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Effect of Microstructural Variation of a Martensitic Stainless Steel on High Temperature Degradation Behavior 马氏体不锈钢显微组织变化对高温降解行为的影响
Pub Date : 2021-01-01 DOI: 10.11648/j.ijmsa.20211006.11
Giselly Bandeira Gomes Dias De Lima, Marcio Roberto Da Rocha
: Martensitic stainless steels are chromium steels with a small addition of Ni. They have a good combination of mechanical properties and corrosion resistance, due to their Cr content [12]. The degradation processes are present in several industrial equipments and, generate repair or replacement actions in a periodic way. In an attempt to minimize these problems, several studies have been developed with this purpose. However, due to the several variables involved in the process, both in design and equipment operation, there is still a fertile field for an effective understanding of these degradation problems. For example, one can cite the effects that the different microstructures developed in martensitic stainless steels, materials commonly used in severe service conditions, present on the behavior of resistance to oxidation of the material. And, also, the environment in which the material is inserted. In a high-temperature environment, impurities are found, among them, compounds such as vanadium pentoxide, which act vigorously in the progression of the oxidation process. Oxidation tests are necessary to relate the behavior and influence exerted on the oxide layer by grain refinement. Thus, the present work aims to analyze the influence of the microstructure of the martensitic stainless steel AISI 420, with application of different treatments. The behavior of this steel was evaluated under different oxidation conditions, in contact with a solution containing Vanadium Pentoxide, and as a control parameter the mass variation of the samples. Analysis of the microstructures and the corrosion/oxidation products were carried out via Optical Microscopy, Scanning Electron Microscopy. As result it was verified the importance of the microstructure in the material's resistance to the action of degradation by oxidation, and its influence on the oxide layer formation process.
马氏体不锈钢是含少量镍的铬钢。由于含有Cr,它们具有良好的机械性能和耐腐蚀性[12]。退化过程存在于许多工业设备中,并以周期性的方式产生修理或更换动作。为了尽量减少这些问题,为此目的进行了几项研究。然而,由于在设计和设备操作过程中涉及的几个变量,仍然有一个肥沃的领域来有效地理解这些退化问题。例如,人们可以引用马氏体不锈钢中不同的微观结构对材料抗氧化性能的影响,马氏体不锈钢通常用于恶劣的使用条件。还有,材料被插入的环境。在高温环境中,杂质被发现,其中,化合物,如五氧化二钒,在氧化过程的进展中起着强烈的作用。为了了解晶粒细化对氧化层的影响及其行为,必须进行氧化试验。因此,本文旨在分析不同处理方法对马氏体不锈钢AISI 420显微组织的影响。在不同的氧化条件下,在与含有五氧化钒的溶液接触时,评估了该钢的行为,并将样品的质量变化作为控制参数。通过光学显微镜、扫描电镜对腐蚀产物和氧化产物进行了显微组织分析。结果验证了微观结构对材料抗氧化降解的重要性,以及对氧化层形成过程的影响。
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引用次数: 0
Experimental Testing and Fabrication of Metal Matrix Composite for Automotive Applications 汽车用金属基复合材料的实验测试与制造
Pub Date : 2021-01-01 DOI: 10.11648/j.ijmsa.20211006.12
Alie Wube Damtew, R. Thiyagarajan
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引用次数: 0
Nurturing Plasmonic Properties of Nanocomposite Thin Films: The Importance of Optimum Oblate Shape 培养纳米复合薄膜的等离子体特性:最佳扁圆形状的重要性
Pub Date : 2021-01-01 DOI: 10.32732/jma.2021.10.2.73
R. Laha
Metal nanoparticles (MNPs) embedded dielectric thin films are very crucial for many optoelectronic applications. This report investigates various ways of tuning the plasmonic properties of such nanocomposite thin films. For this, the well-known plasmon resonance condition was first generalized to include the shape and volume fraction of MNPs. This was followed by deriving an empirical formula for the resonance position (λR) which was worked out to be the positive root of a quadratic equation. The coefficients of the deduced quadratic relation involve the parameters obtained from the empirical fit to some of the experimental dielectric functions of MNPs available in literature. The derived working formula enables research community to tune the LSPR of nanocomposites in the whole range of visible wavelengths. The derived formula also concluded that with known lower volume fractions, shape of MNPs affects λR the most, compared to the other parameters. The derived formula was validated by calculating the full extinction spectra. It was shown for the first time that there exists an optimum value of oblate shape to give maximum resonance for a given nanocomposite.
金属纳米颗粒(MNPs)嵌入电介质薄膜在许多光电应用中是至关重要的。本报告探讨了调整这种纳米复合薄膜等离子体特性的各种方法。为此,首先将众所周知的等离子体共振条件推广到包括MNPs的形状和体积分数。随后推导出共振位置(λR)的经验公式,该公式被计算为二次方程的正根。推导出的二次关系式的系数涉及到文献中对MNPs的一些实验介电函数的经验拟合得到的参数。推导出的工作公式使研究人员能够在整个可见波长范围内调整纳米复合材料的LSPR。推导出的公式还表明,在已知体积分数较低的情况下,MNPs的形状对λR的影响最大。通过计算全消光谱,验证了推导公式的正确性。首次证明了在给定的纳米复合材料中,存在一个能产生最大共振的最佳扁圆形状值。
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引用次数: 1
Improvement of the System of Diagnostics of Metal Structures and Mechanisms of Foundry Cranes 铸造起重机金属结构与机构诊断系统的改进
Pub Date : 2021-01-01 DOI: 10.11648/j.ijmsa.20211004.12
Pеnchuk Valentin Alekseevich, Sidorov Vladimir Anatolyevich
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引用次数: 0
Design of Piezoelectric Tile for Energy Harvesting: Experimental Approach 能量收集用压电瓦的设计:实验方法
Pub Date : 2021-01-01 DOI: 10.32732/jma.2021.10.2.83
Ehsan Maani Miandoab, A. Jafari, Aref Valipour
The generation of electricity by renewable energies is an important need of today's society. Piezoelectric energy harvesting is one of these useful technologies which can generate electricity by applying external force on piezoelectric material. This study illustrates more power generation from piezoelectric tile by changing the situation of piezo discs and connect to proportional electrical circuit. Two different designs of piezoelectric tile are presented by performing experimental analyses. The experimental results showed that placing piezoelectric elements in a bending position leads to higher power generation in comparison with traditional flat positioning, which was approximately 78 times far superior. It is also revealed that by design of an electrical circuit, the tile can be advantageous for lighting in crowded sidewalks with required lighting time. The results of this paper can be beneficial in the design and fabrication of these tiles for different applications.
利用可再生能源发电是当今社会的重要需求。压电能量收集技术是利用压电材料施加外力来发电的一种有用技术。本研究通过改变压电片的位置,并连接成比例电路,使压电片产生更多的电能。通过实验分析,提出了两种不同的压电瓦设计方案。实验结果表明,将压电元件放置在弯曲位置比传统的平面位置产生更高的发电量,约为78倍。通过电路的设计,这种瓷砖可以在需要照明时间的拥挤人行道上照明。本文的研究结果可为不同用途的瓷砖的设计和制造提供参考。
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引用次数: 1
Slope Stability Analysis of the Gbeni Earth Dam (GB3) in Rutile - Sierra Leone 金红石-塞拉利昂Gbeni土坝(GB3)边坡稳定性分析
Pub Date : 2020-12-16 DOI: 10.11648/J.IJMSA.20200906.11
S. S. Turay, Osman Koroma, Abdul A. Koroma
Earth slopes stability analysis is important in the design and construction of earth dams under different loading conditions. Several factors such as difference in water level or rapid drawdown in the reservoir, right after construction, and steady - state seepage may result in instability of Earth Dams for all possible combinations. In this study, three scenarios were evaluated for the Gbeni Earth Dam (GB3) at Sierra Rutile Mining Company in Sierra Leone. It is a zoned earth-filled embankment dam with respective upstream and downstream slopes of 1:3 and 1:2, having a horizontal sand blanket downstream. The upstream slope was subjected to both rapid drawdown in the reservoir of the earth dam and end of construction condition when there is no water present in the reservoir, whilst the downstream slope was assessed for steady seepage and end of construction conditions. The shape of the critical slip surface of both slopes was evaluated using a circular failure surface. The objective of this study was to assess the stability of these slopes under the above conditions using traditional analysis according to the theory of limit states and safety factor in GEO 5 software and its subprograms. The level of water on the upstream and downstream banks, the geotechnical properties of soil materials and boundary conditions of the dam were used as contribution variables and safety factors as the desired output. The study found out that the factor of safety against sliding of the upstream slope marginally drops within the short period after the start of rapid drawdown of water in the reservoir of the dam. Also, the downstream slope was found to be more stable under steady seepage. This accounts for the uncertainties involved in the strength of material, pore pressures in impervious clay core material, and long-term loading condition.
土坡稳定性分析在不同荷载条件下的土坝设计和施工中具有重要意义。在各种可能的组合情况下,土坝的失稳都是由于水库水位的变化或施工后水库水位的迅速下降以及稳态渗流等因素造成的。在本研究中,对塞拉利昂金红石矿业公司的Gbeni土坝(GB3)进行了三种情景评估。为带状填土路堤坝,上下游坡度分别为1:3和1:2,下游为水平砂毯。对上游坡面进行了土坝库区快速落水和库区无水结束施工条件的评估,对下游坡面进行了稳定渗流和结束施工条件的评估。采用圆形破坏面计算了两个边坡的临界滑移面形状。本研究的目的是根据GEO - 5软件及其子程序中的极限状态和安全系数理论,采用传统的分析方法对上述条件下的边坡进行稳定性评价。以上游和下游堤岸水位、土质岩土特性和大坝边界条件作为贡献变量,以安全系数作为期望输出。研究发现,在大坝水库蓄水开始快速降水后的短时间内,上游边坡的抗滑安全系数略有下降。在稳定渗流条件下,下游边坡更加稳定。这考虑了材料强度、不透水粘土芯材孔隙压力和长期加载条件的不确定性。
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引用次数: 0
The Effect of Atmospheric Pollution on Building Materials in the Urban Environment 城市环境中大气污染对建筑材料的影响
Pub Date : 2020-11-15 DOI: 10.32732/jma.2020.9.2.70
A. Kuzmichev, V. Azarov, A. V. Kuzmichev
Nowadays atmospheric pollution affects not only the urban environment in general, but building materials, which leads to their corrosion, in particular. The article discusses the regularities of the adhesion process of particulate matter (dust) on the vertical surfaces of buildings and structures, which are made of various building materials. On the basis of experimental studies, regression dependences of the adhesion of urban dust on different vertical surfaces from random determining factors were obtained. Thus, by studying the regularities of pollution of urban environment objects, made of various building materials, it is possible to achieve their preservation, since they demonstrate the architectural and design features of various historical periods of the country's development.
如今,大气污染不仅影响城市环境,还影响建筑材料,特别是建筑材料的腐蚀。本文讨论了各种建筑材料构成的建筑物和构筑物的垂直表面上颗粒物(粉尘)的附着过程规律。在实验研究的基础上,得到了城市扬尘在不同垂直表面附着的随机决定因素的回归依赖关系。因此,通过研究由各种建筑材料制成的城市环境物体的污染规律,可以实现对它们的保护,因为它们展示了国家发展的各个历史时期的建筑和设计特征。
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引用次数: 1
Development of Flame-Resistant Cotton Fabrics with Casein Using Pad-dry-cure and Supercritical Fluids Methods 用垫干固化和超临界流体法制备酪蛋白阻燃棉织物
Pub Date : 2020-10-17 DOI: 10.11648/J.IJMSA.20200904.11
Sechin Chang, B. Condon, Sunghyun Nam
Traditional pad-dry-cure (PDC) and supercritical carbon dioxide (scCO2) methods were used to study the effectiveness of cotton fabrics treated with casein from bovine milk and eco-friendly inorganic materials, urea and diammonium phosphate. Trials were completed successfully. Thermogravimetric analysis (TGA), microscale combustion calorimeter (MCC), 45° angle and vertical flammability (clothing textiles test) and limiting oxygen index (LOI) tests were carried out for the treated cotton fabrics. When the treated fabrics were tested using the 45° angle flame, the ignited fabrics self-extinguished and left behind a streak of char. Treated higher add-on fabrics were neither consumed by flame, nor produced glowing embers upon self-extinguishing. All untreated cotton fabrics showed limiting oxygen index (LOI) values of about 18% oxygen in nitrogen. For formulations with casein, urea and diammonium phosphate, LOI values of treated fabrics were 29-40% oxygen in nitrogen when add-on values for the formulation were 9.5-18.7wt%. Furthermore, scanning electron microscope (SEM) was employed to characterize the chemical structure on the treated fabrics, as well as, the surface morphology of char areas of treated and untreated fabrics. The results indicate that fabrics treated with casein are flame resistant. The treated fabrics exhibited improved thermal stability, as evidenced by increased ignition times and lower heat release rates. The results of this study show that casein coated flame-resistant fabrics can be readily applied to textile fabrics using a continuous process that is ideal for commercial and industrial applications.
采用传统的垫干固化(PDC)和超临界二氧化碳(scCO2)方法,研究了牛乳酪蛋白与环保无机材料尿素和磷酸二铵处理棉织物的效果。试验顺利完成。对处理后的棉织物进行了热重分析(TGA)、微尺度燃烧量热仪(MCC)、45°角和垂直可燃性(服装纺织品测试)和极限氧指数(LOI)测试。当使用45°角火焰对处理过的织物进行测试时,点燃的织物会自行熄灭,并留下一条煤焦条纹。处理后的高附加织物既不被火焰消耗,也不产生自发熄灭的灼热余烬。所有未经处理的棉织物的极限氧指数(LOI)都在18%左右。对于含有酪蛋白、尿素和磷酸二铵的配方,当配方的添加值为9.5-18.7wt%时,处理过的织物的LOI值为29-40%氧氮。此外,利用扫描电镜(SEM)表征了处理后织物的化学结构,以及处理后和未处理织物焦区的表面形貌。结果表明,经酪蛋白处理的织物具有较好的阻燃性。经过处理的织物表现出更好的热稳定性,如增加的点火时间和更低的热释放率所证明的那样。这项研究的结果表明,酪蛋白涂层阻燃织物可以很容易地应用于纺织织物,使用一个连续的过程,是理想的商业和工业应用。
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引用次数: 4
Review on Biosynthesis, Characterization and Antibacterial Activity of Silver Nanoparticles 纳米银的生物合成、表征及抗菌活性研究进展
Pub Date : 2020-10-13 DOI: 10.11648/j.ijmsa.20200903.12
Tizeta Abera
Recently, nanotechnology has attracted great attention due to its wide applications for different fields of science. Nanoparticles are a cluster of atoms in the range of 1-100 nm that provides mechanical, optical, electrical, and structural advanced, and also an increased surface area than the original substance. Nanostructure materials have got an enhancement to the feature of life and preservation of the environment. Now a day’s silver nanoparticles have gained attention due to its uses in various areas of human interest in the industry, medicine, human health, and agriculture. It is the most popular metallic nanoparticles in antimicrobial, antioxidant, and anti-cancer properties as different researchers reported. The objective of this review is to brief recent progress in the biosynthesis of AgNPs. This review may have a great contribution in the field of green synthesis, characterization, and antibacterial activities of AgNPs. There are three types of nanoparticles synthesis approaches they are physical, chemical, and biological methods. The biological method for the synthesis of AgNPs is a preferable approach due to its simplicity, cost-effectiveness, easily scale up to the industry and non-toxicity. Plants and their parts contain carbohydrates, fats, proteins, nucleic acids, pigments, and several types of secondary metabolites which act as reducing agents to produce nanoparticles from metal salts without producing any toxic by-product. In this review, different researches reported different particle size of AgNPs (0.011 – 90 nm) and shape by using different plant material. I conclude This review is concerned with the green synthesis of AgNPs, characterization, and antibacterial activity of AgNPs.
近年来,纳米技术因其在各个科学领域的广泛应用而引起了人们的广泛关注。纳米粒子是1-100纳米范围内的一簇原子,具有机械、光学、电学和结构方面的优势,并且比原始物质的表面积更大。纳米结构材料具有增强生命特性和保护环境的作用。如今,银纳米颗粒因其在工业、医药、人体健康和农业等人类感兴趣的各个领域的应用而引起了人们的关注。据不同的研究人员报道,它是抗菌、抗氧化和抗癌特性最受欢迎的金属纳米颗粒。本文综述了近年来AgNPs生物合成的研究进展。本文对AgNPs的绿色合成、表征及抗菌活性等方面的研究进行了综述。纳米粒子的合成方法有三种:物理、化学和生物方法。生物法合成AgNPs具有简单、经济、易于规模化、无毒等优点,是一种较好的方法。植物及其部分含有碳水化合物、脂肪、蛋白质、核酸、色素和几种类型的次级代谢物,这些代谢物作为还原剂从金属盐中产生纳米粒子,而不产生任何有毒的副产品。本文综述了不同植物材料制备的AgNPs的不同粒径(0.011 ~ 90nm)和形状。本文就AgNPs的绿色合成、表征及抗菌活性等方面进行了综述。
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引用次数: 5
A Review Paper on: Effect of Different Types of Filler Materials on Marshall Characteristics of Bitumen Hot Mix 不同填料对沥青热混合料马歇尔特性影响的研究综述
Pub Date : 2020-09-25 DOI: 10.11648/J.IJMSA.20200903.11
Gazi Mohammad Harun-Or-Rashid, Mohammad Mohayminul Islam
Bituminous hot mix is one of the most widely used and costly flexible pavement layer. It involves a huge outlay of investment. Precise engineering and usage of proper materials can make it more cost efficient, durable, convenient for users and most importantly ecofriendly. To reduce the cost of construction engineers all over the globe are investigating for the alternative material to obtain same amount of output (strength, stability and durability) by paying a little. There are four constituents of a hot mix, coarse aggregate, fine aggregate, binder and filler. Filler in the bitumen hot mix fill the void in between the aggregates which is very important for strength and stability of the pavement. But the fillers are conventionally used (cement and lime) are very costly which affect the total cost of construction. That’s why the researchers emphasized on the waste material to serve this purpose as well as to keep the environment clean. A large range of waste material like fly ash, bagasse ash, marble dust, stone dust, brick dust, kiln dust, waste concrete dust, foundry sand, bio gypsum, ceramic dust etc. has been use as a filler for numerous research works by the researchers globally. The materials yielded very satisfactory results. Fly ash, bagasse results in nearly same Marshall properties (stability, OBC, %VFA, %VMA, %Va) like the conventional one. Although the brick dust and stone dust provide a high amount of air voids but they also result high stability. More or less all these non-conventional materials are capable to fully or partially replace the conventional filler. This study focused on the effect on the Marshall hot mix design properties after using these fillers mentioned above.
沥青热混合料是应用最广泛、造价最高的柔性路面层之一。这涉及一笔巨额投资。精确的工程设计和使用合适的材料可以使其更具成本效益,耐用,方便用户,最重要的是环保。为了降低成本,世界各地的建筑工程师都在研究替代材料,以获得同样数量的输出(强度,稳定性和耐久性)花费很少。热混合料有四种成分:粗骨料、细骨料、粘结剂和填料。沥青热混合料中的填料填补了集料之间的空隙,这对路面的强度和稳定性至关重要。但常规使用的填料(水泥和石灰)价格昂贵,影响了施工的总成本。这就是为什么研究人员强调废物既能达到这一目的,又能保持环境清洁。粉煤灰、甘蔗渣、大理石粉尘、石材粉尘、砖尘、窑炉粉尘、废混凝土粉尘、铸造砂、生物石膏、陶瓷粉尘等多种废弃物已被全球研究人员用作填料。这些材料产生了非常令人满意的结果。粉煤灰、甘蔗渣产生的马歇尔特性(稳定性、OBC、%VFA、%VMA、%Va)几乎与传统的相同。虽然砖粉和石粉提供了大量的空气空隙,但它们也导致了高稳定性。或多或少,所有这些非常规材料都能够完全或部分取代传统填料。本文主要研究了上述填料对马歇尔热混料设计性能的影响。
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引用次数: 4
期刊
International Journal of Materials Science and Applications
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