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Synthesis and properties of ferromagnetic nanostructures and their possible use in medicine and microwave engineering 铁磁纳米结构的合成、性质及其在医学和微波工程中的应用
A. Belous
Three types of ferromagnetic nanostructures based on barium hexaferrite (BaFe12O19), lanthanum-strontium manganites with perovskite structure (La1-xSrxMnO3) and materials with spinel structure (AFe2O4, A = Ni, Zn, Co, Mn, Fe) have been synthesized by precipitation from aqueous and nonaqueous solutions, by the sol-gel method and from microemulsions. Magnetic properties of the synthesized nanoparticles and films have been investigated. It was shown that the obtained nanoparticles exhibit superparamagnetic properties. It has been found that the synthesized nanoparticles have promise in hyperthermia of cancer cells. It has been shown that the films based on barium hexaferrite can have promise in the creation of nonlinear resonant microwave elements on the basis of high-Q dielectric resonators and ferromagnetic film.
以六铁酸钡(BaFe12O19)、钙钛矿结构镧锶锰矿(La1-xSrxMnO3)和尖晶石结构材料(AFe2O4, A = Ni, Zn, Co, Mn, Fe)为基材,采用溶胶-凝胶法和微乳法制备了三种类型的铁磁纳米结构。研究了合成的纳米颗粒和薄膜的磁性能。结果表明,制备的纳米颗粒具有超顺磁性。研究发现,合成的纳米颗粒在肿瘤细胞热疗方面具有广阔的应用前景。在高q介电谐振器和铁磁薄膜的基础上,六铁氧体钡薄膜在制造非线性谐振微波元件方面具有广阔的应用前景。
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引用次数: 3
Upconversion in Gd2O3: Er, Yb nanophosphors obtained by hydrothermal and reverse microemulsion methods 水热法和反相微乳法制备的Gd2O3: Er, Yb纳米荧光粉的上转化
A. Szysiak, Y. Zhydachevskii, A. Suchocki
Erbium and ytterbium co-doped Gd2O3 nanocrystals were prepared by hydrothermal and reverse microemulsion methods. The upconversion luminescence spectra of Er3+ ions were measured at room temperature. An effect of synthesis conditions on the luminescence efficiency is discussed.
采用水热法和反相微乳法制备了铒镱共掺杂Gd2O3纳米晶。在室温下测量了Er3+离子的上转换发光光谱。讨论了合成条件对发光效率的影响。
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引用次数: 0
Luminescent and scintillation properties of CaWO4 and CaWO4:Bi single crystalline films CaWO4和CaWO4:Bi单晶薄膜的发光和闪烁特性
Y. Zorenko, V. Gorbenko, T. Zorenko, V. Savchyn, A. Voloshinovskii
The work presents the results of studying the growth processes and luminescent properties of the single crystalline films of CaWO4 and CaWO4:Bi tungstates, grown by the Liquid Phase Epitaxy (LPE) method.
本文介绍了用液相外延法(LPE)生长CaWO4和CaWO4:Bi钨酸盐单晶薄膜的生长过程和发光性能的研究结果。
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引用次数: 1
Crystal structure and luminescence of layered perovskites Sr3LnBIIISnO8 (BIII = Sc, In) 层状钙钛矿Sr3LnBIIISnO8 (BIII = Sc, In)的晶体结构与发光性能
Y. Titov, S. Nedilko, V. Chornii, V. Scherbatskii, N. Belyavina, V. Markiv, V. Polubinskii
The Sr3LnInSnO8 (Ln = La, Pr, Nd) and Sr3LaScSnO8 perovskites were synthesized and their structures have been determined by X-ray powder diffraction. The peculiarities of the structures and correlations composition - structure - luminescent properties have been discussed.
合成了sr3linsno8 (Ln = La, Pr, Nd)和Sr3LaScSnO8钙钛矿,并通过x射线粉末衍射对其结构进行了表征。讨论了其结构的特殊性和组成-结构-发光性质的相关性。
{"title":"Crystal structure and luminescence of layered perovskites Sr3LnBIIISnO8 (BIII = Sc, In)","authors":"Y. Titov, S. Nedilko, V. Chornii, V. Scherbatskii, N. Belyavina, V. Markiv, V. Polubinskii","doi":"10.1109/OMEE.2014.6912340","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912340","url":null,"abstract":"The Sr<sub>3</sub>LnInSnO<sub>8</sub> (Ln = La, Pr, Nd) and Sr<sub>3</sub>LaScSnO<sub>8</sub> perovskites were synthesized and their structures have been determined by X-ray powder diffraction. The peculiarities of the structures and correlations composition - structure - luminescent properties have been discussed.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"71 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126403114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of light collection from oxide CaWO4 scintillators 氧化CaWO4闪烁体集光性能优化
V. Mokina, F. Danevich, V. Kobychev, R. V. Kobychev, H. Kraus, V. Mykhaylyk, I. Solskii
The purpose of this work is to study the possibility to improve light collection in conditions similar to than in cryogenic scintillating bolometers. Energy resolution and relative pulse amplitude of scintillation detectors were measured using CaWO4 crystals with different shapes (cylindrical, hexagonal and cube prism), reflector materials and shapes, optical contact and surface conditions (polished and diffused). Light collection was simulated using ZEMAX codes.
这项工作的目的是研究在类似于低温闪烁测热计的条件下改善光收集的可能性。采用不同形状的CaWO4晶体(圆柱形、六角形和立方棱镜)、反射镜材料和形状、光学接触和表面条件(抛光和扩散)测量了闪烁探测器的能量分辨率和相对脉冲幅度。利用ZEMAX代码模拟光采集。
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引用次数: 0
O-Ps-related modes for study of free-volume entities in nanostructured MgAl2O4 ceramics 纳米结构MgAl2O4陶瓷中自由体积实体的o - ps相关模式研究
A. Ingram, H. Klym, O. Shpotyuk, I. Hadzaman
The o-Ps-related modes are used for study of free-volume entities in nanostructured spinel MgAl2O4 ceramics after drying and water-immersion treatment. It is established that that water-sorption processes in magnesium aluminate ceramics leads to corresponding increase in positron trapping rates of extended defects located as addition phases near grain boundaries. These phase extractions and free-volume entities in ceramic structure serve as specific trapping centers for positrons penetrating ceramics. It is demonstrated that Tao-Eldrup model can be adequately used for the calculation free volume (or nanopores size) in MgAl2O4 ceramics using o-Ps lifetimes of the third and the fourth components.
利用o- ps相关模式研究了干燥和水浸处理后纳米尖晶石MgAl2O4陶瓷中的自由体积实体。结果表明,铝酸镁陶瓷的吸水过程导致晶界附近添加相扩展缺陷的正电子俘获率相应增加。这些相萃取和陶瓷结构中的自由体积实体是正电子穿透陶瓷的特定俘获中心。结果表明,Tao-Eldrup模型可以用第三和第四组分的o-Ps寿命来计算MgAl2O4陶瓷的自由体积(或纳米孔尺寸)。
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引用次数: 0
Modifying the properties of crystals in the transition from pure to mixed perovskites 纯钙钛矿向混合钙钛矿过渡过程中晶体性质的改变
M. Biatov, I. Gerasymov, O. Sidletskiy, A. Gektin
Paper describes production of mixed scintillation crystals of perovskite family Y(Al,Ga)O3 and study of their optical and scintillation properties.
本文叙述了Y(Al,Ga)O3钙钛矿族混合闪烁晶体的制备及其光学和闪烁性能的研究。
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引用次数: 0
TL and OSL properties of LiMgPO4:Tb,B LiMgPO4:Tb,B的TL和OSL性质
D. Wróbel, P. Bilski, B. Marczewska, M. Kłosowski
LiMgPO4 (LMP) phosphor is a new highly sensitive material for TL and OSL dosimetry. The objective of the work was to investigate the dosimetric properties of this material. LMP phosphor doped with Tb and B was irradiated with beta rays and alpha particles. Thermoluminescence (TL) and optically stimulated luminescence (OSL) measurements were performed for LMP powders in comparison with Al2O3:C detector (Landauer). The phosphate which was made in our laboratory exhibits a main TL peak at 150°C. The synthesized LiMgPO4:Tb,B is a highly sensitive OSL material for dosimetric applications.
LiMgPO4 (LMP)荧光粉是一种新型的高灵敏度的TL和OSL剂量测定材料。这项工作的目的是研究这种材料的剂量学性质。用β射线和α粒子辐照掺杂Tb和B的LMP荧光粉。用Al2O3:C探测器(Landauer)对LMP粉末进行了热释光(TL)和光激发发光(OSL)测量。在我们实验室制备的磷酸盐在150°C时呈现主TL峰。合成的LiMgPO4:Tb,B是一种高灵敏度的OSL材料,可用于剂量学应用。
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引用次数: 2
Structure and dielectric properties of Na and Ta doped CaCu3Ti4O12 Na和Ta掺杂cuu3ti4o12的结构和介电性能
O. Shtonda, S. Loboda, A. Bogomolov
New ceramic compositions based on Na and Ta doped CaCu3Ti4O12 (CCTO) solid solutions were obtained. The synthesis conditions, parameters of crystal structure and low frequency dielectric properties depending on Na and Ta concentrations were investigated. The solid solutions were obtained by substitution of Ca and Ti in the CCTO structure with Na and Ta, respectively, according to the formula Ca1-xNaxCu3Ti4-xTaxO12. The substitution scheme occurs in a whole range of x from 0 to 1. The sintering temperature of Na and Ta doped CCTO ceramics with 90-95% of theoretical density is lower than of undoped CCTO. 1 kHz dielectric permittivity of Ca1-xNaxCu3Ti4-xTaxO12 ceramics depends on x and varies from 2600 to 9700. Dielectric losses tangent is around 0.1.
制备了基于Na和Ta掺杂CCTO固溶体的新型陶瓷成分。研究了Na和Ta浓度对合成条件、晶体结构参数和低频介电性能的影响。用Na和Ta分别取代CCTO结构中的Ca和Ti得到固溶体,公式为Ca1-xNaxCu3Ti4-xTaxO12。替换方案适用于x从0到1的整个范围。Na和Ta掺杂CCTO陶瓷的烧结温度为理论密度的90 ~ 95%,低于未掺杂CCTO陶瓷的烧结温度。Ca1-xNaxCu3Ti4-xTaxO12陶瓷的介电常数随x的变化而变化,介电常数在2600 ~ 9700之间。介电损耗正切在0.1左右。
{"title":"Structure and dielectric properties of Na and Ta doped CaCu3Ti4O12","authors":"O. Shtonda, S. Loboda, A. Bogomolov","doi":"10.1109/OMEE.2014.6912333","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912333","url":null,"abstract":"New ceramic compositions based on Na and Ta doped CaCu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> (CCTO) solid solutions were obtained. The synthesis conditions, parameters of crystal structure and low frequency dielectric properties depending on Na and Ta concentrations were investigated. The solid solutions were obtained by substitution of Ca and Ti in the CCTO structure with Na and Ta, respectively, according to the formula Ca<sub>1-x</sub>Na<sub>x</sub>Cu<sub>3</sub>Ti<sub>4-x</sub>Ta<sub>x</sub>O<sub>12</sub>. The substitution scheme occurs in a whole range of x from 0 to 1. The sintering temperature of Na and Ta doped CCTO ceramics with 90-95% of theoretical density is lower than of undoped CCTO. 1 kHz dielectric permittivity of Ca<sub>1-x</sub>Na<sub>x</sub>Cu<sub>3</sub>Ti<sub>4-x</sub>Ta<sub>x</sub>O<sub>12</sub> ceramics depends on x and varies from 2600 to 9700. Dielectric losses tangent is around 0.1.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"2016 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127488834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Toward stimulated by defects functionality in manganese(IV) oxide materials 锰(IV)氧化物材料中缺陷功能的激发
G. Sokolsky, S. Ivanov, E. Boldyrev, N. Ivanova, L. Vasylechko
Manganese dioxide obtained by electrolytic doping technique was subjected to investigations of influence of cationic additives in an electrolyte on defects in structure and prospectives of improvements in its functionality. The Chabre-Pannetier model was used for this purpose. The results indicate on the variability of γ/β- γ/α-polymorphs intergrowth ratios, and twinning. There is a necessity to expand single phase Chabre-Pannetier model based on ramsdellite structure matrix towards multiphase "open structure" polymorphs that are frequently occurred in electrodeposited samples of manganese dioxide.
通过电解掺杂技术制备二氧化锰,研究了电解质中阳离子添加剂对二氧化锰结构缺陷的影响以及对二氧化锰功能改进的展望。Chabre-Pannetier模型用于此目的。结果表明γ/β- γ/α-多晶互生长率和孪晶的变异性。有必要将基于ramsdellite结构矩阵的单相Chabre-Pannetier模型扩展到电沉积二氧化锰样品中经常出现的多相“开放结构”多晶。
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引用次数: 1
期刊
International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)
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