Adhi Maulana Yusuf, Satrio Kuntolaksono, Agustina Sus Andreani
In this study, AuNPs were reduced using ortho-hydroxybenzoic acid (o-HBA) and various stabilizing agents (α-CDs and β-CDs). The stability, shape, size, and sensitivity of the Fe3+ detection of AuNPs α-CDs and AuNP β-CDs are compared. Both nanomaterials were characterized using ultraviolet-visible (UV-vis) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, and transmission electron microscopes (TEM). After the addition of Fe3+, the absorption rate of surface plasma resonance (SPR) increased to 524 nm, and the color of AuNPs α-CDs and AuNPs β-CDs was changed from pink to red and purple, respectively. AuNPs α-CDs are more uniform in shape and size than AuNPs β-CDs with a size of 23.34 nm. Further, AuNPs α-CDs are more stable, and the absorption rate at 524 nm wavelength decreases by 17.76%. AuNPs α-CDs have a good linear relationship with a linear regression coefficient of 0.996. The sensitivity of AuNPs α-CDs was good with LoD and LoQ both with 1.21 and 4.02 ppm, respectively. These results show that the sensor is superior in determining Fe3+. In addition, AuNPs α-CDs were used to detect Fe3+ in the tap water in South Tangerang, Banten, Indonesia.
{"title":"The Comparative of α- and β-Cyclodextrin as Stabilizing Agents on AuNPs and Application as Colorimetric Sensors for Fe3+ in Tap Water","authors":"Adhi Maulana Yusuf, Satrio Kuntolaksono, Agustina Sus Andreani","doi":"10.22146/ijc.83796","DOIUrl":"https://doi.org/10.22146/ijc.83796","url":null,"abstract":"In this study, AuNPs were reduced using ortho-hydroxybenzoic acid (o-HBA) and various stabilizing agents (α-CDs and β-CDs). The stability, shape, size, and sensitivity of the Fe3+ detection of AuNPs α-CDs and AuNP β-CDs are compared. Both nanomaterials were characterized using ultraviolet-visible (UV-vis) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, and transmission electron microscopes (TEM). After the addition of Fe3+, the absorption rate of surface plasma resonance (SPR) increased to 524 nm, and the color of AuNPs α-CDs and AuNPs β-CDs was changed from pink to red and purple, respectively. AuNPs α-CDs are more uniform in shape and size than AuNPs β-CDs with a size of 23.34 nm. Further, AuNPs α-CDs are more stable, and the absorption rate at 524 nm wavelength decreases by 17.76%. AuNPs α-CDs have a good linear relationship with a linear regression coefficient of 0.996. The sensitivity of AuNPs α-CDs was good with LoD and LoQ both with 1.21 and 4.02 ppm, respectively. These results show that the sensor is superior in determining Fe3+. In addition, AuNPs α-CDs were used to detect Fe3+ in the tap water in South Tangerang, Banten, Indonesia.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"19 18","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138984390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Z. H. Ali, Dina Saleem, Abbas Khudhair Abbas, Baneen Salam Rasool, Mustafa Sabri Cheyad
In this work, new compounds of amide derivatives (C1-C3) were synthesized through the conversion reaction of p-chloroaniline to diazonium salt (B1), which reacts with aniline to form a new azo-compound (B3). Synthesized of p-alkoxybenzoic acid (A1-A3) and reacts with SOCl2 to form A4-A6 compounds that react with B3 compound to form amide compounds (C1-C3). The synthesized derivatives were tested by docking analysis and characterized via FTIR, 1H-NMR spectra. In the docking study, the interaction diagram also displays many van der Waals interactions, which are used to estimate the synthetic compounds' activity as insecticides like anti-termites. Heptyl came in first on the binding score, followed by octyl and then nonyl. Due to the compounds' modified conformation in interacting with the enzyme's binding pocket, the length of the alkyl residue of the derivative adversely impacted their binding inhibition. The synthesized compounds (C1 and C3) give a good result as anti-E. coli and anti-Staphylococcus strains.
{"title":"Synthesis and Estimation of the Insecticide and Antibacterial Activities for Some New Amide Derivatives","authors":"Z. H. Ali, Dina Saleem, Abbas Khudhair Abbas, Baneen Salam Rasool, Mustafa Sabri Cheyad","doi":"10.22146/ijc.81972","DOIUrl":"https://doi.org/10.22146/ijc.81972","url":null,"abstract":"In this work, new compounds of amide derivatives (C1-C3) were synthesized through the conversion reaction of p-chloroaniline to diazonium salt (B1), which reacts with aniline to form a new azo-compound (B3). Synthesized of p-alkoxybenzoic acid (A1-A3) and reacts with SOCl2 to form A4-A6 compounds that react with B3 compound to form amide compounds (C1-C3). The synthesized derivatives were tested by docking analysis and characterized via FTIR, 1H-NMR spectra. In the docking study, the interaction diagram also displays many van der Waals interactions, which are used to estimate the synthetic compounds' activity as insecticides like anti-termites. Heptyl came in first on the binding score, followed by octyl and then nonyl. Due to the compounds' modified conformation in interacting with the enzyme's binding pocket, the length of the alkyl residue of the derivative adversely impacted their binding inhibition. The synthesized compounds (C1 and C3) give a good result as anti-E. coli and anti-Staphylococcus strains. ","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"30 17","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138984641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohd Rashidi Abdull Manap, Ahmad Fadly Jusoh, Lim Xiang Chuin, Nur Diana Farhana Muhamad Zulkifli, Qhurratul Aina Kholili, Fatin Abu Hasan, Danish Aiman Akmal Mohd Effendy, Ramizah Azis
Spectroscopists face an ongoing challenge in identifying fuel spectra due to a wide range of fuel formulations and the increasing abuse of biodiesel-diesel blends. In Malaysia, a new type of biodiesel-diesel blend known as B7 and B10 has been introduced, which requires rapid and reliable discrimination methods. However, current identification methods are costly and time-consuming. To overcome this issue, a spectroscopy study was conducted using a portable Fourier transform infrared (FTIR) spectrometer to identify biodiesel-diesel blends. The study found that direct identification using spectral libraries was reliable in identifying complex samples but unable to differentiate B7 and B10 due to the libraries' focus on hydrocarbons rather than esters. Instead, FTIR spectroscopy provided unique spectral peaks for each blend. Spectral range influences the discrimination, and the truncated region 1697–1777 and 1164–1224 cm−1 was shown to be reliable for discriminating the B7 and B10. The study concluded that a combination of algorithms, libraries, and hierarchical cluster analysis (HCA) in FTIR spectroscopy could effectively differentiate the blends. The primary objective was to differentiate B7 and B10 by analyzing liquid samples collected in Malaysia using HCA and IR spectroscopies. FTIR spectroscopy provides molecular-specific vibrational signals and is proven as a rapid identification method.
{"title":"Discrimination of Biodiesel-Diesel of B7 and B10 by Infrared Spectroscopy with Dendogram","authors":"Mohd Rashidi Abdull Manap, Ahmad Fadly Jusoh, Lim Xiang Chuin, Nur Diana Farhana Muhamad Zulkifli, Qhurratul Aina Kholili, Fatin Abu Hasan, Danish Aiman Akmal Mohd Effendy, Ramizah Azis","doi":"10.22146/ijc.82499","DOIUrl":"https://doi.org/10.22146/ijc.82499","url":null,"abstract":"Spectroscopists face an ongoing challenge in identifying fuel spectra due to a wide range of fuel formulations and the increasing abuse of biodiesel-diesel blends. In Malaysia, a new type of biodiesel-diesel blend known as B7 and B10 has been introduced, which requires rapid and reliable discrimination methods. However, current identification methods are costly and time-consuming. To overcome this issue, a spectroscopy study was conducted using a portable Fourier transform infrared (FTIR) spectrometer to identify biodiesel-diesel blends. The study found that direct identification using spectral libraries was reliable in identifying complex samples but unable to differentiate B7 and B10 due to the libraries' focus on hydrocarbons rather than esters. Instead, FTIR spectroscopy provided unique spectral peaks for each blend. Spectral range influences the discrimination, and the truncated region 1697–1777 and 1164–1224 cm−1 was shown to be reliable for discriminating the B7 and B10. The study concluded that a combination of algorithms, libraries, and hierarchical cluster analysis (HCA) in FTIR spectroscopy could effectively differentiate the blends. The primary objective was to differentiate B7 and B10 by analyzing liquid samples collected in Malaysia using HCA and IR spectroscopies. FTIR spectroscopy provides molecular-specific vibrational signals and is proven as a rapid identification method.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136113083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tariq Hussein Mgheer, Ali Abdulraheem Kadhim, Zainab Abdalameer Hussein, Zaid Kaheel Kadhim, Muneer Abdul Aly Al-Da’amy, Abbas Jassim Atiyah, Salih Hadi Kadhim, Suma Jaafar Abbas
The current study involves a synthesis of a composite of copper oxide and cobalt oxide as a spinel oxide load over magnesium oxide. This synthesis of nanocomposite material was from nitrate salts of the corresponding metals by co-precipitation method, while it was investigated by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction techniques (XRD), field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), and the activity of these materials was estimated by appreciated adsorption of malachite green oxalate (MGO) dye from its aqueous solution. Adsorption isotherm was investigated using both Freundlich and Langmuir adsorption isotherms. While the results of the spectrophotometric studies showed that the composition of synthesized supported oxides at 450 °C was spinel type with nanoparticle size, and the optimum removal efficiency was around 98% for the adsorption of MGO dye over spinel nanocomposite surface achieved by using a dye concentration of 5 ppm, a mass of adsorbent surface of 5 mg, in terms of the adsorption model's isotherms the obtained results showed that the removal of MGO dye by the surface of this material was more fitted with the Freundlich models' adsorption.
{"title":"Adsorption of Malachite Green Oxalate Dye by CuCo<sub>2</sub>O<sub>4</sub>/MgO Spinel Oxide Nanocomposite","authors":"Tariq Hussein Mgheer, Ali Abdulraheem Kadhim, Zainab Abdalameer Hussein, Zaid Kaheel Kadhim, Muneer Abdul Aly Al-Da’amy, Abbas Jassim Atiyah, Salih Hadi Kadhim, Suma Jaafar Abbas","doi":"10.22146/ijc.83850","DOIUrl":"https://doi.org/10.22146/ijc.83850","url":null,"abstract":"The current study involves a synthesis of a composite of copper oxide and cobalt oxide as a spinel oxide load over magnesium oxide. This synthesis of nanocomposite material was from nitrate salts of the corresponding metals by co-precipitation method, while it was investigated by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction techniques (XRD), field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), and the activity of these materials was estimated by appreciated adsorption of malachite green oxalate (MGO) dye from its aqueous solution. Adsorption isotherm was investigated using both Freundlich and Langmuir adsorption isotherms. While the results of the spectrophotometric studies showed that the composition of synthesized supported oxides at 450 °C was spinel type with nanoparticle size, and the optimum removal efficiency was around 98% for the adsorption of MGO dye over spinel nanocomposite surface achieved by using a dye concentration of 5 ppm, a mass of adsorbent surface of 5 mg, in terms of the adsorption model's isotherms the obtained results showed that the removal of MGO dye by the surface of this material was more fitted with the Freundlich models' adsorption.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"4 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136113232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The gelcasting technique was employed to fabricate porous ceramics utilizing kaolinite clay as the base material with a combination of 20 wt.% cassava starch. The utilization of cassava starch as a pore-template material is a sustainable and eco-friendly approach. The dry mixture compacted pellets underwent calcination for 2 h at three distinct sintering temperatures, namely 900, 1000, and 1100 °C. The present study investigated the impact of sintering temperatures on various ceramic properties, including but not limited to porosity, hardness, crystallinity, lattice strain, and morphology. Furthermore, an increase in sintering temperature led to a reduction in crystallinity of the ceramic material from 81.71 to 78.06%, while the lattice strain increased, as determined by the full width at half maximum peak diffraction calculation. The study determined that the pore size remained microporous (21 Å) across all temperature treatments. Ultimately, a porous ceramic material was fabricated, exhibiting a porosity of 39.44% by volume and a desirable hardness of 94 HB. The optimal sintering temperature for this material was found to be 900 °C. The anticipated application of the porous ceramic, which has taken on a pellet shape, is as a catalyst support for wastewater filtration in the future.
{"title":"Effect of Sintering Temperature on the Microstructure Behavior of Gelcasted Porous Ceramics Using Cassava Starch as Pore Template","authors":"Suriati Eka Putri, Diana Eka Pratiwi, Rachmat Triandi Tjahjanto, Nita Magfirah Ilyas, Dahlang Tahir, Abd Rahman, Heryanto Heryanto","doi":"10.22146/ijc.78875","DOIUrl":"https://doi.org/10.22146/ijc.78875","url":null,"abstract":"The gelcasting technique was employed to fabricate porous ceramics utilizing kaolinite clay as the base material with a combination of 20 wt.% cassava starch. The utilization of cassava starch as a pore-template material is a sustainable and eco-friendly approach. The dry mixture compacted pellets underwent calcination for 2 h at three distinct sintering temperatures, namely 900, 1000, and 1100 °C. The present study investigated the impact of sintering temperatures on various ceramic properties, including but not limited to porosity, hardness, crystallinity, lattice strain, and morphology. Furthermore, an increase in sintering temperature led to a reduction in crystallinity of the ceramic material from 81.71 to 78.06%, while the lattice strain increased, as determined by the full width at half maximum peak diffraction calculation. The study determined that the pore size remained microporous (21 Å) across all temperature treatments. Ultimately, a porous ceramic material was fabricated, exhibiting a porosity of 39.44% by volume and a desirable hardness of 94 HB. The optimal sintering temperature for this material was found to be 900 °C. The anticipated application of the porous ceramic, which has taken on a pellet shape, is as a catalyst support for wastewater filtration in the future.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"1212 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136113073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ty Viet Pham, Duc Viet Ho, Anh Tuan Le, Y Duy Ngo, Nhan Thi Thanh Dang, Thang Quoc Le, Bao Chi Nguyen
This research aims to determine the volatile compounds present in Grewia bulot leaf extracts and evaluate their cytotoxic and antioxidant activities. The volatile constituents of the n-hexane and dichloromethane extracts were identified by using gas chromatography–mass spectrometry. The main compounds identified in the former were neophytadiene (18.2%), methyl palmitate (14.4%), methyl linoleate (9.7%), β-sitosterol (4.5%), and methyl stearate (3.4%), while those in the latter were palmitic acid (9.8%), hexadecane (7.4%), octadecane (6.0%), neophytadiene (5.3%), and 2-tert-butoxyethanol (5.3%). The cytotoxicities of the extracts were examined against four human cancer cell lines (SK-LU-1, Hep-G2, MCF-7, and KB), while their antioxidant activities were assessed using the DPPH radical scavenging assay. The n-hexane and dichloromethane extracts displayed weak activity against these cancer cell lines, with IC50 values ranging from 90.60 ± 3.49 to 98.27 ± 2.77 µg/mL. All extracts showed antioxidant activities, and the methanol extract exhibited the strongest at an SC50 value of 9.39 ± 0.90 µg/mL. This is the first report on the volatile constituents and bioactivities of G. bulot leaf extracts, suggesting their potential application as antioxidants.
{"title":"Volatile Organic Compounds and Antioxidant, Cytotoxic Activities of Extracts from the Leaves of <i>Grewia bulot</i>","authors":"Ty Viet Pham, Duc Viet Ho, Anh Tuan Le, Y Duy Ngo, Nhan Thi Thanh Dang, Thang Quoc Le, Bao Chi Nguyen","doi":"10.22146/ijc.84619","DOIUrl":"https://doi.org/10.22146/ijc.84619","url":null,"abstract":"This research aims to determine the volatile compounds present in Grewia bulot leaf extracts and evaluate their cytotoxic and antioxidant activities. The volatile constituents of the n-hexane and dichloromethane extracts were identified by using gas chromatography–mass spectrometry. The main compounds identified in the former were neophytadiene (18.2%), methyl palmitate (14.4%), methyl linoleate (9.7%), β-sitosterol (4.5%), and methyl stearate (3.4%), while those in the latter were palmitic acid (9.8%), hexadecane (7.4%), octadecane (6.0%), neophytadiene (5.3%), and 2-tert-butoxyethanol (5.3%). The cytotoxicities of the extracts were examined against four human cancer cell lines (SK-LU-1, Hep-G2, MCF-7, and KB), while their antioxidant activities were assessed using the DPPH radical scavenging assay. The n-hexane and dichloromethane extracts displayed weak activity against these cancer cell lines, with IC50 values ranging from 90.60 ± 3.49 to 98.27 ± 2.77 µg/mL. All extracts showed antioxidant activities, and the methanol extract exhibited the strongest at an SC50 value of 9.39 ± 0.90 µg/mL. This is the first report on the volatile constituents and bioactivities of G. bulot leaf extracts, suggesting their potential application as antioxidants.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136114595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this research, the synthesis of new substituted oxazolone derivatives is described via Erlenmeyer synthesis of N-acyl amino acid. Firstly, the azo derivative 1 was prepared by coupling the diazonium salt of 3-amino-4-methoxybenzoic acid with 4,5-dichloroimidazole in sodium hydroxide solution. Benzoyl chloride derivative 2, the key intermediate of the synthesis, was synthesized by the acylation of azo-carboxylic acid derivative 1 with thionyl chloride. The resulting acyl chloride derivative reacted with glycine in a basic catalyst to form a hippuric acid derivative 3. After that, oxazolone derivatives 4a–4f were prepared via the reaction of the hippuric acid derivative with various aromatic aldehydes. All new compound structures were confirmed by spectral techniques, i.e., FTIR, 1H-NMR, 13C-NMR spectroscopy, and elemental analysis. The antimicrobial activity (Staphylococcus aureus and Escherichia coli) of all new compounds was screened in vitro. The results against S. aureus and E. coli showed that most of the tested compounds have an activity ranging from moderate to low. The antioxidant activity of derivative 4a was also evaluated and showed good antioxidant activity.
{"title":"Synthesis, Antibacterial and Antioxidant Evaluation of 2-Substituted-4-arylidene-5(4<i>H</i>)-oxazolone Derivatives","authors":"Lina Saadi, Shaimaa Adnan","doi":"10.22146/ijc.83052","DOIUrl":"https://doi.org/10.22146/ijc.83052","url":null,"abstract":"In this research, the synthesis of new substituted oxazolone derivatives is described via Erlenmeyer synthesis of N-acyl amino acid. Firstly, the azo derivative 1 was prepared by coupling the diazonium salt of 3-amino-4-methoxybenzoic acid with 4,5-dichloroimidazole in sodium hydroxide solution. Benzoyl chloride derivative 2, the key intermediate of the synthesis, was synthesized by the acylation of azo-carboxylic acid derivative 1 with thionyl chloride. The resulting acyl chloride derivative reacted with glycine in a basic catalyst to form a hippuric acid derivative 3. After that, oxazolone derivatives 4a–4f were prepared via the reaction of the hippuric acid derivative with various aromatic aldehydes. All new compound structures were confirmed by spectral techniques, i.e., FTIR, 1H-NMR, 13C-NMR spectroscopy, and elemental analysis. The antimicrobial activity (Staphylococcus aureus and Escherichia coli) of all new compounds was screened in vitro. The results against S. aureus and E. coli showed that most of the tested compounds have an activity ranging from moderate to low. The antioxidant activity of derivative 4a was also evaluated and showed good antioxidant activity.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"136 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136113228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aswati Mindaryani, Vincent Sutresno Hadi Sujoto, Sandrina Christine Michelin Silalahi, Himawan Tri Bayu Murti Petrus, Edia Rahayuningsih
The textile sector leaves 80% of effluent untreated. Carcinogenic, mutagenic, and poisonous synthetic colors in textile waste streams harm the ecosystem. Biodegradable natural dyes are safer than synthetic dyes. Merbau sawdust is abundant in Papua but underutilized. Merbau wood (Intsia bijuga) has considerable tannin and dye potential. Tannin diffuses to the surface, coloring it brown in humid air or water. Merbau extract can be dried to make powdered natural dye. This study examines Merbau sawdust extract drying and natural dye quality at different temperatures. The drying process was carried out in a convective oven at 60, 75, and 90 °C. The data showed that the solid product of natural dye was already dried at 60–90 °C within 100 min. The content of tannin in the dried natural dye powder was analyzed by titration method. The tannin content in the solid product was 0.5–0.9 g tannin/g solid. The drying rate during the constant drying rate period is around 0.00137 to 0.00256 g/cm2 min. The effect of drying temperature (60 to 90 °C) on the tannin degradation is insignificant, based on the titration method and FTIR analysis.
{"title":"Drying of Merbau (<i>Intsia bijuga</i>) Sawdust Extract: Effect of Temperature on the Quality of Natural Dye Product","authors":"Aswati Mindaryani, Vincent Sutresno Hadi Sujoto, Sandrina Christine Michelin Silalahi, Himawan Tri Bayu Murti Petrus, Edia Rahayuningsih","doi":"10.22146/ijc.87624","DOIUrl":"https://doi.org/10.22146/ijc.87624","url":null,"abstract":"The textile sector leaves 80% of effluent untreated. Carcinogenic, mutagenic, and poisonous synthetic colors in textile waste streams harm the ecosystem. Biodegradable natural dyes are safer than synthetic dyes. Merbau sawdust is abundant in Papua but underutilized. Merbau wood (Intsia bijuga) has considerable tannin and dye potential. Tannin diffuses to the surface, coloring it brown in humid air or water. Merbau extract can be dried to make powdered natural dye. This study examines Merbau sawdust extract drying and natural dye quality at different temperatures. The drying process was carried out in a convective oven at 60, 75, and 90 °C. The data showed that the solid product of natural dye was already dried at 60–90 °C within 100 min. The content of tannin in the dried natural dye powder was analyzed by titration method. The tannin content in the solid product was 0.5–0.9 g tannin/g solid. The drying rate during the constant drying rate period is around 0.00137 to 0.00256 g/cm2 min. The effect of drying temperature (60 to 90 °C) on the tannin degradation is insignificant, based on the titration method and FTIR analysis.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"74 2 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136113229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Functionalization of metal-organic frameworks resulting in efficient CO2 adsorption materials became substantial in preventing the worsening environment upon the emission of CO2. In this study, several room-temperature ionic liquids (RTILs) with an imidazolium-based cation of 1-butyl-3-methylimidazolium [bmim]+ and anions of bis(trifluoromethylsulfonyl)imide [TFSI]−, trifluoromethanesulfonate [OTf]−, hexafluorophosphate [PF6]−, and tetrafluoroborate [BF4]− were incorporated into UiO-66 by wet impregnation method under air. The RTILs/UiO-66 composites were characterized by PXRD, FTIR, TGA, nitrogen physisorption, and CO2 adsorption. Based on the type of anions of imidazolium-based RTILs, the CO2 uptake of RTILs/UiO-66 composites followed the trend: [OTf]− > [TFSI]− > [PF₆]− > [BF₄]− at low temperature (273 K) and pressure (100 kPa). The CO2 uptake of pristine UiO-66 increased approximately 1.5 times upon incorporating [bmim][OTf]. The type of anions of imidazolium-based RTILs influences the CO2 adsorption performance of RTILs/UiO-66 composites in which anions containing fluoroalkyl group ([OTf]−, [TFSI]−) exhibited a higher CO2 uptake compared to inorganic fluorinated anions ([BF4]−, [PF6]−). Hence, the incorporation of hydrophobic imidazolium-based RTILs showed a potential to enhance the performance of UiO-66 for CO2 adsorption application.
{"title":"Enhancing the CO<sub>2</sub> Adsorption Performance of UiO-66 by Imidazolium-Based Room-Temperature Ionic Liquids (RTILs) Incorporation","authors":"Laela Mukaromah, Andi Haryanto, Yessi Permana, Aep Patah","doi":"10.22146/ijc.84669","DOIUrl":"https://doi.org/10.22146/ijc.84669","url":null,"abstract":"Functionalization of metal-organic frameworks resulting in efficient CO2 adsorption materials became substantial in preventing the worsening environment upon the emission of CO2. In this study, several room-temperature ionic liquids (RTILs) with an imidazolium-based cation of 1-butyl-3-methylimidazolium [bmim]+ and anions of bis(trifluoromethylsulfonyl)imide [TFSI]−, trifluoromethanesulfonate [OTf]−, hexafluorophosphate [PF6]−, and tetrafluoroborate [BF4]− were incorporated into UiO-66 by wet impregnation method under air. The RTILs/UiO-66 composites were characterized by PXRD, FTIR, TGA, nitrogen physisorption, and CO2 adsorption. Based on the type of anions of imidazolium-based RTILs, the CO2 uptake of RTILs/UiO-66 composites followed the trend: [OTf]− > [TFSI]− > [PF₆]− > [BF₄]− at low temperature (273 K) and pressure (100 kPa). The CO2 uptake of pristine UiO-66 increased approximately 1.5 times upon incorporating [bmim][OTf]. The type of anions of imidazolium-based RTILs influences the CO2 adsorption performance of RTILs/UiO-66 composites in which anions containing fluoroalkyl group ([OTf]−, [TFSI]−) exhibited a higher CO2 uptake compared to inorganic fluorinated anions ([BF4]−, [PF6]−). Hence, the incorporation of hydrophobic imidazolium-based RTILs showed a potential to enhance the performance of UiO-66 for CO2 adsorption application.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"55 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136114342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Azo dye ligand (HMDA), namely N-(4-((E)-((1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-3,5-dioxohepta-1,6-dien-4-yl)diazenyl)phenyl)acetamide was prepared by coupling diazonium salt of 4-aminoacetanilide with curcumin in basic conditions. The HMDA ligand and its Au(III) complex were characterized by elemental analysis, mass spectroscopy, 1H-NMR, FTIR, UV-visible spectra, and molar conductivity. The molar ratio method was applied to ascertain the stoichiometric composition of the Au(III) complex in aqueous solution, which was 1:2 (metal ion to ligand). HMDA ligand binding with Au(III) ion used the enolate form moiety of curcumin under alkaline conditions which was observed by infrared spectra and investigated by elemental analysis and 1H-NMR. HMDA and its Au(III) complex have been evaluated as stains for intestine, pancreas and kidney tissues of mice and exhibited important contrast. Both compounds showed the most potent staining activity toward blood cells, collagen, muscle fibers and cytoplasm in the selected tissues of mice. This azo dye and its complex of Au(III) succeeded in dyeing mice tissues, compared with the conventional stains.
{"title":"Synthesis, Characterization and Staining Ability of Novel Azo Dye Based on Curcumin and Its Au(III) Complex","authors":"Wesam Dheyab Kzar, Hasan Shamran Mohammed, Fatimah Swadi Zghair, Zahia Zizi","doi":"10.22146/ijc.84388","DOIUrl":"https://doi.org/10.22146/ijc.84388","url":null,"abstract":"Azo dye ligand (HMDA), namely N-(4-((E)-((1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-3,5-dioxohepta-1,6-dien-4-yl)diazenyl)phenyl)acetamide was prepared by coupling diazonium salt of 4-aminoacetanilide with curcumin in basic conditions. The HMDA ligand and its Au(III) complex were characterized by elemental analysis, mass spectroscopy, 1H-NMR, FTIR, UV-visible spectra, and molar conductivity. The molar ratio method was applied to ascertain the stoichiometric composition of the Au(III) complex in aqueous solution, which was 1:2 (metal ion to ligand). HMDA ligand binding with Au(III) ion used the enolate form moiety of curcumin under alkaline conditions which was observed by infrared spectra and investigated by elemental analysis and 1H-NMR. HMDA and its Au(III) complex have been evaluated as stains for intestine, pancreas and kidney tissues of mice and exhibited important contrast. Both compounds showed the most potent staining activity toward blood cells, collagen, muscle fibers and cytoplasm in the selected tissues of mice. This azo dye and its complex of Au(III) succeeded in dyeing mice tissues, compared with the conventional stains.","PeriodicalId":13515,"journal":{"name":"Indonesian Journal of Chemistry","volume":"28 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136113990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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