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On the applicability of the rotational diffusion model in liquid crystalline solvents. A nuclear magnetic relaxation study of toluene 旋转扩散模型在液晶溶剂中的适用性。甲苯的核磁弛豫研究
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510220258100
J. Bulthuis, L. Plomp
The model of rotational diffusion in the presence of an orienting potential has been adapted to the case of an asymmetric top molecule in an orienting potential that is defined by two ordering parameters. It has been used to describe the relaxation by the quadrupolar mechanism of the deuterons in toluene, dissolved in «Phase V». No set of diffusion constants could be found, which simultaneously reproduce all spectral densities that were derived from the measured relaxation rates. Only very approximate agreement could be obtained with sets of diffusion constants in which two constants are of the same order of magnitude and the diffusion about the axis in the plane of the benzene ring and perpendicular to the axis of the methylgroup, is slower by an order of magnitude. The anisotropy in the viscosity of the solution has not explicitly been taken into account, but it has been indicated how this might be done. At this stage, therefore, no definitive conclusions can be drawn, but clearly the application of the rotational diffusion model in liquid crystalline solutions should be considered with care
定向势存在时的旋转扩散模型已适应于定向势由两个有序参数定义的不对称顶部分子的情况。它已被用来描述四极性机制的弛豫在甲苯中,溶解在«相V»。没有一组扩散常数可以同时再现由测量的弛豫速率得出的所有谱密度。在两个常数相同数量级的扩散常数组中,只能得到非常近似的一致性,并且在苯环平面上沿轴方向和垂直于甲基轴方向的扩散速度要慢一个数量级。溶液粘度的各向异性没有被明确地考虑在内,但已经指出了如何做到这一点。因此,现阶段还不能得出明确的结论,但显然转动扩散模型在液晶溶液中的应用应该慎重考虑
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引用次数: 14
Performance enhancement of Willshaw type networks through the use of limit cycles 利用极限环提高Willshaw型网络的性能
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510210238700
G. Kohring
Simulation results of a Willshaw type model for storing sparsely coded patterns are presented. It is suggested that random patterns can be stored in Willshaw type models by transforming them into a set of sparsely coded patterns and retrieving this set as a limit cycle. In this way, the number of steps needed to recall a pattern will be a function of the amount of information the pattern contains. A general algorithm for simulating neural networks with sparsely coded patterns is also discussed, and, on a fully connected network of N=36864 neurons (1.4×10 9 couplings), it is shown to achieve effective updaping speeds as high as 1.6×10 11 coupling evaluations per second on one Cray-YMP processor
给出了一种存储稀疏编码模式的Willshaw型模型的仿真结果。建议将随机模式转换为稀疏编码模式集合,并将该集合作为极限环检索,从而将随机模式存储在Willshaw型模型中。通过这种方式,回忆模式所需的步骤数将是模式包含的信息量的函数。本文还讨论了一种用于模拟具有稀疏编码模式的神经网络的通用算法,并且,在N=36864个神经元(1.4×10 9个耦合)的全连接网络上,它被证明可以在一个cry - ymp处理器上实现高达每秒1.6×10 11次耦合评估的有效更新速度
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引用次数: 2
Swollen lamellar phases between two solid walls : undulation forces and generation of defects 两个固体壁之间膨胀的片层相:波动力和缺陷的产生
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510220254300
O. Abillon, E. Perez
Nous avons mesure les forces entre deux surfaces de mica immergees dans une phase lamellaire gonflee a l'eau (CTAB/hexanol/eau salee). Les bicouches s'orientent parallelement aux surfaces de mica. Les courbes force-distance presentent des domaines ou l'eau est continument ejectee d'entre les lamelles, et des domaines ou le systeme saute rapidement a une autre distance en ejectant des lamelles. Nous avons etudie l'effet sur les forces d'un deplacement dans le diagramme de phases a periode spatiale constante et egalement le long de la ligne de dilution
我们测量了两个云母表面浸泡在水膨胀层状相(CTAB/己醇/盐水)之间的力。双层与云母表面平行。力-距离曲线显示的区域是水从片层之间不断喷射的区域,而系统通过喷射片层迅速跳到另一个距离的区域。我们研究了在恒定空间周期的相图中以及沿稀释线的位移对力的影响。
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引用次数: 18
Growth of two dimensional domains in copolymer thin films 共聚物薄膜中二维畴的生长
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510220257100
D. Ausserré, D. Chatenay, G. Coulon, B. Collin
L'apparition de domaines circulaires en relief a la surface de films de copolymeres bisequences deposes sur un solide soumis a une trempe est due a la formation d'un ordre lamellaire dans le film qui s'accompagne d'une quantification de son epaisseur locale. En admettant que la structure des bords des domaines est une simple dislocation, les equations decrivant l'evolution temporelle de la distribution de taille des domaines sont etablies
沉积在淬火固体上的等分共聚物薄膜表面的圆形凸起区域的出现是由于薄膜中层状顺序的形成,并伴随着局部厚度的量化。假设区域边缘结构是简单的位错,建立了描述区域大小分布时间演化的方程。
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引用次数: 26
Generalization in a Hopfield network Hopfield网络的泛化
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510210242100
J. Fontanari
The performance of a Hopfield network in learning an extensive number of concepts having access only to a finite supply of typical data which exemplify the concepts is studied. The minimal number of examples which must be taught to the network in order it starts to create representations for the concepts is calculated analitically. It is shown that the mixture states play a crucial role in the creation of these representations
研究了Hopfield网络在学习大量概念时的性能,这些概念只能接触到有限的典型数据。必须教给网络的最小数量的例子,以便它开始为概念创建表示,是通过分析计算的。结果表明,混合状态在这些表征的产生中起着至关重要的作用
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引用次数: 36
Monte Carlo simulation of collimated beam transmission through turbid media 准直光束通过混浊介质的蒙特卡罗模拟
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510220252100
S. Avrillier, E. Tinet, E. Delettre
An accurate Monte Carlo (MC) computer model is used to calculate the reflectances (R) and transmittances (T) of isotropic scattering media for the case of collimated beam illumination and for a wide range of absorption and scattering coefficients κ and σ per unit length. The MC results are presented by means of sets of curves with distance scaling in order to give an overall understanding of the subject. A simple diagram is constructed with accurate MC results and can be used for direct graphical determination of κ and σ from R and T measurements. The effects of reflections at the boundaries are described in the last section
采用精确的蒙特卡罗(MC)计算机模型计算了准直光束照射下各向同性散射介质的反射率(R)和透射率(T)以及单位长度的吸收和散射系数κ和σ的大范围。MC结果是通过距离缩放的曲线集来呈现的,以便对主题有一个整体的理解。用精确的MC结果构造了一个简单的图,可用于直接从R和T测量中确定κ和σ。最后一节描述了边界处反射的影响
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引用次数: 21
Theory of the formation of quasicrystals 准晶体形成的理论
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510210239900
V. Dmitriev, Yu. M. Gufan, S. Rochal, R. Toledano
A theoretical model is proposed for the formation of quasicrystalline alloys. The icosahedral phase is known to result from a reconstructive transition of the displacive type from a parent crystalline structure. Two order parameters are involved in the transition mechanism: a displacement field which transforms a number of sublattices into icosahedral clusters, and an icosahedral density wave which breaks incommensurately the initial translational order. The main features of the model are introduced through the illustrative example of AlMnSi Un modele theorique est propose pour expliquer la formation des alliages quasicristallins. La phase icosaedrique resulte dans ce modele, d'une transition reconstructive de type displacif a partir d'une phase mere cristalline. Le mecanisme de la transition met en jeu deux parametres d'ordre distincts: un champ de deplacements qui transforme certains sous-reseaux cristallins en assemblages icosaedriques, et une onde de densite qui brise de facon incommensurable l'ordre translationnel de la phase mere. Les principaux aspects de la theorie sont introduits a travers l'exemple de AlMnSi
提出了准晶合金形成的理论模型。二十面体相是由母体晶体结构的位移型重构转变而成的。跃迁机制涉及两个序参量:将若干亚晶格转化为二十面体簇的位移场和不相应地打破初始平动序的二十面体密度波。通过AlMnSi - Un模型理论的实例,介绍了该模型的主要特点,并提出了拟晶体形成的解释方法。La相二叠叠结果为结晶模型,d'une相变重构模型为部分d'une相纯结晶。过渡的机制是由两种不同的参数组成的:一种是位移,一种是转换,一种是结晶,一种是聚合,一种是密度,一种是聚合,一种是不可通约,一种是转化,一种是相变。《理论的基本方面》介绍了阿尔姆斯的一个例子
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引用次数: 3
A disordered lamellar structure in the isotropic phase of a ternary double-chain surfactant system 三元双链表面活性剂体系各向同性相中的无序层状结构
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510220260500
I. Barnes, P. Dérian, S. Hyde, B. Ninham, T. Zemb
et leurs predictions confrontees aux resultats experimentaux. Abstract. 2014 The « anomalous » fluid isotropic phase in the DDAB/tetradecane/water system differs in important ways from microemulsion phases in related systems, and is thus a useful test for models. On the basis of absolute scaled neutron and X-ray scattering data we show here that the microstructure is best characterised as a randomly folded reverse bilayer. All previously reported examples of this structure are restricted to a narrow range of composition and temperature. In this case of a stiff bilayer with low spontaneous interfacial curvature it extends over a large region of the ternary phase diagram at room temperature, the boundaries of which are explained in terms of simple geometric constraints. Other possible microstructures are
我们的预测与我们的实验结果相冲突。DDAB/十四烷/水体系中的“异常”流体各向同性相与相关体系中的微乳液相在许多重要方面有所不同,因此是对模型的有用测试。根据绝对尺度中子和x射线散射数据,我们在这里表明,微观结构的最佳特征是随机折叠的反向双分子层。所有先前报道的这种结构的例子都被限制在一个狭窄的组成和温度范围内。在这种情况下,具有低自发界面曲率的刚性双层在室温下延伸到三元相图的大片区域,其边界用简单的几何约束来解释。其他可能的微观结构有
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引用次数: 37
Spectral dimension of fluid membranes 流体膜的光谱维数
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510210239500
S. Komura, A. Baumgärtner
The spectral dimension d s of polymerized and fluid self-avoiding vesicles are investigated by Monte Carlo methods. For both cases we obtained d s =2, which indicates that these surfaces belong to the same class of «microcanonical» surfaces
用蒙特卡罗方法研究了聚合和流体自避囊泡的光谱维数。对于这两种情况,我们得到了d s =2,这表明这些曲面属于同一类“微正则”曲面
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引用次数: 3
Supersymmetry in hydrodynamics: vorticity as a ghost charge 流体力学中的超对称:涡度作为鬼荷
Pub Date : 1990-11-01 DOI: 10.1051/JPHYS:0199000510220250100
M. Altaisky, S. S. Moiseev
The path-integral approach to classical Hamiltonian dynamics (i.e. the functional-integral representation of classical transition probabilities), recently developed by Gozzi, is applied for studying the perfect fluid. In this way, by studying the symplectic structure of volume-preserving diffeomorphism the Thompson circulation theorem is shown to be equivalent to the conservation of ghost charge ― one of the generators related to the (graded) ISp(2) symmetry present in any Hamiltonian system
最近由Gozzi提出的经典哈密顿动力学的路径积分方法(即经典跃迁概率的函数积分表示)被应用于研究完美流体。这样,通过研究保体积微分同胚的辛结构,证明了汤姆逊循环定理等价于鬼荷守恒——鬼荷守恒是任何哈密顿系统中存在的与(梯度)ISp(2)对称相关的产生子之一
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