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Alternatives in environmental impact assessment: a taxonomy. 环境影响评价的备选方案:分类。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 DOI: 10.1093/inteam/vjaf135
Álvaro Enríquez-de-Salamanca

The consideration of alternatives is central to environmental impact assessment (EIA), as decisions cannot be made without options to choose from. Despite its significance, the treatment of alternatives in EIA practice has inadequacies, driven by factors such as a lack of interest, predefined options, and a limited understanding of the possibilities. An essential requirement for alternatives is that they must be reasonable. We identify three types of unreasonable alternatives-false, contrived, and subtle-which may distort the EIA process. To address ambiguities in existing literature, we propose a taxonomy classifying alternatives into seven groups: implementation, spatial, timing, functional, design, constructive, and operational, answering the questions why, where, when, what, and how. The aim of this taxonomy is to enhance the consideration of alternatives in EIA practice by improving knowledge of the existing possibilities. Early integration of alternatives, particularly during the scoping phase, and a proactive approach are essential to strengthening EIA; otherwise, the process risks becoming a mere environmental authorization rather than a robust decision-making tool.

考虑备选方案是环境影响评估的核心,因为没有备选方案就无法作出决定。尽管具有重要意义,但由于缺乏兴趣、预先确定的选择以及对可能性的理解有限等因素,在环评实践中对替代方案的处理存在不足。选择方案的一个基本要求是它们必须是合理的;我们确定了三种不合理的替代方案:虚假的、人为的和微妙的,它们可能扭曲环评过程。为了解决现有文献中的歧义,我们提出了一种分类法,将备选方案分为七组:实施、空间、时间、功能、设计、建设性和可操作性,并回答了为什么、在哪里、何时、做什么和如何做的问题。本分类法的目的是通过提高对现有可能性的认识,加强对环境影响评估实践中备选方案的考虑。早期整合替代方案,特别是在范围界定阶段,以及积极主动的方法对于加强环境影响评估至关重要;否则,这一过程就有可能成为一种纯粹的环境授权,而不是一种强有力的决策工具。
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引用次数: 0
Field-specific risk management for plant protection products: a "digitalized" way forward. 植保产品的特定领域风险管理:“数字化”前进之路。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 DOI: 10.1093/inteam/vjaf165
Gunnar Kahl, Andrew C Chapple, Frank Scherr, Robin Sur, Thomas G Preuss

Digitalization in agriculture is rapidly progressing. Smart farming technology and usage of farm management information systems implementing detailed geospatial data are used more frequently. The authorization approach of plant protection products in Europe does not currently make use of these advances. A 90th percentile protection goal is currently often established based on a few scenarios representing a realistic worst case of agri-environmental conditions. Within this process, the products receive authorization and mitigation requirements on the product label, which usually cover all fields, no matter whether the field is very vulnerable or not. This is a pragmatic approach that may lead to sufficient protection of most fields while other fields are accepted as being underprotected. To overcome the limitations of the current assessment based on a few worst-case scenarios, a transformation of the current risk assessment scheme towards a digital-driven field-specific risk management is proposed in three phases. The risk assessment procedure on European Union and Member State level would remain in large parts as it is. All three phases make use of the availability of farm management information systems to distribute field-specific restrictions and mitigation requirements. In phase 1, the mitigation requirements, based on standard regulatory scenarios (e.g., FOCUS [Forum for Co-ordination of Pesticide Fate Models and Their Use]), are transferred to the specific fields showing the closest similarities of environmental conditions. In phase 2, field-specific modeling is performed where the standard parameterization can be adapted for local conditions. In phase 3, geospatial data are used to derive field-specific parameterizations for the exposure and effect models. In all phases, each field receives application restrictions and mitigation requirements depending on the local situation, which farmers can provide by combining different mitigation options from a mitigation toolbox. The proposed scheme increases protection of biodiversity without compromising yield production.

农业数字化正在迅速发展。更频繁地使用智能农业技术和实施详细地理空间数据的农场管理信息系统。目前,欧洲植物保护产品的授权方法并没有利用这些进步。目前,90个百分位的保护目标通常是根据代表农业环境条件最坏的现实情况的几种情况来确定的。在这个过程中,产品会收到产品标签上的授权和缓解要求,这些要求通常涵盖所有领域,无论该领域是否非常脆弱。这是一种务实的做法,可能导致对大多数领域的充分保护,同时接受其他领域受到保护。为了克服目前基于少数最坏情况的评估的局限性,提出了当前风险评估方案向数字驱动的特定领域风险管理的转变,分为三个阶段。欧盟和成员国层面的风险评估程序将在很大程度上保持原样。所有三个阶段都利用现有的农场管理信息系统来分发具体的田间限制和缓解要求。在第一阶段,基于标准监管情景(例如FOCUS(农药命运模型及其使用协调论坛)或PERSAM (Vito NV, 2016))的缓解要求被转移到与环境条件最相似的特定领域。在阶段2中,执行特定于现场的建模,其中标准参数化可以适应当地条件。在阶段3中,地理空间数据用于导出暴露和效果模型的特定领域参数化。在所有阶段,每个领域都根据当地情况受到应用限制和缓解要求,农民可以通过结合缓解工具箱中的不同缓解方案来满足这些限制和缓解要求。拟议的方案在不影响产量的情况下增加了对生物多样性的保护。
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引用次数: 0
CARBON SEQUESTRATION SIMULATION STUDY BASED ON THE SWAT MODEL IN THE YILUO RIVER BASIN. 基于swat模型的沂罗河流域固碳模拟研究。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-28 DOI: 10.1093/inteam/vjag037
Mingjie Yang, Peng Zhang, Yuanhong Liu, Saihua Liu, Tao Lin

In terrestrial ecosystems, water and carbon cycles are closely coupled through processes such as photosynthesis, transpiration, and carbon allocation. Although advancements have been made in water-carbon coupling, existing studies predominantly focus on measurement methods and ecosystem model analysis, with insufficient attention paid to the linkages between hydrological processes and vegetation dynamics. This study employed the Yiluo River Basin as a case study, utilizing the Soil and Water Analysis Tool (SWAT) model to simulate the basin's hydrological cycle. By deconstructing and reconstructing the original Hydrological Response Unit (HRU) structure, this modified model was used to simulate actual evapotranspiration (E) and potential evapotranspiration (E0) for each HRU. By applying the light use efficiency (LUE) model and integrating E and E0 data, researchers determined the spatiotemporal distribution characteristics of carbon sequestration (gross primary productivity (GPP) and net primary productivity (NPP)), thereby enriching research on water-carbon linkages. Key findings include: (1) Both annual average GPP and NPP showed a significant upward trend, with NPP values slightly lower than GPP. (2) The annual average values in the upstream areas were notably higher than those in the downstream areas, closely related to vegetation types and evapotranspiration distribution. (3) Summer acted as the primary season for GPP and NPP accumulation, typically exhibiting high evapotranspiration rates and strong carbon sequestration. Over time, driven by climate change and vegetation restoration, spring cumulative contributions of GPP and NPP have gradually increased, thus narrowing the seasonal gap relative to summer.

在陆地生态系统中,水和碳循环通过光合作用、蒸腾作用和碳分配等过程紧密耦合。虽然在水碳耦合方面取得了一定的进展,但现有的研究主要集中在测量方法和生态系统模型分析上,对水文过程与植被动态之间的联系关注不足。本研究以沂罗河流域为例,利用SWAT (Soil and Water Analysis Tool)模型对流域水循环进行模拟。通过对原始水文响应单元(HRU)结构进行解构和重构,利用修正后的模型模拟各HRU的实际蒸散量(E)和潜在蒸散量(E0)。通过应用光利用效率(LUE)模型,整合E和E0数据,确定了碳固存(总初级生产力(GPP)和净初级生产力(NPP))的时空分布特征,从而丰富了水碳联系研究。主要发现包括:(1)年平均GPP和NPP均呈显著上升趋势,其中NPP略低于GPP。(2)上游地区的年平均值显著高于下游地区,与植被类型和蒸散分布密切相关。(3)夏季是GPP和NPP积累的主要季节,蒸散速率高,固碳能力强。随着时间的推移,在气候变化和植被恢复的驱动下,春季GPP和NPP的累积贡献逐渐增加,相对于夏季的季节差距逐渐缩小。
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引用次数: 0
Integrating multi-pathway risk evaluation of arsenic-contaminated soils and the intervention strategies for children. 综合砷污染土壤多途径风险评价与儿童干预策略。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-27 DOI: 10.1093/inteam/vjag036
Ying-Lin Wang, Karen Bradham, Li-Chi Lai, David J Thomas, Kirk Scheckel, Clay Nelson, Winston Dang, Zeng-Yei Hseu, Ling-Chu Chien, Hsing-Cheng Hsi

An accurate evaluation of human health risks from exposure to contaminated soils depends on several factors, including an accurate estimation of the site-specific bioavailability of metals. This study aimed to evaluate the risks associated with exposure to arsenic (As) contaminated soils through ingestion, inhalation, and dermal contact pathways in children under six years old. Additionally, relative bioavailability (RBA) and in vitro bioaccessibility (IVBA) were considered in the ingestion risk calculation, while local inhalation rates (IR) were used for estimating inhalation risk. Forty-one soil samples were collected in this study. Arsenic RBA was determined using a mouse urinary excretion bioassay. Two IVBA methods-EPA Method 1340 and the physiologically based extraction test (PBET)-were evaluated against the RBA values. The RBA of As ranged from 15.4% to 21.8% at Guandu (GD) sites. IVBA values using EPA Method 1340 ranged from 12.0% to 33.1%, while PBET values ranged from 4.3% to 13.0% for the gastric phase (GP) and 5.2% to 12.0% for the intestinal phase (IP). The hazard quotients (HQs) for the soil ingestion pathway in children aged 0-3 and 3-6 years old were below 1 when incorporating RBA and IVBA values. This study demonstrates that site-specific bioavailability assessments provide more accurate risk estimates than total metal concentrations, and that implementing simple hygiene interventions such as frequent handwashing can effectively reduce cumulative health risks from multiple exposure pathways in contaminated soil environments.

准确评价暴露于受污染土壤所造成的人类健康风险取决于若干因素,包括准确估计金属在特定地点的生物利用度。本研究旨在评估六岁以下儿童通过摄入、吸入和皮肤接触途径接触砷(As)污染土壤的风险。此外,在摄入风险计算中考虑了相对生物利用度(RBA)和体外生物可及性(IVBA),而在估计吸入风险时使用了局部吸入率(IR)。本研究共采集了41份土壤样品。采用小鼠尿排泄生物测定法测定砷RBA。两种IVBA方法- epa法1340和生理提取试验(PBET)-对RBA值进行了评估。在官渡(GD)站点,As的RBA为15.4% ~ 21.8%。EPA 1340法测定的IVBA值为12.0% ~ 33.1%,胃期(GP)的PBET值为4.3% ~ 13.0%,肠期(IP)的PBET值为5.2% ~ 12.0%。综合RBA和IVBA值后,0 ~ 3岁和3 ~ 6岁儿童土壤摄食途径的危害商(HQs)均小于1。该研究表明,特定地点的生物利用度评估提供了比总金属浓度更准确的风险估计,并且实施简单的卫生干预措施(如经常洗手)可以有效降低污染土壤环境中多种暴露途径的累积健康风险。
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引用次数: 0
Risk-benefit ranking of nitrification and urease inhibitors applied to agricultural soils using the PROMETHEE method. PROMETHEE方法应用于农业土壤的硝化和脲酶抑制剂的风险效益排序。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-19 DOI: 10.1093/inteam/vjag032
Xin Wang, Patrick Forrestal, Karl Richards, Dumsane Themba Matse, Enda Cummins

Nitrification and urease inhibitors (NUIs) are chemical compounds that can reduce nitrogen (N) loss and potentially enhance fertiliser nitrogen use efficiency (NUE) when combined appropriately with N fertilisers. Many studies have highlighted their agricultural and environmental benefits, including improving crop yields, reducing nitrate leaching, and lowering nitrous oxide emissions. However, their unintended presence in the environment (e.g.,, surface water) and the food chain has raised concerns. Individual inhibitors exhibit different levels of risks and benefits that need to be evaluated separately. In this study, a risk-benefit ranking was conducted to prioritise 10 NUIs based on environmental exposure, toxicity, and benefit through the preference ranking organization method for enrichment evaluation (PROMETHEE). In general, the urease inhibitor N-(n-butyl) thiophosphoric triamide (NBPT) was identified as the most preferred with a net flow value (φ) of 0.11 in the risk-benefit ranking of all NUIs due to its significant agricultural and environmental benefits with low risk from its short half-life. This assessment was supported by the fact that sometimes NIs can increase ammonia emissions, reducing their overall effectiveness in improving NUE compared to UIs. Our results also illustrated that the nitrification inhibitor dicyandiamide (DCD) was a recommended alternative (φ: 0.08) among evaluated NIs. This study assists stakeholders to balance the benefits and potential risks regarding the environment and human health issues associated with the application of NUIs in agriculture.

硝化和脲酶抑制剂(NUIs)是一种化合物,当与氮肥适当结合时,可以减少氮(N)的损失,并有可能提高肥料氮利用效率(NUE)。许多研究强调了它们的农业和环境效益,包括提高作物产量,减少硝酸盐淋失和降低一氧化二氮排放。然而,它们在环境(例如地表水)和食物链中的意外存在引起了人们的关注。单个抑制剂表现出不同程度的风险和益处,需要单独评估。本研究采用富集评价偏好排序组织法(PROMETHEE),根据环境暴露、毒性和效益对10个NUIs进行风险-收益排序。总体而言,脲酶抑制剂N-(正丁基)硫磷三酰胺(NBPT)因其具有显著的农业和环境效益,且半衰期短,风险低,因此在所有NUIs的风险效益排名中,其净流量值(φ)为0.11,被认为是最受欢迎的。这一评估得到以下事实的支持:与美国相比,有时新氮肥会增加氨排放,从而降低其提高氮肥利用效率的总体有效性。我们的结果还表明,在评估的NIs中,硝化抑制剂双氰胺(DCD)是推荐的替代方案(φ: 0.08)。这项研究帮助利益相关者平衡与农业中应用NUIs有关的环境和人类健康问题的利益和潜在风险。
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引用次数: 0
Progressing statistical analysis for regulatory ecotoxicology: developments, processes, and opinions. 监管生态毒理学的统计分析进展:发展、过程和意见。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-19 DOI: 10.1093/inteam/vjag029
Raoul Wolf, David R Fox, S Jannicke Moe

Statistical methods and computational tools applicable to ecotoxicology have developed and improved over recent decades, but regulatory risk assessments haven't kept pace, instead relying on outdated statistical methods and tools. Sessions in recent SETAC meetings dedicated to the development of statistical methods and tools for ecotoxicology have generated a high level of interest and discussion. Ecotoxicologists have expressed interest in the revision of the 2006 OECD document No. 54, "Current approaches in the statistical analysis of ecotoxicity data: a guidance to application" because they believe that the guidance is no longer reflective of contemporary statistical methods and tools; its revision is ongoing. Against this background, a call for papers for Special Series in IEAM was launched in autumn 2024 with manuscript submissions accepted until summer 2025. The purpose of this Special Series was to survey the statistical ecotoxicology landscape and reflect on recent developments, processes, and opinions. The editors of the Special Series welcomed and encouraged contributions and viewpoints from all employment sectors. The resulting series comprises eleven papers (seven original articles, three brief communications, and a workshop synthesis), with authors from academia, industry, government, and other research organizations. The series covers topics such as: recent progress in concentration-response modelling and hypothesis testing, including use of generalized linear models; strengths and weaknesses of established toxicity metrics (ECX, NOEC, BMD); application of toxicity metrics for species sensitivity distribution (SSD) modelling; added values of mechanistic effect modelling; and case studies highlighting opportunities and challenges related to the various statistical methods. This introductory paper aims to give an overview of the papers in the Special Series, summarizes their main topics and methods, and addresses further challenges to progress statistical analysis for regulatory ecotoxicology.

近几十年来,适用于生态毒理学的统计方法和计算工具得到了发展和完善,但监管风险评估却没有跟上步伐,而是依赖于过时的统计方法和工具。在最近的SETAC会议上,致力于开发生态毒理学统计方法和工具的会议引起了高度的兴趣和讨论。生态毒理学家对2006年经合组织第54号文件“生态毒性数据统计分析的当前方法:应用指南”的修订表示了兴趣,因为他们认为该指南不再反映当代统计方法和工具;修订工作正在进行中。在此背景下,IEAM于2024年秋季启动了专题系列论文征集,接受稿件至2025年夏季。这个特别系列的目的是调查统计生态毒理学景观和反映最近的发展,过程和意见。特别丛刊的编辑欢迎并鼓励所有就业部门的贡献和观点。最终的系列包括11篇论文(7篇原创文章,3篇简短的交流和一篇研讨会综合),作者来自学术界、工业界、政府和其他研究组织。该系列涵盖的主题包括:浓度-响应模型和假设检验的最新进展,包括广义线性模型的使用;现有毒性指标(ECX、NOEC、BMD)的优缺点;毒性指标在物种敏感性分布(SSD)建模中的应用;机制效应建模的附加价值;案例研究强调了与各种统计方法相关的机遇和挑战。这篇介绍性的论文旨在对特别系列中的论文进行概述,总结了他们的主要主题和方法,并解决了监管生态毒理学进展统计分析的进一步挑战。
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引用次数: 0
An Updated Unified Zinc Biotic Ligand Model for Protection of Freshwater Aquatic Life and its Application for Site-Specific Water Quality Objectives. 更新的淡水水生生物保护统一锌生物配体模型及其在特定地点水质目标中的应用。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-18 DOI: 10.1093/inteam/vjag031
Adam C Ryan, Robert C Santore, Kenneth C Schiff

A unified biotic ligand model (BLM) was developed to predict acute Zn toxicity to four invertebrates and two fish, and chronic toxicity to three invertebrates and a fish. Developed using a comprehensive ecotoxicity database, this unified BLM represents the first update to the unified Zn BLM in nearly 14 years. For comparative purposes, a unified Zn multiple linear regression (MLR) model was also developed. Both models are unified because they each use a single set of parameters to characterize the effects of toxicity modifying factors (e.g., pH, dissolved organic carbon [DOC], and major ions) on acute and chronic Zn toxicity. While both models were capable of accurately predicting Zn toxicity, the unified BLM performed marginally better based on quantitative model performance scores (MPS) and qualitative single-variable pH and DOC evaluations. The unified Zn BLM, which also performed better than the U.S. Environmental Protection Agency's hardness equation, was then used to normalize separate acute and chronic species sensitivity distributions (SSDs) to develop acute and chronic 5th percentile hazardous concentrations (HC5s) analogous to USEPA's aquatic life ambient water quality criteria (WQC). The unified Zn BLM-based WQC were shown to be protective of threatened and endangered species in California and appear to be protective of chemosensory endpoints for salmonids. Using monitoring data for California as a test case, chronic unified BLM-based WQC were lower than hardness-based WQC in 77% of samples, yet fewer WQC exceedances were observed. Implementation of the Zn BLM for site-specific water quality objectives (SSWQOs) using the fixed monitoring benchmark (FMB) approach indicates that for the California dataset, dry weather and wet weather samples should be considered separately to develop SSWQOs for each condition.

建立了统一的生物配体模型(BLM)来预测Zn对4种无脊椎动物和2种鱼类的急性毒性,以及对3种无脊椎动物和1种鱼类的慢性毒性。使用一个全面的生态毒性数据库开发,这个统一的BLM代表了近14年来对统一Zn BLM的第一次更新。为了便于比较,还建立了统一的Zn多元线性回归(MLR)模型。这两个模型是统一的,因为它们都使用一组参数来表征毒性修饰因子(如pH、溶解有机碳[DOC]和主要离子)对急性和慢性锌毒性的影响。虽然两种模型都能准确预测Zn毒性,但基于定量模型性能评分(MPS)和定性单变量pH和DOC评估,统一BLM的表现略好。统一的Zn BLM也优于美国环境保护署(U.S. Environmental Protection Agency)的硬度方程,然后将不同的急慢性物种敏感性分布(ssd)归一化,得出急慢性第5百分位有害浓度(HC5s),类似于美国环境保护署(USEPA)的水生生物环境水质标准(WQC)。统一的锌blm为基础的WQC被证明是保护受威胁和濒危物种在加州,似乎是保护鲑科的化学感官端点。以加州的监测数据为例,在77%的样本中,基于慢性统一blm的WQC低于基于硬度的WQC,但WQC超标的情况较少。使用固定监测基准(FMB)方法对特定地点水质目标(SSWQOs)实施Zn BLM表明,对于加利福尼亚数据集,应分别考虑干燥天气和潮湿天气样本,以针对每种条件开发SSWQOs。
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引用次数: 0
Screening-level exposure Models to Evaluate the direct Release of Cosmetic Ingredients (MERCI): Development and application to UV filters used in suncare products. 评估化妆品成分直接释放的筛选水平暴露模型(MERCI):用于防晒产品的紫外线过滤器的开发和应用。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-16 DOI: 10.1093/inteam/vjag030
Todd Gouin, Maura Roberts, W Martin Williams, Eva Klingelmann, Sascha Pawlowski, Arnaud Boivin, Ahmed Tlili, Ryan Heisler, Amelie Ott

Concerns regarding the environmental risks of UV-filters used in suncare products have grown in recent years. Much of this concern has been driven by their use in products by consumers engaged in outdoor recreational activities, such as swimming, which can facilitate their direct emissions into aquatic systems. Uncertainties in estimating the amount of a UV-filter that might be directly emitted to water, however, represent a continuing challenge, and include the need to quantify the number of users of suncare products, the skin area covered, the concentration of the UV-filter in the product and the extent to which the UV-filter is 'washed-off'. This study aims to address this gap, which includes the development and application of screening-level exposure Models to Evaluate the direct Release of Cosmetic Ingredients (MERCI). The tier 1 and 2 MERCI models-SUNscreen and multi-SUNscreen-are described, with application to octocrylene, a well-studied UV-filter used in suncare products. Model results suggest that both tools provide reasonable estimates of environmental exposure. Specifically, the tier 1 SUNscreen model, estimates an environmental concentration of 422 ng·L-1 in freshwater and range from 191-428 ng·L-1 in marine water capturing differences between low-moderate tidal dilution rates, whereas sediment concentrations are estimated to be 206 ng·g-1 dw (freshwater) and 94-210 ng·g-1 dw (marine). The tier 2 multi-SUNscreen model, on the other hand, estimates freshwater concentrations of 81 ng·L-1 in water and 0.5 ng·g-1 dw in sediment, results that are observed to be within an order of magnitude of monitoring data. Overall, both models support a conservative, screening-level approach for estimating environmental exposure to UV-filters, and thus represent tools that can be readily utilized to support both risk assessment and research prioritization.

近年来,人们越来越关注防晒产品中使用的紫外线过滤器对环境的危害。这种担忧在很大程度上是由从事户外娱乐活动(如游泳)的消费者在产品中使用它们引起的,这些活动可能促进它们直接排放到水生系统中。然而,在估计可能直接排放到水中的紫外线过滤器的数量方面存在不确定性,这是一个持续的挑战,其中包括需要量化使用防晒产品的人数、覆盖的皮肤面积、产品中紫外线过滤器的浓度以及紫外线过滤器被“洗掉”的程度。本研究旨在填补这一空白,包括开发和应用筛选水平暴露模型来评估化妆品成分的直接释放(MERCI)。第1层和第2层MERCI模型-防晒霜和多重防晒霜-描述了应用于八烯,一种经过充分研究的紫外线过滤器,用于防晒产品。模型结果表明,这两种工具都提供了对环境暴露的合理估计。具体而言,一级防晒模型估计淡水中的环境浓度为422 ng·L-1,海水捕获低-中等潮汐稀释率之间的差异范围为191-428 ng·L-1,而沉积物浓度估计为206 ng·g-1 dw(淡水)和94-210 ng·g-1 dw(海洋)。另一方面,第2层多重防晒霜模型估计水中的淡水浓度为81 ng·L-1,沉积物中的淡水浓度为0.5 ng·g-1 dw,观察到的结果在监测数据的一个数量级内。总的来说,这两种模型都支持保守的筛选级方法来估计紫外线过滤器的环境暴露,因此代表了可以很容易地用于支持风险评估和研究优先级的工具。
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引用次数: 0
Microplastics in an industrial zone wastewater treatment plant: Characterization, fate, and risk assessment. 工业废水处理厂中的微塑料:特性、命运和风险评估。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-14 DOI: 10.1093/inteam/vjag027
Emine Büşra Çolakoğlu, İbrahim Uyanık, Hamdi Mıhçıokur, Adem Yurtsever

The majority of research on microplastic (MP) characterization and removal has focused on municipal wastewater treatment plants (WWTPs). Hence, this study was performed at an industrial zone WWTP with sectors of textile, plastic recycling, furniture, etc. Three monthly sampling campaigns were conducted to analyze the MPs (abundance, shape, color, size, polymer type), and to investigate their fate and removal rate in the WWTP. Furthermore, the environmental risk assessment using EPI Suite™ modeling was conducted for common MP polymer types. The results indicated that the highest MP concentration was detected in the sludge sample (3,734 MP/L), while the lowest one was observed in the effluent sample (52 MP/L). While large MPs (5 mm - 425 µm) were removed by primary treatment processes, smaller MPs (250-125 µm) showed a tendency for accumulation in the sludge. The most dominant MP shapes were fiber and fragment in both wastewater and sludge samples, while the most dominant polymer types were polypropylene (38%), polyethylene (24%), and polyethylene terephthalate (11%). The environmental risk assessment reveals that polyvinyl chloride, polyethylene terephthalate, and polystyrene, present in minimal quantities in this study, are more likely to impact the growth of living organisms significantly compared to more common polymer types like polypropylene and polyethylene. Although the overall MP removal efficiency of the industrial zone WWTP was 88%, a significant quantity of MPs (1.5x109 MP/day) was still discharged into the Kızılırmak river that is mostly used for irrigation. Effective control/reduction of MP discharge necessitates the implementation of tertiary treatment processes in industrial zone WWTPs to prevent soil pollution.

微塑料(MP)的表征和去除研究主要集中在城市污水处理厂(WWTPs)。因此,本研究是在一个工业区的污水处理厂进行的,该工业区有纺织、塑料回收、家具等部门。每月进行三个采样活动,分析MPs(丰度、形状、颜色、大小、聚合物类型),并调查它们在污水处理厂中的命运和去除率。此外,使用EPI Suite™建模对常见MP聚合物类型进行了环境风险评估。结果表明,污泥样品中MP浓度最高(3734 MP/L),出水样品中最低(52 MP/L)。虽然大的MPs (5mm - 425µm)被初级处理工艺去除,但较小的MPs(250-125µm)在污泥中显示出积聚的趋势。在废水和污泥样品中,最主要的MP形状是纤维和碎片,而最主要的聚合物类型是聚丙烯(38%)、聚乙烯(24%)和聚对苯二甲酸乙二醇酯(11%)。环境风险评估显示,与聚丙烯和聚乙烯等更常见的聚合物类型相比,本研究中出现的少量聚氯乙烯、聚对苯二甲酸乙二醇酯和聚苯乙烯更有可能显著影响生物体的生长。虽然工业区污水处理厂的总体MP去除率为88%,但仍有大量的MP (1.5 × 109 MP/d)排放到主要用于灌溉的Kızılırmak河中。要有效控制/减少多酚排放,就必须在工业区污水处理厂实施三级处理工序,以防止土壤污染。
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引用次数: 0
Effectiveness of remediation at contaminated sediment sites based on measurements of bioavailability: testing a conceptual approach. 基于生物利用度测量的污染沉积物修复的有效性:测试一种概念性方法。
IF 8.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-14 DOI: 10.1093/inteam/vjag026
Danielle E Blum, Kenneth M Miller, Robert M Burgess

Remediation of contaminated sediment sites is complex and expensive, critical to the restoration of damaged ecosystems, and essential to the reduction of threats to human health. Along with the challenges of remediating a contaminated site is determining if the remediation has been effective. In this investigation, the use of bioavailability-based metrics was evaluated as a tool for assessing remedial effectiveness. Metrics included surface water concentrations and bioaccumulation in proxy species. Following the identification, collection, and curation of relevant retrospective bioavailability metric datasets, statistical analyses were performed comparing pre-remediation and post-remediation time periods. Statistical analyses used (i) hypothesis testing to identify significant reductions in bioavailability and (ii) regression to assess significant negative slopes. Datasets from three Superfund sites were evaluated in this investigation: Lower Grasse River, New Bedford Harbor, and Stauffer Chemical Company. Both the Lower Grasse River and New Bedford Harbor demonstrated decreases in the bioavailability of total PCBs as the remediations proceeded. Remedial effectiveness was more apparent for the Lower Grasse River compared to New Bedford Harbor most likely because remediation at the former had been completed for several years while it was still on-going at the latter. In contrast, effectiveness of remediation at Stauffer Chemical Company was less obvious based on statistical analyses of the bioavailability metrics. We speculate this reflects the more complicated environmental behavior of mercury compared to PCBs. This preliminary use of retrospective datasets of bioavailability metrics from Superfund sites to assess remediation effectiveness has shown promising results and merits further evaluation at other sites. In addition, contaminants like PCBs appear to be good candidates with this approach while mercury may not be. Also, datasets with good temporal separation of the pre-remediation and the post-remediation time periods are better candidates for this approach.

受污染沉积物场地的修复既复杂又昂贵,对恢复受损生态系统至关重要,对减少对人类健康的威胁至关重要。修复受污染场地的挑战之一是确定修复是否有效。在这项调查中,使用基于生物利用度的指标作为评估补救效果的工具进行了评估。指标包括地表水浓度和替代物种的生物积累。在确定、收集和整理相关的回顾性生物利用度度量数据集之后,对修复前和修复后的时间段进行了统计分析。统计分析使用(i)假设检验来确定生物利用度的显著降低,(ii)回归来评估显著的负斜率。本调查评估了来自三个超级基金站点的数据集:下格拉斯河、新贝德福德港和Stauffer化学公司。下格拉斯河和新贝德福德港都显示,随着修复的进行,总多氯联苯的生物利用度有所下降。与新贝德福德港相比,下格拉斯河的补救效果更为明显,很可能是因为前者的补救工作已经完成了好几年,而后者的补救工作仍在进行中。相比之下,基于生物利用度指标的统计分析,Stauffer化学公司的修复效果不太明显。我们推测,这反映了与多氯联苯相比,汞的环境行为更为复杂。初步使用超级基金站点的生物利用度指标回顾性数据集来评估修复效果已经显示出有希望的结果,值得在其他站点进一步评估。此外,多氯联苯等污染物似乎是这种方法的良好候选者,而汞可能不是。此外,具有良好时间间隔的预修复和后修复时间段的数据集更适合该方法。
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Integrated Environmental Assessment and Management
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