K、Zn和Co的浓度有显著差异(P <0.05)。在沉积物中,只有Cr在两年内有显著差异(P = 0.05)。沉积物中所有金属的浓度都高于水样。生物积累因子(BF)表明,沉积物对重金属的富集比水体更强,沉积物对Zn、Fe和Ni的富集量分别是水体的10倍、6倍和5倍。有些金属在鱼体内的积累量比蟹体内多,反之亦然。研究区域沉积物中重金属含量升高以及生物群中生物积累的证据可能对以鱼类为主要饮食的居民的健康构成严重威胁。这就要求进行定期监测,以避免因食用海产品中的金属而产生潜在的公共卫生问题。
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引用次数: 4
Effect of Indomie industrial effluent discharge on fish fauna of New Calabar River, Port Harcourt 英多米工业废水排放对哈科特港新卡拉巴尔河鱼类区系的影响
Pub Date : 2015-01-19 DOI: 10.4314/gjes.v12i1.5
G. Woke, B. Babatunde, Wokoma Aleleye
The effect of Indomie industrial effluent discharge on the fish fauna of New Calabar River was investigated in order to ascertain the influence of BOD, COD, DO, TDS, TSS, pH, salinity, phosphate and temperature on the composition and distribution of fish fauna. The diversity of the fish fauna was found to be poor, only 12 fish species in 6 families were identified. The highest number (10) of fishes was recorded in station 4 while the least number (1) of fishes was observed in station 1. The fish families were: Cichlidae (38.89%), Clupidae (33.33%), Pomadasyidae (16.67%), Bagridae (11.11%) while Genidae and Muglidae had zero percentage of fishes in its abundant. The resident fish species ( Ethmalosa fimbriata and Tilapia guinensis ) were highly adapted to the changes in the study environment and this was dependent on their trophic relationship within the environment. These species had great affinity for indomie industrial waste, because they feed on waste remains, mud/sediment silts and annelids, juveniles of shrimps and crabs. The deterioration of water quality was evident by the high BOD (12.80mg/L), COD (130mg/L), TDS (37mg/L), TSS (62mg/L), pH (5.2), salinity (50.54mg/L), phosphate (0.14mg/L) and temperature (27 0 C) as well as the low dissolved oxygen (2.8mg/L) values observed. It was recommended that a routine treatment of the effluent before discharge into the water should be carried out so to maintain safe levels of industrial effluent in the immediate and extended environment.
研究了Indomie工业废水排放对新卡拉巴尔河鱼类区系的影响,探讨了BOD、COD、DO、TDS、TSS、pH、盐度、磷酸盐和温度对鱼类区系组成和分布的影响。鱼类区系多样性较差,仅鉴定出6科12种。4号站鱼的数量最多(10条),1号站鱼的数量最少(1条)。鱼科分别为:拟鲤科(38.89%)、拟鲤科(33.33%)、拟鲤科(16.67%)、拟鲤科(11.11%),拟鲤科和拟鲤科的鱼类数量为零。常驻鱼类黄颡鱼(Ethmalosa fibriata)和几内亚罗非鱼(Tilapia guinensis)对研究环境的变化具有高度的适应性,这取决于它们在环境中的营养关系。这些物种对室内工业废物有很大的亲和力,因为它们以废物残留物、泥/沉积物淤泥和环节动物、虾和蟹的幼崽为食。水体BOD (12.80mg/L)、COD (130mg/L)、TDS (37mg/L)、TSS (62mg/L)、pH(5.2)、盐度(50.54mg/L)、磷酸盐(0.14mg/L)、温度(27 0℃)、溶解氧(2.8mg/L)低,水质明显恶化。建议在排放到水中之前对废水进行常规处理,以便在直接和扩展的环境中保持工业废水的安全水平。
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引用次数: 1
Status evaluation of heavy metals in waste disposal sites of champion breweries and plasto crown company, Uyo, Akwa Ibom State, Nigeria 尼日利亚阿夸伊博姆州Uyo市冠军啤酒厂和普拉斯托皇冠公司废物处理场重金属现状评价
Pub Date : 2015-01-19 DOI: 10.4314/GJES.V12I1.6
Us Umana
Sludge and soil samples were collected through purposive sampling method within Champion Breweries and Plasto Crown Company waste disposal sites during wet and dry seasons for status evaluation of their heavy metals (Fe, Pb, Zn, Ni, Cr, Cd, Co and Hg) for comparison with the control site and the world threshold standards for tropical soils. The results showed that the sludge pH value of 7.89 during wet season signified alkaline medium (outside the natural range of acidic medium for soils in the Niger Delta region of Nigeria) which was attributed to the high calcium content of the brewery effluent. The 7.42 pH value during wet season for soil in the Plasto Crown Company waste disposal site indicated alkaline medium which was due to the remnants of the wastes which formed lime to neutralize the acidic medium of the soil while the electrical conductivity values (below 4 dSm-1) indicated the nonsalinity of the soils. More so, a two way analysis of variance (ANOVA) statistical method used to run the analysis revealed that the soil in terms of heavy metal concentrations did not exceed the world threshold standards. Keywords : Soil, sludge, heavy metal concentrations, permissible standards.
在湿季和旱季,通过有目的采样法,在Champion Breweries和Plasto Crown Company的废物处理场收集污泥和土壤样本,评估其重金属(Fe、Pb、Zn、Ni、Cr、Cd、Co和Hg)的状况,并与对照场地和热带土壤的世界阈值标准进行比较。结果表明,雨季污泥pH值为7.89,为碱性介质(超出了尼日利亚尼日尔三角洲地区土壤酸性介质的自然范围),这是由于啤酒厂废水中钙含量高所致。普拉斯托冠公司废弃物处理场雨季土壤pH值为7.42,表明土壤为碱性介质,这是由于废弃物的残留物形成石灰来中和土壤中的酸性介质,而电导率值(低于4 dSm-1)表明土壤为非盐性土壤。更重要的是,用于运行分析的双向方差分析(ANOVA)统计方法显示,土壤中重金属浓度没有超过世界阈值标准。关键词:土壤,污泥,重金属浓度,允许标准。
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引用次数: 0
PHYTOREMEDIATION OF SEWAGE SLUDGE IN SOILS CONTAMINATED WITH HEAVY METALS 重金属污染土壤中污水污泥的植物修复
Pub Date : 2015-01-19 DOI: 10.4314/GJES.V12I1.2
C. O. Awalla
The main source of heavy metals in most soils is sewage sludge. Naturally, the heavy metals in soils are transported to vegetations and cultivated crops. These pollutants need to be either reduced or eliminated in the soil to remediate the effects to man, animals, plants, soils, and groundwater. Hence, Jatropha curcas seedlings were planted on six different media to determine the concentration of heavy metals. Thereafter, it was discovered that Jatropha curcas plants through their roots, stems and leaves metabolism, morphology and mechanisms can reduce the concentration of heavy metals like Zinc, Lead, Chromium, Cadmium, and Copper etc effectively from any medium containing 100% sewage sludge. Thus, it was discovered that Jatropha curcas plant is suitable as a phytoremediator of heavy metals in soils. KEYWORDS : Heavy metal, phytoremediation, sewage sludge, metabolism, morphology.
大多数土壤中重金属的主要来源是污水污泥。自然地,土壤中的重金属被转移到植被和栽培作物中。这些污染物需要在土壤中减少或消除,以弥补对人类、动物、植物、土壤和地下水的影响。因此,将麻疯树幼苗种植在六种不同的培养基上,以测定重金属的浓度。此后,人们发现麻疯树植物通过其根、茎、叶的代谢、形态和机制,可以在任何含100%污泥的培养基中有效地降低锌、铅、铬、镉、铜等重金属的浓度。因此,麻疯树是一种适合作为土壤重金属修复剂的植物。关键词:重金属,植物修复,污泥,代谢,形态
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引用次数: 2
Tannery wastes water treatment using Moringa Stenopetala seed extract 用辣木籽提取物处理制革厂废水
Pub Date : 2015-01-19 DOI: 10.4314/GJES.V12I1.4
Shetie Gatew, W. Mersha
High amount of heavy metal ions like Cr in the environment has been harmful for animal and human health. Bioadsorption of Cr from tannery wastes would be an alternative method to the chemical treatment in tannery industries. Hence, in this study the efficiency of Moringa  stenopetala seed extract to adsorption Cr from tannery waste water was investigated. The influence of solution pH, adsorbent concentration, initial concentration of Cr, contact time and temperature on the efficiency of Moringa stenopetala seed extract for the adsorption of Cr from tannery effluent was studied. Results obtained revealed that in strongly acidic condition Moringa stenopetala seed extract was less efficient to remove Cr. However, the result of the present study showed that Moringa stenopetala seed extract at a concentration of 1g/100 ml and pH of 9.5 decreased the concentration of Cr in tannery waste by 99.86%. In addition, the adsorption data was correlated using the Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin isotherm models. Among models studied Dubinin-Radushkevich isotherm was the best fit with correlation coefficient of 0.958. Moreover, thermodynamics parameters, such as Gibbs free energy (AGo), enthalpy (AHo), and entropy (ASo) were calculated. Results indicated that the bioadsorption of Cr by Moringa stenopetal a seed extract was  spontaneous, feasible and endothermic. The results of this study proved that Moringa stenopetala seed extract can be used to remove Cr from tannery effluent. KEYWORDS : Moringa stenopetala , Cr, tannery, pH, temperature, concentration
环境中含有大量的重金属离子,如铬,对动物和人类的健康都是有害的。生物吸附制革废水中的铬是制革工业中化学处理的一种替代方法。因此,本研究考察了辣木籽提取物对制革废水中铬的吸附效果。研究了溶液pH、吸附剂浓度、Cr初始浓度、接触时间和温度对辣木籽提取物对制革废水中Cr的吸附效果的影响。结果表明,在强酸性条件下,辣木籽提取物对Cr的去除效果较差,而本研究结果表明,辣木籽提取物在浓度为1g/100 ml、pH为9.5的条件下,可使制革废物中Cr的浓度降低99.86%。此外,利用Langmuir、Freundlich、Dubinin-Radushkevich和Temkin等温模型对吸附数据进行了关联。在所研究的模型中,Dubinin-Radushkevich等温线拟合最佳,相关系数为0.958。此外,还计算了吉布斯自由能(AGo)、焓(AHo)和熵(ASo)等热力学参数。结果表明,辣木种子提取物对铬的生物吸附是自发的、可行的、吸热的。研究结果表明,辣木籽提取物可用于制革废水中铬的去除。关键词:辣木,铬,制革,pH,温度,浓度
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引用次数: 4
DIESEL EXPOSURE OF TYMPANOTONUS FUSCATUS AND ITS EFFECTS ON ENZYME ACTIVITY 褐鼓膜虫柴油暴露及其对酶活性的影响
Pub Date : 2015-01-19 DOI: 10.4314/gjes.v12i1.3
O. Edori, D. M. George, E. Edori
The effect of mild concentrations of diesel (10.40,15.60,21.00 and 26.00 mg/l) on some biochemical parameters such as Aspartate transaminase (AST), Alanine transaminase (ALT), and Alkaline phosphatase (ALP), in the tissue of periwinkle ( tympanotonus fuscatus ) were examined using a renewal static bioassay for six days. The activities of the enzymes were measured on 120 specimens of periwinkle of size between 4.5-5.5cm lengths. The result of AST activity in the muscle showed either an increased or decreased activity against the control. The activity of ALT showed significant (p=0.05) decrease in all the test concentrations. ALT also showed significant difference (p=0.05) which were either higher or lower than the control value. In the viscera, activity of AST significantly increased (p=0.05) than that of the control. ALT activity was significantly increased (p=0.05) above the control except at 10.40ml/L where a significant decrease (p=0.05) was observed. Significant increase (p=0.05) was observed in the activity of ALP above the control value except at 10.40ml/L. The result of the tissue enzyme activities indicated alteration in the biochemistry of tympanotonus fuscatus and therefore could be used as a biomarker of aquatic pollution and toxicities. KEYWORDS : Diesel, Tympanotonus fuscatus , Enzyme, Toxicity, pollution
采用更新静态生物测定法,研究了不同浓度柴油(10.40、15.60、21.00和26.00 mg/l)对长春花(tympanotonus fuscatus)组织中谷草转氨酶(AST)、丙氨酸转氨酶(ALT)和碱性磷酸酶(ALP)等生化指标的影响。对120株长度在4.5 ~ 5.5cm之间的长春花进行了酶活性测定。肌内AST活性测定结果显示,与对照组相比,AST活性升高或降低。ALT活性在各浓度下均显著降低(p=0.05)。ALT也有显著性差异(p=0.05),或高于或低于对照组。内脏组织中谷草转氨酶活性显著高于对照组(p=0.05)。ALT活性显著高于对照组(p=0.05),但在10.40ml/L时ALT活性显著降低(p=0.05)。除10.40ml/L时ALP活性高于对照组外,其余各组均显著升高(p=0.05)。组织酶活性测定结果表明褐鼓膜鱼的生物化学变化,可作为水体污染和毒性的生物标志物。关键词:柴油,褐鼓室,酶,毒性,污染
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引用次数: 2
Water quality assessment of underground and surface water resources of Bahir Dar and Periurban areas, north-west Ethiopia 埃塞俄比亚西北部巴希尔达尔和城郊地区地下和地表水资源的水质评价
Pub Date : 2011-01-01 DOI: 10.4314/GJES.V10I1
G. Goshu, O. Akoma
Water quality assessment in the Ethiopian highlands is crucial owing to increasing competing need of water for domestic, agricultural and industrial uses. Twelve physico-chemical parameters were analyzed in water samples collected over a period of five months from three different sources; groundwater (hand dug wells and protected hand pumps) and surface water (streams and lake) in Bahir Dar and peri-urban areas. Differences in water quality parameters between the sources were compared to identify pollutant sources and level of compliance with certain water quality criteria. Based on cluster analysis, the sampling stations were classified into two major categories; inner city and outer city; with the surface waters recording far more pollution by fecal contamination. Chloride, TDS, conductivity, total hardness and all the species of nitrogen (nitrite, nitrate and ammonium) were higher in the inner city than the remaining water habitats except the outer ground water stations. Conductivity decreased along the presumptive pollution categories significantly, i.e. inner > middle > out skirt (P< 0.05) and showed medium to high correlation with chloride, total hardness, nitrate, nitrite, total dissolved solids in ground water (r = 0.58 – 0.85). Dissolved oxygen, pH and SAK254 were higher in the lake station than other water bodies. The results from this research would help in developing best management practices for the Bahir Dar municipal water scheme and for regional water scheme program in the future and provide information for formulating appropriate framework for an integrated water management strategy.
埃塞俄比亚高地的水质评估至关重要,因为家庭、农业和工业用水的竞争需求日益增加。在五个月的时间里,从三个不同的来源收集水样,分析了十二个物理化学参数;Bahir Dar和城郊地区的地下水(手挖井和受保护的手泵)和地表水(溪流和湖泊)。比较不同水源间水质参数的差异,以确定污染源和符合某些水质标准的水平。基于聚类分析,将采样站点分为两大类;内城和外城;地表水记录了更多的粪便污染。除外围地表水站外,城区内的氯化物、TDS、电导率、总硬度和所有种类的氮(亚硝酸盐、硝酸盐和铵态氮)均高于其他水源地。电导率沿推定污染类别呈内>中>外显著下降(P< 0.05),与地下水氯离子、总硬度、硝酸盐、亚硝酸盐、总溶解固形物呈中至高相关性(r = 0.58 ~ 0.85)。湖站溶解氧、pH和SAK254均高于其他水体。这项研究的结果将有助于为未来的巴希尔达尔市政水计划和区域水计划方案制定最佳管理做法,并为制定综合水管理战略的适当框架提供信息。
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引用次数: 4
Effect of crude oil extracts on early stages of African catfish Heterobranchus longifilis (val.) reared under controlled condition 原油提取物对控制条件下饲养的非洲长尾鲶鱼早期生长的影响
Pub Date : 2010-04-16 DOI: 10.4314/GJES.V8I2.53780
I. Ewa-Oboho, O. Amu
Eggs and larvae of Heterobranchus longifilis were exposed to extracts of different concentrations of Nigerian Bonny light crude oil and Exxon Mobil Oso off-shore condensate during a comparative toxicity experiment carried out in the Institute of Oceanography Fish Farm, University of Calabar, Nigeria. Petroleum hydrocarbon was extracted from the two oils in separate 30litre glass aquaria and the eggs and young larvae were contaminated by exposing them to three concentrations of both oils, viz: 101, 103, 102ppm for approximately 10 days. Young eggs seemed to be more sensitive from 5 to 30 hours after fertilization. Extract from 104 ppm of Bonny Light Crude and Oso condensate caused 40% and 30% mortality respectively, after 100h. Embryos contaminated with Bonny Light crude extract did not recover on transfer to clean water. Delayed development was observed in the two-highest concentrations. Heterobranchus longifilis larvae were found to have a “mean critical time” of 4.2 days in the highest concentration of Oso condensate extract when larval integument was damaged. It is concluded that Bonny light crude could be a more dangerous pollutant to juvenile fish than the Oso condensate. KEYWORDS: Heterobranchus longifilis , crude Oil extracts, Mortality, Bonny Light Crude, Exxon Mobil Oso Condensate.
在尼日利亚卡拉巴尔大学海洋学渔场研究所进行的一项比较毒性实验中,长filis异鳃鱼的卵和幼虫暴露于不同浓度的尼日利亚Bonny轻质原油和埃克森美孚Oso近海凝析油提取物中。在不同的30升玻璃水族箱中从这两种油中提取石油碳氢化合物,并将卵和幼幼虫暴露在这两种油的三种浓度(即101,103和102ppm)中约10天。在受精后5到30小时内,年轻的卵子似乎更敏感。104ppm的Bonny轻质原油和Oso凝析油在100h后的死亡率分别为40%和30%。被Bonny Light粗提物污染的胚胎在转移到清洁水中时没有恢复。在两个最高浓度中观察到发育延迟。在最高浓度的Oso凝析液条件下,长尾异枝幼虫被破坏的“平均临界时间”为4.2 d。结论认为,邦尼轻质原油对幼鱼的危害可能大于Oso凝析油。关键词:长鳍异枝,原油提取物,死亡率,邦尼轻质原油,埃克森美孚凝析油
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引用次数: 3
Speciation of heavy metals in the sidments of Gubi dam, Bauchi state, Nigeria 尼日利亚包奇州古比大坝沉积物中重金属的形态
Pub Date : 2010-04-16 DOI: 10.4314/gjes.v8i2.53784
B. M. Wufem, A. Ibrahim, N. Gin, M. Mohammed, E. Ekanem, M. A. Shibdawa
Speciation of heavy metals in the sediments of Gubi Dam in Bauchi, Nigeria was carried out between December, 2001 and March, 2002. The mean total concentrations showed that Tatimari tributary has high Fe, Zn, and Mn, confirming it source and path. The spillway result suggest intensive farming activity along the dam runway. However, the physio-chemical forms of Fe, Pb, and Cr indicate that these metals are associated in high concentration with the mineral matrix of the sediment, as such it is most unlikely to become biologically available. High levels of Cu, Cd, Zn, Mn, Co and Ni are associated with the exchangeable carbonate bound fractions, indicating that they are in potentially available forms and many pose serious problems to the dam ecosystem. KEY WORDS: Sediments, Speciation, Heavy metals, Gubi Dam, Nigeria
2001年12月至2002年3月对尼日利亚包奇古比大坝沉积物中重金属进行了形态分析。平均总浓度表明,Tatimari支流具有较高的铁、锌、锰含量,证实了其来源和路径。溢洪道结果表明沿坝跑道有密集的农业活动。然而,铁、铅和铬的物理化学形式表明,这些金属与沉积物的矿物基质有高浓度的联系,因此它们不太可能成为生物可利用的。高水平的Cu、Cd、Zn、Mn、Co和Ni与可交换的碳酸盐结合组分有关,表明它们具有潜在的可利用形式,并且对大坝生态系统构成严重问题。关键词:沉积物,形态,重金属,古比大坝,尼日利亚
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引用次数: 1
ASSESSMENT OF SOLID WASTE MANAGEMENT IN GBOKO TOWN gboko镇固体废物管理评估
Pub Date : 2010-04-16 DOI: 10.4314/GJES.V8I2.53786
G. Akpen, S. Aondoakaa
Solid waste management appraisal for Gboko town is made. Questionnaires were administered with respect to demographic and waste management data in five zones of the town. The rate of waste generation was determined by using household approach, which involved sorting and weighing of wastes respectively. The data obtained were subjected to statistical analysis using ANOVA and Chi- Square tests. The results showed that there was significant variation in the composition of waste generated. The amount of waste generated per day was estimated at 23,841 kg. In general management of solid waste in Gboko town is not satisfactory calling for more concerted efforts in the areas of public enlightenment campaigns, regular collection and disposal of generated wastes and extension of services to cover more inhabitants of the town. KEY WORDS: Solid wastes, Management, Problems, Gboko town
对Gboko镇固体废物管理进行了评价。对该镇五个地区的人口和废物管理数据进行了问卷调查。垃圾产生率采用家庭法确定,分别包括垃圾分类和称重。所得资料采用方差分析和卡方检验进行统计分析。结果表明,产生的废物组成有显著变化。每天产生的废物量估计为23,841公斤。总的来说,Gboko镇固体废物的管理并不令人满意,需要在公众教育运动、定期收集和处理产生的废物以及扩大服务范围以覆盖该镇更多居民等领域作出更协调一致的努力。关键词:固体废物;管理;问题
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引用次数: 9
期刊
Global Journal of Environmental Sciences
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