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A Review on Recent Advances in Materials of Hybrid Organic–Inorganic Perovskite Solar Cells 有机-无机钙钛矿杂化太阳能电池材料研究进展
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id181
Kawther A. Kalaph, A. Jafar, N. Abdalameer, Amar Moula Hmood
This study is an emphasis on the metal halide perovskite solar cells that are susceptible to factors that influence their power conversion efficiency (PCE). Perovskite solar cells, also known as PSCs, have been shown to have a high power conversion efficiency (PCE) due to a number of various factors. As they reached a power conversion efficiency of 25%, solar cells based on metal halide perovskite were a game-changer in the quest for photovoltaic performance. A flurry of activity in the fields of structure design, materials chemistry, process engineering, and device physics has helped the solid-state perovskite solar cell to become a leading contender for the next generation of solar energy harvesters in the world today. This follows up on the ground-breaking development of the solid-state perovskite solar cell in 2012. This cell has a higher efficiency compared to commercial silicon or other organic and inorganic solar cells, as well as a lower cost of materials and processes. However, it has the disadvantage that these high efficiencies can only be obtained with lead-based perovskites, which increases the cost of the cell. As a result of this fact, a new study area on lead-free metal halide perovskites was established, and it is now exhibiting a remarkable degree of vibrancy. This provided us with the impetus to review this burgeoning area of research and discuss possible alternative elements according to current theoretical and practical investigations that might be utilized to replace lead in metal halide perovskites as well as the features of the perovskite materials that correspond to these elements.
本研究的重点是金属卤化物钙钛矿太阳能电池易受影响其功率转换效率(PCE)的因素。钙钛矿太阳能电池,也被称为PSCs,由于许多不同的因素,已被证明具有很高的功率转换效率(PCE)。基于金属卤化物钙钛矿的太阳能电池达到了25%的能量转换效率,在追求光伏性能方面改变了游戏规则。在结构设计、材料化学、工艺工程和设备物理等领域的一系列活动,帮助固态钙钛矿太阳能电池成为当今世界下一代太阳能收集器的主要竞争者。这是继2012年固态钙钛矿太阳能电池的突破性发展之后的又一进展。与商业硅或其他有机和无机太阳能电池相比,这种电池具有更高的效率,以及更低的材料和工艺成本。然而,它的缺点是这些高效率只能通过铅基钙钛矿获得,这增加了电池的成本。由于这一事实,建立了无铅金属卤化物钙钛矿的一个新的研究领域,并且现在显示出显著的活力。这为我们提供了回顾这一新兴研究领域的动力,并根据当前的理论和实践研究讨论可能用于取代金属卤化物钙钛矿中的铅的替代元素,以及与这些元素对应的钙钛矿材料的特征。
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引用次数: 0
Preparation and Evaluation of Mebendazole 5% Antiparasitic Suspension for Veterinary Use 5%甲苯达唑兽用抗寄生虫混悬液的制备及评价
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id242
F. Majed, Hashim Wahib, Orooba M. Saeed, Ahmed Al-Joubary, N. Laith, Mohammed Jassem
The purpose of this study is to prepare a new formulation of Mebendazole suspension for veterinary therapeutic and antiparasitic use at a concentration of 5% of the poorly water soluble drug mebendazole using suspending agents, dispersing agents such as tween 80, polypropylene glycol, preservatives, and other salts to titrate the PH of the resulting mixtures. Information about all the materials used in the preparation of the formula was collected from pharmacopeia, while materials were provided by Samarra Company. and prepared about three formulae, from which the final one prepared. A study was conducted on the stability of the new formula in different temperature conditions (40, 50, and 60) °C by comparing any change in physicochemical properties concerning form, viscosity, and pH in different storage rooms and other temperatures for 18 months. showed that The results of the new drug proved its stability, both quantitative and qualitative results for suspension 5% formula as well as its physicochemical properties and viscosity tested and also conducted   clinically therapy in the central veterinary hospital the findings demonstrate that Mebendazol is a promising new formulation of it for treatment of hydatid diseases without showing significantly liver toxicity.
本研究的目的是制备一种新的用于兽医治疗和抗寄生虫的咪苯达唑混悬液配方,该混悬液浓度为低水溶性药物咪苯达唑的5%,使用悬浮剂、分散剂(如t80)、聚丙烯乙二醇、防腐剂和其他盐滴定所得混合物的PH值。配方所用材料资料均来自药典,材料由萨迈拉公司提供。并准备了大约三个公式,最后一个是由它们准备的。对新配方在不同温度条件下(40,50和60°C)的稳定性进行了研究,通过比较在不同的储藏室和其他温度下18个月的物理化学性质的变化,包括形式、粘度和pH值。结果表明,该新药具有稳定性,对悬浮液5%配方的定量和定性结果以及其理化性质和粘度进行了测试,并在中心兽医院进行了临床治疗,结果表明,美苯达唑是一种很有前景的治疗包虫病的新配方,且无明显的肝毒性。
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引用次数: 0
Improving the Mechanical Properties of a Car Bumper by Using Glass Fiber Reinforced Composite Laminates and Nano-ceramic Filler 用玻璃纤维增强复合材料层合板和纳米陶瓷填料改善汽车保险杠的力学性能
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id189
N. Hayder, I. Mahmood
In this study, mechanical tests were performed on a Chinese car bumper of the Chery model, which was chosen for examination due to its widespread use in Iraqi streets. It was also compared to the best specimens obtained in these study stages. Glass fiber mats and nanoparticles have been mixed with the unsaturated polyester resin (UPE) in two stages. In the first stage, the fibers have been mixed with a volume fraction of 14% and the mechanical properties have been calculated. In the second stage, different weight fractions of nanoparticles of zirconium oxide (ZrO2) were added to the mixture, and the mechanical tests were recalculated. The experimental test's results illustrated that the tensile strength, fracture toughness, and damping ratio of the composite material were enhanced when mixing 14% vf of glass fiber mats with unsaturated polyester resin by about (285.85%, 207.56%, and 100%) respectively, compared to the car bumper, while the ratio of impact resistance decreased by about (-24.55%). The same tests were repeated after adding different weight fractions (1%, 2%, 2.5%, 3%, 3.5%, 4%) of (ZrO2) and it was observed that adding the nanoparticles had a significant effect on the mechanical properties since at first, it improved them until the nanoparticles ratio reached 2.5 wt.%, but any higher addition than this ratio caused a decrease in the enhancement of the mechanical properties. Thus, it was found that adding 2.5 wt.% nanoparticles gave us the best improvement in the tensile strength, impact resistance, fracture toughness, and damping ratio by about (436.32%, 47.28%, 438.66%, and 52.3%) respectively, compared to the car bumper properties.
在本研究中,对奇瑞车型的中国汽车保险杠进行了力学测试,因为奇瑞车型在伊拉克街道上广泛使用,所以被选中进行测试。还将其与这些研究阶段获得的最佳标本进行了比较。将玻璃纤维垫和纳米颗粒与不饱和聚酯树脂(UPE)分两个阶段混合。在第一阶段,以14%的体积分数混合纤维,并计算其力学性能。在第二阶段,在混合物中加入不同重量分数的氧化锆纳米颗粒(ZrO2),并重新计算力学试验。试验结果表明,当玻璃纤维席子与不饱和聚酯树脂的掺量为14% vf时,复合材料的抗拉强度、断裂韧性和阻尼比分别比汽车保险杠提高了约(285.85%、207.56%和100%),抗冲击比降低了约(-24.55%)。在添加不同重量分数(1%、2%、2.5%、3%、3.5%、4%)的(ZrO2)后,重复进行相同的试验,观察到纳米颗粒的加入对力学性能有显著影响,因为纳米颗粒的加入在一开始可以改善它们,直到纳米颗粒的比例达到2.5 wt.%,但任何高于此比例的添加都会导致力学性能的增强减弱。因此,与汽车保险杠性能相比,添加2.5 wt.%的纳米颗粒可使其抗拉强度、抗冲击性能、断裂韧性和阻尼比分别提高约436.32%、47.28%、438.66%和52.3%。
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引用次数: 1
Production of Ductile Iron Using Inside-Mold Treatment Technique 用模内处理技术生产球墨铸铁
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id176
Harith Hammody Abdullah, Ali Awad Ibraheem, Ahmed Abdel Ameer Khudhair
Ductile Cast Iron is a widely used cast iron. Ductile iron applications are used in various sectors of modern mechanical industries. Ductile iron has wide uses in the field of car industry, military industries, agricultural equipment, construction and mines. The production of ductile iron faces many technical difficulties in our local factories due to the difficulty in providing equipment and technologies for its production by common methods. In this study, we resorted to applying one of the modern methods in the production of ductile iron, which is the treatment process for the molten iron in the sand mold. Magnesium alloys were added inside the sand mold within the casting stream and in the casting cavity for casting production. Specific weights were added and experiments were performed to determine the fusible chemical composition appropriate for preparing ductile cast iron. The study proved that adding magnesium alloys inside the sand mold, whether inside the mold cavity or in the casting channel, is both a successful method for producing ductile iron alloys. It is possible to produce different types of ductile iron by controlling the ratio of alloy additions to the molten metal content during casting.
球墨铸铁是一种应用广泛的铸铁。球墨铸铁应用于现代机械工业的各个部门。球墨铸铁在汽车工业、军事工业、农业装备、建筑和矿山等领域有着广泛的用途。我国地方工厂球墨铸铁的生产面临着许多技术难题,因为一般的生产方法难以提供球墨铸铁的设备和技术。在本研究中,我们采用了一种现代球墨铸铁生产方法,即砂型铁液的处理工艺。在铸流内的砂型内和铸腔内添加镁合金进行铸造生产。为确定适合球墨铸铁制备的易熔化学成分,对其进行了配比试验。研究证明,在砂型内添加镁合金,无论是在型腔内还是在铸道内,都是生产球墨铸铁的一种成功方法。在铸造过程中,通过控制合金添加量与熔融金属含量的比例,可以生产出不同类型的球墨铸铁。
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引用次数: 0
The Influence of Aggressive Media on the Weight and Surface Hardness of Epoxy-Glass Waste Composite 侵蚀介质对环氧玻璃废料复合材料重量和表面硬度的影响
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id170
Hadeel I. Kadhim, Awham M. Hameed, B. Fahad
The world is evolving toward a circular economy, which focuses on decreasing waste and extending the life of commodities. This work suggests using waste of glass to prepare composite. Epoxy was reinforced 50% by weight using waste glass. At room temperature were prepared samples reinforced and unreinforced and immersed in five solutions (HCl, Water, NaOH, Kerosene and Benzene) for four weeks, to find out the resistance of the epoxy after reinforcing. It is found that reinforced samples have resistance of increased after immersion in corrosive media comparison pure epoxy and it was obvious that the hardness were modified by 57% and remain constant during the immersion period in solutions. After immersing specimens in HCl the weight of the specimens decreases by 3.6%, unlike other solutions the weight of the specimens’ increase. Indicating that epoxy gains resistance after being reinforced with glass waste, allowing it to be used in a variety of applications.
世界正在向循环经济发展,其重点是减少浪费和延长商品的使用寿命。本研究建议利用玻璃废料制备复合材料。用废玻璃增强环氧树脂50%的重量。在室温下制备增强和未增强的样品,在五种溶液(HCl、Water、NaOH、煤油和苯)中浸泡4周,测定增强后环氧树脂的耐磨性。结果表明,与纯环氧树脂相比,增强试样在腐蚀介质中浸泡后的耐磨性有所提高,硬度明显提高57%,且在溶液中浸泡期间硬度保持不变。在HCl溶液中浸泡后,样品的重量下降了3.6%,而在其他溶液中,样品的重量增加了。表明环氧树脂在用玻璃废料增强后获得阻力,使其可用于各种应用。
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引用次数: 0
Design of an Aluminum Foundry with Ceramic Fiber Insulation 陶瓷纤维保温铝铸造厂的设计
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id184
Sardam Ali Rasul, Zahraa A. Abdulkader, Qabas K. Abbas, Mersin S. Qadr, N. Switzner
Aluminum is one of the most versatile engineering metals, finding its use in a variety of fields including construction, architecture, aerospace, automotive, consumer products, and many more. The high demand for aluminum production is driven by its advantageous physical, chemical, and mechanical properties, such as a high strength to weight ratio and good corrosion resistance. Additionally, aluminum can be recycled using processes that require only a fraction of the energy required for primary production. Aluminum recycling is primarily accomplished by melting in foundries. In some aluminum foundries, a large amount of energy is lost due to poor insulation and an inaccurate knowledge of the crucible temperature. This project focused on designing a safe, efficient electric aluminum foundry. Using theoretical calculations, an electric foundry was designed to melt 3.0 kg of aluminum cans using ~9 MJ of energy. A prototype was successfully fabricated and tested with attention to the structural, thermal, and electrical design aspects. Experiments showed that the foundry was capable of melting 3.0 kg of aluminum cans using ~11 MJ of energy, which was close to the theoretical calculations. The normalized energy usage of the foundry was ~6.9 MJ per kg of pure aluminum produced, which compares well with benchmarked aluminum recycling foundries.
铝是最通用的工程金属之一,在各种领域都有应用,包括建筑、建筑、航空航天、汽车、消费品等等。铝生产的高需求是由其有利的物理、化学和机械性能驱动的,例如高强度重量比和良好的耐腐蚀性。此外,铝可以回收利用的过程只需要初级生产所需能源的一小部分。铝的回收主要是通过在铸造厂熔化来完成的。在一些铝铸造厂,由于绝缘不良和对坩埚温度的不准确了解,大量的能量损失了。本项目重点设计了一种安全、高效的电动铝铸造机。通过理论计算,设计了一个用~ 9mj能量熔化3.0 kg铝罐的电炉。在结构、热学和电气设计方面,成功地制造了一个原型并进行了测试。实验结果表明,该铸造厂熔化3.0 kg铝罐的能量为~11 MJ,与理论计算接近。铸造厂的标准化能耗约为6.9 MJ / kg纯铝,与基准铝回收铸造厂相当。
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引用次数: 0
Opting of an Organic Rankine Cycle Based on Waste Heat Recovery System to Produce Electric Energy in Cement Plant 基于余热回收系统的有机朗肯循环在水泥厂生产电能中的选择
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id194
Alaa H. Salum, Ban H. Ismail, Samer H. Sadik
This study investigates the feasibility of installing a waste heat recovery system (WHR) in a cement factory in Iraq using the organic thermal Rankine cycle (ORC). Heat losses in the cement industries represent high energy consumption percentages of the total energy inputs. The production of clinker is a sub-process in the cement manufacturing plant and consumes three quarters of the total energy used as heat from combustion. The main sources of waste heat in the cement plant are identified, from these sources of waste heat from the kiln surface to the air, hot air coming out of the clinker cooler, and preheating exhaust gases. It is possible to obtain the total waste heat from these sources in the range of 35-40% of the total heat input. This waste heat energy can be exploited by installing a waste heat recovery system in these plants to generate electricity. It is possible to generate electrical energy by 5.9 MW. When using an organic system to recycle hot gases in plants whose daily production is up to 6000 tons, the installation of such a system could lead to saving 82.5 tons of fuel oil consumption per day, and reducing carbon dioxide emissions by 99.12 tons per day.
本研究探讨了在伊拉克的一家水泥厂使用有机热朗肯循环(ORC)安装废热回收系统(WHR)的可行性。水泥工业的热损失占总能源投入的高能耗百分比。熟料的生产是水泥生产厂的一个子过程,消耗了燃烧热总能量的四分之三。确定了水泥厂废热的主要来源,从这些来源产生的废热从窑面散发到空气中,从熟料冷却器流出的热空气,以及预热废气。从这些热源获得的总废热在总热输入的35-40%之间是可能的。这些余热可以通过在这些工厂安装余热回收系统来发电来利用。可以产生5.9兆瓦的电能。在日产量高达6000吨的工厂中,如果使用有机系统回收热气体,每天可节省82.5吨燃料油消耗,每天可减少99.12吨二氧化碳排放。
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引用次数: 0
Investigation of the Epoxy Concentrations Effect on the Mechanical Properties of Polyurethane Foams 环氧树脂浓度对聚氨酯泡沫塑料力学性能影响的研究
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id225
Dhey Jawad Mohammed, N. Hadi, Z. Alobad
Thermosetting foam had a number of advantage in comparison with unfoamed polymer such as lightweights, higher specifics strength, and stiffness. In this work, preparations and characterizations of polymers foams from polyurethanes have carrying out by means of one shot methods for productions of microcellulars polymers that are using in the lower limp application. Many type of polyols (Local commercial market, Quickmast 110, and Quickmast 120) at equivalents ratios of (isocyanate:polyol) [1:1] mixing with 5 drops of distill water as chemicals blowing agent. Different amounts of epoxy resin [2.5, 5, 7.5, and 10 wt%] mixing with polyol using a magnetic stirrer for 30 min at 50 °C and 30 rpm. The hardener mixing with isocyanates in another container. These two solutions were mixing together, then water was added and mixing by hand to form polyurethane/ epoxy blend foam sample. The mechanical characteristics [hardness, tensile and compression] tests were achieved to display the effects of polyol type, epoxy concentration on the mechanical characteristics of the final product. The results of mechanical characteristics  increasing with additions of epoxy resin at the best ratio is 7.5 wt%.
与非发泡聚合物相比,热固性泡沫具有许多优点,如重量轻、比强度高和刚度高。在这项工作中,聚氨酯聚合物泡沫的制备和表征通过一次性方法进行了微细胞聚合物的生产,这些微细胞聚合物用于较低的柔软应用。许多类型的多元醇(本地商业市场,Quickmast 110和Quickmast 120)以(异氰酸酯:多元醇)的同等比例[1:1]与5滴蒸馏水混合作为化学发泡剂。不同量的环氧树脂[2.5,5,7.5,和10 wt%]与多元醇混合使用磁力搅拌器在50°C和30转/分下搅拌30分钟。硬化剂与异氰酸酯在另一个容器中混合。将这两种溶液混合在一起,然后加水,手工混合,形成聚氨酯/环氧树脂共混泡沫样品。通过力学特性[硬度、拉伸和压缩]试验来显示多元醇类型、环氧树脂浓度对最终产品力学特性的影响。结果表明,环氧树脂的最佳添加比为7.5%,其力学性能有所提高。
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引用次数: 0
Effect of Increasing Calcium Carbonate (as a Filler) on the Plastic Pipes Properties 添加碳酸钙填料对塑料管性能的影响
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id233
Fatima Atiye Lafta, Suhir Abdel Aziz Jabber, Thana'a Abdul Amir, Ali Nazim Abdul Kerim, Lehib Abdul Hussain
Calcium carbonate (CaCO3) was used as a filler in the mixture for plastic pipes to improve the mechanical properties of the product, this research dealt with the study of the effect of increasing the proportion of calcium carbonate (CaCO3) on the properties of the produced pipe through a factory application by preparation of five mixture of polyvinyl chloride with different proportions of calcium carbonate (3, 5, 8, 10, and 15)% with some additional materials for the manufacture of the plastic pipes by using the extrusion method to produce polyvinyl chloride pipes (110mm × 10bar × 6m) for transportation of drinking water,a series of tests were carried out on the raw materials: (bulk density, free flow and sieve analysis) and also on the final product: (dimensions, heat reversion, tensile strength, impact strength, resistance to external blows and strength characteristics determined by long-term hydrostatic strength (rupture), the results of the tests showed a decrease in the tensile strength by increasing the percentage of calcium carbonate addition and by a small amount up to 8% and the decrease became more clear when the percentage of calcium carbonate addition was more than 8%, the results obtained at the level of factory application have proved the possibility of increasing the proportion of calcium carbonate in the mixture of raw materials used in the manufacture of unplasticized polyvinyl chloride (U.P.V.C) pipes (from 3 to 8 %) and the results of the tests on the final product conformed to the certified specification for the proportion of 3, 5, and 8% and did not conform to the certified specification for proportions 10 and 15%.
采用碳酸钙(CaCO3)作为塑料管材混合料的填料,提高产品的力学性能,本研究通过工厂应用,通过制备不同碳酸钙比例(3、5、8、10、10)的聚氯乙烯混合料,研究增加碳酸钙(CaCO3)的掺量对所制管材性能的影响。15)%采用挤压法生产输送饮用水用的聚氯乙烯管道(110mm × 10bar × 6m),再加一些材料,对原料进行了一系列的测试:(容重、自由流量和筛分分析),并对最终产品进行了测试。(尺寸、热还原、抗拉强度、冲击强度、抗外界冲击和长期静水强度(断裂)决定的强度特性),试验结果表明,增加碳酸钙添加量的百分比和少量碳酸钙添加量达到8%时,拉伸强度下降,当碳酸钙添加量超过8%时,下降更加明显。在工厂应用水平上获得的结果证明,在制造未增塑聚氯乙烯(upvc)管道的原料混合物中,碳酸钙的比例可以增加(从3%到8%),最终产品的测试结果符合比例为3,5和8%的认证规范,而不符合比例为10和15%的认证规范。
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引用次数: 0
Electrical Power Generation from Industrial Waste Heat Sources According to the Iraqi Environment 根据伊拉克环境利用工业废热发电
Pub Date : 2022-10-20 DOI: 10.53523/ijoirvol9i2id206
Ashwaq Abdulameer Khalaf
There are a wide range of temperatures wasted in some Iraqi factories ranging from low to medium to high grades, offset by a wide variety of generation techniques and liquids that can be used, this diversity allows us to choose the appropriate generation techniques (and fluids type) with the available waste heat in our factories, allowing us to make the maximum benefit of this wasted thermal energy in accordance with the recommendations of the International Energy Conference. All over Iraq, thermal waste is an abundant source of emission-free power that is frequently overlooked. It is a byproduct of industrial processes that could lower energy costs and reduce overall emissions from electric generation. The thermal waste is produced as long as the operation running. Producing electrical power from thermal waste would help to reduce energy costs. This research paper will explain and discuss choosing the appropriate technology between the three suggested technologies. In addition, the paper will discuss choosing the appropriate organic liquid for (Organic Rankine Cycle) ORC to recover the heat and transform it into an energy based on the waste temperature of some Iraqi industries. Also, it will discuss the choice of appropriate technology for the quantity and quality of this heat. That would help to reduce the waste of energy and air pollution.
在伊拉克的一些工厂中,浪费的温度范围很广,从低到中到高,被各种各样的可使用的发电技术和液体所抵消,这种多样性使我们能够根据我们工厂中可用的废热选择适当的发电技术(和液体类型),使我们能够根据国际能源会议的建议最大限度地利用这种浪费的热能。在整个伊拉克,热废物是一种丰富的无排放能源,但经常被忽视。它是工业过程的副产品,可以降低能源成本,减少发电的总排放量。只要运行,就会产生热废物。利用热废物发电将有助于降低能源成本。这篇研究论文将解释和讨论在三种建议的技术之间选择合适的技术。此外,本文还将根据伊拉克一些工业的废热温度,讨论为ORC(有机朗肯循环)选择合适的有机液体来回收热量并将其转化为能源。此外,还将讨论如何选择适当的技术来保证这种热量的数量和质量。这将有助于减少能源浪费和空气污染。
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引用次数: 2
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Iraqi Journal of Industrial Research
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