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Amorpheus: a Python-based software for the treatment of X-ray scattering data of amorphous and liquid systems Amorpheus:一个基于python的软件,用于处理非晶和液体系统的x射线散射数据
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-01-02 DOI: 10.1080/08957959.2022.2032032
S. Boccato, Y. Garino, G. Morard, B. Zhao, F. Xu, C. Sanloup, A. King, N. Guignot, A. Clark, G. Garbarino, M. Morand, D. Antonangeli
ABSTRACT The diffuse scattering signal of amorphous or liquid systems contains information on the local atomic structure, and this can be related to the density, compressibility, thermal expansion and other thermoelastic properties. However, the analysis and full exploitation of the diffuse scattering signal, in particular for systems under extreme conditions of high pressures and temperatures are difficult to handle. Amorpheus is a Python-based software allowing the determination of the structure factor and the radial distribution function of amorphous and liquid systems. Based on previously reported methodologies, Amorpheus stands out for the implementation of automatic algorithms allowing the user to choose the most suitable parameters for the data treatment and making possible systematic analysis of datasets collected in experiments carried out in Paris-Edinburgh press, multi-anvil apparatus or diamond anvil cell.
摘要非晶或液体系统的散射信号包含局部原子结构的信息,这可能与密度、压缩性、热膨胀和其他热弹性性质有关。然而,扩散散射信号的分析和充分利用,特别是对于在高压和高温的极端条件下的系统来说,是很难处理的。Amorpheus是一个基于Python的软件,允许确定非晶和液体系统的结构因子和径向分布函数。基于之前报道的方法,Amorpheus在实现自动算法方面脱颖而出,该算法允许用户选择最合适的参数进行数据处理,并使在巴黎-爱丁堡压机、多砧装置或金刚石砧室进行的实验中收集的数据集的系统分析成为可能。
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引用次数: 7
Social distancing and related factors during the COVID-19 pandemic in relation to COVID-19 symptoms and diagnosis and mental health. COVID-19 大流行期间的社会疏远和相关因素与 COVID-19 症状和诊断以及心理健康的关系。
4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2022-01-01 Epub Date: 2022-06-07 DOI: 10.1007/s10389-022-01722-2
Ruth Dickey-Chasins, Katelyn F Romm, Amita N Vyas, Karen McDonnell, Yan Wang, Yan Ma, Carla J Berg

Background: Many states, local authorities, organizations, and individuals have taken action to reduce the spread of COVID-19, particularly focused on restricting social interactions. Such actions have raised controversy regarding their implications for the spread of COVID-19 versus mental health.

Methods: We examined correlates of: (1) COVID symptoms and test results (i.e., no symptoms/tested negative, symptoms but not tested, tested positive), and (2) mental health symptoms (depressive/anxiety symptoms, COVID-related stress). Data were drawn from Fall 2020 surveys of young adults (n = 2576; M age = 24.67; 55.8% female; 31.0% sexual minority; 5.4% Black; 12.7% Asian; 11.1% Hispanic) in six metropolitan statistical areas (MSAs) with distinct COVID-related state orders. Correlates of interest included MSA, social distancing behaviors, employment status/nature, household composition, and political orientation.

Results: Overall, 3.0% tested positive for COVID-19; 7.0% had symptoms but no test; 29.1% reported at least moderate depressive/anxiety symptoms on the PHQ-4 Questionnaire. Correlates of testing positive (vs. having no symptoms) included residing in Oklahoma City vs. Boston, San Diego, or Seattle and less social distancing adherence; there were few differences between those without symptoms/negative test and those with symptoms but not tested. Correlates of greater depressive/anxiety symptoms included greater social distancing adherence, being unemployed/laid off (vs. working outside of the home), living with others (other than partners/children), and being Democrat but not Republican (vs. no lean); findings related to COVID-specific stress were similar.

Conclusion: Despite curbing the pandemic, social distancing and individual (e.g., political) and environmental factors that restrict social interaction have negative implications for mental health.

背景:许多州、地方当局、组织和个人都已采取行动来减少 COVID-19 的传播,尤其注重限制社会交往。这些行动对 COVID-19 的传播和心理健康的影响引起了争议:我们研究了以下方面的相关因素(1) COVID 症状和测试结果(即无症状/测试结果为阴性、有症状但未测试、测试结果为阳性),以及 (2) 心理健康症状(抑郁/焦虑症状、COVID 相关压力)。数据来自 2020 年秋季对六个大都会统计区(MSA)的年轻成年人(n = 2576;M 年龄 = 24.67;55.8% 为女性;31.0% 为性少数群体;5.4% 为黑人;12.7% 为亚裔;11.1% 为西班牙裔)进行的调查,这六个大都会统计区的 COVID 相关州令各不相同。相关因素包括大都会统计区、社会疏远行为、就业状况/性质、家庭构成和政治倾向:总体而言,3.0% 的人 COVID-19 检测呈阳性;7.0% 的人有症状但未检测;29.1% 的人在 PHQ-4 问卷上报告了至少中度抑郁/焦虑症状。检测结果呈阳性(与无症状相比)的相关因素包括居住在俄克拉荷马市与波士顿、圣地亚哥或西雅图之间的差异,以及较少的社会距离依从性;无症状/检测结果呈阴性者与有症状但未检测者之间的差异很小。更多抑郁/焦虑症状的相关因素包括:更多坚持社会疏远、失业/被解雇(与在外工作相比)、与他人同住(伴侣/子女除外)、是民主党人而非共和党人(与无党派人士相比);与 COVID 特定压力相关的研究结果相似:结论:尽管大流行病已经得到遏制,但社会疏远以及限制社会交往的个人(如政治)和环境因素会对心理健康产生负面影响。
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引用次数: 0
High pressure effect in the near-infrared emission of Nd3+-doped alkali silicate glasses 掺Nd3+碱硅酸盐玻璃近红外发射的高压效应
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-12-16 DOI: 10.1080/08957959.2021.2012570
Israel Roger Montoya Matos, N. Balzaretti
ABSTRACT The effect of high pressure (7.7 GPa) densification on the absorption and near-infrared emission of Nd-doped lithium, sodium and potassium disilicate glasses was investigated. Judd-Ofelt parameters Ωλ (λ = 2, 4 and 6) were calculated from the absorption spectra, before and after densification of glasses, indicating that the irreversible structural changes induced by pressure increased the symmetry of the Nd-O bonding. Density and refractive index of the glasses also increased, probably related to the close packing of SiO4 tetrahedra during densification. The magnitude of the splitting due to the Stark effect was larger for potassium silicate, before and after densification. The radiative transition probabilities of the hypersensitive transition for sodium and potassium silicate increased after densification while the radiative lifetime decreased. For lithium silicate, the opposite behavior was observed. The experimental results corroborate the influence of alkali ion and densification on the luminescence properties of Nd-doped alkali silicate glasses.
研究了高压(7.7GPa)致密化对掺钕二硅酸锂、钠和钾玻璃吸收和近红外发射的影响。Judd-Ofelt参数Ωλ(λ = 2、4和6),表明压力引起的不可逆结构变化增加了Nd-O键的对称性。玻璃的密度和折射率也有所增加,这可能与致密化过程中SiO4四面体的紧密堆积有关。在致密化前后,硅酸钾由于斯塔克效应引起的分裂幅度较大。致密化后硅酸钠和硅酸钾的超灵敏跃迁的辐射跃迁概率增加,而辐射寿命降低。对于硅酸锂,观察到相反的行为。实验结果证实了碱离子和致密化对掺钕碱硅酸盐玻璃发光性能的影响。
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引用次数: 0
Exploration of the best reference material on anelastic measurement by cyclic loading under high pressure 探索高压下循环载荷非弹性测量的最佳参考材料
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-12-13 DOI: 10.1080/08957959.2021.2013834
Chao Liu, T. Yoshino, D. Yamazaki, N. Tsujino, H. Gomi, M. Sakurai, Youyue Zhang, Ran Wang, L. Guan, Kayan Lau, Y. Tange, Y. Higo
ABSTRACT Anelastic measurement by cyclic loading under high pressure has been developed by means of in situ X-ray observation at a synchrotron facility. In this method, the reference material is a key factor to precisely determine attenuation and moduli of unknown materials. We compared the performance of three types of reference materials (dense polycrystalline alumina, alumina single-crystal parallel to c-axis, and flexible graphite) under the pressure of 3 GPa and the temperature range between 1173 and 1373 K. The phase lags of strain between reference materials and samples show that the flexible graphite is less attenuated than dense polycrystalline alumina and alumina single crystal in various periods. The strain ratios show that the flexible graphite is much softer and can produce the measurable strain in the limited displacement. The flexible graphite, as reference material, is more excellent to detect the relatively lower energy dispersion of mantle minerals at high pressure.
摘要在同步加速器装置上,通过原位X射线观测,发展了高压下循环加载的非弹性测量方法。在这种方法中,参考材料是精确确定未知材料衰减和模量的关键因素。我们比较了三种类型的参考材料(致密多晶氧化铝、平行于c轴的氧化铝单晶和柔性石墨)在3 GPa和1173到1373之间的温度范围 K.参考材料和样品之间的应变相位滞后表明,在不同时期,柔性石墨的衰减小于致密多晶氧化铝和氧化铝单晶。应变比表明,柔性石墨比柔性石墨软得多,能够在有限位移中产生可测量的应变。柔性石墨作为参考材料,在高压下检测地幔矿物相对较低的能量色散方面更为出色。
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引用次数: 1
Three-wall piston-cylinder type pressure cell for muon-spin rotation/relaxation experiments 用于介子自旋/弛豫实验的三壁活塞缸式压力池
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-10-05 DOI: 10.1080/08957959.2021.2013835
R. Khasanov, Ross Urquhart, M. Elender, K. Kamenev
ABSTRACT A three-wall piston-cylinder type high pressure cell for muon-spin rotation/relaxation experiments was designed, manufactured, tested and commissioned. The outer cylinder of the cell body is made from MP35N and the middle and inner cylinders are made from NiCrAl nonmagnetic alloys. The mechanical design and performance of the pressure cell are evaluated and optimised using finite-element analysis. The outcomes of the experimental testing closely match the modelling results. The high pressure cell is shown to reach pressure of up to 3.3 GPa at ambient temperature, corresponding to 3.0 GPa at low temperatures, without irreversible damage.
摘要设计、制造、测试并调试了用于μ介子自旋旋转/弛豫实验的三壁活塞-圆筒型高压电池。电池主体的外筒由MP35N制成,中间筒和内筒由NiCrAl非磁性合金制成。使用有限元分析对压力传感器的机械设计和性能进行了评估和优化。实验测试的结果与建模结果非常吻合。高压电池的压力高达3.3 环境温度下的GPa,相当于3.0 GPa在低温下,没有不可逆的损伤。
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引用次数: 4
Phase relations in the Fe-Fe3C-Fe3N system at 7.8 GPa and 1150°C: implications for C and N hosts in metal-saturated mantle 7.8 GPa和1150℃下Fe-Fe3C-Fe3N体系的相关系:对金属饱和地幔中C和N宿主的影响
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-10-02 DOI: 10.1080/08957959.2021.1998479
A. N. Kruk, Alexander A. Korablin, A. Sokol, Y. Palyanov
ABSTRACT The isothermal section of the Fe-Fe3C-Fe3N phase diagram at 7.8 GPa and 1150°С comprises a three-phase field of γ-Fe + Fe3C + ϵ-Fe3(С/N) in the central part and three two-phase fields (γ-Fe + Fe3C, γ-Fe + ϵ-Fe3 (С/N) and Fe3C + ϵ-Fe3(С/N)) bounded by three single-phase fields of γ-Fe, Fe3C and ϵ-Fe3(С/N) solid solutions along the triangle sides. Thus, native iron can host carbon and nitrogen in the γ-Fe + Fe3C or γ-Fe phases in the mantle depleted in volatiles (20 ppm C and 1 ppm N) at temperatures corresponding to the ∼35 mW/m2 heat flux, and in the Fe3C or ϵ-Fe3(С/N) phases if the contents of volatiles in the mantle reach 250 ppm C and 100 ppm N. Iron carbonitride has quite a large stability field even at low nitrogen concentrations in the system simulating native iron.
文摘的等温部分Fe-Fe3C-Fe3N相图7.8的绩点和1150°С由三相的γ铁+ Fe3C +ϵ-Fe3中部(С/ N)和三个阶段字段(γ铁+ Fe3Cγ铁+ϵ-Fe3(С/ N)和Fe3C +ϵ-Fe3(С/ N))有界的三个单相字段γ铁,Fe3C和ϵ-Fe3沿着三角形(С/ N)固体的解决方案。因此,本机铁可以主机碳和氮的γ铁+ Fe3C或γ铁阶段在地幔耗尽挥发物(20 ppm C和1 ppm N)在温度对应∼35 mW / m2热通量,以及Fe3C或ϵ-Fe3(С/ N)阶段如果地幔中挥发物的内容达到250 ppm C和100 ppm N铁碳氮化物具有相当大的稳定性领域即使在低氮浓度在系统模拟本地铁。
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引用次数: 1
Density and elastic properties of liquid gallium up to 10 GPa using X-ray absorption method combined with externally heated diamond anvil cell 利用X射线吸收法结合外部加热的金刚石砧座电池研究高达10GPa的液态镓的密度和弹性特性
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-10-02 DOI: 10.1080/08957959.2021.1998478
R. Tsuruoka, H. Terasaki, S. Kamada, F. Maeda, T. Kondo, N. Hirao, S. Kawaguchi, Iori Yamada, S. Urakawa, A. Machida
ABSTRACT The density of liquid metals at high pressure and high-temperature provides fundamental and important information for understanding their compression behavior and elastic properties. In this study, the densities of liquid gallium (Ga) were measured up to 10 GPa and 533 K using the X-ray absorption method combined with an externally heated diamond anvil cell. The elastic properties (the isothermal bulk modulus (KT0 ), and its pressure derivative (KT0’)) of liquid Ga were obtained by fitting the density data with three equations of state (EOSs) (Murnaghan, third order Birch–Murnaghan, and Vinet). The KT0 values of liquid Ga were determined to be 45.7 ± 1.0–51.7 ± 1.0 GPa at 500 K assuming KT0’ values of 4–6. The obtained KT0 or KT0 ′ showed almost the same values regardless of the EOS used. Compared with previous results, the compression curve of liquid Ga obtained in this study had a slightly stiffer trend at higher pressures.
液态金属在高压和高温下的密度为理解其压缩行为和弹性特性提供了基本而重要的信息。在这项研究中,液态镓(Ga)的密度被测量到高达10 GPa和533 K,使用X射线吸收法结合外部加热的金刚石砧单元。通过用三个状态方程(EOS)(Murnaghan、三阶Birch–Murnaghan和Vinet)拟合密度数据,获得了液态Ga的弹性特性(等温体积模量(KT0)及其压力导数(KT0'))。液体Ga的KT0值被确定为45.7 ± 1.0–51.7 ± 1 500时的GPa K,假定KT0’值为4–6。无论使用何种EOS,所获得的KT0或KT0′都显示出几乎相同的值。与以前的结果相比,本研究中获得的液态Ga的压缩曲线在更高的压力下具有略硬的趋势。
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引用次数: 0
Vacuum impregnation of apple assisted by high hydrostatic pressure 高静水压力辅助下真空浸渍苹果
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-10-02 DOI: 10.1080/08957959.2021.1981308
M. Gao, Kazuki Nomura, Y. Ando, Yoshiko Nakaura, Zhenya Zhang, Kazutaka Yamamoto
ABSTRACT Apple was impregnated with pigment solution by vacuum heat sealing (VS) and/or high hydrostatic pressure treatment (HHP; 100-600 MPa, 25°C, 5 min). Impregnation efficacy was evaluated as impregnation ratio (%) by image analysis, while damages of cell membrane and texture were quantified by electrical impedance spectroscopy and texture analysis, respectively. Combinations of VS and HHP exclusively achieved 100% impregnation. Meanwhile, the damage was comparable between the samples after VS and VS+100 MPa treatment and aggravated by elevated levels of HHP. As for the texture, breaking stress (hardness) decreased after VS and VS+HHP (100-600 MPa) comparably. Meanwhile, breaking strain (deformability) significantly increased after VS+HHP (200-600 MPa), indicating further damage of strain texture as compared with that after VS and VS+100 MPa treatment. It was indicated that impregnation of apple was fully achieved by a combination of VS and 100 MPa treatment, while minimizing the cell membrane and texture damages.
摘要通过真空热封(VS)和/或高静压处理(HHP;100-600),用颜料溶液浸渍苹果 MPa,25°C,5 分钟)。浸渍效果通过图像分析评估为浸渍率(%),而细胞膜和质地的损伤分别通过电阻抗谱和质地分析进行量化。VS和HHP的组合仅实现了100%的浸渍。同时,VS和VS+100后的样本之间的损伤是可比较的 MPa治疗,并因HHP水平升高而加重。在织构方面,VS和VS+HHP(100-600)后,断裂应力(硬度)降低 MPa)。同时,VS+HHP(200-600)后,断裂应变(变形能力)显著增加 MPa),表明与VS和VS+100之后相比,应变织构的进一步损伤 MPa处理。结果表明,VS和100的组合可以完全实现苹果的浸渍 MPa处理,同时最大限度地减少细胞膜和纹理损伤。
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引用次数: 1
Effect of hydrostatic pressure on magneto-crystalline anisotropy of Heusler Ni2MnSn-based alloy 静水压力对Heusler ni2mnsn基合金磁晶各向异性的影响
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-10-02 DOI: 10.1080/08957959.2021.2001466
J. Kamarád, J. Kaštil, M. Friák, M. Mazalová, O. Schneeweiss, Z. Arnold
ABSTRACT Single crystal of the stoichiometric Ni2MnSn alloy (cubic L21 crystal structure) was prepared by the Czochralski method. The values of the magneto-crystalline anisotropy constant K 1 have been determined at temperature 10 K under ambient and high hydrostatic pressures, K 1 = + 0.17 × 104 and +1.96 × 104 J/m3 (0.7 GPa), respectively. The pressure-induced decrease of magnetization was confirmed and hence the significant non-trivial increase of uniaxial anisotropy with increasing pressure points to a possible distortion of the cubic structure of the single crystal under hydrostatic pressure. Simultaneously, the more pronounced and pressure almost insensitive magneto-crystalline anisotropy, K 1 = + 9.1 × 104 J/m3, has been observed in the martensite phase (orthorhombic structure) of the off-stoichiometric Ni2Mn1.43Sn0.57 alloy. The effect of a directional dependence of the Young modulus that was theoretically derived in the case of the Ni2MnSn-based alloys is discussed.
采用提拉法制备了化学计量比为Ni2MnSn合金的单晶(立方L21晶体结构)。磁晶各向异性常数K1的值已经在温度10下确定 K在环境和高静水压力下,K 1 = + 0.17 × 104和+1.96 × 104 J/m3(0.7 GPa)。压力引起的磁化强度下降得到了证实,因此单轴各向异性随着压力的增加而显著增加,这表明在静水压力下单晶的立方结构可能发生畸变。同时,更明显和压力几乎不敏感的磁晶各向异性,K1 = + 9.1 × 104 在非化学计量的Ni2Mn1.43Sn0.57合金的马氏体相(正交结构)中已经观察到J/m3。讨论了在Ni2MnSn基合金的情况下从理论上导出的杨氏模量的方向依赖性的影响。
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引用次数: 2
Yield strength and hardness of micron-sized powders measured in the diamond cell 在金刚石电池中测量微米级粉末的屈服强度和硬度
IF 2 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2021-10-02 DOI: 10.1080/08957959.2021.1985115
L. Chudinovskikh, R. Boehler
ABSTRACT When powders of polycrystalline transparent materials are compressed in the diamond cell, they undergo a change from translucent to transparent. This effect is due to plastic deformation of the grains leading to a reduction in the size of voids responsible for light scattering. The pressures of the onset and saturation of the optical transmission corelate respectively well with the previously reported yield strengths and hardness obtained by different techniques. From ten measurements on MgO, SiO2, Al2O3, olivine, pyroxene, garnet and a perovskite, we find a ratio between hardness and yield strength of three, which is generally accepted. Preliminary high temperature measurements with the double-sided laser heating technique show that this method may be used for determining rheological properties of minerals at P-T conditions of the deep Earth. This technique for obtaining high optical transmission in polycrystalline materials may also be of interest for modern solid state laser materials.
摘要:当多晶透明材料粉末在金刚石电池中压缩时,它们会发生从半透明到透明的变化。这种效应是由于晶粒的塑性变形导致负责光散射的空隙尺寸减小。光透射取芯板的起始压力和饱和压力分别与先前报道的通过不同技术获得的屈服强度和硬度良好。通过对MgO、SiO2、Al2O3、橄榄石、辉石、石榴石和钙钛矿的十次测量,我们发现硬度和屈服强度之间的比例为三,这是普遍接受的。利用双面激光加热技术进行的初步高温测量表明,该方法可用于确定地球深处P-T条件下矿物的流变特性。这种用于在多晶材料中获得高光学透射率的技术对于现代固态激光材料也可能是感兴趣的。
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引用次数: 2
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High Pressure Research
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