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Sound velocity anomalies of limestone at high pressure and implications for the mantle wedge 高压下灰岩声速异常及其对地幔楔的指示意义
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-10-02 DOI: 10.1080/08957959.2022.2145562
F. Sun, Ying Li, Qiang He, Lei Liu, Zhigang Wang, Chaowen Xu, Yueju Cui, Yi Zhang, Q. Gong, J. Du
ABSTRACT Limestone mainly consisting of CaCO3 is one of the most abundant carbonates on Earth's surface. The sound velocities of limestone at high pressure were determined at room temperature using ultrasonic interferometry in a multi-anvil apparatus. Softening and discontinuities in compressional (P) and shear (S) wave velocities have been observed at around 1.45 GPa due to the phase transition of CaCO3-I to CaCO3-II, and the coexistence of CaCO3-IIIb and CaCO3-III stay up to ∼5 GPa. Limestone under CaCO3-I and CaCO3-III phase has much lower velocities and higher V P/V S ratio than most crustal and mantle minerals and the PREM model. Phase transitions from CaCO3-I to CaCO3-II cause the abrupt reduction of V P, V S, and V P/V S. The low velocities and high/low V P/V S ratio are well consistent with the seismology observed in the mantle wedge. The result suggests that the subduction of limestone into Earth's interior would cause low-velocity anomalies in mantle wedges.
石灰石主要由CaCO3组成,是地球表面最丰富的碳酸盐之一。在多砧装置中使用超声波干涉测量法在室温下测定了石灰石在高压下的声速。在1.45左右观察到压缩(P)和剪切(S)波速度的软化和不连续性 由于CaCO3-I向CaCO3 II的相变,以及CaCO3 IIIb和CaCO3 III的共存,GPa保持在~5 GPa。与大多数地壳和地幔矿物以及PREM模型相比,CaCO3-I和CaCO3-III相下的石灰岩具有更低的速度和更高的V P/V S比。从CaCO3-I到CaCO3-II的相变导致V P、V S和V P/V S的突然降低。低速和高/低V P/V S比与在地幔楔中观察到的地震学非常一致。研究结果表明,石灰岩向地球内部的俯冲将导致地幔楔低速异常。
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引用次数: 0
The structure of sc16 GaP obtained at 17.5 GPa and 1400 K sc16的结构 在17.5获得的GaP GPa和1400 K
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-07-03 DOI: 10.1080/08957959.2022.2113874
B. Lavina, E. Zanardi, A. Mujica, H. Cynn, Y. Meng, J.S. Smith, M. Kong, Y. Lee
ABSTRACT Using a laser-heated diamond anvil cell, a powdered sample of gallium phosphide was compressed to 17.5 GPa and heated up to 1400 K. The material obtained was characterized at room temperature using synchrotron x-ray diffraction. Experimental results were compared with first-principles calculations. The polymorph observed assumes the simple cubic structure (sc16) initially reported for GaAs at high pressures. Microdiffraction mapping showed variable grain sizes of the synthesized phase, with the largest grains located in the middle of the heated spot. Structural refinements were performed on selected grains. The structure predicted based on first-principles calculations is in close agreement with the experiments. The two Ga–P bonds show similar lengths in sc16-GaP; however, the bond angles differ, resulting in a distorted tetrahedral coordination geometry.
利用激光加热的金刚石砧细胞,将磷化镓粉末样品压缩到17.5 GPa,加热到1400 K。用同步加速器x射线衍射在室温下对所得材料进行了表征。实验结果与第一性原理计算结果进行了比较。观察到的多晶体呈现出最初报道的GaAs在高压下的简单立方结构(sc16)。微衍射图显示合成相的晶粒大小变化,最大的晶粒位于受热点的中间。对选定的晶粒进行了结构细化。根据第一性原理计算预测的结构与实验结果非常吻合。两个Ga-P键在sc16-GaP中显示出相似的长度;然而,键角不同,导致扭曲的四面体配位几何。
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引用次数: 0
The systems KCl–CaCO3 and KCl–MgCO3 at 6 GPa 系统KCl–CaCO3和KCl–MgCO3在6 GPa
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-07-03 DOI: 10.1080/08957959.2022.2102426
I. Podborodnikov, A. Shatskiy, A. Arefiev, A. Bekhtenova, K. Litasov
ABSTRACT Continuous variations in the composition of melt inclusions in diamonds from K-rich saline to carbonatitic indicate their possible genetic relationship. This causes interest in the study of chloride-carbonate systems at high pressure. Here we present experimental data on phase relations in the KCl–CaCO3 and KCl–MgCO3 systems at 6 GPa and 1000–1600 °C. The studied systems have the eutectic type of T-X diagrams. Subsolidus phases are represented by aragonite + KCl and magnesite + KCl. The KCl–CaCO3 eutectic is situated at 1200 °C and K2# 20, while the KCl–MgCO3 eutectic is located at 1400 °C and K2# 43, where K2# = 2KCl/(2KCl + CaCO3 + MgCO3)×100 mol%. The concentration of K and Cl in water-soluble chloride, and Ca, Mg, and CO2 in carbonate suggests that K-rich saline fluid entrapped by ‘fibrous’ diamonds could be a low-temperature derivative of a carbonatite melt containing KCl and H2O.
金刚石熔体包裹体组成从富钾盐酸盐到碳酸盐岩的连续变化表明它们之间可能的成因关系。这引起了人们对高压下氯化物-碳酸盐岩体系研究的兴趣。本文给出了KCl-CaCO3和KCl-MgCO3体系在6 GPa和1000-1600℃条件下相关系的实验数据。所研究的体系具有共晶型的T-X图。亚固相以文石+ KCl和菱镁矿+ KCl为代表。KCl-CaCO3共晶位于1200℃和K2# 20,而KCl-MgCO3共晶位于1400℃和K2# 43,其中K2# = 2KCl/(2KCl + CaCO3 + MgCO3)×100 mol%。水溶性氯化物中K和Cl的浓度以及碳酸盐中Ca、Mg和CO2的浓度表明,被“纤维状”钻石包裹的富K盐流体可能是含有KCl和H2O的碳酸盐熔体的低温衍生物。
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引用次数: 1
Performances of a VIPA-based spectrometer for Brillouin scattering experiments in the diamond anvil cell under laser heating 基于VIPA的光谱仪在激光加热下金刚石砧座室布里渊散射实验中的性能
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-07-03 DOI: 10.1080/08957959.2022.2109968
A. Forestier, G. Weck, F. Datchi, P. Loubeyre
ABSTRACT VIPA-based Brillouin spectroscopy is implemented for in-situ measurements at high pressure and temperature in laser-heated diamond anvil cells. Its performances are compared to those of the widely used Tandem Fabry–Perot instrument. A significant reduction of the collection time is in particular enabled. The usefulness of VIPA-Brillouin spectroscopy for High Pressure studies is here illustrated by revisiting the nitrogen melting curve up to 45 GPa. VIPA-Brillouin spectroscopy has the potential to become an important platform to investigate the equation of state properties of warm dense molecular systems.
基于VIPA的布里渊光谱用于激光加热金刚石砧座电池中高压和高温下的原位测量。它的性能与广泛使用的串联法布里-珀罗仪器进行了比较。特别是可以显著缩短收集时间。VIPA布里渊光谱在高压研究中的有用性在这里通过重新查看高达45的氮熔融曲线来说明 GPa。VIPA布里渊光谱有可能成为研究热稠密分子系统状态方程性质的重要平台。
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引用次数: 0
Reassessment of a bond correction method for in situ ultrasonic interferometry on elastic wave velocity measurement under high pressure and high temperature 原位超声干涉测量中键合校正方法在高压高温弹性波速测量中的再评价
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-07-03 DOI: 10.1080/08957959.2022.2112677
M. Noda, T. Inoue, T. Tsuchiya, Y. Higo
ABSTRACT A new bond correction method for simultaneous elastic wave velocity measurement of in situ synchrotron X-ray technique and ultrasonic interferometry combined with a Kawai type multi-anvil apparatus is developed to measure elastic wave velocity precisely. The new method was validated using data from the literature and new elastic constant data of gold obtained under high pressure and high-temperature conditions. Elastic wave velocities corrected using the new method show lower values than those obtained without bond correction and using the conventional method, which show good agreement with datasets by in situ Brillouin scattering measurement and ab initio calculation. When the sample length is 1 mm under ambient conditions, the corrected V P and V S became 3.7% and 1.6% lower, respectively, than values obtained without bond correction under 12 GPa and 900 K. Results show that correcting the bond effect is extremely important, especially when the sample length is less than 1 mm.
摘要为了精确测量弹性波速,提出了一种新的结合校正方法,该方法将同步加速器X射线原位技术和超声干涉测量技术结合Kawai型多砧装置同时测量弹性波速。使用文献数据和在高压和高温条件下获得的金的新弹性常数数据验证了新方法。使用新方法校正的弹性波速显示出比没有键校正和使用传统方法获得的弹性波速更低的值,这与通过原位布里渊散射测量和从头计算获得的数据集显示出良好的一致性。当样本长度为1时 在环境条件下,校正后的V P和V S分别比在12 GPa和900 K.结果表明,校正键合效应非常重要,尤其是当样品长度小于1时 毫米。
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引用次数: 1
Development of a hybrid piston cylinder cell for quasielastic neutron scattering experiments up to 1 GPa 用于高达1gpa准弹性中子散射实验的混合活塞缸池的研制
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-04-03 DOI: 10.1080/08957959.2022.2068954
T. Hattori, S. Ohira-Kawamura, T. Kawasaki
ABSTRACT We have developed a hybrid piston cylinder cell for quasielastic neutron scattering (QENS) experiments up to about 1 GPa. It consists of a fretted cylinder made of the high tensile steel (SNCM439) liner and the Al alloy (NA700) jacket. Performance tests revealed that the cell can withstand a pressure of 0.8 GPa without irreversible damage and has 4.4 times larger neutron transmission at 3.14 meV (5.10 Å in wavelength) than that of a conventional CuBe monobloc cylinder. Combined with the sample assembly devised for suppressing multiple scattering, high quality QENS spectra of water were obtained up to 0.8 GPa. This study illustrates the efficacy of the hybrid cylinders not only for increasing maximum available pressure but also manipulating the available pressure and the signal intensity, depending on the purpose of the experiments.
摘要:我们研制了一种用于准弹性中子散射(QENS)实验的混合式活塞缸实验池,实验强度约为1 GPa。它由高强度钢(SNCM439)衬垫和铝合金(NA700)护套制成的微动圆柱体组成。性能测试表明,该电池可以承受0.8 GPa的压力而不会造成不可逆损伤,并且在3.14 meV(波长5.10 Å)下的中子透射率是传统CuBe单体圆柱体的4.4倍。结合为抑制多重散射而设计的样品组件,获得了高达0.8 GPa的高质量水的QENS光谱。该研究表明,混合动力气缸不仅可以提高最大有效压力,还可以根据实验目的控制有效压力和信号强度。
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引用次数: 0
Review: inactivation of very heat-resistant spores of Bacilus sporothermodurans by high pressure treatment combined with others treatments 综述:高压处理与其他处理相结合对耐高温芽孢杆菌孢子的灭活
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-04-03 DOI: 10.1080/08957959.2022.2079978
C. Aouadhi, Mayasar I. Al-zaban, Albandary Nasser Alsaloom, A. Maaroufi
ABSTRACT Bacillus sporothermoduras spores are known to be very resistant to ultra heat treatment. It is able to germinate and growth in the final product causing the non-sterility of UHT milk. Indeed, the currently used methods for the preservation of dairy products are often not sufficient for the destruction of all the spores potentially present. Faced with the constraint of altering the organoleptic and nutritional quality of milk by increasing the temperature and/or the duration of the treatment, in order to inactivate the highly heat-resistant spores, it has therefore become essential to develop other processes more effective in completely inactivating these spores without modifying the organoleptic characteristics of the product. The use of non-thermal methods offers an interesting alternative to conventional thermal treatments. They inactivate microorganisms, in particular bacterial spores, while preserving the organoleptic and nutritional qualities of the treated product. As a result, they have received special attention in recent years. Consequently, this review aimed to summarize the related investigation on the inactivation of heat-resistant spores of Bacillus sporothermodurans by non-thermal methods.
众所周知,耐高温芽孢杆菌的孢子对超高温处理具有很强的抵抗力。它能够在最终产品中发芽和生长,导致UHT牛奶不无菌。事实上,目前使用的乳制品保存方法通常不足以破坏所有可能存在的孢子。面对通过提高温度和/或处理时间来改变牛奶的感官和营养质量的限制,为了灭活高度耐热的孢子,开发其他更有效的方法来完全灭活这些孢子而不改变产品的感官特性变得至关重要。非热方法的使用为传统热处理提供了一种有趣的替代方案。它们灭活微生物,特别是细菌孢子,同时保持处理产品的感官和营养品质。因此,近年来它们受到了特别关注。因此,本文旨在总结非热法灭活耐孢芽孢杆菌耐热孢子的相关研究。
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引用次数: 1
P-V-T equation of state of α-ScOOH. α-ScOOH的P-V-T状态方程。
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-04-03 DOI: 10.1080/08957959.2022.2089568
Yoshiaki Ito, O. Ikeda, T. Sakamaki, T. Kuribayashi, A. Suzuki
ABSTRACT In this study, an in situ X-ray diffraction study of α-ScOOH, scandium oxyhydroxide with a diaspore-type structure, was conducted at a pressure and temperature of up to 4.12 GPa and 700 K, respectively, to determine the pressure-volume-temperature (P-V-T) equation of state (EoS). Using a least-squares fit of the second-order Birch–Murnaghan EoS to the P-V-T data, the EoS parameters of α-ScOOH were determined as bulk modulus KT 0 = 101(1) GPa, (∂KT /∂T) P  = −0.009(5) GPa K−1, and thermal expansion coefficient at zero pressure α = 3.12(6) 10−5 K−1. α-ScOOH exhibits anisotropic compression and thermal expansion behaviors, which are consistent with those of previous studies on diaspore-type oxyhydroxides. α-ScOOH is more compressible than other diaspore-type oxyhydroxides, and the product of the bulk modulus and volume is approximately constant among diaspore-type M3 + OOH (M = Al, Sc, and Fe).
摘要在本研究中,在高达4.12的压力和温度下,对具有一水硬铝石型结构的氢氧化钪α-ScOOH进行了原位X射线衍射研究 GPa和700 K、 以确定压力-体积-温度(P-V-T)状态方程(EoS)。使用二阶Birch–Murnaghan EoS对P-V-T数据的最小二乘拟合,确定α-ScOOH的EoS参数为体积模量KT 0 = 101(1)GPa = −0.009(5)GPa K−1,零压力下的热膨胀系数α = 3.12(6)10−5 K−1。α-ScOOH表现出各向异性的压缩和热膨胀行为,这与先前对一水硬铝石型氢氧化物的研究一致。α-ScOOH比其他一水硬铝石型氢氧化物更具压缩性,并且体积模量和体积的乘积在M3一水硬硬铝石类型中近似恒定 + 哦(M = Al、Sc和Fe)。
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引用次数: 0
Progress and prospects for cuprate high temperature superconductors under pressure 铜酸盐高温高压超导体的研究进展与展望
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-04-03 DOI: 10.1080/08957959.2022.2059366
Alexander C. Mark, J. Campuzano, R. Hemley
ABSTRACT Since the discovery of high temperature superconductivity in at an unprecedented of 35 K over 35 years ago, high pressure experiments have played a critical role in bdeveloping cuprate superconductivity. Soon after its discovery, compression experiments on revealed a large / , motivating the study of ‘chemical pressure’ in the material that led to the 90 K Superconductor . Cuprate superconductors discovered subsequently exhibited a range of from 30 K to 140 K, including the commonly studied Bi, Tl, and Hg based families. Pressure has large effects on superconductivity in these materials, including raising in the Hg based cuprates from 140 K to 166 K at 30 GPa. Reviewing past experiments indicate that pressure dopes holes into the planes common to all cuprates. Further detailed high pressure studies of these materials should deepen our understanding of cuprate superconductivity and the possibility of reaching still higher in cuprates.
摘要自年发现高温超导电性以来,温度达到了前所未有的35 35年前,高压实验在铜酸盐超导电性的发展中发挥了关键作用。在它被发现后不久,上的压缩实验揭示了一个巨大的/,推动了对材料中“化学压力”的研究,从而导致了90 K超导。随后发现的铜超导体显示出30 K至140 K、 包括通常研究的Bi、Tl和Hg家族。压力对这些材料的超导性有很大影响,包括汞基铜酸盐从140 K至166 K在30 GPa。回顾过去的实验表明,压力将空穴掺杂到所有铜酸盐共有的平面中。对这些材料的进一步详细高压研究应该加深我们对铜酸盐超导性的理解,以及铜酸盐达到更高超导性的可能性。
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引用次数: 7
Measurement of shock and re-shock Hugoniot data of liquid nitrogen 液氮的冲击和再冲击Hugoniot数据的测量
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-01-02 DOI: 10.1080/08957959.2022.2030325
Muhammad Sabeeh Akram, Shumail Sattar, Zhuo-Ning Fan, Qi-jun Liu, Fu-sheng Liu
ABSTRACT In this work, the equation-of-state data for liquid nitrogen shock compressed to 43 GPa along the principal Hugoniot and reflected-shock data up to 91 GPa were reported. A cryogenic target was used to liquefy the gas that was then further compressed by high-speed impactors. The first- and second-shock states were observed by a high-precision Doppler pin system (DPS). Optical wavefrom of DPS resulted in the first-shock velocity from which other derivative quantities i.e. particle-velocity, specific-volume, internal-energy, and Grüneisen-parameter, were determined. Our results and published equation-of-state data were used to extrapolate the principal Hugoniot. Their comparison showed softening above 27 GPa, attributed to the absorption of thermal energy that dissociates the molecular nitrogen. Our single-shock data provided a good match to available Hugoniot data. The reduced velocity profiles allowed us to detect optical reflectance of the dissociated liquid phase, and the apparent shock-velocity was used to determine the true shock-velocity in dissociation threshold.
摘要在这项工作中,液氮冲击压缩到43的状态方程数据 主Hugoniot沿线的GPa和高达91的反射冲击数据 报告了GPa。低温靶被用来液化气体,然后由高速冲击器进一步压缩。利用高精度多普勒钉系统(DPS)观测了第一和第二激波状态。DPS的光波产生了第一冲击速度,由此确定了其他导数,即粒子速度、比体积、内能和Grüneisen参数。我们的结果和已发表的状态方程数据被用来推断主要的Hugoniot。他们的比较显示软化超过27 GPa,归因于对热能的吸收,使分子氮离解。我们的单次冲击数据与Hugoniot的可用数据非常匹配。降低的速度剖面使我们能够检测离解液相的光学反射率,表观冲击速度用于确定离解阈值中的真实冲击速度。
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引用次数: 1
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High Pressure Research
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