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Hydrogeochemical features of Lake Kotokel 科托克尔湖水文地球化学特征
Pub Date : 2021-06-17 DOI: 10.21285/2686-9993-2021-44-2-106-115
N. A. Angakhaeva, A. Plyusnin, A. U. Ukraintsev, M. K. Chernyavskii, E. Peryazeva, D. I. Zhambalova
The purpose of this study is to determine the main hydrochemical parameters of Lake Kotokel deep waters, to identify the role of groundwater feeding it, as well as to establish the features of spatial distribution of macro- and microelements in the lake. Field work was carried out during the ice and ice-free seasons. A special sampler was used to take water samples from the bottom of the lake. Water samples were filtered through the filters with a pore size of 0.45 μm at the sampling site. Plastic bottles were used for the water samples for analysis. Polypropylene containers (15 ml) pretreated with 0.1 N nitric acid were used for the water samples for trace elements. The analysis of the macrocomponent composition of water was carried out in a certified Laboratory of Hydrogeology and Geoecology of the Geological Institute of the Siberian Branch of the Russian Academy of Sciences (Ulan-Ude) according to the standard methods intended for fresh and saline waters. Cations (Ca2+, Mg2+, Na+, K+) were determined by atomic absorption, F-, SiO2 – by the colorimetric method, HCO3- , CO32- and Cl- – by the titrimetric method, SO42- – by the turbidimetric method. The analysis of the trace element content was carried out in the Laboratory of Aquatic Microbiology at the Limnological Institute of the Siberian Branch of the Russian Academy of Sciences (Irkutsk) by the method of inductively coupled plasma on Agilent 7500ce quadrupole mass spectrometer. Conducted research made it possible to determine an inhomogeneous chemical composition of lake water associated with the discharge of fissure-vein waters along the faults that bound the depression from the southeast and northeast and intersect the lake water area from the island to the Istok river. The highest content of dissolved substances was recorded in the strait between Monastyrsky island and the western shore of the lake; the maximum values of hydrocarbonate ion and total mineralization were found here. The maximum content of sulfate ion was found in the southern and southeastern parts of the lake. The dispersion in microelement distribution reaches several mathematical orders. The most variable concentration is characteristic of iron, manganese, copper, zinc, lead, phosphorus, molybdenum, tungsten, strontium. Their high contents were found in the lake water within the location of faults of northeast strike. Therefore, the chemical composition of the water of Lake Kotokel is largely formed by fissure-vein waters. This water is discharged along the tectonic faults of the northeastern strike. The research revealed two centers of subaqueous discharge, which are characterized by the formation of two different associations of microelements in the lake water. The composition of microelements in fissure-vein waters is determined by their interaction degrees with rocks.
本研究的目的是确定科托克尔湖深水的主要水化学参数,确定地下水对其的补给作用,建立湖泊宏量元素和微量元素的空间分布特征。野外工作是在结冰和不结冰的季节进行的。一种特殊的采样器被用来从湖底采集水样。水样在取样处使用孔径为0.45 μm的过滤器进行过滤。用塑料瓶装水样进行分析。水样微量元素采用0.1 N硝酸预处理的聚丙烯容器(15 ml)。根据淡水和咸水的标准方法,在俄罗斯科学院西伯利亚分院地质研究所(乌兰乌德)经认证的水文地质学和地质生态学实验室对水的宏观成分组成进行了分析。阳离子(Ca2+、Mg2+、Na+、K+)用原子吸收法测定,F-、SiO2 -用比色法测定,HCO3-、CO32-、Cl-用滴定法测定,SO42-用比浊法测定。微量元素的分析在俄罗斯科学院西伯利亚分院湖泊研究所(伊尔库茨克)水生微生物实验室进行,采用电感耦合等离子体法,在安捷伦7500ce四极杆质谱仪上进行。所进行的研究使人们有可能确定与裂缝脉水沿断层排放有关的湖水化学成分不均匀,这些断层从东南和东北束缚了洼地,并与从岛屿到伊斯托克河的湖泊水域相交。在Monastyrsky岛和湖西岸之间的海峡中,溶解物质的含量最高;碳酸盐离子和总矿化值均在此出现最大值。硫酸根离子含量最高的是南湖和东湖。微量元素分布中的色散达到几个数量级。最易变化的浓度是铁、锰、铜、锌、铅、磷、钼、钨、锶的特征。它们在东北走向断裂位置的湖水中含量较高。因此,科托克尔湖水体的化学成分主要由裂隙脉水组成。这些水沿着东北走向的构造断层排出。研究发现了两个水下排放中心,其特征是湖水中微量元素形成了两种不同的组合。裂隙脉水中微量元素的组成取决于它们与岩石的相互作用程度。
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引用次数: 1
Hydrogeological dissimilarity of geodynamically different terranes 不同地质体的水文地质差异性
Pub Date : 2021-06-17 DOI: 10.21285/2686-9993-2021-44-2-134-140
V. Glotov
The article presents and analyzes the data on ground waters of active (suprapermafrost) and hindered (subpermafrost) water exchange of geodynamically different terrains in order to prove the hydrogeological importance of their historical and tectonic characteristics. On the example of Trans-Polar Chukotka it is shown that, under suprapermafrost conditions, the ubiquitous eluvial-deluvial nappes are the most water-abundant on the terrane – a fragment of the passive continental margin, whereas they are the least water-abundant on the terrains of the active margin. Hydrogeological situation changes under subpermafrost conditions: more permeable and water-retaining rocks compose the terranes of the active margin. These differences are associated with the level of rock tectonic decompaction and, accordingly, with different intensity of weathering processes in the terrane rocks of different geodynamic origin in suprapermafrost and subpermafrost conditions. The hypergenesis zone on the terranes of the passive continental margin features coarse-grained rock weathering products accumulated in relatively calm geological and historical environments, the aggregate is sandy. The terranes of the active margin, which underwent long-term subvertical and subhorizontal displacements contain more fine-grained weathering products; the aggregate includes sandy loam and clay sand. Since the permafrost strata in both Trans-Polar Chukotka and Eastern Siberia is greater than the depth of hypergene transformations, the terranes of the active continental margin, the rocks of which were impacted by tectonic decompaction processes, mainly of a strike-slip and thrust nature, feature greater water abundance in subpermafrost conditions.
本文介绍和分析了地球动力学上不同地形的活跃(上层)和受阻(下层)水交换的地下水资料,以证明其历史和构造特征的水文地质意义。以跨极楚科奇为例,表明在上冻土条件下,无处不在的淋积-洪积推覆体在被动大陆边缘的地形上是最富水的,而在活动大陆边缘的地形上是最不富水的。在次多年冻土条件下,水文地质情况发生了变化:活动边缘的岩层具有更多的渗透性和保水性。这些差异与岩石构造分解程度有关,因此与不同地球动力成因的地质体在上冻土和次冻土条件下的风化作用强度不同有关。被动大陆边缘地体上的增生带以相对平静的地质历史环境下沉积的粗粒岩石风化产物为特征,骨料为砂质。活动边缘的地层经历了长期的亚垂直和亚水平位移,含有较多的细粒风化产物;骨料包括砂壤土和粘土砂。由于跨极地楚科奇和东西伯利亚的多年冻土地层都大于超生转化的深度,活动大陆边缘的岩层受构造分解作用的影响,主要是走滑和逆冲性质,在亚多年冻土条件下具有更大的水丰度。
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引用次数: 0
Innovative solutions in construction of deep industrial brine, oil and gas wells in deformable fractured reservoirs 可变形裂缝性储层深层工业盐水井、油气井施工的创新解决方案
Pub Date : 2021-06-17 DOI: 10.21285/2686-9993-2021-44-2-125-133
A. Vakhromeev, S. Sverkunov, R. Akchurin, V. M. Ivanishin, V. Ruzhich, I. Tashkevich, M. A. Lisitsyn
The paper deals with the methodological features of drilling and completion of wells in the fractured natural reservoirs containing oil and gas accumulations with different reservoir pressures of fluid-pressure systems from abnormally high to abnormally low. The authors had studied the fluid-pressure systems of industrial lithium-bromine brines, oil and gas fields and accumulations in the south of the Siberian platform for the period from 1983 to 2019. The article summarizes the main results, including new technical solutions protected by the Russian Federation patents. The authors proposed and patented a series of new technical solutions for the immediate consolidation of natural permeable fractures during the primary opening of the reservoir by drilling, as applied to a fractured reservoir. The main task of the study is to preserve the permeability of the fractured system in the bottomhole formation zone under the action of compressive stresses (rock mass) that increase with the formation of a drawdown cone, primarily in the bottomhole formation zone with the increase in the drawdown (ΔP) above critical values. Such an area is the bottomhole formation zone within a radius of the first meters around the well that penetrated the fractured reservoir. Practice has proved that the use of innovative solutions through the advanced consolidation of permeable fractures in the bottomhole formation zone (of fluid-producing oil- and gas-bearing, water-bearing reservoir) in the open (initial natural) state ensures the preservation of natural permeability of natural filtering fractures of the reservoir with the fluid system reservoir pressure from anomalously low to abnormally high. The solution ensures constant permeability of the fractured filtration system throughout the cleaning cycles of the bottomhole formation zone rocks from drilling mud, obtaining of the true calculated hydrodynamic parameters based on the results of well testing in the modes of the “steady-state production method” and well flow rate (productivity) stabilization under further well operation.
本文论述了不同流体压力系统的储层压力从异常高到异常低的裂缝性含油气油藏的钻完井方法特点。作者在1983年至2019年期间研究了西伯利亚平台南部工业锂-溴卤水,油气田和聚集的流体压力系统。文章总结了主要成果,包括受俄罗斯联邦专利保护的新技术解决方案。作者提出并申请了一系列新的技术解决方案,用于裂缝性油藏在油藏初开期间通过钻井对天然渗透性裂缝进行即时固结。该研究的主要任务是在压应力(岩体)的作用下,在井底地层区域内保持裂缝系统的渗透率,压应力(岩体)随着压降锥的形成而增加,特别是在井底地层区域,压降(ΔP)大于临界值。该区域是指在裂缝性储层井周围半径为1米的井底地层区。实践证明,在流体系统储层压力由异常低到异常高的情况下,采用创新的解决方案,在井底地层带(产液含油气、含水储层)处于开放(初始自然)状态时,通过对渗透性裂缝进行超前固结,保证了储层天然过滤裂缝的天然渗透率。该解决方案确保了压裂过滤系统在井底地层地层泥浆清洗周期内的渗透率恒定,并根据“稳态生产法”模式下的试井结果获得了真实的计算水动力参数,并在后续井作业中稳定了井流量(产能)。
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引用次数: 0
Structural features and formation processes of a complex hydrogeochemical section in the Baikal rift zone 贝加尔湖裂谷带复杂水文地球化学剖面构造特征及形成过程
Pub Date : 2021-06-17 DOI: 10.21285/2686-9993-2021-44-2-159-166
S. K. Pavlov
The purpose of the work is to study the effect of organic matter on the formation of ion-salt and gas composition of nitrogen-methane and methane thermal water occurring in the sedimentary rocks of deep horizons of artesian basins. The object of research is the Tunka intermountain artesian basin of the Baikal rift zone and the Tungor gas and oil field of the Okhotsk-Sakhalin basin, in the deep horizons of which soda (inversion) low- and high-mineralized groundwater is common. The study combines the results of the traditional study of the composition of natural solutions and the quantitative research of physical and chemical interactions in the “water – rock” system conducted using the Selector software package according to the degree of the hydrogeochemical process, which was set by the value of the rock/water ratio. Chemically pure water and rocks of medium chemical composition were used in interaction. With the use of physicochemical modeling the formation of thermal water composition in sedimentary rocks depending on the interaction degree between water and rock and the amount of organic matter was unravelled. As a result, it was determined that the organic matter present in the rock has the dominant influence on the intensity of the hydrogeochemical process determining the amount of mineralization, the ratio of components, and the amount of methane, nitrogen, and carbon dioxide produced. The correspondent compositions of the model and natural solutions showed the possibility to form low- and high-mineralized sodium bicarbonate groundwater of different gas-saturation degree in the conditions of deep horizons of sedimentary basins due to the internal reserves of the “water – rock” system not involving any components from external sources.
研究了自流盆地深层沉积岩中有机质对离子盐形成、氮-甲烷气体组成和甲烷热水的影响。研究对象为贝加尔湖裂谷带的Tunka山间自流盆地和鄂霍次克-萨哈林盆地的Tungor气、油田,该盆地深层普遍存在碳酸(反转)低矿化度和高矿化度地下水。本研究将传统的自然溶液组成研究成果与“水-岩”系统中物理化学相互作用的定量研究成果结合起来,根据水地球化学过程的程度,由岩/水比的数值设定。相互作用采用化学纯净水和中等化学成分的岩石。利用物理化学模型揭示了沉积岩中热水成分的形成取决于水岩相互作用程度和有机质含量。因此,确定岩石中存在的有机质对水文地球化学过程的强度具有主导影响,该过程决定了矿化量、成分比例以及甲烷、氮和二氧化碳的产量。模型与自然溶液的对应组成表明,在沉积盆地深层条件下,由于“水-岩”体系的内部储量不含任何外源成分,有可能形成不同气饱和度的低矿化度和高矿化度碳酸氢钠地下水。
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引用次数: 0
Analysis of permafrost effect on water exchange processes 冻土对水交换过程的影响分析
Pub Date : 2021-06-17 DOI: 10.21285/2686-9993-2021-44-2-184-190
V. Shepelev
The article focuses on the importance of studying the water exchange role of the permafrost, which currently occupies a quarter of the Earth's land and is 1.5 km deep in some regions, as well as assessing the permafrost impact on the formation of surface and ground water resources and regime. First of all, the permafrost water exchange function is associated with the freezing of water-saturated rocks and thawing of ice-saturated ones. The author gives individual consideration to the water exchange role of the active layer and the effect of the permafrost long-term dynamics on water exchange direction and scale. The water exchange function of the active layer appears due to the seasonal phase transitions of groundwater from a liquid to a solid state and back. Thus, the volume of water formed by the thawing of underground ice accumulated in the active layer in winter has been estimated about 4·1012 m3. In this regard, it is proposed to give cryohydrogenic part associated with the seasonal transitions of groundwater from the liquid to solid state and back in the active layer of the cryolithozone independent consideration within the hydrological (climatic) cycle of the natural water circulation. It is most certain that the permafrost water exchange function is more significant being associated with longterm permafrost development dynamics under the influence of periodic dramatic climate fluctuations. Thus, during the Holocene climatic optimum about 4.5·1015 m3 of underground ice was converted to the liquid phase. The intensity of water formed from the melting of this amount of ice inflowing its surface and underground reservoirs has been estimated about 820 km3 per year. This fact considered, the author proposes to consider the cryolithogenic part separately in the geological cycle of the natural water cycle.
本文着重强调了研究永久冻土的水交换作用的重要性,永久冻土目前占据了地球陆地的四分之一,在一些地区深达1.5公里,并评估了永久冻土对地表水和地下水资源和状态形成的影响。首先,多年冻土的水交换功能与水饱和岩石的冻结和冰饱和岩石的融化有关。单独考虑了活动层的换水作用和多年冻土长期动态对换水方向和尺度的影响。活动层的水交换功能是由于地下水从液态到固态再返回的季节性相变而出现的。因此,冬季活动层中积累的地下冰融化形成的水量估计约为4·1012 m3。因此,建议在自然水循环的水文(气候)循环中,独立考虑与冰冻岩石带活跃层中地下水从液态到固态再返回的季节转换有关的低温生氢部分。可以肯定的是,在周期性剧烈气候波动的影响下,多年冻土水交换功能与多年冻土的长期发展动态有关。因此,在全新世气候最佳时期,约有4.5·1015 m3的地下冰转化为液相。流入其地表和地下水库的这些冰融化后形成的水的强度估计约为每年820立方千米。考虑到这一事实,笔者建议在自然水循环的地质循环中单独考虑冰岩形成部分。
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引用次数: 0
Polyarene analysis-based identification of natural and technogenic processes in underground hydrosphere 基于聚芳烃分析的地下水圈自然和工艺过程识别
Pub Date : 2021-06-16 DOI: 10.21285/2686-9993-2021-44-2-167-173
A. Khaustov, M. Redina
The purpose of the study is to analyze the possibility to identify the pollution genesis of the underground hydrosphere based on the data on polyarenes as geochemical markers. Their marker role is due to their toxicity, persistence and confinement to specific pollution sources and natural and technogenic processes. The main research method is the analysis of indicator ratios of polyarenes. The object of research is groundwater from different regions of the world, which are polluted by natural and anthropogenic polyarenes. The main directions of domestic and foreign researches as well as the problems of their implementation are shown. The use of indicator ratios enabled successful identification of pyro- and petrogenically polluted samples of groundwater also the examples of the study of polyarenes as geochemical markers were demonstrated. The polyarenes are shown to be an effective indicator of the pollution genesis in the underground hydrosphere. However, their analysis requires the use of modern methods of sampling, sample preparation and extraction, which significantly complicates research in practice.
本研究旨在探讨以聚芳烃为地球化学标记物,识别地下水圈污染成因的可能性。它们的标志作用是由于它们的毒性、持久性和对特定污染源以及自然和技术过程的限制。主要的研究方法是对聚芳烃的指示剂配比进行分析。研究对象是来自世界不同地区的地下水,这些地下水受到自然和人为的多芳烃污染。指出了国内外研究的主要方向和实施中存在的问题。指示剂比值的使用使地下水的热岩污染样品得以成功识别,并举例说明了聚芳烃作为地球化学标志的研究。聚芳烃是地下水圈污染成因的有效指标。然而,它们的分析需要使用现代的采样、样品制备和提取方法,这大大复杂化了实践中的研究。
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引用次数: 0
Identification of Osinsky horizon organogenic structures by 2D and 3D seismic survey data in the north-eastern part of the Nepa-Botuoba anteclise Nepa-Botuoba前陆东北段二维和三维地震资料识别Osinsky层位有机构造
Pub Date : 2021-04-05 DOI: 10.21285/2686-9993-2021-44-1-30-38
R. S. Urenko, A. Vakhromeev
The fields of Eastern Siberia belong to the one of the main centers of hydrocarbon production in the eastern part of Russia. The main part of hydrocarbon reserves is located in the area within the Nepa-Botuoba anteclise, where the Lower Cambrian deposits are major production objects. The main purpose of this research is to provide a detailed study of the inner space and features of organogenic structures of the Cambrian period, as well as to determine the procedures for detecting reef structures by seismic research methods. Statistical processing of the available factual material on reservoir properties has shown a very uneven distribution of cavernosity (porosity). It is found that pores were formed as a result of leaching of shaped formations in loose packing locations of epigenetic dolomite grains, along the cementing substance in the intergranular spaces, along cracks and stylolite seams. To identify organogenic structures in the Osinsky horizon of the Nepa-Botuoba anteclise on the basis of seismic studies some additional methodologies have been selected. Identification of single reef structures in the Osinsky horizon of the Lower Cambrian based on the analysis of seismic amplitudes was carried out by means of a 2D and 3D seismic survey. According to the data of seismic studies, the Nepa-Botuoba anteclise features the development zones of both linear and single carbonate structures. It is also revealed that there is an increase in effective thicknesses in wells located in the annular anomaly. Summing up the results and analyzing the compared materials, it can be concluded that the main identification method of ring zones in wells is the method of longitudinal wave slowness measurement. A comprehensive analysis of 2D and 3D seismic survey data by the common depth point method as well as by a number of other methods using a specific algorithm allowed us to identify individual formations of organogenic (riphogenic) structures in the carbonate section of the north-eastern part of the Nepa-Botuoba anteclise.
东西伯利亚油田是俄罗斯东部主要的油气生产中心之一。油气储量主要分布在内帕—博图巴前陆内,下寒武统矿床是该区的主要生产对象。本研究的主要目的是对寒武纪生物成因构造的内部空间和特征进行详细的研究,并确定用地震研究方法探测生物礁构造的程序。对现有储层物性事实资料的统计处理表明,海绵体(孔隙度)分布极不均匀。研究发现,孔隙的形成是由于在后成白云岩颗粒松散充填位置、沿粒间胶结物质、沿裂缝和柱面岩缝的浸出形成的。为了在地震研究的基础上识别Nepa-Botuoba前陆Osinsky层的有机构造,选择了一些额外的方法。通过二维和三维地震调查,在地震振幅分析的基础上,对下寒武统奥辛斯基层单礁构造进行了识别。根据地震研究资料,Nepa-Botuoba前陆具有线状和单一碳酸盐岩构造发育带。研究还发现,位于环空异常区内的井有效厚度有所增加。总结研究结果并对对比资料进行分析,认为井中圈层识别的主要方法是纵波慢度测量法。通过对2D和3D地震调查数据的综合分析,利用普通深度点法以及使用特定算法的许多其他方法,我们能够识别Nepa-Botuoba前陆东北部碳酸盐岩剖面的有机(产核)结构的单个地层。
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引用次数: 0
Gemological and mineralogical-petrographic study of the Eastern Sayan serpentinites 东萨延蛇纹岩的宝石学和矿物学岩石学研究
Pub Date : 2021-04-05 DOI: 10.21285/2686-9993-2021-44-1-48-55
A. Anisimova
The purpose of the research is to study the mineralogical and petrographic characteristics of the Eastern Sayan serpentinites in order to identify their most decorative varieties. The objects of the study are the samples of serpentinites from the Ulan-Khodinskoye and Khokhurtovskoye deposits of the Eastern Sayan. Six samples were studied macroscopically then polished plates were made from them for gemological examination and thin sections for microscopic examination. All studies were carried out using standard gemological methods at the Gemmology Research Laboratory of the Irkutsk National Research Technical University. The petrographic study of thin sections was carried out using an Axio Lab A1 microscope. Macroscopically, two main ornamental varieties of serpentinite were identified: spotted bluish-green serpentinite and massive serpentinite of the color from dark green to black. The spotted structure of serpentinite is determined by numerous inclusions of ore minerals including magnetite and iron oxides. Its hardness is 4.5 on the Moh’s scale, its gloss is matte. The data on the main gemological characteristics of the samples corresponding to the results of already published studies of gem-quality serpentinites from other deposits were also obtained. Having analyzed the microstructure and mineral composition of the Eastern Sayan serpentinites, their correspondence to the spotty and massive decorative varieties of serpentinites from other Russian deposits was revealed. At the moment, this material is not duly appreciated, although it may well be used as a sculptural and jewelry-ornamental decorative stone.
本研究的目的是研究东萨延蛇纹岩的矿物学和岩石学特征,以确定其最具装饰性的品种。研究对象为东萨扬地区乌兰-霍金斯科耶和霍库尔托夫斯科耶矿床的蛇纹岩样品。对6个样品进行了宏观研究,然后制作了抛光板进行宝石学检查和薄片进行显微镜检查。所有研究都是在伊尔库茨克国立研究技术大学宝石学研究实验室使用标准的宝石学方法进行的。薄片岩石学研究采用Axio Lab A1显微镜进行。宏观上鉴定出两种主要的观赏蛇纹石品种:斑点蓝绿色蛇纹石和块状蛇纹石,颜色从墨绿色到黑色不等。蛇纹岩的斑点结构是由包括磁铁矿和氧化铁在内的许多矿石矿物包裹体决定的。其硬度为莫氏硬度4.5,光泽度为哑光。还获得了样品的主要宝石学特征数据,这些数据与已经发表的关于其他矿床的宝石级蛇纹岩的研究结果相对应。通过对东萨延蛇纹岩微观结构和矿物组成的分析,揭示了其与俄罗斯其他矿床的斑状和块状装饰型蛇纹岩的对应关系。目前,这种材料还没有得到充分的重视,尽管它可以很好地用作雕塑和珠宝装饰石材。
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引用次数: 0
Surface structure of Amur region high grade native gold 黑龙江地区高品位原生金的表面结构
Pub Date : 2021-04-05 DOI: 10.21285/2686-9993-2021-44-1-39-47
М. Радомский, S. Radomskiy, V. Radomskaya
The purpose of the research is to study the surface structure of high grade gold. The subject of research is gold ore fields in the Amur region. The object of the study is samples of native high grade gold grains from these fields. The study uses the methods of thermodynamics and X-ray electron microscopy. The study results in revealing a multilayer structure of the surface of high grade minerals of the Amur region native gold with the following levels: a boundary layer with zero oxidation degree Au0 in the form of yellow metallic gold; an oxide layer with the oxidation degree Au+1 in the form of purple Au2O; an oxide layer with the oxidation degree Au+3 in the form of a yellow-brown Au2O3; a hydrated oxide layer with the oxidation degree Au+3 in the form of a red-yellow-brown Au(OH)3. The methods of electron microscopy have allowed to identify external surface structures – dense oxide layers of the form of Au2O3 and loose hydrated layers of the form of Au(OH)3, whereas the inner layers of metallic and monovalent gold are not visible. Important thermodynamic characteristics of the presented levels are the values of standard oxidation-reduction potentials (E°), which determine their physicochemical properties: for metallic gold E° = +1.68 V; for the oxide layer with the oxidation degree Au+1 in the form of Au2O – E° = +0.32 V; for the oxide layer with the oxidation degree Au+3 in the form of Au2O3 – E° = +1.36 V; for the hydrated oxide layer with the oxidation degree Au+3 in the form of Au(OH)3 – E° = +0.7 V. The results of the conducted studies indicate that the surface structure has several layers that lower the oxidation-reduction potential, which explains the generation and formation of migratory forms of gold in humid hypergene conditions of natural environment.
本研究的目的是研究高品位金的表面结构。本文的研究对象是阿穆尔河地区的金矿田。研究对象是这些矿区的原生高品位金颗粒样品。研究采用了热力学和x射线电子显微镜的方法。研究结果揭示了阿穆尔河地区原生金高品位矿物表面的多层结构,其层次为:以黄色金属金形式存在的零氧化度Au0的边界层;氧化度为Au+1的氧化层,呈紫色Au2O;氧化度为Au+3的氧化层以黄棕色Au2O3的形式存在;氧化度为Au+3的水合氧化层,呈红黄褐色Au(OH)3的形式。电子显微镜的方法已经允许识别外部表面结构- Au2O3形式的致密氧化层和Au(OH)3形式的松散水合层,而金属和单价金的内层是不可见的。标准氧化还原电位(E°)的值决定了它们的物理化学性质:对于金属金E°= +1.68 V;氧化度为Au+1的氧化层形式为Au2O - E°= +0.32 V;氧化度为Au+3的氧化层形式为Au2O3 - E°= +1.36 V;对于氧化度为Au+3的水合氧化层,形式为Au(OH)3 - E°= +0.7 V。研究结果表明,表面结构具有多层结构,降低了氧化还原电位,这解释了金在自然环境湿润的高生条件下迁移形式的产生和形成。
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引用次数: 0
Improving design and application method of screening bucket excavators 改进筛分斗式挖掘机的设计和使用方法
Pub Date : 2021-04-05 DOI: 10.21285/2686-9993-2021-44-1-56-62
A. Cheban
The purpose of the study is to increase the productivity and economic efficiency of mining operations using screening bucket excavators on the basis of the introduction of a new technical and technological solution that expands equipment functionality. The study involves the analysis of known designs of screening buckets installed on excavators that ensure material separation to be carried out simultaneously with excavation and loading works. It is noted that a promising development direction of screening buckets is a design with working drums. The article presents an excavator with a modernized screening bucket and its operation technology, which allows to start rock mass sorting in the bucket while the excavator is turning to the place of unloading. The improved screening bucket is equipped with a hinged movable bottom controlled by hydraulic cylinders to accumulate fine fractions screened through the working drums. Fine fractions accumulated in the moving bottom are unloaded into a dump truck, after which screening continues directly into the body of the dump truck. Screening finished, the movable bottom closes and the excavator unloads the coarse fractions remaining in the bucket into another vehicle. Unloading is carried out by bucket turning. The combination of screening and excavator turning reduces the operation cycle time, which increases the performance of both the excavator and dump trucks. The use of a modernized screening bucket with a moving bottom eliminates the loss of valuable fine material as a result of spilling when the excavator turns for unloading. The movable bottom can be installed on the screening buckets of known designs and does not require their significant alteration. Application of the proposed technical and technological solution will reduce unit costs and increase the efficiency of work.
这项研究的目的是在引进扩大设备功能的新技术和技术解决方案的基础上,提高使用筛选斗式挖掘机采矿作业的生产力和经济效率。该研究包括对安装在挖掘机上的筛分桶的已知设计进行分析,以确保物料分离与挖掘和装载工作同时进行。有工作滚筒的筛分斗设计是筛分斗的发展方向。本文介绍了一种采用现代化筛斗的挖掘机及其操作技术,可以在挖掘机转向卸料地点时,在筛斗内开始进行岩体分选。改进后的筛斗配有液压缸控制的铰接活动底,可将筛出的细粒通过工作滚筒进行堆积。堆积在动底的细粒被卸入自卸车,然后筛分继续直接进入自卸车车体。筛分完成后,活动底关闭,挖掘机将铲斗中剩余的粗馏分卸至另一车辆。卸料是通过翻斗进行的。筛分与挖掘机回转相结合,减少了作业周期时间,提高了挖掘机和自卸车的性能。使用带有移动底的现代化筛斗,消除了挖掘机转弯卸载时因溢出而造成的宝贵细料损失。活动底可以安装在已知设计的筛斗上,不需要对其进行重大改造。提出的技术和工艺方案的应用将降低单位成本,提高工作效率。
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引用次数: 1
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Earth sciences and subsoil use
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