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ELECTROLYSIS OF GRANULATED COPPER-NICKEL MATTE 粒状铜镍锍的电解
Pub Date : 2018-10-13 DOI: 10.17073/0021-3438-2018-5-16-22
O. V. Nechvoglod, S. Sergeeva, K. Pikulin, E. Selivanov
The paper justifies the method of processing sulfide-metal melts including their granulation and subsequent electrolysis of granules. High-speed crystallization ensures ultrafine structure formation and stabilizes non-stoichiometric high-temperature phases leading to an increase in the reactivity of granules during subsequent hydrometallurgical processing. Copper powder was isolated at the cathode, and sulfur-sulfide slime (NiS–Сu9S5–Cu7S4–S) was isolated at the anode in a sulfuric acid solution during the electrolysis of granular copper-nickel matte (Cu : Ni = 1 : 1). The influence of current density and process duration on electrolysis parameters and the quality of copper powder isolated was estimated. Sulfur sulfide slime (containing more than 50 % sulfur) forms a passivation layer on granule surfaces, which prevents reagent feeding and reaction product removal from the interaction zone. Anodic current density of up to 100 A/m2 ensures metal conversion into a solution and copper powder (PMS-1 grade) formation at the cathode. Powder is represented by 1 to 100 μm particles of dendritic and fragmented shapes. High-quality copper powder isolation was achieved when saturating electrolyte with nickel to 28,0 g/dm3 . In this case, anode efficiency was 37 % with respect to sulfur, and cathode efficiency was 92,8 % for copper. The process is recommended for copper and nickel separation when processing sulfide-metal alloys. Copper content of in the solution during electrolysis ranged from 0,4 to 2,0 g/dm3.
本文论证了硫化金属熔体的加工方法,包括其造粒和随后的颗粒电解。高速结晶确保了超细结构的形成,并稳定了非化学计量高温相,从而在随后的湿法冶金处理中提高了颗粒的反应性。在硫酸溶液中电解颗粒状铜镍锍(Cu: Ni = 1:1),阴极分离铜粉,阳极分离硫硫泥(NiS -Сu9S5-Cu7S4-S),考察了电流密度和工艺时间对电解参数和分离铜粉质量的影响。硫硫化泥(含硫超过50%)在颗粒表面形成钝化层,阻止了试剂的进料和反应产物从相互作用区去除。阳极电流密度高达100 A/m2,确保金属转化为溶液,并在阴极形成铜粉(PMS-1级)。粉末以1 ~ 100 μm的树枝状和碎片状颗粒为代表。当电解液中镍饱和至28,0 g/dm3时,实现了高质量的铜粉隔离。在这种情况下,阳极效率相对于硫为37%,阴极效率为92,8 %的铜。在加工硫化金属合金时,推荐采用该工艺分离铜镍。电解过程中溶液中铜的含量为0.4 ~ 2.0 g/dm3。
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引用次数: 1
TO THE 100TH ANNIVERSARY OF THE BIRTH OF SERGEI IVANOVICH KUZNETSOV 为谢尔盖·伊万诺维奇·库兹涅佐夫诞辰100周年干杯
A. Editorial
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引用次数: 0
SIMULATION OF FINAL DIRECT EXTRUSION STAGE FOR LARGE RODS WITH LOW EXTRUSION RATIO 低挤压比大棒材最终直接挤压阶段的模拟
Pub Date : 2018-10-13 DOI: 10.17073/0021-3438-2018-5-48-55
V. Kargin, A. Y. Deryabin
The direct extrusion of large 7075 alloy bars 188, 214, 252, 283, 326, 560 mm in diameter was simulated with 0 and 0,5 friction coefficients, 80° and 90° die cone angles from the 800 mm diameter container at the 200 MN press using the DEFORM-2D software package. It provided the distribution of metal flow radial velocities on the dummy block working surface versus the contact friction value, die cone angle and extrusion ratio factor at the main and final stages of extrusion. Butt-end height at the beginning of back-end extrusion defect formation was taken equal to a distance between the dummy block plane and the plane of extruded metal feeding into flat or cone die openings. The joint effect of the extrusion ratio factor, friction coefficient and die cone angle on the butt-end height, extrusion force, deformation and stress intensity factors, and die opening edge temperature was studied. Numerical experiments were performed based on the 23 complete factorial design for the following parameter variability intervals: Х1 = 3÷9, Х2 = 0÷0,5, Х3 = 80÷90°. Friction between the tool and the blank at the final extrusion stage has a negative effect due to a noticeable radial velocity reduction. This leads to the earlier initiation of central back-end extrusion defect formation. Extrusion into the conical die and increasing the extrusion ratio factor, on the contrary, speeds up radial flow velocity and ensures that the back-end extrusion defect starts forming later. The main factor that determines butt-end height is the extrusion ratio factor. A mathematical model is proposed to select the butt-end thickness for specific conditions of extruding large bars with low extrusion ratios.
利用DEFORM-2D软件包,对直径为188,214,252,283,326,560 mm的7075合金棒材在200 MN压力机上,以0和0.5摩擦系数,80°和90°的模锥角从直径为800 mm的容器中直接挤压进行了模拟。给出了在挤压主、末阶段金属流径向速度与接触摩擦值、模锥角、挤压比系数的关系。后端挤压缺陷形成开始时的对端高度等于虚拟块平面与挤压金属进入平模或锥模开口的平面之间的距离。研究了挤压比系数、摩擦系数和模锥角对对端高度、挤压力、变形和应力强度因素以及开模边缘温度的联合影响。数值试验采用23全因子设计,参数变异区间为Х1 = 3÷9, Х2 = 0÷0,5, Х3 = 80÷90°。在最后的挤压阶段,由于径向速度明显降低,工具和毛坯之间的摩擦产生了负面影响。这导致中心后端挤压缺陷形成较早。挤压进锥形模具,增大挤压比系数,反而加快了径向流动速度,保证了后端挤压缺陷开始成形较晚。决定顶端高度的主要因素是挤压比因素。针对低挤压比大棒材挤压的具体情况,提出了选择顶端厚度的数学模型。
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引用次数: 0
SOME ASPECTS OF INFLUENCE EXERTED BY LARGE-SCALE EFFECT NATURE AT CYCLIC TESTS ON OPERATION AND RELIABILITY OF ALUMINUM ALLOY PRODUCTS 循环试验中大规模效应性质对铝合金产品运行和可靠性的影响
Pub Date : 2018-10-13 DOI: 10.17073/0021-3438-2018-5-56-65
E. Chernyshov, A. Romanov, V. V. Mylnikov
The article describes a study into the large-scale effect and properties of surface layers of solids in case of the Al–Mg system (AMg2) aluminum alloy. It demonstrates the dependence of surface layer properties on the absolute sizes of bodies. The conclusions obtained can be extended to studying the influence of different shapes of solids on their surface and linear bulk properties. New technology development and technological advance constantly toughen metal consumption requirements of engineering devices thus making it rather difficult to avoid fatigue striations and cracks forming in critical parts. In certain cases they may form at the earliest stages of operation, i.e. parts run with cracks most of their life cycle. Therefore, comprehensive assessment of their performance and life requires reliable data on the evolution of cyclic strength and durability parameters, and maximum information on the process of damage accumulation at all stages of fatigue loading: stages of crack origin and development leading to structural failure. Therefore, the need to improve the methods of fatigue testing and failure pattern detection is one of the most relevant problems of technical advance. It is established that the difference in deformation at a surface leads to changes in work-hardenability that involves changes in surface damageability and strength performance of samples. An approach to the large-scale effect as a phenomenon is considered from the perspective of the difference in surface layer plastic deformation for samples of different absolute sizes.
本文研究了Al-Mg系(AMg2)铝合金表面固体层的大规模效应和性能。它证明了表面层性质对物体绝对尺寸的依赖性。所得结论可推广到研究不同形状固体对其表面和线性体积性能的影响。新技术的发展和技术的进步不断提高了工程装置对金属的消耗要求,使得在关键部件上很难避免疲劳条纹和裂纹的形成。在某些情况下,裂纹可能在操作的最初阶段形成,即零件在其生命周期的大部分时间里都带着裂纹运行。因此,对其性能和寿命的综合评估需要可靠的循环强度和耐久性参数演变数据,以及在疲劳加载的各个阶段(裂纹产生和发展导致结构破坏的阶段)损伤积累过程的最大信息。因此,需要改进疲劳试验和失效模式检测方法是技术进步中最相关的问题之一。研究表明,表面变形的差异会导致加工淬透性的变化,而加工淬透性的变化涉及到试样的表面损伤性和强度性能的变化。从不同绝对尺寸试样的表面层塑性变形差异的角度考虑了大尺度效应作为一种现象的途径。
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引用次数: 8
PREDICTION OF AZ91 CASTING MISRUNS AND ALLOY FLUIDITY USING NUMERICAL SIMULATION az91铸造失误及合金流动性的数值模拟预测
Pub Date : 2018-10-13 DOI: 10.17073/0021-3438-2018-5-31-38
A. Petrova, V. Bazhenov, A. Koltygin
Prediction of the misrun formation in thin-walled castings of magnesium alloys is a crucial task for foundry. The computer simulation of the casting processes can be used to solve this problem. A reasonable simulation results requires the correct thermal properties of the alloy and the mold over a wide range of temperatures and the value of interfacial heat transfer coefficient between the casting and the mold, and the critical solid fraction at which the alloy flow in the mold is choked off. In this paper we determine the interfacial heat transfer coefficient between the magnesium alloy ML5 (AZ91) and the sand mold with a furan binder. It was done by the comparing the simulated spiral test lengths with the experimental spiral test lengths obtained under the same conditions. Above the liquidus temperature the interfacial heat transfer coefficient IHTCL = 1500 W/(m2 ·K) at pouring temperatures 670 and 740 °С and IHTCL = 1800 W/(m2 ·K) at pouring temperature 810 °С. Below the solidus temperature the interfacial heat transfer coefficient IHTCS = 600 W/(m2 ·K). We also determined the critical solid fraction of ML5 (AZ91) magnesium alloy for the casting made in the furan bonded sand mold (at a cooling rate ~2 K/s) and it was 0.1–0.15. We compared the simulated misruns position and the experimental misrun position in the «Protective cup» casting produced from the ML5 (AZ91) alloy into the sand mold with furan binder. The value of the critical solid fraction was clarified. The castings were made at pouring temperatures 630 and 670 °C, and the critical solid fraction was 0.1 in both cases.
镁合金薄壁铸件失稳形成的预测是铸造行业的一项重要任务。铸造过程的计算机模拟可以解决这一问题。合理的模拟结果要求在较宽的温度范围内合金和模具的热性能、铸件与模具之间的界面传热系数值以及合金在模具中流动被阻塞的临界固相分数正确。采用呋喃粘结剂测定了镁合金ML5 (AZ91)与砂型之间的界面传热系数。将模拟的螺旋试验长度与相同条件下的实验螺旋试验长度进行比较。在液相温度以上,浇注温度670°和740°С时界面换热系数IHTCL = 1500 W/(m2·K),浇注温度810°С时界面换热系数IHTCL = 1800 W/(m2·K)。在固相温度以下,界面换热系数IHTCS = 600 W/(m2·K)。在冷却速度~2 K/s的情况下,确定了呋喃粘接砂型铸造用ML5 (AZ91)镁合金的临界固相分数为0.1 ~ 0.15。用呋喃粘结剂对ML5 (AZ91)合金生产的“保护杯”铸件在砂型内的模拟失稳位置和实验失稳位置进行了比较。澄清了临界固相分数的取值。浇注温度分别为630℃和670℃,临界固相分数均为0.1。
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引用次数: 0
STUDY INTO STRUCTURAL EVOLUTION OF TWO-PHASE TITANIUM ALLOY DURING THERMAL DEFORMATION PROCESSING 热变形过程中两相钛合金组织演变的研究
Pub Date : 2018-10-13 DOI: 10.17073/0021-3438-2018-5-66-71
A. Churyumov, V. V. Spasenko, D. M. Hazhina, A. Mikhaylovskaya, A. Solonin, A. Prosviryakov
This paper studies Ti–3,5Fe–4Cu–0,2B two-phase titanium alloy behavior during its thermal deformation processing under uniaxial compression. Boron was added to obtain a fine-grained structure in the cast state. Samples of alloys 6 mm in diameter were obtained by melting pure components in a vacuum induction furnace with their subsequent crystallization into a solid copper mold. Uniaxial compression tests with a true strain of 0,9 were performed using the Gleeble 3800 thermal-mechanical physical simulation system at 750, 800 and 900 °C and strain rates of 0,1; 1 and 10 s–1. Scanning electron microscopy was used to study the microstructure of the alloy in its initial and deformed states. A model of flow stress dependence on temperature and strain rate was built as a result of the tests. It is shown that pressure treatment involves recrystallization of the initial cast structure containing solid solutions based on α-Ti, β-Ti and titanium diboride aggregates. During the deformation process, the volume fraction of α-titanium solid solution grains decreases with rising temperature, and the fraction of the β phase, on the contrary, increases. In this case, the average grain size of solid solutions based on α-Ti and β-Ti varies insignificantly after deformation in almost all of the studied modes. It is shown that the preferred mode of hot pressure treatment for obtaining a high complex of mechanical properties in the investigated alloy is a temperature range of 750– 800 °C, since α-phase grain sizes increase from 2,2 to 4,5 μm with an increase in temperature to 900 °C.
本文研究了Ti-3, 5Fe-4Cu-0,2B两相钛合金在单轴压缩热变形过程中的行为。在铸态中加入硼以获得细晶组织。通过在真空感应炉中熔化纯组分并将其随后结晶到固体铜模中,获得了直径为6 mm的合金样品。采用Gleeble 3800热-机械物理模拟系统,在750、800和900℃下,应变率为0,1,进行了真应变为0,9的单轴压缩试验;1和10s - 1。采用扫描电子显微镜对合金初始态和变形态的显微组织进行了研究。根据试验结果,建立了流动应力随温度和应变速率变化的模型。结果表明,压力处理使含有α-Ti、β-Ti和二硼化钛等固溶体的初铸组织发生再结晶。变形过程中,α-钛固溶体晶粒体积分数随温度升高而减小,β相体积分数相反增大。在这种情况下,α-Ti和β-Ti固溶体在变形后的平均晶粒尺寸变化不大。结果表明:在750 ~ 800℃的温度范围内,α相晶粒尺寸从2,2 μm增大到4,5 μm,可以获得较高的复合力学性能;
{"title":"STUDY INTO STRUCTURAL EVOLUTION OF TWO-PHASE TITANIUM ALLOY DURING THERMAL DEFORMATION PROCESSING","authors":"A. Churyumov, V. V. Spasenko, D. M. Hazhina, A. Mikhaylovskaya, A. Solonin, A. Prosviryakov","doi":"10.17073/0021-3438-2018-5-66-71","DOIUrl":"https://doi.org/10.17073/0021-3438-2018-5-66-71","url":null,"abstract":"This paper studies Ti–3,5Fe–4Cu–0,2B two-phase titanium alloy behavior during its thermal deformation processing under uniaxial compression. Boron was added to obtain a fine-grained structure in the cast state. Samples of alloys 6 mm in diameter were obtained by melting pure components in a vacuum induction furnace with their subsequent crystallization into a solid copper mold. Uniaxial compression tests with a true strain of 0,9 were performed using the Gleeble 3800 thermal-mechanical physical simulation system at 750, 800 and 900 °C and strain rates of 0,1; 1 and 10 s–1. Scanning electron microscopy was used to study the microstructure of the alloy in its initial and deformed states. A model of flow stress dependence on temperature and strain rate was built as a result of the tests. It is shown that pressure treatment involves recrystallization of the initial cast structure containing solid solutions based on α-Ti, β-Ti and titanium diboride aggregates. During the deformation process, the volume fraction of α-titanium solid solution grains decreases with rising temperature, and the fraction of the β phase, on the contrary, increases. In this case, the average grain size of solid solutions based on α-Ti and β-Ti varies insignificantly after deformation in almost all of the studied modes. It is shown that the preferred mode of hot pressure treatment for obtaining a high complex of mechanical properties in the investigated alloy is a temperature range of 750– 800 °C, since α-phase grain sizes increase from 2,2 to 4,5 μm with an increase in temperature to 900 °C.","PeriodicalId":14523,"journal":{"name":"Izvestiya Vuzov Tsvetnaya Metallurgiya (Proceedings of Higher Schools Nonferrous Metallurgy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87039292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
EFFECT OF CAPILLARY PRESSURE IN NANOBUBBLES ON THEIR ADHERENCE TO PARTICLES DURING FROTH FLOATATION. PART 6. INFORMATIVITY OF BUBBLE SPREADING CURVES 泡沫浮选过程中纳米气泡中毛细压力对其粘附颗粒的影响。第6部分。气泡扩散曲线的信息性
V. I. Melik-Gaikazyan, N. P. Emel’yanova, D. V. Dolzhenkov
Spreading curves (SCs) are calculated for bubble diameters (de) 1 mm and 1 μm on substrates with different wettability: from maximumhydrophobicity (Г) to maximum-hydrophilicity (Ф) as well as incompletely wettable (Нх) ones, where x = 0,8; 0,6; 0,4 and 0,2 is the fraction of an ionized collector monolayer under the bubble. The calculations were based on the results of a numerical solution of the Laplace equation in the form of 12-figure tables such as Bashforth and Adams tables. They demonstrate firstly that the SCs obtained are identical to those calculated for bubbles with de = 20 and 10 nm, and thus SC shapes are unchanged in the 105 range, i.e. virtually for all flotation bubbles, and secondly that SC shapes and their mutual arrangement depend on substrate wettability. Spreading curves clearly illustrate the advantages of substrate Г adhesion to the bubble in comparison with substrate Ф, and for Нх an advantage of the substrate with a larger fraction of x. It is quantitatively shown that even with small spreading of nanobubbles adhered to the particle, their adherence force increases billion times so that large bubbles can fix on their increased perimeters and lead the particle to flotation. If, however, the adhesion of large bubbles to nanobubbles occurs before spreading of the latter, they will come off together, and the particle will not float. This mechanism was used for particle flotation in the processes of the Bessel brothers, Potter-Delpra and two processes of F. Elmor in the late 19th and early 20th centuries. The prospect of increasing the productivity and cost-efficiency of modern froth flotation by activating particle flotation not only with nanobubbles but also with larger bubbles is considered.
计算了不同润湿性衬底上气泡直径(de)为1 mm和1 μm时的扩散曲线(SCs):从最大疏水性(Г)到最大亲水性(Ф)以及不完全可湿性(Нх)衬底,其中x = 0,8;0, 6;0,4和0,2是气泡下电离收集器单层的分数。这些计算是基于拉普拉斯方程的数值解的结果,以Bashforth和Adams表格等12位数表格的形式进行的。他们首先证明,得到的SC与de = 20和10 nm的气泡计算的SC相同,因此SC形状在105范围内不变,即几乎适用于所有浮选气泡;其次,SC形状及其相互排列取决于衬底的润湿性。铺展曲线清楚地说明了底物Г与底物Ф相比,与底物Ф相比,底物Нх具有较大x分数的优势。定量表明,即使纳米气泡粘附在颗粒上的铺展很小,其粘附力也会增加十亿倍,从而使大气泡能够固定在其增加的周长上,并导致颗粒浮选。然而,如果在纳米气泡扩散之前,大气泡与纳米气泡发生了粘附,它们就会一起脱落,颗粒就不会漂浮。在19世纪末和20世纪初,贝塞尔兄弟、波特-德尔普拉和F.埃尔莫尔的两个过程中都使用了这种机制来进行颗粒浮选。展望了利用纳米气泡和更大气泡激活颗粒浮选提高现代泡沫浮选生产效率和成本效益的前景。
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引用次数: 0
STUDY INTO CARBOTHERMIC METHOD OF TITANIUM RAW MATERIAL DECOMPOSITION IN CASE OF ARTIFICIALLY SYNTHESIZED PEROVSKITE 研究了人工合成钙钛矿情况下钛原料的碳热分解方法
Pub Date : 2018-10-12 DOI: 10.17073/0021-3438-2018-5-23-30
O. N. Budin, A. Kropachev, D. G. Agafonov, V. V. Сherepov
The article states the advantages of carbothermic perovskite concentrate decomposition in comparison with hydrometallurgical methods. The papers using the carbothermic method are noted. The paper provides information on existing perovskite processing methods that found no industrial application. The results obtained when studying titanium raw material decomposition in case of CaO·TiO2 artificially synthesized perovskite are given. Artificial perovskite was synthesized in a muffle furnace where a mixture of oxides (CaO = 41,2 wt.% and TiO2 = 58,8 wt.%) was premixed for 15 minutes and then briquetted into pellets using a 15 mm steel mold on a 147 МPa hydraulic press. The temperature of CaTiO3 synthesis was 1300 °C with a holding time of 4 hours. Experiments with a different carbon excess (20 and 30 wt.% of the content stoichiometrically required to recover perovskite components) were carried out. The carbothermic process of artificial perovskite decomposition (4 g pellets) was carried out in a vacuum furnace with a graphite heater in two stages: at 1500 °C, 1 hour holding time and 10,1 kPa residual pressure in an argon atmosphere at the first stage, and at t = 1750 °C, τ = 1 h, 1,3 Pa residual chamber pressure at the second one. Reaction products were studied by X-ray diffraction analysis on the «D8 Advance Bruker AXS» diffractometer. Experimental results demonstrated the practical possibility of titanium and calcium extraction from perovskite using the carbothermic method.
本文阐述了碳热法分解钙钛矿精矿与湿法冶金法的优越性。对采用碳热法的论文进行了评述。本文提供了没有工业应用的现有钙钛矿加工方法的信息。给出了在CaO·TiO2人工合成钙钛矿的情况下,研究钛原料分解的结果。人工钙钛矿是在马弗炉中合成的,其中氧化物(CaO = 41,2 wt.%和TiO2 = 58,8 wt.%)的混合物预混15分钟,然后在147 МPa液压机上使用15 mm钢模具压块成球团。合成CaTiO3的温度为1300℃,保温时间为4小时。实验采用不同的碳过量(20和30 wt.%的含量的化学计量要求回收钙钛矿成分)进行。在带石墨加热器的真空炉中进行了人工钙钛矿(4 g球团)的碳热分解过程,分两个阶段进行:第一步在1500℃、保温时间1 h、残余压力10.1 kPa的氩气环境中进行,第二期在t = 1750℃、τ = 1 h、残余腔压1.3 Pa的条件下进行。用D8 Advance Bruker AXS衍射仪对反应产物进行了x射线衍射分析。实验结果证明了碳热法从钙钛矿中提取钛和钙的可行性。
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引用次数: 1
STUDY INTO STRUCTURE AND PROPERTIES OF SOLDERS BASED ON ALUMINUM AND ZINC IN THE FORM OF SMALL-SECTION CAST BARS 研究了铝锌基小截面铸钢焊料的组织和性能
Pub Date : 2018-10-12 DOI: 10.17073/0021-3438-2018-5-39-47
K. Nikitin, I. Timoshkin, V. I. Nikitin
The study covers Al–Cu–Si (A34 grade) and Zn–Al–Cu (Welco52 grade) solders. It is found that A34 solder (Al–28%Cu–6%Si) melts and crystallizes in a narrow range of temperatures (~18 °C). Solidus and liquidus temperatures of A34 solder are ~508 °С and ~526 °С, respectively. Zn–Al–Cu (Zn–4%Al–2,5% Cu) solder has a eutectic composition, so it melts and crystallizes at a constant temperature of ~389 °С. Densities of investigated solders in their liquid and solid states are studied. A34 solder has a density of 3,02 and 3,32 g/cm3 , respectively. Zinc solder density is 6,28 g/cm3 in the liquid state, and 6,69 g/cm3 in the solid state. The influence of casting conditions on the structure of cast alloys in the form of bars with cross sections of 13, 10, and 5 mm2 was investigated. Main structural components of solder alloys reduce in size as cross sections decrease. The aluminium-based solid solution dendrites and CuAl2 phase are reduced in the A34 solder microstructure. In zinc solders, the most severely reduced ones are zinc-based solid solution dendrites. The best castability is observed in melts obtained from 5 mm2 section bar solders with studied sample gaps of 2,0, 1,5 and 1,0 mm. Eutectic zinc solder features better castability in comparison with A34: castability of the melt obtained from the 5 mm2 section zinc solder rod with a sample gap width of 2,0 mm is 100 % (for A34 melt solder obtained from a rod of the same cross section it was 98 %). Experiments on soldering AK12 alloy plates and 3003 alloy sheets demonstrated that there is a tight border in the solder/base material system and no any defects such as pores or unsoldered areas. There was a slight interpenetration of solder alloys into base materials, especially when soldering AK12 cast plates.
该研究涵盖了Al-Cu-Si (A34级)和Zn-Al-Cu (Welco52级)焊料。结果表明,A34焊料(Al-28%Cu-6%Si)在较窄的温度范围(~18℃)内熔融结晶。A34焊料的固相温度和液相温度分别为~508°С和~526°С。Zn-Al-Cu (zn - 4% al - 2.5% Cu)焊料具有共晶成分,因此在~389°С恒温下熔化结晶。研究了所研究的焊料在液态和固态下的密度。A34焊料的密度分别为3.02和3.32 g/cm3。液态锌焊料密度为6.28 g/cm3,固态锌焊料密度为6.69 g/cm3。研究了铸造条件对13、10和5 mm2棒状合金组织的影响。焊料合金的主要结构部件的尺寸随着截面的减小而减小。在A34焊料组织中,铝基固溶体枝晶和CuAl2相减少。在锌焊料中,还原最严重的是锌基固溶体枝晶。最好的浇注性是在5mm2的棒材焊料中获得的熔体,所研究的样品间隙为2,0,1,5和1,0 mm。与A34相比,共晶锌焊料具有更好的浇注性:从样品间隙宽度为2,0 mm的5mm2截面锌焊料棒中获得的熔体浇注性为100%(从相同横截面的棒中获得的A34熔体焊料为98%)。焊接AK12合金板和3003合金板的实验表明,焊料/基材系统边界紧密,没有气孔或未焊区等缺陷。焊料合金在基材中有轻微的相互渗透,特别是在焊接AK12铸板时。
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引用次数: 0
THE EFFECT OF DIALKYLDITHIOPHOSPHATE REAGENTS ON COPPER FLOTATION FROM PYRITIC SLAGS 二烷基二硫代磷酸盐药剂对黄铁矿渣浮选铜的影响
M. N. Sabanova, N. Orekhova, O. Gorlova, I. Glagoleva
The paper studies the patterns of copper slag mineral phase separation by flotation depending on the modification of the additional BTF series collecting agent (dialkyldithiophosphate derivatives) and the ratio of main and additional collecting agent consumptions. The results of open and locked-cycle laboratory flotation tests are presented, and the effect of pulp pH on copper extraction is observed. The reasons for the copper extraction gain during grinding and subsequent flotation in acidic medium are analyzed. The aggregates of copper and iron sulfides are identified in slags thus proving decoppering effectiveness with a decrease in pH to slightly acidic values due to the active flotation of intergrown pieces of copper-containing phases with iron sulfide (pyrite, pyrrhotine). It is shown that the additional BTF series collecting agent added to the main collecting agent – potassium butyl xanthate – makes it possible to reduce the total consumption of the combined collecting agents while maintaining copper extraction and concentrate quality as compared to the consumption of only xanthate necessary to achieve the same parameters. The best results were achieved with the use of the BTF 1614 reagent in combination with potassium butyl xanthate at the BCC : BTF = 3 : 1 ratio. At an optimum pH = 5,5÷6,8, the increase in copper extraction to the concentrate was 11.13%, and gold and silver extraction increased by 9.68% and 9.93%, respectively.
通过对BTF系列附加捕收剂(二烷基二硫代磷酸盐衍生物)的改性,以及主捕收剂用量与附加捕收剂用量的比例,研究了铜渣矿物浮选分相模式。介绍了室内开、锁循环浮选试验结果,并观察了矿浆pH对铜浸出的影响。分析了酸性介质中磨矿和浮选过程中铜浸出增益的原因。在炉渣中发现了铜和铁的硫化物集合体,从而证明了脱铜的有效性,由于含铜相与硫化铁(黄铁矿、磁黄铁矿)的共生块的主动浮选,pH值降低到微酸性值。结果表明,在主捕收剂丁基黄药钾的基础上添加BTF系列捕收剂,与仅使用黄药达到相同的参数相比,可以在保持铜萃取和精矿质量的同时减少组合捕收剂的总消耗。BTF - 1614试剂与丁基黄药钾以BCC: BTF = 3:1的比例配用,效果最佳。在最佳pH = 5、5÷6、8时,精矿铜提取率提高了11.13%,金、银提取率分别提高了9.68%和9.93%。
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Izvestiya Vuzov Tsvetnaya Metallurgiya (Proceedings of Higher Schools Nonferrous Metallurgy
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