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An Experimental Study of Acid Diversion by Using Gelled Acid Systems Based on Viscoelastic Surfactants: A Case Study on One of Iran Southwest Oilfields 粘弹性表面活性剂胶凝酸体系引酸试验研究——以伊朗西南某油田为例
Pub Date : 2019-01-01 DOI: 10.22050/IJOGST.2018.139168.1464
A. M. Ghahfarrokhi, E. Kazemzadeh, H. Behbahani, G. Safian
In matrix acidizing operations, the main goal is increasing permeability. For production engineers, it is desirable that acid could be injected into whole [M.N.1] [amehri.gh2] pay zone. Sometimes, this pay zone has a long height and various sub-layers which have different permeability values. To prevent acid from going completely into the most permeable sub-layer, one of the useful techniques is using diverters, and one of the major groups of diverters is gel diverters. Diverter viscosity changes by temperature and pH, and an increase in viscosity leads to a decrease in its permeability; thus, acid can permeate further through less permeable sub-layers. In this study, two kinds of different viscoelastic surfactants (VES) provided by two different companies were used to produce gel to divert acid into a core plug sample having lower permeability in a dual parallel acid injection set-up. The core plug samples were taken from the pay zone of Ahwaz oilfield, one of Iran southwest oilfields. Before performing the injection test, some viscosity measurement tests were carried out. Unfortunately, one of these two VES’s did not have an acceptable quality and failed to pass the injection tests. However, the other one passed all the tests successfully and diverted the injection fluid. The water permeability values of the low-perm and high-perm core plug samples were 0.91 md and 6.4 md respectively, whereas, after injection, they rose to 1.5 and 18.5 md respectively.
在基质酸化作业中,主要目标是提高渗透率。对于生产工程师来说,理想的做法是将酸注入整个[M.N.]1] [amehri。[2]产层。有时该产层具有较长的高度和不同的子层,这些子层具有不同的渗透率值。为了防止酸完全进入最具渗透性的亚层,一种有用的技术是使用暂堵剂,其中一种主要的暂堵剂是凝胶暂堵剂。导流剂粘度随温度和pH值的变化而变化,粘度增大导致导流剂渗透率降低;因此,酸可以通过渗透性较差的子层进一步渗透。在这项研究中,两家不同公司提供的两种不同的粘弹性表面活性剂(VES)被用于生产凝胶,以将酸转移到双平行酸注入装置中渗透率较低的岩心塞样品中。岩心塞样取自伊朗西南油田之一的Ahwaz油田产层。在进行注入试验之前,进行了一些粘度测量试验。不幸的是,这两个VES中有一个质量不合格,未能通过注射测试。然而,另一个成功地通过了所有测试,并转移了注入液。低、高温岩心塞样渗透率分别为0.91 md和6.4 md,注入后渗透率分别为1.5 md和18.5 md。
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引用次数: 2
A Numerical Investigation into the Effect of Controllable Parameters on the Natural Gas Storage in a Weak Reservoir-type Aquifer 弱储集型含水层可控参数对天然气储层影响的数值研究
Pub Date : 2019-01-01 DOI: 10.22050/IJOGST.2018.119136.1441
A. Jafari, Peyman Sadirli, Reza Gharibshahi, E. K. Tooseh, Masoud Samivand, A. Teymouri
Natural gas storage process in aquifer, due to fluid flow behavior of gas and water in the porous medium and because of their contact with each other under reservoir conditions, faces several challenges. Therefore, there should be a clear understanding of the injected gas behavior before and after the injection into the reservoir. This research simulates the natural gas storage in aquifer by using Eclipse 300 software. For this purpose, a core sample was considered as the porous medium for gas injection, and a composition of natural gas was injected into the core in different conditions. Moreover, by using Plackett-Burman method, all of the factors affected in this process were screened, and finally four main significant parameters, including the flow rate of injected gas, permeability, pressure, and irreducible water saturation were selected for designing a design of experiments (DOE) plan. Response surface method (RSM) is one of the best methods of experimental design used for optimizing the process and finding the best combination of parameters to have a high stored gas volume and a high recovered gas volume. The simulation includes 28 runs with four considered parameters, and the output is the recovered gas, which in turn is vital for the process accomplishment. Sensitivity analysis and grid independency test were checked. To this end, three grids with different number of cells in x-direction were generated, and by analyzing the results of gas saturation in the porous medium for each model, a grid with 11250 cells (50 elements in x-direction and 15 elements in y- and z-directions) was then chosen as the main grid. Uncertainty analysis and the validation of numerical simulations were carried out, and good agreement was observed between the numerical results and experimental data. In addition, the numerical results showed that the flow rate of the injected gas had a significant impact on the process in comparison with other parameters. Furthermore, increasing permeability and decreasing pressure and irreducible water saturation raise the amount of trapped gas in aquifers. Therefore, for having the maximum stored gas volume and a high recovered gas volume, the best combination of parameters is a high gas injection flow rate (0.9 cc/min), high permeability (1.54 md), a low pressure (2254 psi), and irreducible water saturation. (0.46). Finally, in a natural gas storage operation in an aquifer, both rock properties and operational parameters play important roles, and they should be optimized in order to have the highest amount of stored gas.
由于气水在多孔介质中的流动特性和储层条件下的相互接触,含水层天然气的储气过程面临着诸多挑战。因此,对注入储层前后的注气行为要有一个清晰的认识。利用Eclipse 300软件对含水层天然气储层进行模拟。为此,将岩心样品作为注气的多孔介质,在不同条件下向岩心注入一种天然气成分。利用Plackett-Burman方法对影响这一过程的所有因素进行筛选,最终筛选出注气量、渗透率、压力、不可还原含水饱和度4个主要重要参数,设计实验设计(DOE)方案。响应面法(RSM)是一种最佳的实验设计方法,用于优化工艺流程,寻找最佳的参数组合,以获得高储气量和高采收率。模拟包括28次运行,考虑了四个参数,输出是回收的气体,这对过程的完成至关重要。进行敏感性分析和网格独立性检验。为此,在x方向上生成了3个不同单元格数的网格,通过分析每个模型的孔隙介质中气体饱和度结果,选择一个单元格数为11250的网格(x方向50个单元,y和z方向15个单元)作为主网格。对数值模拟进行了不确定度分析和验证,数值结果与实验数据吻合较好。此外,数值计算结果表明,与其他参数相比,注入气体的流量对过程有显著影响。此外,渗透率的增加和压力的降低以及含水饱和度的不降低也增加了含水层中被困气体的数量。因此,为了获得最大的储气量和高采收率,最佳参数组合是高注气量(0.9 cc/min)、高渗透率(1.54 md)、低压(2254 psi)和不可降低的含水饱和度。(0.46)。最后,在含水层天然气储气作业中,岩石性质和作业参数都起着重要的作用,为了获得最大的储气量,必须对其进行优化。
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引用次数: 1
CFD Simulation of Parameters Affecting Hydrodynamics of Packed Beds: Effects of Particle Shape, Bed Size, and Bed Length 影响填料床流体动力学参数的CFD模拟:颗粒形状、床层尺寸和床层长度的影响
Pub Date : 2019-01-01 DOI: 10.22050/IJOGST.2018.104379.1418
Saei Mohammadmahdi, A. Miroliaei
Packed bed reactors have many applications in different industries such as chemical, petrochemical, and refinery industries. In this work, the effects of some parameters such as the shape and size of particles, bed size, and bed length on the hydrodynamics of the packed beds containing three spherical, cylindrical, and cubic particles types are investigated using CFD. The effect of the combination of three particles types in a packed bed was also simulated. The simulation results show that flow channeling occurs in some parts of the bed which are not suitably covered by particles. It was also seen that flow channeling in the packed bed with cubic particles are more than those containing spherical and cylindrical particles. According to the CFD simulations, wake and vortex flows are created in all the beds, and the shape of particles affects these phenomena. The comparison of the pressure drop created in the packed beds indicates that the pressure drop in the packed beds having three particle types is lower than the packed beds containing only spherical, cylindrical, or cubic particles. Finally, the numerical results were compared with empirical correlations in the literature and showed good agreement.
填料床反应器在化工、石化、炼油等行业中有着广泛的应用。本文利用CFD研究了颗粒形状、粒径、床层尺寸、床层长度等参数对含球形、圆柱形和立方颗粒填料床流体力学的影响。模拟了充填床中三种颗粒类型组合的影响。模拟结果表明,在颗粒覆盖不充分的床层部分会发生窜流。立方体颗粒充填床的流道比球形和圆柱形颗粒充填床的流道多。根据CFD模拟,所有床层都产生了尾流和涡旋流,颗粒的形状影响了这些现象。对充填床中产生的压降的比较表明,具有三种颗粒类型的充填床的压降低于仅含有球形、圆柱形或立方颗粒的充填床。最后,将数值结果与文献中的经验相关性进行了比较,结果吻合较好。
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引用次数: 1
Analyzing the Illumination and Resolution in Seismic Survey Designing 地震勘探设计中的照度与分辨率分析
Pub Date : 2018-10-01 DOI: 10.22050/IJOGST.2018.101878.1416
S. Saffarzadeh, A. Javaherian, Hossein Hasani, M. Sadri
Seismic modeling aids the geophysicists to have a better understanding of the subsurface image before the seismic acquisition, processing, and interpretation. In this regard, seismic survey modeling is employed to make a model close to the real structure and to obtain very realistic synthetic seismic data. The objective of this study is to analyze the resolution and illumination of the fault by designing appropriate 3D seismic survey parameters. The ray-based seismic modeling was built using 2D seismic data, geological reports, and the well logs in one of the oil fields in the southwest of Iran. A pre-stack depth migration simulator was used to evaluate the survey geometry on the resulting seismic image. The results proved that a survey designer could improve the image of the target in a seismic section by applying the ray-based analyses, with respect to illumination and resolution studies.
地震建模有助于地球物理学家在地震采集、处理和解释之前更好地了解地下图像。为此,采用地震测量建模,使模型接近真实构造,得到非常逼真的合成地震资料。本研究的目的是通过设计合适的三维地震测量参数来分析断层的分辨率和光照。基于射线的地震模型是利用伊朗西南部一个油田的二维地震数据、地质报告和测井数据建立的。利用叠前深度偏移模拟器对所得地震图像的测量几何形状进行评估。结果表明,在光照和分辨率研究方面,测量设计人员可以通过应用基于射线的分析来改善地震剖面中目标的图像。
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引用次数: 0
A Review of Reservoir Rock Typing Methods in Carbonate Reservoirs: Relation between Geological, Seismic, and Reservoir Rock Types 碳酸盐岩储层岩石类型方法综述:地质、地震和储层岩石类型的关系
Pub Date : 2018-10-01 DOI: 10.22050/IJOGST.2019.136243.1461
A. Kadkhodaie-Ilkhchi, Rahim Kadkhodaie-Ilkhchi
Carbonate reservoirs rock typing plays a pivotal role in the construction of reservoir static models and volumetric calculations. The procedure for rock type determination starts with the determination of depositional and diagenetic rock types through petrographic studies of the thin sections prepared from core plugs and cuttings. In the second step of rock typing study, electrofacies are determined based on the classification of well log responses using an appropriate clustering algorithm. The well logs used for electrofacies determination include porosity logs (NPHI, DT, and RHOB), lithodensity log (PEF), and gamma ray log. The third step deals with flow unit determination and pore size distribution analysis. To this end, flow zone indicator (FZI) is calculated from available core analysis data. Through the application of appropriate cutoffs to FZI values, reservoir rock types are classified for the studying interval. In the last step, representative capillary pressure and relative permeability curves are assigned to the reservoir rock types (RRT) based upon a detailed analysis of available laboratory data. Through the analysis of drill stem test (DST) and GDT (gas down to) and ODT (oil down to) data, necessary adjustments are made on the generated PC curves so that they are representative of reservoir conditions. Via the estimation of permeability by using a suitable method, RRT log is generated throughout the logged interval. Finally, by making a link between RRT’s and an appropriate set of seismic attributes, a cube of reservoir rock types is generated in time or depth domain. The current paper reviews different reservoir rock typing approaches from geology to seismic and dynamic and proposes an integrated rock typing workflow for worldwide carbonate reservoirs.
碳酸盐岩储层岩石类型在储层静态模型的建立和体积计算中起着至关重要的作用。确定岩石类型的程序首先通过岩石学研究岩心塞和岩屑制备的薄片来确定沉积和成岩岩石类型。在岩石分型研究的第二步,根据测井响应的分类,使用适当的聚类算法确定电相。用于电相测定的测井资料包括孔隙度测井(NPHI、DT和RHOB)、岩石密度测井(PEF)和伽马射线测井。第三步是流动单元的确定和孔径分布的分析。为此,根据现有岩心分析数据,计算出流动区指标FZI。通过对FZI值应用合适的截止值,对研究层段进行储层岩石类型划分。最后,在详细分析现有实验室数据的基础上,对储层岩石类型(RRT)进行代表性毛管压力和相对渗透率曲线的划分。通过对钻杆测试(DST)、GDT (gas down to)和ODT (oil down to)数据的分析,对生成的PC曲线进行必要的调整,使其能够代表储层条件。通过采用合适的方法估算渗透率,生成整个测井层段的RRT测井。最后,通过将RRT与一组合适的地震属性联系起来,在时间或深度域中生成储层岩石类型的立方体。本文综述了从地质到地震、动力等不同的储层岩石分型方法,提出了一套适用于全球碳酸盐岩储层的综合岩石分型工作流程。
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引用次数: 18
Evaluation of Reservoir Properties Using Wireline Logs of Well Sarai-Sidhu-1, Punjab Platform, Central Indus Basin, Pakistan 巴基斯坦中部印度河盆地旁遮普平台Sarai-Sidhu-1井电缆测井储层物性评价
Pub Date : 2018-10-01 DOI: 10.22050/IJOGST.2018.95773.1400
Syed W. Haider, M. Yar, Raja Ahtisham Ghafoor, T. Khan
The well Sarai Sidhu-01 is located on Punjab Platform, Central Indus Basin, Pakistan. Punjab Platform is the eastern part of Central Indus Basin, and tectonically it is the stable portion of Indus Basin, which was least affected during Tertiary Himalayan orogeny. This study attempts to decipher reservoir potential for hydrocarbon exploration. It aims to delineate a subsurface hydrocarbon bearing zone and to estimate the reservoir properties. A complete suite of wireline logs containing Caliper log (CALI), gamma ray log (GR), spontaneous potential log (SP), neutron log (ON), density log (OD), and resistivity logs (MSFL, LLS, and LLD) with all drilling parameters and well tops were utilized. The methodology adopted to accomplish this task includes the calculation of volume of shale (Vsh) by using gamma ray log and effective porosity (OE) by using density and neutron logs. Resistivity of water (Rw) was calculated by SPmethod, and the saturation of water (Sw) and the saturation of hydrocarbons (Sh) is calculated with the help of Archie’s equation. According to log signatures, Lumshiwal formation of early Cretaceous age encountered in well in the depth range of 5433 ft. to 5797 ft. was marked as a possible reservoir, and this zone was evaluated for its reservoir potential in detail using a set of equations. The average values calculated for different parameters are as follows: Vsh= 30%, OE= 17%, Sw= 46%, and Sh= 54%. The analysis shows that Sh is low, so it is inferred that Lumshiwal formation has a low potential and is economically not feasible for hydrocarbons production.
Sarai Sidhu-01井位于巴基斯坦中部印度河盆地旁遮普平台。旁遮普地台是中印度河盆地的东部,构造上是印度河盆地的稳定部分,受喜马拉雅第三纪造山运动的影响最小。这项研究试图破译油气勘探的储集潜力。其目的是圈定地下含油气带,评价储层物性。使用了一套完整的电缆测井工具,包括井径测井(CALI)、伽马测井(GR)、自然电位测井(SP)、中子测井(ON)、密度测井(OD)和电阻率测井(MSFL、LLS和LLD),涵盖了所有钻井参数和井顶。完成这项任务所采用的方法包括利用伽马测井计算页岩体积(Vsh)和利用密度和中子测井计算有效孔隙度(OE)。采用spw法计算水的电阻率(Rw),利用Archie方程计算水的饱和度(Sw)和烃的饱和度(Sh)。根据测井特征,将井深5433 ~ 5797 ft的早白垩世Lumshiwal组标记为可能的储层,并利用一组方程对该储层潜力进行了详细评价。不同参数计算的平均值为:Vsh= 30%, OE= 17%, Sw= 46%, Sh= 54%。分析表明,页岩气含量低,推断Lumshiwal组潜力低,经济上不可行。
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引用次数: 0
An Experimental and Theoretical Analysis of Foam Formation in the Sour Gas Sweetening Process 含酸气脱硫过程泡沫形成的实验与理论分析
Pub Date : 2018-10-01 DOI: 10.22050/IJOGST.2018.111128.1430
M. Fatemi, B. H. Shahraki
Use of amine solutions for the removal of acid gases such as carbon dioxide (CO2) and hydrogen sulfide (H2S) from natural gas is the most common method, and, in this process, operational problems because of foaming are reported. Foaming can lead to the entrainment of liquid into downstream process equipment and might result in a situation in which the process specifications cannot be met for acid gases. Alkanolamines in general have a negative effect on downstream process equipment, and the loss of amines has a negative effect on the health, safety, and environment (HSE). The foam reducing agents are often used to reduce the risk of heavy foaming in amine plants. This study concerns with foaming in amine-based CO2 plants. To investigate foaming related to CO2 removal from natural gas by amine solutions, the fundamental theory of foaming in gas-liquid contactors was first reviewed. Then, experimental techniques related to this phenomenon in diethanolamine (DEA)/CO2 absorbers were considered. After that, foaming of diethanolamine solution polluted with different impurities was noticed, and the tendency of foam was measured by considering their foaming indices. To analyze the experimental measurements and experimental observations, a mathematical model was developed too. The model could justify the experimental measurement reasonably.
使用胺溶液去除天然气中的酸性气体,如二氧化碳(CO2)和硫化氢(H2S)是最常用的方法,在此过程中,由于起泡而导致的操作问题也有报道。发泡可能导致液体夹带到下游工艺设备中,并可能导致酸性气体无法满足工艺规范的情况。烷醇胺通常对下游工艺设备有负面影响,胺的损失对健康、安全和环境(HSE)有负面影响。在胺厂中,经常使用泡沫还原剂来降低重泡沫的风险。本研究涉及胺基CO2装置的发泡。为了研究胺溶液脱除天然气中CO2的发泡问题,首先综述了气液接触器发泡的基本理论。然后,在二乙醇胺(DEA)/CO2吸收剂中考虑了与该现象相关的实验技术。然后观察了不同杂质污染的二乙醇胺溶液的起泡情况,并结合其起泡指标测定了其起泡趋势。为了分析实验测量和实验观察结果,建立了数学模型。该模型能合理地验证实验测量结果。
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引用次数: 2
An Experimental Investigation of Water Effects on Asphaltene Surface Behavior through Interfacial Tension Measurements 通过界面张力测量研究水对沥青质表面行为的影响
Pub Date : 2018-10-01 DOI: 10.22050/IJOGST.2018.108233.1422
R. Moghadasi, J. Moghadasi, S. Kord
As a physiochemical property, asphaltenes are known to be one the most surface active compounds in crude oil. Due to such property, their behavior is most probably influenced by fluid-fluid interactions at the contact surface (interface). Potentially and naturally, in most cases, water is in contact with crude oil and is co-produced with it as well. Considering that asphaltene molecules are polar compounds similar to water molecules, asphaltenes are interfacially affected by water while they are absorbed to the interface. Such effects could be investigated by interfacial tension (IFT) changes when de-ionized water is used and dead-crude oil does not contain other surface active impurities like metallic compounds. In this study, extensive IFT experiments were conducted between three different oil samples and distilled water in a wide range of pressure from 2000 to 0 psia. The reversibility of asphaltene absorbance to the interface was also investigated by reversing the pressure path from 0 to 2000 psia. The results show that oil/water IFT changes with pressure, but upward/downward oscillations were detected. Such an oscillating behavior of IFT trends was related to asphaltenes surface activity as the oil samples used did not contain other impurities. Oscillations were reduced as resin to asphaltene ratio was increased, suggesting the non-absorbable behavior of the asphaltenes stabilized by resins. A microscopic surface experiment on one of the samples showed that at a certain concentration and particle size, a rigid film of absorbed asphaltenes was created at the interface instantaneously. The high rigidity of such a film gives rise to a hypothesis, which states that water affects asphaltene surface behavior possibly through strong hydrogen bonding (H-bond). Reversing the pressure path revealed that asphaltene surface absorbance is partially irreversible. The experiments were conducted three times, and each data set was presented along with an average of three sets for each sample.
作为一种物理化学性质,沥青质被认为是原油中最具表面活性的化合物之一。由于这种性质,它们的行为很可能受到接触面(界面)上流体-流体相互作用的影响。在大多数情况下,水都可能与原油接触,并与原油共同开采。考虑到沥青质分子是类似于水分子的极性化合物,沥青质在被吸收到界面时受到水的界面影响。当使用去离子水且死原油不含其他表面活性杂质(如金属化合物)时,可以通过界面张力(IFT)变化来研究这种影响。在本研究中,在2000至0 psia的压力范围内,在三种不同的油样和蒸馏水之间进行了广泛的IFT实验。通过从0到2000 psia的反向压力路径,研究了沥青质对界面吸光度的可逆性。结果表明:油水间IFT随压力变化,但存在上下振荡;IFT趋势的这种振荡行为与沥青质的表面活性有关,因为所使用的油样不含其他杂质。随着树脂与沥青质比例的增加,振荡减少,表明树脂稳定的沥青质具有不可吸收性。其中一个样品的微观表面实验表明,在一定的浓度和粒度下,在界面上瞬间形成一层被吸收的沥青质刚性膜。这种膜的高刚性产生了一种假设,即水可能通过强氢键(h -键)影响沥青质的表面行为。反向压力路径表明,沥青质的表面吸收部分不可逆。实验进行了三次,每个数据集与每个样本的平均三组一起呈现。
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引用次数: 4
Numerical Investigation of the Impact of Inlet Channel Numbers on the Flow Pattern, Performance, and Erosion of Gas-particle Cyclone 入口通道数对气-颗粒旋风分离器流态、性能和侵蚀影响的数值研究
Pub Date : 2018-10-01 DOI: 10.22050/IJOGST.2018.98556.1409
S. M. Vahedi, F. Parvaz, M. Kamali, Hasti Jafari Jebeli
The effect of adding extra inlet channels on the operation of the Stairmand Cyclone has been investigated numerically. The Reynolds stress model (RSM) and Eulerian-Lagrangian method were used to investigate the complex turbulent flow and cyclone performance. The impacts of one-way coupling and two-way coupling models on the cyclone efficiency and the calculation of cut-off size diameter were examined. The results showed that a rise in channel number increases the tangential velocity and extends the Rankine vortex region. Moreover, in the four-inlet cyclone, the direction of flow changes unlike the one-inlet and two-inlet cyclones, and it behaves like a jet flow. According to the results, the collection efficiency and cut-off size diameter of the four-inlet cyclone are respectively about 10.78% higher and 35% lower than those of one-inlet configuration. Therefore, the performance of four-inlet cyclone is the highest among the three investigated configurations due to high tangential and axial velocities. A cyclone with more inlets has a more symmetrical flow pattern. Consequently, the four-inlet cyclone has the lowest flux of erosion among the others. The results of cyclone performance reveal a slight difference between one-way coupling and two-way coupling models.
数值研究了增加额外进口通道对楼梯式旋风分离器运行的影响。采用雷诺应力模型(RSM)和欧拉-拉格朗日方法研究了复杂湍流流动和旋风分离器的性能。考察了单向耦合和双向耦合模型对旋流器效率和截止粒径计算的影响。结果表明,通道数的增加增加了切向速度,扩大了朗肯涡区。此外,在四入口旋风中,流动方向的变化与单入口和双入口旋风不同,它的行为类似于射流。结果表明,四入口旋流器的收集效率和截止粒径分别比单入口旋流器高10.78%和低35%。因此,由于高的切向和轴向速度,四入口旋风器的性能在三种所研究的配置中是最高的。具有更多入口的旋风具有更对称的流型。因此,四入口气旋的侵蚀通量最低。结果表明,单向耦合和双向耦合模型在旋风分离器性能上略有不同。
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引用次数: 8
Prediction of the Products Yield of Delayed Coking for Iranian Vacuum Residues 伊朗真空渣油延迟焦化产率的预测
Pub Date : 2018-07-01 DOI: 10.22050/IJOGST.2017.102019.1415
Farshad Torabi Esfahani, J. Ivakpour, M. Ehsani
In this work, new correlations are proposed to predict the products yield of delayed coking as a function of CCR and temperature based on the experimental results. For this purpose, selected Iranian vacuum residues with Conradson carbon residue (CCR) values between 13.40-22.19 wt.% were heated at a 10 °C/min heating rate and thermally cracked in a temperature range of 400-500 °C in a laboratory batch atmospheric delayed coking reactor for 2 hours. The amount of distillate (C5+-500 °C) and coke yield were measured in all the experiments, and the gas (C1-C4) product yield was calculated based on mass balance between products and feedstock in each experiment. According to the developed functions, products yield changes with CCR value linearly and is a power function of temperature. The further investigation of the results show that by a 1 wt.% increase in CCR value, the distillate yield decreases by about 2.1 wt.%, but the amount of coke and gas yields rise by 1.2 wt.% and 0.9 wt.% respectively.
本文在实验结果的基础上,提出了延迟焦化产物产率随CCR和温度变化的关系式。为此,选择康拉德森碳渣(CCR)值在13.40-22.19 wt.%之间的伊朗真空渣油,在实验室间歇式常压延迟焦化反应器中,以10°C/min的升温速率加热,并在400-500°C的温度范围内热裂解2小时。在所有实验中都测量了馏出物(C5+-500℃)的量和焦炭收率,并根据每次实验中产物与原料之间的质量平衡计算了气(C1-C4)产物收率。根据所建立的函数,产品收率随CCR值线性变化,是温度的幂函数。进一步研究结果表明,CCR值每提高1 wt.%,馏出物产率降低约2.1 wt.%,但焦炭量和气产率分别提高1.2 wt.%和0.9 wt.%。
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引用次数: 0
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Iranian Journal of Oil and Gas Science and Technology
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