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Accuracy of coordinate measurements at phase modulation by digital raster 数字光栅相位调制的坐标测量精度
Pub Date : 2024-04-05 DOI: 10.32446/0368-1025it.2024-2-35-41
V. A. Solomatin, Dmitriy G. Otkupman
The development of optical-electronic instruments for measuring linear and angular quantities based on focal-plane array (photomatrices) using a digital phase analyzer (digital raster) is considered. It is shown that, unlike a phase raster with a mechanical drive, a digital raster provides the possibility of automation and increased measurement accuracy, reducing the weight and size characteristics of the measuring instrument. A method for constructing a digital raster is proposed, based on the use of photomatrices in combination with computer technologies. To ensure the required accuracy of the developed opto-electronic devices, the sources and components of the measurement error were investigated. The influence of the discrete structure of a digital raster on the error in measuring image coordinates has been studied. Mathematical expressions are obtained for calculating the limiting values of coordinate measurement errors caused by parasitic phase modulation that occurs when using a digital raster (sampling error). The dependence of these errors on image parameters and pixel size has been determined. It is shown that, based on the permissible maximum sampling error, it is possible to calculate the required dimensions of a photomatrix pixel, while the size of the sampling pixel can be larger than the size of the photomatrix pixel, which is very signifi cant from the point of view of energy relations. The results obtained will be useful in the development of optical-electronic means of angular and linear measurements with digital rasters.
本研究考虑了利用数字相位分析仪(数字光栅)开发基于焦平面阵列(光矩阵)的线性和角度测量光学电子仪器的问题。研究表明,与带机械传动的相位光栅不同,数字光栅可以实现自动化,提高测量精度,减少测量仪器的重量和尺寸。在结合计算机技术使用照相法的基础上,提出了一种构建数字光栅的方法。为确保所开发的光电设备达到所需的精度,对测量误差的来源和组成部分进行了研究。研究了数字光栅的离散结构对测量图像坐标误差的影响。通过数学表达式,计算了在使用数字光栅(采样误差)时由寄生相位调制引起的坐标测量误差的极限值。确定了这些误差与图像参数和像素大小的关系。结果表明,根据允许的最大采样误差,可以计算出光栅像素的所需尺寸,而采样像素的尺寸可以大于光栅像素的尺寸,从能量关系的角度来看,这一点非常重要。所获得的结果将有助于开发利用数字光栅进行角度和线性测量的光学电子手段。
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引用次数: 0
Estimation of traditional numerical characteristics of lognormal distribution laws of a one-dimensional random variable in conditions of large volume statistical data 在大量统计数据条件下估计一维随机变量对数正态分布规律的传统数字特征
Pub Date : 2024-04-05 DOI: 10.32446/0368-1025it.2024-2-23-29
A. V. Lapko, V. A. Lapko
The efficiency of estimating the numerical characteristics of a family of the lognormal distribution law of a onedimensional random variable under conditions of large volumes of statistical data is considered. To circumvent the problem of large samples, methods of discretization the range of values of a random variable based on the formulas of Sturges, Brooks-Carruthers, Heinhold-Gaede and the formula proposed by the authors of this article are used. Data arrays have been generated that make it possible to evaluate the numerical characteristics of the laws of distribution of random variables, taking into account their discrete values. Based on the transformed data arrays, estimates of the mathematical expectation, standard deviation, skewness and kurtosis coefficients were calculated. Estimates of the numerical characteristics of the considered distribution laws under the conditions of a continuous and discrete random variable are compared for different volumes of initial statistical data. The effectiveness of methods for estimating the numerical characteristics of the family of the lognormal distribution law based on the initial statistical data and on the results of transformations of these data using known discretization formulas has been established. The reliability of the comparison of the effectiveness indicators of the studied methods was confirmed by using the Kolmogorov-Smirnov criterion. It is shown that the discretization formula proposed by the authors of this article is better and more effective compared to traditional methods.
本研究考虑了在大量统计数据条件下估算一维随机变量对数正态分布规律族数值特征的效率问题。为了规避大样本问题,使用了基于 Sturges、Brooks-Carruthers、Heinhold-Gaede 公式和本文作者提出的公式的随机变量取值范围离散化方法。生成的数据阵列可以评估随机变量分布规律的数字特征,同时考虑到其离散值。根据转换后的数据阵列,计算出数学期望、标准偏差、偏度和峰度系数的估计值。在连续和离散随机变量的条件下,对所考虑的分布规律的数字特征进行了估计,并针对不同的初始统计数据量进行了比较。根据初始统计数据和使用已知离散化公式对这些数据进行转换的结果,确定了估计对数正态分布定律族数值特征的方法的有效性。使用 Kolmogorov-Smirnov 准则确认了所研究方法有效性指标比较的可靠性。结果表明,本文作者提出的离散化公式比传统方法更好、更有效。
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引用次数: 0
Method for asynchronous analysis of a glottal source based on a two-level autoregressive model of the speech signal 基于语音信号两级自回归模型的声源异步分析方法
Pub Date : 2024-04-05 DOI: 10.32446/0368-1025it.2024-2-55-62
V. V. Savchenko, L. V. Savchenko
The task of analyzing a glottal source over a short observation interval is considered. The acute problem of insufficient performance of known methods for analyzing a glottal source is pointed out, regardless of the mode of data preparation: synchronous with the main tone of speech sounds or asynchronous. A method for analyzing the glottal source based on a two-level autoregressive model of the speech signal is proposed. Its software implementation based on the high-speed Burg-Levinson computational procedure is described. It does not require synchronization of the sequence of observations used with the main tone of the speech signal and is characterized by a relatively small amount of computational costs. Using the described software implementation, a full-scale experiment was set up and conducted, where the vowel sounds of the control speaker’s speech were used as the object of study. Based on the results of the experiment, the increased performance of the proposed method was confirmed and its requirements for the duration of the speech signal during voice analysis in real time were formulated. It is shown that the optimal duration is in the range from 32 to 128 ms. The results obtained can be used in the development and research of digital speech communication systems, voice control, biometrics, biomedicine and other speech systems where the voice characteristics of the speaker’s speech are of paramount importance.
研究考虑了在较短观察间隔内分析声源的任务。研究指出,无论采用何种数据准备模式:与语音主音同步或非同步,已知的喉音源分析方法都存在性能不足的严重问题。本文提出了一种基于语音信号两级自回归模型的声源分析方法。介绍了基于高速 Burg-Levinson 计算程序的软件实现方法。该方法无需将观测序列与语音信号的主音同步,而且计算成本相对较低。利用所描述的软件实现,建立并进行了一次全面的实验,将对照组说话者语音中的元音作为研究对象。根据实验结果,确认了所提方法性能的提高,并制定了实时语音分析过程中对语音信号持续时间的要求。结果表明,最佳持续时间范围为 32 至 128 毫秒。所获得的结果可用于数字语音通信系统、语音控制、生物识别、生物医学和其他语音系统的开发和研究,在这些系统中,说话者的语音特征至关重要。
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引用次数: 0
Comparative analysis and classification of measurement procedures and procedures for transferring of unit of quantity as elements of metrological traceability chain of measurement results 作为测量结果计量溯源链要素的测量程序和量值单位传递程序的比较分析和分类
Pub Date : 2024-04-05 DOI: 10.32446/0368-1025it.2024-2-63-72
A. Tumilovich
The article analyzes types of measurement procedures and procedures for transferring a unit of quantity, such as: primary reference measurement procedures, reference measurement procedures, calibration procedures, validation procedures, end-user measurement procedures and measurement procedures. The article discusses requirements for developing the presented procedures, their research and approval. The article presents a classification of procedures depending on their place in metrological traceability chain, type of determined metrological characteristics and their application in the field of regulation. Based on the results of the analysis of regulatory documents, a table that describes basic requirements for development and approval of measurement procedures and procedures for transferring a unit of quantity is presented. The article also discusses requirements established for conformity assessment procedures for measurement procedures and procedures for transferring а unit of quantity, such as certification, validation and verification of procedures. The article presents definitions and scope of application for conformity assessment of measurement procedures and procedures for transferring a unit of quantity. Based on the analysis of requirements for conformity assessment of procedures, a flowchart for selecting appropriate conformity assessment procedure is presented. Due to this scheme, laboratories will be able to unambiguously choose one or another conformity assessment procedure to approve the required measurement method or method of transferring a unit of value. In particular, in preparation for accreditation for compliance with the requirements of ISO/IEC 17025-2017 “General requirements for the competence of testing and calibration laboratories.” The proposed scheme of choosing a procedure for conformity assessment of a specific measurement procedure eliminates ambiguity of the requirements of regulatory documents.
文章分析了测量程序和量值单位传递程序的类型,如:主要参考测量程序、参考测量程序、校准程序、验证程序、最终用户测量程序和测量程序。文章讨论了制定、研究和批准程序的要求。文章根据程序在计量溯源链中的位置、确定的计量特性类型及其在监管领域的应用,对程序进行了分类。根据对规范性文件的分析结果,提出了一个表格,描述了制定和批准测量程序和量值单位传递程序的基本要求。文章还讨论了为测量程序和量值单位传递程序的合格评定程序制定的要求,如程序的认证、确认和验证。文章介绍了测量程序和量值单位传递程序合格评定的定义和适用范围。根据对程序合格评定要求的分析,提出了选择适当合格评定程序的流程图。有了这一方案,实验室就能明确地选择一种或另一种合格评定程序,以批准所需的测量方法或量值单位传递方法。特别是在准备按照 ISO/IEC 17025-2017 "检测和校准实验室能力的通用要求 "的要求进行认可时。选择特定测量程序合格评定程序的拟议方案消除了规范性文件要求的模糊性。
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引用次数: 0
Method of instantaneous signal synchronization of measuring pulse generators 测量脉冲发生器的瞬时信号同步方法
Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2024-1-48-55
O. G. Bondar, E. O. Brezhneva, M. D. Pushkarev
The synchronization methods used in the pulse generators of the G5 measuring group in the external trigger mode are analyzed. The factors determining the error in the formation of time intervals in this mode have been studied. It is shown that the main source of errors in the formation of time intervals during external triggering of measuring pulse generators is the variation in the position of the clock generator reference pulses relative to the external trigger pulses. An analytical review of synchronization methods based on the sampling of time intervals by a multi-tap delay line as a pulse signal propagates along it is carried out. The method of instantaneous synchronization of output pulses is proposed, using sampling of the period of the reference pulses of the clock generator with a multi-tap delay line and fixing the position of the edge of the external trigger pulse within the period of the reference frequency by triggers that control the multiplexer, which connects the output of the multi-tap delay line to the output of the device, at which the edge of the next reference clock pulse generator lags by a minimum time from the front of the external trigger pulse. A device is presented that makes it possible to implement the proposed solution. The simulation of the device was carried out, illustrating the details of its functioning. Jitter was assessed on a prototype device using an integrated 5-tap delay line with a total delay of 20 ns. The method can be applied in measuring pulse generators and belongs to the field of pulse technology.
分析了 G5 测量组脉冲发生器在外部触发模式下使用的同步方法。研究了在这种模式下形成时间间隔误差的决定因素。结果表明,测量脉冲发生器外部触发时形成时间间隔误差的主要原因是时钟发生器参考脉冲相对于外部触发脉冲的位置变化。本文对基于脉冲信号沿多抽头延迟线传播时对时间间隔进行采样的同步方法进行了分析评述。提出了输出脉冲瞬时同步的方法,利用多抽头延迟线对时钟发生器参考脉冲的周期进行采样,并通过控制多路复用器的触发器将外部触发脉冲的边缘位置固定在参考频率的周期内,多路复用器将多抽头延迟线的输出连接到设备的输出,在该设备上,下一个参考时钟脉冲发生器的边缘与外部触发脉冲的前沿滞后最短的时间。本文介绍了一种能够实现拟议解决方案的设备。对该设备进行了仿真,说明了其工作细节。在使用总延迟为 20 ns 的集成 5 抽头延迟线的原型设备上对抖动进行了评估。该方法可用于测量脉冲发生器,属于脉冲技术领域。
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引用次数: 0
Ensuring metrological traceability of reference materials of gas mixtures composition 确保气体混合物成分标准物质的计量可追溯性
Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2024-1-61-66
A. V. Kolobova
The modern concept of metrological assurance for gas analytical measuring instruments with the use of reference materials of gas mixtures composition in cylinders under pressure is presented. The reference materials of gas mixtures composition of approved type in cylinders under pressure, which are the most often means of mole fraction and mass concentration units transfer in gas analytical measurements, are considered. The certified value in these reference materials is the content of the target component (or components) in the gas medium (analytical matrix). All the produced reference materials of gas mixtures composition, which are used for ensuring the uniformity of measurements are traceable to the State primary standard of units of mole fraction, mass fraction and mass concentration of components in gas and gas condensate media GET 154-2019, which characteristics are confirmed on the international level by the results of about 90 international comparisons. The paper presents a methodology for ensuring metrological traceability of reference materials of gas mixtures composition using GET 154-2019, taking into account the constantly increasing park of gas analytical instruments and the emergence of new measuring tasks in various fields of industry and environmental control. Currently, a park of secondary and working standards has been created at enterprises producing reference materials of gas mixtures composition, and their traceability to GET 154-2019 has been implemented according to the state verification scheme. The paper presents the results of international comparisons with participation of GET 154-2019, confirming the comparability of the obtained and reference value of the target component content in reference gas mixtures at the international level. The variety and large number of relevant gas analytical measurement tasks in various industries and the social sphere determines the need to choose priority areas for improving the existing reference base, including the structure of the GET 154 Standard and the nomenclature of reference gas mixtures. The strategic program of the Gas Analysis working group of the Consultative Committee of the Amount of Substance of the International Bureau of Weights and Measures developed for the period up to 2030 has been analysed and a review of the long-term tasks of gas analytical measurements is given. The currently existing GET 154-2019 Standard of the latest generation provides reproduction, storage and transfer of the components’ mole fraction units in gas and gas condensate media in the range from 1.5·10 –8 to 99.99999 %, and mass concentration units in the range from 1.0·10–6 to 2.0·105 mg/m3, what is confirmed by the results of participation in international comparisons and published CMC positions in the International database of calibration and measurement capabilities (about 400 CMCs positions).
本文介绍了使用钢瓶加压气体混合物成分标准物质为气体分析测量仪器提供计量保证的现代理念。本文考虑了气瓶中经批准的气体混合物成分标准物质,这些标准物质是气体分析测量中最常用的分子分数和质量浓度单位传递手段。这些标准物质的认证值是气体介质(分析基质)中目标成分的含量。所有用于确保测量均匀性的气体混合物成分标准物质都可追溯到气体和气体凝析介质 GET 154-2019 中各组分的摩尔分数、质量分数和质量浓度单位的国家主要标准。本文介绍了使用 GET 154-2019 确保气体混合物成分标准物质计量溯源性的方法,同时考虑到气体分析仪器园区的不断扩大以及工业和环境控制各领域新测量任务的出现。目前,已在生产混合气体成分标准物质的企业中建立了二级标准和工作标准园,并根据国家验证计划实现了这些标准物质与 GET 154-2019 的溯源。本文介绍了参与 GET 154-2019 国际比对的结果,证实所获得的参考混合气体中目标成分含量与参考值在国际上具有可比性。各行各业和社会领域的相关气体分析测量任务种类繁多,数量巨大,这决定了需要选择优先领域来改进现有的参考基础,包括 GET 154 标准的结构和参考气体混合物的命名。对国际计量局物质数量咨询委员会气体分析工作组制定的 2030 年之前的战略计划进行了分析,并对气体分析测量的长期任务进行了回顾。现行的最新一代 GET 154-2019 标准规定了气体和气体冷凝物介质中 1.5-10 -8 至 99.99999 % 范围内的组分摩尔分数单位和 1.0-10-6 至 2.0-105 mg/m3 范围内的质量浓度单位的再现、存储和传输,这一点在参与国际比对的结果以及校准和测量能力国际数据库(约 400 个 CMC 位置)中公布的 CMC 位置中得到了证实。
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引用次数: 0
State primary special standard of the unit of length GET 199-2024: ensuring the uniformity of measurements of high-precision total stations and their analogues in the mode of three-dimensional measurements 长度单位国家主要特殊标准 GET 199-2024:确保高精度全站仪及其类似设备在三维测量模式下的测量一致性
Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2024-1-12-18
S. I. Donchenko, O. V. Denisenko, I. S. Silvestrov, A. V. Mazurkevich, V. I. Lesnichenko
The metrological support of optical-electronic means of measuring spatial coordinates is described. To meet modern consumer requirements for the accuracy of measurements of spatial coordinates with electronic tacheometers and their analogues (laser scanners, absolute trackers), the State primary special standard of the unit of length GET 199-2024 includes technical means for reproducing, storing and transmitting the unit of length in three-dimensional measurement mode. A reference complex of three-dimensional measurements (coordinate measurements, coordinate increments) has been developed and studied. The means and methods for transmitting a unit of length are presented, as well as the metrological characteristics of the GET 199-2024 in the mode of measuring coordinate increments (length). The sources of non-excluded systematic error and the standard deviation of the measurement result are determined.  As a result of the research performed, it became possible to reproduce a unit of length in the mode of measuring coordinate increments in the range of 0–60 m with a standard deviation of no more than 25 μm for 10 independent measurements and a non-excluded systematic error (with a confidence probability of 0.99) of 19 μm. The functionality of the GET 199-2024 will allow solving current problems of metrological support for high-precision electronic total stations and their analogues in three-dimensional measurement mode.
描述了测量空间坐标的光学电子手段的计量支持。为满足现代消费者对使用电子测距仪及其类似仪器(激光扫描仪、绝对跟踪仪)测量空间坐标精度的要求,长度单位 GET 199-2024 国家主要特殊标准包括在三维测量模式下复制、存储和传输长度单位的技术手段。已经开发和研究了三维测量(坐标测量、坐标增量)的参考综合体。文中介绍了传输长度单位的手段和方法,以及 GET 199-2024 在测量坐标增量(长度)模式下的计量特性。确定了未排除系统误差的来源和测量结果的标准偏差。 研究结果表明,在 0-60 米的坐标增量测量模式下,10 次独立测量的标准偏差不超过 25 μm,不排除系统误差(置信度为 0.99)为 19 μm,从而可以再现长度单位。GET 199-2024 的功能可解决目前高精度电子全站仪及其类似仪器在三维测量模式下的计量支持问题。
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引用次数: 0
Methodology for determining the degree of magnetic induction of transformers with a sinusoidal magnetic flux 正弦磁通变压器磁感应强度的测定方法
Pub Date : 2024-03-08 DOI: 10.32446/10.32446/0368-1025it.2024-1-35-39
S. Plotnikov
The research presented in the article is aimed at reducing losses in the magnetic circuits of electrical machines. These losses amount to up to 5 % of the generated electricity, do not depend on the load and can increase over the life of the equipment. To effectively design and construct transformers with low no-load losses, total losses in steel are minimized by optimizing the crystal grain size and thickness of core sheets, improving the steel texture and magnetic circuit design, etc. However, the hysteresis, classical eddy current and anomalous eddy current components of losses in steel react in different directions to these measures, which does not effectively minimize total losses. To determine the three components of losses, a modernized method of three frequencies is proposed, which takes into account the dependence of the hysteresis loss coefficient on frequency. A formula for correcting this coefficient is derived. It is shown that the indicator of the degree of magnetic induction given in most modern scientific sources in the expression for eddy current anomalous losses has become irrelevant. A method for calculating this indicator for the core of a specific transformer is presented, which uses the loss components and total losses in steel found by the method of three frequencies and the total losses in steel at a reduced primary voltage. For the transformer under study, the degree of magnetic induction in anomalous losses was 1.88. The results obtained can be used in the design of dry and oil transformers of different powers operating with a sinusoidal magnetic flux.
文章中介绍的研究旨在减少电机磁路中的损耗。这些损耗高达发电量的 5%,与负载无关,并会随着设备寿命的延长而增加。为了有效地设计和制造空载损耗低的变压器,需要通过优化晶体晶粒大小和铁芯片厚度、改善钢材质地和磁路设计等方法将钢材的总损耗降至最低。然而,钢中损耗的磁滞、经典涡流和异常涡流成分对这些措施的反应方向不同,无法有效地将总损耗降至最低。为了确定损耗的三个组成部分,提出了一种现代化的三频方法,该方法考虑到了磁滞损耗系数对频率的依赖性。得出了修正该系数的公式。结果表明,大多数现代科学资料在涡流反常损耗的表达式中给出的磁感应强度指标已变得无关紧要。本文提出了一种针对特定变压器铁芯计算该指标的方法,该方法使用了通过三频法计算出的损耗分量和钢材总损耗,以及在初级电压降低时的钢材总损耗。对于所研究的变压器,异常损耗的磁感应强度为 1.88。所得结果可用于设计以正弦磁通运行的不同功率的干式和油式变压器。
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引用次数: 0
State primary special standard of acceleration unit in the field of gravimetry GET 190-2023: reproduction and transmission of the unit under the influence of geophysical factors 重力测量领域加速度单位国家初级特殊标准 GET 190-2023:地球物理因素影响下的单位再现和传输
Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2024-1-4-11
L. F. Vitushkin, E. P. Krivtsov, P. P. Krolitsky, V. V. Nalivaev, O. A. Orlov, M. M. Haleev
The relevance of research on the reproduction and transmission of the acceleration unit in gravimetry is determined by the development of measuring instruments for the absolute value of the acceleration of free fall and its changes. Qualitative and quantitative changes in the instrument base are due to the requirements of applied tasks solved using gravimetric data in such fields as geodesy, navigation, geodynamics, as well as the expansion of the field of practical application of absolute gravimeters. At the same time, in order to solve applied problems, along with accuracy requirements at a level close to the maximum achievable at the current level of technology development, maximum territorial coverage of measurement sites within the entire territory of the Russian Federation is often necessary. The accuracy of the results obtained with the help of measuring instruments is determined by the level of their metrological support, the main stages of which are the reproduction of the corresponding unit by the standard and its transfer to the measuring instrument. An analysis of possible sources of errors in gravimetric equipment has shown that when reproducing and transmitting the acceleration unit in gravimetry, it is necessary to take into account the influence of geophysical factors that manifest themselves as additional accelerations of a gravitational or inertial nature. The distribution of the gravitational field within a gravimetric point can manifest itself as an additional constant acceleration. Seismic processes and lunar and solar tides manifest themselves as variable accelerations. For various stages of metrological support of gravimetric devices, the mechanisms of the effects of such accelerations have been studied, as well as methods for accounting and reducing their influence using additional equipment have been developed. An additional gravimetric point with a cryogenic relative gravimeter and a broadband seismometer, as well as transported absolute ballistic and relative quartz gravimeters, were introduced into the State primary special standard of acceleration units in the field of gravimetry GET 190-2023.
重力测量学中加速度单位的再现和传输研究的相关性是由自由落体加速度绝对值及其变化的测量仪器的发展决定的。由于大地测量学、导航、地球动力学等领域利用重力测量数据解决应用任务的要求,以及绝对重力仪实际应用领域的扩大,仪器基础发生了质和量的变化。与此同时,为了解决应用问题,同时满足接近当前技术发展水平所能达到的最高精度要求,通常需要在俄罗斯联邦全境最大限度地覆盖测量点。借助测量仪器获得的结果的准确性取决于其计量支持的水平,其主要阶段是按照标准复制相应的单位并将其传输到测量仪器。对重力测量设备中可能的误差来源进行的分析表明,在重力测量中复制和传输加速度单位时,必须考虑到地球物理因素的影响,这些因素表现为重力或惯性性质的附加加速度。重力测量点内的重力场分布可以表现为额外的恒定加速度。地震过程以及月球和太阳潮汐则表现为可变加速度。针对重力测量装置的不同计量支持阶段,对这些加速度的影响机制进行了研究,并开发了使用附加设备计算和减少其影响的方法。在重力测量领域的加速度单位国家主要特殊标准 GET 190-2023 中,增加了一个带有低温相对重力仪和宽带地震仪的重力测量点,以及运输绝对弹道重力仪和相对石英重力仪。
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引用次数: 0
Dynamics of changes in the temperature coefficient of electrical conductivity of distilled water in conductometric cells during heating and cooling 加热和冷却过程中电导测量池中蒸馏水电导率温度系数的动态变化
Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2023-12-56-60
I. Ageev, Yuri M. Rybin
The problem of taking into account the influence of air on the properties of distilled water is considered, namely the lack of a single generally accepted method for calculating such an influence. The sensitivity of the structure of water to the influence of external factors is described and the possibility of recording and studying such factors by changes in the temperature coefficient of electrical conductivity of water is shown. The dependences of the temperature coefficient of electrical conductivity of distilled water on the rate of change in water temperature, the degree of filling of conductometric cells, as well as on the intensity of the exchange of carbon dioxide between water and air across their interface have been studied. It is noted that these metabolic processes are currently insufficiently studied. A hardware-software measuring complex has been developed and manufactured to study the temperature coefficient of electrical conductivity of water when its temperature changes within the range of 20–55 °C. The temperature coefficient of electrical conductivity of water in sealed conductometric cells was measured at different degrees of filling the cells with distilled water and the rate of heating and cooling of water. The degree of filling of the cells varied within the range of 10–100 %, the rate of change in water temperature varied within the range of 0.04–2.00 °C/min. With a constant heating and cooling time of 15 minutes in all experiments, the change in speed was achieved by changing the temperature of the heating element. The integral temperature coefficient of electrical conductivity is calculated based on the initial and final values of electrical conductivity and water temperature in each measurement cycle. The dependences of the temperature coefficient of electrical conductivity on the rate of change in water temperature at several constant degrees of cell filling were obtained. It has been shown that with a constant ratio of the volumes of water and air in the cell and an increase in the rate of heating of water, the temperature coefficient of electrical conductivity of water decreases by 19–22 %. It has been established that at a constant rate of water heating, with a decrease in the volume of water in the cell, the temperature coefficient of electrical conductivity of water decreases by 40–42 %. The results obtained can be used to quantify the dissociation coefficient of carbonic acid, the mobility of hydrogen ions, as well as the intensity of the gas exchange process under various external influences on water. Refinement of data on the electrical conductive properties of water and processes at the water/air interface is necessary for the development of models of atmospheric phenomena and climate change, as well as for the creation of sensors for weak changes in environmental parameters for the purposes of both environmental monitoring and medical diagnostics.
考虑到空气对蒸馏水特性的影响问题,即缺乏计算这种影响的单一公认方法。描述了水的结构对外部因素影响的敏感性,并展示了通过水的导电温度系数的变化来记录和研究这些因素的可能性。我们研究了蒸馏水的电导率温度系数与水温变化率、电导池的填充程度以及水和空气在界面上交换二氧化碳的强度之间的关系。值得注意的是,目前对这些新陈代谢过程的研究还不够充分。为了研究水在 20-55 °C 范围内温度变化时的电导率温度系数,我们开发并制造了一个硬件-软件测量综合装置。在不同的蒸馏水填充度以及水的加热和冷却速度下,测量了密封电导池中水的电导率温度系数。电池的填充度在 10-100 % 的范围内变化,水温变化率在 0.04-2.00 °C/min 的范围内变化。在所有实验中,加热和冷却时间恒定为 15 分钟,速度的变化是通过改变加热元件的温度来实现的。根据每个测量周期中电导率和水温的初始值和最终值,计算出电导率的积分温度系数。得出了在几个恒定的电池填充度下,电导率温度系数与水温变化率的关系。结果表明,当电池中水和空气的体积比保持不变,且水的加热速率增加时,水的导电率温度系数会降低 19-22%。实验证明,在水加热速度不变的情况下,随着电池中水体积的减少,水的导电温度系数会降低 40-42%。所获得的结果可用于量化碳酸的解离系数、氢离子的流动性以及水在各种外部影响下气体交换过程的强度。完善有关水的导电特性和水/空气界面过程的数据,对于开发大气现象和气候变化模型,以及创建用于环境监测和医疗诊断的环境参数微弱变化传感器都是必要的。
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Izmeritel`naya Tekhnika
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