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Investigation of microstructure, machinability, and mechanical properties of new-generation hybrid lead-free brass alloys 新一代杂化无铅黄铜合金的显微组织、切削性能和力学性能研究
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0263
Özbey Semih, Artir Recep
Abstract In this study, hybrid alloys were obtained by casting method with alloy elements and additive such as Si and MoS2, which can be used instead of lead, and compared with Ecobrass and free cutting brass samples used in the market in terms of microstructure, mechanical, and machinability properties. The microstructures of lead-free hybridized brass consists of alpha, beta, and intermetallic compound which were confirmed by the results of X-Ray Diffraction analysis and Scanning Electron Microscopy-Energy Dispersive Spectroscopy. The hardness values of the beta phase in the microstructure are between 180 and 220 Vickers hardness. It has been observed that increasing the amount of beta prime phase also increases the hardness. The machinability of samples was evaluated in terms of surface roughness and chip formation. Chips obtained from samples after machining process were categorized according to ISO 6385-G1 standard. Chip morphologies were examined under optic microscope and scanning electron microscope. The surface roughness value of samples with MoS2 additives was found to be the lowest due to its lubricity effect. Moreover, morphologies, distribution of phases, and intermetallic compounds in the microstructure are found to have a great impact on the machinability and ultimate tensile strength.
摘要:本研究采用浇铸法制备了可代替铅使用的合金元素和添加剂Si、MoS2等混合合金,并与市场上常用的Ecobrass和自由切削黄铜样品进行了显微组织、力学性能和可切削性能的比较。无铅杂化黄铜的显微结构由α、β和金属间化合物组成,经x射线衍射分析和扫描电镜-能谱分析证实。显微组织中β相的硬度值在180 ~ 220维氏之间。研究发现,增加初相的量也能提高硬度。根据表面粗糙度和切屑形成来评估样品的可加工性。根据ISO 6385-G1标准对加工后样品获得的切屑进行分类。在光学显微镜和扫描电镜下观察芯片的形貌。添加了二硫化钼的样品,由于其润滑作用,表面粗糙度值最低。此外,微观组织中的形貌、相分布和金属间化合物对可加工性和极限抗拉强度有很大影响。
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引用次数: 0
Density and surface tension measurements of molten Al–Si based alloys 熔融铝硅基合金的密度和表面张力测量
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0286
Hiroyuki Fukuyama, Hideo Higashi, M. Adachi, Makoto Ohtsuka
Abstract This study is part of a series of studies aimed at measuring the thermophysical properties of molten phase change material-type metallic thermal energy storage materials near 873 K (600°C). The target material is Al–Si based alloys. First, as a feasibility study, density measurements of the molten state of three Al–Si binary alloys (Al–12.2Si, Al–50Si and Al–90Si in atomic%) were performed. A highly accurate non-contact density measurement method based on the static magnetic field superposition electromagnetic levitation (EML) method was employed as the density measurement method. The validity of this experimental method was confirmed, and density of molten Al–Si base alloys (ADC12 and Al–5.9mass%Si–1.6mass%Fe) were measured as a function of temperature with an expanded uncertainty of 1.2%. In addition, the surface tension of the alloys was measured by the droplet oscillation method using the EML technique. The surface tension was successfully obtained as a function of temperature with expanded uncertainty of 2.3%.
摘要本研究是一系列研究的一部分,旨在测量873附近熔融相变材料型金属储能材料的热物理性质 K(600°C)。目标材料是Al–Si基合金。首先,作为可行性研究,对三种Al–Si二元合金(Al–12.2Si、Al–50Si和Al–90Si,以原子%计)的熔融状态进行了密度测量。密度测量方法采用了一种基于静态磁场叠加电磁悬浮(EML)方法的高精度非接触式密度测量方法。该实验方法的有效性得到了证实,并测量了熔融Al–Si基合金(ADC12和Al–5.9mass%Si–1.6mass%Fe)的密度作为温度的函数,扩展不确定度为1.2%。此外,使用EML技术通过液滴振荡法测量了合金的表面张力。成功地获得了表面张力作为温度的函数,扩展不确定度为2.3%。
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引用次数: 0
Study on diffusion kinetics of chromium and nickel electrochemical co-deposition in a NaCl–KCl–NaF–Cr2O3–NiO molten salt 铬和镍在NaCl–KCl–NaF–Cr2O3–NiO熔盐中电化学共沉积的扩散动力学研究
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0276
Shixian Zhang, K. Hu, X. Zhao, J. Liang, Yungang Li
Abstract The process of preparing surface composite by molten salt co-deposition is the result of the mass transfer of active particles in molten salt, electrochemical reduction, and solid diffusion. In this study, we prepared Cr–Ni alloy/low-carbon steel surface composites in NaCl, KCl, NaF, Cr2O3, and NiO melt salt system successfully, and analyzed the entire diffusion dynamics process, aiming to find out the limiting links and provide ideas for further improving the preparation efficiency. The results show that chromium and nickel ions are simultaneously reduced on the cathode surface through two and one steps, respectively. And an alloy layer with Fe content of 64.52 wt%, Ni content of 28.96 wt%, and Cr content of 6.52 wt% is formed on the surface of low-carbon steel substrate. The average diffusion coefficients of chromium and nickel atoms in the surface composites are 1.16 × 10−14 and 1.44 × 10−14 m2·s−1. The mass transfer process in molten salt is the limiting link in the whole preparation process.
摘要熔盐共沉积制备表面复合材料的过程是活性颗粒在熔盐中传质、电化学还原和固体扩散的结果。在本研究中,我们在NaCl、KCl、NaF、Cr2O3和NiO熔盐体系中成功制备了Cr–Ni合金/低碳钢表面复合材料,并分析了整个扩散动力学过程,旨在找出限制环节,为进一步提高制备效率提供思路。结果表明,铬离子和镍离子分别通过两步和一步在阴极表面同时还原。以及Fe含量为64.52的合金层 wt%,Ni含量为28.96 wt%,Cr含量为6.52 在低碳钢基材的表面上形成wt%。铬和镍原子在表面复合材料中的平均扩散系数分别为1.16×10-14和1.44×10-14 m2·s−1.熔盐中的传质过程是整个制备过程中的限制环节。
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引用次数: 0
Temperature uniformity optimization with power-frequency coordinated variation in multi-source microwave based on sequential quadratic programming 基于顺序二次规划的多源微波工频协调变化温度均匀性优化
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0279
Biao Yang, Zemin Han, Cheng Cheng, Hao Gao, Zhaogang Wu
Abstract The focus of this study is to regulate the variation in the input parameters of multiple microwave sources in a high-frequency multimode resonant heating system to achieve uniform heating. First, this study deeply expands the theoretical process of frequency change and proposes a frequency-shifting strategy with hot spot alternation to ensure that the temperature difference range of each hot spot does not continuously expand during the heating process. Then, a sequential quadratic programming algorithm is introduced to reconstruct the input power values to improve the heating efficiency according to the different microwave absorption efficiencies of the heated material at different frequencies. Finally, a numerical calculation model for multi-source microwave power-frequency cooperative heating is established based on the finite-element method, and the temperature uniformity index is effectively calculated. Numerical calculations show that the proposed method can improve the uniformity in single-material heating and multi-material heating cases by 56.8–94.3% and 44.4–76.6%, respectively, over that of fixed-frequency heating while achieving improved heating efficiency on the basis of frequency conversion.
摘要本文研究的重点是调节高频多模谐振加热系统中多个微波源输入参数的变化,以实现均匀加热。首先,本研究深入扩展了频率变化的理论过程,提出了热点交替的移频策略,以保证在加热过程中各热点的温差范围不会不断扩大。然后,根据被加热材料在不同频率下的不同微波吸收效率,引入顺序二次规划算法重构输入功率值,以提高加热效率。最后,基于有限元法建立了多源微波工频协同加热的数值计算模型,有效地计算了温度均匀性指标。数值计算表明,该方法在单材料加热和多材料加热情况下,加热均匀性比定频加热分别提高56.8-94.3%和44.4-76.6%,同时在变频的基础上提高了加热效率。
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引用次数: 0
Heat management of LED-based Cu2O deposits on the optimal structure of heat sink 基于散热器最佳结构的LED基Cu2O沉积物的热管理
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0277
Congrong Wang, Chao Zhang, Qiduan Chen, Hui Lin, Xinting Sun, Jiahao Li, Mingder Jean
Abstract This report investigates the thermal performance of light-emitting diodes (LEDs) using a heat sink structure based on an optimized design and a sprayed cuprous oxide (Cu2O) coating. An orthogonal array of 18 aluminum plates with various heat-dissipated structures was created. The optimal junction temperature of the LED package is determined by using the signal-to-noise ratio (S/N) of the heat-dissipated structure based on Taguchi’s method as well as the heat dissipation coating. According to the analysis of variance, the most important factors that influence the junction temperature can be obtained as the depth of groove, the layout of holes, the layout of LEDs, and the number of Cu block. These significant factors constituted approximately 91.06% of the variation in the experiment. The results show that by optimizing the structure of the LED heat sink based on the heat-dissipated coating, the efficiency of the junction temperature is increased by 23.88%. Also, a gain of 1.30 dB corresponds to a 9.67% reduction in variance, which indicates the improvement through the optimal setting by 1.162 times of variance, showing good reproducibility. Overall, the coating is based on the optimized design of the structure of the heat sink that has good heat transfer capability, which can provide a good solution to the heat-dissipated problem of LED and further give guidance to the future development of LED.
摘要本报告使用基于优化设计的散热器结构和喷涂的氧化亚铜(Cu2O)涂层研究了发光二极管(LED)的热性能。创建了具有各种散热结构的18块铝板的正交阵列。LED封装的最佳结温是通过使用基于田口方法的散热结构的信噪比(S/N)以及散热涂层来确定的。根据方差分析,可以得出影响结温度的最重要因素是凹槽的深度、孔的布局、LED的布局和Cu块的数量。这些显著因素约占实验变化的91.06%。结果表明,通过优化基于散热涂层的LED散热器结构,结温效率提高了23.88%,增益为1.30 dB对应于9.67%的方差减少,这表明通过最佳设置改进了1.162倍的方差,显示出良好的再现性。总体而言,该涂层是基于对具有良好传热能力的散热器结构的优化设计,可以很好地解决LED的散热问题,并进一步指导LED的未来发展。
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引用次数: 0
Soft sensor method for endpoint carbon content and temperature of BOF based on multi-cluster dynamic adaptive selection ensemble learning 基于多聚类动态自适应选择集成学习的转炉末端碳含量和温度软测量方法
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0287
Bin Shao, Hui Liu, Fu-gang Chen
Abstract The accurate control of the endpoint in converter steelmaking is of great significance and value for energy saving, emission reduction, and steel quality improvement. The key to endpoint control lies in accurately predicting the carbon content and temperature. Converter steelmaking is a dynamic process with a large fluctuation of samples, and traditional ensemble learning methods ignore the differences among the query samples and use all the sub-models to predict. The different performances of each sub-model lead to the performance degradation of ensemble learning. To address this issue, we propose a soft sensor method based on multi-cluster dynamic adaptive selection (MC-DAS) ensemble learning for converter steelmaking endpoint carbon content and temperature prediction. First, to ensure the diversity of the ensemble learning base model, we propose a clustering algorithm with different data partition characteristics to construct a pool of diverse base models. Second, a model adaptive selection strategy is proposed, which involves constructing diverse similarity regions for individual query samples and assessing the model’s performance in these regions to identify the most suitable model and weight combination for each respective query sample. Compared with the traditional ensemble learning method, the simulation results of actual converter steelmaking process data show that the prediction accuracy of carbon content within ±0.02% error range reaches 92.8%, and temperature within ±10°C error range reaches 91.6%.
转炉炼钢终点的精确控制对节能减排、提高钢材质量具有重要意义和价值。终点控制的关键在于准确预测碳含量和温度。转炉炼钢是一个样本波动较大的动态过程,传统的集成学习方法忽略了查询样本之间的差异,使用所有子模型进行预测。每个子模型的不同性能导致集成学习的性能下降。针对这一问题,提出了一种基于多聚类动态自适应选择(MC-DAS)集成学习的软测量方法,用于转炉炼钢终点碳含量和温度预测。首先,为了保证集成学习基模型的多样性,我们提出了一种具有不同数据分区特征的聚类算法,构建了一个多样化的基模型池。其次,提出了一种模型自适应选择策略,该策略包括为单个查询样本构建不同的相似区域,并评估模型在这些区域中的性能,以确定每个查询样本最合适的模型和权重组合。与传统集成学习方法相比,对转炉炼钢实际过程数据的仿真结果表明,碳含量在±0.02%误差范围内的预测精度达到92.8%,温度在±10℃误差范围内的预测精度达到91.6%。
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引用次数: 0
Cation-doping effects on the conductivities of the mayenite Ca12Al14O33 阳离子掺杂对马氏体Ca12Al14O33电导率的影响
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0295
Xingping Song, Yaqiong Guo, Wenzhuo Chen, Keke Hou, Xiaoxu Duan, Jungu Xu
Abstract The mayenite Ca 12 Al 14 O 33 material, owing to its oxide ion conducting behavior and the low cost of raw materials, has the potential of being applied in solid oxide fuel cells as an electrolyte. However, suffering from the relatively low oxide ion conductivity, there is still a long way to go for its practical application. To enhance the oxide ion conduction in Ca 12 Al 14 O 33 , many efforts have been endowed to this from different research groups but hardly succeeded. In this work, the Ca 12 Al 14 O 33 -based materials with Y, In, and Cu-doping on the Ca or Al sites were fabricated through a traditional solid-state reaction method (for Y-doping on Ca and Cu-doping on Al) or a glass-crystallization method (for In-doping on Al), with their electrical conductivities being studied. The results revealed that the solid solution regions of Ca 12− x Y x Al 14 O 33+ δ , Ca 12 Al 14− x In x O 33 , and Ca 12 Al 14− x Cu x O 33− δ were 0 ≤ x ≤ 0.15, 0 ≤ x ≤ 0.1, and 0 ≤ x ≤ 0.3, respectively. The electrical conductivities of all these doped materials were investigated.
摘要/ Abstract摘要:mayenite ca12al14o33材料由于具有良好的氧化离子导电性能和低廉的原材料成本,在固体氧化物燃料电池中具有作为电解质的应用潜力。然而,由于氧化离子电导率相对较低,其实际应用还有很长的路要走。为了提高ca12al14o33的氧化离子导电性,不同的研究小组做了很多努力,但很少成功。本文通过传统的固相反应法(Y掺杂在Ca上,cu掺杂在Al上)或玻璃结晶法(In掺杂在Al上)制备了在Ca或Al上掺杂Y、In和cu的Ca - 12al - 14o33基材料,并对其电导率进行了研究。结果表明,Ca 12−x Y x Al 14 O 33+ δ、Ca 12 Al 14−x In x O 33和Ca 12 Al 14−x Cu x O 33−δ的固溶体区分别为0≤x≤0.15、0≤x≤0.1和0≤x≤0.3。研究了这些掺杂材料的电导率。
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引用次数: 0
Investigation of the liquidus temperature calculation method for medium manganese steel 中锰钢液相温度计算方法的探讨
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0285
Li Min, Liu Hongbo, Xie Rongyuan, Che Xiaorui, Liu Ying, Xu Hao, Zhang Caidong, Tian Zhiqiang
Abstract The liquidus temperature and temperature drop coefficients of medium manganese steel were systematically studied using Factsage and differential scanning calorimetry (DSC) experiments. The results indicated that the temperature drop coefficients of C, Mn, Cr, Si, and Al were complex, while the coefficients of Mo, V, and Nb were of a constant value. Based on the temperature drop coefficients, the empirical formula for calculating the liquidus temperature of medium manganese steel was established. The liquidus temperature calculated using the empirical formula was 1422.7°C, while that obtained by the DSC experiment was 1422.9°C. By comparison with different calculation formulas, the liquidus temperature obtained from the formula that was constructed in this study was much closer to the experiment one, indicating the high accuracy of the empirical formula in predicting the liquidus temperature of medium manganese steel.
摘要采用Factsage和差示扫描量热法(DSC)实验系统地研究了中锰钢的液相温度和温降系数。结果表明,C、Mn、Cr、Si、Al的降温系数为复系数,Mo、V、Nb的降温系数为恒定值。根据温度降系数,建立了计算中锰钢液相温度的经验公式。经验公式计算得到的液相温度为1422.7℃,DSC实验得到的液相温度为1422.9℃。通过与不同计算公式的比较,本研究构建的公式得到的液相温度与实验值更为接近,表明经验公式对中锰钢液相温度的预测精度较高。
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引用次数: 0
SELECTION OF DUST PARTICLES IN A STRIATION IN GLOW DISCHARGE IN INERT GASES WITH DIFFERENT IONIZATION POTENTIALS 不同电离势惰性气体辉光放电条纹中粉尘颗粒的选择
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1615/hightempmatproc.2023047043
L. Novikov, E. Dzlieva, M. Golubev, S. Pavlov, M. Gasilov, V. Karasev
In this study, an experimental investigation of the effects of dust particle selection was carried out, in which the type of plasma-forming gas was varied. Using working gases with different ionization potentials, plasma filters (plasma-dust traps) capable of holding dust particles from 3 to 6.3 µm in size were obtained. The correspondence between the main parameters of the discharge (the longitudinal field and the electron temperature) and the size of the levitated particles was obtained from the numerical estimates. From the results obtained in the study, it was possible to create plasma filters with specified and finely tuned particle parameters. This makes it possible to create dusty plasmas with particles of required sizes.
实验研究了不同等离子体形成气体类型对尘埃粒子选择的影响。使用具有不同电离电位的工作气体,获得了能够容纳3至6.3 μ m大小的尘埃颗粒的等离子体过滤器(等离子体粉尘捕集器)。通过数值估计得到了放电主要参数(纵向场和电子温度)与悬浮粒子尺寸的对应关系。从研究中获得的结果来看,有可能创建具有指定和微调粒子参数的等离子体过滤器。这使得制造具有所需大小粒子的尘埃等离子体成为可能。
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引用次数: 0
Study on the cladding path during the solidification process of multi-layer cladding of large steel ingots 大型钢锭多层熔覆凝固过程中熔覆路径的研究
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0267
Li Yi-hong, Ni Jin-Yu, Zhao Yu-kun, He Yi-bo, Ren Zhi-feng, Chen Hui-qin
Abstract Aiming at the quality problems such as segregation, porosity and shrinkage cavities that are difficult to eliminate due to the size effect of large die-cast steel ingots as large forging blanks, the idea of layered casting of large steel ingots is proposed. The transient heat transfer process and cladding path of the ingot core and cladding layer under different molten steel casting temperatures, different ingot core diameters and different ingot core preheating temperatures were studied by combining numerical simulation and thermal experiments. The research results show that the cladding path has a certain functional relationship with the diameter of the ingot core and the preheating temperature of the ingot core. Obviously, the interfacial melting rate can be significantly improved. The thermal scaling experiment was carried out on the cladding path under the condition of a casting temperature of 1,560°C and no preheating of the ingot core. The microhardness of the interface is higher than that of the clad steel ingot, and the metallurgical bond of the interface is good.
摘要针对大型压铸钢锭作为大型锻件由于尺寸效应而难以消除的偏析、气孔和缩孔等质量问题,提出了大型钢锭分层铸造的思想。采用数值模拟与热实验相结合的方法,研究了不同铸钢液温度、不同钢芯直径和不同钢芯预热温度下,钢芯和熔覆层的瞬态传热过程和熔覆路径。研究结果表明,熔覆路径与钢芯直径和钢芯预热温度有一定的函数关系。显然,可以显著提高界面熔化速率。在浇注温度为1560℃、钢锭芯不预热的条件下,对熔覆路径进行了热结垢实验。界面显微硬度高于包钢锭,界面的冶金结合良好。
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引用次数: 0
期刊
High Temperature Materials and Processes
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