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Development of backsheet tests and measurements to improve correlation of accelerated exposures to fielded modules 开发背板测试和测量,以改善对现场模块加速暴露的相关性
Pub Date : 2015-09-23 DOI: 10.1117/12.2188627
T. Felder, W. Gambogi, J. Kopchick, Lucas Amspacher, R. Peacock, Benjamin Foltz, K. Stika, A. Bradley, B. Hamzavy, Bao-Ling Yu, L. Garreau-iles, O. Fu, Hongjie Hu, T. Trout
Matching accelerated test results to field observations is an important objective in the photovoltaic industry. We continue to develop test methods to strengthen correlations. We have previously reported good correlation of FTIR spectra between accelerated tests and field measurements. The availability of portable FTIR spectrometers has made measurement in the field convenient and reliable. Recently, nano-indentation has shown promise to correlate changes in backsheet mechanical properties. A precisely shaped stylus is pressed into a sample, load vs displacement recorded and mechanical properties of interest calculated in a nondestructive test. This test can be done on full size modules, allowing area variations in mechanical properties to be recorded. Finally, we will discuss optical profilometry. In this technique a white light interferogram of a surface is Fourier transformed to produce a three-dimensional image. Height differences from 1 nm to 5 mm can be detected over an area of a few cm. This technique can be used on minimodules, and is useful to determine crack and defect dimensions. Results will be presented correlating accelerated tests with fielded modules covering spectroscopic, mechanical, and morphological changes.
将加速测试结果与现场观测相匹配是光伏行业的一个重要目标。我们继续开发测试方法来加强相关性。我们以前已经报道了加速试验和现场测量之间的FTIR光谱的良好相关性。便携式FTIR光谱仪的问世,使现场测量方便、可靠。最近,纳米压痕显示出与背板机械性能变化相关的希望。将形状精确的触针压入样品中,记录载荷与位移,并在无损测试中计算感兴趣的机械性能。该测试可以在全尺寸模块上进行,允许记录机械性能的区域变化。最后,我们将讨论光学轮廓术。在这种技术白光干涉图的表面是傅里叶变换,以产生一个三维图像。在几厘米的区域内可以检测到1纳米到5毫米的高度差。该技术可用于微型模块,并可用于确定裂纹和缺陷的尺寸。结果将提出相关的加速测试与现场模块涵盖光谱,机械和形态的变化。
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引用次数: 11
Survey of potential-induced degradation in thin-film modules 薄膜组件中电势诱导降解的研究
Pub Date : 2015-09-23 DOI: 10.1117/12.2188958
P. Hacke, K. Terwilliger, S. Glick, Greg Perrin, S. Kurtz
CdTe and CIGS type modules were tested for potential-‐induced degradation with positive and negative 1,000 V bias applied to the active cell circuit in an 85°C, 85% relative humidity environmental chamber. Both CdTe module types tested exhibited degradation under negative bias. I-‐V curve data indicated the first module type was affected sequentially by shunting followed by a recovery and then by series resistance losses; the second was affected by recombination losses. The first type showed transparent conductive oxide delamination from the glass after about 750 h of stress testing in the environmental chamber and exhibited power degradation within five weeks in field tests with -‐1,000 V system voltage. Performance of CIGS modules differed depending on the technology generation. Under negative bias, the older module design showed an initial 12% (relative) improvement, possibly because of the influx of sodium ions that has been reported to benefit the electrical properties, followed by severe degradation with continued stress testing. The newer design CIGS module exhibited the best stability of the four thin-‐film module types tested with a total loss of 9.5 % (relative) power drop after 3,100 h of test with negative voltage bias, but not clearly by system voltage stress effects considering similar behavior by a sister module in-‐chamber in open-‐circuit condition. Relative rates of current leakage-‐to-‐ground between chamber tests and modules placed outdoors under system voltage stress are compared to extrapolate anticipated coulombs transferred for given extents of degradation of the module power. This analysis correctly placed which module type failed in the field first, but overestimated the time to failure. The performance of modules at 85°C with dark current Imp applied through the cell circuit are discussed with respect to stand-‐alone fielded modules biased to near their maximum power point with load resistors.
CdTe和CIGS型模块在85°C, 85%相对湿度的环境室中,在正负1000 V偏置下测试了电位诱导的降解。两种测试的CdTe模块类型在负偏置下都表现出退化。I- V曲线数据表明,第一种模块类型依次受到分流、恢复和串联电阻损失的影响;第二是受到重组损失的影响。第一种类型在环境室中进行约750小时的应力测试后,玻璃上出现透明导电氧化物分层,在- - 1,000 V系统电压的现场测试中,在5周内出现功率下降。CIGS模块的性能因技术的不同而不同。在负偏压下,旧的模块设计显示出最初12%(相对)的改进,可能是因为钠离子的流入,据报道,钠离子有利于电性能,随后在持续的压力测试中严重退化。新设计的CIGS模块在四种薄膜模块类型中表现出最好的稳定性,在负电压偏置测试3100小时后,总损耗为9.5%(相对)功率下降,但考虑到开路条件下的姊妹模块在开路条件下的相似行为,系统电压应力效应并不明显。在系统电压应力下,将室内测试和置于室外的模块之间的相对漏地电流率与给定模块功率退化程度下的预期传输库仑进行比较。该分析正确地将哪个模块类型首先放在字段中,但是高估了故障发生的时间。讨论了在85°C下,通过电池电路施加暗电流Imp时,模块的性能,以及负载电阻偏置到其最大功率点附近的独立场模块。
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引用次数: 3
A data science approach to understanding photovoltaic module degradation 理解光伏组件退化的数据科学方法
Pub Date : 2015-09-23 DOI: 10.1117/12.2209204
Nicholas R. Wheeler, A. Gok, T. Peshek, L. Bruckman, Nikhil Goel, Davis Zabiyaka, Cara Fagerholm, Thomas Dang, Christopher Alcantara, M. Terry, R. French
The expected lifetime performance and degradation of photovoltaic (PV) modules is a major issue facing the levelized cost of electricity of PV as a competitive energy source. Studies that quantify the rates and mechanisms of performance degradation are needed not only for bankability and adoption of these promising technologies, but also for the diagnosis and improvement of their mechanistic degradation pathways. Towards this goal, a generalizable approach to degradation science studies utilizing data science principles has been developed and applied to c-Si PV modules. By combining domain knowledge and data derived insights, mechanistic degradation pathways are indicated that link environmental stressors to the degradation of PV module performance characteristics. Targeted studies guided by these results have yielded predictive equations describing rates of degradation, and further studies are underway to achieve this for additional mechanistic pathways of interest.
光伏(PV)组件的预期寿命性能和退化是光伏作为一种有竞争力的能源所面临的一个主要问题。量化性能退化的速率和机制的研究不仅是为了这些有前途的技术的可融资性和采用,而且也是为了诊断和改进其机械退化途径。为了实现这一目标,已经开发了一种利用数据科学原理进行降解科学研究的通用方法,并将其应用于c-Si光伏组件。通过结合领域知识和数据得出的见解,指出了将环境压力因素与光伏组件性能特征的退化联系起来的机械退化途径。在这些结果的指导下,有针对性的研究已经产生了描述降解速率的预测方程,进一步的研究正在进行中,以实现其他感兴趣的机制途径。
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引用次数: 4
Cracking and delamination behaviors of photovoltaic backsheet after accelerated laboratory weathering 实验室加速风化后光伏背板的开裂和分层行为
Pub Date : 2015-09-23 DOI: 10.1117/12.2188557
Chiao-Chi Lin, Yadong Lyu, D. Hunston, J. H. Kim, K. Wan, D. Stanley, X. Gu
The channel crack and delamination phenomena that occurred during tensile tests were utilized to study surface cracking and delamination properties of a multilayered backsheet. A model sample of commercial PPE (polyethylene terephthalate (PET)/PET/ethylene vinyl acetate (EVA)) backsheet was studied. Fragmentation testing was performed after accelerated aging with and without ultraviolet (UV) irradiation in two relative humidity (RH) levels (5 % RH and 60 % RH) at elevated temperature (85 °C) conditions for 11 days and 22 days. Results suggest that the embrittled surface layer resulting from the UV photo-degradation is responsible for surface cracking when the strain applied on the sample is far below the yielding strain (2.2 %) of the PPE sample. There was no surface cracking observed on the un-aged sample and samples aged without UV irradiation. According to the fragmentation testing results, the calculated fracture toughness (KIC) values of the embrittled surface layer are as low as 0.027 MPa·m1/2 to 0.104 MPa·m1/2, depending on the humidity levels and aging times. Surface analysis using attenuated total reflectance Fourier transform infrared and atomic force microscopy shows the degradation mechanism of the embrittled surface layer is a combination of the photodegradation within a certain degradation depth and the moisture erosion effect depending on the moisture levels. Specifically, UV irradiation provides a chemical degradation effect while moisture plays a synergistic effect on surface erosion, which influences surface roughness after aging. Finally, there was no delamination observed during tensile testing in this study, suggesting the surface cracking problem is more significant than the delamination for the PPE backsheet material and conditions tested here.
利用拉伸试验过程中出现的通道裂纹和分层现象,研究了多层背板的表面裂纹和分层特性。对商用PPE(聚对苯二甲酸乙二醇酯(PET)/PET/醋酸乙烯酯(EVA))背板的模型样品进行了研究。在两种相对湿度(5% RH和60% RH)、高温(85°C)条件下,分别进行了11天和22天的加速老化,并在有和没有紫外线(UV)照射下进行了破碎试验。结果表明,当施加在样品上的应变远低于PPE样品的屈服应变(2.2%)时,由紫外光降解产生的脆化表面层是导致表面开裂的原因。未时效和未经紫外线辐照时效的样品均未观察到表面开裂。根据破碎试验结果,计算得到的脆化面层断裂韧性(KIC)值随湿度和时效次数的变化可低至0.027 MPa·m1/2 ~ 0.104 MPa·m1/2。利用衰减全反射傅立叶变换红外和原子力显微镜进行表面分析表明,脆性面层的降解机制是一定降解深度内的光降解和取决于水分水平的水分侵蚀效应的结合。具体来说,紫外线照射提供了化学降解作用,而水分对表面侵蚀起协同作用,影响老化后的表面粗糙度。最后,在本研究的拉伸测试中没有观察到分层现象,这表明PPE背板材料和测试条件的表面开裂问题比分层问题更严重。
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引用次数: 14
Raman spectroscopy study of SiC thin films prepared by PECVD for solar cell working in hard environment 硬质环境下太阳能电池用PECVD制备SiC薄膜的拉曼光谱研究
Pub Date : 2015-09-23 DOI: 10.1117/12.2186749
V. Sasinková, J. Huran, A. Kleinová, P. Boháček, J. Arbet, M. Sekáčová
Amorphous silicon carbide films were deposited by plasma enhanced chemical vapor deposition (PECVD) technology using SiH4, CH4, H2 and NH3 gas as precursors. The concentration of elements in the films was determined by RBS and ERD analytical method. Chemical compositions were analyzed by FT-IR spectroscopy. Raman spectroscopy study of the SiC films were performed by using a Raman microscope. Irradiation of samples with neutrons to fluencies A(7.9x1014 cm-2), B(5x1015 cm-2) and C(3.4x1016 cm-2) was performed at room temperature. Raman spectroscopy results of SiC films showed decreasing of Raman band feature intensity after neutron irradiation and slightly decreased with increased neutron fluencies. Raman spectra differences between types of films before and after neutron irradiation are discussed. The electrical properties of SiC films were determined by the I-V measurement at 295 K. The measured currents were greater (about two order) after irradiation than the current before irradiation for all samples and rose up with neutron fluencies.
以SiH4、CH4、H2和NH3气体为前驱体,采用等离子体增强化学气相沉积(PECVD)技术制备了非晶碳化硅薄膜。采用RBS和ERD分析方法测定了膜中元素的浓度。用傅里叶变换红外光谱分析其化学成分。利用拉曼显微镜对SiC薄膜进行了拉曼光谱研究。在室温下用中子照射样品到A(7.9x1014 cm-2), B(5x1015 cm-2)和C(3.4x1016 cm-2)。碳化硅薄膜的拉曼光谱结果表明,中子辐照后,薄膜的拉曼带特征强度减小,随中子通量的增加略有减小。讨论了中子辐照前后不同类型薄膜的拉曼光谱差异。在295 K下,通过I-V测量测定了SiC薄膜的电学性能。所有样品辐照后测得的电流都比辐照前大(约两个数量级),且随中子通量的增大而增大。
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引用次数: 3
Analysis of PV modules based on thin film solar cells by dark measurements technique 利用暗测量技术分析基于薄膜太阳能电池的光伏组件
Pub Date : 2015-09-23 DOI: 10.1117/12.2187369
K. Agroui, M. Pellegrino, F. Giovanni
The dark measurements technique which were developed to analyze the material properties of solar cells in a PV module and performed either at DC or at AC conditions, can give useful information on the quality of the active material. This technique leads to better understanding the PV module degradation processes, occurring during indoor qualification testing or in real operating conditions. To this purpose an indoor testing laboratory has been set up to detect and monitor the PV modules degradation. A simple technique, based on the analysis of the behaviour of PV devices biased by an AC signal on dark conditions, has been developed to easily and quickly evaluate some parameters like the series, the shunt resistances and the capacitance affecting their electrical characteristics. In the present paper the technique basic concepts will be illustrated. Preliminary experimental results, achieved by applying the technique to some kinds of PV modules based on simple and triple junction’s silicon amorphous solar cells, will be presented.
暗测量技术用于分析光伏组件中太阳能电池的材料特性,可以在直流或交流条件下进行,可以提供有关活性材料质量的有用信息。该技术可以更好地理解在室内鉴定测试或实际操作条件下发生的光伏组件退化过程。为此,建立了一个室内测试实验室来检测和监测光伏组件的退化。基于对在黑暗条件下受交流信号偏置的光伏器件行为的分析,已经开发出一种简单的技术,可以轻松快速地评估一些参数,如串联、分流电阻和影响其电气特性的电容。本文将阐述该技术的基本概念。本文将介绍将该技术应用于基于简单和三结硅非晶太阳能电池的几种光伏组件的初步实验结果。
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引用次数: 0
PID: from material properties to outdoor performance and quality control counter measures PID:从材料性能到室外性能及质量控制的对策
Pub Date : 2015-09-23 DOI: 10.1117/12.2188464
J. Berghold, S. Koch, S. Pingel, S. Janke, A. Ukar, P. Grunow, T. Shioda
Although the main root causes and referring counter measures for PID are known, a significant part of the industrial modules are still found to be PID sensitive in testing and PID is increasingly evident in field. This paper discusses field occurrence of PID with respect to environmental conditions and material properties. Different PID pattern in field and in test are analyzed in terms of the potential distribution and surface conductivity. Examples are given for the correlation of PID lab tests of a (commercial) BOM with real outdoor degradation. PID progress is predicted for different locations and compared with measurement data. Suitable quality control measures are discussed for the modules as well as for the encapsulation material
虽然PID产生的主要原因和参考对策已经知道,但在测试中仍然发现有相当一部分工业模块对PID敏感,PID在现场的应用越来越明显。本文从环境条件和材料性能两方面讨论了PID的现场发生情况。从电势分布和表面电导率两方面分析了现场和试验中不同的PID模式。给出了一种(商用)BOM的PID实验室测试与实际室外退化的相关性的实例。对不同位置的PID进度进行了预测,并与实测数据进行了比较。讨论了模块和封装材料的质量控制措施
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引用次数: 16
Critical analysis on degradation mechanism of dye-sensitized solar cells 染料敏化太阳能电池降解机理的关键分析
Pub Date : 2015-09-23 DOI: 10.1117/12.2186968
M. Mohamad Shahimin, S. Suhaimi, Mohd Halim Abd Wahid, V. Retnasamy, N. A. Ahmad Hambali, A. Reshak
This paper reports on a précis of degradation mechanism for dye-sensitized solar cell (DSSCs). The review indicates progress in the understanding of degradation mechanism, in particular, the large improvement in the analysis of the materials used in DSSCs. The paper discussed on the stability issues of the dye, advancement of the photoelectrode film lifetime, changes in the electrolyte components and degradation analysis of the counter electrode. The photoelectrochemical parameters were evaluated in view of the possible degradation routes via open circuit voltage (Voc), short circuit current (Isc), fill factor (FF) and overall conversion efficiency (η) from the current-voltage curve. This analysis covers several types of materials that have paved the way for better-performing solar cells and directly influenced the stability and reliability of DSSCs. The new research trend together with the previous research has been highlighted to examine the key challenges faced in developing the ultimate DSSCs.
本文报道了染料敏化太阳能电池(DSSCs)的降解机理。综述表明,对降解机理的理解取得了进展,特别是对DSSCs所用材料的分析有了很大的改进。本文讨论了染料的稳定性问题、光电极膜寿命的进展、电解质成分的变化以及对电极的降解分析。通过开路电压(Voc)、短路电流(Isc)、填充系数(FF)和总转换效率(η)从电流-电压曲线上评价了可能的降解途径。该分析涵盖了几种类型的材料,这些材料为性能更好的太阳能电池铺平了道路,并直接影响了DSSCs的稳定性和可靠性。新的研究趋势与以往的研究一起被强调,以检查在开发最终的DSSCs面临的关键挑战。
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引用次数: 1
Investigation of power values of PV rooftop systems based on heat gain reduction 基于减热的屋顶光伏系统功率值研究
Pub Date : 2015-09-23 DOI: 10.1117/12.2188534
Tanokkorn Chenvidhya, M. Seapan, P. Parinya, B. Wiengmoon, D. Chenvidhya, R. Songprakorp, C. Limsakul, Yaowanee Sangpongsanont, Nittaya Tannil
PV rooftop system can generally be installed to produce electricity for the domestic house, office, small enterprise as well as factory. Such a system has direct useful for reducing peak load, meanwhile it also provides shaded area on the roof and hence the heat gain into the building is reduced. This study aims to investigate the shading effect on reduction of heat transfer into the building. The 49 kWp of PV rooftop system has been installed on the deck of the office building located in the middle of Thailand where the latitude of 14 ° above the equator. The estimation of heat gain into the building due to the solar irradiation throughout a day for one year has been carried out, before and after the installation of the PV rooftop system. Then the Newton’s law of cooling is applied to calculate the heat gain. The calculation and the measurement of the heat reduction are compared. Finally, the indirect benefit of the PV rooftop system installed is evaluated in terms of power value.
光伏屋顶系统一般可以安装在家庭住宅,办公室,小型企业和工厂发电。这样的系统对降低峰值负荷有直接的帮助,同时它也在屋顶上提供阴影区域,因此减少了进入建筑物的热量。本研究旨在探讨遮阳对减少建筑热量传递的影响。49 kWp的光伏屋顶系统安装在位于泰国中部的办公大楼的甲板上,那里的纬度为赤道以上14°。在安装光伏屋顶系统之前和之后,对一年中每天由于太阳照射而进入建筑物的热量进行了估计。然后应用牛顿冷却定律计算热增益。对热消减量的计算和测量进行了比较。最后,根据电力价值评估安装光伏屋顶系统的间接效益。
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引用次数: 3
PV industry growth and module reliability in Thailand 泰国光伏产业增长和组件可靠性
Pub Date : 2015-09-23 DOI: 10.1117/12.2188494
D. Chenvidhya, M. Seapan, Yaowanee Sangpongsanont, Tanokkorn Chenvidhya, C. Limsakul, R. Songprakorp
The PV applications in Thailand are now installed more than 1.2 GWp cumulatively. It is due to the National Renewable Energy Program and its targets. In the latest Alternative Energy Development Plan (AEDP), the PV electricity production target has increased from 2 GWp to 3 GWp. With this rapid growth, customers and manufacturers seek for module standard testing. So far over one thousands of PV modules per annum have been tested since 2012. The normal tests include type approval test according to TIS standard, acceptance test and testing for local standard development. For type test, the most module failure was found during damp heat test. For annual evaluation test, the power degradation and delamination of power was found between 0 to 6 percent from its nameplate after deployment of 0 to 5 years in the field. For thin-film module, the degradation and delamination was found in range of 0 to 13 percent (about 5 percent on average) from its nameplate for the modules in operation with less than 5 years. However, for the PV modules at the reference site on campus operated for 12 years, the power degradation was ranging from 10 to 15 percent. Therefore, a long term performance assessment needs to be considered to ensure the system reliability.
泰国的光伏应用目前累计安装超过1.2 GWp。这要归功于国家可再生能源计划及其目标。在最新的替代能源发展计划(AEDP)中,光伏发电目标已从2 GWp增加到3 GWp。随着这种快速增长,客户和制造商寻求模块标准测试。自2012年以来,每年有超过1000个光伏组件进行测试。正常的试验包括按照TIS标准进行型式认可试验、验收试验和地方标准制定试验。型式试验中,湿热试验中发现的模块故障最多。在年度评估测试中,经过0 - 5年的现场部署,功率退化和功率分层率在其铭牌上的0 - 6%之间。对于薄膜组件,在运行不到5年的模块中,发现降解和分层的范围为0 - 13%(平均约5%)。然而,对于在校园参考地点运行了12年的光伏模块,功率下降幅度在10%到15%之间。因此,需要考虑长期的性能评估,以确保系统的可靠性。
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引用次数: 0
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