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Effect of Eu 2 O 3 Concentrations Doped Li-Na-K Borate Glasses on Luminescence Properties for Red Emission Material 铕掺杂Li-Na-K硼酸盐玻璃对红色发射材料发光性能的影响
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-29 DOI: 10.1080/10584587.2023.2234578
N. Jarucha, Y. Ruangtaweep, P. Meejitpaisan, P. Nawarat, P. Kanthang, N. Wongdamnern, P. Limsuwan, H.J. Kim, J. Kaewkhao, T. Sareein
AbstractThis paper investigated the europium-doped lithium sodium potassium borate glasses (LNKBEu). Glass was made using a melt-quenching technique with a range of europium doping concentrations ranging from 0.0 to 5.0 mol%. The absorption spectra showed that photons in the visible light and near infrared ranges were absorbed by the LNKBEu glasses. Photon absorption at 394 nm can excite the mirror to emit a number of photons in the VIS region, such as 590, 613, 652, and 701 nm. The results showed that 3.0 mol% was the optimal concentration of LNKBEu glass. Therefore, 3.0LNKBEu glass was studied using Judd-Ofelt (JO) analysis, which revealed an interesting possibility of its use. This glass is a high power red laser device.Keywords: Alkali borate glasseseuropiumrare earthphotoluminescence Disclosure StatementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis project is funded by the National Research Council of Thailand (NRCT) (Contract No. N41A650404) and CERNTEK COMPANY LIMITED. The authors would like to thank graduate students and research associates at the Center of Excellence in Glass Technology and Materials Science, as well as the Division of Industrial Materials Faculty of Science and Technology Rajamangala University of Technology Phra Nakhon, for their continuous collaboration in research.
摘要研究了掺铕硼酸锂钠钾玻璃(LNKBEu)。玻璃是用熔体淬火技术制成的,铕掺杂浓度范围为0.0 ~ 5.0 mol%。吸收光谱表明,LNKBEu玻璃吸收了可见光和近红外波段的光子。在394 nm处的光子吸收可以激发反射镜在VIS区域发射一定数量的光子,如590、613、652和701 nm。结果表明,LNKBEu玻璃的最佳浓度为3.0 mol%。因此,使用Judd-Ofelt (JO)分析对3.0LNKBEu玻璃进行了研究,揭示了其使用的有趣可能性。这个玻璃是一个高功率的红色激光装置。关键词:碱硼酸盐玻璃铕稀土地球光致发光披露声明作者未报告潜在利益冲突。本项目由泰国国家研究委员会(NRCT)资助(合同编号:N41A650404)和CERNTEK COMPANY LIMITED。作者要感谢玻璃技术和材料科学卓越中心的研究生和研究人员,以及拉贾曼加拉科技大学工业材料学院的科学和技术部门,感谢他们在研究方面的持续合作。
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引用次数: 0
Piezoelectric PVDF-TrFE/PET Energy Harvesters for Structural Health Monitoring (SHM) Applications 用于结构健康监测(SHM)的压电PVDF-TrFE/PET能量采集器
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2023.2239101
Berkay Kullukçu, Mohammad J. Bathaei, Muhammad Awais, Hadi Mirzajani, Levent Beker
Abstract This study presents a piezoelectric energy harvester made of poly(vinylidene fluoride-trifluoroethylene)/polyethylene terephthalate for use in structural health monitoring applications. The piezoelectric energy harvester was made of a layer of polyvinylidene fluoride-trifluoroethylene (PVDF/TrFE). In addition, PET sheets, double-sided micron-thick tapes, and PVDF-TrFE sheets were utilized in the fabrication of the device. The proposed device was characterized by measuring its output voltage and current. The output power of the harvester was sufficient to operate a MEMS pressure sensor under wind pressure, with a maximum current of 291.34 µA and a maximum voltage of 937.01 mV. The power value obtained was 272.99 µW.
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引用次数: 1
Synthesis, Structure and Thermal Properties of the Cu2NiSeTe Cu2NiSeTe的合成、结构和热性能
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2023.2227048
Kh. M. Guliyeva, N. N. Mursakulov, N. A. Aliyeva, Y. I. Aliyev
Abstract A compound Cu2NiSeTe with cation-cation and anion-anion substitution has been synthesized. Structural phase analysis was carried out by XRD. The thermal properties of the resulting compound at high temperatures were studied. The studies were carried out on a Differential Scanning Calorimeter in the temperature range T = 20-1000 °C. Thermal transitions were observed at temperatures T = 144, 587, 647, 714 °C. These transitions were analyzed and the thermodynamic potentials were determined. According to the mechanism of phonon-phonon interaction, an increase in heat capacity at high temperatures was found.
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引用次数: 0
Ruderman–Kittel–Kasuya–Yosida–like Ferromagnetism in Nonmetal Doped Y 2 O 3 非金属掺杂y2o3的类ruderman - kittel - kasuya - yosida铁磁性
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2023.2227047
J. Li, M. Luo, Y. H. Shen
AbstractA wide-gap semiconductor of Yttria (Y2O3) doped with nonmetal elements (B, C, and N) are investigated by using the first-principles method. We mainly discuss the exchange coupling between two dopants and find that the exchange coupling in current cases are sensitive to the B-B, C-C, and N-N distance. Unitary ferromagnetic (FM) and antiferromagnetic (AFM) states have been observed in the two-B-doped and two-N-doped Y2O3 structures, respectively. Surprisingly, as the C-C distance increases, a transformation between FM and AFM has been found, which shows an RKKY-like interaction due to the p-d hybridization between the C dopant and intrinsic Y atoms.Keywords: Y2O3ferromagneticRKKY-like interactionDFT calculations Disclosure StatementNo potential conflict of interest was reported by the author(s).Additional informationFundingWe thank the National Supercomputer Center in Shenzhen. The work is supported by the Natural Science Foundation of Shanghai (Grant No. 19ZR1419800).
用第一性原理法研究了非金属元素(B、C、N)掺杂钇(Y2O3)的宽间隙半导体。我们主要讨论了两种掺杂剂之间的交换耦合,发现当前情况下的交换耦合对B-B、C-C和N-N距离敏感。在双b掺杂和双n掺杂的Y2O3结构中分别观察到单一铁磁态(FM)和反铁磁态(AFM)。令人惊讶的是,随着C-C距离的增加,FM和AFM之间发生了转变,这是由于C掺杂剂和Y原子之间的p-d杂化导致的rkky -样相互作用。关键词:y2o3铁磁rkky -like相互作用dft计算披露声明作者未报告潜在利益冲突。我们感谢位于深圳的国家超级计算机中心。上海市自然科学基金(批准号:19ZR1419800)资助。
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引用次数: 0
Structural and Optical Properties of PEDOT: PSS PEDOT: PSS的结构和光学性质
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2023.2227056
Babak Emdadi, Ahmed Asimov
AbstractIn recent years, films fabricated from poly (3, 4-ethylenedioxythiophene): poly (4-styrenesulfonate) (PEDOT: PSS) aqueous dispersions have attracted lot of attention due to their exceptional advantages of high transparency in the visible range, excellent thermal stability and aqueous solution processibility. The effect of annealing on the structural, and optical properties of films obtained by the spin coating method on glass substrates has been investigated. This work investigated the impact of second annealing on the structural, and optical properties of poly (3, 4-ethylene dioxythiophene): poly (styrene sulfonate) (PEDOT: PSS) thin films. Thin films PEDOT: PSS of about 150 nm thicknesses were deposited by sol-gel method spin coating technique at room temperature. The obtained films were annealed twice: by annealing at 110 °C temperature for 15 min, and at 170 °C within one hour. The films were characterized by X-ray diffraction (XRD), spectroscopic ellipsometry (SE), photoluminescence spectroscopy, and atomic force microscopy (AFM) methods. Studies have shown that second annealing has reduced defects, efficiently.Keywords: PEDOTconducting polymersX-ray diffraction analysisellipsometry investigationAFM image Disclosure StatementNo potential conflict of interest was reported by the author(s).
摘要近年来,由聚(3,4 -乙烯二氧噻吩):聚(4-苯乙烯磺酸盐)(PEDOT: PSS)水分散体制备的薄膜因其在可见光范围内具有高透明度、优异的热稳定性和水溶液可加工性等优点而受到广泛关注。研究了退火对玻璃基板上自旋镀膜的结构和光学性能的影响。本文研究了二次退火对聚(3,4 -乙烯二氧噻吩):聚(苯乙烯磺酸盐)(PEDOT: PSS)薄膜结构和光学性能的影响。采用溶胶-凝胶自旋镀膜技术在室温下制备了厚度约150 nm的PEDOT: PSS薄膜。将得到的薄膜退火两次:在110°C温度下退火15 min,在170°C温度下退火1小时。采用x射线衍射(XRD)、椭偏光谱(SE)、光致发光光谱和原子力显微镜(AFM)等方法对薄膜进行了表征。研究表明,二次退火可以有效地减少缺陷。关键词:pedot导电聚合物x射线衍射分析椭偏法研究afm图像披露声明作者未报告潜在利益冲突。
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引用次数: 0
Research on Cloud Platform Software Aging Prediction Method Based on VMD-ARIMA-BilSTM Combined Model 基于VMD-ARIMA-BilSTM组合模型的云平台软件老化预测方法研究
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2023.2192665
Fengdong Shi, Zhi Yuan, Min Wang, Jun Cui
AbstractWhen the cloud platform runs under heavy load for a long time, internal resources will be consumed and errors will accumulate continuously. As a result, the software aging phenomenon occurs, which ultimately degrades the performance and reliability of the software system. Aiming at the above problems, this paper proposes a hybrid model based on integrated variational mode decomposition, moving average free regression and long and short memory network (VMD-ARIMA-BILSTM) to predict the software aging problem. Firstly, the original resource utilization rate is decomposed into stationary time series and non-stationary time series by variational mode decomposition. Then, the advantages of moving average free regression and bidirectional long short-term memory network are used to predict stationary and non-stationary series respectively. Finally, the prediction results are reconstructed to obtain the final prediction results. Experimental results show that compared with single ARIMA and BI-LSTM, the hybrid model designed in this paper has higher prediction accuracy and faster convergence speed.Keywords: Cloud platformsoftware agingVMDARIMABILSTM Disclosure StatementNo potential conflict of interest was reported by the author(s).
摘要当云平台长期在高负荷下运行时,会消耗内部资源,导致错误不断积累。因此,会出现软件老化现象,最终降低软件系统的性能和可靠性。针对上述问题,本文提出了一种基于变分模态分解、移动平均自由回归和长短时记忆网络的混合模型(VMD-ARIMA-BILSTM)来预测软件老化问题。首先,通过变分模态分解将原始资源利用率分解为平稳时间序列和非平稳时间序列;然后利用移动平均自由回归和双向长短期记忆网络的优势分别对平稳序列和非平稳序列进行预测。最后对预测结果进行重构,得到最终的预测结果。实验结果表明,与单一ARIMA和BI-LSTM相比,本文设计的混合模型具有更高的预测精度和更快的收敛速度。关键词:云平台软件老化vmdarimabilstm披露声明作者未报告潜在利益冲突。
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引用次数: 0
Modification of Structural and Dielectric Properties of SmFeO 3 Orthoferrites System by Ce Doping Ce掺杂改性smfeo3正铁氧体体系的结构和介电性能
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2023.2239098
Uma Gaikwad, Smita Acharya, Shraddha Shirbhate, Chitra Khade
AbstractRare-earth orthoferrites RFeO3 are important functional materials and are very promising due to their unique electrical properties. Amongst various orthoferrites systems, SmFeO3 is emerging as potential system having various multifunctional behaviour with structural modifications by doping or microstructural effect. In the present attempt, we explore SmFeO3 system and modify it by partially replacing Sm by Ce. We have synthesised pure SmFeO3 based system through Sol-Gel one of the combustion method. X-ray diffraction study confirms the formation of pure and highly crystalline single phase without any impurity. To get more clarity about structural features, Rietveld Refinement has been carried out using by Full-Proof Software which confirms the formation of orthorhombic structure with Pbnm space group. Dielectric study confirms that Ce doping in SmFeO3 modify dielectric constant from one order to two order. The response of polarisation with respect to applied electric field has been studied by P-E loop tracer. The remanent polarisation (pr) enhanced from 0.040 to 0.050 µC/cm2 for x = 0.10 after applied maximum electric field. An improvement in the ferroelectric loop was obtained due to the suppression of oxygen vacancies and the reduced leakage current density (10 − 8 A/cm2 at 20 kV/cm).Keywords: Orthoferritessol gelperovskitedielectric properties AcknowledgmentAMRL laboratory, Dept. of Physics, RTMNU, Nagpur, India is acknowledged for providing the Ferroelectric (P-E loop) as well as Dielectric characterization facility.Disclosure StatementNo potential conflict of interest was reported by the author(s).
稀土正铁氧体RFeO3是一种重要的功能材料,由于其独特的电学性能,具有广阔的应用前景。在各种正铁氧体体系中,SmFeO3是一种具有多种多功能行为的潜在体系,可以通过掺杂或微结构效应进行结构修饰。在本次尝试中,我们探索了SmFeO3体系,并将其部分替换为Ce。采用溶胶-凝胶燃烧法合成了纯SmFeO3基体系。x射线衍射研究证实形成了纯净、高结晶的单相,无任何杂质。为了更清楚地了解结构特征,利用Full-Proof Software进行Rietveld细化,确认了具有Pbnm空间群的正交结构的形成。电介质研究证实,Ce掺杂使SmFeO3的介电常数由一个量级提高到两个量级。用P-E环示踪器研究了极化对外加电场的响应。施加最大电场后,当x = 0.10时,剩余极化(pr)从0.040µC/cm2增加到0.050µC/cm2。由于抑制了氧空位和降低了漏电流密度(20 kV/cm时10−8 A/cm2),铁电回路得到了改进。印度那格浦尔RTMNU物理系amrl实验室因提供铁电(P-E环路)和介电表征设备而受到认可。披露声明作者未报告潜在的利益冲突。
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引用次数: 0
Impact of Ferroelectric Material BaTiO3 on Negative Capacitance TFET Device and Its Circuit Application 铁电材料BaTiO3对负电容TFET器件的影响及其电路应用
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2023.2227054
Amandeep Singh, Sanjeet Kumar Sinha, Sweta Chander
With the increase in scaling of transistors in nanometer regime, various short channel effects are emerging in transistor operation that are required to resolved while putting conventional transistor to any practical application. Various device modifications and structure improvizations have been made and reported by the researchers to overcome the short channel effects and replace the conventional MOSFET with an optimized device in practical circuit applications. The device structure proposed in this work incorporates the negative capacitance phenomenon for making subthreshold swing steeper and enhancing current ratio of TFET. Further the device dimensions are being optimized to get improvised characteristics and best results are obtained at 3 nm thick BaTiO3 Ferroelectric material for making negative capacitance gate stack. In this paper, negative capacitance TFET so formed is used for implementing inverter and 1 T DRAM cell. Results obtained shows that the inverter and DRAM cell operates at a very lower supply voltage and are more suitable for low power applications as compared to conventional circuits.
随着纳米尺度下晶体管尺寸的增大,晶体管工作中出现了各种各样的短沟道效应,传统晶体管在实际应用中必须加以解决。为了克服短沟道效应,并在实际电路应用中用优化的器件取代传统的MOSFET,研究人员已经对器件进行了各种修改和结构改进。本文所提出的器件结构结合了负电容现象,使TFET的亚阈值摆幅更陡,提高了电流比。此外,还对器件尺寸进行了优化以获得临时特性,并在3nm厚的BaTiO3铁电材料上获得了最佳效果,用于制作负电容栅极堆。本文采用负电容TFET来实现逆变器和1t DRAM单元。结果表明,与传统电路相比,逆变器和DRAM单元工作在非常低的电源电压下,更适合于低功耗应用。
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引用次数: 0
Extension of Surface Charge Density Studies of Metal Oxide Semiconductor (MOS) Structure to Polarization Studies of Metal Ferroelectric Metal (MFM) Structure in Bulk Form: Experimental and Simulation of Polarization Data 金属氧化物半导体(MOS)结构的表面电荷密度研究延伸到金属铁电金属(MFM)结构的本体极化研究:极化数据的实验与模拟
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2023.2239096
Syed Mahboob, None Rizwana
Ba(NdxTi(1-2x)Nbx)O3 and (Na0.5Bi0.5)(NdyTi1-2yNby)O3 relaxor ferroelectric materials were prepared through solid state sintering route. The polarization as a function of electric field (PE loops) were measured with Radiant technologies PE loop tracer. In the present studies we have extended the surface charge density studies of metal oxide semiconductor (MOS) structure to the polarization studies of metal ferroelectric and metal (MFM) structure in bulk form by combining it with the modified Glazounov and Arrhenius equations. The simulation is in good agreement the experimental data. In the case of Ba(NdxTi(1-2x)Nbx)O3 ceramics the value of dipole moment (p) are 2.24x10−26 C.m, 1.80x10−26 C.m, 2.23x10−26 C.m & 2.21x 10−26 C.m for x = 0.025, 0.05, 0.1 & 0.2, respectively. The values of surface potential (Ψp) are 466 meV, 503 meV, 552 meV & 505 meV for x = 0.025, 0.05, 0.1 & 0.2, respectively.
采用固态烧结法制备了Ba(NdxTi(1-2x)Nbx)O3和(Na0.5Bi0.5)(NdyTi1-2yNby)O3弛豫铁电材料。利用辐射技术测量了极化随电场(PE环路)的变化规律。在本研究中,我们将金属氧化物半导体(MOS)结构的表面电荷密度研究与修正的Glazounov和Arrhenius方程相结合,将其扩展到体形金属铁电和金属(MFM)结构的极化研究。仿真结果与实验结果吻合较好。对于Ba(NdxTi(1-2x)Nbx)O3陶瓷,当x = 0.025、0.05、0.1和0.2时,偶极矩(p)分别为2.24 × 10−26 cm、1.80 × 10−26 cm、2.23 × 10−26 cm和2.21 × 10−26 cm。x = 0.025、0.05、0.1和0.2时,表面电位(Ψp)分别为466 meV、503 meV、552 meV和505 meV。
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引用次数: 0
Catalytic Conversion of Ni 12 P 5 in Situ on the Surface of Carbon Nanotubes to Promote Polysulfide Conversion in High-Performance Lithium-Sulfur Batteries 碳纳米管表面Ni 12p5原位催化转化促进高性能锂硫电池中多硫化物的转化
4区 工程技术 Q4 Materials Science Pub Date : 2023-09-02 DOI: 10.1080/10584587.2022.2143187
Shenghong Mao, Wenxiao Su, Chunyuan Liu, Fu Zhao, Hongxia Zhao, Xiaoping Zheng
Abstract Lithium-sulfur batteries have received lots of attention due to their high energy density and cheap material. The poor electrical conductivity and slow electrochemical kinetics of sulfur hinder their application. Here, we in situ grow Ni12P5 on carbon nanotube to prepare composites as sulfur host. Electrochemical tests show that Ni12P5 acts as an electrocatalyst in the lithium-sulfur batteries, initiating the oxidation of Li2S6 and Li2S4 at higher potentials, significantly improving the reaction kinetics during charging and discharging. The CNT@Ni12P5/S composite exhibited 1352 mAh/g initial discharge capacity at 0.1 C and a retention capacity of 85% after 100 cycles at 0.2 C.
摘要锂硫电池因其高能量密度和廉价的材料而受到广泛关注。硫的导电性差和电化学动力学慢阻碍了其应用。本文在碳纳米管上原位生长Ni12P5,制备了以硫为主体的复合材料。电化学测试表明,Ni12P5在锂硫电池中起到电催化剂的作用,在更高的电位下引发Li2S6和Li2S4的氧化,显著改善了充放电过程中的反应动力学。CNT@Ni12P5/S复合材料在0.1℃下的初始放电容量为1352 mAh/g,在0.2℃下循环100次后的保持容量为85%。关键词:锂硫电池阴极磷化镍电催化催化动力学披露声明作者未报告潜在的利益冲突。项目资助:甘肃省自然科学基金重点项目(No.22JR5RA313)、甘肃省教育厅甘肃高校创新基金项目(No.2021A-162, No.2022A-169)、兰州市人才创新创业计划项目(No.114)。兰州理工学院青年科技创新计划项目(No.2020KJ-18)和2019年兰州市首批科技计划项目(No.2019-1-46)。
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引用次数: 0
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Integrated Ferroelectrics
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