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Mechanism of bonding of Fe/Al bimetal during heat treatment of compound cast parts 复合铸件热处理过程中Fe/Al双金属结合机理
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-11-01 DOI: 10.1080/13640461.2020.1853392
H. Honarjoo, R. Raiszadeh
ABSTRACT The formation of bonding between Al and Fe after the initial compound casting and during a heat treatment regime is investigated. No significant bonding was observed between the two metals after the initial casting. This observation was attributed to the presence of oxide films on the liquid Al and solid Fe alloys. The heat treatment of the cast part at 973 K (700°C) for at least 15 min is shown to cause the two alloys to bond to each other seamlessly. The cracks that formed on the Al oxide layer (due to the pouring stresses or the remelting of the alloy) is suggested to provide the necessary paths for the contact between the Al melt and the trapped atmosphere between the Al and Fe alloys, and the contact between the Al melt and the Fe surface. A detailed mechanism for the bonding is presented in this paper.
摘要:本文研究了Al和Fe在初始复合铸造后和热处理过程中形成的键合。初次铸造后,两种金属之间没有明显的结合。这一观察结果归因于液态铝和固态铁合金上存在氧化膜。在973 K(700°C)下对铸件进行至少15分钟的热处理可以使两种合金无缝地结合在一起。在Al氧化层上形成的裂纹(由于浇注应力或合金的重熔)为Al熔体与Al和Fe合金之间的俘获气氛以及Al熔体与Fe表面的接触提供了必要的途径。本文详细介绍了这种结合的机理。
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引用次数: 3
Development of ultra-high strength carbide-free bainitic cast steels 超高强度无碳化物贝氏体钢的研制
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-11-01 DOI: 10.1080/13640461.2020.1843778
N. Tenaglia, A. Basso, J. Massone, R. Boeri
ABSTRACT High-silicon cast steels and proper heat treatment cycles were designed in order to obtain carbide-free bainitic microstructures. The design process allowed to obtain the desired microstructures after heat treatment cycles compatible with industrial practices and using low amounts of inexpensive alloying elements. The different chemical compositions and austempering temperatures tested resulted in ultra-high-strength steels showing remarkably total elongations. The obtained tensile properties satisfy the minimum requirements specified for AHSS in ASTM A1088 standard, and also the requirements for high-strength cast steels stated in ASTM A148. Moreover, many microstructures developed in this work reach the tensile performance of the very expensive maraging steels.
为了获得无碳化物贝氏体组织,设计了高硅铸钢和适当的热处理循环。该设计过程允许在热处理循环后获得所需的微观结构,该热处理循环与工业实践兼容,并使用少量廉价的合金元素。测试的不同化学成分和等温淬火温度导致超高强度钢显示出显著的总伸长率。获得的拉伸性能满足ASTM A1088标准中规定的AHSS的最低要求,以及ASTM A148中规定的高强度铸钢的要求。此外,在这项工作中开发的许多微观结构达到了非常昂贵的马氏体时效钢的拉伸性能。
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引用次数: 1
Phase transition and microstructure investigation of perferritic isothermed ductile iron (IDI) 过铁素体等温球墨铸铁(IDI)的相变及显微组织研究
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-10-21 DOI: 10.1080/13640461.2020.1833477
M. Landesberger, R. Koos, Maximilian Erber, Matteo Pernumian, S. Masaggia, M. Hoelzel, W. Volk
ABSTRACT Optical analysis, dilatometry as well as neutron diffraction are utilised to investigate the phase transition within ductile iron both in-situ and after the heat treatment process for perferritic isothermed ductile iron (IDI). A suitable annealing temperature is chosen by calculating a phase diagram for the investigated alloy. The phase transition which happens slightly above upper intercritical temperature is followed by neutron diffraction, while dilatometry elucidates the IDI microstructure evolution for cooling rates from 40 to 0.125 K/s. The dilatometry results are visualised in a CCT diagram and further investigated with metallography. An additionally used colour etching method is basis for discussing the formation of the pearlitic/ferritic network. The presence of 2 vol.-% of ferrite was sufficient to achieve the typical IDI microstructure. Finally, the cementite phase volume fractions and crystal structure are evaluated. . The lattice constants of ferrite and cementite were independent of the formed microstructure.
摘要利用光学分析、膨胀计和中子衍射研究了全铁等温球墨铸铁(IDI)在原位和热处理后的相变。通过计算所研究合金的相图来选择合适的退火温度。相变发生在略高于上临界温度的温度之后是中子衍射,而膨胀计阐明了在40至0.125K/s的冷却速率下IDI微观结构的演变。膨胀测量结果在CCT图中可视化,并用金相学进行进一步研究。另外使用的彩色蚀刻方法是讨论珠光体/铁素体网络形成的基础。2体积%铁氧体的存在足以实现典型的IDI微观结构。最后,对渗碳体的相体积分数和晶体结构进行了评价。铁素体和渗碳体的晶格常数与所形成的微观结构无关。
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引用次数: 0
Effects of thermal exposure on the microstructure and mechanical properties of Al-12Si-4Cu-1Ni-1Mg-2Mn piston alloys 热暴露对Al-12Si-4Cu-1Ni-1Mg-2Mn活塞合金组织和力学性能的影响
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-10-21 DOI: 10.1080/13640461.2020.1838077
B. Lin, S. Xia, Yue Tang, Yuliang Zhao, Kun Liu, Huaqiang Xiao, Shaobo Li, Weiweng Zhang
ABSTRACT The effect of thermal exposure on the elevated-temperature mechanical properties of heat-treated Al-12Si-4Cu-1Ni-1 Mg-2Mn piston alloys was investigated using optical microscopy (OM), scanning electron microscope (SEM), transmission electron microscopy (TEM), and tensile tests at elevated temperatures. The results showed that coarsening of the strengthening precipitates following a prolonged exposure at 350°C had a deleterious effect on the elevated-temperature tensile properties. Further thermal exposure up to 50 h did not result in even a slight reduction in the strength. After exposure at 350°C, the value of elevated-temperature ultimate tensile strengths of Al-12Si-4Cu-1Ni-1 Mg-2Mn piston alloys were 92, 80, and 73 MPa for 0 h, 10 h, and 100 h of thermal exposure, respectively, which are superior to those of the commercial piston alloys. The high-performance, elevated-temperature mechanical properties of Al-12Si-4Cu-1Ni-1 Mg-2Mn piston alloys can be attributed to the high thermal stability Mn-rich intermetallics and Al3CuNi.
摘要采用光学显微镜(OM)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和高温拉伸试验研究了热暴露对热处理的Al-12Si-4Cu-1Ni-1Mg-2Mn活塞合金高温力学性能的影响。结果表明,在350°C下长时间暴露后,强化沉淀物的粗化对高温拉伸性能产生了有害影响。长达50小时的进一步热暴露甚至没有导致强度的轻微降低。在350°C下暴露后,Al-12Si-4Cu-1Ni-1Mg-2Mn活塞合金在热暴露0小时、10小时和100小时的高温极限拉伸强度分别为92、80和73MPa,这优于商业活塞合金。Al-12Si-4Cu-1Ni-1Mg-2Mn活塞合金的高性能、高温力学性能可归因于富含Mn的金属间化合物和Al3CuNi的高热稳定性。
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引用次数: 3
The origin of thermal expansion differences in various size fractions of silica sand 不同粒径硅砂热膨胀差异的成因
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-10-20 DOI: 10.1080/13640461.2020.1838078
Judit Svidró, A. Diószegi, József Tamás Svidró
ABSTRACT In this study, thermophysical properties of a commonly used silica sand were investigated and their relation to its granulometric and chemical composition was studied. Thermal expansion and differential scanning calorimetry tests were performed on individual fractions of the silica sand together with X-ray fluorescence measurements to determine their constituents. It was found that the various size fractions of silica sand exhibit different levels of thermal expansion based on the differences in SiO2 content. The expansion behaviour of two additional silica samples and a recycled olivine sand was also investigated in relation to its grain size to justify the findings.
摘要本研究对一种常用硅砂的热物理性质进行了研究,并研究了其与粒度和化学成分的关系。对硅砂的各个部分进行热膨胀和差示扫描量热测试,并进行X射线荧光测量,以确定其成分。研究发现,基于SiO2含量的差异,不同粒度的硅砂表现出不同的热膨胀水平。还研究了两个额外的二氧化硅样品和一个回收的橄榄石砂的膨胀行为与其粒度的关系,以证明这一发现的合理性。
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引用次数: 6
Extrema of micro-hardness in fully pearlitic compacted graphite cast iron 完全珠光体压实石墨铸铁的显微硬度极值
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-09-02 DOI: 10.1080/13640461.2020.1832308
J. Lacaze, C. Moussa, Y. Thébault, W. Guesser
ABSTRACT For improving the mechanical strength of cast irons, a fully pearlitic matrix is sought by alloying with tin, copper and manganese. This applies in particular to the compacted graphite irons considered here. While average macro- and micro-hardness values were similar for the four fully pearlitic alloys under study, it was found that high copper and low tin content showed some very high maximum micro-hardness values, significantly higher than the corresponding mean. Such values may be seen as hard points in the material that would certainly impair machinability. Discussion of the reasons for these extreme values opens directions for further studies.
为了提高铸铁的机械强度,通过与锡、铜和锰合金化来寻求完全珠光体基体。这尤其适用于这里考虑的压实石墨铁。虽然四种完全珠光体合金的宏观和微观硬度平均值相似,但高铜含量和低锡含量合金的最大显微硬度值非常高,显著高于相应的平均值。这些值可能被视为材料中的硬点,这肯定会损害可加工性。对这些极值原因的讨论为进一步研究开辟了方向。
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引用次数: 3
Effect of the cooling rate on the tensile strength of pearlitic lamellar graphite cast iron 冷却速率对珠光体层状石墨铸铁抗拉强度的影响
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-09-02 DOI: 10.1080/13640461.2020.1822573
F. O. Lima, L. F. Bauri, H. B. Pereira, C. Azevedo
ABSTRACT The effects of cooling rate and carbon equivalent on the tensile strength of pearlitic lamellar graphite cast irons were investigated. The cooling rate was varied from 6°C/s to 35°C/s for values of the carbon equivalent equal to 4.17% and 3.83%. The increase in the cooling rate promoted the refining of the eutectic cell size, primary dendrite modulus, interdendritic hydraulic diameter and pearlite interlamellar spacing. The increase in the cooling rate also refined their graphite flakes, changing the morphology from B to E type. The reduction in the carbon equivalent increased the proportion of primary dendrites from 25% to 40%. The maximum tensile strength increased from 274 to 524 MPa with the increase in the cooling rate and the reduction in the carbon equivalent. These results were used to test two tensile strength predictive models based on modified versions of the Griffith and Hall-Petch equations.
研究了冷却速度和碳当量对珠光体片层石墨铸铁抗拉强度的影响。当碳当量分别为4.17%和3.83%时,冷却速率在6°C/s至35°C/s之间变化。冷却速率的增加促进了共晶细胞尺寸、初生枝晶模量、枝晶间水力直径和珠光体层间距的细化。冷却速率的增加也细化了它们的石墨薄片,使其形态从B型变为E型。碳当量的减少使一次枝晶的比例从25%增加到40%。随着冷却速率的增加和碳当量的减少,最大抗拉强度从274 MPa增加到524 MPa。这些结果用于测试两个基于Griffith和Hall-Petch方程修正版本的抗拉强度预测模型。
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引用次数: 3
Thermodynamic behaviour of nitrogen in the carbon saturated Fe-Mn-Si alloy during casting 碳饱和铁锰硅合金中氮在铸造过程中的热力学行为
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-09-02 DOI: 10.1080/13640461.2020.1834176
Min-Kyu Paek, Junmo Jeon, D. Lindberg
ABSTRACT The evolution of nitrogen gas formation in cast iron was studied based on the information of the N solubility in the carbon-saturated iron-containing Mn and Si over the wide temperature range. In order to verify the accuracy of the Fe-Mn-Si-C phase diagram, the transition temperatures of the Fe-Mn-2.7 wt%Si-Csat alloys were measured according to the Mn concentration using a differential scanning calorimetry under the purified Ar atmosphere. The recent thermodynamic modelling result of the Fe-Mn-Si-C-N system was used to describe the solubility limit of N in liquid and solid solution in the carbon saturated iron alloys. The cooling and quenching experiments were also carried out to check the effects of temperature and phase transformation on the N solubility limit in the temperature range from 500°C to 900°C.
基于N在碳饱和含铁Mn和Si中的溶解度信息,研究了铸铁中氮气形成的演化过程。为了验证Fe-Mn-Si-C相图的准确性,利用差示扫描量热法在纯化氩气氛下,根据Mn浓度测量了Fe-Mn-2.7 wt%Si-Csat合金的转变温度。利用Fe-Mn-Si-C-N体系的热力学模拟结果,描述了N在饱和碳铁合金中液相和固相的溶解度极限。在500 ~ 900℃温度范围内进行了冷却和淬火实验,考察了温度和相变对N溶解度极限的影响。
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引用次数: 2
Structure formation and multistep nucleation in CASTING Al-Mg-Si alloys 铸造Al-Mg-Si合金的组织形成和多步形核
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-09-02 DOI: 10.1080/13640461.2020.1822632
O. Trudonoshyn, O. Prach, A. Slyudova, V. Lisovskii
ABSTRACT The process of multistep nucleation during solidification in hypoeutectic Al-Mg-Si casting alloys was investigated. The morphology of the nucleating particles, Mg2Si primary crystals and Al-Mg2Si eutectic, was investigated with scanning electron microscopy (SEM) on polished and deep etched microsections. The mechanism of formation of the Mg2Si crystal was attributed to heterogeneous nucleation on the nucleating particles. It was observed that the majority of the alloys particles found in the studied are oxides. It was established that eutectic Al–Mg2Si in hypoeutectic alloys has the morphology of ‘eutectic crystal’, where one face of the crystal has triangular-spiral morphology. The mechanism of formation of Al-Mg2Si eutectic cells is attributed to epitaxial growth on Mg2Si crystals. The microhardness of the structural components (Mg2Si crystals, α-Al dendrites, Al-Mg2Si eutectic, and Al3Ti crystals) was measured using Vickers hardness tester.
研究了亚共晶Al-Mg-Si铸造合金凝固过程中的多步形核过程。用扫描电子显微镜(SEM)在抛光和深蚀刻的微切片上研究了成核颗粒Mg2Si初晶和Al-Mg2Si共晶的形态。Mg2Si晶体的形成机制归因于成核颗粒上的非均匀成核。据观察,在研究中发现的大多数合金颗粒都是氧化物。研究表明,亚共晶合金中的共晶Al–Mg2Si具有“共晶晶体”的形态,其中晶体的一面具有三角形螺旋形态。Al-Mg2Si共晶电池的形成机理是在Mg2Si晶体上外延生长。用维氏硬度计测量了结构成分(Mg2Si晶体、α-Al枝晶、Al-Mg2Si共晶和Al3Ti晶体)的显微硬度。
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引用次数: 5
Simulations and experiments of mould filling in lost foam casting 消失模铸造充型的模拟与试验
IF 1.4 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2020-09-02 DOI: 10.1080/13640461.2020.1822572
Feng-jun Li, Hua Zhao, F. Ren, Shaobiao Song, X. Shao, A. Volinsky
ABSTRACT A new method for mould filling calculation of lost foam casting (LFC) was developed based on the main hypothesis, which assumes that every point on the melt-pattern interface moves in the radial direction. The value of the normal velocity is calculated by an empirical formula, which is the function of the degree of vacuum, pattern density, pouring temperature, metallic static head, etc. At a given time step, every interface point moves to a new position, and all the points form the shape of the melt-pattern interface. Based on the new position of the interface and the given velocity of the interface cell, the fluid flow and the temperature distribution of the molten metal can be calculated during the mould filling process of LFC. The calculated results were validated by experiments.
摘要基于熔模界面上各点径向运动的主要假设,提出了一种计算消失模铸造充型量的新方法。法向速度是真空程度、模型密度、浇注温度、金属静水头等因素的函数,用经验公式计算出法向速度。在给定的时间步长,每个界面点移动到一个新的位置,所有的点形成熔化模式界面的形状。根据新的界面位置和给定的界面单元速度,可以计算出LFC充型过程中的流体流动和熔融金属的温度分布。通过实验验证了计算结果。
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引用次数: 3
期刊
International Journal of Cast Metals Research
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