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Structural analysis of non-stoichiometric lithium cuprates, Li2+2xCu1-2xO2-x. Effects of lithium content and thermal treatments 非化学计量比的铜酸锂Li2+2xCu1-2xO2-x的结构分析。锂含量和热处理的影响
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1700
Luis Palacios, G. González, O. Ovalle-Encinia, E. Lima, E. Ramírez-Meneses, H. Pfeiffer
Lithium cuprate (Li2CuO2) is being used for a wide range of applications due to its high lithium diffusion through the layer structure. Moreover, Li2+2xCu1-xO2-x non-stoichiometric material shows enhanced physicochemical properties. Therefore, lithium location understanding is highly important for lithium cuprate applications. This paper reports the structural coherence analysis, local and long atomic arrangement of Li2+2xCu1-xO2-x using X-ray diffraction (XRD), pair distribution function (PDF) and solid-state nuclear magnetic resonance (NMR) techniques. Li2CuO2, containing different excess quantities of lithium (from 0 to 60 at%), were synthesized by solid-state reaction. The synthesized ceramics presented nonstoichiometric structures, with Li2CuO2 type-structure. Two structural models were proposed to explain the high enhancement physicochemical properties of these ceramics; (i) the extra lithium atoms substitute copper sites, and (ii) lithium species occupy interstitial sites in the crystalline structure. Additionally, further thermal treatments rearrange the non-stoichiometric crystalline structures into the stable Li2CuO2 phase.
铜酸锂(Li2CuO2)由于其通过层结构的高锂扩散性而被用于广泛的应用。此外,Li2+2xCu1-xO2-x非化学计量材料显示出增强的物理化学性质。因此,了解锂的位置对于铜酸锂的应用非常重要。本文利用x射线衍射(XRD)、对分布函数(PDF)和固态核磁共振(NMR)技术对Li2+2xCu1-xO2-x的结构相干分析、局域和长原子排列进行了研究。通过固态反应合成了含有不同过量锂(0至60at%)的Li2CuO2。合成的陶瓷呈现非化学计量结构,具有Li2CuO2型结构。提出了两个结构模型来解释这些陶瓷的高增强物理化学性质;(i) 额外的锂原子取代铜位点,以及(ii)锂物种占据晶体结构中的间隙位点。此外,进一步的热处理将非化学计量的晶体结构重新排列成稳定的Li2CuO2相。
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引用次数: 0
Unsaturated Polyester Resin/Aluminum Tri-hydroxide Added with Short Glass Fiber for Battery Box 电池盒用添加短玻璃纤维的不饱和聚酯树脂/氢氧化铝
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1904
S. Kaleg, S. Sudirja, A. C. Budiman, Amin Amin, A. Muharam, A. Hapid, K. Diharjo, D. Ariawan
A battery box made of polymer material must consider mechanical strengthand flame retardancy. One solution to increase the flame retardancy of polymers is toadd a flame retardant filler. However, sometimes adding a flame retardant filler cancause degradation of mechanical strength compared to neat polymers. The combinationof more than one type of filler or hybrid fillers can produce the optimal combination offlame retardancy and mechanical strength. An experimental study was carried out tocharacterize several composite polymer samples of unsaturated polyester (UP) resincombined with fillers of aluminum tri-hydroxide (ATH) to increase flame retardancyand short glass fiber (G) to improve mechanical strength. The DSC results show thatthe maximum endothermic of all samples occurred at a temperature of around 70 ºC.The TGA results prove that ATH and G can maintain the thermal stability of UP so thatthe composite samples were degraded at higher temperatures by reducing the rate ofweight degradation due to a temperature of around 0.1%/ºC. The burning test alsoshows that samples with ATH and G have a lower burning rate value than neat UP. Formechanical characterization, the tensile strength of the samples with ATH and G waslower than that of neat UP. However, UP/ATH/G2 showed an optimal compositioncompared to other filler compositions with a tensile strength of 41.5 MPa. This samplealso produces an optimal bending strength of 68.9 MPa and even higher than neat UP.These results were confirmed by SEM observations, in which filler G was exfoliated inthe UP. The broken G particles on the fracture surface observation prove the goodinterlock bonding between UP and G, which contributes to increasing the mechanicalstrength of the UP composite.
聚合物材料制成的电池盒必须考虑机械强度和阻燃性。提高聚合物阻燃性的一种解决方案是添加阻燃填料。然而,与纯聚合物相比,有时添加阻燃填料会导致机械强度下降。多种填料或混合填料的组合可以产生阻燃性和机械强度的最佳组合。对几种不饱和聚酯(UP)树脂与氢氧化铝(ATH)填料复合提高阻燃性能和短玻璃纤维(G)提高机械强度的复合聚合物样品进行了实验研究。DSC结果表明,所有样品的最大吸热发生在70ºC左右的温度下。TGA结果证明,ATH和G可以保持UP的热稳定性,因此复合材料样品在更高的温度下被降解,因为温度约为0.1%/ºC。燃烧试验还表明,具有ATH和G的样品具有燃烧速率值低于纯UP。在力学性能表征中,含有ATH和G的样品的拉伸强度低于纯UP的样品。然而,与拉伸强度为41.5MPa的其他填料组合物相比,UP/ATH/G2显示出最佳的组成。该样品还产生了68.9MPa的最佳弯曲强度,甚至高于纯UP。SEM观察证实了这些结果,其中填料G在UP中剥落。断裂表面观察到的断裂的G颗粒证明了UP和G之间的良好的键合,这有助于提高UP复合材料的机械强度。
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引用次数: 0
Chaotic logistic map sequences with good auto-correlation properties 具有良好自相关特性的混沌逻辑映射序列
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1786
Gerardo Laguna-Sanchez, Daniela Aguirre-Guerrero, Ismael Ariel Robles-Martinez
In this work, chaotic sequences with good auto-correlation properties are presented. The studied sequences are synthesized by means of the logistic map function and, been chaotic but fully deterministic, become a good alternative for well-known sequences, for example the Zadoff-Chu sequences, especially for small size sequences commonly used for frame synchronization purposes in digital communications systems. A new auto-correlation goodness metric is proposed, and it is employed as objective function in order to maximize the correlation goodness for short synchronization sequences synthesized by means the logistic map function.
本文提出了具有良好自相关特性的混沌序列。所研究的序列是由逻辑映射函数合成的,具有混沌但完全确定的特点,可以很好地替代已知的序列,如Zadoff-Chu序列,特别是用于数字通信系统中帧同步目的的小尺寸序列。提出了一种新的自相关优度度量,并以逻辑映射函数合成的短同步序列的相关优度最大化为目标函数。
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引用次数: 0
An intermediate water gravity wavelength and wave height measurement inside a large wave flume tank 大型波浪水槽中水重力波长和波高的测量
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1757
Safa M. Aldarabseh, P. Merati
This paper discusses an intermediate water gravity wavelength and wave height measurement method. Three methods were used to obtain wave height, wavelength, and period. Firstly, conventional methods used two Honeywell pressure sensors mounted at the bottom of the wave tank at two different locations. Secondly, using the transfer function of the flap wavemaker (the relationship between wave height and the wave paddle stroke). Thirdly, the Laser Sheet technique (PIV image processing technique). The significant wave height and period from pressure reading sensors of regular gravity waves were obtained from the Raleigh distribution and Zero up crossing technique. Wavelength was obtained indirectly by using a dispersion relationship that was solved by using the Newton Raphson numerical method from both the pressure sensors and the transfer function of the flap wavemaker. This experiment was focused on getting the direct value of wave measurements by developing an image processing technique in a clear large wave flume tank to replace the conventional methods and eliminate the error that may produce by using the numerical methods. The PIV setup with the CCD camera was used to capture wave images. The image processing technique based on Canny edge detection with constant threshold value was used to detect the edge of the waves. The experimental result showed a good agreement between the results obtained from these three methods, with the percent of error up to 8.683%.
本文讨论了一种中水重力波长和波高的测量方法。使用三种方法来获得波高、波长和周期。首先,传统方法使用两个霍尼韦尔压力传感器,安装在波浪箱底部的两个不同位置。其次,利用襟翼造波器的传递函数(波浪高度与波浪桨行程的关系)。第三,激光薄板技术(PIV图像处理技术)。利用Raleigh分布和零上交叉技术获得了规则重力波压力读数传感器的有效波高和周期。波长是通过使用色散关系间接获得的,该色散关系通过使用Newton-Raphson数值方法从压力传感器和襟翼造波器的传递函数求解。本实验的重点是通过在透明的大型波浪水槽中开发图像处理技术来获得波浪测量的直接值,以取代传统的方法,并消除使用数值方法可能产生的误差。利用CCD相机的PIV装置来捕捉波浪图像。采用基于恒定阈值Canny边缘检测的图像处理技术来检测波浪的边缘。实验结果表明,三种方法的结果吻合较好,误差率高达8.683%。
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引用次数: 0
Hybird RNN based feature extraction for early prediction of CVDs using ECG Signals for type 2 diabetic patients 基于混合RNN特征提取的2型糖尿病患者心电信号cvd早期预测
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1844
Tamilselvan Thangaraju, O. P. Sharma
Diabetes mellitus patients are at an increased risk of cardiovascular illness, and cardiovascular complications are the primary cause of morbidity. Diabetes is linked to both morbidity and mortality. Type-2 Diabetes causes a prothrombotic state that leads to acute coronary syndromes by causing endothelial damage and lowering antiaggregant factors like nitric oxide and prostacyclin, as well as increasing thrombotic substances like fibrinogen and factor VII, and suppressing fibrinolysis with factors like plasminogen activator inhibitors. The accurate identification and diagnosis of CVD (Cardio Vascular Disease) is dependent on the correct detection of the ECG signal from the heart. The ECG signal is extremely important in the early detection of cardiac problems. The ECG signal of diabetic individuals offers vital information about the heart and is one of the most important diagnostic tools used by doctors to identify cardiovascular disorders. The time gap between two consecutive QRS complexes appearing contiguous in an ECG is known as heart rate.  The most appealing feature is that HRV (Heart Rate Variability) measurement is non-invasive and repeatable. A number of machine learning techniques have been proposed for the non-invasive automated identification of diabetes. This paper discusses innovative methods for analyzing electrocardiogram (ECG) signals in order to extract important diagnostic information. The ECG signal is first treated using a dual tree complex wavelet transform (DTCWT-SG) with threshold method. Subsequently, the features are extracted from detailed coefficients of DTCWT-SG filter, Eigen vectors by minimum normalization method and Rajan Transform. Main key features are extracted using these three methods. These features are classified and analyzed by different machine learning classifiers. The proposed approach was tested on DICARDIA, MIT-BIH and Physionet database and the performance analysis shows that the hybrid Recurrent Neural Network (RNN) (LSTM+GRU Gated Recurrent Units) achieves better prediction of 98.8% compared to state of art techniques.
糖尿病患者患心血管疾病的风险增加,心血管并发症是发病的主要原因。糖尿病与发病率和死亡率都有关。2型糖尿病通过引起内皮损伤和降低抗聚集因子如一氧化氮和前列环素,以及增加血栓形成物质如纤维蛋白原和因子VII,以及抑制纤溶酶原激活物抑制剂等因子的纤维蛋白溶解,导致血栓形成状态,从而导致急性冠状动脉综合征。准确的识别和诊断CVD(心血管疾病)依赖于正确检测来自心脏的ECG信号。心电信号在心脏疾病的早期检测中具有极其重要的意义。糖尿病患者的心电图信号提供了关于心脏的重要信息,是医生用来识别心血管疾病的最重要的诊断工具之一。在心电图上连续出现的两个QRS复合体之间的时间间隔称为心率。最吸引人的特点是HRV(心率变异性)测量是非侵入性和可重复的。许多机器学习技术已经被提出用于糖尿病的非侵入性自动识别。本文讨论了分析心电图信号的创新方法,以提取重要的诊断信息。首先采用带阈值法的双树复小波变换对心电信号进行处理。然后,通过最小归一化方法和Rajan变换从DTCWT-SG滤波器的详细系数、特征向量中提取特征。利用这三种方法提取了主要的关键特征。这些特征通过不同的机器学习分类器进行分类和分析。该方法在DICARDIA、MIT-BIH和Physionet数据库上进行了测试,性能分析表明,与现有技术相比,混合递归神经网络(RNN) (LSTM+GRU门控递归单元)的预测率达到了98.8%。
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引用次数: 0
Properties of hydroxyapatite from tilapia (Oreochromis niloticus) bones: An approach towards its potential use as a dye adsorbent 罗非鱼(Oreochromis niloticus)骨中羟基磷灰石的性质:其作为染料吸附剂的潜在用途
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1903
C. O. García-Sifuentes, Beatriz Guadalupe González-González, H. Santacruz-Ortega, F. Brown‐Bojorquez, Rosa Elena Navarro-Gautrín, Rocío Sugich-Miranda, E. Carvajal‐Millan
The properties of hydroxyapatite (HAp) obtained from tilapia (Oreochromis niloticus) bones and its potential use as a dye adsorbent using methyl orange (MO) as a model dye were evaluated. HAp was produced by the calcination of dried tilapia bones at 900 °C for 4 h. Then, HAp was characterized using thermogravimetric (TGA) and differential thermogravimetric (dTG) analyses, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM) and energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), x-ray diffraction (XRD), among others. The HAp obtained was used for MO dye adsorption in a batch process. The yield of HAp was 51.6%. FTIR showed characteristic bands of functional groups of HAp [OH- and (PO4)3-]. FESEM images showed HAp with different morphologies and a porous surface. The EDS analysis indicated the presence of calcium and phosphorus with an atomic ratio of Ca/P of 1.60, TEM images revealed the formation of agglomerates and an average particle size of 655.1 nm. HAp and β-tricalcium phosphate (β-TCP) phases were identified through XRD. The HAp point of zero charge (pHpzc) was 9.7 indicating a possible adsorption of anionic dyes at pH< pHpzc and cationic dyes at pH> pHpzc. The HAp was able to successfully adsorb 82.6% of MO dye from aqueous solution. These findings demonstrated that the HAp obtained from tilapia (O. niloticus) bones possesses suitable properties to be used as a potential material to remove dyes.
以甲基橙(MO)为模型染料,研究了从罗非鱼(Oreochromis niloticus)骨中提取的羟基磷灰石(HAp)的性能及其作为染料吸附剂的潜力。将罗非鱼干骨在900℃下煅烧4 h制备HAp,然后利用热重(TGA)和差热重(dTG)分析、傅里叶变换红外光谱(FTIR)、场发射扫描电镜(FESEM)和能谱(EDS)、透射电镜(TEM)、x射线衍射(XRD)等对HAp进行表征。所得HAp用于MO染料的间歇吸附。HAp的产率为51.6%。FTIR显示HAp [OH-和(PO4)3-]官能团的特征波段。FESEM图像显示HAp具有不同的形貌和多孔表面。能谱分析表明,样品中存在钙和磷,Ca/P原子比为1.60;透射电镜显示,样品中存在团聚体,平均粒径为655.1 nm。通过XRD对HAp和β-磷酸三钙(β-TCP)相进行了鉴定。零电荷点(pHpzc)为9.7,表明在pH< pHpzc时阴离子染料可能被吸附,在pH> pHpzc时阳离子染料可能被吸附。HAp能成功吸附82.6%的MO染料。这些发现表明,从罗非鱼(O. niloticus)骨骼中获得的羟基磷灰石具有合适的性能,可以作为一种潜在的去除染料的材料。
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引用次数: 0
Performance analysis on the low-power energy harvesting wireless sensor networks with a novel relay selection scheme 基于新型中继选择方案的低功耗能量采集无线传感器网络性能分析
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1846
Hoang-Sy Nguyen, Hoang-Phuong Van
Simultaneous wireless information and power transfer (SWIPT) has been utilized widely in wireless sensor networks (WSNs) to design systems that can sustain themselves by harvesting energy from the surrounding areas. In this study, we investigated the performance of the so-called low-power energy harvesting (LPEH) WSN. Being different from other studies, we equipped each relay with a battery whose characteristics were described by an on/off (1/0) decision scheme as per the Markov property. In this context, an optimal loop interference relay selection (OPLIRS) was proposed and investigated. Moreover, the crucial role of the log-normal distribution method in characterizing the LPEH WSN’s constraints was proven and emphasized. The system performance was evaluated in terms of the overall ergodic outage probability (OP) both analytically and numerically with Monte Carlo simulation. Readers can refer to this paper for guidelines on defining the networks’ constraints, analytically derivating the problems, or use the presented results for possible comparison studies.
同时无线信息和功率传输(SWIPT)已在无线传感器网络(WSN)中被广泛用于设计能够通过从周围区域获取能量来维持自身的系统。在本研究中,我们研究了所谓的低功率能量采集(LPEH)WSN的性能。与其他研究不同的是,我们为每个继电器配备了一个电池,其特性由根据马尔可夫特性的开/关(1/0)决策方案描述。在此背景下,提出并研究了最优环路干扰中继选择(OPLIRS)。此外,还证明并强调了对数正态分布方法在表征LPEH WSN约束方面的关键作用。通过蒙特卡洛模拟,从分析和数值两个方面,根据总体遍历中断概率(OP)对系统性能进行了评估。读者可以参考这篇论文,以获得关于定义网络约束、分析推导问题的指南,或者将所提供的结果用于可能的比较研究。
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引用次数: 0
Recovery of Membrane Permeability after Filtration of Sago Starch Suspension by Tangential Flow Filtration 切向流过滤法过滤Sago淀粉悬浮液后膜渗透性的恢复
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1814
O. Carvajal-Zarrabal, Samantha Ling Chee Siong, M. Abdullah, Y. Tan, Esaki Shoji, M. Morales-Mora, J. Carrillo-Ahumada, C. Nolasco-Hipólito
Sago starch is extracted from the stems of the sago palm, Metroxylon sagu, in south-east Asia. Sago starch processing generates approximately 20 tons of starch containing effluents that can be recovered and marketed to sustain a small-scale industry. Tangential flow filtration (TFF) using microfiltration membranes (MFM) has been demonstrated as an effective method for separating suspended solids in biological effluents. When TFF was applied to concentrate sago starch suspensions (SSS), membrane permeability and lifecycle were impacted due to frequent fouling. This study evaluated cleaning methods to recover the permeability and extend the lifecycle of MFM following TFF application. Polysulfone membrane filter cassettes of pore size 0.45 µm and surface area 0.1 m2 were each used to separate starch in 100 L of SSS. Following separation, six chemical and physical cleaning methods were tested at laboratory-scale and the degree of cleaning was measured by normalized permeate flux (NPF) and normalized water permeability (NWP). The results showed that soaking the membranes in a 0.2 M NaOH solution (up to 91%, (p<0.05) within the shortest time of 72 h, (p<0.05) was the best cleaning method. The procedure has been utilized to maintain and extend the lifecycle of the MFM for streams containing starch suspensions.
西米淀粉是从东南亚的西米棕榈(Metroxylon sagu)的茎中提取的。Sago淀粉加工产生大约20吨含淀粉的废水,这些废水可以回收并销售,以维持小规模工业。使用微滤膜(MFM)的切向流过滤(TFF)已被证明是分离生物废水中悬浮固体的有效方法。当TFF用于浓缩西米淀粉悬浮液(SSS)时,由于频繁的结垢,膜的渗透性和寿命受到影响。本研究评估了TFF应用后恢复渗透性和延长MFM使用寿命的清洁方法。孔径0.45µm、表面积0.1m2的聚砜膜滤盒分别用于分离100L SSS中的淀粉。分离后,在实验室规模上测试了六种化学和物理清洁方法,并通过归一化渗透通量(NPF)和归一化透水性(NWP)测量清洁程度。结果表明,在最短的72小时内(p<0.05),将膜浸泡在0.2M NaOH溶液中(高达91%,(p<0.01)是最佳的清洗方法。该程序已被用于维持和延长含有淀粉悬浮液的流的MFM的生命周期。
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引用次数: 0
Event-driven Architecture and REST Architectural Style: An Exploratory Study on Modularity 事件驱动架构和REST架构风格:模块化的探索性研究
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1764
Kleinner Farias, Luan Lazzari
Event-driven architecture has been widely adopted in the software industry, emerging as an alternative to the development of enterprise applications based on REST architectural style. However, little is known about the effects of event-driven architecture on modularity while enterprise applications evolve. Consequently, practitioners end up adopting it without any empirical evidence about its impacts on essential indicators, including separation of concerns, coupling, cohesion, complexity, and size. This article, therefore, reports an exploratory study comparing event-driven architecture and REST style in terms of modularity. A realistic application was developed using an event-driven architecture and REST through ve evolution scenarios. In each scenario, a feature was added. The generated versions were compared using ten metrics. The initial results suggest that the event-driven architecture improved the separation of concerns, but was outperformed considering the metrics of coupling, cohesion, complexity and size. The findings are encouraging and can be seen as a first step in a more ambitious agenda to empirically evaluate the bene ts of event-driven architecture against the REST architectural style.
事件驱动的体系结构在软件行业中被广泛采用,作为基于REST体系结构风格的企业应用程序开发的替代方案而出现。然而,在企业应用程序发展的过程中,事件驱动的体系结构对模块化的影响知之甚少。因此,从业者最终采用了它,而没有任何关于它对基本指标的影响的经验证据,包括关注点分离、耦合、内聚、复杂性和大小。因此,本文报告了一项探索性研究,比较了事件驱动架构和REST风格在模块化方面的差异。通过五个演进场景,使用事件驱动架构和REST开发了一个实际的应用程序。在每个场景中,都添加了一个特性。生成的版本使用十个指标进行比较。最初的结果表明,事件驱动的体系结构改善了关注点的分离,但考虑到耦合、内聚、复杂性和大小的指标,它的表现要好得多。这些发现是令人鼓舞的,并且可以被看作是更雄心勃勃的议程的第一步,以经验评估事件驱动架构与REST架构风格的优势。
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引用次数: 1
A nature-inspired algorithm to find community structure in complex networks 一种在复杂网络中寻找社区结构的自然启发算法
Q3 Engineering Pub Date : 2023-06-27 DOI: 10.22201/icat.24486736e.2023.21.3.1787
Bilal Saoud
Complex networks have in generally communities. These communities are very important. Network’s communities represent sets of nodes, which are very connected. In this research, we developed a new method to find the community structure in networks. Our method is based on flower pollination algorithm (FPA) witch is used in the splitting process. The splitting of networks in our method maximizes a function of quality called modularity. We provide a general framework for implementing our new method to find community structure in networks. We present the effectiveness of our method by comparison with some known methods on computer-generated and real-world networks.
复杂的网络通常在社区中。这些社区非常重要。网络的社区代表了节点的集合,这些节点是紧密相连的。在这项研究中,我们开发了一种新的方法来寻找网络中的社区结构。我们的方法是基于花授粉算法(FPA),它被用于分割过程。在我们的方法中,网络的分割最大化了一个称为模块化的质量函数。我们提供了一个通用的框架来实现我们在网络中寻找社区结构的新方法。通过与一些已知方法在计算机生成和现实世界网络上的比较,我们证明了我们的方法的有效性。
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引用次数: 0
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Journal of Applied Research and Technology
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