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Influence of Deposition Parameters of ITO Films on the Performance of HJT Solar Cells ITO薄膜沉积参数对HJT太阳能电池性能的影响
4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-09-15 DOI: 10.1155/2023/1065503
Guoping Huang, Guixiang Zhao, Xixi Huang, Hao Zhuang, Zhongjian Zhang, Ronggang Gao, Fengxian Xie
TCO (transparent conductive oxide) films are widely used in solar cells due to the characteristics of transparency and conductivity. In this paper, ITO (indium tin oxide) transparent conductive films are prepared on common slides by DC magnetron sputtering, and the preparation process and characteristics of ITO films are studied. The target for sputtering is ITO, with the mass ratio of In203 and Sn02 was 90% : 10%. The sheet resistance, carrier concentration, and carrier mobility of ITO films are measured and analyzed by a UV-Vis spectrophotometer, four-point probe, and Hall effect measurement system. By changing the oxygen content, deposition temperature, and sputtering power to studied the effects on the light transmittance and electrical conductivity of the ITO films, further studied the effects on the HJT (heterojunction with intrinsic thin film) solar cells, and finally determined the appropriate preparation parameters. Results show that the resistance is 6 . 4 10 4 Ω cm , the light transmittance is beyond 90.6%, efficiency is 23.78%, and bifacial ratio is 84% when oxygen content is 2.2%, sputtering power is 3 kw, and deposition temperature is 190°C.
透明导电氧化物(TCO)薄膜由于具有透明和导电性的特点,在太阳能电池中得到了广泛的应用。本文采用直流磁控溅射技术在普通载玻片上制备了ITO(氧化铟锡)透明导电薄膜,并对ITO薄膜的制备工艺和特性进行了研究。溅射靶材为ITO,其中In203和Sn02的质量比为90%:10%。利用紫外-可见分光光度计、四点探针和霍尔效应测量系统对ITO薄膜的片电阻、载流子浓度和载流子迁移率进行了测量和分析。通过改变氧含量、沉积温度和溅射功率来研究对ITO薄膜透光率和电导率的影响,进一步研究对HJT(异质结与本质薄膜)太阳能电池的影响,最终确定合适的制备参数。结果表明,电阻为6。4∗10−4 Ω•cm,当氧含量为2.2%,溅射功率为3 kw,沉积温度为190℃时,透射率超过90.6%,效率为23.78%,双面比为84%。
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引用次数: 0
Numerical Study of High Spectral Efficiency and High-Temperature Energy Harvesting Metamaterial Emitter to Improve Thermophotovoltaic Performance 提高热光伏性能的高光谱效率和高温能量收集超材料发射器的数值研究
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-09-07 DOI: 10.1155/2023/5442031
Sifan Tamiru, Fekadu Tolessa, Birke Alemu, Solomon Tiruneh, A. Belay, Gurmu Alemu, T. Gurumurthi
Design work was done on a broadband and wide-angle selective pyramid metamaterial emitter. COMSOL Multiphysics software was used to study the emitter, which was made of tungsten and aluminum nitride. The width of the unit cell and the tungsten ground thickness were fixed while other geometric parameters, such as the base length of the pyramid, the height of the pyramid, and the thickness of the dielectric, were tuned to produce the emitter’s desired broadband emission. A high average emissivity over 0.96 below the cutoff wavelength (0.1 μm-2.2 μm) was seen in the numerical simulation. The developed metamaterial emitter also had good emissivity across a broad range of incidence angles, from 0° to 60°, and was polarization independent. In addition, the planned emitter for the InGaAs cell has a better spectral efficiency than the blackbody other designed emitter. In general, the planned selective nanopyramid emitter was realized with 75% spectrum efficiency for InGaAs band gap energy (0.55 eV) at 1200 K, which was greater than blackbody and prior papers.
设计工作是在宽带和广角选择性金字塔超材料发射器。COMSOL Multiphysics软件用于研究由钨和氮化铝制成的发射极。晶胞的宽度和钨接地厚度是固定的,而其他几何参数,如金字塔的基极长度、金字塔的高度和电介质的厚度,则被调谐以产生发射器所需的宽带发射。截止波长以下0.96以上的高平均发射率(0.1 μm-2.2 μm)。所开发的超材料发射器在0°至60°的宽入射角范围内也具有良好的发射率,并且与偏振无关。此外,InGaAs电池的计划发射极比其他设计的黑体发射极具有更好的光谱效率。一般来说,计划中的选择性纳米金字塔发射极以75%的InGaAs带隙能量(0.55 eV) K、 其大于黑体和先前的论文。
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引用次数: 0
Dynamic Performance Improvement Using Model Reference Adaptive Control of Photovoltaic Systems under Fast-Changing Atmospheric Conditions 快速变化大气条件下光伏系统模型参考自适应控制的动态性能改进
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-08-29 DOI: 10.1155/2023/5703727
Yves Abessolo Mindzie, J. Kenfack, Voufo Joseph, Urbain Nzotcha, Dieudonné Marcel Djanssou, Raphael Mbounguen
The effectiveness of a photovoltaic (PV) system can be increased by using maximum power point tracking (MPPT). The literature has suggested a number of methods for tracking the maximum power point (MPP). However, this number of methods most often presents a high convergence speed in reaching the MPP, complexity under their implementation, power fluctuations, overshoots, and great difficulty in reaching the MPP under fast-changing atmospheric conditions, thus influencing the efficiency of PV systems. Intending to improve the performance of PV systems under rapid changes in the atmosphere, this paper proposes model reference adaptive control (MRAC) as a technique for tracking the MPP based on the employ of reference models such as optimal voltage and current at the MPP ( V MPP and I MPP ). The MATLAB/Simulink environment is used to produce the simulation results; the Kyocera Solar KC 130 GT module is used here as a photovoltaic power plant, connected to a boost converter, supplying a resistive load. The Lyapunov theory was used to demonstrate the stability of the system. The simulation outcomes obtained using the suggested method are compared with those obtained by techniques such as perturb and observe (P&O), incremental conductance (INC), variable step incremental conductance (VSINC), particle swarm optimization (PSO), and grey wolf optimization (GWO), thus showing a very large improvement under standard test and fast-changing atmospheric conditions of the technique proposed on the other techniques in terms of convergence speed and tracking efficiency. The simulation results prove that the suggested method has great tracking effectiveness (>99.88%), less time for convergence (<0.01 s), and simple implementation complexity under fast-changing atmospheric conditions without both transient and steady-state power oscillations, overshoots, and chattering effects, thus causing a great minimization of energy losses, and the proposed technique reaches exactly the MPP under fast-changing atmospheric conditions.
光伏(PV)系统的有效性可以通过使用最大功率点跟踪(MPPT)来提高。文献提出了许多跟踪最大功率点(MPP)的方法。然而,在快速变化的大气条件下,这一数量的方法通常在达到MPP时表现出高收敛速度、实现的复杂性、功率波动、超调以及达到MPP的巨大困难,从而影响光伏系统的效率。为了提高光伏系统在大气快速变化下的性能,本文提出了模型参考自适应控制(MRAC),作为一种基于参考模型(如MPP处的最佳电压和电流)跟踪MPP的技术(V MPP和I MPP)。使用MATLAB/Simulink环境生成仿真结果;Kyocera Solar KC 130 GT模块在这里用作光伏发电厂,连接到升压转换器,为电阻负载供电。利用李雅普诺夫理论证明了系统的稳定性。将使用所提出的方法获得的模拟结果与通过扰动和观测(P&O)、增量电导(INC)、变步长增量电导(VSINC),粒子群优化(PSO)和灰狼优化(GWO)等技术获得的结果进行了比较,从而显示出在标准测试和快速变化的大气条件下,所提出的技术在收敛速度和跟踪效率方面比其他技术有很大的改进。仿真结果表明,该方法具有良好的跟踪效果(>99.88%),收敛时间短(<0.01 s) ,以及在快速变化的大气条件下的简单实现复杂性,而没有瞬态和稳态功率振荡、过冲和抖振效应,从而使能量损失大大最小化,并且所提出的技术在快速变化大气条件下精确地达到了MPP。
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引用次数: 0
Preparation of TiO2 Grafted on Graphene and Study on their Photocatalytic Properties 石墨烯接枝TiO2的制备及其光催化性能研究
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-08-22 DOI: 10.1155/2023/8676430
Longli Lin, Lihua Shi, Simei Liu, Jieyi He
TiO2 has potential application prospects in the fields of environmental pollution control and energy conversion, while its characteristics including proneness to agglomeration and low activity affect practical applications. In view of this, P25 TiO2 and graphene were taken as raw materials to prepare the modified TiO2 catalyst. The modification mechanism of TiO2 was explained by characterizing the phase composition, microscopic morphology, and functional groups and analyzing the specific surface area and particle size. Then, the photocatalytic performance of the material was explored by taking methyl orange as the target to be degraded. Results show that TiO2 is well grafted to the laminated structure of graphene using physicochemical interactions among the introduced functional groups after modifying P25 TiO2 and graphene. This way, the 10.00 mg·L-1 methyl orange solution is almost completely degraded within 12 min at a reaction rate that is 1.81 times higher than that of P25 TiO2. Even after being used for 10 times, the performance still remains stable. The modification process is simple, and the method is reliable. Results can promote the practical application of TiO2 photocatalytic technology.
TiO2在环境污染控制和能源转换领域具有潜在的应用前景,但其易团聚、活性低等特点影响了实际应用。有鉴于此,以P25 TiO2和石墨烯为原料制备了改性TiO2催化剂。通过表征TiO2的相组成、微观形貌和官能团,并分析其比表面积和粒径,解释了TiO2的改性机理。然后,以甲基橙为降解目标,考察了该材料的光催化性能。结果表明,在对P25 TiO2和石墨烯进行改性后,TiO2利用引入的官能团之间的物理化学相互作用很好地接枝到石墨烯的层状结构上。这样,10.00 mg·L-1甲基橙溶液在12 min,反应速率是P25 TiO2的1.81倍。即使使用了10次,性能仍然保持稳定。改性过程简单,方法可靠。研究结果可促进TiO2光催化技术的实际应用。
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引用次数: 0
Retracted: Application of Machine Learning in Multi-Directional Model to Follow Solar Energy Using Photo Sensor Matrix 撤下:机器学习在利用光电传感器矩阵跟踪太阳能的多向模型中的应用
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-08-16 DOI: 10.1155/2023/9763709
International Journal of Photoenergy
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引用次数: 0
Energy-Environmental One-Year Dynamic Simulation and Ranking Analysis of Using Flat Plate Solar Water Heater to Supply the Heating Demand of an Apartment in the USA: A Comprehensive Review 利用平板太阳能热水器满足美国某公寓供暖需求的能源-环境一年期动态模拟与排名分析:综述
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-08-09 DOI: 10.1155/2023/3323276
Daryosh Mohamadi Janaki, Ehsan Kiani Harchegani, T. Rezaei, Mohammadreza Bakhtdehkordi
Nowadays, owing to the increasing demand for water heating, solar water heaters (SWHs) are an appropriate alternative to heating based on fossil or electric fuels. Solar heating has received a lot of attention due to its reduction of environmental pollution and ensuring future energy security. Moreover, it is cost-effective in the long run. Given the importance of the above, there is a lack of a comprehensive review of the potential for heat supply at the residential scale in different US states. In addition, finding the most suitable place to use SWHs has not been studied so far. Therefore, in the present work, for the first time, the energy-environmental assessment of 50 US state centers during a one-year period has been done using TSOL commercial software. Furthermore, using step-wise weight assessment ratio analysis (SWARA) and weighted aggregated sum product assessment (WASPAS) computational methods, the weighting of criteria and ranking of studied stations were performed, respectively. The results indicated that of the eight parameters studied, the parameters “total solar fraction” and “solar contribution to domestic hot water” have the highest and lowest final normalized weight, respectively. Moreover, the WASPAS method using the decision matrix showed that Phoenix, Santa Fe, and Tallahassee stations are the top 3 stations in terms of using SWHs, respectively, and Juneau, Olympia, and Montpelier stations are three inappropriate stations in this regard, respectively. The VIekriterijumsko KOmpromisno Rangiranje (VIKOR), intelligent transportation system deployment analysis system (IDAS), and technique for order of preference by similarity to ideal solution (TOPSIS) methods also validated the results of the present work, which were completely consistent. The results of the economic analysis revealed that the Santa Fe station with the price of each kW of energy produced at $0.021 has the cheapest solar heat generation.
如今,由于对水加热的需求不断增加,太阳能热水器(SWHs)是一种合适的替代基于化石燃料或电力燃料的加热。太阳能采暖因其减少环境污染和确保未来能源安全而受到广泛关注。此外,从长远来看,它具有成本效益。鉴于上述重要性,缺乏对美国不同州住宅规模供热潜力的全面审查。此外,如何找到最合适的地方使用污水处理厂至今尚未研究。因此,在本工作中,首次使用TSOL商业软件对美国50个州中心进行了为期一年的能源环境评价。采用逐步加权评价比率分析(SWARA)和加权总和积评价(WASPAS)计算方法,分别对研究站点的标准进行加权和排序。结果表明,在研究的8个参数中,“总太阳能分数”和“太阳能对生活热水的贡献”参数的最终归一化权重分别最高和最低。使用决策矩阵的WASPAS方法表明,Phoenix、Santa Fe和Tallahassee站分别是使用SWHs最好的3个站,而Juneau、Olympia和Montpelier站分别是使用SWHs最不合适的3个站。VIekriterijumsko KOmpromisno Rangiranje (VIKOR)、智能交通系统部署分析系统(IDAS)和TOPSIS (TOPSIS)方法也验证了本工作的结果,两者完全一致。经济分析结果显示,每千瓦发电价格为0.021美元的圣达菲电站是太阳能发电最便宜的电站。
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引用次数: 2
A Review of the Technological Advances in the Design of Highly Efficient Perovskite Solar Cells 高效钙钛矿太阳能电池设计技术进展综述
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-08-07 DOI: 10.1155/2023/3801813
George G. Njema, J. Kibet
The search for renewable and sustainable energy for energy security and better environmental protection against hazardous emissions from petro-based fuels has gained significant momentum in the last decade. Towards this end, energy from the sun has proven to be reliable and inexhaustible. Therefore, better light harvesting technologies have to be sought. Herein, the current trends in the development of perovskite solar cells with a focus on device engineering, band alignment, device fabrication with superior light harvesting properties, and numerical simulation of solar cell architectures are critically reviewed. This work will form the basis for future scientist to have a better scientific background on the design of highly efficient solar cell devices, which are cost-effective to fabricate, highly stable, and eco-friendly. This review presents thorough essential information on perovskite solar cell technology and tracks methodically their technological performance overtime. The photovoltaic (PV) technology can help to reduce pollution related to greenhouse gas emissions, criterion pollutant emissions, and emissions from heavy metals and radioactive species by nearly 90%. Following the introduction of highly efficient perovskite solar cell (PSC) technologies, the problems associated with stability, short life-time and lead-based perovskite solar cell configurations have significantly been minimized. The fabrication and simulation of perovskite solar cells has been made possible with advanced technologies and state-of-the-art computational codes. Furthermore, device simulation strategies have lately been used to understand, select appropriate materials, and gain insights into solar cell devices’ physical behavior in order to improve their performances. Numerical simulation softwares such as the 1-dimenional solar cell capacitance simulator (SCAPS-1D), Silvaco ATLAS, and wx-analysis of microelectronic and photonic structures (wxAMPS) used to understand the device engineering of solar cells are critically discussed. Because of the need to produce charge collection selectivity, hole transport materials (HTMs) as well as electron transport materials (ETMs) constitute essential PSC components. In this work, the synthesis of inorganic HTMs, as well as their characteristics and uses in various PSCs comprising mesoporous and planar designs, are explored in detail. It is anticipated that the performance of inorganic HTLs on PSCs would encourage further research which will have a significant influence on the future designs and fabrication of highly efficient solar cells.
在过去十年中,寻求可再生和可持续能源以实现能源安全和更好的环境保护,防止石油燃料的有害排放,这一努力势头强劲。为此,来自太阳的能量已被证明是可靠和取之不尽的。因此,必须寻求更好的光采集技术。本文重点评述了钙钛矿太阳能电池的发展趋势,重点是器件工程、能带对准、具有优异光捕获性能的器件制造以及太阳能电池结构的数值模拟。这项工作将为未来的科学家在设计高效太阳能电池设备方面提供更好的科学背景奠定基础,这些设备制造成本效益高、高度稳定且环保。这篇综述提供了关于钙钛矿太阳能电池技术的全面基本信息,并有条不紊地跟踪了它们的技术性能。光伏技术可以帮助将与温室气体排放、标准污染物排放以及重金属和放射性物质排放相关的污染减少近90%。随着高效钙钛矿太阳能电池(PSC)技术的引入,与稳定性、短寿命和铅基钙钛矿太阳能电池配置相关的问题已显著最小化。利用先进的技术和最先进的计算代码,钙钛矿太阳能电池的制造和模拟成为可能。此外,器件模拟策略最近被用于理解、选择合适的材料,并深入了解太阳能电池器件的物理行为,以提高其性能。重点讨论了用于理解太阳能电池器件工程的一维太阳能电池电容模拟器(SCAPS-1D)、Silvaco ATLAS和微电子和光子结构wx分析(wxAMPS)等数值模拟软件。由于需要产生电荷收集选择性,空穴传输材料(HTM)和电子传输材料(ETM)构成了PSC的重要组成部分。在这项工作中,详细探索了无机HTM的合成,以及它们的特性和在包括介孔和平面设计的各种PSC中的用途。预计无机HTL在PSCs上的性能将鼓励进一步的研究,这将对未来高效太阳能电池的设计和制造产生重大影响。
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引用次数: 0
Enhancing Photovoltaic Module Fault Diagnosis with Unmanned Aerial Vehicles and Deep Learning-Based Image Analysis 无人机增强光伏组件故障诊断及深度学习图像分析
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-07-29 DOI: 10.1155/2023/8665729
J. Jerome Vasanth, S. Naveen Venkatesh, V. Sugumaran, V. Mahamuni
Artificial intelligence (AI) has evolved into a powerful tool that has wide-spread application in computer vision such as computer-aided inspection, industrial control systems, and navigation of robots. Monitoring the condition of machineries and mechanical components for the presence of faults with the aid of image-based automated analysis is one major application of computer vision. Diagnosing machinery faults from images can be made feasible with the adoption of deep learning and machine learning techniques. The primary objective of this study is to detect malfunctions in photovoltaic (PV) modules by utilizing a combination of deep learning and machine learning methodologies, with the assistance of RGB images captured via unmanned aerial vehicles. Six test conditions of PV modules such as good panel, snail trail, delamination, glass breakage, discoloration, and burn marks were considered in the study. The overall experimentation was carried out in two phases: (i) deep learning phase and (ii) machine learning phase. In the initial deep learning phase, the final fully connected layer of six pretrained networks, namely, DenseNet-201, VGG19, ResNet-50, GoogLeNet, VGG16, and AlexNet, was utilized to extract PVM image features. During the machine learning phase, feature selection from the extracted features was carried out using the J48 decision tree algorithm. Post selection of features, three families of classifiers such as tree, Bayes, and lazy were applied to determine the best feature extractor-classifier pair. The combination of DenseNet-201 features with k-nearest neighbour (IBK) classifier produced the overall classification accuracy of 100.00% among all other pretrained network features and classifiers considered.
人工智能(AI)已经发展成为一种强大的工具,在计算机辅助检测、工业控制系统、机器人导航等计算机视觉领域有着广泛的应用。借助基于图像的自动分析来监测机械和机械部件的故障状态是计算机视觉的一个主要应用。采用深度学习和机器学习技术,从图像中诊断机械故障是可行的。本研究的主要目标是利用深度学习和机器学习方法的结合,在无人机捕获的RGB图像的帮助下,检测光伏(PV)模块的故障。研究中考虑了光伏组件的6个测试条件:面板良好、螺迹、分层、玻璃破碎、变色、烧痕。整个实验分两个阶段进行:(i)深度学习阶段和(ii)机器学习阶段。在初始深度学习阶段,利用DenseNet-201、VGG19、ResNet-50、GoogLeNet、VGG16和AlexNet这6个预训练网络的最终全连接层提取PVM图像特征。在机器学习阶段,使用J48决策树算法从提取的特征中进行特征选择。在特征选择后,应用tree、Bayes和lazy三大类分类器来确定最佳特征提取-分类器对。DenseNet-201特征与k-最近邻(IBK)分类器相结合,在所有其他预训练网络特征和分类器中,总体分类准确率为100.00%。
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引用次数: 0
An Improved Tuning of PID Controller for PV Battery-Powered Brushless DC Motor Speed Regulation Using Hybrid Horse Herd Particle Swarm Optimization 基于混合群粒子群优化的光伏电池驱动无刷直流电机调速PID控制器的改进整定
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-07-18 DOI: 10.1155/2023/2777505
A. RamaKrishnan, A. Shunmugalatha, K. Premkumar
In this study, speed control of PV battery-powered brushless DC motor (BLDC) is controlled by novel hybrid horse herd particle swarm optimization- (HHHPSO-) tuned proportional integral derivative (PID) controller. The optimal gain parameter of the PID controller is tuned by hybrid horse herd optimization algorithm. The purpose of the newly developed HHHPSO algorithm is to enhance the performance of the classic horse herd algorithm (HHA), specifically in two different ways. In the first place, it bolsters HHA’s aptitude for exploratory learning related to the ageing issue. By doing so, it is possible to circumvent the phenomenon of the local minimum stagnation. Second, it permits HHA to have a superior capability of exploitation with the assistance of hybridization through the utilisation of particle swarm optimization. This hybrid technique helps improve the rate convergences of the HHA method. The time domain-based performance indices were considered as an objective function such as addition of integral of squared speed error, integral of squared current error, and integral of squared electromagnetic torque error for finding the optimal gain values for the PID controller using HHHPSO. The proposed HHHPSO-tuned PID controller for PV battery-powered BLDC motor is tested for various working conditions such as constant speed conditions, varying speed conditions, and varying load conditions and also compared with state-of-the-art method. The proposed method has quick rise time around 20-21 msec, quick settling time around 35-39 msec, zero steady-state error, and zero overshoot than state-of-the-art optimization method. The proposed control techniques were also tested in hardware to confirm the suitability for real-time applications.
本研究采用一种新型混合马群粒子群优化(HHHPSO)调谐比例积分导数(PID)控制器对光伏电池供电的无刷直流电动机(BLDC)进行调速控制。采用混合马群优化算法对PID控制器的最优增益参数进行整定。新开发的HHHPSO算法的目的是提高经典的马群算法(HHA)的性能,具体从两个方面进行改进。首先,它支持HHA在与老龄化问题相关的探索性学习方面的能力。这样做,就有可能避免局部最小停滞现象。其次,利用粒子群优化,使HHA在杂交的辅助下具有优越的开发能力。这种混合技术有助于提高HHA方法的速度收敛性。将速度误差平方积分、电流误差平方积分、电磁转矩误差平方积分等时域性能指标相加作为目标函数,利用HHHPSO求出PID控制器的最优增益值。对所提出的基于hhhpso调谐的无刷直流电机PID控制器进行了恒速、变速、变负载等工况测试,并与现有方法进行了比较。与现有优化方法相比,该方法的上升时间约为20-21 msec,沉降时间约为35-39 msec,稳态误差为零,超调量为零。提出的控制技术也在硬件上进行了测试,以确认实时应用的适用性。
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引用次数: 0
Monocrystalline Silicon PERC Solar Cell with Rear-Side AlOx Film Formed by Furnace Oxidation 炉氧化形成背面AlOx膜的单晶硅PERC太阳能电池
IF 3.2 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Pub Date : 2023-07-17 DOI: 10.1155/2023/3312619
Ching-Hui Hsu, Daosong Lao, Likarn Wang
In this study, AlOx passivation layers on the rear sides of silicon PERC solar cells are formed by thermally oxidizing 3 nm-thick aluminum films deposited in advance by an e-gun evaporator. The oxidation process is conducted in a furnace full of oxygen at 400°C for a duration of 10 minutes, followed by annealing for a duration of 3 minutes at 700°C, and then the stacking of SiNx films on the back surfaces. After that, a second annealing process is done at 400°C for a duration of 10 minutes to repair the defects resulting from the bombardment of ions on the passivation layer. With the thermal oxidation method applied, we confirmed the existence of an AlOx passivation layer with a negative charge density of − 3.21 × 10 12  cm-2 for an annealed sample, in contrast to − 6.17 × 10 11  cm-2 for an unannealed sample.
在本研究中,硅PERC太阳能电池背面的AlOx钝化层是通过热氧化3 nm厚的铝膜。氧化过程在充满氧气的熔炉中在400°C下进行10分钟,然后在700°C下退火3分钟,然后将SiNx膜堆叠在背面。之后,在400°C下进行第二次退火工艺,持续10分钟,以修复离子轰击钝化层产生的缺陷。采用热氧化法,我们证实了AlOx钝化层的存在,其负电荷密度为−3.21×10 12 退火样品的cm-2,与−6.17×10 11形成对比 未退火样品的cm-2。
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International Journal of Photoenergy
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