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Design of a holographic micro-scale spectrum-splitting photovoltaic system 全息微尺度分光光伏系统的设计
Pub Date : 2015-09-05 DOI: 10.1117/12.2187073
Yuechen Wu, S. Vorndran, Silvana Ayala Pelaez, J. Russo, R. Kostuk
Micro-scale PV technology combines the high conversion efficiency of concentrated photovoltaics (CPV) with the low costs and the simple form of flat panel PV. Some of the benefits of micro-scale PV include: reduced semiconductor material usage; improved heat rejection capacity; and more versatile PV cell interconnect configurations. Spectrumsplitting is also a beneficial technique to increase the efficiency and reduce the cost of photovoltaic systems. It spatially separates the incident solar spectrum into spectral components and directs them to PV cells with matching bandgaps. This approach avoids the current and lattice matching problems that exist in tandem multi-junction systems. In this paper, we applied the ideas of spectrum-splitting in a micro-scale PV system, and demonstrated a holographic micro-scale spectrum-splitting photovoltaic system. This system consists of a volume transmission hologram in combination with a micro-lens array. An analysis methodology was developed to design the system and determine the performance of the resulting system. The spatial characteristics of the dispersed spectrum, the overall system conversion efficiency, and the improvement over best bandgap will be discussed.
微型光伏技术将聚光光伏(CPV)的高转换效率与平板光伏的低成本和简单形式相结合。微型光伏的一些好处包括:减少半导体材料的使用;提高散热能力;以及更通用的光伏电池互连配置。光谱分解也是提高光伏系统效率和降低成本的一种有益技术。它在空间上将入射太阳光谱分离成光谱分量,并将其引导到具有匹配带隙的光伏电池中。这种方法避免了串联多结系统中存在的电流和晶格匹配问题。本文将光谱分裂的思想应用到微尺度光伏系统中,演示了一种全息微尺度分光光伏系统。该系统由体透射全息图与微透镜阵列相结合组成。开发了一种分析方法来设计系统并确定最终系统的性能。讨论了分散光谱的空间特性、系统的整体转换效率以及最佳带隙的改进。
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引用次数: 0
Testing and optical modeling of novel concentrating solar receiver geometries to increase light trapping and effective solar absorptance 新型聚光太阳能接收器几何形状的测试和光学建模,以增加光捕获和有效的太阳能吸收
Pub Date : 2015-09-05 DOI: 10.1117/12.2186647
J. Yellowhair, C. Ho, Jesus D. Ortega, J. Christian, C. Andraka
Concentrating solar power receivers are comprised of panels of tubes arranged in a cylindrical or cubical shape on top of a tower. The tubes contain heat-transfer fluid that absorbs energy from the concentrated sunlight incident on the tubes. To increase the solar absorptance, black paint or a solar selective coating is applied to the surface of the tubes. However, these coatings degrade over time and must be reapplied, which reduces the system performance and increases costs. This paper presents an evaluation of novel receiver shapes and geometries that create a light-trapping effect, thereby increasing the effective solar absorptance and efficiency of the solar receiver. Several prototype shapes were fabricated from Inconel 718 and tested in Sandia’s solar furnace at an irradiance of ~30 W/cm2. Photographic methods were used to capture the irradiance distribution on the receiver surfaces. The irradiance profiles were compared to results from raytracing models. The effective solar absorptance was also evaluated using the ray-tracing models. Results showed that relative to a flat plate, the new geometries could increase the effective solar absorptance from 86% to 92% for an intrinsic material absorptance of 86%, and from 60% to 73% for an intrinsic material absorptance of 60%.
聚光太阳能接收器由安装在塔顶的圆柱形或立方形的管板组成。这些管子含有传热流体,可以吸收集中在管子上的太阳光的能量。为了增加太阳能吸收率,在管的表面涂上黑色涂料或太阳能选择性涂层。然而,随着时间的推移,这些涂层会降解,必须重新涂抹,这会降低系统性能并增加成本。本文介绍了一种新型接收器形状和几何形状的评估,这种形状和几何形状可以产生光捕获效应,从而增加太阳能接收器的有效太阳能吸收率和效率。用Inconel 718制作了几个原型形状,并在桑迪亚的太阳炉中以~30 W/cm2的辐照度进行了测试。采用摄影方法捕捉了接收机表面的辐照度分布。辐照度曲线与射线追踪模型的结果进行了比较。利用射线追踪模型对有效太阳吸收率进行了评价。结果表明,相对于平板,当材料吸收率为86%时,有效吸收率从86%提高到92%;当材料吸收率为60%时,有效吸收率从60%提高到73%。
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引用次数: 11
Investigating photoluminescence quantum yield of silicon nanocrystals formed in SiOx with different initial Si excess 研究不同初始硅过量在SiOx中形成的硅纳米晶体的光致发光量子产率
Pub Date : 2015-09-04 DOI: 10.1117/12.2191105
Nguyen Xuan Chung, Rens Limpens, T. Gregorkiewicz
Optical properties of silicon nanocrystals dispersed in SiO2 matrix were investigated in terms of photoluminescence quantum yield at room temperature. Two multilayer samples, prepared from substoichiometric silicon oxide layers by annealing at 1150°C were used to investigate the influence of Si concentration. Significant reduction of photoluminescence quantum yield and a very specific change of its excitation energy dependence upon variation of silicon excess are concluded from the experimental data. Possible mechanisms leading to these changes are discussed.
从室温光致发光量子产率的角度研究了分散在SiO2基体中的硅纳米晶体的光学性质。采用亚化学计量氧化硅层在1150℃下退火制备了两个多层样品,研究了Si浓度的影响。实验数据表明,光致发光量子产率显著降低,激发能随硅过剩量的变化而变化。讨论了导致这些变化的可能机制。
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引用次数: 8
Analysis of metallic nanoantennas for solar energy conversion 用于太阳能转换的金属纳米天线分析
Pub Date : 2015-09-04 DOI: 10.1117/12.2188597
B. Mora Ventura, R. Díaz de León, G. Garcia-Torales, J. Flores, J. Alda, F. J. González
Recently thermo-electrical nanoantennas, also known as Seebeck nanoantennas, have been proposed as an alternative for solar energy harvesting applications. In this work we present the optical and thermal analysis of metallic nanoantennas operating at infrared wavelengths, this study is performed by numerical simulations using COMSOL Multiphysics. Several different nanoantenna designs were analyzed including dipoles, bowties and square spiral antennas. Results show that metallic nanoantennas can be tuned to absorb electromagnetic energy at infrared wavelengths, and that numerical simulation can be useful in optimizing the performance of these types of nanoantennas at optical and infrared wavelengths.
最近,热电纳米天线,也被称为塞贝克纳米天线,被提出作为太阳能收集应用的替代方案。在这项工作中,我们介绍了在红外波长下工作的金属纳米天线的光学和热分析,本研究通过COMSOL Multiphysics进行了数值模拟。分析了几种不同的纳米天线设计,包括偶极子天线、蝴蝶结天线和方形螺旋天线。结果表明,金属纳米天线可以调谐以吸收红外波长的电磁能量,并且数值模拟有助于优化这些类型的纳米天线在光学和红外波长的性能。
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引用次数: 2
On the road toward a hot carrier solar cell 在通往热载体太阳能电池的道路上
Pub Date : 2015-09-04 DOI: 10.1117/12.2190910
P. Taylor, J. Fields, R. Collins
We suggest a new paradigm for solar cells that uses a nanostructured crystalline collector (silicon) in an amorphous absorber matrix (hydrogenated amorphous silicon). Previously amorphous absorbers have received no serious consideration because of their low carrier mobilities. Specifically, we demonstrate that carriers generated in the amorphous region are transported out of this region before losing their energy to heat. This result establishes the possibility of using a wide range of nanostructured amorphous matrices to dramatically increase the efficiencies of solar cells. The use of an amorphous absorber provides a highly desirable and flexible approach to producing low-cost, hot carrier solar cells. Since amorphous materials can be grown over a much wider composition space than crystalline materials, this surprising result greatly broadens the absorbing materials that can be used to dramatically increase the efficiencies of solar cells.
我们提出了一种新的太阳能电池范例,即在非晶吸收基质(氢化非晶硅)中使用纳米结构晶体集热器(硅)。以前无定形吸收剂由于其载流子迁移率低而没有得到认真的考虑。具体来说,我们证明了在无定形区域产生的载流子在失去能量之前被输送出该区域。这一结果建立了使用广泛的纳米结构非晶矩阵来显著提高太阳能电池效率的可能性。非晶吸收剂的使用为生产低成本的热载流子太阳能电池提供了一种非常理想和灵活的方法。由于非晶材料可以生长在比晶体材料更宽的组成空间中,这一令人惊讶的结果大大拓宽了可用于大幅提高太阳能电池效率的吸收材料。
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引用次数: 0
Performance comparison of front-side silver pastes using polyalkylene carbonates for cleaner burning binder system 聚碳酸亚烯清洁燃烧粘结剂系统正面银浆性能比较
Pub Date : 2015-09-04 DOI: 10.1117/12.2189561
R. Stephenson, P. Ferraro
Clean-burning binder systems used in paste formulations for front side solar cell applications offer advantages of reduced residual carbon, improved conductive feature density, and overall performance and reliability. This paper presents the technical advantages of employing polyalkylene carbonates (QPAC®) as the principle binder for paste formulations used in front side solar screen printing applications. Thermal and rheological characteristics are presented and compared with standard or conventional pastes currently employed in production lines producing solar cell front side geometry. Microstructural comparisons of conductive features of the front side geometry are examined and related to aspects of adhesion performance and resistive losses.
清洁燃烧粘合剂系统用于粘贴配方的前端太阳能电池应用提供减少残余碳,提高导电特征密度,整体性能和可靠性的优点。本文介绍了采用聚碳酸乙烯酯(QPAC®)作为粘贴配方的主要粘合剂用于正面太阳能丝网印刷应用的技术优势。介绍了热学和流变学特性,并与目前在生产太阳能电池正面几何形状的生产线上使用的标准或传统浆料进行了比较。微观结构的比较导电特征的正面几何检查和相关的粘附性能和电阻损失方面。
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引用次数: 0
Organic photovoltaic devices with concurrent solar energy harvesting and charge storage capability 具有同步太阳能收集和电荷存储能力的有机光伏器件
Pub Date : 2015-09-04 DOI: 10.1117/12.2187671
A. Takshi, Tete Tevi, F. Rahimi
Due to large variation of the solar energy availability in a day, energy storage is required in many applications when solar cells are used. However, application of external energy storage devices, such as batteries and supercapacitors, increases the cost of solar energy systems and requires additional charging circuitry. This combination is bulky and relatively expensive, which is not ideal for many applications. In this work, a novel idea is presented for making electrochemical devices with dual properties of solar energy harvesting and internal charge storage. The device is essentially a supercapacitor with a photoactive electrode. Energy harvesting occurs through light absorption at one of the electrodes made of a composite of a conducting polymer (i.e. PEDOT:PSS) and a Porphyrin dye. The energy storage takes place in the both photoactive and counter electrode (CE). We have studied the effect of the CE material on the device characteristics. Using Y-Carbon (a commercial available electrode), an open circuit voltage of 0.49 V was achieved in light across the cell with ~1 mF capacitance. The other two choices for CE were activated carbon and carbon nanotube based electrodes. The cyclic voltammetry and impedance spectroscopy demonstrated that the Y Carbon electrode was a better match.
由于太阳能在一天内的可用性变化很大,在使用太阳能电池的许多应用中都需要能量存储。然而,外部能量存储设备的应用,如电池和超级电容器,增加了太阳能系统的成本,并需要额外的充电电路。这种组合既笨重又相对昂贵,对于许多应用来说并不理想。本文提出了一种制造具有太阳能收集和内部电荷存储双重特性的电化学器件的新思路。该装置本质上是一个带有光活性电极的超级电容器。能量收集通过其中一个电极的光吸收发生,该电极由导电聚合物(即PEDOT:PSS)和卟啉染料组成。能量储存发生在光活性电极和反电极(CE)中。我们研究了CE材料对器件特性的影响。使用Y-Carbon(一种商用电极),在电容为~ 1mf的电池上实现了0.49 V的开路电压。CE的另外两种选择是活性炭和碳纳米管电极。循环伏安法和阻抗谱法表明,Y碳电极具有较好的匹配性。
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引用次数: 4
Ultrafast time-resolved spectroscopy of lead halide perovskite films 卤化铅钙钛矿薄膜的超快时间分辨光谱
Pub Date : 2015-09-04 DOI: 10.1117/12.2187714
M. Idowu, S. Yau, O. Varnavski, T. Goodson
Recently, lead halide perovskites which are organic-inorganic hybrid structures, have been discovered to be highly efficient as light absorbers. Herein, we show the investigation of the excited state dynamics and emission properties of non-stoichiometric precursor formed lead halide perovskites grown by interdiffusion method using steady-state and time-resolved spectroscopic measurements. The influence of the different ratios of the non-stoichiometric precursor solution was examined. The observed photoluminescence properties were correlated with the femtosecond transient absorption measurements.
近年来,人们发现卤化铅钙钛矿是一种有机-无机杂化结构,是一种高效的光吸收剂。本文采用稳态和时间分辨光谱测量方法,研究了用互扩散法生长的卤化铅钙钛矿的非化学计量前驱体的激发态动力学和发射特性。考察了不同比例的非化学计量前驱体溶液的影响。观察到的光致发光特性与飞秒瞬态吸收测量值相关。
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引用次数: 0
Photochemical upconversion of light for renewable energy and more 光化学上转换光为可再生能源等
Pub Date : 2015-09-04 DOI: 10.1117/12.2195424
T. Schmidt, Rowan W. MacQueen
Photochemical upconversion has been put forward as a candidate technology to improve the light-harvesting capabilities of thin-film photovoltaic cells, by harvesting transmitted sub-bandgap light and re-radiating the absorbed energy at a usable wavelength. Efficiencies of 10% have been observed under solar-level irradiation, and up to 86% (quantum yield of 43%) has been observed under strong irradiance. In this proceeding, we explain the triplet-triplet annihilation mechanism underlying photochemical upconversion and delve into the chemical kinetics to extract strategies to improve device performance. We suggest that one of these strategies, concentrating the sensitizer species, may be flawed without proper consideration of the sensitizer identity, due to enhanced emitter triplet decay caused by the external heavy atom effect.
光化学上转换已被提出作为提高薄膜光伏电池光捕获能力的候选技术,通过收集透射的亚带隙光并将吸收的能量以可用波长重新辐射。在太阳辐照水平下观察到效率为10%,在强辐照下观察到效率高达86%(量子产率为43%)。在这一过程中,我们解释了光化学上转换背后的三重态-三重态湮灭机制,并深入研究了化学动力学,以提取提高器件性能的策略。我们认为,由于外部重原子效应导致发射极三重态衰变增强,在没有适当考虑敏化剂特性的情况下,集中敏化剂可能存在缺陷。
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引用次数: 3
Effect of size and composition fluctuations on the luminescent properties of ensemble of InGaAs nano-objects 尺寸和组成波动对InGaAs纳米物体系综发光性能的影响
Pub Date : 2015-09-04 DOI: 10.1117/12.2183491
A. Yakovliev, Roman Holubenko
The luminescent properties of InGaAs/GaAs heterostructures with InGaAs nanoscale objects were investigated. Multilayer heterostructures were grown using molecular beam epitaxy technique. The shapes of the photoluminescence spectra were studied in the temperature range from 10 K to 290 K. The electronic spectrum of heterosystems as well as the energy of interband transitions for InGaAs nano-objects were calculated for different sizes and InGaAs component composition. It is shown that the shape of the photoluminescence spectra is determined by the Gaussian distribution of the energy of band-to-band optical transitions between the ground states of the conduction band and valence band of nanoscale objects. The physical reason for the observed energy dispertion is the variation of sizes, heterogeneity of component composition and strain relief in the ensemble of InGaAs nano-objects. Non-monotonous temperature dependence of the width of the photoluminescence spectra indicates the existence of temperature-dependent redistribution of photoexcited charge carriers between neighbouring nanoislands having different energy of the ground states.
研究了InGaAs/GaAs异质结构与InGaAs纳米材料的发光特性。采用分子束外延技术生长了多层异质结构。在10 ~ 290 K的温度范围内,研究了其光致发光光谱的形状。计算了不同尺寸和InGaAs组分组成下InGaAs纳米物体的异质体系电子能谱和带间跃迁能量。结果表明,光致发光光谱的形状是由纳米物体的导带基态和价带基态之间的带间光学跃迁能量的高斯分布决定的。观察到的能量分散的物理原因是InGaAs纳米物体系综中尺寸的变化、成分的非均质性和应变的释放。光致发光光谱宽度的非单调温度依赖性表明,具有不同基态能量的相邻纳米岛之间存在光激发载流子的温度依赖性再分布。
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引用次数: 0
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SPIE Optics + Photonics for Sustainable Energy
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