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Investigation of degradation mechanisms of perovskite-based photovoltaic devices using laser beam induced current mapping 基于激光束感应电流成像的钙钛矿基光伏器件降解机理研究
Pub Date : 2015-09-05 DOI: 10.1117/12.2195789
Zhaoning Song, Suneth C. Watthage, A. Phillips, Geethika K. Liyanage, R. Khanal, Brandon L. Tompkins, R. Ellingson, M. Heben
Solution processed thin film photovoltaic devices incorporating organohalide perovskites have progressed rapidly in recent years and achieved energy conversion efficiencies greater than 20%. However, an important issue limiting their commercialization is that device efficiencies often drop within the first few hundred hours of operation. To explore the origin of the device degradation and failure in perovskite solar cells, we investigated the spatial uniformity of current collection at different stages of aging using two-dimensional laser beam induced current (LBIC) mapping. We validated that the local decomposition of the perovskite material is likely due to interactions with moisture in the air by comparing photocurrent collection in perovskite devices that were maintained in different controlled environments. We show that the addition of a poly(methyl methacrylate)/single-wall carbon nanotube (PMMA/SWCNT) encapsulation layer prevents degradation of the device in moist air. This suggests a route toward perovskite solar cells with improved operational stability and moisture resistance.
结合有机卤化物钙钛矿的溶液加工薄膜光伏器件近年来发展迅速,能量转换效率大于20%。然而,限制其商业化的一个重要问题是,设备效率通常在运行的前几百小时内下降。为了探究钙钛矿太阳能电池器件退化和失效的原因,我们利用二维激光束感应电流(LBIC)测绘技术研究了钙钛矿太阳能电池在不同老化阶段电流收集的空间均匀性。通过比较维持在不同受控环境中的钙钛矿器件中的光电流收集,我们验证了钙钛矿材料的局部分解可能是由于与空气中的水分相互作用。我们发现,添加聚甲基丙烯酸甲酯/单壁碳纳米管(PMMA/SWCNT)包封层可以防止器件在潮湿空气中降解。这为钙钛矿太阳能电池提供了一条改进操作稳定性和抗湿性的途径。
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引用次数: 15
Robust measurement of thin-film photovoltaic modules exhibiting light-induced transients 显示光致瞬变的薄膜光伏组件的鲁棒测量
Pub Date : 2015-09-05 DOI: 10.1117/12.2188827
M. Deceglie, T. Silverman, B. Marion, S. Kurtz
Light-induced changes to the current-voltage characteristic of thin-film photovoltaic modules (i.e. light-soaking effects) frustrate the repeatable measurement of their operating power. We describe best practices for mitigating, or stabilizing, light-soaking effects for both CdTe and CIGS modules to enable robust, repeatable, and relevant power measurements. We motivate the practices by detailing how modules react to changes in different stabilization methods. We also describe and demonstrate a method for validating alternative stabilization procedures, such as those relying on forward bias in the dark. Reliable measurements of module power are critical for qualification testing, reliability testing, and power rating.
光引起的薄膜光伏组件的电流电压特性变化(即光浸泡效应)阻碍了其工作功率的可重复测量。我们描述了减轻或稳定CdTe和CIGS模块光吸收效应的最佳实践,以实现稳健、可重复和相关的功率测量。我们通过详细说明模块如何对不同稳定方法的变化做出反应来激励实践。我们还描述并演示了一种验证替代稳定程序的方法,例如在黑暗中依赖于前向偏差的方法。模块功率的可靠测量对于资格测试、可靠性测试和额定功率至关重要。
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引用次数: 7
Sol-gel deposition and plasma treatment of intrinsic, aluminum-doped, and gallium-doped zinc oxide thin films as transparent conductive electrodes 本征、掺铝和掺镓氧化锌薄膜作为透明导电电极的溶胶-凝胶沉积和等离子体处理
Pub Date : 2015-09-05 DOI: 10.1117/12.2186144
Zhaozhao Zhu, T. Mankowski, K. Balakrishnan, A. S. Shikoh, F. Touati, M. Benammar, M. Mansuripur, C. Falco
Zinc oxide and aluminum/gallium-doped zinc oxide thin films were deposited via sol-gel spin-coating technique. Employing plasma treatment as alternative to post thermal annealing, we found that the morphologies of these thin films have changed and the sheet resistances have been significantly enhanced. These plasma-treated thin films also show very good optical properties, with transmittance above 90% averaged over the visible wavelength range. Our best aluminum/gallium-doped zinc oxide thin films exhibit sheet resistances (Rs) of ~ 200 Ω/sq and ~ 150 Ω/sq, respectively.
采用溶胶-凝胶自旋镀膜技术制备了氧化锌和掺铝/镓氧化锌薄膜。采用等离子体处理替代热后退火,我们发现这些薄膜的形貌发生了变化,薄片电阻显著增强。这些经等离子体处理的薄膜也显示出非常好的光学性能,在可见光波长范围内的平均透过率超过90%。我们最好的铝/镓掺杂氧化锌薄膜的片电阻(Rs)分别为~ 200 Ω/sq和~ 150 Ω/sq。
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引用次数: 9
In-situ/operando soft x-ray spectroscopy characterization of interfacial phenomena in energy materials and devices 原位/operando软x射线光谱表征能源材料和器件中界面现象
Pub Date : 2015-09-05 DOI: 10.1117/12.2187742
Yi-sheng Liu, P. Glans, T. Arthur, Fuminori Mizuno, Chinglin Chang, W. Pong, Jinghua Guo
Many important energy systems are based on the complexity of material architecture, chemistry and interactions among constituents within. To understand and thus ultimately control the energy applications calls for in-situ/operando characterization tools. Recently, we have developed the in-situ/operando soft X-ray spectroscopic systems for the studies of catalytic and electrochemical reactions, and reveal how to overcome the challenge that soft X-rays cannot easily peek into the high-pressure catalytic or liquid electrochemical reactions. The unique design of in-situ/operando soft X-ray spectroscopy instrumentation and fabrication principle and one example are presented.
许多重要的能源系统是建立在复杂的材料结构、化学和内部成分之间相互作用的基础上的。为了理解并最终控制能源应用,需要使用原位/操作表征工具。最近,我们开发了用于催化和电化学反应研究的原位/operando软x射线光谱系统,并揭示了如何克服软x射线难以窥探高压催化或液体电化学反应的挑战。介绍了原位/operando软x射线光谱仪器的独特设计、制作原理和一个实例。
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引用次数: 1
Synchrotron-based spectroscopy for solar energy conversion 基于同步加速器的光谱学用于太阳能转换
Pub Date : 2015-09-05 DOI: 10.1117/12.2187038
F. Himpsel, P. Cook, I. Zegkinoglou, I. Boukahil, R. Qiao, W. Yang, S. Pemmaraju, D. Prendergast, C. Kronawitter, M. Kibria, Z. Mi, L. Vayssieres
X-rays from synchrotron radiation enable incisive spectroscopic techniques which speed up the discovery of new materials for photovoltaics and photoelectrochemistry. A particularly useful method is X-ray absorption spectroscopy (XAS), which probes empty electronic states. XAS is element- and bond-specific, with the additional capability of determining the bond orientation. Close feedback from density functional calculations makes it possible to discover and exploit systematic trends in the electronic properties. Case studies are presented, such as solar cells that combine an absorber with an electron donor and an acceptor in one molecular complex and nanowire arrays serving as photoanodes for water splitting. In addition to the energy levels the lifetimes of the charge carriers play an essential role in device performance. A new generation of laser-like X-ray sources will make it possible to follow the fate of excited charge carriers traveling across a molecular complex or through a device structure in real time.
来自同步辐射的x射线使敏锐的光谱技术加速了光伏和光电化学新材料的发现。一种特别有用的方法是x射线吸收光谱(XAS),它可以探测空电子态。XAS是特定于元素和键的,具有确定键取向的附加功能。密度泛函计算的密切反馈使得发现和利用电子性质的系统趋势成为可能。案例研究提出,如太阳能电池结合吸收剂与电子供体和受体在一个分子复合物和纳米线阵列作为光阳极水分解。除了能级外,载流子的寿命在器件性能中起着至关重要的作用。新一代类似激光的x射线源将使跟踪激发载流子穿越分子复合物或实时穿过器件结构的命运成为可能。
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引用次数: 0
Solar selective coatings based on carbon: transition metal nanocomposites 基于碳-过渡金属纳米复合材料的太阳能选择性涂层
Pub Date : 2015-09-05 DOI: 10.1117/12.2189515
I. Heras, E. Guillén, M. Krause, A. Pardo, J. Endrino, R. Escobar Galindo
The design of an efficient and stable solar selective coating for Concentrating Solar Power central receivers requires a complex study of the materials candidates that compose the coating. Carbon-transition metal nanocomposites were studied in this work as absorber materials because they show appropriate optical properties with high absorption in the solar region and low thermal emittance in the infrared. Furthermore metal carbides are thermal and mechanical stable in air at high temperatures. In this work a solar selective coating was grown by a dual source filtered cathodic vacuum arc. The complete stack consists on an infrared reflection layer, an absorber layer of carbon-zirconium carbide nanocomposites and an antireflection layer. The aim of this research is optimize the absorber layer and for that, the metal content was controlled by adjusting the pulse ratio between the two arc sources. The elemental composition was determined by Ion Beam Analysis, X-Ray diffraction measurements show the crystal structure and the optical properties were characterized by spectroscopic ellipsometry measurements. The reflectance spectra of the complete selective coating were simulated with the optical software CODE. Bruggeman effective medium approximation was employed to average the dielectric functions of the two components which constitute the nanocomposite in the absorber layer. The optimized coating exhibited a solar absorptance of 95.41% and thermal emittance of 3.5% for 400°C. The simulated results were validated with a deposited multilayer selective coating.
为聚光太阳能中央接收器设计一种高效稳定的太阳能选择性涂层,需要对构成涂层的候选材料进行复杂的研究。由于碳-过渡金属纳米复合材料具有良好的光学性能,在太阳区域具有高吸收率,在红外区域具有低热发射率,因此本文研究了碳-过渡金属纳米复合材料作为吸收材料。此外,金属碳化物在高温下在空气中具有热稳定性和机械稳定性。本文采用双源过滤阴极真空电弧生长了一种太阳能选择性涂层。完整的叠层由红外反射层、碳-碳化锆纳米复合材料吸收层和增反射层组成。本研究的目的是优化吸收层,并通过调节两个电弧源之间的脉冲比来控制金属含量。通过离子束分析确定了元素组成,x射线衍射测量显示了晶体结构,通过椭偏光谱测量表征了光学性质。利用光学软件CODE对全选择性涂层的反射光谱进行了模拟。采用Bruggeman有效介质近似法对吸收层中构成纳米复合材料的两组分的介电函数进行平均。优化后的涂层在400℃时的太阳吸收率为95.41%,热发射率为3.5%。用沉积的多层选择性涂层对模拟结果进行了验证。
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引用次数: 0
Concentrating PV module output power using a wireless microcontroller based automatic sun tracker 聚光光伏模块输出功率采用无线微控制器为基础的自动太阳跟踪器
Pub Date : 2015-09-05 DOI: 10.1117/12.2186942
A. Abou-Elnour, Asma Salem, Salma M. Ghanem, Ismail Amin Ali
In the present work, a wireless two dimensional microcontroller based sun tracker is designed and implemented. The proposed system has three main components namely the controlling unit, the wireless communication system, and the monitoring and recording unit. Controlling features are fully obtained in the present system using an efficient microcontroller based programming environment. Design equations, which are implemented, allow the usage of the system anywhere anytime without extra hardware tracking circuits. The sun tracker continuously calculates the photovoltaic module’s tilt and azimuth angles by using accurate sun movement equations. The system generates the motors controlling signals to allocate the photovoltaic module to receive the maximize amount of solar energy on its surface from sunrise to sunset. For monitoring purpose the output of the movable photovoltaic module and from a south faced fixed module are wirelessly transmitted to the local monitoring system where the data are recorded, analyzed, and published. The proposed system is successfully implemented and tested for long periods under realistic operating conditions and the obtained positioning results are in excellent agreement with the theoretical ones.
本文设计并实现了一种基于无线二维微控制器的太阳跟踪器。所提出的系统有三个主要组成部分,即控制单元、无线通信系统和监控记录单元。本系统采用高效的单片机编程环境,充分实现了控制特性。设计方程,这是实现,允许使用系统的任何地方,任何时间,没有额外的硬件跟踪电路。太阳跟踪器通过精确的太阳运动方程连续计算光伏组件的倾斜角和方位角。系统产生电机控制信号,分配光伏组件从日出到日落在其表面接收最大数量的太阳能。为监测目的,将可移动光伏组件的输出和来自南向固定模块的输出无线传输到本地监测系统,在本地监测系统中记录、分析和发布所述数据。该系统在实际运行条件下进行了长时间的成功实施和测试,得到的定位结果与理论结果吻合良好。
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引用次数: 1
Holographic lens spectrum splitting photovoltaic system for increased diffuse collection and annual energy yield 全息透镜分光光伏系统增加漫射收集和年能源产量
Pub Date : 2015-09-05 DOI: 10.1117/12.2187124
S. Vorndran, Yuechen Wu, Silvana Ayala, R. Kostuk
Concentrating and spectrum splitting photovoltaic (PV) modules have a limited acceptance angle and thus suffer from optical loss under off-axis illumination. This loss manifests itself as a substantial reduction in energy yield in locations where a significant portion of insulation is diffuse. In this work, a spectrum splitting PV system is designed to efficiently collect and convert light in a range of illumination conditions. The system uses a holographic lens to concentrate shortwavelength light onto a smaller, more expensive indium gallium phosphide (InGaP) PV cell. The high efficiency PV cell near the axis is surrounded with silicon (Si), a less expensive material that collects a broader portion of the solar spectrum. Under direct illumination, the device achieves increased conversion efficiency from spectrum splitting. Under diffuse illumination, the device collects light with efficiency comparable to a flat-panel Si module. Design of the holographic lens is discussed. Optical efficiency and power output of the module under a range of illumination conditions from direct to diffuse are simulated with non-sequential raytracing software. Using direct and diffuse Typical Metrological Year (TMY3) irradiance measurements, annual energy yield of the module is calculated for several installation sites. Energy yield of the spectrum splitting module is compared to that of a full flat-panel Si reference module.
聚光和分光光伏(PV)组件在离轴照明下接收角度有限,存在光损耗。这种损失表现为在大量绝缘扩散的位置产生能量的大量减少。在这项工作中,设计了一个分光光伏系统,用于在一系列照明条件下有效地收集和转换光。该系统使用全息透镜将短波长的光集中到一个更小、更昂贵的磷化铟镓(InGaP)光伏电池上。轴附近的高效光伏电池被硅(Si)包围,这是一种更便宜的材料,可以收集更广泛的太阳光谱。在直接照明下,该器件通过分光实现了更高的转换效率。在漫射照明下,该装置收集光的效率可与平板硅模块相媲美。讨论了全息透镜的设计。利用非顺序光线追踪软件模拟了从直接到漫射的一系列光照条件下模块的光效率和功率输出。使用直接和扩散典型计量年(TMY3)辐照度测量,计算了几个安装地点的模块年发电量。将分光模块的产能与全平板硅参考模块的产能进行了比较。
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引用次数: 0
Metal-complex/semiconductor hybrids for carbon dioxide fixation 用于二氧化碳固定的金属配合物/半导体杂合物
Pub Date : 2015-09-05 DOI: 10.1117/12.2187341
K. Maeda, R. Kuriki, Keita Sekizawa, O. Ishitani
A hybrid photocatalyst consisting of a catalytic Ru complex and polymeric carbon nitride (band gap, 2.7 eV) was capable of reducing CO2 into HCOOH with ~80% selectivity under visible light (λ > 420 nm) in the presence of a suitable electron donor. Introduction of mesoporosity into the graphitic carbon nitride structure to increase the specific surface area was essential to enhancing the activity. However, higher surface area (in other words, lower crystallinity) that originated from excessively introduced mesopores had a negative impact on activity. Promoting electron injection from carbon nitride to the catalytic Ru unit as well as strengthening the electronic interactions between the two units improved the activity. Under the optimal condition, a turnover number (TON, with respect to the Ru complex used) greater than 1000 and an apparent quantum yield of 5.7% (at 400 nm) were obtained, which are the greatest among heterogeneous photocatalysts for visible-light CO2 reduction ever reported.
在合适的电子给体存在的可见光(λ > 420 nm)下,由Ru络合物和聚合氮化碳(带隙2.7 eV)组成的杂化光催化剂能以80%的选择性将CO2还原为HCOOH。在氮化碳石墨结构中引入介孔以增加比表面积是提高活性的必要条件。然而,由于过度引入介孔而产生的较高的表面积(换句话说,较低的结晶度)对活性有负面影响。促进氮化碳向Ru催化单元的电子注入以及加强两个单元之间的电子相互作用提高了活性。在最优条件下,钌络合物的周转数(TON)大于1000,表观量子产率(400 nm)为5.7%,是目前报道的用于可见光CO2还原的多相光催化剂中最高的。
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引用次数: 2
Demonstration of an intermediate-scale lens-to-channel waveguide solar concentrator 中等规模透镜-通道波导太阳能聚光器的演示
Pub Date : 2015-09-05 DOI: 10.1117/12.2188697
R. Huang, Y. Liu, C. Madsen
Solar concentrating photovoltaic systems have the potential to reduce total cost and achieve higher efficiency by replacing a large solar cell surface with cheaper optical devices, in which a large area of light can be efficiently collected and concentrated to a small optical device and guided to an array of co-located photovoltaic cells with high optical efficiency. We present an experimental demonstration for a lens-to-channel waveguide solar concentrator using a commercially-available Fresnel lens array. In this work, a 60 mm by 60 mm lens to channel waveguide system is used for demonstration. A separate, aluminum-coated 45° coupler is fabricated and attached to the waveguide to improve the coupling efficiency and to avoid any inherent decoupling loss. The fabrication details and component performance of the prototype device are discussed.
太阳能聚光光伏系统具有降低总成本和实现更高效率的潜力,通过使用更便宜的光学器件取代大型太阳能电池表面,其中大面积的光可以有效地收集和集中到小型光学器件中,并引导到具有高光效率的共定位光伏电池阵列中。我们提出了一个实验演示的透镜到通道波导太阳能聚光器使用市售菲涅耳透镜阵列。在这项工作中,使用了一个60mm × 60mm的透镜通道波导系统进行演示。一个单独的,铝涂层45°耦合器被制造并连接到波导,以提高耦合效率,并避免任何固有的去耦损失。讨论了原型器件的制作细节和器件性能。
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引用次数: 0
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