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ANTIADHESION FLUOROCARBON COATINGS WITH INDUCED SURFACE CHARGE FOR PROTECTION AGAINST BIODEGRADATION 具有诱导表面电荷的抗粘附氟碳涂层,用于防止生物降解
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1615/hightempmatproc.v27.i4.40
V. Elinson, P. Shchur, E. Rusanova, V.V.  Shchelkova
This paper analyzes the results of studying the antimicrobial properties of nanostructured fluorocarbon films deposited on polymers by ion-plasma technology. For the first time, the dependence of the surface charge and antimicrobial properties over time was established. As the negative charge drains, the number of colonies of the studied bacteria and fungi increases. Fluorocarbon films were formed using a two-component gas mixture (CF4 + C6H12) with different ratios of components. Antimicrobial activity on fluorocarbon coatings is maintained for 12 months.
本文分析了离子等离子体技术对聚合物表面纳米结构氟碳膜抗菌性能的研究结果。首次建立了表面电荷和抗菌性能随时间的依赖关系。随着负电荷的流失,所研究的细菌和真菌的菌落数量增加。采用不同组分比例的双组分气体混合物(CF4 + C6H12)形成氟碳薄膜。氟碳涂料的抗菌活性可维持12个月。
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引用次数: 0
FORMATION OF WEAR-RESISTANT ANODIC OXIDE FILMS ON SILICON ALUMINUM ALLOY FOR ELECTRICAL AND ELECTRONIC MATERIALS 电气电子材料用硅铝合金耐磨阳极氧化膜的形成
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1615/hightempmatproc.2023045568
Daniel Nmadu, U. Uma, A. Parshuto, N. Eli-Chukwu, Elena Stepanova Parshuto, I. Smyaglikov
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引用次数: 0
Effect of reactor wall temperature on benzene oxidation in a barrier discharge 反应器壁温对屏障放电中苯氧化的影响
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1615/hightempmatproc.2023048357
A. Leshchik, Andrey R. Ocheredko, S. Kudryashov, A. Ryabov, T. Petrenko
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引用次数: 0
EFFECTS OF HOLDING TIME ON MICROSTRUCTURE AND SHEAR STRENGTH OF RESISTANCE SPOT-WELDED JOINTS BETWEEN MILD STEEL AND ALUMINUM WITH ZINC POWDER FILLER 保温时间对填充锌粉的低碳钢与铝电阻点焊接头组织及抗剪强度的影响
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1615/hightempmatproc.2023048181
M. A. Hendrawan, K. A. Ilman, Takahiro Kunimine
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引用次数: 1
Effect of different isothermal times on the microstructure and mechanical properties of high-strength rebar 不同等温时间对高强钢筋组织和力学性能的影响
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0266
Tianyou Wang, Zhiying Li, Jie Wang, Changrong Li, Zeyun Zeng, Fulong Wei
Abstract High-strength rebar plays a supporting role in large engineering structures due to its excellent performance. In this study, the effect of different isothermal time treatments (30, 60, 100, and 200 s) at 650°C on the microstructure transformation and mechanical properties of rebars was investigated. The hot-rolling process was simulated by Gleeble-3800 thermal simulator. The microstructure, precipitates, and mechanical properties of high-strength rebar were characterized by scanning electron microscopy, transmission electron microscopy (TEM), and a universal tensile test machine. Results show that when the isothermal time increased from 30 to 200 s, the ferrite grain size decreased from 10.632 to 8.326 μm, and the pearlite lamellar spacing was refined from 0.230 to 0.142 μm. The TEM confirmed that when the isothermal time increased from 30 to 200 s, the nanoscale (Nb, V, and Ti) C precipitates were uniformly distributed in the ferrite matrix and grain boundary, and the size of precipitates decreased from 34.014 to 29.916 nm; thus, the tensile strength increased from 752.477 to 780.713 MPa, and the yield strength increased from 574.714 to 621.434 MPa.
摘要高强度钢筋以其优异的性能在大型工程结构中起着支撑作用。在本研究中,不同等温时间处理(30、60、100和200 s) 研究了650°C温度对钢筋组织转变和力学性能的影响。采用Gleeble-3800热模拟机对热轧过程进行了模拟。通过扫描电子显微镜、透射电子显微镜和万能拉伸试验机对高强度钢筋的微观结构、析出相和力学性能进行了表征。结果表明,当等温时间从30增加到200时 s、 铁素体晶粒尺寸从10.632减小到8.326 μm,珠光体片层间距从0.230细化到0.142 μm。TEM证实,当等温时间从30增加到200时 s、 纳米级(Nb、V和Ti)C沉淀物均匀分布在铁氧体基体和晶界中,沉淀物的尺寸从34.014减小到29.916 nm;因此,抗拉强度从752.477增加到780.713 MPa,屈服强度从574.714提高到621.434 MPa。
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引用次数: 0
High-temperature corrosion behaviours of nickel–iron-based alloys with different molybdenum and tungsten contents in a coal ash/flue gas environment 不同钼和钨含量的镍铁合金在煤灰/烟气环境中的高温腐蚀行为
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0275
M. Zhu, Xin Zhang, Chunlin Huang, Jin-Tao Lu, Huihui Zhang, Yimeng Ma, Mingjing Wang
Abstract High-temperature coal ash/flue gas corrosion behaviours of three nickel–iron based superalloys for boiler tubes with different Mo and W contents (1.8% Mo + 1.2% W for S1 alloy, 0.8% Mo + 0.2% W for S2 alloy, and 0.5% Mo + 2.2% W for S3 alloy) at 650 and 700°C were studied. The microstructure, phase compositions, and morphologies together with element distribution for corrosion products were investigated with a metallographic microscope, a scanning electron microscope equipped with an energy-dispersive spectroscope, and X-ray diffractometer. The results show that the corrosion resistance of the Ni–Fe-based alloy decreases with the increasing total content of Mo and W in the alloy at both 650 and 700°C; the outer layer of the corrosion products was mainly composed of FeCr2O4 while the inner layer was mainly composed of Cr2O3. Peeling of the oxide films formed on the surfaces of S1 and S3 alloys was observed but no obvious spalling was observed for the S2 alloy. The reactions among Mo, W, and S in the coal ash/flue gas increased the internal stress in the oxide scale, which would cause the failure of the oxide scale. Graphical Abstract High-temperature corrosion behaviours of three nickel–iron-based superalloys for boiler tubes with different Mo and W contents in simulated coal ash/flue gas at 650 and 700°C were studied. The corrosion resistance of the Ni–Fe-based alloy decreases with the increasing total contents of Mo and W in the alloy at both 650 and 700°C; peeling of the oxide films formed on the surfaces of S1 and S3 alloys was observed but no obvious spalling was observed for the S2 alloy. Reactions between Mo, W, and S in the coal ash/flue gas increased the internal stress in the oxide scale, which would cause the failure of the oxide scale.
摘要研究了三种不同Mo和W含量的镍铁基高温合金(S1合金为1.8%Mo+1.2%W,S2合金为0.8%Mo+0.2%W,S3合金为0.5%Mo+2.2%W)在650和700°C下对锅炉管的高温煤灰/烟气腐蚀行为。用金相显微镜、带能谱仪的扫描电子显微镜和X射线衍射仪研究了腐蚀产物的微观结构、相组成、形貌以及元素分布。结果表明,在650°C和700°C下,Ni–Fe基合金的耐蚀性随着合金中Mo和W总含量的增加而降低;腐蚀产物的外层主要由FeCr2O4组成,而内层主要由Cr2O3组成。观察到S1和S3合金表面上形成的氧化膜剥落,但S2合金没有观察到明显的剥落。煤灰/烟气中Mo、W和S之间的反应增加了氧化皮中的内应力,这将导致氧化皮的失效。研究了三种不同Mo和W含量的镍铁基高温合金在650和700°C模拟煤灰/烟气中对锅炉管的高温腐蚀行为。在650°C和700°C下,Ni–Fe基合金的耐蚀性随着合金中Mo和W总含量的增加而降低;观察到在S1和S3合金的表面上形成的氧化膜的剥离,但是对于S2合金没有观察到明显的剥落。煤灰/烟气中Mo、W和S之间的反应增加了氧化皮中的内应力,这将导致氧化皮的失效。
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引用次数: 0
THRESHOLD EFFECT IN DUSTY CLUSTERS IN A MAGNETIC FIELD 磁场中尘星团的阈值效应
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1615/hightempmatproc.2023047765
L. Novikov, S. Pavlov, E. Dzlieva, Sergey Tarasov, D. Yanitsin, V. Karasev
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引用次数: 0
Contribution of thermal dissociation during steel nitriding in electron beam plasma 电子束等离子体中钢氮化过程中热解离的贡献
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1615/hightempmatproc.2023047747
A. Tyunkov, A. Andronov, E. Oks, Y. Yushkov, D. Zolotukhin
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引用次数: 0
MAGNETRON SPUTTER DEPOSITION OF TUNGSTEN COATINGS IN DEUTERIUM-HELIUM MIXTURES 磁控溅射沉积氘氦混合物中钨涂层
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1615/hightempmatproc.v27.i4.30
M. Kharkov, G.S. Lomonosov, D. Kolodko, M. Kukushkina, A. Kaziev, A. Tumarkin, O. Ogorodnikova
The electrical parameters of a high-power impulse magnetron sputtering (HiPIMS) discharge operating in H2/He mixtures were studied using different values of the pulse width, repetition frequency, and power. Deposition of tungsten (W) coatings was carried out in a magnetron discharge with a thermally insulated W target in two regimes at different pulse widths (80 and 500 µs) and frequencies (2 and 0.5 kHz). The average discharge power was fixed at Pd = 1500 W. Fusion-relevant molecular deuterium/helium (He) and hydrogen/He gas mixtures with a 90/10 flow ratio were used in the experiments.
研究了H2/He混合物中不同脉冲宽度、重复频率和功率下的高功率脉冲磁控溅射放电的电学参数。在不同的脉冲宽度(80µs和500µs)和频率(2和0.5 kHz)下,用磁控管放电对钨(W)涂层进行了沉积。平均放电功率固定在Pd = 1500w。实验采用与聚变相关的分子氘/氦(He)和氢/氦气体混合物,流动比为90/10。
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引用次数: 0
Enhancing the efficiency of polytetrafluoroethylene-modified silica hydrosols coated solar panels by using artificial neural network and response surface methodology 利用人工神经网络和响应面方法提高聚四氟乙烯改性硅溶胶涂层太阳能电池板的效率
IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/htmp-2022-0273
Kirthika Ramasamy, C. Murugesan, Senthilkumar Thamilkolunthu
Abstract In this article, an attempt was made to improve the efficiency of coated solar panels by using artificial neural networks (ANNs) and response surface methodology (RSM). Using the spray coating technique, the glass surface of the photovoltaic solar panel was coated with silicon dioxide nanoparticles incorporated with polytetrafluoroethylene-modified silica sols. Multilayer perceptron with feed-forward back-propagation algorithm was used to develop ANN models for improving the efficiency of the coated solar panels. Out of the 200 sets of data collected, 75% were used for training and 25% were used for testing. On evaluating the models using performance indicators, a four-input technological parameter model (silicon dioxide nanoparticle quantity, coating thickness, surface temperature and solar insolation) with eight neurons in a single hidden layer combination was observed to be the best. The prediction accuracy indicator values of the ANN model were 0.9612 for the coefficient of determination, 0.1971 for the mean absolute percentage error, 0.2317 for the relative root mean square error and 0.00741 for the mean bias error. Using a central composite design model, empirical relationships were developed between input and output responses. The significance of the developed model was ascertained by using analysis of variance, up to a 95% confidence level. For optimization, the RSM was used, and a high efficiency of 17.1% was predicted for the coated solar panel with optimized factors; it was validated to a very high level of predictability. Using interaction and perturbation plots, a ranking of the parameters was done.
摘要本文试图利用人工神经网络和响应面方法来提高涂层太阳能电池板的效率。采用喷涂技术,在光伏太阳能电池板的玻璃表面涂上掺有聚四氟乙烯改性硅溶胶的二氧化硅纳米颗粒。采用多层感知器和前馈-反向传播算法建立了提高涂层太阳能电池板效率的神经网络模型。在收集的200组数据中,75%用于训练,25%用于测试。在使用性能指标评估模型时,观察到在单个隐藏层组合中有八个神经元的四输入技术参数模型(二氧化硅纳米颗粒数量、涂层厚度、表面温度和太阳辐射)是最好的。ANN模型的预测精度指标值为决定系数0.9612,平均绝对百分比误差0.1971,相对均方根误差0.2317,平均偏差误差0.00741。使用中心复合设计模型,在输入和输出响应之间建立了经验关系。通过方差分析确定了所开发模型的显著性,置信度高达95%。对于优化,使用RSM,并且在优化因子下预测涂层太阳能电池板的高效率为17.1%;它被证实具有很高的可预测性。使用相互作用图和扰动图,对参数进行了排序。
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High Temperature Materials and Processes
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