Pub Date : 2019-01-01DOI: 10.22050/IJOGST.2018.139168.1464
A. M. Ghahfarrokhi, E. Kazemzadeh, H. Behbahani, G. Safian
In matrix acidizing operations, the main goal is increasing permeability. For production engineers, it is desirable that acid could be injected into whole [M.N.1] [amehri.gh2] pay zone. Sometimes, this pay zone has a long height and various sub-layers which have different permeability values. To prevent acid from going completely into the most permeable sub-layer, one of the useful techniques is using diverters, and one of the major groups of diverters is gel diverters. Diverter viscosity changes by temperature and pH, and an increase in viscosity leads to a decrease in its permeability; thus, acid can permeate further through less permeable sub-layers. In this study, two kinds of different viscoelastic surfactants (VES) provided by two different companies were used to produce gel to divert acid into a core plug sample having lower permeability in a dual parallel acid injection set-up. The core plug samples were taken from the pay zone of Ahwaz oilfield, one of Iran southwest oilfields. Before performing the injection test, some viscosity measurement tests were carried out. Unfortunately, one of these two VES’s did not have an acceptable quality and failed to pass the injection tests. However, the other one passed all the tests successfully and diverted the injection fluid. The water permeability values of the low-perm and high-perm core plug samples were 0.91 md and 6.4 md respectively, whereas, after injection, they rose to 1.5 and 18.5 md respectively.
{"title":"An Experimental Study of Acid Diversion by Using Gelled Acid Systems Based on Viscoelastic Surfactants: A Case Study on One of Iran Southwest Oilfields","authors":"A. M. Ghahfarrokhi, E. Kazemzadeh, H. Behbahani, G. Safian","doi":"10.22050/IJOGST.2018.139168.1464","DOIUrl":"https://doi.org/10.22050/IJOGST.2018.139168.1464","url":null,"abstract":"In matrix acidizing operations, the main goal is increasing permeability. For production engineers, it is desirable that acid could be injected into whole [M.N.1] [amehri.gh2] pay zone. Sometimes, this pay zone has a long height and various sub-layers which have different permeability values. To prevent acid from going completely into the most permeable sub-layer, one of the useful techniques is using diverters, and one of the major groups of diverters is gel diverters. Diverter viscosity changes by temperature and pH, and an increase in viscosity leads to a decrease in its permeability; thus, acid can permeate further through less permeable sub-layers. In this study, two kinds of different viscoelastic surfactants (VES) provided by two different companies were used to produce gel to divert acid into a core plug sample having lower permeability in a dual parallel acid injection set-up. The core plug samples were taken from the pay zone of Ahwaz oilfield, one of Iran southwest oilfields. Before performing the injection test, some viscosity measurement tests were carried out. Unfortunately, one of these two VES’s did not have an acceptable quality and failed to pass the injection tests. However, the other one passed all the tests successfully and diverted the injection fluid. The water permeability values of the low-perm and high-perm core plug samples were 0.91 md and 6.4 md respectively, whereas, after injection, they rose to 1.5 and 18.5 md respectively.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"43 1","pages":"32-46"},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87259008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-01-01DOI: 10.22050/IJOGST.2018.119136.1441
A. Jafari, Peyman Sadirli, Reza Gharibshahi, E. K. Tooseh, Masoud Samivand, A. Teymouri
Natural gas storage process in aquifer, due to fluid flow behavior of gas and water in the porous medium and because of their contact with each other under reservoir conditions, faces several challenges. Therefore, there should be a clear understanding of the injected gas behavior before and after the injection into the reservoir. This research simulates the natural gas storage in aquifer by using Eclipse 300 software. For this purpose, a core sample was considered as the porous medium for gas injection, and a composition of natural gas was injected into the core in different conditions. Moreover, by using Plackett-Burman method, all of the factors affected in this process were screened, and finally four main significant parameters, including the flow rate of injected gas, permeability, pressure, and irreducible water saturation were selected for designing a design of experiments (DOE) plan. Response surface method (RSM) is one of the best methods of experimental design used for optimizing the process and finding the best combination of parameters to have a high stored gas volume and a high recovered gas volume. The simulation includes 28 runs with four considered parameters, and the output is the recovered gas, which in turn is vital for the process accomplishment. Sensitivity analysis and grid independency test were checked. To this end, three grids with different number of cells in x-direction were generated, and by analyzing the results of gas saturation in the porous medium for each model, a grid with 11250 cells (50 elements in x-direction and 15 elements in y- and z-directions) was then chosen as the main grid. Uncertainty analysis and the validation of numerical simulations were carried out, and good agreement was observed between the numerical results and experimental data. In addition, the numerical results showed that the flow rate of the injected gas had a significant impact on the process in comparison with other parameters. Furthermore, increasing permeability and decreasing pressure and irreducible water saturation raise the amount of trapped gas in aquifers. Therefore, for having the maximum stored gas volume and a high recovered gas volume, the best combination of parameters is a high gas injection flow rate (0.9 cc/min), high permeability (1.54 md), a low pressure (2254 psi), and irreducible water saturation. (0.46). Finally, in a natural gas storage operation in an aquifer, both rock properties and operational parameters play important roles, and they should be optimized in order to have the highest amount of stored gas.
{"title":"A Numerical Investigation into the Effect of Controllable Parameters on the Natural Gas Storage in a Weak Reservoir-type Aquifer","authors":"A. Jafari, Peyman Sadirli, Reza Gharibshahi, E. K. Tooseh, Masoud Samivand, A. Teymouri","doi":"10.22050/IJOGST.2018.119136.1441","DOIUrl":"https://doi.org/10.22050/IJOGST.2018.119136.1441","url":null,"abstract":"Natural gas storage process in aquifer, due to fluid flow behavior of gas and water in the porous medium and because of their contact with each other under reservoir conditions, faces several challenges. Therefore, there should be a clear understanding of the injected gas behavior before and after the injection into the reservoir. This research simulates the natural gas storage in aquifer by using Eclipse 300 software. For this purpose, a core sample was considered as the porous medium for gas injection, and a composition of natural gas was injected into the core in different conditions. Moreover, by using Plackett-Burman method, all of the factors affected in this process were screened, and finally four main significant parameters, including the flow rate of injected gas, permeability, pressure, and irreducible water saturation were selected for designing a design of experiments (DOE) plan. Response surface method (RSM) is one of the best methods of experimental design used for optimizing the process and finding the best combination of parameters to have a high stored gas volume and a high recovered gas volume. The simulation includes 28 runs with four considered parameters, and the output is the recovered gas, which in turn is vital for the process accomplishment. Sensitivity analysis and grid independency test were checked. To this end, three grids with different number of cells in x-direction were generated, and by analyzing the results of gas saturation in the porous medium for each model, a grid with 11250 cells (50 elements in x-direction and 15 elements in y- and z-directions) was then chosen as the main grid. Uncertainty analysis and the validation of numerical simulations were carried out, and good agreement was observed between the numerical results and experimental data. In addition, the numerical results showed that the flow rate of the injected gas had a significant impact on the process in comparison with other parameters. Furthermore, increasing permeability and decreasing pressure and irreducible water saturation raise the amount of trapped gas in aquifers. Therefore, for having the maximum stored gas volume and a high recovered gas volume, the best combination of parameters is a high gas injection flow rate (0.9 cc/min), high permeability (1.54 md), a low pressure (2254 psi), and irreducible water saturation. (0.46). Finally, in a natural gas storage operation in an aquifer, both rock properties and operational parameters play important roles, and they should be optimized in order to have the highest amount of stored gas.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"18 1","pages":"11-31"},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73647981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-01-01DOI: 10.22050/IJOGST.2018.104379.1418
Saei Mohammadmahdi, A. Miroliaei
Packed bed reactors have many applications in different industries such as chemical, petrochemical, and refinery industries. In this work, the effects of some parameters such as the shape and size of particles, bed size, and bed length on the hydrodynamics of the packed beds containing three spherical, cylindrical, and cubic particles types are investigated using CFD. The effect of the combination of three particles types in a packed bed was also simulated. The simulation results show that flow channeling occurs in some parts of the bed which are not suitably covered by particles. It was also seen that flow channeling in the packed bed with cubic particles are more than those containing spherical and cylindrical particles. According to the CFD simulations, wake and vortex flows are created in all the beds, and the shape of particles affects these phenomena. The comparison of the pressure drop created in the packed beds indicates that the pressure drop in the packed beds having three particle types is lower than the packed beds containing only spherical, cylindrical, or cubic particles. Finally, the numerical results were compared with empirical correlations in the literature and showed good agreement.
{"title":"CFD Simulation of Parameters Affecting Hydrodynamics of Packed Beds: Effects of Particle Shape, Bed Size, and Bed Length","authors":"Saei Mohammadmahdi, A. Miroliaei","doi":"10.22050/IJOGST.2018.104379.1418","DOIUrl":"https://doi.org/10.22050/IJOGST.2018.104379.1418","url":null,"abstract":"Packed bed reactors have many applications in different industries such as chemical, petrochemical, and refinery industries. In this work, the effects of some parameters such as the shape and size of particles, bed size, and bed length on the hydrodynamics of the packed beds containing three spherical, cylindrical, and cubic particles types are investigated using CFD. The effect of the combination of three particles types in a packed bed was also simulated. The simulation results show that flow channeling occurs in some parts of the bed which are not suitably covered by particles. It was also seen that flow channeling in the packed bed with cubic particles are more than those containing spherical and cylindrical particles. According to the CFD simulations, wake and vortex flows are created in all the beds, and the shape of particles affects these phenomena. The comparison of the pressure drop created in the packed beds indicates that the pressure drop in the packed beds having three particle types is lower than the packed beds containing only spherical, cylindrical, or cubic particles. Finally, the numerical results were compared with empirical correlations in the literature and showed good agreement.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"1 1","pages":"78-102"},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89934349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-01DOI: 10.22050/IJOGST.2018.101878.1416
S. Saffarzadeh, A. Javaherian, Hossein Hasani, M. Sadri
Seismic modeling aids the geophysicists to have a better understanding of the subsurface image before the seismic acquisition, processing, and interpretation. In this regard, seismic survey modeling is employed to make a model close to the real structure and to obtain very realistic synthetic seismic data. The objective of this study is to analyze the resolution and illumination of the fault by designing appropriate 3D seismic survey parameters. The ray-based seismic modeling was built using 2D seismic data, geological reports, and the well logs in one of the oil fields in the southwest of Iran. A pre-stack depth migration simulator was used to evaluate the survey geometry on the resulting seismic image. The results proved that a survey designer could improve the image of the target in a seismic section by applying the ray-based analyses, with respect to illumination and resolution studies.
{"title":"Analyzing the Illumination and Resolution in Seismic Survey Designing","authors":"S. Saffarzadeh, A. Javaherian, Hossein Hasani, M. Sadri","doi":"10.22050/IJOGST.2018.101878.1416","DOIUrl":"https://doi.org/10.22050/IJOGST.2018.101878.1416","url":null,"abstract":"Seismic modeling aids the geophysicists to have a better understanding of the subsurface image before the seismic acquisition, processing, and interpretation. In this regard, seismic survey modeling is employed to make a model close to the real structure and to obtain very realistic synthetic seismic data. The objective of this study is to analyze the resolution and illumination of the fault by designing appropriate 3D seismic survey parameters. The ray-based seismic modeling was built using 2D seismic data, geological reports, and the well logs in one of the oil fields in the southwest of Iran. A pre-stack depth migration simulator was used to evaluate the survey geometry on the resulting seismic image. The results proved that a survey designer could improve the image of the target in a seismic section by applying the ray-based analyses, with respect to illumination and resolution studies.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"69 1","pages":"1-12"},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72717723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-01DOI: 10.22050/IJOGST.2019.136243.1461
A. Kadkhodaie-Ilkhchi, Rahim Kadkhodaie-Ilkhchi
Carbonate reservoirs rock typing plays a pivotal role in the construction of reservoir static models and volumetric calculations. The procedure for rock type determination starts with the determination of depositional and diagenetic rock types through petrographic studies of the thin sections prepared from core plugs and cuttings. In the second step of rock typing study, electrofacies are determined based on the classification of well log responses using an appropriate clustering algorithm. The well logs used for electrofacies determination include porosity logs (NPHI, DT, and RHOB), lithodensity log (PEF), and gamma ray log. The third step deals with flow unit determination and pore size distribution analysis. To this end, flow zone indicator (FZI) is calculated from available core analysis data. Through the application of appropriate cutoffs to FZI values, reservoir rock types are classified for the studying interval. In the last step, representative capillary pressure and relative permeability curves are assigned to the reservoir rock types (RRT) based upon a detailed analysis of available laboratory data. Through the analysis of drill stem test (DST) and GDT (gas down to) and ODT (oil down to) data, necessary adjustments are made on the generated PC curves so that they are representative of reservoir conditions. Via the estimation of permeability by using a suitable method, RRT log is generated throughout the logged interval. Finally, by making a link between RRT’s and an appropriate set of seismic attributes, a cube of reservoir rock types is generated in time or depth domain. The current paper reviews different reservoir rock typing approaches from geology to seismic and dynamic and proposes an integrated rock typing workflow for worldwide carbonate reservoirs.
碳酸盐岩储层岩石类型在储层静态模型的建立和体积计算中起着至关重要的作用。确定岩石类型的程序首先通过岩石学研究岩心塞和岩屑制备的薄片来确定沉积和成岩岩石类型。在岩石分型研究的第二步,根据测井响应的分类,使用适当的聚类算法确定电相。用于电相测定的测井资料包括孔隙度测井(NPHI、DT和RHOB)、岩石密度测井(PEF)和伽马射线测井。第三步是流动单元的确定和孔径分布的分析。为此,根据现有岩心分析数据,计算出流动区指标FZI。通过对FZI值应用合适的截止值,对研究层段进行储层岩石类型划分。最后,在详细分析现有实验室数据的基础上,对储层岩石类型(RRT)进行代表性毛管压力和相对渗透率曲线的划分。通过对钻杆测试(DST)、GDT (gas down to)和ODT (oil down to)数据的分析,对生成的PC曲线进行必要的调整,使其能够代表储层条件。通过采用合适的方法估算渗透率,生成整个测井层段的RRT测井。最后,通过将RRT与一组合适的地震属性联系起来,在时间或深度域中生成储层岩石类型的立方体。本文综述了从地质到地震、动力等不同的储层岩石分型方法,提出了一套适用于全球碳酸盐岩储层的综合岩石分型工作流程。
{"title":"A Review of Reservoir Rock Typing Methods in Carbonate Reservoirs: Relation between Geological, Seismic, and Reservoir Rock Types","authors":"A. Kadkhodaie-Ilkhchi, Rahim Kadkhodaie-Ilkhchi","doi":"10.22050/IJOGST.2019.136243.1461","DOIUrl":"https://doi.org/10.22050/IJOGST.2019.136243.1461","url":null,"abstract":"Carbonate reservoirs rock typing plays a pivotal role in the construction of reservoir static models and volumetric calculations. The procedure for rock type determination starts with the determination of depositional and diagenetic rock types through petrographic studies of the thin sections prepared from core plugs and cuttings. In the second step of rock typing study, electrofacies are determined based on the classification of well log responses using an appropriate clustering algorithm. The well logs used for electrofacies determination include porosity logs (NPHI, DT, and RHOB), lithodensity log (PEF), and gamma ray log. The third step deals with flow unit determination and pore size distribution analysis. To this end, flow zone indicator (FZI) is calculated from available core analysis data. Through the application of appropriate cutoffs to FZI values, reservoir rock types are classified for the studying interval. In the last step, representative capillary pressure and relative permeability curves are assigned to the reservoir rock types (RRT) based upon a detailed analysis of available laboratory data. Through the analysis of drill stem test (DST) and GDT (gas down to) and ODT (oil down to) data, necessary adjustments are made on the generated PC curves so that they are representative of reservoir conditions. Via the estimation of permeability by using a suitable method, RRT log is generated throughout the logged interval. Finally, by making a link between RRT’s and an appropriate set of seismic attributes, a cube of reservoir rock types is generated in time or depth domain. The current paper reviews different reservoir rock typing approaches from geology to seismic and dynamic and proposes an integrated rock typing workflow for worldwide carbonate reservoirs.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"39 1","pages":"13-35"},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91397930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-01DOI: 10.22050/IJOGST.2018.95773.1400
Syed W. Haider, M. Yar, Raja Ahtisham Ghafoor, T. Khan
The well Sarai Sidhu-01 is located on Punjab Platform, Central Indus Basin, Pakistan. Punjab Platform is the eastern part of Central Indus Basin, and tectonically it is the stable portion of Indus Basin, which was least affected during Tertiary Himalayan orogeny. This study attempts to decipher reservoir potential for hydrocarbon exploration. It aims to delineate a subsurface hydrocarbon bearing zone and to estimate the reservoir properties. A complete suite of wireline logs containing Caliper log (CALI), gamma ray log (GR), spontaneous potential log (SP), neutron log (ON), density log (OD), and resistivity logs (MSFL, LLS, and LLD) with all drilling parameters and well tops were utilized. The methodology adopted to accomplish this task includes the calculation of volume of shale (Vsh) by using gamma ray log and effective porosity (OE) by using density and neutron logs. Resistivity of water (Rw) was calculated by SPmethod, and the saturation of water (Sw) and the saturation of hydrocarbons (Sh) is calculated with the help of Archie’s equation. According to log signatures, Lumshiwal formation of early Cretaceous age encountered in well in the depth range of 5433 ft. to 5797 ft. was marked as a possible reservoir, and this zone was evaluated for its reservoir potential in detail using a set of equations. The average values calculated for different parameters are as follows: Vsh= 30%, OE= 17%, Sw= 46%, and Sh= 54%. The analysis shows that Sh is low, so it is inferred that Lumshiwal formation has a low potential and is economically not feasible for hydrocarbons production.
{"title":"Evaluation of Reservoir Properties Using Wireline Logs of Well Sarai-Sidhu-1, Punjab Platform, Central Indus Basin, Pakistan","authors":"Syed W. Haider, M. Yar, Raja Ahtisham Ghafoor, T. Khan","doi":"10.22050/IJOGST.2018.95773.1400","DOIUrl":"https://doi.org/10.22050/IJOGST.2018.95773.1400","url":null,"abstract":"The well Sarai Sidhu-01 is located on Punjab Platform, Central Indus Basin, Pakistan. Punjab Platform is the eastern part of Central Indus Basin, and tectonically it is the stable portion of Indus Basin, which was least affected during Tertiary Himalayan orogeny. This study attempts to decipher reservoir potential for hydrocarbon exploration. It aims to delineate a subsurface hydrocarbon bearing zone and to estimate the reservoir properties. A complete suite of wireline logs containing Caliper log (CALI), gamma ray log (GR), spontaneous potential log (SP), neutron log (ON), density log (OD), and resistivity logs (MSFL, LLS, and LLD) with all drilling parameters and well tops were utilized. The methodology adopted to accomplish this task includes the calculation of volume of shale (Vsh) by using gamma ray log and effective porosity (OE) by using density and neutron logs. Resistivity of water (Rw) was calculated by SPmethod, and the saturation of water (Sw) and the saturation of hydrocarbons (Sh) is calculated with the help of Archie’s equation. According to log signatures, Lumshiwal formation of early Cretaceous age encountered in well in the depth range of 5433 ft. to 5797 ft. was marked as a possible reservoir, and this zone was evaluated for its reservoir potential in detail using a set of equations. The average values calculated for different parameters are as follows: Vsh= 30%, OE= 17%, Sw= 46%, and Sh= 54%. The analysis shows that Sh is low, so it is inferred that Lumshiwal formation has a low potential and is economically not feasible for hydrocarbons production.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"54 1","pages":"36-44"},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75165001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-01DOI: 10.22050/IJOGST.2018.111128.1430
M. Fatemi, B. H. Shahraki
Use of amine solutions for the removal of acid gases such as carbon dioxide (CO2) and hydrogen sulfide (H2S) from natural gas is the most common method, and, in this process, operational problems because of foaming are reported. Foaming can lead to the entrainment of liquid into downstream process equipment and might result in a situation in which the process specifications cannot be met for acid gases. Alkanolamines in general have a negative effect on downstream process equipment, and the loss of amines has a negative effect on the health, safety, and environment (HSE). The foam reducing agents are often used to reduce the risk of heavy foaming in amine plants. This study concerns with foaming in amine-based CO2 plants. To investigate foaming related to CO2 removal from natural gas by amine solutions, the fundamental theory of foaming in gas-liquid contactors was first reviewed. Then, experimental techniques related to this phenomenon in diethanolamine (DEA)/CO2 absorbers were considered. After that, foaming of diethanolamine solution polluted with different impurities was noticed, and the tendency of foam was measured by considering their foaming indices. To analyze the experimental measurements and experimental observations, a mathematical model was developed too. The model could justify the experimental measurement reasonably.
{"title":"An Experimental and Theoretical Analysis of Foam Formation in the Sour Gas Sweetening Process","authors":"M. Fatemi, B. H. Shahraki","doi":"10.22050/IJOGST.2018.111128.1430","DOIUrl":"https://doi.org/10.22050/IJOGST.2018.111128.1430","url":null,"abstract":"Use of amine solutions for the removal of acid gases such as carbon dioxide (CO2) and hydrogen sulfide (H2S) from natural gas is the most common method, and, in this process, operational problems because of foaming are reported. Foaming can lead to the entrainment of liquid into downstream process equipment and might result in a situation in which the process specifications cannot be met for acid gases. Alkanolamines in general have a negative effect on downstream process equipment, and the loss of amines has a negative effect on the health, safety, and environment (HSE). The foam reducing agents are often used to reduce the risk of heavy foaming in amine plants. This study concerns with foaming in amine-based CO2 plants. To investigate foaming related to CO2 removal from natural gas by amine solutions, the fundamental theory of foaming in gas-liquid contactors was first reviewed. Then, experimental techniques related to this phenomenon in diethanolamine (DEA)/CO2 absorbers were considered. After that, foaming of diethanolamine solution polluted with different impurities was noticed, and the tendency of foam was measured by considering their foaming indices. To analyze the experimental measurements and experimental observations, a mathematical model was developed too. The model could justify the experimental measurement reasonably.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"80 1","pages":"79-89"},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83386292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-01DOI: 10.22050/IJOGST.2018.108233.1422
R. Moghadasi, J. Moghadasi, S. Kord
As a physiochemical property, asphaltenes are known to be one the most surface active compounds in crude oil. Due to such property, their behavior is most probably influenced by fluid-fluid interactions at the contact surface (interface). Potentially and naturally, in most cases, water is in contact with crude oil and is co-produced with it as well. Considering that asphaltene molecules are polar compounds similar to water molecules, asphaltenes are interfacially affected by water while they are absorbed to the interface. Such effects could be investigated by interfacial tension (IFT) changes when de-ionized water is used and dead-crude oil does not contain other surface active impurities like metallic compounds. In this study, extensive IFT experiments were conducted between three different oil samples and distilled water in a wide range of pressure from 2000 to 0 psia. The reversibility of asphaltene absorbance to the interface was also investigated by reversing the pressure path from 0 to 2000 psia. The results show that oil/water IFT changes with pressure, but upward/downward oscillations were detected. Such an oscillating behavior of IFT trends was related to asphaltenes surface activity as the oil samples used did not contain other impurities. Oscillations were reduced as resin to asphaltene ratio was increased, suggesting the non-absorbable behavior of the asphaltenes stabilized by resins. A microscopic surface experiment on one of the samples showed that at a certain concentration and particle size, a rigid film of absorbed asphaltenes was created at the interface instantaneously. The high rigidity of such a film gives rise to a hypothesis, which states that water affects asphaltene surface behavior possibly through strong hydrogen bonding (H-bond). Reversing the pressure path revealed that asphaltene surface absorbance is partially irreversible. The experiments were conducted three times, and each data set was presented along with an average of three sets for each sample.
{"title":"An Experimental Investigation of Water Effects on Asphaltene Surface Behavior through Interfacial Tension Measurements","authors":"R. Moghadasi, J. Moghadasi, S. Kord","doi":"10.22050/IJOGST.2018.108233.1422","DOIUrl":"https://doi.org/10.22050/IJOGST.2018.108233.1422","url":null,"abstract":"As a physiochemical property, asphaltenes are known to be one the most surface active compounds in crude oil. Due to such property, their behavior is most probably influenced by fluid-fluid interactions at the contact surface (interface). Potentially and naturally, in most cases, water is in contact with crude oil and is co-produced with it as well. Considering that asphaltene molecules are polar compounds similar to water molecules, asphaltenes are interfacially affected by water while they are absorbed to the interface. Such effects could be investigated by interfacial tension (IFT) changes when de-ionized water is used and dead-crude oil does not contain other surface active impurities like metallic compounds. In this study, extensive IFT experiments were conducted between three different oil samples and distilled water in a wide range of pressure from 2000 to 0 psia. The reversibility of asphaltene absorbance to the interface was also investigated by reversing the pressure path from 0 to 2000 psia. The results show that oil/water IFT changes with pressure, but upward/downward oscillations were detected. Such an oscillating behavior of IFT trends was related to asphaltenes surface activity as the oil samples used did not contain other impurities. Oscillations were reduced as resin to asphaltene ratio was increased, suggesting the non-absorbable behavior of the asphaltenes stabilized by resins. A microscopic surface experiment on one of the samples showed that at a certain concentration and particle size, a rigid film of absorbed asphaltenes was created at the interface instantaneously. The high rigidity of such a film gives rise to a hypothesis, which states that water affects asphaltene surface behavior possibly through strong hydrogen bonding (H-bond). Reversing the pressure path revealed that asphaltene surface absorbance is partially irreversible. The experiments were conducted three times, and each data set was presented along with an average of three sets for each sample.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"68 1","pages":"45-58"},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88625467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-10-01DOI: 10.22050/IJOGST.2018.98556.1409
S. M. Vahedi, F. Parvaz, M. Kamali, Hasti Jafari Jebeli
The effect of adding extra inlet channels on the operation of the Stairmand Cyclone has been investigated numerically. The Reynolds stress model (RSM) and Eulerian-Lagrangian method were used to investigate the complex turbulent flow and cyclone performance. The impacts of one-way coupling and two-way coupling models on the cyclone efficiency and the calculation of cut-off size diameter were examined. The results showed that a rise in channel number increases the tangential velocity and extends the Rankine vortex region. Moreover, in the four-inlet cyclone, the direction of flow changes unlike the one-inlet and two-inlet cyclones, and it behaves like a jet flow. According to the results, the collection efficiency and cut-off size diameter of the four-inlet cyclone are respectively about 10.78% higher and 35% lower than those of one-inlet configuration. Therefore, the performance of four-inlet cyclone is the highest among the three investigated configurations due to high tangential and axial velocities. A cyclone with more inlets has a more symmetrical flow pattern. Consequently, the four-inlet cyclone has the lowest flux of erosion among the others. The results of cyclone performance reveal a slight difference between one-way coupling and two-way coupling models.
{"title":"Numerical Investigation of the Impact of Inlet Channel Numbers on the Flow Pattern, Performance, and Erosion of Gas-particle Cyclone","authors":"S. M. Vahedi, F. Parvaz, M. Kamali, Hasti Jafari Jebeli","doi":"10.22050/IJOGST.2018.98556.1409","DOIUrl":"https://doi.org/10.22050/IJOGST.2018.98556.1409","url":null,"abstract":"The effect of adding extra inlet channels on the operation of the Stairmand Cyclone has been investigated numerically. The Reynolds stress model (RSM) and Eulerian-Lagrangian method were used to investigate the complex turbulent flow and cyclone performance. The impacts of one-way coupling and two-way coupling models on the cyclone efficiency and the calculation of cut-off size diameter were examined. The results showed that a rise in channel number increases the tangential velocity and extends the Rankine vortex region. Moreover, in the four-inlet cyclone, the direction of flow changes unlike the one-inlet and two-inlet cyclones, and it behaves like a jet flow. According to the results, the collection efficiency and cut-off size diameter of the four-inlet cyclone are respectively about 10.78% higher and 35% lower than those of one-inlet configuration. Therefore, the performance of four-inlet cyclone is the highest among the three investigated configurations due to high tangential and axial velocities. A cyclone with more inlets has a more symmetrical flow pattern. Consequently, the four-inlet cyclone has the lowest flux of erosion among the others. The results of cyclone performance reveal a slight difference between one-way coupling and two-way coupling models.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"30 4","pages":"59-78"},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91451726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-07-01DOI: 10.22050/IJOGST.2017.102019.1415
Farshad Torabi Esfahani, J. Ivakpour, M. Ehsani
In this work, new correlations are proposed to predict the products yield of delayed coking as a function of CCR and temperature based on the experimental results. For this purpose, selected Iranian vacuum residues with Conradson carbon residue (CCR) values between 13.40-22.19 wt.% were heated at a 10 °C/min heating rate and thermally cracked in a temperature range of 400-500 °C in a laboratory batch atmospheric delayed coking reactor for 2 hours. The amount of distillate (C5+-500 °C) and coke yield were measured in all the experiments, and the gas (C1-C4) product yield was calculated based on mass balance between products and feedstock in each experiment. According to the developed functions, products yield changes with CCR value linearly and is a power function of temperature. The further investigation of the results show that by a 1 wt.% increase in CCR value, the distillate yield decreases by about 2.1 wt.%, but the amount of coke and gas yields rise by 1.2 wt.% and 0.9 wt.% respectively.
{"title":"Prediction of the Products Yield of Delayed Coking for Iranian Vacuum Residues","authors":"Farshad Torabi Esfahani, J. Ivakpour, M. Ehsani","doi":"10.22050/IJOGST.2017.102019.1415","DOIUrl":"https://doi.org/10.22050/IJOGST.2017.102019.1415","url":null,"abstract":"In this work, new correlations are proposed to predict the products yield of delayed coking as a function of CCR and temperature based on the experimental results. For this purpose, selected Iranian vacuum residues with Conradson carbon residue (CCR) values between 13.40-22.19 wt.% were heated at a 10 °C/min heating rate and thermally cracked in a temperature range of 400-500 °C in a laboratory batch atmospheric delayed coking reactor for 2 hours. The amount of distillate (C5+-500 °C) and coke yield were measured in all the experiments, and the gas (C1-C4) product yield was calculated based on mass balance between products and feedstock in each experiment. According to the developed functions, products yield changes with CCR value linearly and is a power function of temperature. The further investigation of the results show that by a 1 wt.% increase in CCR value, the distillate yield decreases by about 2.1 wt.%, but the amount of coke and gas yields rise by 1.2 wt.% and 0.9 wt.% respectively.","PeriodicalId":14575,"journal":{"name":"Iranian Journal of Oil and Gas Science and Technology","volume":"3 1","pages":"53-64"},"PeriodicalIF":0.0,"publicationDate":"2018-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79060347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}